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US3198109A - Printing of container closure gaskets - Google Patents

Printing of container closure gaskets Download PDF

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Publication number
US3198109A
US3198109A US107198A US10719861A US3198109A US 3198109 A US3198109 A US 3198109A US 107198 A US107198 A US 107198A US 10719861 A US10719861 A US 10719861A US 3198109 A US3198109 A US 3198109A
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Prior art keywords
plate
design
compound
printing
sheet
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US107198A
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James L Dwyer
Richard J Haberlin
George A Lothrop
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WR Grace and Co
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WR Grace and Co
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/12Stencil printing; Silk-screen printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41FPRINTING MACHINES OR PRESSES
    • B41F15/00Screen printers
    • B41F15/14Details
    • B41F15/34Screens, Frames; Holders therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41FPRINTING MACHINES OR PRESSES
    • B41F15/00Screen printers
    • B41F15/14Details
    • B41F15/44Squeegees or doctors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns

Definitions

  • This invention pertains to a method and apparatus for applying sealing or gasketing compound during the manufacture of container closures and the like. More particularly, it is directed to a method of forming can end, crown closure and similar gaskets on flat stock from which gasketed container closures can then be fabricated.
  • Can end gaskets have been formed on punched can ends by nozzle lining.
  • Nozzle lining involves applying a fluid gasket-forming compound through a nozzle to the edge of a can end, usually while spinning the can end if it is round. This method is mechanically complex and is not Well suited to the lining of irregular shaped ends such as rectangular or oval shapes.
  • the compound application mechanism for irregular ends is usually based on the more complex and less reliable pantograph or die lining techniques.
  • container gaskets by a method akin to silk screen printing.
  • the gaskets are formed in this method on flat metal sheet by forcing a fluid compound through a printing screen or stencil which carries the desired design, and closures with the gaskets are subsequently stamped from the metal sheet after setting the compound to its solid elastomeric form. See United States Patent No. 2,516,647.
  • the method of this invention comprises the printing of a fluid gasket-forming composition of the shape desired onto a metal sheet.
  • the printing is accomplished by forcing the composition through a rigid, dimensionally stable, stencil or plate which is finely perforated in the area Where the composition is to be transferred.
  • the printing is essentially on contact printing. This permits good definition to be obtained and facilities and securing of the requisite uniform film weights.
  • the printing steps is followed by conversion of the composition so printed to form-stable gaskets.
  • the metal sheet is thereafter cut or stamped into can ends, crown closures, lug caps and the like in a conventional manner.
  • the essence of this invention resides in effecting the printing through the use of a fairly rigid, dimensionally or form-stable plate having the desired design or gasket shape defined therein by minute perforations.
  • the de sign is composed of a multiplicity of small independent holes or perforations surrounded by a continuous lattice- Work of the plate material.
  • the printing plate is sufliciently rigid and so mounted as to be substantially inflexible under the conditions of use.
  • the perforation may be formed by any convenient method such as drilling or engraving, but it is much preferred to prepare the perforated design in the printing plate by etching because of the number of holes involved and their minute size.
  • a more specific and preferred embodiment of this invention is concerned with the use of curvilinear perforated plates in the printing step which permits linecontact printing. This materially improves the separation between the printing plate and the metal sheet and greatly reduces variations in the film weights of the gaskets.
  • Dry film thicknesses in the order of 0.025 to 1 millimeter are generally required for the types of container sealing gaskets contemplated.
  • the present invention is particularly suited to the making of gaskets of 0.050 to 0.250 millimeter thickness, which thickness encompasses the majority of the can sealing applications. It has been established that the process of this invention is capable of depositing films of this thickness in a single step.
  • the individual band widths for conventional can gaskets will usually be in the range of 2 to 8 millimeters.
  • the method of this invention is particularly suited to the printing of gaskets which have two or more bands. It permits placement of dual or multi-band gaskets with a precision that is difficult to achieve by other methods.
  • the perforated plate used in the printing of a gasket-forming compound will contain a plurality of the desired container closure gasket designs arranged in a uniform pattern.
  • ing plate in the manner of this invention permits a high degree of uniformity to be achieved even after several hundred or thousand cycles of printing. Dry weight variations in any one design and between designs are normally less than :5 percent and are usually within :2 percent.
  • This precision is secured while printing or laying down relatively large amounts of material, generally over 1 milligram per square centimeter of the gasket band (dry film weight). This precision is highly desirable because inadequate film weights in one or more areas result in gasket or closure failures and excessive weights result in waste of the compound besides creating other difliculties.
  • crown closures can be made by the method of this invention as well as pregasketed electrical conduit junction box covers.
  • Masonite panels decorated with a relatively thick design of an elastomer and useful in the manufacture of glass top tables can also be made.
  • FIGURE 1 illustrates the present process applied to the fabrication of gasketed can ends.
  • the printing in this instance is carried out with a planar perforated plate using a flexible squeegee to force compound through the perforations, in a manner similar to silk screen printing;
  • FIGURE 2 shows in enlarged detail a segment of one of the perforated gasket designs in the printing plate
  • FIGURE 3 shows in cross-section an oscillating curvilinear printing plate
  • FIGURE 4 illustrates a continuous rotary printing method
  • FIGURE 5 schematically illustrates one method of placing the perforated gasket designs in the printing plate.
  • the printing plate 10 of this invention is attached to a suitable rigid framework 11.
  • the printing plate contains a plurality of can end designs compound to be printed is placed on one end of the reverse side of plate 10 and is forced into thejperforations by a I rubber squeegee 14 which is pulled along the length of the plate.
  • the frame is then lifted up, strip 13 is moved I forward to the next position, the'frame is again placed down on the strip and the cycle is repeated.
  • the still fluid can end gaskets from the proceeding cycle are illustrated at 15. 7 V
  • the fluid composition thus transferred to sheet 13 is convertedto-a solid elastomeric or deformable plastic form in a conventional manner, as in a'dryingand heating oven 16.
  • the sheet with the form-stable shapes isthen transferred to a punching machine 17 that stamps the 4 trouble is experienced with viscosities below about 10,000 centipoises (Brookfield Model LVFSX No. 4 Spindle, 60 1'.p.m., 27 C.). Viscositites as high as 200,000 centipoises can be handled. It is preferred to use relatively plastic or pseudo-plastic compounds to avoid run out.or
  • the Precision Interchemical Rotary viscometer determines the flow properties of a compound over a range of shear stresses.
  • the PIRV slope is the logarithmic rate of change of the shear stress with the shear rate as determined by' plotting on log-log paper the shear stress in gasketed can ends from the sheet. The can ends are removed at 18 and the perforated scrap at-19.
  • FIGURE 2 shows in enlarged detail a plan view of a segment 0f-one of the perforated designs 12 in the printing plate.
  • the design consists of a multiplicity of small independent perforations or holes 20, usually arranged in a unform geometric pattern. . Whileround holes are'illustrated, they may have any shape desired such as triangular, square, hexagonal, ovoid and the like.
