US20150123190A1 - Non-volatile memory device integrated with cmos soi fet on a single chip - Google Patents
Non-volatile memory device integrated with cmos soi fet on a single chip Download PDFInfo
- Publication number
- US20150123190A1 US20150123190A1 US14/591,048 US201514591048A US2015123190A1 US 20150123190 A1 US20150123190 A1 US 20150123190A1 US 201514591048 A US201514591048 A US 201514591048A US 2015123190 A1 US2015123190 A1 US 2015123190A1
- Authority
- US
- United States
- Prior art keywords
- layer
- soi
- gate
- substrate
- device region
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000004065 semiconductor Substances 0.000 claims abstract description 61
- 239000000758 substrate Substances 0.000 claims abstract description 60
- 230000000903 blocking effect Effects 0.000 claims abstract description 19
- 239000004020 conductor Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims description 22
- 239000003989 dielectric material Substances 0.000 claims description 13
- 125000006850 spacer group Chemical group 0.000 claims description 10
- 230000005669 field effect Effects 0.000 claims description 7
- 239000012212 insulator Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 abstract description 31
- 238000001020 plasma etching Methods 0.000 description 10
- 239000007943 implant Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000002019 doping agent Substances 0.000 description 7
- 238000005530 etching Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 238000005229 chemical vapour deposition Methods 0.000 description 5
- 150000004767 nitrides Chemical class 0.000 description 5
- 238000000206 photolithography Methods 0.000 description 5
- 229910021332 silicide Inorganic materials 0.000 description 5
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical group [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 229910052814 silicon oxide Inorganic materials 0.000 description 5
- 229910052581 Si3N4 Inorganic materials 0.000 description 4
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 4
- 229910052785 arsenic Inorganic materials 0.000 description 4
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 4
- 238000000231 atomic layer deposition Methods 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 238000005468 ion implantation Methods 0.000 description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910018503 SF6 Inorganic materials 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000059 patterning Methods 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229920002120 photoresistant polymer Polymers 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 230000005641 tunneling Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002194 amorphous carbon material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- OKZIUSOJQLYFSE-UHFFFAOYSA-N difluoroboron Chemical compound F[B]F OKZIUSOJQLYFSE-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- WRQGPGZATPOHHX-UHFFFAOYSA-N ethyl 2-oxohexanoate Chemical compound CCCCC(=O)C(=O)OCC WRQGPGZATPOHHX-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002052 molecular layer Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- SFZCNBIFKDRMGX-UHFFFAOYSA-N sulfur hexafluoride Chemical compound FS(F)(F)(F)(F)F SFZCNBIFKDRMGX-UHFFFAOYSA-N 0.000 description 1
- 229960000909 sulfur hexafluoride Drugs 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1203—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1203—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI
- H01L27/1207—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI combined with devices in contact with the semiconductor body, i.e. bulk/SOI hybrid circuits
-
- H01L27/11521—
-
- H01L27/11526—
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/788—Field effect transistors with field effect produced by an insulated gate with floating gate
- H01L29/7881—Programmable transistors with only two possible levels of programmation
- H01L29/7883—Programmable transistors with only two possible levels of programmation charging by tunnelling of carriers, e.g. Fowler-Nordheim tunnelling
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/30—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/40—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the peripheral circuit region
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/40—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the peripheral circuit region
- H10B41/42—Simultaneous manufacture of periphery and memory cells
Definitions
- the present invention relates generally to semiconductor devices, and more specifically, to SOI CMOS devices fabricated with embedded non-volatile memory devices.
- CMOS complementary metal-oxide semiconductor
- Flash memory is a non-volatile memory that can be electrically erased and reprogrammed multiple times. As flash memory is non-volatile, there is no need to have power to maintain the information stored in the chip. Also, flash memory, when packaged in, for example, a “memory card”, is very durable. For these reasons, flash memory has gained popularity in the use of memory cards and USB flash drives for storage and transfer of data. Flash memory has also become the dominant technology wherever a significant amount of non-volatile, solid state storage is needed. For example, flash memory is used in many common devices such as gaming consoles, digital cameras, laptop computers, digital audio players, and mobile devices.
- each memory cell includes two gates, e.g., a bottom floating gate and a top control gate.
- the floating gate is disposed above a channel and is completely insulated about its periphery by an oxide layer. That is, an insulator layer is provided at the interface between the channel and the floating gate, as well as between the interface of the floating gate and the control gate.
- NVRAM non-volatile random-access memory
- an embodiment of the present invention provides a semiconductor structure.
- the semiconductor structure includes a semiconductor on insulator (SOI) field effect transistor (FET) formed in a predefined SOI device region of an SOI substrate, the SOI FET comprising: a first portion of a buried oxide (BOX) layer, a first portion of an SOI layer, a gate dielectric layer overlying the first portion of the SOI layer, and a gate conductor layer overlying the gate dielectric; and a nonvolatile memory device formed in a predefined nonvolatile semiconductor memory device region of the SOI substrate, the nonvolatile memory device comprising: a tunnel oxide layer overlying a semiconductor substrate, a floating gate layer overlying the tunnel oxide layer, a blocking oxide layer overlying the floating gate layer and a control gate layer overlying the blocking oxide layer, the tunnel oxide layer comprises a second portion of the BOX layer coplanar with the first portion of the BOX layer in the SOI device region and the floating gate layer comprises a second portion of
- FIG. 1 is a vertical cross-sectional view of a semiconductor structure comprising an SOI substrate, according to an embodiment of the present invention.
- FIG. 2 is a vertical cross-sectional view of the semiconductor structure shown in FIG. 1 after STI regions are formed thereby defining three active areas in an active SOI layer, according to an embodiment of the present invention.
- FIG. 3 is a vertical cross-sectional view of the semiconductor structure shown in FIG. 2 , after an optional step of performing a threshold adjust ion implantation for a NVRAM device being formed in a nonvolatile semiconductor memory device region of the SOI substrate, according to an embodiment of the present invention.
- FIG. 4 is a vertical cross-sectional view of the semiconductor structure shown in FIG. 3 after common gate stack layers and a hard mask have been formed on the surface of the SOI substrate, in accordance with an embodiment of the present invention.
- FIG. 5 is a vertical cross-sectional view of the semiconductor structure shown in FIG. 4 after patterning the hard mask layer for subsequent gate stack etching, according to an embodiment of the present invention.
- FIG. 6 is a vertical cross-sectional view of the semiconductor structure shown in FIG. 5 after gate stack formation in an SOI device region and the NVRAM device region, in accordance with an embodiment of the present invention.
- FIG. 7 is a vertical cross-sectional view of the semiconductor structure shown in FIG. 6 after another mask has been formed which exposes portions of the SOI layer and BOX layer in the NVRAM device region and a substrate contact region, according to an embodiment of the present invention.
- FIG. 8 is a vertical cross-sectional view of the semiconductor structure shown in FIG. 7 after removal of the exposed portions of the SOI and BOX layers, in accordance with an embodiment of the present invention.
- FIG. 9 is a vertical cross-sectional view of a resulting structure following the removal of the mask layer, according to an embodiment of the present invention.
- FIG. 10 is a vertical cross-sectional view of the semiconductor structure shown in FIG. 9 after spacers are formed on the sidewalls of the gate stacks, in accordance with an embodiment of the present invention.
- FIG. 11 is a vertical cross-sectional view of the semiconductor structure shown in FIG. 10 after an optional step of performing a halo implant, in accordance with an embodiment of the present invention.
- FIG. 12 is a vertical cross-sectional view of the semiconductor structure shown in FIG. 11 after an embedded contact area is formed in the substrate contact region, according to an embodiment of the present invention.
