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US2863465A - Apparatus for metal cleaning by molten salt baths - Google Patents

Apparatus for metal cleaning by molten salt baths Download PDF

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Publication number
US2863465A
US2863465A US480862A US48086255A US2863465A US 2863465 A US2863465 A US 2863465A US 480862 A US480862 A US 480862A US 48086255 A US48086255 A US 48086255A US 2863465 A US2863465 A US 2863465A
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United States
Prior art keywords
sludge
molten salt
bath
work zone
basin
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Expired - Lifetime
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US480862A
Inventor
Robert H Shoemaker
John A Faler
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Kolene Corp
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Kolene Corp
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Publication date
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Priority to US480862A priority Critical patent/US2863465A/en
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Publication of US2863465A publication Critical patent/US2863465A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/28Cleaning or pickling metallic material with solutions or molten salts with molten salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G3/00Apparatus for cleaning or pickling metallic material

Definitions

  • Patent No. 2,458,661 of January 11, 1949 there is described a metal cleaning process using a molten salt bath for the cleaning of metal.
  • Numerous other patents also disclose compositions and processes of this general type.
  • Patents Nos. 2,635,062 and 2,635,063 of April 4, 1953 disclose what are known as continuous strip baths for cleaning metal strip continuously in molten salt baths.
  • This application relates to improvements in baths for both types of processes.
  • One object of this application is to provide for the removal of the sludge by means of side chambers, that is to say, chambers within the bath but to one side or both sides of the work area, with some sort of mechanical means for removal of the sludge deposited in such side chambers.
  • One way of removing the sludge from such side chamher is to provide in the side chamber a lift out pan into which the sludge is deposited and which may be lifted out for removal of the sludge.
  • This application also has for an object the provision of means within a bath for agitating and stirring it so as to improve its operation and to assist in moving sludge into a side chamber or side settling basin where such chamber is provided in accordance with what has been described just above in connection with sludge removal.
  • Figs. 1 and 2 are a diagrammatic end elevation crosssection and plan view of the bath showing a side sludge settling chamber for settling sludge together with a pump for moving the molten salt from the work chamber to the side settling chamber.
  • Figs. 1 and 2 show a molten salt bath comprising a pot having burner tubes or heating pipes 11 for heating salt which fills the pot 10 to a level 14 and within the tubes or pipes 11 is a work area 15 to the left of which is a side chamber 16 in which is disposed a lift out pan 24 provided with a lift out bail 26.
  • Pan 24 fills with sludge and may be lifted out for the removal of such sludge.
  • an agitation means comprising agitators 48.
  • a pump 50 having its inlet 52 located within the work area 15 and its outlet 51 in the side chamber 16 where the sludge may be settled.
  • a barrier wall 55 having an overflow opening 56 which enables free movement of the liquid to the work area from the side chamber, with the level maintained equal in both the work area 15 and the side chamber 16 by means of the overflow opening 56.
  • the agitation means 48 constantly agitates the bath for the purposes of continuously and smoothly directing sludge out of the work area into the side chamber.
  • agitation of the salt bath as here disclosed insures rapid movement of the salt over the heating means, to heat the salt more rapidly, to accelerate heat transfer from the heating means to prolong their life, to insure more nearly uniform heating of the salt, and to prevent formation of deposits on the heating means.
  • a molten salt bath apparatus for cleaning metals of surface impurities comprising a pot having a work zone and having to one side of said work zone a settling basin, with said work zone and settling basin being relatively separated and barriered, heater tubes in said work zone and settling basin, means in the work zone for agitating said bath and for pumping said bath from said work zone to said basin, and an overflow means for permitting overflow from said basin to flow over it back to said work zone, and mechanical means for removing from said basin impurities settled therein as a sludge.
  • a molten salt bath apparatus for cleaning metals of surface impurities comprising a pot having a work zone and having to one side of said work zone a. settling basin, with said work Zone and settling basin being relatively separated and barriered, heater tubes in said work zone and settling basin, means in the work zone for agitating said bath and for pumping said bath from said work zone to said basin, and an overflow means for permitting overflow from said basin to flow over it back to said work zone, and mechanical means for removing from said basin impurities settled therein as a sludge, said first means comprising an agitator in said bath.
  • a molten salt bath apparatus for cleaning metals of surface impurities comprising a pot having a Work zone and having to one side of said work zone a settling basin, with, said ,Work zone and settling basin being relatively separated and barriered, heater tubes in said work zone and settling basin, means in the Work zone for agitating said bath and for pumping said bath from said Work zone to said basin, and an overflow means for permitting overflow from said basin to flow over it back to said Work zone, and mechanical means for removing from said basin impurities settled therein as a sludge, said first means including a pump Whose inlet is. in the work zone and Whose outlet is in the basin and operating for pumping faster than the impurities settle as a-sludge in the work zone.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Description