  • the composition transferred to the metal sheet in the manner of this invention is initially in the form. ofsmall individual liquid dots which, depending on the rheology of the composition, may immediately flow together or may be made to flow together thereafter as; by heating to form a'continuous film.
  • the printing plate can have a thickness 1n the range reciprocal seconds.”
  • V I the range reciprocal seconds
  • thesolids content, i.e. the dry film weight to the Wet film weight ratio, of the compounds be in the range of 50 to 100 percent.
  • the compound should wet the surface of the plate being printed, i.e. a 3 to 6 millimeter drop of compound on the surface should have no tendency for withdrawal, Aslight enlargement of the drop is preferred.
  • the wettabilityof the surface being printed can be improvedby suitable mean such as coating it with a thin adhesive or lacquer.
  • compound is not forced through the 7 holes onto. the sheet being printed, but is forced into the holes slightly in advance of and at the time the plate is in contact with the sheet.
  • Thefluidcompound is then-removed orpulled from the holes because of its adherence to the sheet/ There may be a slight amount-of force of 0.100 to 0.500 millimeter. It has been found that if the plate is toothin, the amount of compoundtransferred is insufficient for most gasketapplications, and if the plate has a thickness over about 0.500 millimeten'the perforations do not completely empty or drain with each cycle, with the hole sizes and compoundrheologies customarily used. A fair amount of rigidity in the printing plate'is de-' sired so that it will not stretch or distort during use and will continueto give clean separations afterseveral thousand cycles. t
  • the perforated design contains, or has a mesh, in the range of 250 to 2 500, preferably 550 to 1500, holes per square centimeter.
  • the surface area encompassed by the open end of a single perforation is in they range of 0.015
  • the open or free areaofthe' applied to thecompound by the squeegee as separation begins but it is not significant, nor is it desirable because it causes variable flow out and loss :of definition.
  • the rate of separation of. the printing plate from the sheet influences, With a great dealof variability, the relative amount of compound that is retained by the plate and the amount which adheres and transfers to the sheet because differences in separation rates result in different holes preferably falls within the range of 40 to 75 percent 1 of the total areaencompassed by the design.
  • the pull-off resistance, or energy required to separate the printing plate 4 from the metal sheet decreases as the mesh of the design For the same percentage open area in the designfthe finer meshes printwith better. definition.
  • unduly coarse mesh may give some cumulative smearing when used with a undercut channel.
  • the reverse side'of the plate is maintained smooth, i.e. the lattice workabout the perforations is on level" with the background of the design on the reverse surface of the printing plate. Thi permits a better doctoring or squeegeeing action'and so supports the blade. astoprevent wear and flexing of' the blade into the holes. Usually the hole size andspacing is uniform .throughout the perforated design, but it may be desirable to have some gradation in. some gasket applications.
  • The; printing plate is "designed. to be essentially in contact with the metal sheet at the time transfer of the compound begins; It is desirable not to separate or shim 'the plate by more than 0.03' millimeter, with a precision definition and non-uniform transfer of The composition orchemical constituents of the gasketforming compounds being printed is not too important,
  • Compound A is a butadiene-styrene-acrylonitrile terpolymer dispersion carried in a paraflinic solvent, with a clay filler added.
  • Compound B is a SBR rubber (70 weight percent butadiene, 30 weight percent styrene) dispersed in an aromatic solvent, with a small amount of clay filler added.
  • Compound C is an alcohol dispersion of a low molecular weight liquid neoprene.
  • Compound D is a polyvinyl chloride plastisol.
  • FIGURE 3 The use of a curvilinear perforated printing plate is illustrated in FIGURE 3.
  • the curvilinear design is preferred because it gives clean separation between the printing plate and the sheet being printed.
  • the printing plate 21 is attached to a frame 22 which is shaped to form part of an arc of a cylinder.
  • the radius of curvature when using a curvilinear plate is preferably in the range of 0.05 to 1.5 meters.
  • the obverse face of plate 21 is placed against the surface of the metal sheet 23 which is to receive the gasket shapes.
  • Plate 21 is perforated by holes 24 in the areas where it is desired to print.
  • the squeegee blade 25 is initially placed at one end of the frame on the reverse side of the plate, and that end portion of the plate is placed in contact with sheet 23.
  • Compound 26 to be printed is placed in front of the squeegee blade.
  • the screen and frame is then oscillated or rocked in the direction indicated.
  • the squeegee is activated in such a manner by conventional means (not shown) that it moves synchronously in the direction indicated with the rocking of the printing plate, and is kept just about at the point of tangency between the plate and sheet 23.
  • the printing cycle is repeated by slightly lifting frame 22 and plate 21 up, advancing sheet 23 while oscillating the frame back to the starting position and correspondingly moving the squeegee, and then again bringing the plate in contact with sheet 23.
  • a printing plate 30 is fabricated into a full cylinder which permits continuous rotary printing and avoids the intermittent step-wise printing methods illustrated in FIGURES 1 and 3.
  • the printing plate 30 is so mounted as to be able to rotate continuously while in contact with the sheet 31 which receives the gaskets. Sheet 31 is continuously advancing in the direction indicated.
  • the printing cylinder is shown in crosssection and contains holes or perforations 32 in the periphery thereof through which compound is transferred to the plate in the pattern desired.
  • Hollow cylinder 30 contains a shoe 33 which operates on the principle of a journal-bearing to develop a hydraulic pressure on the compound 34 trapped in the channel between the shoe and the perforated cylinder 30.
  • the radius of the face of the shoe is less than the radius of the roller and is more closely spaced to the cylinder at the bottom.
  • Compound can be admitted into the cylinder as needed in any convenient manner such as by an external pump operating through an inlet line in the axis of the cylinder.
  • the picking up of excess compound by doctor blade 35 and transfer thereof by internal pump 37 may not be necessary.
  • the compound can be allowed to stay on the inner surface of cylinder 30 and make a full revolution around the cylinder and be returned to the channel between the shoe and cylinder 30 in this manner.
  • the plate 30 in this instance has a thickness of 0.185 millimeter and an internal diameter of 92.5 centimeters.
  • the shoe 33 has a radius of curvature on its outer face of 30.8 centimeters and is spaced 38.1 millimeters from the inner surface of the cylinder at its upper point and 0.062 millimeter at its lowest point. Its lowest point is about 0.095 millimeter in advance of the line of tangency between the cylinder and sheet 31.
  • FIGURE 5 illustrates a method of preparing and placing the etchable design on the metal surface.
  • the design comprises a multiplicity of small independent etchable areas.
  • the etachable areas may be undersize with respect to the finished size of the etched areas to be produced. This depends on the type and thickness of the metal plate being used.
  • the etchable areas are surrounded by a continuous lattice-work of non-etachable areas.
  • an enlarged design 40 of the mesh pattern is prepared. It comprises a suitable supporting mem her having the desired mesh pattern, i.e. a multiplicity of small dots 41 in greatly enlarged detail.
  • the mesh pattern can be prepared, for example, by hand inking or can be taken from an available mesh pattern.
