US3219473A - Method of coating and smoothing wood surface - Google Patents
Method of coating and smoothing wood surface Download PDFInfo
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- US3219473A US3219473A US421819A US42181964A US3219473A US 3219473 A US3219473 A US 3219473A US 421819 A US421819 A US 421819A US 42181964 A US42181964 A US 42181964A US 3219473 A US3219473 A US 3219473A
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- wood
- nib
- product
- rubbing
- buffing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N7/00—After-treatment, e.g. reducing swelling or shrinkage, surfacing; Protecting the edges of boards against access of humidity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/06—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to wood
- B05D7/08—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to wood using synthetic lacquers or varnishes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/12—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by mechanical means
Definitions
- the present invention relates to the art of finishing wood panels and like products which present a smooth, regular, porous, firm, heat-insulating, flat-faced whitewood or equivalent surface. More particularly, the invention is directed to an improved method of rapidly processing said surface into a shiny substantially nibfree coated surface of stainable porosity which is stabilized against nib-raising and capable of receiving conventional fiinishing materials such as a top coat with or without an intervening base coat.
- An important object of the present invention is to provide a novel method of producing a rubbed porous-coated wood surface which, in comparison with a scuff-sanded porous Wash-coated or size-coatd wood surface, is improved in one or more of the following respects: in smoothness; in shineiness or gloss; in freedom from nibs; in attractiveness of appearance; in its ability to resist the penetration of liquids, including subsequent coating materials, and in the uniformity of its resistance; in its ability to produce equal or superior finishing results with less finishing materials; and in its stability against nibraising.
- important objects of the present invention are: (l) to produce a smooth shiny substantially nib-free coated and rubbed wood surface of stainable porosity having a more uniform appearance than, and an increased gloss over, that which is possessed before the coating operation; (2) to produce a porous-coated surface which is stabilized against nib raising; and (3) to produce an otherwise superior surface finish suitable for various uses, including the application of conventional finishing materials and particularly suited for interior use.
- Another important object is to accomplish all of the more important objects of this invention in a simple and inexpensive method capable of being rapidly performed in a production line.
- the present invention resides in my discovery of an improved method for eliminating upstanding nibs from the flat face of a wood, hardboard, chipboard or other like cellulosic product, having a smooth regular porous firm white-wood or equivalent surface, as that product 3,219,473 Patented Nov.
- My improved method pressure smoothes said coated surface into a substantially nib-free state, having a more uniform appearance than (and a substantially increased gloss over) that of the same surface before the coating operation.
- the rubbed coating on that surface not only stabilizes it against nib-raising but renders it capable of accepting subsequent coating materials more uniformly than it could before the coating operation.
- the rubbing conditions also insure that the rubbed surface shall have a stainable porosity because, if that surface is not porous before the rubbing operation, it will become porous as a result of the rubbing operation, and, if it is porous before the rubbing operation, it will remain porous after that operation. After one pass under most conditions of operation, the surface of the coating material is tack-free and hard.
- FIG. 2 is a somewhat schematic view of a device for practicing the coating step of my invention wherein a wood panel or the like is coated with a plastic material;
- FIG. 3 is a somewhat schematic view of the apparatus used for practicing that rubbing step of my invention wherein a coated panel or the like is rubbed to glossify its coating,
- the production line shown in FIG. 1 includes suitable conveying means for carrying a wood panel or the like successively through the following equipment, viz: (a) a rubbing machine R1 of the type disclosed in the Alexander U.S. Patent No. 2,827,935, which machine uses the frictional heat and pressure of a high speed rubbing operation to pressure smooth, glossify and density a thin surface layer of an uncoated or white-wood panel; (b) a coating machine C which operates to coat the rubbed white-wood surface with a suitable wood-finishing plastic material; (c) a pair of heaters H1 and H2 for heating the plastic coated surface primarily to drive off the solvent if any and thereby prepare it for the next rubbing operation; ((1) a rubbing machine R2, which may be the same as R1, for practicing the rubbing step of the present invention so as to achieve the objects of the present invention including the glossification of the surface of the coated panel; and (e) another similar rubbing machine R3 for repeating the rubbing operation to improve the gloss.
- the coating machine may be of conventional form.
- One such form as shown includes: a supply trough T for holding a supply bath of the plastic material; a plastic material applicator A in the form of a soft rubber roller coater having a durometer of about 6 to 10', said coater rotating on a fixed axis with its lower side immersed in the plastic material bath; a spring-loaded Wiper W for wiping the plastic material deposited by the applicator A; and a spring-loaded drive assembly, including a drive roll D1 directly over the roller coater A and another drive roll D2 directly over the wiper W, for driving (through the coater) the wood product being coated thereby.
- the spring-loaded drive assembly is mounted on bracket B which can be vertically adjusted to produce a gap of desired size between the drive rolls D1 and D2 and their respective opposite, i.e. the roller coater A and the wiper W.
- the roller coater A and the drive rolls D1 and D2 are all driven at the same speed.
- the drive assembly which is heavily spring-loaded, is vertically adjusted to an elevation such as to provide a minimum gap of slightly smaller vertical width than the vertical thickness of the panel so that when the panel passes through the coater, it will raise the drive rolls D1 and D2 to a small extent but nevertheless large enough to insure a satisfactory pressure on both sides of the panel for panel driving and coating purposes. If the resulting wiper pressure is too heavy, the wiper W, which is more lightly spring-loaded, may be adjusted to insure a lighter pressure for wiping purposes. In other words, the yield of the wiper W to the pressure of the springloaded drive assembly may be adjusted. No claim of novelty is made as to the specific form of coating mechanism, the heaters, or the conveyors illustrated in the drawing.
- the apparatus shown in FIG. 3 includes a pair of horizontally spaced and aligned conveyor sections or portions 1 and 2, each of which contains a plurality of freely rotatable rollers 3.
- the upper surfaces of the rollers 3 project slightly above the surface of the conveyor frame to support a piece of plywood or a planar wood product such as a flush door or wall panel 4.
- the wall panel 4 is freely movable on the rollers 3.
- the adjacent spaced ends of conveyor portions 1, 2 are mounted on correspondingly spaced brackets 5, 6 which are secured by any suitable means, such as welding, to upstanding supporting members 7, 8, of inverted L-shape.
- the supporting members 7, 8 are also provided with upwardly turned lip portions 7a, 8a, respectively, which are spaced from each other to define an opening 9 between them.
- the opening 9 is arranged to receive an arcuate portion of a cylindrical member or contact drum 10 fixedly mounted on drive shaft 11, which is driven by any suitable driving means such as a motor (not shown).
- This contact drum 10 is preferably approximately 16 inches in diameter but may be of any diameter desired according to the size of the apparatus shown in the drawing, and is preferably covered with one or more cylindrical layers or sleeves 10a, composed of rubber or other suitable yieldable material so that the roll can compel the belt to conform to uneven or irregular surfaces. If rubber is used it may be vulcanized to the surface of the drum 10.
- the arcuate portion of the drum 10, which extends through the opening 9, is positioned for tangential engagement with the under surface of a panel positioned on the conveyor rollers 3.
- a continuous or endless surface treating belt 12 preferably composed of cork or containing a cork surface, is arranged around the peripheries of the rotating contact drum 10 and an idler drum 13, which is fixedly mounted for rotating movement on a shaft 14 supported in any suitable manner.
- the drums 10 and 13 are rotated by drive shaft 11 in the counterclockwise direction indicated by arrows D and I, the idler drum 13 being used to maintain the desired tension in the surface treating belt 12.
- a surface treating belt having a cork surface e.g., as exemplified by the belts presently made under U.S. Patent 2,542,058, except that the very mild abrasive sometimes employed in such cork belts is unnecessary and may be omitted.
- Any other relatively nonabrasive polishing frictional belt material such as canvas, or other cloth made of natural or synthetic fibers, may be employed so long as it is capable of'frictionally developing the requisite temperature when the requisite operating conditions are employed, and of withstanding both the operating temperatures and pressures.
- belts composed of asbestos cloth, popped perlite or expanded vermiculite may be used.
- the asbestos cloth belt should be sized in a 2% animal glue solution and then dried under tension in order to stiffen it and thereby prevent its wrinkling during use.
- the vermiculite and perlite particles should be uniformly sized in the same manner as cork particles. This means that the particles should be of uniform size to get the highest percentage of rubbing area and that the uniform size used should be small for hard wearing particles and progressively larger for the progressively softer wearing particles which tend more and more rapidly to wear out.
- the panel 4 is rapidly moved from left to right along the conveyor by a feed roll 15, which is arranged above and in contact with the upper surface of the panel.
- the feed roll 15 is preferably covered with rubber in the conventional manner to increase traction and is driven in the direction of the arrow F by means of a shaft 16 on which the roll 15 is fixedly mounted.
- the shaft 16 is supported on any suitable type of resilient bearing pedestal (not shown) which permits a limited amount of vertical movement so that the roll 15 will exert a downward pressure on the work in the direction of the arrow P.
- the weight of the roll itself may be augmented, if desired, by auxiliary weights, springs or other means for exerting the required downward pressure, which should be substantial.
- the shaft is preferably driven by means of a belt 17 which is arranged around the shaft 16 in such a manner as to pull downwardly on the shaft 16 as it is being driven.
- a panel 4 is fed into the space between drums 10 and 15.
- the substantial pressure of the roll 15 against the panel forced the undersurface of that panel downwardly against the treating belt 12 as the panel passes therebetween.
- the panel is fed or propelled by the feed roll at a linear speed approximating the peripheral speed of the feed roll, there being relatively little or no slippage therebetween.
- the contact drum 10 drives the surface treating belt in a direction opposite to that of the panel and at a substantially higher speed. Under these conditions, a temperature, high enough to soften the applied plastic material, is believed to be momentarily produced on the surface of the panel along the line of contact between the belt and the panel.
- the temperature produced may also soften the lignin in the surface Wood and the surface wood itself momentarily, and more or less instantaneously, without softening the underlying wood structure of the panel.
- the pressure exerted against the panel along the same line of contact may compress and densify the softened surface wood without compressing or densifying the underlying wood structure.
- the softened plastic flows and more completely fills the pores of the surface layer. Since heat and pressure are thus applied to the panel progressively along its length, the surface of that panel is progressively improved in a like manner.
- the same operating conditions effective on natural wood are applicable to artificial wood products.
- Natural wood in its many available forms including plywood, and also artificial wood products, such as untempered hard board, chip stock and the like, may be satisfactorily treated in accordance with the method of this invention.
- a wide variety of plastic materials have been found to be suitable for the purposes of this invention.
- plastic materials is intended broadly to include synthetic and natural materials of the size-coat or wash-coat type, having film-forming binders of a resinous nature, which embrace natural and synthetic resins, including cellulose derivatives, each binder of which (1) is capable of flowing and penetrating the wood to which it is applied, at least when dissolved or suspended in a liquid vehicle, (2) is either a solid or liquid after removal of the evaporable vehicle, (3) is capable of flowing under heat and pressure, and (4) thereafter assumes a rigid or hardened condition.
- plastic in its final hardened form should remain hard at the temperatures to which it will be subject in use; and it must be capable of satisfactorily accepting a top coating of lacquer, varnish or paint directly or with an intervening base coat.
- the plastic in its final form should be resistant to the solvents, plasticizers and other ingredients normally contained in siccative finishing materials if they are to be applied.
- plastic materials or plastic additives all are of the film-forming type. They must be thin enough to absorb and penetrate into the wood surface being processed. They constitute a synthetic or natural coating composition capable of forming a film (a) upon the evaporation of a liquid volatile in which its solids are dissolved (or suspended) or (b) by chemical reaction, such as polymerization, or (c) by evaporation and chemical reaction.
- a thin pentrating coat designated wash-coat by some woodworker and size-coat by others, is conventionally employed on white wood for the purpose of stiffening and raising the nibs to facilitate their removal by a scuffsanding operation. Since the practice of my invention and the prior art practice of wash-coating (or size-coating) and scuff-sanding both involve the use of a penetrating coat placed on white wood for the purpose of promoting the production of a nib-free surface by a subsequent rubbing operation, I propose to use the term nib-coat to designate generally those penetrating coats,
- the nib-coated surface has a more uniform appearance and a substantially increased gloss. It also has the capati bility of accepting subsequent coats of Wood-finishing materials more uniformly.
- thermoplastic materials which possess the qualifications necessary to function as nib-coats, embrace both the thermoplastic and thermosetting types of plastic materials. For most purposes, the thermosetting plastic materials are preferred.
- Suitable plastic materials which may be used for the purposes of this invention are the phenolaldehyde resins, such as phenol-formaldehyde resins, phenol-furfural resins, melamine-formaldehyde resins, urea-formaldehyde resins, heat-convertible alkyd resins, and polyester resins.
- phenolaldehyde resins such as phenol-formaldehyde resins, phenol-furfural resins, melamine-formaldehyde resins, urea-formaldehyde resins, heat-convertible alkyd resins, and polyester resins.