1958 R. H. SHOEMAKER ET AL 3,
APPARATUS FOR METAL CLEANING BY MOLTEN SALT BATHS Filed Jan. 10, 1955 INVENTORS. ROBERT H. SHOEMAKEIR- BY JOHN A. FALER ATTORNEY United States Patent Ofilice Patented Dec. 9, 1958 APPARATUS FOR NIETAL CLEANING BY MOLTEN SALT BATHS Robert H. Shoemaker and John A. Faler, Detroit, Mich., assignors to Kolene Corporation, Detroit, Mich.
Application January 10, 1955, Serial No. 480,862
3 Claims. (Cl. 134-104) This application relates particularly to the cleaning of metals by means of molten salt baths and is specifically directed to improvements in apparatus used for such purposes and more specifically to means for sludge removal, for replenishing the salt of the bath, and for agitation of the bath.
Introduction For some years the art has been utilizing molten salt baths for the cleaning of metals. In Patent No. 2,458,661 of January 11, 1949, there is described a metal cleaning process using a molten salt bath for the cleaning of metal. Numerous other patents also disclose compositions and processes of this general type. Patents Nos. 2,635,062 and 2,635,063 of April 4, 1953, disclose what are known as continuous strip baths for cleaning metal strip continuously in molten salt baths.
It is to the art of cleaning metal by means of molten salt baths, to which this application relates.
In the cleaning of metals by means of means of molten salt baths, there are generally two processes known to the trade. One is known as the batch process, wherein a batch of work parts are deposited in the bath, and then withdrawn after an interval. The other process more specifically shown in Patent No. 2,635,062 is known as the continuous strip process, where a strip of metal to be cleaned moves continuously through a bath.
This application relates to improvements in baths for both types of processes.
Sludge removal In such baths, sludge is formed and eventually settles to the bottom of the bath. Removal of such sludge is a primary concern of this application.
One object of this application is to provide for the removal of the sludge by means of side chambers, that is to say, chambers within the bath but to one side or both sides of the work area, with some sort of mechanical means for removal of the sludge deposited in such side chambers.
One way of removing the sludge from such side chamher is to provide in the side chamber a lift out pan into which the sludge is deposited and which may be lifted out for removal of the sludge.
This application also has for an object the provision of means within a bath for agitating and stirring it so as to improve its operation and to assist in moving sludge into a side chamber or side settling basin where such chamber is provided in accordance with what has been described just above in connection with sludge removal.
Aided by an understanding of the invention as may be obtained from the foregoing, reference will now be had to the apended drawing in which a specific embodiment of the foregoing concepts have been disclosed.
In the drawing:
Figs. 1 and 2 are a diagrammatic end elevation crosssection and plan view of the bath showing a side sludge settling chamber for settling sludge together with a pump for moving the molten salt from the work chamber to the side settling chamber.
Figs. 1 and 2 show a molten salt bath comprising a pot having burner tubes or heating pipes 11 for heating salt which fills the pot 10 to a level 14 and within the tubes or pipes 11 is a work area 15 to the left of which is a side chamber 16 in which is disposed a lift out pan 24 provided with a lift out bail 26. Pan 24 fills with sludge and may be lifted out for the removal of such sludge.
In addition, there is provided an agitation means comprising agitators 48. Also, there is provided a pump 50 having its inlet 52 located within the work area 15 and its outlet 51 in the side chamber 16 where the sludge may be settled.
Between the work area 15 and the side chamber 16 is a barrier wall 55 having an overflow opening 56 which enables free movement of the liquid to the work area from the side chamber, with the level maintained equal in both the work area 15 and the side chamber 16 by means of the overflow opening 56.
The agitation means 48 constantly agitates the bath for the purposes of continuously and smoothly directing sludge out of the work area into the side chamber.
It will be observed that agitation of the salt bath as here disclosed insures rapid movement of the salt over the heating means, to heat the salt more rapidly, to accelerate heat transfer from the heating means to prolong their life, to insure more nearly uniform heating of the salt, and to prevent formation of deposits on the heating means.
Now having described the embodiments heretofore disclosed, reference should be had to the claims which follow.
We claim:
1. A molten salt bath apparatus for cleaning metals of surface impurities comprising a pot having a work zone and having to one side of said work zone a settling basin, with said work zone and settling basin being relatively separated and barriered, heater tubes in said work zone and settling basin, means in the work zone for agitating said bath and for pumping said bath from said work zone to said basin, and an overflow means for permitting overflow from said basin to flow over it back to said work zone, and mechanical means for removing from said basin impurities settled therein as a sludge.
2. A molten salt bath apparatus for cleaning metals of surface impurities comprising a pot having a work zone and having to one side of said work zone a. settling basin, with said work Zone and settling basin being relatively separated and barriered, heater tubes in said work zone and settling basin, means in the work zone for agitating said bath and for pumping said bath from said work zone to said basin, and an overflow means for permitting overflow from said basin to flow over it back to said work zone, and mechanical means for removing from said basin impurities settled therein as a sludge, said first means comprising an agitator in said bath.
3. A molten salt bath apparatus for cleaning metals of surface impurities comprising a pot having a Work zone and having to one side of said work zone a settling basin, with, said ,Work zone and settling basin being relatively separated and barriered, heater tubes in said work zone and settling basin, means in the Work zone for agitating said bath and for pumping said bath from said Work zone to said basin, and an overflow means for permitting overflow from said basin to flow over it back to said Work zone, and mechanical means for removing from said basin impurities settled therein as a sludge, said first means including a pump Whose inlet is. in the work zone and Whose outlet is in the basin and operating for pumping faster than the impurities settle as a-sludge in the work zone.
References Cited in the file of this patent UNITED STATES PATENTS
US480862A 1955-01-10 1955-01-10 Apparatus for metal cleaning by molten salt baths Expired - Lifetime US2863465A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2967530A (en) * 1957-07-05 1961-01-10 Kolene Corp Apparatus and method for cleaning metal work pieces
US3033712A (en) * 1959-03-10 1962-05-08 Elmer L Brevik Equipment and process for agitated tank cleaning
US3850184A (en) * 1972-05-03 1974-11-26 Service Tectonics Inc Parts treating apparatus
US4078942A (en) * 1977-01-21 1978-03-14 Allegheny Ludlum Industries, Inc. Method and apparatus for cleaning strip in a molten salt bath
US4093472A (en) * 1977-02-17 1978-06-06 Allegheny Ludlum Industries, Inc. Apparatus for cleaning strip
US4534655A (en) * 1984-09-24 1985-08-13 Komax Systems, Inc. Proportioning device
US20070023343A1 (en) * 2005-07-29 2007-02-01 Terry Shoemaker Systems and methods for mixing paint