  • any errors in the precision of the small etchable areas are greatly reduced when the design is reduced to its finished size.
  • the surface area of the enlarged dots have a precision within 1 5 percent.
  • these dots may be relatively undersized with respect to the final area of the holes to be etched if they were drawn on the same scale.
  • the gasket band design may or may not be superposed on the mesh pattern at this point.
  • the enlarged mesh pattern has been drawn to include the gasket band pattern.
  • the band pattern can be placed on the mesh pattern by using a suitable overlay prior to or at the point where the negative master is photographed to produce the positives used to develop the resist on the metal surface.
  • the enlarged master so prepared is then photographically reduced preferably at least 5 times by conventional methods to produce a positive in step 42 with care being taken to avoid distortion.
  • the positive so obtained is developed and is used in step 43 to develop a resist on the metal surface to be etched.
  • the resist is developed in a conventional manner to give etchable areas corresponding to the original dots 41 of the master.
  • the holes are etched in the plate or roll in-step 44, again in a conventional manner. Electrolytic, acid etching and the like may be used. Carehas to be taken in the layout of the design and in control of the etching conditions to avoid undercutting and loss of the design or a radius of curvature of.91.5 centimeters.
  • etchable areas as to obtain complete through penetration of the etchable areas before full development of the width of each hole has been obtained. This permits the holes to be brought out to size gradually without running into breakthrough between the cavities. 'The etching action is facilitated by having the edges ofthe etchable areas about 0.8 to 1.2 millimeters undersize for each millimeter of depth that is to be etched.
  • Example A 307 can end gasket design was prepared in the manner illustrated in FIGURE 5.
  • the number 307 refers to a can end that has an outside diameter of 3 inches after double seaming on a standard American Number 2 can body.
  • the gasket design on the printing plate had 'an internal diameter of 88 millimeters and an outside diameter of 96 millimeters.
  • the design was composed of a regular pattern of square holes.
  • the width of each of the perforated holes, after etching, was 0.225 millimeter $0.015 millimeter, as measured on the surface.
  • the perforations created'about a 50 percent free open area within the gasket design area.
  • the master of this'design had an internal diameter of 88 millimeters and an outside diameter of 96 millimeters. Each square dot in the master had a width of about 0.200 millimeter $0.015 millimeter.
  • V The master was prepared by overlaying 80'mesh bolting cloth (Tyler) with a negative of the gasketband design. This master, with registration marks thereon, was photographically reproduced with there being two films (Kronar type) in the camera. . The simultaneously The positives were placed on either side of a 6x 12 x 0.250 millimeter copper plate coated on both sides with a resist (Kodak Photo ResistEastman Kodak Company, Catalogue C, 1959), using carbon are light. Care'was taken 'to assure exact registration of the areas to beetched on both sides of the plate.
  • the total wet film weight of the 307 gasket was 119 milligrams and the dry film weight was 85 milligrams.
  • the composition was set to an elastomeric solid byheating at 185 C. for 3 minutes. Gasketed 307 can ends were then stamped from the pattern on the tin plate and were conventionally double seamed onto can end bodies without difficulty.
  • Number 307 can end gasket designs were also prepared in the following manner, which is preferred because of the precision and simplicity it offers.
  • a punched metal sheet conventionally used as a filter suppport was used to obtain the mesh pattern.
  • the punched holes had diameters of 2.97 millimeters and were located on 3.90 millimeters triangular centers.
  • This punched sheet was photographically reproduced to give a positive of the same scale. This positive was then reduced in size seven times to give a negative of the mesh pattern with the white dots thereon corresponding to the areas to be etched having a diameter of 0.420 millimeter $0.015 millimeter. This negative was overlayed with a negative of the gasket band design and the composite was used as a master to simultaneously prepare two positives with registration marks as previously described.
  • the positives were placed on either side of a 0.200 millimeter thick 302 stainless steel sheet coated with a resist, with there being exact registration between the mesh patterns on each sideof the metal sheet.
  • the resist coatings were thendeveloped, and the plate was etched on each side to. develop the perforations.
  • the final diameters of the holes after etching was 0.516 millimeter, 10.015 millimeter, as measured on the surface.
  • the perforations created about-a 60 percent free open area within the band area.
  • the band had an internal diameter of 88 millimeters, and an external diameter of 96 millimeters.
  • a method of'fabricating container closure gaskets by transferring a fluid gasket-forming composition through a stencil onto a sheet, said stencil having a permeable area of the desired gasket shape, and subsequently setting the composition so transferred to a deformable solid
  • the improvement comprising the use of a rigid form-stable sheet as said stencil, the gasket design in the sheet being composed of a multiplicity'of small independent perforations with the surrounding continuous lattice-work on the -reverse.'side of the sheet being substantially on a level with the remaining background of the sheet, said sheet having a thickness in the range of 0. 100 to 0.500 millimeter, and said design having in the range of 250 to 2500 perforations per square centimeter wherein the perforations occupy 40 to 75% of the total area encompassed by the design.
  • a method of forming a can end gasket on metal sheet comprising placing the obverse face of a form-stable printing plate in contact with the top surface of a metal sheet to receive said gasket, said plate having a can end gasket design therein consisting of a multiplicity of independent small holes, defined by a continuous surrounding latticework, placing a fluid gasket-forming composition on the reverse side of said perforated plate, forcing said composition through said holes and into contact with said surface, separating said plate from said sheet and leaving a predetermined amount of compound on said surface, and converting the compound so transferred to a form-stable shape, said sheet having a thickness in the range of 0.100 to 0.500 millimeter, and said design having in the of 250 to 2500 perforations per square centimeter wherein the perforations occupy 40 to 75 of the total area encompassed by the design.

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Description

Aug. 3, 1965 J, DWYER ETAL PRINTING OF CONTAINER CLOSURE GASKETS Filed May 2, 1961 ETCH DRYING 8| HEATING FIG. 2
FIG. 3
TRANSFER IMAGE TO PLATE STAMPING l Ll8 GASKETED 32 CAN ENDS FIG. 4
PHOTO- GRAPHICALLY REDUCE SCRAP United States Patent 3,198,109 PRINTING 0F (ZGNTAINER KJLQSURE GASKETS James'L. Dwyer, Concord, Richard J. Haberlin, Weston, and George A. Latin-op, Qoucord, Mass assignors to W. R. Grace 8: Co., Cambridge, Mass, a corporation of Connecticut Filed May 2, 1961, Ser. No. 107,198 8 Claims. (Cl. 101-129) This invention pertains to a method and apparatus for applying sealing or gasketing compound during the manufacture of container closures and the like. More particularly, it is directed to a method of forming can end, crown closure and similar gaskets on flat stock from which gasketed container closures can then be fabricated.
Can end gaskets have been formed on punched can ends by nozzle lining. Nozzle lining involves applying a fluid gasket-forming compound through a nozzle to the edge of a can end, usually while spinning the can end if it is round. This method is mechanically complex and is not Well suited to the lining of irregular shaped ends such as rectangular or oval shapes. The compound application mechanism for irregular ends is usually based on the more complex and less reliable pantograph or die lining techniques.