- the alkyd or polymerizable polyesters that may be utilized are any of the unsaturated polyhydric alcohol polycarboxylic acid polyesters made from unsaturated polycarboxylic acids and/ or unsaturated polyhydric alcohols either in admixture with a cross-linking monomer such as styrene, diallyl phthalate, triallyl cyanurate, and others, which resins cure without giving off by-products, or in admixture with drying oil components to form more conventional alkyd resins which cure by splitting out water.
- a cross-linking monomer such as styrene, diallyl phthalate, triallyl cyanurate, and others
- a preferred type of polyester is essentially a condensation product of a dihydric alcohol and a dicarboxylic acid, such as maleic acid or anhydride, or fumaric acid, a polyester of saturated dihydric alcohols such as the ethylene, propylene and butylene glycols, with or without modifying amounts of saturated dicarboxylic acids such as phthalic anhydride, tetrachlorophthalic anhydride, succinic acid, adipic acid, and others.
- These preferred polyesters when mixed with a suitable monomer are preferably in thin liquid form or made into liquids by the use of suitable solvents or dispersed as an emulsion.
- polyester materials may be catalyzed with peroxide-type catalysts such as benzoyl peroxide, methyl ethyl ketone peroxide, hydroperoxides, metal driers such as cobalt naphthanate, etc., and cured at temperatures ranging from room temperature to 200 C. or more. Small proportions of trihydric alcohols or tricarboxylic acids, or alcohols and carboxylic acids of higher functionality, may be incorporated in the polyester molecule, if desired.
- a suitable resin is produced from glycerol and phthalic anhydride.
- alkyd resins which, per se, are not heat-convertible if such resins are modified by adding a small proportion of a heat-convertible material thereto such, for example, as dimethyl phthalate, glycerol phthalate, etc.
- thermoplastic materials examples include the polyamides, and vinylidene chloride acrylo-nitrile resins commercially marketed under the trade names nylon and Saran, respectively, the trifluorochloro-ethylene resins marketed under the trade name Kel-F and vinyl chlorideacetate resins, vinyl-formal resins, methyl methacrylate and polymethyl alphachloro acrylate resins, etc.
- the above resins should be either in liquid form as produced or convertible into a liquid by the use of evaporable solvents, or dispersed as an emulsion in water. It is satisfactory to use partially condensed resins of the formaldehyde type in water solution; but, because water tends to cause raising of the surface grain, it is preferred to employ hydrocarbon, alcohol or other organic solvents when possible.
- thermosetting resins such as the phenol-formaldehyde, melamine-formaldehyde, etc., are employed, it is preferable that the polymerization of the plastic solids be relatively far advanced so that while fur ther polymerization occurs from the heat supplied by the friction member the quantity of polymerization necessary is kept near a minimum.
- the plastic is preferably maintained in a sufliciently fluid condition to render it relatively easy to impregnate or interpenetrate the pores of the Wood surface by merely brushing, rolling, or spraying the plastic on the surface to be treated.
- thermoplastic materials or partially polymerized thermosetting materials are used,
- the desired fluidity is obtained by dissolving or suspending them in a suitable liquid vehicle which is evaporated prior to the friction treatment.
- Plastic materials or nib-coats are characterized by the fact that their resin or plastic content is solidifiable (and thus capable of forming a firm film when applied to a suitable surface) either upon evaporation of a liquid vehicle in which it is dissolved or suspended or by the polymerization or both, and that they are in a soft or softened state during the rubbing treatment and that they are hard or hardened, thereafter, at room temperatures.
- resinous nib-coats composed of either or both thermoplastic and thermosetting resins. I particularly prefer those which harden (or solidfy) quickly either on application of heat or evaporation of solvent or both, because they permit the use of a rapid mass production process, such as that illustrated and described above.
- the preferred quantity of plastic solids in the finished surface resulting from the method of this invention varies somewhat depending upon the amount of material more or less permanently taken up by the wood.
- the dry weight of plastic solids, after it has been applied to the wood ranges from /2 pound to 7 /2 pounds per 1000 square feet of wood surface
- the dry weight of the plastic solids taken up by and remaining with the wood at the end of the rubbing operation will inherently vary from about .5 pound per 1000 square feet for the dense close grained woods to about 1.25 pounds for the softer more porous woods such as Douglas fir, pine and luaun.
- the solvent or vehicle normally employed in it may be removed by any conventional method of drying, including drying in the air, countercurrent forced air drying, heating, etc.
- drying in the air countercurrent forced air drying, heating, etc.
- the temperature of the plastic should be kept below the temperature at which it will cure to rigid form during the drying operation.
- the solvent or vehicle is first evaporated from the plastic material on the surface, the contacting of that plastic-impregnated surface with the high-speed frictional surface tends to cause gumming of the frictional surface and in the case of some solvents would cause a fire hazard and is therefore undesirable.
- the method of this invention impregnates only a very thin surface layer of wood. Where natural wood densification occurs, it also is limited to said very thin surface layer. Although it is not known for certain it is believed that the high temperature which results from the treatment with the apparatus shown in the drawing is, in conjunction with the simultaneously applied pressure, responsible for the uniform distribution in the surface layer of the various plastic materials including those which have not heretofore been considered satisfactory for impregnating wood.
- thermosetting plastic materials a portion of the heat functions to further polymerize or cure the plastic solids and thus advance them toward a hard infusible condition in situ in the pores of the surface wood.
- One of the virtues of the process is that when a thermosetting resin is used, which will cure slowly at room temperature, the friction treatment need only cure the outermost surface of the plastic, and this is accomplished in a small fraction of a second.
- temperatures employed should fall within or exceed the lignin softening-melting range of 400 F.525 F., a temperature well above the conventional softening temperatures for thermoplastic resins and the curing temperatures for most of the thermosetting resins.
- the preferred operating temperatures may exceed the above range so long as the contact time is reduced sufficiently to prevent charring of the surface wood in all instances and scorching in those instances where it is objectionable.
- the work feed rate, the belt speed and the pressure must be correlated to effect the softening of the above mentioned plastic materials and to produce the desired improvement of the desired thin layer without charring and in most cases without scorching the wood.
- the desired results are believed to be achieved when the temperatures developed are high and since only a very thin layer of wood is heated, it is desirable to complete the treatment with the apparatus of the drawing within a time period of less than half a second when natural wood is treated, and preferably within a period not exceeding A of a second.
- the period of treatment depends on the width of the rubbing contact band and the rate of feed or feed speed of the work. With the 16-inch rubber covered drum of the apparatus of the drawing, it is estimated that the width of the band of contact is about inch when the pressure applied by feed roller 21 is 7% pounds per lineal inch of roller length.
- the same limitations on time of treatment are applicable to each treatment in those cases mentioned hereafter in which the wood is passed through the apparatus two or more times.
- the temperature developed during the treatment for any given rate of work feed and width of pressure contact depends on the pressure and the belt speed, increasing as either or both of these factors increase and vice versa. I believe that the best results are achieved when the temperature developed closely approaches the scorch ing temperature of the wood for the treatment time employed.
- the presence of residual evaporable solvent or other vehicle in the plastic on the surface at the instant of contact by the friction member holds down the temperature which is attained since a portion of the heat is employed in completing the evaporation of that solvent.
- the applied plastic material be substantially free of evaporable vehicle or solvent before contact with the friction member. For this reason it is also undesirable to apply the process of this invention to green wood or wet wood.
- a single pass of the treated surface beneath the roll 10 at a feed rate of feet per minute or more is insufficient to completely polymerize or cure some thermosetting plastic materials to their hard infusible condition.
- the work feed rate may be decreased or the surface may be passed beneath the roll 10 repeatedly.
- a satisfactory cure of at least the outer surface has been obtained by a single pass through the apparatus of the drawing at a belt speed of about 4000 feet per minute and a work feed rate of 90 feet per minute, but a slight improvement in surface appearance is noted on a second pass. Additional passes may be required when phenol-formaldehyde, polyamides or polyester resins are employed, and may also be required if any significant quantity of evaporable vehicle remains in the plastic when it is given the first treatment.
- the maximum pressure exerted during the treatment of natural wood may be varied widely.
- the actual maximum pressure exerted by the apparatus of the drawing is difficult to determine since it varies over the narrow band of contact from zero at the extreme edges of the band to a maximum pressure at the center.
- the pressure is believed to cause a fiow of the heated plastic and either rub off softened plastic material which lies on the surface or force it into the pores of the wood or both.
- Excellent results have been obtained when the diameter of drum is 16 inches and the downward pressure exerted by roller ranges from 7 /2 pounds to 15 pounds per lineal inch of contact between the belt and the Wood surface along the length of the roller.
- Rubbing pressures of the above-noted order also render the buffing medium inherently capable of removing substantially all of any excess coating material on the panel during one pass of the panel through the rubbing zone and they cause the bufiing medium to work compressively against the resistance of the wood, as distinguished from the resistance of the coating material. For example, if an excess amount of coating material was so deposited on the wood as to form a continuous unbroken overlying film, my bufiing medium will not buff the top surface of that overlying film. On the contrary, it will inherently press downwardly through that film until it works against the resistance of the underlying wood as distinguished from the resistance of the overlying film.
- the buffing medium normally will be eifective to remove most if not all of the excess material and to pressure smooth the nib-coated surface into a shiny porous substantially nib-free condition.
- the coating material is in a hardened tack-free state.
- the pressures may be greater or less than the indicated range of 7 /2 to 15 pounds per lineal inch. If, for example, the drum 10 is of larger diameter than 16 inches, thus increasing the width of the band of contact, the maximum pressure may have to be increased by increasing the force exerted by roller 15 in order to obtain the desired degree of plastic impregnation and permanent compression of the surface wood. It will be apparent that the belt speed, Work feed rate and the pressure can be altered relative to each other within the general limits above given to establish the best operative conditions for the particular plastic and wood to which it is applied.
- Example I 3550-50 100 Denatured ethanol or methanol 100 Acid accelerator (Beckamine Accelerator P-198 3 1 Obtained from Reichhold Chemical Company.
- the prepared plastic or nib-coat solution was wiped on the surface of 2' x 4' Douglas fir plywood panels to obtain 2 pounds of melamine plastic (dry weight) per 1000 square feet of surface.
- the alcohol solvent was dried in air until the surface was only slightly tacky to the touch.
- the plastic-impregnated surface was then passed beneath the rotating belt 12 travelling at a pcripheral speed between 4000 and 4800 feet per minute with the lineal speed of the plywood panel under the drum being approximately feet per minute.
- the plywood panel was passed beneath belt 12 and thus twice rubbed under pressure. An inspection of the surface after the treatment revealed no substantial change in its natural wood grain appearance except the surface was glossier, more light-reflective and smoother to the touch than the untreated wood.
- the treated surface resulting from the practice followed in Example I, is inherently porous.
- the porous treated surface was then primed and coated with a standard outdoor enamel paint obtained from Porter Paint Company, Louisville, Kentucky, and allowed to dry. Approximately one-third less primer and paint, as total finishing material, was required to obtain a suitable high grade painted surface than is usually required on an untreated surface.
- the treated panels, and untreated plywood were sub jected to a water-absorption test by positioning Water on the surface of each and observing the time required to penetrate into the surface.
- the untreated plywood panel soaked up the water placed on its surface in /2 to 1 minute.
- the panels prepared in accordance with the method of this invention continued to resist the penetration of water 24 hours after they were initially wetted with water.
- Example 11 plastic material in liquid form was perpared by admixing:
- Phenol-formaldehyde resin in alcohol 68% resin solids (Plyophen-SOZS Denatured ethanol or methanol 172 1 Obtained from Reichhold Chemical Company.
- the resin mixture was applied to the surface of a number of 2 x 4' panels of Douglas fir plywood, gum and birch by wiping to obtain 2 /2 pounds of plastic solids (dry weight) per thousand square feet of surface.
- the alcohol solvent was evaporated until the surfaces were only slightly tacky to the touch.
- the substantially dry plastic-impregnated surfaces were then contacted with the apparatus of the drawing by passing the belt 12 over the surface four times under the condtions specified in Example I.
- the nib-coated panels, thus treated, were primed and painted with the enamel paint used in Example I, the total quantity of primer and enamel being at the rate of 360 square feet per gallon.
- test panels from the treated surfaces were subjected to outdoor weathering by vertically disposing the panels on the southwest Wall of a building, located near Louisville, Kentucky, for five months, extending from March to August.
- untreated plywood stock and panels of untreated surfaces painted in an identical manner were positioned adjacent to the panels treated in accordance with this invention.
- an inspection of the panels revealed the following.
- the surface of the painted untreated plywood stock was substantially covered with checks and cracks and was badly discolored.
- the painted stock treated inaccordance with this invention was free of checks and cracks and for all practical purposes had the same appearance as it had when placed outside.
- Example III A plastic solution was prepared by admixing:
- the plastic solution was applied to the surfaces of a number of 2' by 4 panels of Douglas fir plywood, walnut and gum, by wiping to obtain about 2 /2 pounds of plastic solids (dry weight per thousand square feet of surface). After coating, these panels were treated in exactly the same manner as was used in treating the panels of Example I, A similar reduction in the quantity of paint was observed. The water absorption tests on the treated panels gave results substantially identical to those set forth for the panels in Example I.
