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US2156306A - Austenitic addition material for fusion welding - Google Patents

Austenitic addition material for fusion welding Download PDF

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Publication number
US2156306A
US2156306A US118262A US11826236A US2156306A US 2156306 A US2156306 A US 2156306A US 118262 A US118262 A US 118262A US 11826236 A US11826236 A US 11826236A US 2156306 A US2156306 A US 2156306A
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US
United States
Prior art keywords
austenitic
nickel
manganese
fusion welding
filler material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US118262A
Inventor
Rapatz Franz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gebrueder Boehler and Co AG
Original Assignee
Gebrueder Boehler and Co AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gebrueder Boehler and Co AG filed Critical Gebrueder Boehler and Co AG
Application granted granted Critical
Publication of US2156306A publication Critical patent/US2156306A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent
    • B23K35/3073Fe as the principal constituent with Mn as next major constituent
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9335Product by special process
    • Y10S428/939Molten or fused coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12639Adjacent, identical composition, components
    • Y10T428/12646Group VIII or IB metal-base
    • Y10T428/12653Fe, containing 0.01-1.7% carbon [i.e., steel]

Definitions

  • U base material which may common steel or. highlyalloyed steel with high Patented May 2, 1939 PATENT OFFICE AUSTENITIC Franz Rapatz,
  • This invention relates to austenitic addition material for fusion welding of non-austenitic be either unalloyed or low tensile strength.
  • the invention consists essentially in .the selection, as addition material for austenitic manganese-nickel steels, within certain well defined limits, with or without additions of 'chromium, molybdenum, copper, vanadium, ti-
  • tantium tantalum and zirconium.
  • Austenitic chromium-nickel steels containing. about 20% chromium and. about 20%, or more, nickel, have heretofore been pose. This invention attains the same result by using steels of far lower alloy content.
  • the silicon content definitely influences the crystallinestructure. It has been observed that with increasing silicon content there is a strong tendency towards forming dendritic crystalline structures. A' high silicon content may alsobe maintained in certain cases for other reasons.
  • the invention comprises welding steel, and particularly for uniting contiguous members 'of nonaustenltic steel, which filler material is an austenitic nickel-manganese steel-containing, aside from the iron, 0.01% to 0.5%- carbon, 3% to 25% manganese, to nickel, and 0.01% to 3% silicon. Narrower ranges for these ingredients are 0.05% carbon, 8% to 15% manganese, 8% to 4% fusion welding, of
  • Chromium may be present in an amount up to 6%; and molybdenum may be added in an amount up to 15%, preferably between 1% and 3%.
  • the molybdenum content may be entirely or partly replaced by copper, the copper content not exceeding 5% and being preferably between 2% and 3%.
  • the molybdenum content may also be entirely or partly replaced by vanadium, the vanadium content not exceeding 3% and being preferably'betwee'n 0.4% to 1%, or by up to 3% (preferably 0.5% to 1.5% of one or more of the elements titanium, tantalum, and zirconium.
  • a welded joint comprising at least two contiguous non-austenitic steel members united by weld filler material, said filler material being composed of fully austenitic nickel-manganese steel containing 0.01% to 0.2% carbon, 3% to manganese, 20% to 3% nickel, 0.01% to 3% silicon, and the remainder principally iron.
  • a welded joint comprising at least two'contiguous non-austenitic steel members united by weld filler material, said filler material being composed of fully austenitic nickel-manganese steel containing 0.05% to 0.2% carbon, 8% to 15% manganese, 8% to 4% nickel, 0.2% to 3% silicon, and the remainder principally iron.
  • a welded joint comprising at least two .contiguous non-austenitic steel members united by weld filler material, said filler material being composed of fully austenitic nickel-manganese steel containing 0.05% to 0.2% carbon, 8% to to 4%. nickel, 0.2% to 3% silicon,-chromium in an amount not exceeding 6%, and the remainder iron.
  • a welded joint comprising at least two contiguous non-austenitic steel members united by weld filler material, said filler material being composed of fully austenitic nickel-manganese carbon, 8% to 15% manganese, 8% to 4% 'ckel, 0.2% to 3% silicon, substantial amounts not exceeding 3% of at least one metal of the group-consisting of molybdenum, vanadium, titanium, tantalum,
  • a welded joint comprising at least two contiguous non-austenitic steel members united by weld filler material, said filler material being composed of fully austenitic nickel-manganese steel containing 0.05% to 0.2% carbon, 8% to 15% manganese, 8% to 4% nickel, 0.2% to 3% silicon, chromium in an amount not exceeding 6%, and 0.5% to 1.5% of at least one metal of. the group consisting of molybdenum, vanadium, titanium, tantalum, zirconium, and the remainder substantially all iron.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Arc Welding In General (AREA)

