US2753260A - High silicon-carbon tool steel - Google Patents
High silicon-carbon tool steel Download PDFInfo
- Publication number
- US2753260A US2753260A US326345A US32634552A US2753260A US 2753260 A US2753260 A US 2753260A US 326345 A US326345 A US 326345A US 32634552 A US32634552 A US 32634552A US 2753260 A US2753260 A US 2753260A
- Authority
- US
- United States
- Prior art keywords
- steel
- silicon
- steels
- hardening
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 title description 3
- 229910001315 Tool steel Inorganic materials 0.000 title description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 14
- 239000010703 silicon Substances 0.000 claims description 14
- 229910052804 chromium Inorganic materials 0.000 claims description 12
- 239000011651 chromium Substances 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 10
- 238000005496 tempering Methods 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 description 41
- 239000010959 steel Substances 0.000 description 41
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229910000734 martensite Inorganic materials 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 229910000851 Alloy steel Inorganic materials 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910001143 Oil hardening tool steel Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001208 Crucible steel Inorganic materials 0.000 description 1
- 241001124569 Lycaenidae Species 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000014987 copper Nutrition 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
Definitions
- This invention pertains to a steel eminently adapted for use in tools employed for the forming of hot metal, such as die blocks, punches and the like, the steel being characterized in being relatively shallow. hardening on quenching, and being hardenable to Rockwell C 60 or higher and in maintaining such high hardness after tempering for about two hours at 700 F., the steel containing as essential alloying constituents carbon, manganese, silicon and chromium in the proportions set forth hereinafter.
- the invention also pertains to tools for forming hot metal made of this steel.
- hot forming operations there are many hot forming operations in which the die, punch, mandrel, and the like, get quite hot, say over about 900 B, because of fairly long and intimate contact of the forming tool with the hot metal being formed.
- high alloy steels generally classified as hot work steels, which have appreciable resistance to softening at temperatures from about 900 to 1100 F.
- Prominent among these hot work steels are: 0.30/.40% C, 5% Cr steels with some V, Mo, and W; and 0.30% C, 9 W, 3% Cr steel with some V and Mo.
- Tools made from these steels must of necessity be tempered about 900 F. and consequently they are below Rockwell C 60 in hardness, and generally no higher than Rockwell C 50.
- the steel be shallow hardening, so that in sections about 1% thick or larger, the steel when water quenched hardens to martensite only at the surface and to some distance below the surface, the core being of appreciably lower hardness.
- This provides the die with a good combination of wear resistance and toughness.
- shallow hardened dies used for cold forming of metals but as yet no steel has been available for shallow hardened dies for hot forming because the known steels which are shallow hardening have little resistance to softening at temperatures beyond about 500 F., and the steels which have good resistance to softening are all very deep hardening steels.
- composition of the steel of this invention is as follows:
- the shallow hardenability of the steel is best established by the conventional Jominy test, and data are given for several steels in Table II. Included in this table for comparison purposes are data on a conventional oil hardening tool steel.
- a hot metal forming tool is meant to include such tools as die blocks, punches and the like.
- An alloy steel consisting essentially of about: 1.6 to 1.9% silicon, 0.9 to 1.2% chromium, 1 to 1.1% carbon, 0.25 to 0.5% manganese, under 0.3% of other elements, balance iron, characterized in being relatively shallow hardening and in being hardenable to a minimum of about Rockwell C 60, and in maintaining such hardness after tempering for about two hours at 700 F.
- a hot metal forming tool made of an alloy steel containing about: 1.6 to 1.9% silicon, 0.9 to' 1.2% chromium, l to 1.1% carbon, 0.25 to 0.5 manganese, under 0.3% of other elements, balance iron, said steel being characterized in being relatively shallow hardening and in being hardenable to a minimum of about Rockwell C 60, and in maintaining such hardness after tempering for about two hours at 700 F.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mounting, Exchange, And Manufacturing Of Dies (AREA)
- Forging (AREA)
Description
United States Patent HIGH SILICON-CARBON TOOL STEEL Peter Payson, New York, N. Y., assignor to Crucible Steel Company of America, New York, N. Y., a corporation of New Jersey No Drawing. Application December 16, 1952,
Serial No. 326,345
2 Claims. (Cl. 75-126) This invention pertains to a steel eminently adapted for use in tools employed for the forming of hot metal, such as die blocks, punches and the like, the steel being characterized in being relatively shallow. hardening on quenching, and being hardenable to Rockwell C 60 or higher and in maintaining such high hardness after tempering for about two hours at 700 F., the steel containing as essential alloying constituents carbon, manganese, silicon and chromium in the proportions set forth hereinafter.
The invention also pertains to tools for forming hot metal made of this steel.
It is the object of this invention to provide a relatively shallow hardening steel for die blocks, punches, and the like, for forming hot metal. It is a further object of this invention to provide a steel which will harden to upward of Rockwell C 60 and which will retain this high hardness when tempered up to at least 700 F.