- Example IV Parts by weight Alkyd resin-monomeric styrene modified (Polylite 8237 50 Acetone l50)
- Example V a Parts by weight Urea-formaldehyde resin (65% urea-formaldehyde resin solids in waterPlyamine P-631 100 Water 225 Catalyst (TB6-6388 1.5 Catalyst (TB6-3994 I 0.75
- This resin is a colloid suspension in water when applied to the wood, but the water is evaporated prior to the friction treatment.
- Example VI Vinylidene chloride acrylo-nitrile resin (Saran F-l22- A-20 Latex 52% solids 1 Obtained from Dow Chemical Company.
- This resin is an emulsion in water when applied, but the water is evaporated prior to the friction treatment.
- Example VII Parts by weight Polyamide resin (Zytel #61 15 Denatured ethanol Water 20 1 Obtained from E. I. Dupont de Nemours & Co.
- the alcohol and water are heated to about F. and the dry resin (nylon) stirred in the hot liquid until it dissolves.
- the resulting solution is then applied to the wood.
- thermoplastic material having a softening temperature higher than the curing temperatures of the phenolformaldehyde resins, it is advisable to increase either (a) the length of the rubbing time (or the width of the rubbing band) or (b) the magnitude of the rubbing pressure or both.
- a plastic material of this higher softening character is exemplified by trifluorochloroethylene resins, such as Kel-F available from the M. W. Kellog Company.
- the frictional bufiing member in compressively rubbing against the resistance of the wood may to some extent either (a) wipe the surfaceoverlying unsorbed plastic material into the pores of the wood or (b) rub it off or (0) do both; and that, at the same time, it may soften the natural wood lignin in a thin surface layer of very small depth and density that very thin surface layer without densifying the remainder of the wood.
- there is ordinarily no visibly intact film of plastic on the surface so the wood retains its natural appearance, except for enhanced gloss.
- the friction-ally developed heat partially or completely cures the resin, thus producing a finished product in much less time and with less effort and equipment than required for prior resin coated or impregnated wood products.
- my process differs (a) from the scufi' sanding of porous surfaces, such as wash-coated wood, (b) from the sealer sanding of impervious surfaces, such as the surfaces of sealer coats or equivalent films on wood, and (c) from other correspondingly light-pressure sanding, bufiing and other rubbing operations of impervious coating surfaces, such as the surfaces of top coats.
- My process differs from said scuff-sanding and other processes in that it requires a substantially higher rubbing pressure and produces a distinctly superior result.
- natural wood When natural wood, treated by this process, is intended for interior use, it. may be used, if desired, without any finish coat other than that provided by the nib-coat, or it may be provided with a wax finish. In either event, it retains fully its naturalwood appearance. It has been found that it may be stained by incorporating a stain in the plastic material or by applying a stain to the finished product. While the porosity of the surface (produced in accordance with the practice of the present invention) will vary with variations in the wood and in the operating conditions of the process, such surface will have sufficient porosity to accept soluble stains. In addition it will accept pigmented stains employing fine pigment particle sizes 'butwill not satisfactorily accept some of the coarser pigmented stains. Besides stains, insecticidal, fungicidal and other special purpose materials may be used.
- the foregoing process has become known as the super microseal process. From the foregoing, it will be understood or observed; (1) that the super microseal process is useful in eliminating upstanding nibs from the surface of cellulosic and other firm porous heat-insulating materials such as wood, untempered hardboard, chipboard and like products presenting a relatively smooth regular porous firm heat-insulating surface, one that preferably is fiat and substantially panar; and (2) that the belt 12 moves toward and away from the surface of the product being rubbed through a concavo-convex path and has its convex side pressed against said product surface by a rotating rubber covered contact drum 10, which thus functions as a yielding backing member for the belt.
- the super microseal process is useful in eliminating upstanding nibs from the surface of cellulosic and other firm porous heat-insulating materials such as wood, untempered hardboard, chipboard and like products presenting a relatively smooth regular porous firm heat-insulating surface, one that preferably is fiat and substantially panar; and
- results obtained by the practice of the invention, on a ligno-cellulosic or other like product surface containing the plasticizable binder of natural Wood may be improved by initially rubbing the white wood preceding the nib-coating step, using the process of Alexander Patent No. 2,827,935, now known as the microseal process, which is substantially the same as this super microseal process except that the coating step is omitted. Where microsealing precedes super microsealing, microsealing may flatten all nibs within reach of the surface rubbing medium.
- super microsealing in accordance with the nib coat practice of this invention, eliminates upstanding nibs by embedding the flattened nibs in the coating material and by preventing such nibs from rising after the rubbing or buifin g operation.
- the best results can be obained by: microsealing the natural Wood to glossify its surface; nib-coating the glossified surface with the plastic material to permeate that surface; drying the nib-coated surface; rubbing the permeated surface in the manner described above; and
- these rubbing operations may be preceded by coarse and fine (or polish) sanding operations and all such operations may be performed on a single conveyor line providing a constant product speed ranging up to 160 feet per minute or more.
- the machines for sanding and rubbing may all be of the character shown in the drawing.
- Naturally coarse and polish (or fine) sanding belts such as 00 and 000 grades, respectively, normally will be used on the coarse and polish-sanding machines, while each rubbing or bufiing machine will use a rubbing belt 12 or its equivalent. All buffing belts may travel at the same speed or in the same speed range running from about 1700 to 5000 lineal feet per minute.
- the drying operation preferably should proceed somewhat gradually. Good results have been obtained with two drying zones, one having a drying temperature approximating 100 to 150 F. and the other a drying temperature approximating 200 to 250 F.
- My invention contemplates the use of belts which move through a blunt-nosed concave-convex path, i.e. one having a flat-faced apex and of corresponding fiat-faced backing members providing wider bands of rubbing con tact in order to increase the total frictional heat generated.
- the solids deposit may be too heavy.
- the solution to this problem is either to rub the panel with one or more additional rubbing operations, or to thin down the plastic solution in order to reduce the amount of solids deposited.
- the final super-microsealed surface acts like a conventionally sealed surface in that it stabilizes the wood surface against fiber raising and prepares it for the direct reception of a top coat or other finish coat. Unlike a conventionally sealed surface, however, it is not actually sealed, but remains porous. This is one of the advantages of this process since the treatment may be applied at the factory and the panel subsequently stained and finish coated on the job without the necessity of sealer coats and sealer sanding operations.
- the minimum super microsealing pressure will vary with such factors as the specie of wood, the type of nibcoat used, the softness-hardness or plasticity of the nibcoat material when rubbed and the product-feed and rubbing-belt speeds employed in practicing the process. Consequently, the minimum super microsealing pressures may range upwardly from a limit as low as 30 lbs. per foot in some cases to a top limit in other cases which should not go much, if any, higher than 60 lbs. per ft. A lb. per ft. pressure is recommended. Rubbing pressures in excess of lbs. per ft. may be employed but normally they do not provide any improvement in operation or result sufficient to justify their use. Their use should be considered if the heaters are to be reduced or eliminated.
- the better practice presently indicated is to apply the minimum amount of coating material which will consistently produce good results with relatively little waste. This amount will vary not only with the specie of wood but also with the s-olids content of the nib-coat used, the plasticity (softness or hardness) of the nib-coat material when rubbed, and the product-feed and rubbing-belt speeds and the rubbingpressure used in practicing the process. In some cases, the minimum amount of material (which should be used) will normally be at the heretofore indicated low limit of about /2 lb. In other instances, the minimum amount will range upwardly from said low limit to a top limit which need not go much, if any, higher than about 1.25 pounds. While the desired minimum amount may thus vary for each given operating condition, it can always be easily and quickly determined by routine experiment.
- the coating should not be stiif, rigid, inflexible or unyieldingly hard.
- it should be deformably soft or plastic enough to flow under pressure and thereby not only permit the rubbing medium to rub against the resistance of the wood as distinguished from the resistance of the coating material but: also permit the rubbing medium to pressure smooth it under compressive rubbing conditions.
- the coating material may, however, be dry, tacky or even wet but a Wet coating is not recommended.
- the first rubbing operation should pressure rub it into a porous and substantially nib-free state and should pressure smooth it into a shiny state, which preferably should be uniform since its attractiveness will be in direct proportion to its uniformity.
- the rubbed coated surface should be dry to the touch after the first rub, but, again, it may be tacky or wet to a lesser degree than it was immediately before the first rub. If dry, it may (if desired) be placed in use as is, i.e. without a base or top coat. If not dry, it should not be placed into use as is" without further processing it into a dry state and this may be most conveniently done by one or more additional rubs.
- the nib-coat should preferably be dry after the last rub. However, it may be pre-finished in a tacky or wet state, so long as the operators observe the wood-finishing conditions, which govern the application of one coat safely upon another.
- Waxes cannot be used as nib-coats because subsequent coats, such as base coats and top coats, will not adhere satisfactorily to a waxed surface.
- Resins derived from the natural polymer cellulose, and spirit varnishes can be used as nib-coats.
- nitrocellulose lacquer solutions and spirit varnishes both make excellent nib-coats.
- Resinous materials such as drying oils and the oil varnishes, can also be used but they usually are not as satisfactory as the other materials mentioned.
- Example VIII A low-viscosity polyester-resin-forming material in a liquid state (free of volatile liquid) was prepared by mixing 100 grams of Reich-hold Polylite 8048 with /2 gram of catalyst (60% methyl ethyl ketone peroxide). This volatile-liquid-free resin-forming liquid was clothwiped over a 2' x 4' X /4 Birch plywood panel to produce (on a dry solids basis) a spread of about 6 lbs. per 1,000 ft. or 22 grams per 8' square. The difference between the weights of the resin container and the wiping cloth before and after spreading indicated that 21.2 grams were spread. Immediately after the coating operation, the panel was subjected to 4 passes or rubs. The results are tabulated as follows:
- Example X A 22% solids nitrocellulose lacquer solution, obtained from the Pittsburgh Plate Glass Co., was diluted with lacquer thinner to make a solution containing 15% nitrocellulose solids. This solution was wiped on a 2/0 and 4/0 plant sanded 1' x 1 /2 x A" Birch plywood panel. The spread rate provided lbs. of dry material per 1000 ft. of surface (3.4 grams wet spread). About 1 /2 minutes were required to perform the test piece coating operation.
- test piece was then passed through the plant SMS (i.e. super microseal) drying oven (22 secs. at 250 F.) and then passed (twice) over the cork belt.
- plant SMS i.e. super microseal drying oven
- Example XI A shellac varnish (identified as Sherwin-Williams Pure White Shellac, 3 lb. Cut, 30.5% solids) was cloth wiped over a 1' x 1 /2 x A" White Birch plywood panel to produce a 5.6 gram wet spread which, on a dry solids basis, equals 2 /2 lbs. per 1,000 ft. The panel was allowed to dry at room temperature overnight. After one rub, it had uniform shine quality which rated Fair. Two weeks later it was re-rubbed twice under the same conditions and rated Good after each rub.
- Example XII Sherwin-Williams Rexpar spar varnish composed of 55% non-volatiles (linseed oil, tung oil and phenolic resin) and 45% volatiles (mineral spirits) was cloth wiped and re-wiped over three 1' x 1 /2 x
- a Birch plywood panel in amounts providing the smooth and uniform wet spreads hereinafter indicated, viz:
- said nib-coating step is performed with a low viscosity polyester-resin-forming material in a liquid state free of volatile liquids.
- said nib-coating step is performed with a low viscosity epoxy-resin-forming material in a liquid state free of volatile liquids.
- An improved method for eliminating upstanding nibs from the flat face of a wood, hardboard, chipboard and other like cellulosic product, having a smooth regular porous firm white-wood or equivalent surface, as the product moves rapidly through a longitudinal path including a rubbing zone comprising:
- said nib-coating step is performed 1) by applying said plastic material in an amount providing, on a dry weight basis, not less than about /2 lb. of binder per 1000 square feet of coated surface, and
- said nib-coating step is performed with the amount of said plastic material on said surface controlled to provide a porous coat prior to the bufling step.
- said nib-coating step is performed (1) with said plastic material containing said binder combined with an evaporable liquid vehicle;
- said method includes the step of evaporating substantially all of the evaporable liquid prior to the bufiing step.
- said nib-coating step is performed with a plastic material binder (1) which hardens upon the evaporation of said liquid vehicle.
- said nib-coating steps is performed with said plastic material containing a partially polymerized thermosetting binder.
- said nib-coating step is performed with said plastic material containing a thermoplastic binder.
- said buffing step is performed (1) with a buffiing contact time of not more than /2 second.
- said bufiing step is preformed with a buffing medium (1) having a relatively non-abrasive rubbing surface which is yieldably pressed, by a backing member, against, and into intimate flattened contact over, said contact band.
- said nib-coating step is performed (1) with said plastic material containing said binder combined with an evaporable liquid vehicle,
- said method includes the step of evaporating substantially all of the evaporable liquid prior to said buffing;
- the bufling contact time being of the order of a fraction of a second for each inch of contact band width.