More recently, it has been proposed to form container gaskets by a method akin to silk screen printing. The gaskets are formed in this method on flat metal sheet by forcing a fluid compound through a printing screen or stencil which carries the desired design, and closures with the gaskets are subsequently stamped from the metal sheet after setting the compound to its solid elastomeric form. See United States Patent No. 2,516,647.
The traditional screen printing method is inherently intermittent because the metal sheet must be stationary when printed. The improvements of the silk screen method that have been suggested in the past for making the method continuous are usually complex and generally unsatisfactory. Also, experimental work has shown that the uniform gasket thicknesses and weights which are required for container closures are difficult to achieve by this method for such reasons as screen flexibility or distortion, squeegee wear and poor separation between the screen and metal sheet.
In brief compass, the method of this invention comprises the printing of a fluid gasket-forming composition of the shape desired onto a metal sheet. The printing is accomplished by forcing the composition through a rigid, dimensionally stable, stencil or plate which is finely perforated in the area Where the composition is to be transferred. The printing is essentially on contact printing. This permits good definition to be obtained and facilities and securing of the requisite uniform film weights. The printing steps is followed by conversion of the composition so printed to form-stable gaskets.
The metal sheet is thereafter cut or stamped into can ends, crown closures, lug caps and the like in a conventional manner.
The essence of this invention resides in effecting the printing through the use of a fairly rigid, dimensionally or form-stable plate having the desired design or gasket shape defined therein by minute perforations. The de sign is composed of a multiplicity of small independent holes or perforations surrounded by a continuous lattice- Work of the plate material. The printing plate is sufliciently rigid and so mounted as to be substantially inflexible under the conditions of use.
The perforation may be formed by any convenient method such as drilling or engraving, but it is much preferred to prepare the perforated design in the printing plate by etching because of the number of holes involved and their minute size.
A more specific and preferred embodiment of this invention is concerned with the use of curvilinear perforated plates in the printing step which permits linecontact printing. This materially improves the separation between the printing plate and the metal sheet and greatly reduces variations in the film weights of the gaskets.
Dry film thicknesses in the order of 0.025 to 1 millimeter are generally required for the types of container sealing gaskets contemplated. The present invention is particularly suited to the making of gaskets of 0.050 to 0.250 millimeter thickness, which thickness encompasses the majority of the can sealing applications. It has been established that the process of this invention is capable of depositing films of this thickness in a single step. The individual band widths for conventional can gaskets will usually be in the range of 2 to 8 millimeters. The method of this invention is particularly suited to the printing of gaskets which have two or more bands. It permits placement of dual or multi-band gaskets with a precision that is difficult to achieve by other methods.
Usually the perforated plate used in the printing of a gasket-forming compound will contain a plurality of the desired container closure gasket designs arranged in a uniform pattern. ing plate in the manner of this invention permits a high degree of uniformity to be achieved even after several hundred or thousand cycles of printing. Dry weight variations in any one design and between designs are normally less than :5 percent and are usually within :2 percent. This precision is secured while printing or laying down relatively large amounts of material, generally over 1 milligram per square centimeter of the gasket band (dry film weight). This precision is highly desirable because inadequate film weights in one or more areas result in gasket or closure failures and excessive weights result in waste of the compound besides creating other difliculties.
While this invention is particularly directed to the manufacture of can end gaskets, it will be appreciated by those skilled in the art that the present invention can be usefully applied in any situation where it is desired to place a repeating pattern of a fluid polymer-containing system, such as a dispersion, solution, melt or emulsion, on a receptive form-stable substratum. Thus crown closures can be made by the method of this invention as well as pregasketed electrical conduit junction box covers. Masonite panels decorated with a relatively thick design of an elastomer and useful in the manufacture of glass top tables can also be made.
The nature and scope of this invention will become clear from the following discussion and examples made with reference to the drawings attached to and forming a part of the specification.
In the drawings:
FIGURE 1 illustrates the present process applied to the fabrication of gasketed can ends. The printing in this instance is carried out with a planar perforated plate using a flexible squeegee to force compound through the perforations, in a manner similar to silk screen printing;
FIGURE 2 shows in enlarged detail a segment of one of the perforated gasket designs in the printing plate;
FIGURE 3 shows in cross-section an oscillating curvilinear printing plate;
FIGURE 4 illustrates a continuous rotary printing method; and
FIGURE 5 schematically illustrates one method of placing the perforated gasket designs in the printing plate.
Referring to FIGURE 1, the printing plate 10 of this invention is attached to a suitable rigid framework 11.
The use of a rigid perforated print 12. The plate is placed Withits obverse side on the strip or sheet of metal 13 which is to receive the gaskets. The
The printing plate contains a plurality of can end designs compound to be printed is placed on one end of the reverse side of plate 10 and is forced into thejperforations by a I rubber squeegee 14 which is pulled along the length of the plate. The frame is then lifted up, strip 13 is moved I forward to the next position, the'frame is again placed down on the strip and the cycle is repeated. The still fluid can end gaskets from the proceeding cycle are illustrated at 15. 7 V The fluid composition thus transferred to sheet 13 is convertedto-a solid elastomeric or deformable plastic form in a conventional manner, as in a'dryingand heating oven 16. The sheet with the form-stable shapes isthen transferred to a punching machine 17 that stamps the 4 trouble is experienced with viscosities below about 10,000 centipoises (Brookfield Model LVFSX No. 4 Spindle, 60 1'.p.m., 27 C.). Viscositites as high as 200,000 centipoises can be handled. It is preferred to use relatively plastic or pseudo-plastic compounds to avoid run out.or
flow 0f the compound after printing. This may be more precisely defined by sayingYthat it .i preferred to use compounds whose PIRV? slope falls in the range of 0.3
to 0.6. I
The Precision Interchemical Rotary viscometer determines the flow properties of a compound over a range of shear stresses. The PIRV slope is the logarithmic rate of change of the shear stress with the shear rate as determined by' plotting on log-log paper the shear stress in gasketed can ends from the sheet. The can ends are removed at 18 and the perforated scrap at-19.
FIGURE 2 shows in enlarged detail a plan view of a segment 0f-one of the perforated designs 12 in the printing plate. The design consists of a multiplicity of small independent perforations or holes 20, usually arranged in a unform geometric pattern. .Whileround holes are'illustrated, they may have any shape desired such as triangular, square, hexagonal, ovoid and the like.
The composition transferred to the metal sheet in the manner of this invention is initially in the form. ofsmall individual liquid dots which, depending on the rheology of the composition, may immediately flow together or may be made to flow together thereafter as; by heating to form a'continuous film. Generally speaking, it is preferred to have the mesh of the perforated design, i.e. the number of holes per unit area, so .fine .that coalescence is not a problem. In some application, of course, it may not be necessary for the individual dots to coalesce.