There are many hot forming operations in which the die, punch, mandrel, and the like, get quite hot, say over about 900 B, because of fairly long and intimate contact of the forming tool with the hot metal being formed. For these operations it is customary to use high alloy steels generally classified as hot work steels, which have appreciable resistance to softening at temperatures from about 900 to 1100 F. Prominent among these hot work steels are: 0.30/.40% C, 5% Cr steels with some V, Mo, and W; and 0.30% C, 9 W, 3% Cr steel with some V and Mo. Tools made from these steels must of necessity be tempered about 900 F. and consequently they are below Rockwell C 60 in hardness, and generally no higher than Rockwell C 50.
There are other operations such as the forging of flat objects, for example, knife blades, compressor blades, turbine buckets, and the like, particularly in the blocking stages, where contact between the hot metal and the die is of relatively short duration and the die surface does not get beyond about 700 F. in temperature. It is for the latter type of service that the steel of this invention is intended.
In order to avoid wear of the hot working tool, it is desirable to heat treat the die to high hardness, say
over about Rockwell C 60. Furthermore, it is preferable in this type of service that the steel be shallow hardening, so that in sections about 1% thick or larger, the steel when water quenched hardens to martensite only at the surface and to some distance below the surface, the core being of appreciably lower hardness. This provides the die with a good combination of wear resistance and toughness. There are many shallow hardened dies used for cold forming of metals but as yet no steel has been available for shallow hardened dies for hot forming because the known steels which are shallow hardening have little resistance to softening at temperatures beyond about 500 F., and the steels which have good resistance to softening are all very deep hardening steels.
Now I have invented a steel in which shallow hardening and high attainable hardness are combined with excellent resistance to softening at temperatures up to at least 700 F. I have discovered that silicon effectively causes resistance to softening in the tempering of martensite as discussed in the publication, The Effect of Silicon on the Tempering of Martensite, by A. G. Allten and P. Payson, American Society for Metals, 1952, preprint No. 10. Therefore, silicon over 1.0%, and preferably over 1.5%, is an important constituent of my steel. In order to develop high hardness: in the steel and partly also to provide residual carbides which are beneficial both for developing shallow hardening and to improve wear resistance of the martensite of the steel, I use upward of 0.90% carbon, and preferably over 1.0% carbon. Since the combination of high carbon and high silicon in the steel is conducive to the formation of graphite in the steel when it is annealed, and since for this application it is desired to avoid such formation, I maintain chromium in the steel at a level over about 0.75%. Manganese is also present in the steel up to about 0.60% for the usual purposes of deoxidation and desulfurization, but higher amounts are undesirable from the viewpoint of low hardenability. Also from the viewpoint of low hardenability, the elements nickel, molybdenum, coppers, etc., should be present in no more than residual amounts.
The composition of the steel of this invention is as follows:
. 0.9/1.2. up to 0.5%.. under 0.3%.
Other elements such as nickel plus molybdenum plus copper, etc. Balance The effect of silicon on the tempering of hardened steels containing about 1.0 carbon and 1.0 chromium is shown in Table I.
TABLE I Effect of silicon on tempering of hardened 1.0 carbon,
1.0 chromium steels It is clear from the above that to maintain a hardness of Rockwell C 60 with a temper over 600 F., it is desirable to hold the level of silicon over 1.0%. I have therefore set the low limit for silicon in the steel of this invention at 1.2%, and preferably 1.6%. Silicon has only a minor efiect on increase of hardenability but it does increase the hardness of the annealed steel appreciably and therefore I limit the silicon to a maximum of 2.5%.
The shallow hardenability of the steel is best established by the conventional Jominy test, and data are given for several steels in Table II. Included in this table for comparison purposes are data on a conventional oil hardening tool steel.
TABLE II Hdrdenability of high carbon-silicon steels Austen- Rockwell C Hardness at Initizing dieated Position on .Tnrniny Bar S1 01' Temper- Bar in lfiths of an inch ature,
4l40 e 0.97 0.53 1.1 1475 65 64 61 49 49 39 4141". 0.97 1.03 1.1 1 475 65 65 64 62 54 44 38 4l42 1.01 1.74 1.1 1,550 66 66 65 63 59 42 4l43 1.00 2.10 1.1 1,550 66 66 65 64 61 45 42 4144". 0.99 2.22 2.2 1 600 67 67 66 66 65 61 46 'Oil Hardening 'Iool Steel 1,475 66 65 64 63 It is clear from the above that the steels of this inventional oil hardening tool steel.
tion are definitely shallower hardening than the conven- Furthermore, these data show that chromium as high as 2% makes the steel much deeper hardening than the 1.0% chromium steels. For this reason, I limit the chromium in the steel of this invention to 1.5%.
In the appended claims, the expression a hot metal forming tool is meant to include such tools as die blocks, punches and the like.
What is claimed is: b
1. An alloy steel consisting essentially of about: 1.6 to 1.9% silicon, 0.9 to 1.2% chromium, 1 to 1.1% carbon, 0.25 to 0.5% manganese, under 0.3% of other elements, balance iron, characterized in being relatively shallow hardening and in being hardenable to a minimum of about Rockwell C 60, and in maintaining such hardness after tempering for about two hours at 700 F.