- said bufling step is performed 1(1) with a bufiing contact time not more than V2 second, and
- An improved method for eliminating upstanding nibs from the flat face of a wood, hardboard, chipboard and other like cellulosic product, having a smooth regular porous firm white-wood or equivalent surface, as the product moves rapidly through a longitudinal path comprising:
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Description
Nov. 23, 1965 RUBBING MACHINES H EAT ER COATING MACHINE L. E. DIMOND METHOD OF COATING AND SMOOTHING WOOD SURFACE Filed Dec. 29, 1964 RUBBING MACHINE R2 INVENTOR. LLOYD E. DIMOND ATTORNEY COATING MACHINE C\ l United States Patent f 3,219,473 METHOD ()F COATING AND SMOOTHING WOOD SURFACE Lloyd E. Dimond, Louisville, Ky., assiguor to General Plywood Corporation, Louisville, Ky., a corporation of Kentucky Filed Dec. 29, 1964, Ser. No. 421,819 18 Claims. (Cl. 117-64) The present application is a continuation-in-part of my co-pending U.S. application S.N. 150,709 filed Nov. 7, 1961, which was a continuation-in-part of my U.S. application S.N. 681,541 filed August 29, 1957, which, in turn, was a continuation-in-part of my parent U.S. ap plication S.N 611,874, filed September 25, 1956, all three now abandoned.
The present invention relates to the art of finishing wood panels and like products which present a smooth, regular, porous, firm, heat-insulating, flat-faced whitewood or equivalent surface. More particularly, the invention is directed to an improved method of rapidly processing said surface into a shiny substantially nibfree coated surface of stainable porosity which is stabilized against nib-raising and capable of receiving conventional fiinishing materials such as a top coat with or without an intervening base coat.
In the practical wood finishing art prevailing in and prior to 19541955, one conventional practice, for completing the preparation of a wood surface (such as a finish-sanded white-wood surface) for the reception of subsequent finish coats such as base coats and top coats, was to size-coat or wash-coat that surface for the purpose of stiffening and raising its nibs and then to cut off the upstanding nibs close to the surface by a scuifsanding operation, which leaves the surface in a porous condition. The present invention is directed to the production of a porous more or less nib-free coated surface of improved characteristics by a novel method which involves the coating and rubbing of that surface.
An important object of the present invention is to provide a novel method of producing a rubbed porous-coated wood surface which, in comparison with a scuff-sanded porous Wash-coated or size-coatd wood surface, is improved in one or more of the following respects: in smoothness; in shineiness or gloss; in freedom from nibs; in attractiveness of appearance; in its ability to resist the penetration of liquids, including subsequent coating materials, and in the uniformity of its resistance; in its ability to produce equal or superior finishing results with less finishing materials; and in its stability against nibraising.
More partcularly, important objects of the present invention are: (l) to produce a smooth shiny substantially nib-free coated and rubbed wood surface of stainable porosity having a more uniform appearance than, and an increased gloss over, that which is possessed before the coating operation; (2) to produce a porous-coated surface which is stabilized against nib raising; and (3) to produce an otherwise superior surface finish suitable for various uses, including the application of conventional finishing materials and particularly suited for interior use.
Another important object is to accomplish all of the more important objects of this invention in a simple and inexpensive method capable of being rapidly performed in a production line.
The present invention resides in my discovery of an improved method for eliminating upstanding nibs from the flat face of a wood, hardboard, chipboard or other like cellulosic product, having a smooth regular porous firm white-wood or equivalent surface, as that product 3,219,473 Patented Nov. 23, 1965 ing under heat and pressure and thereafter assuming a hardened state, (3) which, when applied, is in a fluid state such that it is capable of flowing and penetrating said surface, and (4) which is capable of receiving overlying coatings of other wood-finishing materials including top coats and intervening base coats; and (B) as the coated product makes one pass through the rubbing zone, compressively bufling its flat coated face frictionally with a buffing medium (1) at a high buffing-speed and (2) at a heavy bufiing-pressure, which is so elevated, above those usable for scuff-sanding, as to (a) render said buffing medium capable, during said one pass, of removing substantially all of any excess coating material on the product, and (b) to cause said buffing medium to buff against the resistance of said fiat white-wood face of said product, as distinguished from the resistance of said coating material on said product, (i) with a buifing force suflicient to pressure smooth the nib-coated surface into a shiny, porous and substantially nib-free state.
My improved method pressure smoothes said coated surface into a substantially nib-free state, having a more uniform appearance than (and a substantially increased gloss over) that of the same surface before the coating operation. The rubbed coating on that surface not only stabilizes it against nib-raising but renders it capable of accepting subsequent coating materials more uniformly than it could before the coating operation. The rubbing conditions also insure that the rubbed surface shall have a stainable porosity because, if that surface is not porous before the rubbing operation, it will become porous as a result of the rubbing operation, and, if it is porous before the rubbing operation, it will remain porous after that operation. After one pass under most conditions of operation, the surface of the coating material is tack-free and hard.
An apparatus for practicing my invention is illustrated in the accompanying drawing wherein:
FIG. 1 is a somewhat schematic side elevation of a production line of presently preferred form for practicing my invention;
FIG. 2 is a somewhat schematic view of a device for practicing the coating step of my invention wherein a wood panel or the like is coated with a plastic material; and
FIG. 3 is a somewhat schematic view of the apparatus used for practicing that rubbing step of my invention wherein a coated panel or the like is rubbed to glossify its coating,
The production line shown in FIG. 1 includes suitable conveying means for carrying a wood panel or the like successively through the following equipment, viz: (a) a rubbing machine R1 of the type disclosed in the Alexander U.S. Patent No. 2,827,935, which machine uses the frictional heat and pressure of a high speed rubbing operation to pressure smooth, glossify and density a thin surface layer of an uncoated or white-wood panel; (b) a coating machine C which operates to coat the rubbed white-wood surface with a suitable wood-finishing plastic material; (c) a pair of heaters H1 and H2 for heating the plastic coated surface primarily to drive off the solvent if any and thereby prepare it for the next rubbing operation; ((1) a rubbing machine R2, which may be the same as R1, for practicing the rubbing step of the present invention so as to achieve the objects of the present invention including the glossification of the surface of the coated panel; and (e) another similar rubbing machine R3 for repeating the rubbing operation to improve the gloss.
The coating machine may be of conventional form. One such form as shown includes: a supply trough T for holding a supply bath of the plastic material; a plastic material applicator A in the form of a soft rubber roller coater having a durometer of about 6 to 10', said coater rotating on a fixed axis with its lower side immersed in the plastic material bath; a spring-loaded Wiper W for wiping the plastic material deposited by the applicator A; and a spring-loaded drive assembly, including a drive roll D1 directly over the roller coater A and another drive roll D2 directly over the wiper W, for driving (through the coater) the wood product being coated thereby. The spring-loaded drive assembly is mounted on bracket B which can be vertically adjusted to produce a gap of desired size between the drive rolls D1 and D2 and their respective opposite, i.e. the roller coater A and the wiper W. The roller coater A and the drive rolls D1 and D2 are all driven at the same speed.
In initially preparing the coating machine for operation on a fiat wood panel, for example, the drive assembly, which is heavily spring-loaded, is vertically adjusted to an elevation such as to provide a minimum gap of slightly smaller vertical width than the vertical thickness of the panel so that when the panel passes through the coater, it will raise the drive rolls D1 and D2 to a small extent but nevertheless large enough to insure a satisfactory pressure on both sides of the panel for panel driving and coating purposes. If the resulting wiper pressure is too heavy, the wiper W, which is more lightly spring-loaded, may be adjusted to insure a lighter pressure for wiping purposes. In other words, the yield of the wiper W to the pressure of the springloaded drive assembly may be adjusted. No claim of novelty is made as to the specific form of coating mechanism, the heaters, or the conveyors illustrated in the drawing.
After the panel (with its wiped coating) has passed through the heaters it is ready to be rubbed by the rubbing machine R2 which is shown in FIG. 3.
The apparatus shown in FIG. 3 includes a pair of horizontally spaced and aligned conveyor sections or portions 1 and 2, each of which contains a plurality of freely rotatable rollers 3. The upper surfaces of the rollers 3 project slightly above the surface of the conveyor frame to support a piece of plywood or a planar wood product such as a flush door or wall panel 4. Thus, the wall panel 4 is freely movable on the rollers 3. The adjacent spaced ends of conveyor portions 1, 2 are mounted on correspondingly spaced brackets 5, 6 which are secured by any suitable means, such as welding, to upstanding supporting members 7, 8, of inverted L-shape. The supporting members 7, 8 are also provided with upwardly turned lip portions 7a, 8a, respectively, which are spaced from each other to define an opening 9 between them.
The opening 9 is arranged to receive an arcuate portion of a cylindrical member or contact drum 10 fixedly mounted on drive shaft 11, which is driven by any suitable driving means such as a motor (not shown). This contact drum 10 is preferably approximately 16 inches in diameter but may be of any diameter desired according to the size of the apparatus shown in the drawing, and is preferably covered with one or more cylindrical layers or sleeves 10a, composed of rubber or other suitable yieldable material so that the roll can compel the belt to conform to uneven or irregular surfaces. If rubber is used it may be vulcanized to the surface of the drum 10. The arcuate portion of the drum 10, which extends through the opening 9, is positioned for tangential engagement with the under surface of a panel positioned on the conveyor rollers 3.
In order to treat the surface of the panel 4 which has been preliminarily impregnated with plastic material, a continuous or endless surface treating belt 12, preferably composed of cork or containing a cork surface, is arranged around the peripheries of the rotating contact drum 10 and an idler drum 13, which is fixedly mounted for rotating movement on a shaft 14 supported in any suitable manner. The drums 10 and 13 are rotated by drive shaft 11 in the counterclockwise direction indicated by arrows D and I, the idler drum 13 being used to maintain the desired tension in the surface treating belt 12.
It is preferable to employ :a surface treating belt having a cork surface, e.g., as exemplified by the belts presently made under U.S. Patent 2,542,058, except that the very mild abrasive sometimes employed in such cork belts is unnecessary and may be omitted. Any other relatively nonabrasive polishing frictional belt material, such as canvas, or other cloth made of natural or synthetic fibers, may be employed so long as it is capable of'frictionally developing the requisite temperature when the requisite operating conditions are employed, and of withstanding both the operating temperatures and pressures. For example, belts composed of asbestos cloth, popped perlite or expanded vermiculite may be used. The asbestos cloth belt should be sized in a 2% animal glue solution and then dried under tension in order to stiffen it and thereby prevent its wrinkling during use. The vermiculite and perlite particles should be uniformly sized in the same manner as cork particles. This means that the particles should be of uniform size to get the highest percentage of rubbing area and that the uniform size used should be small for hard wearing particles and progressively larger for the progressively softer wearing particles which tend more and more rapidly to wear out.
The panel 4 is rapidly moved from left to right along the conveyor by a feed roll 15, which is arranged above and in contact with the upper surface of the panel. The feed roll 15 is preferably covered with rubber in the conventional manner to increase traction and is driven in the direction of the arrow F by means of a shaft 16 on which the roll 15 is fixedly mounted. The shaft 16 is supported on any suitable type of resilient bearing pedestal (not shown) which permits a limited amount of vertical movement so that the roll 15 will exert a downward pressure on the work in the direction of the arrow P. The weight of the roll itself may be augmented, if desired, by auxiliary weights, springs or other means for exerting the required downward pressure, which should be substantial. The shaft is preferably driven by means of a belt 17 which is arranged around the shaft 16 in such a manner as to pull downwardly on the shaft 16 as it is being driven.
In operation, a panel 4 is fed into the space between drums 10 and 15. The substantial pressure of the roll 15 against the panel forced the undersurface of that panel downwardly against the treating belt 12 as the panel passes therebetween. The panel is fed or propelled by the feed roll at a linear speed approximating the peripheral speed of the feed roll, there being relatively little or no slippage therebetween. The contact drum 10 drives the surface treating belt in a direction opposite to that of the panel and at a substantially higher speed. Under these conditions, a temperature, high enough to soften the applied plastic material, is believed to be momentarily produced on the surface of the panel along the line of contact between the belt and the panel.
When natural wood is treated the temperature produced may also soften the lignin in the surface Wood and the surface wood itself momentarily, and more or less instantaneously, without softening the underlying wood structure of the panel. As a result of this softened surface wood condition, the pressure exerted against the panel along the same line of contact may compress and densify the softened surface wood without compressing or densifying the underlying wood structure.
During the rubbing operation, the softened plastic flows and more completely fills the pores of the surface layer. Since heat and pressure are thus applied to the panel progressively along its length, the surface of that panel is progressively improved in a like manner. The same operating conditions effective on natural wood are applicable to artificial wood products.
Natural wood, in its many available forms including plywood, and also artificial wood products, such as untempered hard board, chip stock and the like, may be satisfactorily treated in accordance with the method of this invention. A wide variety of plastic materials have been found to be suitable for the purposes of this invention. As used in this specification and in the appended claims the term plastic materials is intended broadly to include synthetic and natural materials of the size-coat or wash-coat type, having film-forming binders of a resinous nature, which embrace natural and synthetic resins, including cellulose derivatives, each binder of which (1) is capable of flowing and penetrating the wood to which it is applied, at least when dissolved or suspended in a liquid vehicle, (2) is either a solid or liquid after removal of the evaporable vehicle, (3) is capable of flowing under heat and pressure, and (4) thereafter assumes a rigid or hardened condition. In addition, in its final hardened form, it should remain hard at the temperatures to which it will be subject in use; and it must be capable of satisfactorily accepting a top coating of lacquer, varnish or paint directly or with an intervening base coat. The plastic in its final form should be resistant to the solvents, plasticizers and other ingredients normally contained in siccative finishing materials if they are to be applied.