- FIG. 13 illustrates a resulting integrated structure which includes both SOI CMOS FET and NVRAM devices formed on a single chip, in accordance with an embodiment of the present invention.
- FIG. 13 illustrates a schematic cross-section of one embodiment of a semiconductor structure.
- the structure illustrated in FIG. 13 includes a typical SOI FET device formed in a predefined SOI device region 108 and a nonvolatile semiconductor memory (NVRAM) device formed in a predefined nonvolatile semiconductor memory device region 110 .
- NVRAM nonvolatile semiconductor memory
- the embodiments of the present invention are not limited to a particular type of SOI FET device (i.e., the SOI FET device may be either n-type field effect transistor (NFET) or a p-type field effect transistor (PFET) or combinations of NFETs and PFETs).
- NFET n-type field effect transistor
- PFET p-type field effect transistor
- an embodiment of the present invention utilizes a thin buried insulating layer of the provided SOI substrate as a tunnel oxide layer of NVRAM device.
- the semiconductor structure presented in an embodiment of the invention utilizes a thin semiconductor layer of the SOI substrate as a floating gate of the NVRAM device. Accordingly, the integrated structure of an embodiment of the present invention is an improvement over prior art as it eliminates one or more process steps and thereby reduces the fabrication complexity, cost and thermal cycles.
- FIGS. 1-13 illustrate cross-sections of a substrate during one embodiment of a process for making a semiconductor structure containing CMOS FET devices and NVRAM devices.
- an SOI substrate 101 is provided, which typically includes a semiconductor substrate 102 , a buried insulating layer 104 , such as a buried oxide (BOX) when the insulator is an oxide (e.g., silicon dioxide (SiO 2 )), formed on the substrate 102 , and a semiconductor layer 106 over the BOX layer 104 .
- BOX buried oxide
- the terms “buried insulating layer” and “buried oxide (BOX)” layer are used interchangeably herein.
- the substrate 102 can be a P-substrate, N-substrate or a hybrid-orientation (i.e. having different crystal orientation than the semiconductor layer 106 ) substrate.
- the substrate 102 can comprise any crystalline semiconductor, such as silicon (Si), silicon germanium (SiGe), germanium (Ge), gallium (Ga), arsenic (As) or other semiconductors, including compound semiconductors.
- the buried insulating layer 104 can be an oxide, nitride, oxynitride or other insulation materials. In a preferred embodiment, the buried insulating layer 104 has a thickness in the range from approximately 3 nm to approximately 20 nm, but the invention is not so limited.
- the semiconductor layer will be referred to herein as SOI layer 106 .
- the SOI layer 106 can comprise any crystalline semiconductor, such as silicon (Si), silicon germanium (SiGe), germanium (Ge), gallium (Ga), arsenic (As) or other semiconductors, including compound semiconductors.
- the SOI layer 106 has a thickness in the range from approximately 3 nm to approximately 10 nm, but the invention is not so limited.
- Commercially available SOI substrates often have a thicker SOI layer.
- the SOI layer 106 can be thinned using techniques such as oxidative thinning to achieve the desired SOI layer 106 thickness for the techniques described in an embodiment of the present invention.
- the substrate 102 and SOI layer 106 may be different materials.
- At least one active area is defined in the active (SOI) layer.
- SOI active
- STI shallow trench isolation
- the three active areas may include SOI device region 108 , nonvolatile semiconductor memory device region 110 , and substrate contact region 112 .
- the STI isolation process may begin by first forming a dielectric hardmask (not shown) on portions of the SOI layer 106 that will serve as active areas of the device.
- Portions of the SOI layer 106 , buried insulating layer 104 , and portions of the substrate 102 outside of the active regions which are not protected by the dielectric hardmask may then be removed, for example, using reactive ion etching (RIE) (these portions of the SOI layer 106 , buried insulating layer 104 and substrate 102 that are removed correspond to non-active areas of the device).
- An STI dielectric material may then be blanket deposited onto the structure, e.g., using chemical vapor deposition (CVD), plasma enhanced CVD (PECVD), atomic or molecular layer deposition (ALD or MLD), spin on dielectric (SOD) or some combination of these techniques.
- CVD chemical vapor deposition
- PECVD plasma enhanced CVD
- ALD or MLD atomic or molecular layer deposition
- SOD spin on dielectric
- Suitable STI dielectric materials include, but are not limited to, a silicon nitride liner followed by a silicon oxide fill.
- the deposited STI dielectric material can be planarized using a technique such as chemical-mechanical planarization (CMP) in order to remove the STI dielectric material from the active regions 108 , 110 , and 112 .
- CMP chemical-mechanical planarization
- the STI dielectric material that remains is shown in FIG. 2 as STI regions 202 .
- the dielectric hardmask may then be removed from the active regions using RIE, wet chemical etch, vapor etching or some combination of these techniques to expose the SOI device region 108 , the nonvolatile semiconductor memory device region 110 , and the substrate contact region 112 .
- STI region electrically isolating dielectric region
- FIG. 3 illustrates an optional step of performing a threshold adjust ion implantation for the NVRAM device being formed in the nonvolatile semiconductor memory device region 110 .
- a blocking mask 302 may be formed over SOI device region 108 and over substrate contact region 112 to block the ion implantation from these regions, and only allowing the ion implantation into the semiconductor memory device region 110 .
- This blocking mask 302 can be a photoresist material formed by conventional photolithography techniques.
- a suitable P type dopant such as boron may be implanted into the semiconductor memory region 110 (i.e. NVRAM device) through the opening of mask 302 , at a dose of approximately 1E13 atoms/cm 2 and an energy from approximately 20 to approximately 100 KeV.
- the P type dopant may be driven in for a time duration ranging from approximately 5 seconds to approximately 10 minutes at a temperature ranging from approximately 900° C. to approximately 1100° C. to form the region of P concentration of approximately 1E17 to approximately 1E19 atoms/cm 3 .
- the threshold adjust implant (generally shown by lines 304 ) is made with high energy, it penetrates through the SOI layer 106 , buried insulating layer 104 deep into the substrate 102 , as shown in FIG. 3 . If a PFET NVRAM device is to be formed, a suitable N type dopant such as phosphorus or arsenic can be used.
- additional gate stack layers may be formed on the substrate, using any suitable process, currently known or developed in the future.
- These additional gate stack layers may include a gate conductor layer 404 and gate dielectric 402 .
- thin dielectric layer 402 may be grown or deposited on the SOI layer 106 , followed by forming a layer 404 of conductive material on the thin dielectric layer 402 .
- the gate conductor layer 404 may comprise any suitable gate conductor material, such as polysilicon, metal nitride materials (e.g. TiN), and metals or stacks of different conductor materials, though one layer is shown for illustrative purposes.
- the gate dielectric layer 402 may comprise any suitable gate dielectric material, such as oxide, nitride, high-K materials such as Hf-based dielectrics, and combination of different dielectric layers.
- a second hard mask 406 may be formed over the gate conductor layer 404 by any suitable process to any suitable thickness, as shown in FIG. 4 .
- the hard mask layer 406 in at least one embodiment, includes silicon oxide (SiO 2 ).
- the hard mask layer 406 may include silicon nitride (Si 3 N 4 ), silicon oxynitride (SiON), silicon carbide (SiC), silicon oxycarbide (SiOC), spin-on glass (SOG), a low-k film, tetraethylorthosilicate (TEOS), plasma enhanced CVD oxide (PE-oxide), amorphous carbon material, other suitable materials, and/or combinations thereof.