The printing plate can have a thickness 1n the range reciprocal seconds." V I .From the standpoint of obtaining the relatively heavy 'dynes per square centimeter against the shear rate in film weights desired for can sealing applications, it is preferred that thesolids content, i.e. the dry film weight to the Wet film weight ratio, of the compounds be in the range of 50 to 100 percent. The compound should wet the surface of the plate being printed, i.e. a 3 to 6 millimeter drop of compound on the surface should have no tendency for withdrawal, Aslight enlargement of the drop is preferred. The wettabilityof the surface being printed can be improvedby suitable mean such as coating it with a thin adhesive or lacquer.
Generally speaking, compound is not forced through the 7 holes onto. the sheet being printed, but is forced into the holes slightly in advance of and at the time the plate is in contact with the sheet. Thefluidcompound is then-removed orpulled from the holes because of its adherence to the sheet/ There may be a slight amount-of force of 0.100 to 0.500 millimeter. It has been found that if the plate is toothin, the amount of compoundtransferred is insufficient for most gasketapplications, and if the plate has a thickness over about 0.500 millimeten'the perforations do not completely empty or drain with each cycle, with the hole sizes and compoundrheologies customarily used. A fair amount of rigidity in the printing plate'is de-' sired so that it will not stretch or distort during use and will continueto give clean separations afterseveral thousand cycles. t
L The perforated design contains, or has a mesh, in the range of 250 to 2 500, preferably 550 to 1500, holes per square centimeter. The surface area encompassed by the open end of a single perforation is in they range of 0.015
to 0.235 square millimeter. The open or free areaofthe' applied to thecompound by the squeegee as separation begins but it is not significant, nor is it desirable because it causes variable flow out and loss :of definition. i The rate of separation of. the printing plate from the sheet influences, With a great dealof variability, the relative amount of compound that is retained by the plate and the amount which adheres and transfers to the sheet because differences in separation rates result in different holes preferably falls within the range of 40 to 75 percent 1 of the total areaencompassed by the design. The pull-off resistance, or energy required to separate the printing plate 4 from the metal sheet, decreases as the mesh of the design For the same percentage open area in the designfthe finer meshes printwith better. definition.
becomes finer.
In this connection, itis desirable in some instances to recess or form a channel inthe'obverse or printing side of the design, perferably in the orderfof 0.0025 to 0.0110 millimeter deep, inorder to permit some underflow or spreading out of the compound around each hole. An
unduly coarse mesh may give some cumulative smearing when used with a undercut channel. The reverse side'of the plateis maintained smooth, i.e. the lattice workabout the perforations is on level" with the background of the design on the reverse surface of the printing plate. Thi permits a better doctoring or squeegeeing action'and so supports the blade. astoprevent wear and flexing of' the blade into the holes. Usually the hole size andspacing is uniform .throughout the perforated design, but it may be desirable to have some gradation in. some gasket applications.
shear stresses on the compound beingprinted, which is usually a non-Newtonian fluid. It is desirable to have a linear line of separation across the Width of. the printing plate with'no or'little fluctuation in the shear force along the line' in order to obtain uniform film Weights. This linear line of separation is obtained with a rigid plate, as opposed to thecustornary woven and flexible screens that are used in silk screen printing. A Woven screen, sometimes initially, but usually after some wear, sags or distorts in the middle of the frame and results in different snap-off rates along the line ofseparaition across the width of the screen. Also, it can be appreciated that the problem of obtaining uniform separations makes the use of-curvilinear printing plates. preferable. 1
The; printing plate is "designed. to be essentially in contact with the metal sheet at the time transfer of the compound begins; It is desirable not to separate or shim 'the plate by more than 0.03' millimeter, with a precision definition and non-uniform transfer of The composition orchemical constituents of the gasketforming compounds being printed is not too important,
nor is the rheology. of the compounds too material. Some Precisionlnterchemical Rotary viscometer, see: Precislon Scientific Co. Instruction Manual, Catalogue No. 64-945,
B. Barrish, issued-June 14:, 1955, Precision Scientific 00.,
37 W. Cortland St, Chicago 47, Ill.
that each hole and design is properly filled prior to separation of the printing plate from the metal sheet. It has been found that the hydrostatic force on the compound, created by moving the squeegee over the plate, varies considerably because of non-uniform squeegeeing velocity, squeegee angle and shape, compound rheology and the like. It is desirable, therefore, to provide for the creation of a considerable excess hydrostatic force on the compound to assure spreading of the compound and filling of the holes, and to prevent overfilling by maintaining the obverse side of the holes in contact with the metal sheet or substantially so in the area of squeegee contact.
The following table gives the physical properties of gasket-forming compounds that can be printed successfully by the technique of this invention.
Compound A B O D PI RV slope Total solids, percent Brookfield viscosity, oentipoises (Model LVFSX, No. 4 Spindle, 25 0.):
6 rpm 60 r.p.m
Compound A is a butadiene-styrene-acrylonitrile terpolymer dispersion carried in a paraflinic solvent, with a clay filler added.
Compound B is a SBR rubber (70 weight percent butadiene, 30 weight percent styrene) dispersed in an aromatic solvent, with a small amount of clay filler added.
Compound C is an alcohol dispersion of a low molecular weight liquid neoprene.
Compound D is a polyvinyl chloride plastisol.
The use of a curvilinear perforated printing plate is illustrated in FIGURE 3. The curvilinear design is preferred because it gives clean separation between the printing plate and the sheet being printed. As illustrated (in cross-section) the printing plate 21 is attached to a frame 22 which is shaped to form part of an arc of a cylinder. The radius of curvature when using a curvilinear plate is preferably in the range of 0.05 to 1.5 meters. The obverse face of plate 21 is placed against the surface of the metal sheet 23 which is to receive the gasket shapes. Plate 21 is perforated by holes 24 in the areas where it is desired to print. The squeegee blade 25 is initially placed at one end of the frame on the reverse side of the plate, and that end portion of the plate is placed in contact with sheet 23. Compound 26 to be printed is placed in front of the squeegee blade. The screen and frame is then oscillated or rocked in the direction indicated. The squeegee is activated in such a manner by conventional means (not shown) that it moves synchronously in the direction indicated with the rocking of the printing plate, and is kept just about at the point of tangency between the plate and sheet 23. The printing cycle is repeated by slightly lifting frame 22 and plate 21 up, advancing sheet 23 while oscillating the frame back to the starting position and correspondingly moving the squeegee, and then again bringing the plate in contact with sheet 23.