Stated otherwise, the foregoing plastic materials or plastic additives all are of the film-forming type. They must be thin enough to absorb and penetrate into the wood surface being processed. They constitute a synthetic or natural coating composition capable of forming a film (a) upon the evaporation of a liquid volatile in which its solids are dissolved (or suspended) or (b) by chemical reaction, such as polymerization, or (c) by evaporation and chemical reaction.
In the prior art practice of eliminating nibs, a thin pentrating coat, designated wash-coat by some woodworker and size-coat by others, is conventionally employed on white wood for the purpose of stiffening and raising the nibs to facilitate their removal by a scuffsanding operation. Since the practice of my invention and the prior art practice of wash-coating (or size-coating) and scuff-sanding both involve the use of a penetrating coat placed on white wood for the purpose of promoting the production of a nib-free surface by a subsequent rubbing operation, I propose to use the term nib-coat to designate generally those penetrating coats,
which, in accordance with my invention, may be ernployed on white wood for the purpose of preparing its surface for the removal of nibs therefrom or the embedment of the nibs therein (or both) by a compressive frictional rubbing operation.
In other words, the term nib-coat designates a coat of a thin surface-penetrating wood-finishing plastic material of the size-or-wash-coat type, which has a filmforming binder of a resinous nature, and which, when properly applied to white wood and compressively rubbed under frictional pressure, not only leaves the surface in a smooth shiny state of stainable porosity capable of receiving a top coat (either directly or with one or more intervening coats of wood-finishing materials such as stains, fillers or sealers), but also substantially stabilizes that surface against nib-raising. Moreover, when the white wood surface, which existed before the nib-coating operation, is compared with the nib-coated surface, which emerges from the rubbing operation, it will be found that the nib-coated surface has a more uniform appearance and a substantially increased gloss. It also has the capati bility of accepting subsequent coats of Wood-finishing materials more uniformly.
Plastic materials, which possess the qualifications necessary to function as nib-coats, embrace both the thermoplastic and thermosetting types of plastic materials. For most purposes, the thermosetting plastic materials are preferred.
Examples of suitable plastic materials which may be used for the purposes of this invention are the phenolaldehyde resins, such as phenol-formaldehyde resins, phenol-furfural resins, melamine-formaldehyde resins, urea-formaldehyde resins, heat-convertible alkyd resins, and polyester resins. The alkyd or polymerizable polyesters that may be utilized are any of the unsaturated polyhydric alcohol polycarboxylic acid polyesters made from unsaturated polycarboxylic acids and/ or unsaturated polyhydric alcohols either in admixture with a cross-linking monomer such as styrene, diallyl phthalate, triallyl cyanurate, and others, which resins cure without giving off by-products, or in admixture with drying oil components to form more conventional alkyd resins which cure by splitting out water.
A preferred type of polyester is essentially a condensation product of a dihydric alcohol and a dicarboxylic acid, such as maleic acid or anhydride, or fumaric acid, a polyester of saturated dihydric alcohols such as the ethylene, propylene and butylene glycols, with or without modifying amounts of saturated dicarboxylic acids such as phthalic anhydride, tetrachlorophthalic anhydride, succinic acid, adipic acid, and others. These preferred polyesters when mixed with a suitable monomer are preferably in thin liquid form or made into liquids by the use of suitable solvents or dispersed as an emulsion.
These polyester materials may be catalyzed with peroxide-type catalysts such as benzoyl peroxide, methyl ethyl ketone peroxide, hydroperoxides, metal driers such as cobalt naphthanate, etc., and cured at temperatures ranging from room temperature to 200 C. or more. Small proportions of trihydric alcohols or tricarboxylic acids, or alcohols and carboxylic acids of higher functionality, may be incorporated in the polyester molecule, if desired. A suitable resin is produced from glycerol and phthalic anhydride. It is possible to employ alkyd resins which, per se, are not heat-convertible if such resins are modified by adding a small proportion of a heat-convertible material thereto such, for example, as dimethyl phthalate, glycerol phthalate, etc.
Examples of suitable thermoplastic materials are the polyamides, and vinylidene chloride acrylo-nitrile resins commercially marketed under the trade names nylon and Saran, respectively, the trifluorochloro-ethylene resins marketed under the trade name Kel-F and vinyl chlorideacetate resins, vinyl-formal resins, methyl methacrylate and polymethyl alphachloro acrylate resins, etc.
The above resins should be either in liquid form as produced or convertible into a liquid by the use of evaporable solvents, or dispersed as an emulsion in water. It is satisfactory to use partially condensed resins of the formaldehyde type in water solution; but, because water tends to cause raising of the surface grain, it is preferred to employ hydrocarbon, alcohol or other organic solvents when possible. When thermosetting resins such as the phenol-formaldehyde, melamine-formaldehyde, etc., are employed, it is preferable that the polymerization of the plastic solids be relatively far advanced so that while fur ther polymerization occurs from the heat supplied by the friction member the quantity of polymerization necessary is kept near a minimum.
In the application of such plastic materials to wood surfaces, the plastic is preferably maintained in a sufliciently fluid condition to render it relatively easy to impregnate or interpenetrate the pores of the Wood surface by merely brushing, rolling, or spraying the plastic on the surface to be treated. When thermoplastic materials or partially polymerized thermosetting materials are used,
the desired fluidity is obtained by dissolving or suspending them in a suitable liquid vehicle which is evaporated prior to the friction treatment.
Plastic materials or nib-coats, as above defined, are characterized by the fact that their resin or plastic content is solidifiable (and thus capable of forming a firm film when applied to a suitable surface) either upon evaporation of a liquid vehicle in which it is dissolved or suspended or by the polymerization or both, and that they are in a soft or softened state during the rubbing treatment and that they are hard or hardened, thereafter, at room temperatures.
The best results are obtained with resinous nib-coats composed of either or both thermoplastic and thermosetting resins. I particularly prefer those which harden (or solidfy) quickly either on application of heat or evaporation of solvent or both, because they permit the use of a rapid mass production process, such as that illustrated and described above.
When using the types of plastic materials specifically referred to hereafter, it has been found that the best results are obtained when the proportion of plastic solids in the solution (i.e. the starting composition) ranges between about 15% and about 50%. Excellent results are being obtained in commercial practice with compositions containing about 15% solids. In general, it is feasible to employ solutions containing the higher percentages of plastic solids on the more porous woods, such as Douglas fir, pine, and other soft woods, and it is preferable to decrease the plastic solids as the porosity of the wood decreases.
The preferred quantity of plastic solids in the finished surface resulting from the method of this invention varies somewhat depending upon the amount of material more or less permanently taken up by the wood. For example, if the dry weight of plastic solids, after it has been applied to the wood, ranges from /2 pound to 7 /2 pounds per 1000 square feet of wood surface, the dry weight of the plastic solids taken up by and remaining with the wood at the end of the rubbing operation will inherently vary from about .5 pound per 1000 square feet for the dense close grained woods to about 1.25 pounds for the softer more porous woods such as Douglas fir, pine and luaun.
After the plastic solution has been applied to the wood surface, the solvent or vehicle normally employed in it, may be removed by any conventional method of drying, including drying in the air, countercurrent forced air drying, heating, etc. When heat is used and the plastic is thermosetting, the temperature of the plastic should be kept below the temperature at which it will cure to rigid form during the drying operation. Unless the solvent or vehicle is first evaporated from the plastic material on the surface, the contacting of that plastic-impregnated surface with the high-speed frictional surface tends to cause gumming of the frictional surface and in the case of some solvents would cause a fire hazard and is therefore undesirable.
The method of this invention impregnates only a very thin surface layer of wood. Where natural wood densification occurs, it also is limited to said very thin surface layer. Although it is not known for certain it is believed that the high temperature which results from the treatment with the apparatus shown in the drawing is, in conjunction with the simultaneously applied pressure, responsible for the uniform distribution in the surface layer of the various plastic materials including those which have not heretofore been considered satisfactory for impregnating wood. It is believed that a portion of the generated heat first softens the applied plastic material, simultaneously softens the lignin in the natural wood adjacent to the surface and, in the case of thermosetting plastic materials, a portion of the heat functions to further polymerize or cure the plastic solids and thus advance them toward a hard infusible condition in situ in the pores of the surface wood. One of the virtues of the process is that when a thermosetting resin is used, which will cure slowly at room temperature, the friction treatment need only cure the outermost surface of the plastic, and this is accomplished in a small fraction of a second.
Although it is difficult to determine the precise temperatures and pressures which are obtained in the practice of this invention with the apparatus of the drawing, when natural wood is treated temperatures employed should fall within or exceed the lignin softening-melting range of 400 F.525 F., a temperature well above the conventional softening temperatures for thermoplastic resins and the curing temperatures for most of the thermosetting resins. The preferred operating temperatures may exceed the above range so long as the contact time is reduced sufficiently to prevent charring of the surface wood in all instances and scorching in those instances where it is objectionable.
In operating the apparatus of the drawing for treatment of natural wood, the work feed rate, the belt speed and the pressure must be correlated to effect the softening of the above mentioned plastic materials and to produce the desired improvement of the desired thin layer without charring and in most cases without scorching the wood.
Since the desired results are believed to be achieved when the temperatures developed are high and since only a very thin layer of wood is heated, it is desirable to complete the treatment with the apparatus of the drawing within a time period of less than half a second when natural wood is treated, and preferably within a period not exceeding A of a second. The period of treatment depends on the width of the rubbing contact band and the rate of feed or feed speed of the work. With the 16-inch rubber covered drum of the apparatus of the drawing, it is estimated that the width of the band of contact is about inch when the pressure applied by feed roller 21 is 7% pounds per lineal inch of roller length. The same limitations on time of treatment are applicable to each treatment in those cases mentioned hereafter in which the wood is passed through the apparatus two or more times.
The temperature developed during the treatment for any given rate of work feed and width of pressure contact depends on the pressure and the belt speed, increasing as either or both of these factors increase and vice versa. I believe that the best results are achieved when the temperature developed closely approaches the scorch ing temperature of the wood for the treatment time employed. The presence of residual evaporable solvent or other vehicle in the plastic on the surface at the instant of contact by the friction member holds down the temperature which is attained since a portion of the heat is employed in completing the evaporation of that solvent. For this reason it is preferred that the applied plastic material be substantially free of evaporable vehicle or solvent before contact with the friction member. For this reason it is also undesirable to apply the process of this invention to green wood or wet wood.
A single pass of the treated surface beneath the roll 10 at a feed rate of feet per minute or more is insufficient to completely polymerize or cure some thermosetting plastic materials to their hard infusible condition. In order to obtain a fuller cure of the surface in such cases or to greater depths in others, the work feed rate may be decreased or the surface may be passed beneath the roll 10 repeatedly. For melamine-formaldehyde and urea-formaldehyde plastic materials, a satisfactory cure of at least the outer surface has been obtained by a single pass through the apparatus of the drawing at a belt speed of about 4000 feet per minute and a work feed rate of 90 feet per minute, but a slight improvement in surface appearance is noted on a second pass. Additional passes may be required when phenol-formaldehyde, polyamides or polyester resins are employed, and may also be required if any significant quantity of evaporable vehicle remains in the plastic when it is given the first treatment.
The maximum pressure exerted during the treatment of natural wood may be varied widely. The actual maximum pressure exerted by the apparatus of the drawing is difficult to determine since it varies over the narrow band of contact from zero at the extreme edges of the band to a maximum pressure at the center. The pressure is believed to cause a fiow of the heated plastic and either rub off softened plastic material which lies on the surface or force it into the pores of the wood or both. Excellent results have been obtained when the diameter of drum is 16 inches and the downward pressure exerted by roller ranges from 7 /2 pounds to 15 pounds per lineal inch of contact between the belt and the Wood surface along the length of the roller.
Pressures of this order substantially exceed the scuffsanding pressure used on size-coated or washcoated wood. My experience indicates that the highest of the scuff-sanding pressures is substantially below one pound per square inch (1 psi.) and therefore substantially less than one pound per lineal inch along a one inch (1) wide band of rubbing contact of the character involved in my invention.
Rubbing pressures of the above-noted order also render the buffing medium inherently capable of removing substantially all of any excess coating material on the panel during one pass of the panel through the rubbing zone and they cause the bufiing medium to work compressively against the resistance of the wood, as distinguished from the resistance of the coating material. For example, if an excess amount of coating material was so deposited on the wood as to form a continuous unbroken overlying film, my bufiing medium will not buff the top surface of that overlying film. On the contrary, it will inherently press downwardly through that film until it works against the resistance of the underlying wood as distinguished from the resistance of the overlying film.
As a consequence of the pressures employed, the buffing medium normally will be eifective to remove most if not all of the excess material and to pressure smooth the nib-coated surface into a shiny porous substantially nib-free condition. Usually the coating material is in a hardened tack-free state.