Description

U base material which may common steel or. highlyalloyed steel with high Patented May 2, 1939 PATENT OFFICE AUSTENITIC Franz Rapatz,
assignor to v(lebr. Bi)
ADDITION MATERIAL FOR FUSION WELDING Buderich-Dusseldort, Germany, hler 8; C0. Aktiengesell schaft, Wien, Vienna, Germany No Drawing. Application December 30, 1936, Serial No. 118,262., In Austria January 11, 1936 Claims.
-This invention relates to austenitic addition material for fusion welding of non-austenitic be either unalloyed or low tensile strength.
The invention consists essentially in .the selection, as addition material for austenitic manganese-nickel steels, within certain well defined limits, with or without additions of 'chromium, molybdenum, copper, vanadium, ti-
tantium, tantalum and zirconium.
Austenitic chromium-nickel steels, containing. about 20% chromium and. about 20%, or more, nickel, have heretofore been pose. This invention attains the same result by using steels of far lower alloy content.
To attain this end, a small and limited field in which the required characteristics, 1. e., a tensile strength of 85,340 lbs/sq. in. or more, could be realized, had amongst the many possible 'austenitic steels by diligent research. Anappropriate selection had to be made from amongst the alloying elements nickel, manganese and chromium, to obtain a dendritic crystalline structure and ductility coefficients which do not cause stresses." The choiceof a correct carbon content is of capital importance;
dition, the silicon content definitely influences the crystallinestructure. It has been observed that with increasing silicon content there is a strong tendency towards forming dendritic crystalline structures. A' high silicon content may alsobe maintained in certain cases for other reasons.
The following examples of austenitic alloys were found by experiment .to meet the abovedescribed conditions in the welding of non-aus-' tenitic steels:
O Si Mn Ni Cr Mo Percent Percent Percent Percent Percent Percent 0. 0.08 12. 50 5. 60 3. 80 l. 20 0. l0 0.07 10. 50 6. 00 3. 80 l. 10 0.09 0.09 17.00 11.00 4.00 1.20 Y
0. 10 0.00 12. 00 ll. 00 3. 80 l.
In accordance with the principles disclosed filler material for above, the invention comprises welding steel, and particularly for uniting contiguous members 'of nonaustenltic steel, which filler material is an austenitic nickel-manganese steel-containing, aside from the iron, 0.01% to 0.5%- carbon, 3% to 25% manganese, to nickel, and 0.01% to 3% silicon. Narrower ranges for these ingredients are 0.05% carbon, 8% to 15% manganese, 8% to 4% fusion welding, of
used for this purto bev carefully selected from,
carbon contents between ODS-0.20% have been found to be the most appropriate. In ad- 15% manganese, 8%
steel containing 0.05% to 0.2%
nickel, and 0.01% to 0.2% silicon. Chromium may be present in an amount up to 6%; and molybdenum may be added in an amount up to 15%, preferably between 1% and 3%. The molybdenum content may be entirely or partly replaced by copper, the copper content not exceeding 5% and being preferably between 2% and 3%. The molybdenum content may also be entirely or partly replaced by vanadium, the vanadium content not exceeding 3% and being preferably'betwee'n 0.4% to 1%, or by up to 3% (preferably 0.5% to 1.5% of one or more of the elements titanium, tantalum, and zirconium.
I claim:
.l. A welded joint comprising at least two contiguous non-austenitic steel members united by weld filler material, said filler material being composed of fully austenitic nickel-manganese steel containing 0.01% to 0.2% carbon, 3% to manganese, 20% to 3% nickel, 0.01% to 3% silicon, and the remainder principally iron.
2. A welded joint comprising at least two'contiguous non-austenitic steel members united by weld filler material, said filler material being composed of fully austenitic nickel-manganese steel containing 0.05% to 0.2% carbon, 8% to 15% manganese, 8% to 4% nickel, 0.2% to 3% silicon, and the remainder principally iron.
3. A welded joint comprising at least two .contiguous non-austenitic steel members united by weld filler material, said filler material being composed of fully austenitic nickel-manganese steel containing 0.05% to 0.2% carbon, 8% to to 4%. nickel, 0.2% to 3% silicon,-chromium in an amount not exceeding 6%, and the remainder iron.
4. A welded joint comprising at least two contiguous non-austenitic steel members united by weld filler material, said filler material being composed of fully austenitic nickel-manganese carbon, 8% to 15% manganese, 8% to 4% 'ckel, 0.2% to 3% silicon, substantial amounts not exceeding 3% of at least one metal of the group-consisting of molybdenum, vanadium, titanium, tantalum,
zirconium, and the remainder iron.
5. A welded joint comprising at least two contiguous non-austenitic steel members united by weld filler material, said filler material being composed of fully austenitic nickel-manganese steel containing 0.05% to 0.2% carbon, 8% to 15% manganese, 8% to 4% nickel, 0.2% to 3% silicon, chromium in an amount not exceeding 6%, and 0.5% to 1.5% of at least one metal of. the group consisting of molybdenum, vanadium, titanium, tantalum, zirconium, and the remainder substantially all iron.
, FRANZ RAPATZ.
US118262A 1936-01-11 1936-12-30 Austenitic addition material for fusion welding Expired - Lifetime US2156306A (en)