In FIGURE 4, a printing plate 30 is fabricated into a full cylinder which permits continuous rotary printing and avoids the intermittent step-wise printing methods illustrated in FIGURES 1 and 3. The printing plate 30 is so mounted as to be able to rotate continuously while in contact with the sheet 31 which receives the gaskets. Sheet 31 is continuously advancing in the direction indicated. The printing cylinder is shown in crosssection and contains holes or perforations 32 in the periphery thereof through which compound is transferred to the plate in the pattern desired. Hollow cylinder 30 contains a shoe 33 which operates on the principle of a journal-bearing to develop a hydraulic pressure on the compound 34 trapped in the channel between the shoe and the perforated cylinder 30. The radius of the face of the shoe is less than the radius of the roller and is more closely spaced to the cylinder at the bottom. As the compound passes down the channel between the roller and the shoe, it is put under hydraulic pressure, and this pressure forces it into the holes 32 to the obverse side of the perforated cylinder 30. As rotation of cylinder 30 continues, the compound in holes 32 is brought into contact with the surface of sheet 31 and is transferred thereto as previously described. Excess compound, in the particular embodiment illustrated, is scraped off the inner surface of cylinder 30 by doctor blade 35 into area 36 between the doctor blade and the shoe. From there it is transferred by a pump 37 to the upper portion of the channel between the shoe and cylinder 30. Compound can be admitted into the cylinder as needed in any convenient manner such as by an external pump operating through an inlet line in the axis of the cylinder. The picking up of excess compound by doctor blade 35 and transfer thereof by internal pump 37 may not be necessary. The compound can be allowed to stay on the inner surface of cylinder 30 and make a full revolution around the cylinder and be returned to the channel between the shoe and cylinder 30 in this manner.
The plate 30 in this instance has a thickness of 0.185 millimeter and an internal diameter of 92.5 centimeters. The shoe 33 has a radius of curvature on its outer face of 30.8 centimeters and is spaced 38.1 millimeters from the inner surface of the cylinder at its upper point and 0.062 millimeter at its lowest point. Its lowest point is about 0.095 millimeter in advance of the line of tangency between the cylinder and sheet 31.
FIGURE 5 illustrates a method of preparing and placing the etchable design on the metal surface. The design comprises a multiplicity of small independent etchable areas. The etachable areas may be undersize with respect to the finished size of the etched areas to be produced. This depends on the type and thickness of the metal plate being used. The etchable areas are surrounded by a continuous lattice-work of non-etachable areas.
In one method, an enlarged design 40 of the mesh pattern is prepared. It comprises a suitable supporting mem her having the desired mesh pattern, i.e. a multiplicity of small dots 41 in greatly enlarged detail. The mesh pattern can be prepared, for example, by hand inking or can be taken from an available mesh pattern. By using an enlargement, any errors in the precision of the small etchable areas are greatly reduced when the design is reduced to its finished size. Even so it is preferred that the surface area of the enlarged dots have a precision within 1 5 percent. As noted previously, these dots may be relatively undersized with respect to the final area of the holes to be etched if they were drawn on the same scale. The gasket band design may or may not be superposed on the mesh pattern at this point. As illustrated, the enlarged mesh pattern has been drawn to include the gasket band pattern. However, the band pattern can be placed on the mesh pattern by using a suitable overlay prior to or at the point where the negative master is photographed to produce the positives used to develop the resist on the metal surface.
The enlarged master so prepared is then photographically reduced preferably at least 5 times by conventional methods to produce a positive in step 42 with care being taken to avoid distortion. The positive so obtained is developed and is used in step 43 to develop a resist on the metal surface to be etched. The resist is developed in a conventional manner to give etchable areas corresponding to the original dots 41 of the master.
The technique of preparing a positive print from an enlarged master is useful when an existing mesh design or pattern with sufiicient precision cannot be found. Positives have been prepared from suitable mesh patterns exposed films were developed to give two positives.
such as a woven screen by directly photographing the pattern without reduction. I V
It has been found to be particularlyadvantageous to etch both sides ofthe plate simultaneously. In order to do this it is necessary to have the minute etchable areas on both sides ofthe plate in exact registration. This can be done by coating both sides of the plate with a resist, placing the platebetween two photographically produced positives which are exact duplicates, with suitable registration marks being present on the positives, and exposing the resist. Exact registration of the mesh design can be assured by photographing a negative master that has suitable registration marks using two films placed together in the camera, and then developing the simultaneously exposed films.
The holes are etched in the plate or roll in-step 44, again in a conventional manner. Electrolytic, acid etching and the like may be used. Carehas to be taken in the layout of the design and in control of the etching conditions to avoid undercutting and loss of the design or a radius of curvature of.91.5 centimeters.
portions thereof before complete perforation of the plate is obtained. It is preferred to so design the etchable areas as to obtain complete through penetration of the etchable areas before full development of the width of each hole has been obtained. This permits the holes to be brought out to size gradually without running into breakthrough between the cavities. 'The etching action is facilitated by having the edges ofthe etchable areas about 0.8 to 1.2 millimeters undersize for each millimeter of depth that is to be etched.
Example A 307 can end gasket design was prepared in the manner illustrated in FIGURE 5. The number 307 refers to a can end that has an outside diameter of 3 inches after double seaming on a standard American Number 2 can body. The gasket design on the printing plate had 'an internal diameter of 88 millimeters and an outside diameter of 96 millimeters. The design was composed of a regular pattern of square holes. The width of each of the perforated holes, after etching, was 0.225 millimeter $0.015 millimeter, as measured on the surface. There were 990 holes used per square centimeter of the band 'width, with there being about 13 rows of holes across the width of the band. The perforations created'about a 50 percent free open area within the gasket design area. The master of this'design had an internal diameter of 88 millimeters and an outside diameter of 96 millimeters. Each square dot in the master had a width of about 0.200 millimeter $0.015 millimeter. V The master was prepared by overlaying 80'mesh bolting cloth (Tyler) with a negative of the gasketband design. This master, with registration marks thereon, was photographically reproduced with there being two films (Kronar type) in the camera. .The simultaneously The positives were placed on either side of a 6x 12 x 0.250 millimeter copper plate coated on both sides with a resist (Kodak Photo ResistEastman Kodak Company, Catalogue C, 1959), using carbon are light. Care'was taken 'to assure exact registration of the areas to beetched on both sides of the plate.
It. was not necessary here to have the'etchable areas iappreciably undersize with respect to the final size'of the perforations because there is negligible sideways etching with such thin copper sheet and with the thread offered by the bolting cloth. 7 p p The images in the resist were developed to give etchable areas on the metal.
crementally etched in a conventional manner using an iron perchlorate solution until the desired hole .diametersare uniformity Ereached. p The copper plate soprepared with this 307 can end. gasket design in it, along with others of varied hole sizes and patterns, was attached to a supporting frame having The etchable areas were then in- This arrangement was used to print pound tin plate (0.250 millimeter thick) with 307 can end gaskets. The compound used was compound a identified in the table, supra. Copper platescannot be used with some compounds because copper will'affect the stability of some compounds. A square edged rubber squeegee was used to force compound into the perforations, and transfer to the sheet was secured by rocking the perforated plate as described in connection with FIGURE 3. I
The total wet film weight of the 307 gasket was 119 milligrams and the dry film weight was 85 milligrams. The composition was set to an elastomeric solid byheating at 185 C. for 3 minutes. Gasketed 307 can ends were then stamped from the pattern on the tin plate and were conventionally double seamed onto can end bodies without difficulty.
Number 307 can end gasket designs were also prepared in the following manner, which is preferred because of the precision and simplicity it offers.