Under proper conditions of belt speed and work speed the pressures may be greater or less than the indicated range of 7 /2 to 15 pounds per lineal inch. If, for example, the drum 10 is of larger diameter than 16 inches, thus increasing the width of the band of contact, the maximum pressure may have to be increased by increasing the force exerted by roller 15 in order to obtain the desired degree of plastic impregnation and permanent compression of the surface wood. It will be apparent that the belt speed, Work feed rate and the pressure can be altered relative to each other within the general limits above given to establish the best operative conditions for the particular plastic and wood to which it is applied.
A number of examples are set forth below which contain typical representatives of the plastics and operating conditions which can be employed in carrying out the method of this invention. It is to be understood that the scope of the invention is not intended to be limited to the particular materials or conditions employed therein.
Example I 3550-50 100 Denatured ethanol or methanol 100 Acid accelerator (Beckamine Accelerator P-198 3 1 Obtained from Reichhold Chemical Company.
The prepared plastic or nib-coat solution was wiped on the surface of 2' x 4' Douglas fir plywood panels to obtain 2 pounds of melamine plastic (dry weight) per 1000 square feet of surface. The alcohol solvent was dried in air until the surface was only slightly tacky to the touch. The plastic-impregnated surface was then passed beneath the rotating belt 12 travelling at a pcripheral speed between 4000 and 4800 feet per minute with the lineal speed of the plywood panel under the drum being approximately feet per minute. The plywood panel was passed beneath belt 12 and thus twice rubbed under pressure. An inspection of the surface after the treatment revealed no substantial change in its natural wood grain appearance except the surface was glossier, more light-reflective and smoother to the touch than the untreated wood. The treated surface, resulting from the practice followed in Example I, is inherently porous. The porous treated surface was then primed and coated with a standard outdoor enamel paint obtained from Porter Paint Company, Louisville, Kentucky, and allowed to dry. Approximately one-third less primer and paint, as total finishing material, was required to obtain a suitable high grade painted surface than is usually required on an untreated surface.
The treated panels, and untreated plywood, were sub jected to a water-absorption test by positioning Water on the surface of each and observing the time required to penetrate into the surface. The untreated plywood panel soaked up the water placed on its surface in /2 to 1 minute. A similar wood surface treated in accordance with this invention, except that no plastic was added prior to the frictional rubbing operation, resisted the penetration of water for 15 minutes. The panels prepared in accordance with the method of this invention continued to resist the penetration of water 24 hours after they were initially wetted with water.
Excellent results have also been obtained with the plastic of Example I on the hard woods, birch, gum, white oak, red oak, Philippine mahogany, African mahogany, Walnut, and cherry. However, with these Woods which are less porous than Douglas fir, the added ethanol or methanol is increased to 150 parts by weight to facilitate initial penetration.
Example 11 plastic material in liquid form was perpared by admixing:
Parts by Weight Phenol-formaldehyde resin in alcohol, 68% resin solids (Plyophen-SOZS Denatured ethanol or methanol 172 1 Obtained from Reichhold Chemical Company.
The resin mixture was applied to the surface of a number of 2 x 4' panels of Douglas fir plywood, gum and birch by wiping to obtain 2 /2 pounds of plastic solids (dry weight) per thousand square feet of surface. The alcohol solvent was evaporated until the surfaces were only slightly tacky to the touch. The substantially dry plastic-impregnated surfaces were then contacted with the apparatus of the drawing by passing the belt 12 over the surface four times under the condtions specified in Example I. The nib-coated panels, thus treated, were primed and painted with the enamel paint used in Example I, the total quantity of primer and enamel being at the rate of 360 square feet per gallon. Portions of untreated plywood of the same types were primed and painted with the same primer and enamel paint; and, in order to obtain comparable sealing and a comparable enamel coated surface, it was necessary to employ paint at the rate of 240 square feet per gallon, or one-third more primer and paint.
After the painted surfaces had thoroughly dried, test panels from the treated surfaces were subjected to outdoor weathering by vertically disposing the panels on the southwest Wall of a building, located near Louisville, Kentucky, for five months, extending from March to August. For comparison purposes, untreated plywood stock and panels of untreated surfaces painted in an identical manner were positioned adjacent to the panels treated in accordance with this invention. At the end of five months exposure to the weather, an inspection of the panels revealed the following. The surface of the painted untreated plywood stock was substantially covered with checks and cracks and was badly discolored. The painted stock treated inaccordance with this invention was free of checks and cracks and for all practical purposes had the same appearance as it had when placed outside.
Example III A plastic solution was prepared by admixing:
Parts by weight Urea-formaldehyde resin solution in alcohol (50% l 1 Obtained from Reichhold Chemical Company.
The plastic solution was applied to the surfaces of a number of 2' by 4 panels of Douglas fir plywood, walnut and gum, by wiping to obtain about 2 /2 pounds of plastic solids (dry weight per thousand square feet of surface). After coating, these panels were treated in exactly the same manner as was used in treating the panels of Example I, A similar reduction in the quantity of paint was observed. The water absorption tests on the treated panels gave results substantially identical to those set forth for the panels in Example I.
The following examples are examples of plastic solutions which were used in accordance with the manipulative stepsof the method as set forth in Example I, except as indicated, and substantially comparable results were obtained in each case to those obtained in Examples I and II.
Example IV Parts by weight Alkyd resin-monomeric styrene modified (Polylite 8237 50 Acetone l50 Example V a Parts by weight Urea-formaldehyde resin (65% urea-formaldehyde resin solids in waterPlyamine P-631 100 Water 225 Catalyst (TB6-6388 1.5 Catalyst (TB6-3994 I 0.75
1 Obtained from Reichhold Chemical Company.
The panels were passed twice through the apparatus of the drawing. This resin is a colloid suspension in water when applied to the wood, but the water is evaporated prior to the friction treatment.
Example VI Vinylidene chloride acrylo-nitrile resin (Saran F-l22- A-20 Latex 52% solids 1 Obtained from Dow Chemical Company.
The panels were passed once through the apparatus of the drawing. This resin is an emulsion in water when applied, but the water is evaporated prior to the friction treatment.
In the comparative water absorption test no evidence of penetration by moisture was observed after 24 hours.
Example VII Parts by weight Polyamide resin (Zytel #61 15 Denatured ethanol Water 20 1 Obtained from E. I. Dupont de Nemours & Co.
The alcohol and water are heated to about F. and the dry resin (nylon) stirred in the hot liquid until it dissolves. The resulting solution is then applied to the wood.
When using a thermoplastic material, having a softening temperature higher than the curing temperatures of the phenolformaldehyde resins, it is advisable to increase either (a) the length of the rubbing time (or the width of the rubbing band) or (b) the magnitude of the rubbing pressure or both. A plastic material of this higher softening character is exemplified by trifluorochloroethylene resins, such as Kel-F available from the M. W. Kellog Company.
While the reason for the beneficial results which flow from the use of the process on natural wood are not fully understood, it is believed: that the frictional bufiing member in compressively rubbing against the resistance of the wood, may to some extent either (a) wipe the surfaceoverlying unsorbed plastic material into the pores of the wood or (b) rub it off or (0) do both; and that, at the same time, it may soften the natural wood lignin in a thin surface layer of very small depth and density that very thin surface layer without densifying the remainder of the wood. This results in a thin, highly glossified outer wood surface which is relatively heavily impregnated with plastic. Moreover, there is ordinarily no visibly intact film of plastic on the surface so the wood retains its natural appearance, except for enhanced gloss. Finally, when a thermosetting resin is employed, the friction-ally developed heat partially or completely cures the resin, thus producing a finished product in much less time and with less effort and equipment than required for prior resin coated or impregnated wood products.
The practice of my invention inherently produces a porous surface. In fact, in most cases, the coated surface should be porous before the rubbing operation. In all cases, it is porous after the rubbing operation. In all cases, it is porous after the rubbing operation. It will be apperent that my process differs (a) from the scufi' sanding of porous surfaces, such as wash-coated wood, (b) from the sealer sanding of impervious surfaces, such as the surfaces of sealer coats or equivalent films on wood, and (c) from other correspondingly light-pressure sanding, bufiing and other rubbing operations of impervious coating surfaces, such as the surfaces of top coats. My process differs from said scuff-sanding and other processes in that it requires a substantially higher rubbing pressure and produces a distinctly superior result.
When natural wood, treated by this process, is intended for interior use, it. may be used, if desired, without any finish coat other than that provided by the nib-coat, or it may be provided with a wax finish. In either event, it retains fully its naturalwood appearance. It has been found that it may be stained by incorporating a stain in the plastic material or by applying a stain to the finished product. While the porosity of the surface (produced in accordance with the practice of the present invention) will vary with variations in the wood and in the operating conditions of the process, such surface will have sufficient porosity to accept soluble stains. In addition it will accept pigmented stains employing fine pigment particle sizes 'butwill not satisfactorily accept some of the coarser pigmented stains. Besides stains, insecticidal, fungicidal and other special purpose materials may be used.
The foregoing process has become known as the super microseal process. From the foregoing, it will be understood or observed; (1) that the super microseal process is useful in eliminating upstanding nibs from the surface of cellulosic and other firm porous heat-insulating materials such as wood, untempered hardboard, chipboard and like products presenting a relatively smooth regular porous firm heat-insulating surface, one that preferably is fiat and substantially panar; and (2) that the belt 12 moves toward and away from the surface of the product being rubbed through a concavo-convex path and has its convex side pressed against said product surface by a rotating rubber covered contact drum 10, which thus functions as a yielding backing member for the belt.
The results obtained by the practice of the invention, on a ligno-cellulosic or other like product surface containing the plasticizable binder of natural Wood, may be improved by initially rubbing the white wood preceding the nib-coating step, using the process of Alexander Patent No. 2,827,935, now known as the microseal process, which is substantially the same as this super microseal process except that the coating step is omitted. Where microsealing precedes super microsealing, microsealing may flatten all nibs within reach of the surface rubbing medium. In that event, super microsealing, in accordance with the nib coat practice of this invention, eliminates upstanding nibs by embedding the flattened nibs in the coating material and by preventing such nibs from rising after the rubbing or buifin g operation.
Normally the best results can be obained by: microsealing the natural Wood to glossify its surface; nib-coating the glossified surface with the plastic material to permeate that surface; drying the nib-coated surface; rubbing the permeated surface in the manner described above; and
then repeating the rubbing operation. As a matter of fact, these rubbing operations may be preceded by coarse and fine (or polish) sanding operations and all such operations may be performed on a single conveyor line providing a constant product speed ranging up to 160 feet per minute or more. Again the machines for sanding and rubbing may all be of the character shown in the drawing. Naturally coarse and polish (or fine) sanding belts, such as 00 and 000 grades, respectively, normally will be used on the coarse and polish-sanding machines, while each rubbing or bufiing machine will use a rubbing belt 12 or its equivalent. All buffing belts may travel at the same speed or in the same speed range running from about 1700 to 5000 lineal feet per minute.
The drying operation preferably should proceed somewhat gradually. Good results have been obtained with two drying zones, one having a drying temperature approximating 100 to 150 F. and the other a drying temperature approximating 200 to 250 F.
My invention contemplates the use of belts which move through a blunt-nosed concave-convex path, i.e. one having a flat-faced apex and of corresponding fiat-faced backing members providing wider bands of rubbing con tact in order to increase the total frictional heat generated.
If the plastic material is too viscous, the solids deposit may be too heavy. The solution to this problem is either to rub the panel with one or more additional rubbing operations, or to thin down the plastic solution in order to reduce the amount of solids deposited.
The final super-microsealed surface, produced in accordance with the practice of this invention, acts like a conventionally sealed surface in that it stabilizes the wood surface against fiber raising and prepares it for the direct reception of a top coat or other finish coat. Unlike a conventionally sealed surface, however, it is not actually sealed, but remains porous. This is one of the advantages of this process since the treatment may be applied at the factory and the panel subsequently stained and finish coated on the job without the necessity of sealer coats and sealer sanding operations.
The quality of a super microsealed surface progressively improves with a progressive improvement in the quality of the starting white wood surface. Consequently, while rough sanded panels ranging from 1/0 to 3/0 and polished sanded panels ranging from 4/0 to 6/0 may be super microsealed, the recommended practice is to microseal all starting white-wood panels before super microsealing them.
The minimum super microsealing pressure will vary with such factors as the specie of wood, the type of nibcoat used, the softness-hardness or plasticity of the nibcoat material when rubbed and the product-feed and rubbing-belt speeds employed in practicing the process. Consequently, the minimum super microsealing pressures may range upwardly from a limit as low as 30 lbs. per foot in some cases to a top limit in other cases which should not go much, if any, higher than 60 lbs. per ft. A lb. per ft. pressure is recommended. Rubbing pressures in excess of lbs. per ft. may be employed but normally they do not provide any improvement in operation or result sufficient to justify their use. Their use should be considered if the heaters are to be reduced or eliminated.
