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US2314852A - Heat treatment of magnesium base alloys - Google Patents

Heat treatment of magnesium base alloys Download PDF

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Publication number
US2314852A
US2314852A US414176A US41417641A US2314852A US 2314852 A US2314852 A US 2314852A US 414176 A US414176 A US 414176A US 41417641 A US41417641 A US 41417641A US 2314852 A US2314852 A US 2314852A
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Prior art keywords
heat treatment
magnesium base
base alloys
magnesium
yield point
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Expired - Lifetime
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US414176A
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Brandt Alfred
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ANGLO CALIFORNIA NAT BANK OF S
ANGLO CALIFORNIA NATIONAL BANK OF SAN FRANCISCO
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ANGLO CALIFORNIA NAT BANK OF S
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Priority to US434599A priority Critical patent/US2314853A/en
Priority to US453731A priority patent/US2314854A/en
Application granted granted Critical
Publication of US2314852A publication Critical patent/US2314852A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C23/00Alloys based on magnesium
    • C22C23/02Alloys based on magnesium with aluminium as the next major constituent

Definitions

  • This invention relates to high percentage magnesium base alloys and is particularly concerned with raising the yield point (proof stress) of the alloys by subjecting the same in the as-cast" condition to a single-step heat treatment within a range of not less than 100 C. but less than 250 C., having avoided any previous thermal treatment at higher temperatures.
  • the singlestep thermal treatment at low temperatures leaves the strength of the material substantially unaltered, and the elongation may even decrease to some extent.
  • the yield point is materially increased. Uniformity of results, reduction of wastage, the lessening of fire risks, are also possible-advantages.
  • the singlestep heat treatment between 100 C. and 250 C. is applied to magnesium base alloys containing more than 7% but less than 12% of aluminum,
  • Th top line of each of the various columns in the drawing indicates the yield point (tons per square inch, for 0.1% permanent deformation) of the heat-treated casting, the line in the same column somewhat below it indicating the yield point of the unheat-treated alloy, that is to say, the alloy in the condition resulting from casting, or in other words, the condition known as as cast" condition.
  • the table given below contains the percentages by weight of "the castings subject totolerance for usual impurities together with the heat treatment which they received, namelyz' Heat treatment in days at 0.
  • alloys were made up and cast into tensile test bars in accordance with the specifications of the British Air Ministry Department of Technical Development. 0.1% yield point was determined in the case of each alloy in the "as cast con-, dition, and after heat treatment at C. for 1, 2 and 3 days, after heat treatment at C. for 1, 2 and 3 days and after heat treatment at 240 C. for 1, 2 and 3 days. Duplicate tests were carried out in each case.
  • An alloy consisting principally of magnesium and containing from '7 to 12% of aluminum, at least about 0.2% and less than 4% ofzinc and from 0.1% to 1.0% of manganese,- and the balanc substantially all magnesium, the total amount of alloying constituents not exceeding 12%, in the form of shaped castings the yield point of which has been raised without appreciable increase in strength by heat treatment in the as-cast condition at a temperature within the range of 100 C. to 250 C.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)