A punched metal sheet conventionally used as a filter suppport was used to obtain the mesh pattern. The punched holes had diameters of 2.97 millimeters and were located on 3.90 millimeters triangular centers. This punched sheet: was photographically reproduced to give a positive of the same scale. This positive was then reduced in size seven times to give a negative of the mesh pattern with the white dots thereon corresponding to the areas to be etched having a diameter of 0.420 millimeter $0.015 millimeter. This negative was overlayed with a negative of the gasket band design and the composite was used as a master to simultaneously prepare two positives with registration marks as previously described.
The positives were placed on either side of a 0.200 millimeter thick 302 stainless steel sheet coated with a resist, with there being exact registration between the mesh patterns on each sideof the metal sheet. The resist coatings were thendeveloped, and the plate was etched on each side to. develop the perforations.
The final diameters of the holes after etching was 0.516 millimeter, 10.015 millimeter, as measured on the surface. There was 275 holesper square centimeter of the band width of the gasket design, with-there being about 6 to 7 rows of holes across the widthof the band. The perforations created about-a 60 percent free open area within the band area. The band had an internal diameter of 88 millimeters, and an external diameter of 96 millimeters.
' Having described this invention, what is sought to be protected by Letters Patent is succinctly set forth in the following claims. V i
What isclaimed is:
1. In a method of'fabricating container closure gaskets by transferring a fluid gasket-forming composition through a stencil onto a sheet, said stencil having a permeable area of the desired gasket shape, and subsequently setting the composition so transferred to a deformable solid, the improvement comprising the use of a rigid form-stable sheet as said stencil, the gasket design in the sheet being composed of a multiplicity'of small independent perforations with the surrounding continuous lattice-work on the -reverse.'side of the sheet being substantially on a level with the remaining background of the sheet, said sheet having a thickness in the range of 0. 100 to 0.500 millimeter, and said design having in the range of 250 to 2500 perforations per square centimeter wherein the perforations occupy 40 to 75% of the total area encompassed by the design. a
1 work, said, sheet having a thickness in the range of 0.100
to 0.500 millimeter, and said design having in the range of 250 to2500 perforations per square centimeter wherein the perforations occupy 40 to 75% of the total area encompassed by the design.
3. The plate of claim 2 when curvilinear.
4. A method of forming a can end gasket on metal sheet comprising placing the obverse face of a form-stable printing plate in contact with the top surface of a metal sheet to receive said gasket, said plate having a can end gasket design therein consisting of a multiplicity of independent small holes, defined by a continuous surrounding latticework, placing a fluid gasket-forming composition on the reverse side of said perforated plate, forcing said composition through said holes and into contact with said surface, separating said plate from said sheet and leaving a predetermined amount of compound on said surface, and converting the compound so transferred to a form-stable shape, said sheet having a thickness in the range of 0.100 to 0.500 millimeter, and said design having in the of 250 to 2500 perforations per square centimeter wherein the perforations occupy 40 to 75 of the total area encompassed by the design.
5. The method of claim 4 wherein said fluid gasketforming composition has a PIRV slope in the range of 0.3 to 0.6.
6. The method of claim 4 wherein said plate is curvilinear and forms essentially a line contact with said metal sheet.
7. The method of claim 6 wherein said compound is forced through said holes from a channel between said 10 reverse side and a curved member, wherein the compound is subjected to hydraulic pressure.
8. The method of claim 6 wherein said plate forms a full cylinder, and is continuously rotating during the trans fer of said compound.
References Cited by the Examiner UNITED STATES PATENTS 1,480,348 1/24 Cadgene et al 101-120 2,109,336 2/38 Marsden 101-119 X 2,276,181 3/42 Foster 101-129 X 2,369,960 2/45 Gage et a1. 76107 2,424,949 7/47 White. 2,456,615 12/48 Bergiund 1859 2,516,647 7/50 Rogers et al. 2,743,629 5/56 Pellegrino et al 76--107 2,895,412 7/59 Reed. 2,928,340 3/60 Stein et al. 3,004,297 10/61 Stover 18-59 FOREIGN PATENTS 692,614 6/53 Great Britain. 827,003 1/60 Great Britain.
WILLIAM B. PENN, Primary Examiner.
W. A. WILTZ, DAVID KLEIN, Examiners.

Claims (1)

  1. 4. A METHOD OF FORMING A CAN END GASKET ON METAL SHEET COMPRISING PLACING THE OBVERSE FACE OF A FORM-STABLE PRINTING PLATE IN CONTACT WITH THE TOP SURFACE OF A METAL SHEET TO RECEIVE SAID GASKET, SAID PLATE HAVING A CAN END GASKET DESIGN THEEIN CONSISTING OF A MULTIPLICITY OF INDEPENDENT SMALL HOLES, DEFINED BY A CONTINUOUS SURROUNDING LATTICEWORK, PLACING A FLUID GASKET-FORMING COMPOSITION ON THE REVERSE SIDE OF SAID PERFORATED PLATE, FORCING SAID COMPOSITION THROUGH SAID HOLES AND INTO CONTACT WITH SAID SURFACE, SEPARATING SAID PLATE FROM SAID SHEET AND LEAVING A PREDETERMINED AMOUNT OF COMPOUND ON SAID SURFACE, AND CONVERTING THE COMPOUND SO TRANSFERRED TO A FORM-STABLE SHAPE, SAID SHEET HAVING A THICKNESS IN THE RANGE OF 0.100 TO 0.500 MILLIMETER, AND SAID DESIGN HAVING IN THE OF 250 TO 2500 PERFORATIONS PER SQUARE CENTIMETER WHEREIN THE PERFOATIONS OCCUPY 40 TO 75% OF THE TOTAL AREA ENCOMPASSED BY THE DESIGN.