- the hard mask layer 406 may be formed using methods such as CVD, PVD, or ALD and may have a thickness ranging from approximately 5 to approximately 50 nm.
- the hard mask layer 406 may be patterned, as shown in FIG. 5 .
- the formation and patterning of the hard mask 406 may be performed through any number of known processes.
- a resist layer may be patterned (e.g., photolithography) on the hard mask layer 406 and then the hard mask layer 406 may be etched to create a FET hard mask 502 in the SOI device region 108 and a NVRAM hard mask 504 in the NVRAM device region 110 .
- the FET hard mask 502 and the NVRAM hard mask 504 are made from the hard mask layer 406 .
- the FET hard mask 502 and the NVRAM hard mask 504 may be used for a subsequent gate stack etching step described below.
- FIG. 6 illustrates gate stack formation in the SOI device region 108 and the NVRAM device region 110 .
- an anisotropic (e.g., silicon) RIE may be used to remove portions of gate conductor layer 404 and gate dielectric layer 402 not masked by the FET hard mask 502 and NVRAM hard mask 504 .
- the active SOI layer 106 acts as an etch stop layer.
- the RIE can stop on the gate dielectric layer 402 , and subsequently portions of the gate dielectric layer 402 may be removed by using a short wet-etch of the exposed gate dielectric layer 402 .
- This step completes the gate stack formation for the CMOS FET device in the SOI device region 108 .
- gate stack formation for the adjacent NVRAM device may continue in the NVRAM device region 110 , as described below.
- another mask 702 may be formed over the SOI device region 108 and at least portions of the STI regions 202 , as shown in FIG. 7 .
- the mask layer 702 includes photoresist formed by conventional photolithography.
- the mask 702 exposes portions of the SOI layer 106 (e.g., portion 706 ) and buried insulating layer 104 (e.g. portion 704 ) in the NVRAM device region 110 and substrate contact region 112 .
- mask 702 may leave some portions of STI regions 202 exposed as well.
- a conventional etching technique and chemistry may be employed to remove exposed portions of the SOI layer 106 and buried insulating layer 104 .
- the SOI layer 106 may be etched to the buried insulating layer 104 .
- Etching may be anisotropic, which is commonly accomplished by, for example, RIE using gasses such as sulfur hexafluoride (SF 6 ), hydrogen bromide (HBr) or other gaseous compounds as etchants.
- the buried insulating (BOX) layer 104 may be removed in exposed areas of NVRAM device region 110 and substrate contact region 112 , such as by RIE or in a diluted HF solution to form the structure shown in FIG. 8 .
- FIG. 9 illustrates a resulting structure following the removal of the mask layer 702 .
- first gate stack structure 904 is formed in the SOI device region 108 .
- the first gate stack structure 904 contains the gate dielectric layer 906 located on a portion of the active SOI layer 106 .
- Gate dielectric layer 906 of the first gate stack structure 904 is one of the two remaining portions of the gate dielectric layer 402 described above in connection with FIG. 4 .
- the gate dielectric layer 906 may comprise any suitable gate dielectric material, such as oxide, nitride, high-K materials such as Hf-based dielectrics, and combination of different dielectric layers.
- the gate stack structure 904 includes a gate conductor layer 908 .
- Gate conductor layer 908 of the first gate stack structure 904 is one of the two remaining portions of the gate conductor layer 404 described above in connection with FIG. 4 . Accordingly, the gate conductor layer 908 may comprise any suitable gate conductor material, such as polysilicon, nitride materials (e.g. TiN), and metals or stacks of different conductor or semiconductor materials. As shown in FIG. 9 , the first gate stack 904 is protected by the FET hard mask 502 .
- FIG. 9 further illustrates second gate structure 920 formed in the NVRAM device region 110 .
- the second gate stack (memory gate stack) structure 920 includes the tunnel oxide layer 922 , floating gate layer 924 , blocking oxide layer 926 , and a control gate layer 928 .
- tunnel oxide layer comprises a portion of the original buried insulating layer 104 .
- Tunnel oxide layer 922 is used for charging or discharging of the floating gate electrode (by tunneling electrons).
- the buried insulating layer 104 of the commercial substrate 101 should be of the order of, for example, approximately 4 nm to approximately 15 nm.
- floating gate layer 924 comprises a portion of the original active SOI layer 106 .
- Floating gate layer 924 of the second gate stack structure 920 overlies the tunnel oxide layer 922 .
- Floating gate layer 924 comprises a storage element of a NVRAM device.
- blocking oxide layer 926 comprises another portion of the gate dielectric layer 402 described above in connection with FIG. 4 .
- blocking oxide layer 926 comprises a different dielectric material than gate dielectric layer 402 described in connection with FIG. 4 , that can be achieved by an additional masked etch and dielectric deposition sequence (not shown).
- both blocking oxide layer 926 and gate dielectric layer 402 may comprise a multi-layer dielectric material, which may include two or more dielectric materials having, for example, different dielectric constants.
- Blocking oxide layer 926 of the second gate stack structure 920 overlies the floating gate layer 924 .
- Top layer of the second gate structure 920 is the control gate layer 928 , overlying the blocking oxide layer 926 .
- the control gate layer 928 comprises another portion of the gate conductor layer 404 described above in connection with FIG. 4 .
- the second gate stack structure 920 is protected by a hard mask, the NVRAM hard mask 504 in this case.
- STI regions 202 located in both the NVRAM device region 110 and substrate contact region 112 may have a recess 902 on opposing sidewalls, as illustrated in FIG. 9 .
- the location of this recess 902 is determined by the location of mask 702 shown in FIGS. 7 and 8 , and is created by the etch of the BOX layer portion 704 described above in connection with FIG. 8 .
- spacers 1002 and 1004 may be formed on the sidewalls of the gate stacks 920 and 904 , respectively, using any method now known or developed in the future.
- the spacers 1002 are formed on both sidewalls of the second gate stack structure 920 and on both sidewalls of the NVRAM hard mask 504 in the NVRAM device region 110 .
- the spacers 1004 are formed on both sidewalls of the first gate stack structure 904 and on both sidewalls of the FET hard mask 502 in the SOI device region 108 .
- the sidewall spacers 1002 and 1004 may be made of materials including, but not limited to, silicon nitride and silicon oxide, or combinations of layers and may have a horizontal thickness of approximately 2 nm to approximately 20 nm, preferably approximately 3 nm to approximately 10 nm.
- the sidewall spacers 1002 and 1004 may be formed, for example, by depositing an insulating layer over the first and second gate stacks using known deposition techniques including, for example, chemical vapor deposition (CVD) and atomic layer deposition (ALD) and then removing excess material on the horizontal surfaces using an anisotropic etching process, such as reactive ion etching (RIE) or plasma etching (not shown).
- CVD chemical vapor deposition
- ALD atomic layer deposition
- anisotropic etching process such as reactive ion etching (RIE) or plasma etching (not shown).
- the sidewall spacer formation may be followed by a halo implant, illustrated in FIG. 11 .
- a halo implant illustrated in FIG. 11 .
- FIG. 11 once the spacers 1002 and 1004 are formed another mask 1102 may be formed by photolithography to cover the SOI device region 108 and the substrate contact region 112 .
- the mask 1102 has an opening in the NVRAM region 110 .
- a tilt angle implant 1104 may be possible to form halo/extension regions.
- the implantation may be performed into the opening in the mask 1102 , while it is blocked from SOI device region 108 and substrate contact region 112 .
- the angle of the implant may be equal to approximately 5 to 40 degrees.
- an embedded contact area 1206 may be formed in the substrate contact region 112 .