2. A hot metal forming tool made of an alloy steel containing about: 1.6 to 1.9% silicon, 0.9 to' 1.2% chromium, l to 1.1% carbon, 0.25 to 0.5 manganese, under 0.3% of other elements, balance iron, said steel being characterized in being relatively shallow hardening and in being hardenable to a minimum of about Rockwell C 60, and in maintaining such hardness after tempering for about two hours at 700 F.
References Cited in the file of this patent UNITED STATES PATENTS
Claims (1)
1. AN ALLOY STEEL CONSISTING ESSENTIALLY OF ABOUT: 1.6 TO 1.9% SILICON, 0.9 TO 1.2% CHROMIUM, 1 TO 1.1% CARBON, 0.25 TO 0.5% MANGANESE, UNDER 0.3% OF OTHER ELEMENTS, BALANCE IRON, CHARACTERIZED IN BEING RELATIVELY SHALLOW HARDENING AND IN BEING HARDENABLE TO A MINIMUM OF ABOUT ROCKWELL "C" 60, AND IN MAINTAINING SUCH HARDNESS AFTER TEMPERING FOR ABOUT TWO HOURS AT 700* F.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US326345A US2753260A (en) | 1952-12-16 | 1952-12-16 | High silicon-carbon tool steel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US326345A US2753260A (en) | 1952-12-16 | 1952-12-16 | High silicon-carbon tool steel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2753260A true US2753260A (en) | 1956-07-03 |
Family
ID=23271824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US326345A Expired - Lifetime US2753260A (en) | 1952-12-16 | 1952-12-16 | High silicon-carbon tool steel |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2753260A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3295966A (en) * | 1964-04-30 | 1967-01-03 | Crucible Steel Co America | Versatile low-alloy tool steel |
| US3306734A (en) * | 1963-05-28 | 1967-02-28 | Crucible Steel Co America | Low-alloy bearing steel |
| US3663314A (en) * | 1970-10-14 | 1972-05-16 | Kaizo Monma | Bearing steel composition |
| US4016015A (en) * | 1972-10-31 | 1977-04-05 | Centre De Recherches Metallurgiques-Centrium Voor Research In De Metallurgie | Rolled steel rod or bar |
| EP0337639A1 (en) * | 1988-04-05 | 1989-10-18 | Koyo Seiko Co., Ltd. | A high carbon chromium bearing steel |
| US20020024166A1 (en) * | 2000-06-16 | 2002-02-28 | Hiroshi Fukada | Punch and die |
| EP1158064A4 (en) * | 1999-10-21 | 2004-09-22 | Koyo Seiko Co | Steel for large bearing and parts for large bearing |
| US20070160490A1 (en) * | 2006-01-09 | 2007-07-12 | Ati Properties, Inc. | Tool and bearing steels |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2004331A (en) * | 1932-12-02 | 1935-06-11 | S K F Ind Inc | Alloy steels |
| US2519627A (en) * | 1948-03-20 | 1950-08-22 | Timken Roller Bearing Co | Graphitic steel of controllable hardenability and article made therefrom |
-
1952
- 1952-12-16 US US326345A patent/US2753260A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2004331A (en) * | 1932-12-02 | 1935-06-11 | S K F Ind Inc | Alloy steels |
| US2519627A (en) * | 1948-03-20 | 1950-08-22 | Timken Roller Bearing Co | Graphitic steel of controllable hardenability and article made therefrom |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3306734A (en) * | 1963-05-28 | 1967-02-28 | Crucible Steel Co America | Low-alloy bearing steel |
| US3295966A (en) * | 1964-04-30 | 1967-01-03 | Crucible Steel Co America | Versatile low-alloy tool steel |
| US3663314A (en) * | 1970-10-14 | 1972-05-16 | Kaizo Monma | Bearing steel composition |
| US4016015A (en) * | 1972-10-31 | 1977-04-05 | Centre De Recherches Metallurgiques-Centrium Voor Research In De Metallurgie | Rolled steel rod or bar |
| EP0337639A1 (en) * | 1988-04-05 | 1989-10-18 | Koyo Seiko Co., Ltd. | A high carbon chromium bearing steel |
| EP1158064A4 (en) * | 1999-10-21 | 2004-09-22 | Koyo Seiko Co | Steel for large bearing and parts for large bearing |
| US20020024166A1 (en) * | 2000-06-16 | 2002-02-28 | Hiroshi Fukada | Punch and die |
| EP1164002A3 (en) * | 2000-06-16 | 2003-05-21 | Takeda Chemical Industries, Ltd. | Punch and die |
| US20070160490A1 (en) * | 2006-01-09 | 2007-07-12 | Ati Properties, Inc. | Tool and bearing steels |
| US7387692B2 (en) | 2006-01-09 | 2008-06-17 | Ati Properties, Inc. | Tool and bearing steels |
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