Description

March 23, 1943.
A. BRANDT HEAT TRIilAEIIMEll'l QF MAGNESIUM BASE ALLOYS Filed Oct. 8, 1941 BCDEFGH 3mm: W364 m&z
Patented Mar. 23, 1943 HEAT TREATMENT OF MAGNESIUM BASE ALLOYS Alfred Brandt, Swansea, Wales, assignor, by mesne assignments, to The Anglo California National Bank of San Francisco, San Francisco, Calif., a national banking association, as trustee Application october 8, 1941, Serial No. 414,176 In Great Britain September 9, 1940 2 Claims.
This invention relates to high percentage magnesium base alloys and is particularly concerned with raising the yield point (proof stress) of the alloys by subjecting the same in the as-cast" condition to a single-step heat treatment within a range of not less than 100 C. but less than 250 C., having avoided any previous thermal treatment at higher temperatures.
It is an object of the present invention to avoid the so-called solution heat treatment at temperatures far above 250, which constitutes, with subsequent chilling, the first stage of the thermal treatment of magnesium bas alloys which has therefore been the standard practice in treating castings of this type, an annealing treatment at a lower temperature,' below 200 C., being preferably carried out as a second stage. The singlestep thermal treatment at low temperatures leaves the strength of the material substantially unaltered, and the elongation may even decrease to some extent. On the other hand, the yield point is materially increased. Uniformity of results, reduction of wastage, the lessening of fire risks, are also possible-advantages.
According to the present invention, the singlestep heat treatment between 100 C. and 250 C. is applied to magnesium base alloys containing more than 7% but less than 12% of aluminum,
' plus at least about 0.2% and less than 4% zinc,
and also containing from 0.1% to 1.0% of manganese. the total amount of alloying constituents being not'above 12%.
The following examples illustrate various indinates corresponding to yield point in tons per square inch.
Turning now to the figure of the drawing and reading from the left, the efiect of the heat treatment of magnesium base alloy castings A to H inclusive of the hereinafter appearing table is illustrated. Th top line of each of the various columns in the drawing indicates the yield point (tons per square inch, for 0.1% permanent deformation) of the heat-treated casting, the line in the same column somewhat below it indicating the yield point of the unheat-treated alloy, that is to say, the alloy in the condition resulting from casting, or in other words, the condition known as as cast" condition.
The table given below contains the percentages by weight of "the castings subject totolerance for usual impurities together with the heat treatment which they received, namelyz' Heat treatment in days at 0.
3x140 3x140 2x140 3x140 3x175 1x240 1x240 3x175 In preparing the above examples and diagrams, alloys were made up and cast into tensile test bars in accordance with the specifications of the British Air Ministry Department of Technical Development. 0.1% yield point was determined in the case of each alloy in the "as cast con-, dition, and after heat treatment at C. for 1, 2 and 3 days, after heat treatment at C. for 1, 2 and 3 days and after heat treatment at 240 C. for 1, 2 and 3 days. Duplicate tests were carried out in each case.
I claim:
1. A method for improving the yield point of cast magnesium base alloys containing more than 7% but less than 12% of aluminum, at least about 0.2% and less than 4% of zinc and from 0.1% to 1.0%.of manganese, the total amount of alloying constituents being not above 12% the balance being substantially all magnesium, which comprises subjecting such alloys in the as-cast condition to a heat treatment at a temperature within the range of 100 C. to 250 C.
2. An alloy consisting principally of magnesium and containing from '7 to 12% of aluminum, at least about 0.2% and less than 4% ofzinc and from 0.1% to 1.0% of manganese,- and the balanc substantially all magnesium, the total amount of alloying constituents not exceeding 12%, in the form of shaped castings the yield point of which has been raised without appreciable increase in strength by heat treatment in the as-cast condition at a temperature within the range of 100 C. to 250 C.
ALFRED BRANDT.
US414176A 1940-09-09 1941-10-08 Heat treatment of magnesium base alloys Expired - Lifetime US2314852A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US434599A US2314853A (en) 1941-10-08 1942-03-13 Heat treatment of magnesium base alloys
US453731A US2314854A (en) 1941-10-08 1942-08-05 Heat treatment of magnesium base alloys

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GB2314852X 1940-09-09

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989008726A1 (en) * 1988-03-07 1989-09-21 Allied-Signal Inc. Ingot cast magnesium alloys with improved corrosion resistance
US20090068053A1 (en) * 2004-05-19 2009-03-12 Yuequn Ma High strength and high ductility magnesium alloy and its preparation method
WO2010146804A1 (en) * 2009-06-17 2010-12-23 Kabushiki Kaisha Toyota Chuo Kenkyusho Recycled magnesium alloy, process for producing the same, and magnesium alloy

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989008726A1 (en) * 1988-03-07 1989-09-21 Allied-Signal Inc. Ingot cast magnesium alloys with improved corrosion resistance
US20090068053A1 (en) * 2004-05-19 2009-03-12 Yuequn Ma High strength and high ductility magnesium alloy and its preparation method
WO2010146804A1 (en) * 2009-06-17 2010-12-23 Kabushiki Kaisha Toyota Chuo Kenkyusho Recycled magnesium alloy, process for producing the same, and magnesium alloy
CN102803534A (en) * 2009-06-17 2012-11-28 丰田自动车株式会社 Recycled magnesium alloy, process for producing the same, and magnesium alloy
US9169542B2 (en) 2009-06-17 2015-10-27 Kabushiki Kaisha Toyota Chuo Kenkyusho Recycled magnesium alloy, process for producing the same, and magnesium alloy
CN102803534B (en) * 2009-06-17 2015-11-25 丰田自动车株式会社 Recycling magnesium alloy, its manufacture method and magnesium alloy
DE112010002575B4 (en) * 2009-06-17 2018-02-22 Toyota Jidosha Kabushiki Kaisha Recycled magnesium alloy, process for improving the corrosion resistance of a recycled magnesium alloy and magnesium alloy

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