- yet another mask 1202 may be formed by photolithography to block the introduction of substrate contact dopants implant into other active regions such as SOI device region 108 and NVRAM region 110 .
- the embodiments of the present invention are not limited to a particular type of doping in the substrate.
- the ion implant process represented by arrows 1204 may be performed to implant, for example, P-type dopant materials, e.g., boron, boron di-fluoride (BF 2 ), etc., into the (p-type) substrate 102 .
- the ion implant process 1204 is performed using at a boron dopant dose of approximately 5E15 ions/cm 2 and at an energy level of approximately 5 keV.
- N-type dopant materials such as arsenic, phosphorus, and the like may be implanted into the n-type substrate 102 to form the contact area 1206 . As shown in FIG. 12 , the contact area 1206 is separated from the memory device formed in the NVRAM region 110 by the STI region 202 .
- FIG. 13 illustrates a resulting integrated structure which includes both SOI CMOS FET device formed in the region 108 and NVRAM device formed in the region 110 on a single chip.
- well-known in the art salicide process may be employed to form silicide regions 1304 on top of the gate conductors (after removing NVRAM hard mask 504 and FET hard mask 502 ) and to form silicide regions 1302 on top of the source/drain region in both the NVRAM device region 110 and the SOI device region 108 .
- an interlevel dielectric (ILD) 1306 may be deposited over the substrate.
- ILD interlevel dielectric
- a patterned resist may be deposited (not shown) and trenches may be etched through the ILD 1306 , and a metal, such as tungsten or titanium nitride, may be deposited in the trenches, resulting in contacts 1308 to the silicide regions 1302 in both the NVRAM device region 110 and the SOI device region 108 .
- silicide region 1302 may be formed above the substrate contact area 1206 in the substrate contact region 112 and contact 1308 may be formed in the substrate contact region 112 to provide electrical connection to the contact area 1206 .
- contacts are formed to provide electrical contact to the gate silicide regions 1304 of the SOI FET gate and the NVRAM device control gate (not shown).
- metal wiring using copper or aluminum may be formed to interconnect the SOI FETs and NVRAM devices to form a semiconductor structure.
- a SOI CMOS device is formed in the SOI device region 108 and a NVRAM device is formed in the NVRAM device region 110 .
- the tunnel oxide layer 922 of the NVRAM device is coplanar and made of the same material as a portion of the buried insulating layer (BOX) 104 in the SOI device region 108 . This usage of a portion of the BOX layer for both the BOX 104 and the tunnel oxide 922 advantageously eliminates at least one thermal cycle to form an additional oxide.
- the floating gate layer 924 of the NVRAM device is coplanar and made of the same material as the active SOI layer 106 in the SOI device region 108 .
- the blocking oxide layer 926 of the NVRAM device is coplanar and optionally made of the same material as the gate dielectric layer 906 of the SOI FET, though it is contemplated that the blocking oxide layer 926 can be a different material than gate dielectric layer 906 .
- NVRAM control gate 928 is coplanar and optionally made of the same material as SOI FET gate 908 .
- a substrate contact may be formed in the substrate contact region 112 substantially simultaneously with the NVRAM device formed in the NVRAM device region 110 .
- NVRAM control gate 928 the SOI FET gate 908 , the NVRAM blocking oxide 926 and the SOI FET gate dielectric 906
- RMG Replacement Metal Gate
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Semiconductor Memories (AREA)
- Thin Film Transistor (AREA)
- Non-Volatile Memory (AREA)
Abstract
Description
- The present application is a continuation of, and claims priority under 35 U.S.C. §120, U.S. patent application Ser. No. 13/865,267, filed on Apr. 18, 2013, which is incorporated by reference in its entirety.
- The present invention relates generally to semiconductor devices, and more specifically, to SOI CMOS devices fabricated with embedded non-volatile memory devices.
- SOI (Semiconductor-on-Insulator) CMOS (Complimentary metal-oxide semiconductor) technology can provide high performance devices, such as field effect transistors (FETs).
- Flash memory is a non-volatile memory that can be electrically erased and reprogrammed multiple times. As flash memory is non-volatile, there is no need to have power to maintain the information stored in the chip. Also, flash memory, when packaged in, for example, a “memory card”, is very durable. For these reasons, flash memory has gained popularity in the use of memory cards and USB flash drives for storage and transfer of data. Flash memory has also become the dominant technology wherever a significant amount of non-volatile, solid state storage is needed. For example, flash memory is used in many common devices such as gaming consoles, digital cameras, laptop computers, digital audio players, and mobile devices.
- In traditional stacked flash memory, each memory cell includes two gates, e.g., a bottom floating gate and a top control gate. The floating gate is disposed above a channel and is completely insulated about its periphery by an oxide layer. That is, an insulator layer is provided at the interface between the channel and the floating gate, as well as between the interface of the floating gate and the control gate.
- A single poly non-volatile random-access memory (NVRAM) has been used to provide non-volatile memory functionality integrated with standard CMOS processes, however these single-poly NVRAM techniques typically occupy more chip area. Thus, providing both high performance FETs and NVRAM devices on the same chip while maintaining high NVRAM density is challenging using conventional methods.
- It would be desirable to provide a cost-effective structure and method to integrate both SOI CMOS devices and higher density NVRAM devices on a single chip.
- In one aspect, an embodiment of the present invention provides a semiconductor structure. The semiconductor structure includes a semiconductor on insulator (SOI) field effect transistor (FET) formed in a predefined SOI device region of an SOI substrate, the SOI FET comprising: a first portion of a buried oxide (BOX) layer, a first portion of an SOI layer, a gate dielectric layer overlying the first portion of the SOI layer, and a gate conductor layer overlying the gate dielectric; and a nonvolatile memory device formed in a predefined nonvolatile semiconductor memory device region of the SOI substrate, the nonvolatile memory device comprising: a tunnel oxide layer overlying a semiconductor substrate, a floating gate layer overlying the tunnel oxide layer, a blocking oxide layer overlying the floating gate layer and a control gate layer overlying the blocking oxide layer, the tunnel oxide layer comprises a second portion of the BOX layer coplanar with the first portion of the BOX layer in the SOI device region and the floating gate layer comprises a second portion of the SOI layer coplanar with the first portion of the SOI layer in the SOI device region.