Since the rubbing medium functions to remove substantially all of any excess coating material, the better practice presently indicated is to apply the minimum amount of coating material which will consistently produce good results with relatively little waste. This amount will vary not only with the specie of wood but also with the s-olids content of the nib-coat used, the plasticity (softness or hardness) of the nib-coat material when rubbed, and the product-feed and rubbing-belt speeds and the rubbingpressure used in practicing the process. In some cases, the minimum amount of material (which should be used) will normally be at the heretofore indicated low limit of about /2 lb. In other instances, the minimum amount will range upwardly from said low limit to a top limit which need not go much, if any, higher than about 1.25 pounds. While the desired minimum amount may thus vary for each given operating condition, it can always be easily and quickly determined by routine experiment.
At the beginning of the first rub, the coating should not be stiif, rigid, inflexible or unyieldingly hard. Preferably, it should be deformably soft or plastic enough to flow under pressure and thereby not only permit the rubbing medium to rub against the resistance of the wood as distinguished from the resistance of the coating material but: also permit the rubbing medium to pressure smooth it under compressive rubbing conditions. The coating material may, however, be dry, tacky or even wet but a Wet coating is not recommended.
The first rubbing operation should pressure rub it into a porous and substantially nib-free state and should pressure smooth it into a shiny state, which preferably should be uniform since its attractiveness will be in direct proportion to its uniformity. Preferably the rubbed coated surface should be dry to the touch after the first rub, but, again, it may be tacky or wet to a lesser degree than it was immediately before the first rub. If dry, it may (if desired) be placed in use as is, i.e. without a base or top coat. If not dry, it should not be placed into use as is" without further processing it into a dry state and this may be most conveniently done by one or more additional rubs.
If the super microsealed product, resulting from one or more nib-coat rubbing operations, is to be pre-finished, i.e. top coated at the factory, the nib-coat should preferably be dry after the last rub. However, it may be pre-finished in a tacky or wet state, so long as the operators observe the wood-finishing conditions, which govern the application of one coat safely upon another.
Waxes cannot be used as nib-coats because subsequent coats, such as base coats and top coats, will not adhere satisfactorily to a waxed surface.
Resins, derived from the natural polymer cellulose, and spirit varnishes can be used as nib-coats. Thus, nitrocellulose lacquer solutions and spirit varnishes both make excellent nib-coats.
Resinous materials, such as drying oils and the oil varnishes, can also be used but they usually are not as satisfactory as the other materials mentioned.
Representative examples of the use of (a) liquid resins, i.e. polyester and epoxy resins without solvents, (b) nitrocellulose lacquer solutions and spirit varnishes, and (c) oil varnishes and drying oils follow.
In Examples VIII through XIII, which follow, a wide belt Timesaver type of machine was set to operate with a belt speed approximating 4020 f.p.m., a 90 f.p.m. feed speed and a 90 lbs. per foot rubbing pressure. The wood was rubbed by a cork belt (#126) which had previously rubbed an estimated 5000 to 6000 4 x 8' wood panels.
Example VIII A low-viscosity polyester-resin-forming material in a liquid state (free of volatile liquid) was prepared by mixing 100 grams of Reich-hold Polylite 8048 with /2 gram of catalyst (60% methyl ethyl ketone peroxide). This volatile-liquid-free resin-forming liquid was clothwiped over a 2' x 4' X /4 Birch plywood panel to produce (on a dry solids basis) a spread of about 6 lbs. per 1,000 ft. or 22 grams per 8' square. The difference between the weights of the resin container and the wiping cloth before and after spreading indicated that 21.2 grams were spread. Immediately after the coating operation, the panel was subjected to 4 passes or rubs. The results are tabulated as follows:
#l-POLYESTER RESIN, 6 LB. SPREAD A low viscosity epoxy-resin-forming material in a liquid state (free of volatile liquids) was prepared by mixing 100 grams of Reichhold Epotu-f 37-128 with 50 grams of Reichhold Epotuf hardener #2611. The conditions were the same except that (a) the coating was air dried for 1% hrs., (b) 20.1 grams were spread and (c) the Birch panel was twice rubbed. The results were substantially the same as those tabulated through the second rub of Example VIII, the coating being slightly tacky before the first rub and the degree of shine being fairly good and good, respectively, after the first and second rubs. A corresponding test on a Douglas Fir panel gave similar results.
Example X A 22% solids nitrocellulose lacquer solution, obtained from the Pittsburgh Plate Glass Co., was diluted with lacquer thinner to make a solution containing 15% nitrocellulose solids. This solution was wiped on a 2/0 and 4/0 plant sanded 1' x 1 /2 x A" Birch plywood panel. The spread rate provided lbs. of dry material per 1000 ft. of surface (3.4 grams wet spread). About 1 /2 minutes were required to perform the test piece coating operation.
The test piece was then passed through the plant SMS (i.e. super microseal) drying oven (22 secs. at 250 F.) and then passed (twice) over the cork belt. The condition of the coated surface was noted as follows:
(1) Immediately after spreadingslightly damp to the touch; nibs are present; not glossy.
(2) After heating in plant SMS oven but before first passdry to the touch; nibs are present; not glossy.
(3) After first pass on wide belt machine -dry to the touch; nib free; glossy (good SMS).
(4) After second pass on wide belt machine-dry to the touch; nib free; glossy (a little more than after first pass) (good SMS).
Example XI A shellac varnish (identified as Sherwin-Williams Pure White Shellac, 3 lb. Cut, 30.5% solids) was cloth wiped over a 1' x 1 /2 x A" White Birch plywood panel to produce a 5.6 gram wet spread which, on a dry solids basis, equals 2 /2 lbs. per 1,000 ft. The panel was allowed to dry at room temperature overnight. After one rub, it had uniform shine quality which rated Fair. Two weeks later it was re-rubbed twice under the same conditions and rated Good after each rub.
Example XII Sherwin-Williams Rexpar spar varnish, composed of 55% non-volatiles (linseed oil, tung oil and phenolic resin) and 45% volatiles (mineral spirits) was cloth wiped and re-wiped over three 1' x 1 /2 x A Birch plywood panel in amounts providing the smooth and uniform wet spreads hereinafter indicated, viz:
Panel 21.5 grams of wet spread providing 1.2 lbs. of dry solids/1000 sq. ft,
Panel 33.9 grams of Wet spread providing 3.1 lbs of dry solids/1000 sq. ft.,
Panel 4-9.1 grams of wet spread providing 7.3 lbs. of dry solids/1000 sq. ft.
The results are tabulated as follows:
#2-L/O VARNISH, 1.2 LB. SPREAD Conditions of nib-coated surfaces Wet, Remove Press. Degree Nibetc. sub. all smooth of shine free excess (a) Before 1st rub--. Slightly N n Dul1 No.
wet. (b) After 1st rub Dry Yes. Yes--." Fair- Yes (0) After 2d rub Dry Yes Yes-.-" Good. Yes (d) After 3d rub Dry Yes"-.- Yes Good... Yes (e) After 4th rub Dry Yes Yes Good Yes #3L/O VARNISH 3.1 LB. SPREAD (a) Before 1st rub--- Wet Dull No. (b) After 1st rub- Damp Fair Yes (0) After 2d rub Slightly Fair Yes damp. (d) After 3d rub. Dry Fairly; Yes
goo (e) After 4th rub Dry Good-.. Yes
#4L/O VARNISH 7.3 LB. SPREAD (a) Before 1st rub.-- Very? Yes..." Dull No.
we (b) After 1st rub Wet Yes Yes P0011. (0) After 2d rub Slightly Yes Yes Poor to wet. fair. ((1) After 3d rub Tacky Yes- Yes Fair--. Yes. (e) After 4th ruh Slightly Yes Yes Fairly Yes.
tacky. good.
1 After the 1st tub of #4, the nib-coated surface probably had some excess but, if so, such excess was not visible as such; hence most of it was rubbed ofi during the 1st rub.
2 After each of the 1st and 2d rubs of #4, if any nibs were present, I was unable to detect them.
Example XIII Archer-Daniels-Midland Co. Pol-mer-ik linseed oil (free of volatile liquid) was cloth-wiped over a 1'X11/2'X%" white Birch plywood panel in an amount providing a wet spread of 1.7 grams equalling a dry spread of 2 /2 lbs. per 1000 ft. After drying overnight, it was twice rubbed producing a surface, which rated poor. Two weeks later it was thrice rerubbed and rated as a high average. An average finish commercially produced in the plant is a good finish; hence, a high average is very good.
Similar tests using domestic tung oil sold by Solvent Services. Inc. and dehydrated caster oil sold by Reliance 17 Varnish Company were rated after each of 2 rubs as low average which is equivalent to fair. While these panels would not normally be recommended for use as is, they could be satisfactorily employed in top coated panels such as prefinished panels.
It may be noted that all panels for Examples 8-13 appeared to be substantially nib-free after the first rub.
Having described my invention, I claim:
1. An improved method for eliminating upstanding nibs from the flat face of a wood, hardboard, chipboard and other like cellulosic product, having a smooth regular porous firm whitewood or equivalent surface, a the product moves rapidly through a longitudinal path in cluding a rubbing zone, comprising:
(A) nib-coating said flat white-wood face of said product with a wood-finishing plastic material of the yp (1) which has a film-forming binder of a resinous nature,
(2) which is capable of flowing under heat and pressure and thereafter assuming a hardened state,
(3) which, when applied, is in a fluid state such that it is capable of flowing and penetrating said surface to form a nib-coat,
(4) which is capable of receiving overlying coatings 'of other wood-finishing materials including top-coats and intervening base coats, and
(5) which comprises a low viscosity resin-forming material in a liquid state free of volatile liquid; and
(B) as the coated product makes one pass through said rubbing zone, compressively bufling its fiat nibcoated face frictionally with a bufiing medium (1) at a high bufiing-speed and (2) at a heavy bufling-pressure, which is so elevated, above those usable for scuff-sanding, as
(a) to render said bufiing medium capable,
during said one pass, of removing substantially all of any excess coating material on the product, and
(b) to cause said bufiing medium to buff against the resistance of said fiat whitewood face of said product, as distinguished from the resistance of said coating material on said product,
(i) with a bufling force sufiicient to pressure smooth the nib-coated surface into a shiny, porous and substantially nib-free state.
2. The method of claim 1 wherein:
(A) said nib-coating step is performed with a volatileliquid-free drying oil; and
(B) said buffing step is repeated at least once.
3. The method of claim 1 wherein:
(A) said nib-coating step is performed with a low viscosity polyester-resin-forming material in a liquid state free of volatile liquids.
4. The method of claim 1 wherein:
(A) said nib-coating step is performed with a low viscosity epoxy-resin-forming material in a liquid state free of volatile liquids.
5. An improved method for eliminating upstanding nibs from the flat face of a wood, hardboard, chipboard and other like cellulosic product, having a smooth regular porous firm white-wood or equivalent surface, as the product moves rapidly through a longitudinal path including a rubbing zone, comprising:
(A) nib-coating said flat white-wood face of said product with a wood-finishing plastic material of the t pe,
y (1) which has a film-forming binder of a resinous nature,
(2) which is capable of flowing under heat and 18 pressure and thereafter assuming a hardened state,
(3) which, when applied, is in a fluid state such that it is capable of flowing and penetrating said surface to form a nib-coat, and
(4) which is capable of receiving overlying coatings of other wood-finishing materials including top-coats and interventing base coats; and
(B) as the coated product makes one pass through said rubbing zone, compressively bufiing its flat nib coated face frictionally with a bufiing medium (1) at a high bufling-speed and (2) at a heavy bufling-pressure, which i so elevated, abov those usable for scuff-sanding, as
(a) to render said bufiing medium capable,
during said one pass, of removing substantially all of any excess coating material on the product, and
(b) to cause said bufiing medium to buflf against the resistance of said flat whitewood face of said product, as distinguished from the resistance of said coating material on said product,
(i) with a but-ling force sufiicient to pressure smooth the nib-coated surface into a shiny, porous and substantially nib-free state.
6. The method of claim 5 wherein:'
(A) said nib-coating step is performed 1) by applying said plastic material in an amount providing, on a dry weight basis, not less than about /2 lb. of binder per 1000 square feet of coated surface, and
(2) by allowing said plastic material to absorb into and interpenetrate a thin layer of said coated surface.
7. The method of claim 5 wherein:
(A) said nib-coating step is performed with the amount of said plastic material on said surface controlled to provide a porous coat prior to the bufling step.
8. The method of claim 5 wherein:
(A) said nib-coating step is performed (1) with said plastic material containing said binder combined with an evaporable liquid vehicle; and
(B) said method includes the step of evaporating substantially all of the evaporable liquid prior to the bufiing step.
9. The method of claim 8 wherein:
(A) said nib-coating step is performed with a plastic material binder (1) which hardens upon the evaporation of said liquid vehicle.
10. The method of claim 8 wherein:
(A) said nib-coating steps is performed with said plastic material containing a partially polymerized thermosetting binder.
11. The method of claim 8 wherein:
(A) said nib-coating step is performed with said plastic material containing a thermoplastic binder.
12. The method of claim 5 wherein:
(A) said buffing step is performed with a buffing medium,
(1) which maintains, in said rubbing zone, a band of buffing contact,
(a) which, in the direction of its length, ex-
tends across the longitudinal path of product movement, and
(b) which, in the direction of its width, ex-
tends along said path,
(c) the buffing contact time being of the order of a fraction of a second for each inch of contact band width.