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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3735730A (en) * 1969-12-22 1973-05-29 Mitter & Co Apparatus for applying a flowable medium to a carrier
US3785284A (en) * 1969-01-28 1974-01-15 Stork Brabant Bv Screen printing machine
US3796153A (en) * 1972-02-25 1974-03-12 Precision Screen Machines Squeegee assembly with last motion flood roller mount
US3807302A (en) * 1971-07-20 1974-04-30 Zimmer P Roller squeegee device with fluid pressure increasing means
FR2220387A1 (en) * 1973-03-09 1974-10-04 Encoline Process Ltd
US3890896A (en) * 1972-01-04 1975-06-24 Peter Zimmer Textile-printing machine
US3921521A (en) * 1970-07-23 1975-11-25 Zimmer Peter Squeegee device
US4078488A (en) * 1975-07-26 1978-03-14 Engineering Components Limited Method of preparing a printing screen by molding
EP0071014A1 (en) * 1981-07-02 1983-02-09 Fritz Buser Ag Maschinenfabrik Method and element to transfer printing ink to a material in screen printing
FR2516448A1 (en) * 1981-11-18 1983-05-20 Armstrong World Ind Inc METHOD FOR MANUFACTURING A ROTATING PRINTING FRAME WITH THICK ZONES
FR2596676A1 (en) * 1986-04-07 1987-10-09 Vernhet Louis Method for producing an adhesive surface and adhesive support (backing) obtained, in particular with a view to transferring an element
US5017394A (en) * 1986-10-13 1991-05-21 The Lucks Company Method for making edible base shapes having pictorial images for decorating foodstuffs
US5375516A (en) * 1992-07-16 1994-12-27 Riso Kagaku Corporation Stencil printing device having a plurality of printing drums arranged on an incline
DE19736000A1 (en) * 1997-08-19 1999-02-25 Heberndorfer Leistenfabrik Direct goods labeling method
EP1474294A1 (en) * 2002-01-11 2004-11-10 Yong-Seok Choi Method of silk screen printing
US20150182991A1 (en) * 2013-12-31 2015-07-02 Johnson & Johnson Consumer Companies, Inc. Process for forming an integral film product
US10624362B2 (en) 2015-01-07 2020-04-21 The Lucks Company, Llc Edible print substrates and methods of making and using the same
US10661302B2 (en) 2013-12-31 2020-05-26 Johnson & Johnson Consumer Inc. Process for forming a shaped film product
US11247226B2 (en) 2013-12-31 2022-02-15 Johnson & Johnson Consumer Inc. Process for forming a multilayered shaped film product

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US1480348A (en) * 1922-12-05 1924-01-08 Cadgene Ernest Fabric-printing machine
US2109336A (en) * 1935-07-10 1938-02-22 Marsden Leonard Machine for depositing cream, chocolate, or the like on biscuits
US2276181A (en) * 1939-06-30 1942-03-10 Velveray Corp Fabric printing procedure
US2369960A (en) * 1943-12-06 1945-02-20 Gage Printing Company Ltd Method of making templates
US2424949A (en) * 1943-11-08 1947-07-29 T & T Vicars Ltd Coating of articles
US2456615A (en) * 1948-12-21 berglund
US2516647A (en) * 1946-05-13 1950-07-25 Continental Can Co Method of making closure elements
GB692614A (en) * 1949-09-08 1953-06-10 Hunt A H Ltd Improvements in or relating to the metallisation of the surfaces of dielectric material
US2743629A (en) * 1952-11-18 1956-05-01 Photo Color Process Corp Method of making tools and dies
US2895412A (en) * 1958-04-01 1959-07-21 Dry Screen Process Inc Printing apparatus
GB827003A (en) * 1957-01-09 1960-01-27 Associated Trapinex Ltd Improvements in or relating to screen printing
US2928340A (en) * 1957-03-21 1960-03-15 Stein Textile printing machine
US3004297A (en) * 1958-08-12 1961-10-17 Anchor Hocking Glass Corp Method for forming a gasket

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US2456615A (en) * 1948-12-21 berglund
US1480348A (en) * 1922-12-05 1924-01-08 Cadgene Ernest Fabric-printing machine
US2109336A (en) * 1935-07-10 1938-02-22 Marsden Leonard Machine for depositing cream, chocolate, or the like on biscuits
US2276181A (en) * 1939-06-30 1942-03-10 Velveray Corp Fabric printing procedure
US2424949A (en) * 1943-11-08 1947-07-29 T & T Vicars Ltd Coating of articles
US2369960A (en) * 1943-12-06 1945-02-20 Gage Printing Company Ltd Method of making templates
US2516647A (en) * 1946-05-13 1950-07-25 Continental Can Co Method of making closure elements
GB692614A (en) * 1949-09-08 1953-06-10 Hunt A H Ltd Improvements in or relating to the metallisation of the surfaces of dielectric material
US2743629A (en) * 1952-11-18 1956-05-01 Photo Color Process Corp Method of making tools and dies
GB827003A (en) * 1957-01-09 1960-01-27 Associated Trapinex Ltd Improvements in or relating to screen printing
US2928340A (en) * 1957-03-21 1960-03-15 Stein Textile printing machine
US2895412A (en) * 1958-04-01 1959-07-21 Dry Screen Process Inc Printing apparatus
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Cited By (22)

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Publication number Priority date Publication date Assignee Title
US3785284A (en) * 1969-01-28 1974-01-15 Stork Brabant Bv Screen printing machine
US3735730A (en) * 1969-12-22 1973-05-29 Mitter & Co Apparatus for applying a flowable medium to a carrier
US3921521A (en) * 1970-07-23 1975-11-25 Zimmer Peter Squeegee device
US3807302A (en) * 1971-07-20 1974-04-30 Zimmer P Roller squeegee device with fluid pressure increasing means
US3890896A (en) * 1972-01-04 1975-06-24 Peter Zimmer Textile-printing machine
US3796153A (en) * 1972-02-25 1974-03-12 Precision Screen Machines Squeegee assembly with last motion flood roller mount
FR2220387A1 (en) * 1973-03-09 1974-10-04 Encoline Process Ltd
US4078488A (en) * 1975-07-26 1978-03-14 Engineering Components Limited Method of preparing a printing screen by molding
EP0071014A1 (en) * 1981-07-02 1983-02-09 Fritz Buser Ag Maschinenfabrik Method and element to transfer printing ink to a material in screen printing
FR2516448A1 (en) * 1981-11-18 1983-05-20 Armstrong World Ind Inc METHOD FOR MANUFACTURING A ROTATING PRINTING FRAME WITH THICK ZONES
FR2596676A1 (en) * 1986-04-07 1987-10-09 Vernhet Louis Method for producing an adhesive surface and adhesive support (backing) obtained, in particular with a view to transferring an element
US5017394A (en) * 1986-10-13 1991-05-21 The Lucks Company Method for making edible base shapes having pictorial images for decorating foodstuffs
US5375516A (en) * 1992-07-16 1994-12-27 Riso Kagaku Corporation Stencil printing device having a plurality of printing drums arranged on an incline
DE19736000A1 (en) * 1997-08-19 1999-02-25 Heberndorfer Leistenfabrik Direct goods labeling method
EP1474294A1 (en) * 2002-01-11 2004-11-10 Yong-Seok Choi Method of silk screen printing
EP1474294A4 (en) * 2002-01-11 2005-11-02 Yong-Seok Choi Method of silk screen printing
US20150182991A1 (en) * 2013-12-31 2015-07-02 Johnson & Johnson Consumer Companies, Inc. Process for forming an integral film product
US10661302B2 (en) 2013-12-31 2020-05-26 Johnson & Johnson Consumer Inc. Process for forming a shaped film product
US11203037B2 (en) 2013-12-31 2021-12-21 Johnson & Johnson Consumer Inc. Apparatus for forming a shaped film product
US11247226B2 (en) 2013-12-31 2022-02-15 Johnson & Johnson Consumer Inc. Process for forming a multilayered shaped film product
US10624362B2 (en) 2015-01-07 2020-04-21 The Lucks Company, Llc Edible print substrates and methods of making and using the same
US10925296B2 (en) 2015-01-07 2021-02-23 The Lucks Company, Llc Edible print substrates and methods of making and using the same

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