-
FIG. 1 is a vertical cross-sectional view of a semiconductor structure comprising an SOI substrate, according to an embodiment of the present invention. -
FIG. 2 is a vertical cross-sectional view of the semiconductor structure shown inFIG. 1 after STI regions are formed thereby defining three active areas in an active SOI layer, according to an embodiment of the present invention. -
FIG. 3 is a vertical cross-sectional view of the semiconductor structure shown inFIG. 2 , after an optional step of performing a threshold adjust ion implantation for a NVRAM device being formed in a nonvolatile semiconductor memory device region of the SOI substrate, according to an embodiment of the present invention. -
FIG. 4 is a vertical cross-sectional view of the semiconductor structure shown inFIG. 3 after common gate stack layers and a hard mask have been formed on the surface of the SOI substrate, in accordance with an embodiment of the present invention. -
FIG. 5 is a vertical cross-sectional view of the semiconductor structure shown inFIG. 4 after patterning the hard mask layer for subsequent gate stack etching, according to an embodiment of the present invention. -
FIG. 6 is a vertical cross-sectional view of the semiconductor structure shown inFIG. 5 after gate stack formation in an SOI device region and the NVRAM device region, in accordance with an embodiment of the present invention. -
FIG. 7 is a vertical cross-sectional view of the semiconductor structure shown inFIG. 6 after another mask has been formed which exposes portions of the SOI layer and BOX layer in the NVRAM device region and a substrate contact region, according to an embodiment of the present invention. -
FIG. 8 is a vertical cross-sectional view of the semiconductor structure shown inFIG. 7 after removal of the exposed portions of the SOI and BOX layers, in accordance with an embodiment of the present invention. -
FIG. 9 is a vertical cross-sectional view of a resulting structure following the removal of the mask layer, according to an embodiment of the present invention. -
FIG. 10 is a vertical cross-sectional view of the semiconductor structure shown inFIG. 9 after spacers are formed on the sidewalls of the gate stacks, in accordance with an embodiment of the present invention. -
FIG. 11 is a vertical cross-sectional view of the semiconductor structure shown inFIG. 10 after an optional step of performing a halo implant, in accordance with an embodiment of the present invention. -
FIG. 12 is a vertical cross-sectional view of the semiconductor structure shown inFIG. 11 after an embedded contact area is formed in the substrate contact region, according to an embodiment of the present invention. -
FIG. 13 illustrates a resulting integrated structure which includes both SOI CMOS FET and NVRAM devices formed on a single chip, in accordance with an embodiment of the present invention. - Detailed embodiments of the methods and structures of the present invention are described herein; however, it is to be understood that the disclosed embodiments are merely illustrative of the described methods and structures that can be embodied in various forms. In addition, each of the examples given in connection with the various embodiments of the invention is intended to be illustrative, and not restrictive. Further, the Figures are not necessarily to scale, some features can be exaggerated to show details of particular components. Therefore, specific structural and functional details disclosed herein are not to be interpreted as limiting, but merely as a representative basis for teaching one skilled in the art to variously employ the methods and structures of the present invention.
- An embodiment of the present invention relates to a method and structure for integrating SOI CMOS FET devices and NVRAM devices on a single chip.
FIG. 13 illustrates a schematic cross-section of one embodiment of a semiconductor structure. The structure illustrated inFIG. 13 includes a typical SOI FET device formed in a predefinedSOI device region 108 and a nonvolatile semiconductor memory (NVRAM) device formed in a predefined nonvolatile semiconductormemory device region 110. The embodiments of the present invention are not limited to a particular type of SOI FET device (i.e., the SOI FET device may be either n-type field effect transistor (NFET) or a p-type field effect transistor (PFET) or combinations of NFETs and PFETs). Advantageously, an embodiment of the present invention utilizes a thin buried insulating layer of the provided SOI substrate as a tunnel oxide layer of NVRAM device. According to an aspect of the invention, the semiconductor structure presented in an embodiment of the invention utilizes a thin semiconductor layer of the SOI substrate as a floating gate of the NVRAM device. Accordingly, the integrated structure of an embodiment of the present invention is an improvement over prior art as it eliminates one or more process steps and thereby reduces the fabrication complexity, cost and thermal cycles. - The fabrication process begins with a semiconductor-on-insulator (SOI) substrate.
FIGS. 1-13 illustrate cross-sections of a substrate during one embodiment of a process for making a semiconductor structure containing CMOS FET devices and NVRAM devices. Referring toFIG. 1 , anSOI substrate 101 is provided, which typically includes asemiconductor substrate 102, a buriedinsulating layer 104, such as a buried oxide (BOX) when the insulator is an oxide (e.g., silicon dioxide (SiO2)), formed on thesubstrate 102, and asemiconductor layer 106 over theBOX layer 104. The terms “buried insulating layer” and “buried oxide (BOX)” layer are used interchangeably herein. Thesubstrate 102 can be a P-substrate, N-substrate or a hybrid-orientation (i.e. having different crystal orientation than the semiconductor layer 106) substrate. Thesubstrate 102 can comprise any crystalline semiconductor, such as silicon (Si), silicon germanium (SiGe), germanium (Ge), gallium (Ga), arsenic (As) or other semiconductors, including compound semiconductors. The buriedinsulating layer 104 can be an oxide, nitride, oxynitride or other insulation materials. In a preferred embodiment, the buriedinsulating layer 104 has a thickness in the range from approximately 3 nm to approximately 20 nm, but the invention is not so limited. The semiconductor layer will be referred to herein asSOI layer 106. TheSOI layer 106 can comprise any crystalline semiconductor, such as silicon (Si), silicon germanium (SiGe), germanium (Ge), gallium (Ga), arsenic (As) or other semiconductors, including compound semiconductors. Preferably, theSOI layer 106 has a thickness in the range from approximately 3 nm to approximately 10 nm, but the invention is not so limited. Commercially available SOI substrates often have a thicker SOI layer. Thus, theSOI layer 106 can be thinned using techniques such as oxidative thinning to achieve the desiredSOI layer 106 thickness for the techniques described in an embodiment of the present invention. Thesubstrate 102 andSOI layer 106 may be different materials. - Next, at least one active area is defined in the active (SOI) layer. This can be accomplished in a number of different ways, for example, one being by way of shallow trench isolation (STI). Thus, in the exemplary embodiment shown in
FIG. 2 , STI is being used to define three active areas in theactive SOI layer 106 of thesubstrate 101 ofFIG. 1 . The three active areas may includeSOI device region 108, nonvolatile semiconductormemory device region 110, andsubstrate contact region 112. The STI isolation process may begin by first forming a dielectric hardmask (not shown) on portions of theSOI layer 106 that will serve as active areas of the device. Portions of theSOI layer 106, buried insulatinglayer 104, and portions of thesubstrate 102 outside of the active regions which are not protected by the dielectric hardmask may then be removed, for example, using reactive ion etching (RIE) (these portions of theSOI layer 106, buried insulatinglayer 104 andsubstrate 102 that are removed correspond to non-active areas of the device). An STI dielectric material may then be blanket deposited onto the structure, e.g., using chemical vapor deposition (CVD), plasma enhanced CVD (PECVD), atomic or molecular layer deposition (ALD or MLD), spin on dielectric (SOD) or some combination of these techniques. Suitable STI dielectric materials include, but are not limited to, a silicon nitride liner followed by a silicon oxide fill. The deposited STI dielectric material can be planarized using a technique such as chemical-mechanical planarization (CMP) in order to remove the STI dielectric material from theactive regions FIG. 2 asSTI regions 202. The dielectric hardmask may then be removed from the active regions using RIE, wet chemical etch, vapor etching or some combination of these techniques to expose theSOI device region 108, the nonvolatile semiconductormemory device region 110, and thesubstrate contact region 112. Thus, according to this process, the portions of theSOI layer 106, buried insulatinglayer 104, andsubstrate 102 that were removed were replaced with an electrically isolating dielectric region (STI region) 202. As shown inFIG. 2 ,STI regions 202 extend into thesubstrate 102 to a depth sufficient to provide electrical isolation between the SOI and NVRAM devices (subsequently formed as described below). - In SOI technology, the threshold voltage of a device may be of critical importance and may be controlled by several factors including the doping level in the channel of the device.