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1508015A (en) * 1922-10-16 1924-09-09 Gen Chemical Corp Process of diluting acids
US1899657A (en) * 1927-10-01 1933-02-28 Metalwash Machinery Co Washing machinery
US2155854A (en) * 1937-05-26 1939-04-25 American Rolling Mill Co Pickling process
US2244301A (en) * 1938-11-28 1941-06-03 Gore John T P Le Device for washing dishes and the like
US2295912A (en) * 1940-06-03 1942-09-15 Teletype Corp Dehydrating and treating apparatus
US2410380A (en) * 1944-12-21 1946-10-29 Liquid Carbonic Canadian Corp Label scraping attachment for bottle washing machines
US2477948A (en) * 1946-10-12 1949-08-02 Dorr Co Sand scrubber
US2552852A (en) * 1945-10-16 1951-05-15 Westinghouse Electric Corp Dishwashing apparatus having detergent dispensing means
US2604386A (en) * 1950-12-19 1952-07-22 Clayton Manufacturing Co Detergent dissolving apparatus
US2628627A (en) * 1947-08-09 1953-02-17 Ernest L Huff Apparatus for treating continuous products

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1508015A (en) * 1922-10-16 1924-09-09 Gen Chemical Corp Process of diluting acids
US1899657A (en) * 1927-10-01 1933-02-28 Metalwash Machinery Co Washing machinery
US2155854A (en) * 1937-05-26 1939-04-25 American Rolling Mill Co Pickling process
US2244301A (en) * 1938-11-28 1941-06-03 Gore John T P Le Device for washing dishes and the like
US2295912A (en) * 1940-06-03 1942-09-15 Teletype Corp Dehydrating and treating apparatus
US2410380A (en) * 1944-12-21 1946-10-29 Liquid Carbonic Canadian Corp Label scraping attachment for bottle washing machines
US2552852A (en) * 1945-10-16 1951-05-15 Westinghouse Electric Corp Dishwashing apparatus having detergent dispensing means
US2477948A (en) * 1946-10-12 1949-08-02 Dorr Co Sand scrubber
US2628627A (en) * 1947-08-09 1953-02-17 Ernest L Huff Apparatus for treating continuous products
US2604386A (en) * 1950-12-19 1952-07-22 Clayton Manufacturing Co Detergent dissolving apparatus

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2967530A (en) * 1957-07-05 1961-01-10 Kolene Corp Apparatus and method for cleaning metal work pieces
US3033712A (en) * 1959-03-10 1962-05-08 Elmer L Brevik Equipment and process for agitated tank cleaning
US3850184A (en) * 1972-05-03 1974-11-26 Service Tectonics Inc Parts treating apparatus
US4078942A (en) * 1977-01-21 1978-03-14 Allegheny Ludlum Industries, Inc. Method and apparatus for cleaning strip in a molten salt bath
US4093472A (en) * 1977-02-17 1978-06-06 Allegheny Ludlum Industries, Inc. Apparatus for cleaning strip
US4534655A (en) * 1984-09-24 1985-08-13 Komax Systems, Inc. Proportioning device
US20070023343A1 (en) * 2005-07-29 2007-02-01 Terry Shoemaker Systems and methods for mixing paint
US7628529B2 (en) * 2005-07-29 2009-12-08 Toyota Motor Engineering & Manufacturing North America, Inc. Systems and methods for mixing paint

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