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Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2456933A (en) * 1943-11-25 1948-12-21 Gen Electric Brazing alloy
US2588700A (en) * 1945-07-26 1952-03-11 Babcock & Wilcox Co Welded joint
US2729881A (en) * 1951-06-20 1956-01-10 Baker & Co Inc Composite metal article of chrome steel and platinum components
US2745771A (en) * 1953-11-06 1956-05-15 Int Nickel Co Metal arc welding of 90-10 type copper-nickel material
US2860230A (en) * 1955-01-04 1958-11-11 Kellogg M W Co Fastening means and method
US2908568A (en) * 1955-06-10 1959-10-13 Gen Am Transport Methods of making nickel phosphorous alloys
US3024137A (en) * 1960-03-17 1962-03-06 Int Nickel Co All-position nickel-chromium alloy welding electrode
US3066215A (en) * 1959-11-18 1962-11-27 Armco Steel Corp Welding method and product
US3139511A (en) * 1961-05-18 1964-06-30 Standard Pressed Steel Co Fusion cladding technique and product
US3223818A (en) * 1961-04-27 1965-12-14 Smith Corp A O Method of welding
WO1981000820A1 (en) * 1979-09-19 1981-04-02 Research Corp Cast iron welding materials
US4534793A (en) * 1979-09-19 1985-08-13 Research Corporation Cast iron welding materials and method
US4726854A (en) * 1979-09-19 1988-02-23 Research Corporation Cast iron welding electrodes
US20120267420A1 (en) * 2011-03-23 2012-10-25 Justin Lee Cheney Fine grained ni-based alloys for resistance to stress corrosion cracking and methods for their design
US9738959B2 (en) 2012-10-11 2017-08-22 Scoperta, Inc. Non-magnetic metal alloy compositions and applications
US9802387B2 (en) 2013-11-26 2017-10-31 Scoperta, Inc. Corrosion resistant hardfacing alloy
US10100388B2 (en) 2011-12-30 2018-10-16 Scoperta, Inc. Coating compositions
US10105796B2 (en) 2015-09-04 2018-10-23 Scoperta, Inc. Chromium free and low-chromium wear resistant alloys
US10173290B2 (en) 2014-06-09 2019-01-08 Scoperta, Inc. Crack resistant hardfacing alloys
US10329647B2 (en) 2014-12-16 2019-06-25 Scoperta, Inc. Tough and wear resistant ferrous alloys containing multiple hardphases
US10345252B2 (en) 2013-10-10 2019-07-09 Scoperta, Inc. Methods of selecting material compositions and designing materials having a target property
US10465267B2 (en) 2014-07-24 2019-11-05 Scoperta, Inc. Hardfacing alloys resistant to hot tearing and cracking
US10465269B2 (en) 2014-07-24 2019-11-05 Scoperta, Inc. Impact resistant hardfacing and alloys and methods for making the same
US10851444B2 (en) 2015-09-08 2020-12-01 Oerlikon Metco (Us) Inc. Non-magnetic, strong carbide forming alloys for powder manufacture
US10954588B2 (en) 2015-11-10 2021-03-23 Oerlikon Metco (Us) Inc. Oxidation controlled twin wire arc spray materials
US11279996B2 (en) 2016-03-22 2022-03-22 Oerlikon Metco (Us) Inc. Fully readable thermal spray coating
US11939646B2 (en) 2018-10-26 2024-03-26 Oerlikon Metco (Us) Inc. Corrosion and wear resistant nickel based alloys
US12076788B2 (en) 2019-05-03 2024-09-03 Oerlikon Metco (Us) Inc. Powder feedstock for wear resistant bulk welding configured to optimize manufacturability

Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2456933A (en) * 1943-11-25 1948-12-21 Gen Electric Brazing alloy
US2588700A (en) * 1945-07-26 1952-03-11 Babcock & Wilcox Co Welded joint
US2729881A (en) * 1951-06-20 1956-01-10 Baker & Co Inc Composite metal article of chrome steel and platinum components
US2745771A (en) * 1953-11-06 1956-05-15 Int Nickel Co Metal arc welding of 90-10 type copper-nickel material
US2860230A (en) * 1955-01-04 1958-11-11 Kellogg M W Co Fastening means and method
US2908568A (en) * 1955-06-10 1959-10-13 Gen Am Transport Methods of making nickel phosphorous alloys
US3066215A (en) * 1959-11-18 1962-11-27 Armco Steel Corp Welding method and product
US3024137A (en) * 1960-03-17 1962-03-06 Int Nickel Co All-position nickel-chromium alloy welding electrode
US3223818A (en) * 1961-04-27 1965-12-14 Smith Corp A O Method of welding
US3139511A (en) * 1961-05-18 1964-06-30 Standard Pressed Steel Co Fusion cladding technique and product
WO1981000820A1 (en) * 1979-09-19 1981-04-02 Research Corp Cast iron welding materials
JPS56501276A (en) * 1979-09-19 1981-09-10
US4534793A (en) * 1979-09-19 1985-08-13 Research Corporation Cast iron welding materials and method
US4726854A (en) * 1979-09-19 1988-02-23 Research Corporation Cast iron welding electrodes
US20120267420A1 (en) * 2011-03-23 2012-10-25 Justin Lee Cheney Fine grained ni-based alloys for resistance to stress corrosion cracking and methods for their design
US8640941B2 (en) * 2011-03-23 2014-02-04 Scoperta, Inc. Fine grained Ni-based alloys for resistance to stress corrosion cracking and methods for their design
US8973806B2 (en) 2011-03-23 2015-03-10 Scoperta, Inc. Fine grained Ni-based alloys for resistance to stress corrosion cracking and methods for their design
US10100388B2 (en) 2011-12-30 2018-10-16 Scoperta, Inc. Coating compositions
US11085102B2 (en) 2011-12-30 2021-08-10 Oerlikon Metco (Us) Inc. Coating compositions
US9738959B2 (en) 2012-10-11 2017-08-22 Scoperta, Inc. Non-magnetic metal alloy compositions and applications
US10345252B2 (en) 2013-10-10 2019-07-09 Scoperta, Inc. Methods of selecting material compositions and designing materials having a target property
US11175250B2 (en) 2013-10-10 2021-11-16 Oerlikon Metco (Us) Inc. Methods of selecting material compositions and designing materials having a target property
US10495590B2 (en) 2013-10-10 2019-12-03 Scoperta, Inc. Methods of selecting material compositions and designing materials having a target property
US9802387B2 (en) 2013-11-26 2017-10-31 Scoperta, Inc. Corrosion resistant hardfacing alloy
US11111912B2 (en) 2014-06-09 2021-09-07 Oerlikon Metco (Us) Inc. Crack resistant hardfacing alloys
US11130205B2 (en) 2014-06-09 2021-09-28 Oerlikon Metco (Us) Inc. Crack resistant hardfacing alloys
US10173290B2 (en) 2014-06-09 2019-01-08 Scoperta, Inc. Crack resistant hardfacing alloys
US10465269B2 (en) 2014-07-24 2019-11-05 Scoperta, Inc. Impact resistant hardfacing and alloys and methods for making the same
US10465267B2 (en) 2014-07-24 2019-11-05 Scoperta, Inc. Hardfacing alloys resistant to hot tearing and cracking
US10329647B2 (en) 2014-12-16 2019-06-25 Scoperta, Inc. Tough and wear resistant ferrous alloys containing multiple hardphases
US11253957B2 (en) 2015-09-04 2022-02-22 Oerlikon Metco (Us) Inc. Chromium free and low-chromium wear resistant alloys
US10105796B2 (en) 2015-09-04 2018-10-23 Scoperta, Inc. Chromium free and low-chromium wear resistant alloys
US10851444B2 (en) 2015-09-08 2020-12-01 Oerlikon Metco (Us) Inc. Non-magnetic, strong carbide forming alloys for powder manufacture
US10954588B2 (en) 2015-11-10 2021-03-23 Oerlikon Metco (Us) Inc. Oxidation controlled twin wire arc spray materials
US11279996B2 (en) 2016-03-22 2022-03-22 Oerlikon Metco (Us) Inc. Fully readable thermal spray coating
US11939646B2 (en) 2018-10-26 2024-03-26 Oerlikon Metco (Us) Inc. Corrosion and wear resistant nickel based alloys
US12076788B2 (en) 2019-05-03 2024-09-03 Oerlikon Metco (Us) Inc. Powder feedstock for wear resistant bulk welding configured to optimize manufacturability

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