FIG. 3 illustrates an optional step of performing a threshold adjust ion implantation for the NVRAM device being formed in the nonvolatile semiconductormemory device region 110. As shown inFIG. 3 a blockingmask 302 may be formed overSOI device region 108 and oversubstrate contact region 112 to block the ion implantation from these regions, and only allowing the ion implantation into the semiconductormemory device region 110. This blockingmask 302 can be a photoresist material formed by conventional photolithography techniques. According to one embodiment of the present invention in which an NFET NVRAM device is formed, a suitable P type dopant such as boron may be implanted into the semiconductor memory region 110 (i.e. NVRAM device) through the opening ofmask 302, at a dose of approximately 1E13 atoms/cm2 and an energy from approximately 20 to approximately 100 KeV. The P type dopant may be driven in for a time duration ranging from approximately 5 seconds to approximately 10 minutes at a temperature ranging from approximately 900° C. to approximately 1100° C. to form the region of P concentration of approximately 1E17 to approximately 1E19 atoms/cm3. It should be noted that as the threshold adjust implant (generally shown by lines 304) is made with high energy, it penetrates through theSOI layer 106, buried insulatinglayer 104 deep into thesubstrate 102, as shown inFIG. 3 . If a PFET NVRAM device is to be formed, a suitable N type dopant such as phosphorus or arsenic can be used. - Next, as shown in
FIG. 4 , themask 302 may be removed and additional gate stack layers may be formed on the substrate, using any suitable process, currently known or developed in the future. These additional gate stack layers may include agate conductor layer 404 andgate dielectric 402. For example,thin dielectric layer 402 may be grown or deposited on theSOI layer 106, followed by forming alayer 404 of conductive material on thethin dielectric layer 402. Thegate conductor layer 404 may comprise any suitable gate conductor material, such as polysilicon, metal nitride materials (e.g. TiN), and metals or stacks of different conductor materials, though one layer is shown for illustrative purposes. Thegate dielectric layer 402 may comprise any suitable gate dielectric material, such as oxide, nitride, high-K materials such as Hf-based dielectrics, and combination of different dielectric layers. Next, a secondhard mask 406 may be formed over thegate conductor layer 404 by any suitable process to any suitable thickness, as shown inFIG. 4 . Thehard mask layer 406, in at least one embodiment, includes silicon oxide (SiO2). Thehard mask layer 406, in other embodiments, may include silicon nitride (Si3N4), silicon oxynitride (SiON), silicon carbide (SiC), silicon oxycarbide (SiOC), spin-on glass (SOG), a low-k film, tetraethylorthosilicate (TEOS), plasma enhanced CVD oxide (PE-oxide), amorphous carbon material, other suitable materials, and/or combinations thereof. Thehard mask layer 406 may be formed using methods such as CVD, PVD, or ALD and may have a thickness ranging from approximately 5 to approximately 50 nm. - Next, the
hard mask layer 406 may be patterned, as shown inFIG. 5 . The formation and patterning of thehard mask 406 may be performed through any number of known processes. For example, a resist layer may be patterned (e.g., photolithography) on thehard mask layer 406 and then thehard mask layer 406 may be etched to create a FEThard mask 502 in theSOI device region 108 and a NVRAMhard mask 504 in theNVRAM device region 110. The FEThard mask 502 and the NVRAMhard mask 504 are made from thehard mask layer 406. The FEThard mask 502 and the NVRAMhard mask 504 may be used for a subsequent gate stack etching step described below. -
FIG. 6 illustrates gate stack formation in theSOI device region 108 and theNVRAM device region 110. According to an exemplary embodiment, an anisotropic (e.g., silicon) RIE may be used to remove portions ofgate conductor layer 404 andgate dielectric layer 402 not masked by the FEThard mask 502 and NVRAMhard mask 504. Theactive SOI layer 106 acts as an etch stop layer. According to an alternate embodiment of the invention, the RIE can stop on thegate dielectric layer 402, and subsequently portions of thegate dielectric layer 402 may be removed by using a short wet-etch of the exposedgate dielectric layer 402. This step completes the gate stack formation for the CMOS FET device in theSOI device region 108. However, in accordance with an embodiment of the present invention, gate stack formation for the adjacent NVRAM device may continue in theNVRAM device region 110, as described below. - Next, another
mask 702 may be formed over theSOI device region 108 and at least portions of theSTI regions 202, as shown inFIG. 7 . Themask layer 702, in at least one embodiment, includes photoresist formed by conventional photolithography. Themask 702 exposes portions of the SOI layer 106 (e.g., portion 706) and buried insulating layer 104 (e.g. portion 704) in theNVRAM device region 110 andsubstrate contact region 112. According to an embodiment of the present invention,mask 702 may leave some portions ofSTI regions 202 exposed as well. - Next, referring to
FIG. 8 , a conventional etching technique and chemistry may be employed to remove exposed portions of theSOI layer 106 and buried insulatinglayer 104. During a first etching step, theSOI layer 106 may be etched to the buried insulatinglayer 104. Etching may be anisotropic, which is commonly accomplished by, for example, RIE using gasses such as sulfur hexafluoride (SF6), hydrogen bromide (HBr) or other gaseous compounds as etchants. Next, the buried insulating (BOX)layer 104 may be removed in exposed areas ofNVRAM device region 110 andsubstrate contact region 112, such as by RIE or in a diluted HF solution to form the structure shown inFIG. 8 . -
FIG. 9 illustrates a resulting structure following the removal of themask layer 702. As shown inFIG. 9 , firstgate stack structure 904 is formed in theSOI device region 108. The firstgate stack structure 904 contains thegate dielectric layer 906 located on a portion of theactive SOI layer 106.Gate dielectric layer 906 of the firstgate stack structure 904 is one of the two remaining portions of thegate dielectric layer 402 described above in connection withFIG. 4 . Accordingly, thegate dielectric layer 906 may comprise any suitable gate dielectric material, such as oxide, nitride, high-K materials such as Hf-based dielectrics, and combination of different dielectric layers. Furthermore, thegate stack structure 904 includes agate conductor layer 908.Gate conductor layer 908 of the firstgate stack structure 904 is one of the two remaining portions of thegate conductor layer 404 described above in connection withFIG. 4 . Accordingly, thegate conductor layer 908 may comprise any suitable gate conductor material, such as polysilicon, nitride materials (e.g. TiN), and metals or stacks of different conductor or semiconductor materials. As shown inFIG. 9 , thefirst gate stack 904 is protected by the FEThard mask 502. -