13. The method of claim 12 wherein:
(A) said buffing step is performed (1) with a buffiing contact time of not more than /2 second.
14. The method of claim 12 wherein:
(A) said bufiing step is preformed with a buffing medium (1) having a relatively non-abrasive rubbing surface which is yieldably pressed, by a backing member, against, and into intimate flattened contact over, said contact band.
15. The method of claim 5 wherein:
(A) said nib-coating step is performed (1) with said plastic material containing said binder combined with an evaporable liquid vehicle,
(2) with the amount of said plastic material on said surface controlled to provide a porous coat for the bufling operation,
(a) the amount applied, on a dry weight basis, being not less than about /2 lb. of binder per 1000 square feet of coated surface, and
(3) by allowing said plastic material to absorb into and interpenetrate a thin layer of said coated surface;
(B) said method includes the step of evaporating substantially all of the evaporable liquid prior to said buffing; and
(C) said bufiing operation is performed with a bufling medium,
(1) which maintains, in said rubbing zone, a band of rubbing contact,
(a) which, in the direction of its length, ex-
tends across the longitudinal path of product movement, and
(b) which, in the direction of its width, ex-
tends along said path,
(c) the bufling contact time being of the order of a fraction of a second for each inch of contact band width.
16, The method of claim 15 wherein:
(A) said bufling step is performed 1(1) with a bufiing contact time not more than V2 second, and
-(2) with a bufling pressure suflicient to rub the exposed surface of said nib-coat into a tack-free state,
17. The method of claim 16 wherein:
(A) said buffing step is performed with a buffing medium,
(1) having a relatively non-abrasive heat-insulating bufling surface -(a) which is yieldably pressed against, and into intimate flattened contact over, said contact band.
18. An improved method for eliminating upstanding nibs from the flat face of a wood, hardboard, chipboard and other like cellulosic product, having a smooth regular porous firm white-wood or equivalent surface, as the product moves rapidly through a longitudinal path, comprising:
(A) nib-coating said flat white-wood face of said product with a wood-finishing plastic material of the type,
(1) which has a film-forming binder of a resinous nature,
(2) which is capable of flowing under heat and pressure and thereafter assuming a hardened state,
(3) which, when applied, is in a fluid state such that it is capable of flowing and penetrating said surface to form a nib-coat, and
(4) which is capable of receiving overlying coatings of other wood-finishing materials including top-coats and intervening base coats; and
(B) compressively bufling said flat nib-coated face frictionally a sufiicient number of times to render said face shiny, porous and substantially nib-free, said buffing operation including, as the coated product makes one pass through a buffing zone, the step of buffing said coated face frictionally with a bufling medium (1) at a high bufling-speed and (2) at a heavy buffing pressure, which is so elevated, above those usable for a scuff-sanding as (a) to render said buffing medium capable,
during said one pass, of removing substantially all of any excess coating material on the product, and
(b) to cause said bufling medium to bufif against the resistance of said flat white-wood face of said product, as distinguished from the resistance of said coating material on said product,
(i) with a bufling force sufiicient to pressure smooth said nib-coated surface.
No references cited.
WILLIAM D. MARTIN, Primary Examiner.
MURRAY KATZ, Examiner.
Claims (1)
1. AN IMPROVED METHOD FOR ELIMINATING UPSTANDING NIBS FROM THE FLAT FACE OF A WOOD, HARDBOARD, CHIPBOARD AND OTHER LIKE CELLULOSIC PRODUCT HAVING A SMOOTH REGULAR POROUS FIM WHITEWOOD OR EQUIVALENT SURFACE, AS THE PRODUCT MOVES RAPIDLY THROUGH A LONGITUDINAL PATH INCLUDING A RUBBING ZONE, COMRPISING: (A) NIB-COATING SAID FLAT WHITE-WOOD FACE OF SAID PRODUCT WITH A WOOD-FINISHING PLASTIC MATERIAL OF THE TYPE, (1) WHICH HAS A FILM-FORMING BINDER OF A RESINOUS NATURE, (2) WHICH IS CAPABLE OF FLOWING UNDER HEAT AND PRESSURE AND THEREAFTER ASSUMING A HARDENED STATE, (3) WHICH, WHEN APPLIED, IS A FLUID STATE SUCH THAT IT IS CAPABLE OF FLOWING AND PENETRATING SAID SURFACE TO FORM A NIB-COAT, (4) WHICH IS CAPABLE OF RECEIVING OVERLYING COATINGS OF OTHER WOOD-FINISHING MATERIALS INCLUDING TOP-COATS AND INTERVENING BASE COATS, AND (5) WHICH COMPRISES A LOW VISCOSITY RESIN-FORMING MATERIAL IN A LIQUID STATE FREE OF VOLATILE LIQUID; AND (B) AS THE COATED PRODUCT MAKES ONE PASS THROUGH SAID RUBBING ZONE, COMPRESSIVELY BUFFING ITS FLAT NIBCOATED FACE FRICTIONALLY WITH A BUFFING MEDIUM (1) AT A HIGH BUFFING-SPEED AND (2) AT A BUFFING-PRESSURE, WHIC IS SO ELEVATED, ABOVE THOSE USABLE FOR SCUFF-SANDING, AS (A) TO RENDER SAID BUFFING MEDIUM CAPABLE, DURING SAID ONE PASS, OF REMOVING SUBSTANTIALLY ALL OF ANY EXCESS COATING MATERIAL ON THE PRODUCT, AND (B) TO CAUSE SAID BUFFING MEDIUM TO BUFF AGAINST THE RESISTANCE OF SAID FLAT WHITEWOOD FACE OF SAID PRODUCT, AS DISTINGUISHED FROM THE RESISTANCE OF SAID COATING MATERIAL ON SAID PRODUCT, (I) WITH A BUFFING FORCE SUFFICIENT TO PRESSURE SMOOTH THE NIB-COATED SURFACE INTO A SHINY, POROUS AND SUBSTANTIALLY NIB-FREE STATE.
Priority Applications (1)
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US421819A US3219473A (en) | 1964-12-29 | 1964-12-29 | Method of coating and smoothing wood surface |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US421819A US3219473A (en) | 1964-12-29 | 1964-12-29 | Method of coating and smoothing wood surface |
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US3219473A true US3219473A (en) | 1965-11-23 |
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ID=23672172
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Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3516851A (en) * | 1967-04-25 | 1970-06-23 | Heinolan Faneritehdas Zacharia | Method of treatment of a porous substance,especially treatment of semisolid wallboard with fire- and other extinguishing substances |
US3518105A (en) * | 1969-02-11 | 1970-06-30 | Clifford T Mcelroy | Panel-treating process |
US3912836A (en) * | 1972-04-27 | 1975-10-14 | Eriksson Erik Gustav L | Procedure for surface treatment of wood |
NL8501550A (en) * | 1985-05-30 | 1986-12-16 | Houthandel Lambert Van Den Bos | Planed wood surface treatment system - uses roller on which skirting moves, whilst heated smoothing iron is pressed over wood surface |
EP0457038A1 (en) * | 1990-05-16 | 1991-11-21 | Hans Feierabend Gmbh | Process and apparatus for coating boards of moisture sensitive material on all sides |
US5099782A (en) * | 1988-02-17 | 1992-03-31 | Dai Nippon Insatsu Kabushiki Kaisha | Apparatus for forming a coating of a viscous liquid on an object |
US5260174A (en) * | 1989-02-17 | 1993-11-09 | Dai Nippon Insatsu Kabushiki Kaisha | Method and apparatus for forming a coating of a viscous liquid on an object |
EP0744260A1 (en) * | 1995-05-23 | 1996-11-27 | Homag Maschinenbau Ag | Method and apparatus for continuous machining of porous wooden work pieces, and in particular the edges |
WO2000015357A2 (en) * | 1998-09-16 | 2000-03-23 | Seidner Marc A | Polymer fill coating for laminate or composite wood products and method of making same |
EP1068907A2 (en) * | 1999-07-16 | 2001-01-17 | Rohm And Haas Company | Method of powder coating a substrate |
US6180172B1 (en) * | 1994-11-29 | 2001-01-30 | Henkel Kommanditgesellschaft Auf Aktien | Process and apparatus for treating surfaces |
US20040152856A1 (en) * | 2002-12-30 | 2004-08-05 | Ju-Kil Lee | Acryl-modified polyester resin composition and method of preparing the same |
US8691340B2 (en) | 2008-12-31 | 2014-04-08 | Apinee, Inc. | Preservation of wood, compositions and methods thereof |
US20160186440A1 (en) * | 2013-08-07 | 2016-06-30 | Knauf Gips Kg | Method and device for producing coated, and in particular painted, building boards and associated painted building board |
EP2480714B1 (en) * | 2009-07-27 | 2016-08-31 | Herbert Mikowitsch | Method for treating a surface of a compressed-wood board |
US9878464B1 (en) | 2011-06-30 | 2018-01-30 | Apinee, Inc. | Preservation of cellulosic materials, compositions and methods thereof |
EP3453464A3 (en) * | 2017-09-11 | 2019-06-19 | Hesse GmbH & Co. KG | Rolling coating of lacquers and wood surfaces |
BE1029380B1 (en) * | 2021-05-05 | 2022-12-05 | Decospan | PROCEDURE FOR TREATMENT OF WOODEN PANELS |
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1964
- 1964-12-29 US US421819A patent/US3219473A/en not_active Expired - Lifetime
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Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3516851A (en) * | 1967-04-25 | 1970-06-23 | Heinolan Faneritehdas Zacharia | Method of treatment of a porous substance,especially treatment of semisolid wallboard with fire- and other extinguishing substances |
US3518105A (en) * | 1969-02-11 | 1970-06-30 | Clifford T Mcelroy | Panel-treating process |
US3912836A (en) * | 1972-04-27 | 1975-10-14 | Eriksson Erik Gustav L | Procedure for surface treatment of wood |
NL8501550A (en) * | 1985-05-30 | 1986-12-16 | Houthandel Lambert Van Den Bos | Planed wood surface treatment system - uses roller on which skirting moves, whilst heated smoothing iron is pressed over wood surface |
US5099782A (en) * | 1988-02-17 | 1992-03-31 | Dai Nippon Insatsu Kabushiki Kaisha | Apparatus for forming a coating of a viscous liquid on an object |
US5260174A (en) * | 1989-02-17 | 1993-11-09 | Dai Nippon Insatsu Kabushiki Kaisha | Method and apparatus for forming a coating of a viscous liquid on an object |
EP0457038A1 (en) * | 1990-05-16 | 1991-11-21 | Hans Feierabend Gmbh | Process and apparatus for coating boards of moisture sensitive material on all sides |
US6180172B1 (en) * | 1994-11-29 | 2001-01-30 | Henkel Kommanditgesellschaft Auf Aktien | Process and apparatus for treating surfaces |
EP0744260A1 (en) * | 1995-05-23 | 1996-11-27 | Homag Maschinenbau Ag | Method and apparatus for continuous machining of porous wooden work pieces, and in particular the edges |
WO2000015357A2 (en) * | 1998-09-16 | 2000-03-23 | Seidner Marc A | Polymer fill coating for laminate or composite wood products and method of making same |
WO2000015357A3 (en) * | 1998-09-16 | 2000-05-25 | Marc A Seidner | Polymer fill coating for laminate or composite wood products and method of making same |
EP1068907A2 (en) * | 1999-07-16 | 2001-01-17 | Rohm And Haas Company | Method of powder coating a substrate |
EP1068907A3 (en) * | 1999-07-16 | 2004-01-21 | Rohm And Haas Company | Method of powder coating a substrate |
US20040152856A1 (en) * | 2002-12-30 | 2004-08-05 | Ju-Kil Lee | Acryl-modified polyester resin composition and method of preparing the same |
US7339017B2 (en) * | 2002-12-30 | 2008-03-04 | Dpi Co., Ltd. | Acryl-modified polyester resin composition and method of preparing the same |
US8691340B2 (en) | 2008-12-31 | 2014-04-08 | Apinee, Inc. | Preservation of wood, compositions and methods thereof |
US9314938B2 (en) | 2008-12-31 | 2016-04-19 | Apinee, Inc. | Preservation of wood, compositions and methods thereof |
EP2480714B1 (en) * | 2009-07-27 | 2016-08-31 | Herbert Mikowitsch | Method for treating a surface of a compressed-wood board |
US9878464B1 (en) | 2011-06-30 | 2018-01-30 | Apinee, Inc. | Preservation of cellulosic materials, compositions and methods thereof |
US20160186440A1 (en) * | 2013-08-07 | 2016-06-30 | Knauf Gips Kg | Method and device for producing coated, and in particular painted, building boards and associated painted building board |
US10544592B2 (en) * | 2013-08-07 | 2020-01-28 | Knauf Gips Kg | Method and device for producing coated, and in particular painted, building boards and associated painted building board |
EP3453464A3 (en) * | 2017-09-11 | 2019-06-19 | Hesse GmbH & Co. KG | Rolling coating of lacquers and wood surfaces |
BE1029380B1 (en) * | 2021-05-05 | 2022-12-05 | Decospan | PROCEDURE FOR TREATMENT OF WOODEN PANELS |
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