FIG. 9 further illustratessecond gate structure 920 formed in theNVRAM device region 110. As shown inFIG. 9 , the second gate stack (memory gate stack)structure 920 includes thetunnel oxide layer 922, floatinggate layer 924, blockingoxide layer 926, and acontrol gate layer 928. According to an embodiment of the present invention, tunnel oxide layer comprises a portion of the original buried insulatinglayer 104.Tunnel oxide layer 922 is used for charging or discharging of the floating gate electrode (by tunneling electrons). In a preferred embodiment, to obtain a suitable tunneling current, the buried insulatinglayer 104 of thecommercial substrate 101 should be of the order of, for example, approximately 4 nm to approximately 15 nm. In accordance with an embodiment of the present invention, floatinggate layer 924 comprises a portion of the originalactive SOI layer 106. Floatinggate layer 924 of the secondgate stack structure 920 overlies thetunnel oxide layer 922. Floatinggate layer 924 comprises a storage element of a NVRAM device. In addition, in accordance with an embodiment of the present invention, blockingoxide layer 926 comprises another portion of thegate dielectric layer 402 described above in connection withFIG. 4 . In an alternate embodiment, blockingoxide layer 926 comprises a different dielectric material than gatedielectric layer 402 described in connection withFIG. 4 , that can be achieved by an additional masked etch and dielectric deposition sequence (not shown). In yet another embodiment, both blockingoxide layer 926 andgate dielectric layer 402 may comprise a multi-layer dielectric material, which may include two or more dielectric materials having, for example, different dielectric constants.Blocking oxide layer 926 of the secondgate stack structure 920 overlies the floatinggate layer 924. Top layer of thesecond gate structure 920 is thecontrol gate layer 928, overlying the blockingoxide layer 926. According to an embodiment of the present invention, thecontrol gate layer 928 comprises another portion of thegate conductor layer 404 described above in connection withFIG. 4 . Similarly, to the firstgate stack structure 904, the secondgate stack structure 920 is protected by a hard mask, the NVRAMhard mask 504 in this case. At least in one embodiment of the present invention,STI regions 202 located in both theNVRAM device region 110 andsubstrate contact region 112 may have arecess 902 on opposing sidewalls, as illustrated inFIG. 9 . The location of thisrecess 902 is determined by the location ofmask 702 shown inFIGS. 7 and 8 , and is created by the etch of the BOX layer portion 704 described above in connection withFIG. 8 . - Next, referring to
FIG. 10 ,spacers spacers 1002 are formed on both sidewalls of the secondgate stack structure 920 and on both sidewalls of the NVRAMhard mask 504 in theNVRAM device region 110. Similarly, thespacers 1004 are formed on both sidewalls of the firstgate stack structure 904 and on both sidewalls of the FEThard mask 502 in theSOI device region 108. Thesidewall spacers sidewall spacers - Optionally, the sidewall spacer formation may be followed by a halo implant, illustrated in
FIG. 11 . As shown inFIG. 11 , once thespacers mask 1102 may be formed by photolithography to cover theSOI device region 108 and thesubstrate contact region 112. Themask 1102 has an opening in theNVRAM region 110. According, to an embodiment of the invention, atilt angle implant 1104 may be possible to form halo/extension regions. As shown inFIG. 11 , the implantation may be performed into the opening in themask 1102, while it is blocked fromSOI device region 108 andsubstrate contact region 112. In an embodiment of the present invention, the angle of the implant may be equal to approximately 5 to 40 degrees. - Next, referring to
FIG. 12 , an embeddedcontact area 1206 may be formed in thesubstrate contact region 112. As shown inFIG. 12 yet anothermask 1202 may be formed by photolithography to block the introduction of substrate contact dopants implant into other active regions such asSOI device region 108 andNVRAM region 110. The embodiments of the present invention are not limited to a particular type of doping in the substrate. The ion implant process represented byarrows 1204 may be performed to implant, for example, P-type dopant materials, e.g., boron, boron di-fluoride (BF2), etc., into the (p-type)substrate 102. In one illustrative example, theion implant process 1204 is performed using at a boron dopant dose of approximately 5E15 ions/cm2 and at an energy level of approximately 5 keV. In an alternative embodiment, N-type dopant materials, such as arsenic, phosphorus, and the like may be implanted into the n-type substrate 102 to form thecontact area 1206. As shown inFIG. 12 , thecontact area 1206 is separated from the memory device formed in theNVRAM region 110 by theSTI region 202. -
FIG. 13 illustrates a resulting integrated structure which includes both SOI CMOS FET device formed in theregion 108 and NVRAM device formed in theregion 110 on a single chip. It should be noted that well-known in the art salicide process may be employed to formsilicide regions 1304 on top of the gate conductors (after removing NVRAMhard mask 504 and FET hard mask 502) and to formsilicide regions 1302 on top of the source/drain region in both theNVRAM device region 110 and theSOI device region 108. Next, still referring toFIG. 13 , an interlevel dielectric (ILD) 1306 may be deposited over the substrate. Using standard processes, a patterned resist may be deposited (not shown) and trenches may be etched through theILD 1306, and a metal, such as tungsten or titanium nitride, may be deposited in the trenches, resulting incontacts 1308 to thesilicide regions 1302 in both theNVRAM device region 110 and theSOI device region 108. Similarly,silicide region 1302 may be formed above thesubstrate contact area 1206 in thesubstrate contact region 112 andcontact 1308 may be formed in thesubstrate contact region 112 to provide electrical connection to thecontact area 1206. Similarly, contacts are formed to provide electrical contact to thegate silicide regions 1304 of the SOI FET gate and the NVRAM device control gate (not shown). Additionally, using standard processes, metal wiring using copper or aluminum may be formed to interconnect the SOI FETs and NVRAM devices to form a semiconductor structure. - To summarize, in accordance with an embodiment of the present invention shown in
FIG. 13 , a SOI CMOS device is formed in theSOI device region 108 and a NVRAM device is formed in theNVRAM device region 110. In accordance with an embodiment of the present invention, thetunnel oxide layer 922 of the NVRAM device is coplanar and made of the same material as a portion of the buried insulating layer (BOX) 104 in theSOI device region 108. This usage of a portion of the BOX layer for both theBOX 104 and thetunnel oxide 922 advantageously eliminates at least one thermal cycle to form an additional oxide. In accordance with another aspect of the present invention the floatinggate layer 924 of the NVRAM device is coplanar and made of the same material as theactive SOI layer 106 in theSOI device region 108. According to yet another aspect of the present invention, the blockingoxide layer 926 of the NVRAM device is coplanar and optionally made of the same material as thegate dielectric layer 906 of the SOI FET, though it is contemplated that the blockingoxide layer 926 can be a different material than gatedielectric layer 906. According to yet another aspect of the present invention,NVRAM control gate 928 is coplanar and optionally made of the same material asSOI FET gate 908. According to yet another aspect of the present invention, a substrate contact may be formed in thesubstrate contact region 112 substantially simultaneously with the NVRAM device formed in theNVRAM device region 110. - Even though a single NVRAM device and a single SOI FET is shown for illustration purposes, it should be understood that multiple NVRAM devices and multiple SOI FETs can be constructed in NFET and PFET varieties to form semiconductor structures. As another example, while a gate-first integration flow is described in forming the
NVRAM control gate 928, theSOI FET gate 908, theNVRAM blocking oxide 926 and the SOIFET gate dielectric 906, it should be understood that embodiments of the present invention can be equally applied for alternate CMOS gate integration flows, such as the Replacement Metal Gate (RMG) flow. - While the present invention has been particularly shown and described with respect to preferred embodiments thereof, it will be understood by those skilled in the art that the foregoing and other changes in forms and details can be made without departing from the spirit and scope of the present invention. It is therefore intended that the present invention not be limited to the exact forms and details described and illustrated, but fall within the scope of the appended claims.
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/591,048 US20150123190A1 (en) | 2013-04-18 | 2015-01-07 | Non-volatile memory device integrated with cmos soi fet on a single chip |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/865,267 US8963228B2 (en) | 2013-04-18 | 2013-04-18 | Non-volatile memory device integrated with CMOS SOI FET on a single chip |
US14/591,048 US20150123190A1 (en) | 2013-04-18 | 2015-01-07 | Non-volatile memory device integrated with cmos soi fet on a single chip |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/865,267 Continuation US8963228B2 (en) | 2013-04-18 | 2013-04-18 | Non-volatile memory device integrated with CMOS SOI FET on a single chip |
Publications (1)
Publication Number | Publication Date |
---|---|
US20150123190A1 true US20150123190A1 (en) | 2015-05-07 |
Family
ID=51728379
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/865,267 Expired - Fee Related US8963228B2 (en) | 2013-04-18 | 2013-04-18 | Non-volatile memory device integrated with CMOS SOI FET on a single chip |
US14/591,048 Abandoned US20150123190A1 (en) | 2013-04-18 | 2015-01-07 | Non-volatile memory device integrated with cmos soi fet on a single chip |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/865,267 Expired - Fee Related US8963228B2 (en) | 2013-04-18 | 2013-04-18 | Non-volatile memory device integrated with CMOS SOI FET on a single chip |
Country Status (1)
Country | Link |
---|---|
US (2) | US8963228B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10720444B2 (en) | 2018-08-20 | 2020-07-21 | Sandisk Technologies Llc | Three-dimensional flat memory device including a dual dipole blocking dielectric layer and methods of making the same |
US11600628B2 (en) * | 2020-01-15 | 2023-03-07 | Globalfoundries U.S. Inc. | Floating gate memory cell and memory array structure |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20160211250A1 (en) * | 2015-01-15 | 2016-07-21 | Infineon Technologies Ag | Semiconductor substrate arrangement, a semiconductor device, and a method for processing a semiconductor substrate |
US9786755B2 (en) | 2015-03-18 | 2017-10-10 | Stmicroelectronics (Crolles 2) Sas | Process for producing, from an SOI and in particular an FDSOI type substrate, transistors having gate oxides of different thicknesses, and corresponding integrated circuit |
US9685457B2 (en) * | 2015-07-22 | 2017-06-20 | Globalfoundries Inc. | Method including a formation of a transistor and semiconductor structure including a first transistor and a second transistor |
US9634019B1 (en) * | 2015-10-01 | 2017-04-25 | Silicon Storage Technology, Inc. | Non-volatile split gate memory cells with integrated high K metal gate, and method of making same |
US9941300B2 (en) | 2015-12-16 | 2018-04-10 | Globalfoundries Inc. | Structure and method for fully depleted silicon on insulator structure for threshold voltage modification |
US10763270B2 (en) * | 2018-04-27 | 2020-09-01 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method for forming an integrated circuit and an integrated circuit |
JP7163175B2 (en) * | 2018-12-26 | 2022-10-31 | ルネサスエレクトロニクス株式会社 | Semiconductor device manufacturing method |
US11615992B2 (en) | 2020-01-15 | 2023-03-28 | International Business Machines Corporation | Substrate isolated VTFET devices |
KR20230040504A (en) * | 2021-09-16 | 2023-03-23 | 삼성전자주식회사 | Semiconductor device and method for fabricating the same |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100117136A1 (en) * | 2008-11-13 | 2010-05-13 | Naoki Yasuda | Nonvolatile semiconductor memory device and manufacturing method thereof |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6788574B1 (en) | 2001-12-06 | 2004-09-07 | Virage Logic Corporation | Electrically-alterable non-volatile memory cell |
US7169667B2 (en) * | 2003-07-30 | 2007-01-30 | Promos Technologies Inc. | Nonvolatile memory cell with multiple floating gates formed after the select gate |
US7588988B2 (en) * | 2004-08-31 | 2009-09-15 | Micron Technology, Inc. | Method of forming apparatus having oxide films formed using atomic layer deposition |
US20070296034A1 (en) | 2006-06-26 | 2007-12-27 | Hsin-Ming Chen | Silicon-on-insulator (soi) memory device |
JP2008251646A (en) | 2007-03-29 | 2008-10-16 | Seiko Epson Corp | Nonvolatile semiconductor memory device, manufacturing method therefor, and semiconductor device |
JP2009076680A (en) * | 2007-09-20 | 2009-04-09 | Toshiba Corp | Non-volatile semiconductor storage device and its operating method |
US8232599B2 (en) | 2010-01-07 | 2012-07-31 | International Business Machines Corporation | Bulk substrate FET integrated on CMOS SOI |
US8299519B2 (en) | 2010-01-11 | 2012-10-30 | International Business Machines Corporation | Read transistor for single poly non-volatile memory using body contacted SOI device |
EP2381470B1 (en) * | 2010-04-22 | 2012-08-22 | Soitec | Semiconductor device comprising a field-effect transistor in a silicon-on-insulator structure |
EP2495762B1 (en) * | 2011-03-03 | 2017-11-01 | IMEC vzw | Method for producing a floating gate semiconductor memory device |
EP2500933A1 (en) * | 2011-03-11 | 2012-09-19 | S.O.I. TEC Silicon | Multi-layer structures and process for fabricating semiconductor devices |
-
2013
- 2013-04-18 US US13/865,267 patent/US8963228B2/en not_active Expired - Fee Related
-
2015
- 2015-01-07 US US14/591,048 patent/US20150123190A1/en not_active Abandoned
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100117136A1 (en) * | 2008-11-13 | 2010-05-13 | Naoki Yasuda | Nonvolatile semiconductor memory device and manufacturing method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10720444B2 (en) | 2018-08-20 | 2020-07-21 | Sandisk Technologies Llc | Three-dimensional flat memory device including a dual dipole blocking dielectric layer and methods of making the same |
US11631691B2 (en) | 2018-08-20 | 2023-04-18 | Sandisk Technologies Llc | Three-dimensional flat memory device including a dual dipole blocking dielectric layer and methods of making the same |
US11600628B2 (en) * | 2020-01-15 | 2023-03-07 | Globalfoundries U.S. Inc. | Floating gate memory cell and memory array structure |
Also Published As
Publication number | Publication date |
---|---|
US8963228B2 (en) | 2015-02-24 |
US20140312404A1 (en) | 2014-10-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8963228B2 (en) | Non-volatile memory device integrated with CMOS SOI FET on a single chip | |
US11417670B2 (en) | Structure and method for single gate non-volatile memory device | |
US11456383B2 (en) | Semiconductor device having a contact plug with an air gap spacer | |
US9082837B2 (en) | Nonvolatile memory bitcell with inlaid high k metal select gate | |
US7488650B2 (en) | Method of forming trench-gate electrode for FinFET device | |
US9373695B2 (en) | Method for improving selectivity of epi process | |
US9111867B2 (en) | Split gate nanocrystal memory integration | |
US11823949B2 (en) | FinFet with source/drain regions comprising an insulator layer | |
US20130140639A1 (en) | High gate density devices and methods | |
US10319731B2 (en) | Integrated circuit structure having VFET and embedded memory structure and method of forming same | |
CN106373924B (en) | Method for forming semiconductor structure | |
US9613965B2 (en) | Embedded transistor | |
US8969940B1 (en) | Method of gate strapping in split-gate memory cell with inlaid gate | |
US11855162B2 (en) | Contacts for semiconductor devices and methods of forming the same | |
US11901455B2 (en) | Method of manufacturing a FinFET by implanting a dielectric with a dopant | |
US8558313B2 (en) | Bulk substrate FET integrated on CMOS SOI | |
US11152508B2 (en) | Semiconductor device including two-dimensional material layer | |
US7192822B2 (en) | Method of fabricating CMOS type semiconductor device having dual gates | |
US20240332357A1 (en) | Transistor Contacts and Methods of Forming the Same | |
US20240021619A1 (en) | Finfet device and method | |
WO2016168994A1 (en) | Tunnelling transistor and tunnelling transistor manufacturing method | |
US7816203B1 (en) | Method for fabricating a semiconductor device | |
CN115132727A (en) | Semiconductor structure and forming method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: INTERNATIONAL BUSINESS MACHINES CORPORATION, NEW Y Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:CHOU, ANTHONY I.;KUMAR, ARVIND;REEL/FRAME:034650/0627 Effective date: 20130416 |
|
AS | Assignment |
Owner name: GLOBALFOUNDRIES U.S. 2 LLC, NEW YORK Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:INTERNATIONAL BUSINESS MACHINES CORPORATION;REEL/FRAME:036550/0001 Effective date: 20150629 |
|
AS | Assignment |
Owner name: GLOBALFOUNDRIES INC., CAYMAN ISLANDS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:GLOBALFOUNDRIES U.S. 2 LLC;GLOBALFOUNDRIES U.S. INC.;REEL/FRAME:036779/0001 Effective date: 20150910 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |
|
AS | Assignment |
Owner name: GLOBALFOUNDRIES U.S. INC., NEW YORK Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:WILMINGTON TRUST, NATIONAL ASSOCIATION;REEL/FRAME:056987/0001 Effective date: 20201117 |