[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

US20080141603A1 - Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture - Google Patents

Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture Download PDF

Info

Publication number
US20080141603A1
US20080141603A1 US11/639,338 US63933806A US2008141603A1 US 20080141603 A1 US20080141603 A1 US 20080141603A1 US 63933806 A US63933806 A US 63933806A US 2008141603 A1 US2008141603 A1 US 2008141603A1
Authority
US
United States
Prior art keywords
tile
grout
resin
tiles
underlayment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/639,338
Inventor
Raymond S. Harvey
Thomas M. Moy
Timothy A. Tufts
Cynthia E. MacLellan
Amy J. Gran
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Composites IP LLC
Original Assignee
Ashland Licensing and Intellectual Property LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ashland Licensing and Intellectual Property LLC filed Critical Ashland Licensing and Intellectual Property LLC
Priority to US11/639,338 priority Critical patent/US20080141603A1/en
Assigned to ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC reassignment ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: GRAN, AMY J., HARVEY, RAYMOND S., MACLELLAN, CYNTHIA E., MOY, THOMAS M., TUFTS, TIMOTHY A.
Priority to AU2007334096A priority patent/AU2007334096A1/en
Priority to PCT/US2007/086758 priority patent/WO2008076670A2/en
Priority to MX2009006364A priority patent/MX2009006364A/en
Priority to CA002672480A priority patent/CA2672480A1/en
Priority to EP07855016A priority patent/EP2092137A2/en
Priority to CNA2007800461909A priority patent/CN101600840A/en
Priority to JP2009541490A priority patent/JP2010513752A/en
Priority to BRPI0720030-7A priority patent/BRPI0720030A2/en
Priority to TW096147965A priority patent/TW200835834A/en
Publication of US20080141603A1 publication Critical patent/US20080141603A1/en
Assigned to BANK OF AMERICA, N.A. AS ADMINISTRATIVE AGENT reassignment BANK OF AMERICA, N.A. AS ADMINISTRATIVE AGENT SECURITY AGREEMENT Assignors: AQUALON COMPANY, ASHLAND LICENSING AND INTELLECTUAL PROPERTY..., HERCULES INCORPORATED
Priority to CO09073662A priority patent/CO6231059A2/en
Assigned to HERCULES INCORPORATED, AQUALON COMPANY, ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC reassignment HERCULES INCORPORATED RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Abandoned legal-status Critical Current

Links

Images

Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/18Separately-laid insulating layers; Other additional insulating measures; Floating floors
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/14Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/18Separately-laid insulating layers; Other additional insulating measures; Floating floors
    • E04F15/182Underlayers coated with adhesive or mortar to receive the flooring
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/18Separately-laid insulating layers; Other additional insulating measures; Floating floors
    • E04F15/186Underlayers covered with a mesh or the like

Definitions

  • the present disclosure relates to a floating floor tile installation comprising tiles bonded together with polymeric grout on an underlayment.
  • the tile installation provides for a floating floor over an existing floor.
  • the disclosure also relates to a method of manufacturing the tile installation.
  • the tile installation provides for a fast and economical method of manufacturing a floating floor over an existing floor.
  • floor tiles are installed by mortaring tile directly onto a wood or cement floor and then grouting the tile with a cementatious grout.
  • a cementations backer-board is first applied to the floor followed by mortaring the tile to the cementatious backer-board.
  • This conventional process of laying floor tile is time-consuming and labor intensive.
  • conventional tile floors are expensive to install owing to high labor costs.
  • water-based cementatious mortars and grouts can not be used with flooring and tiles that are adversely affected by moisture.
  • flooring made of water swellable materials such as particle board can not be easily used with water-based cements.
  • certain types of colored marble tiles swell when exposed to water and would not be usable with a water-based mortar or grout.
  • the present disclosure relates to a floating floor tile installation and a method of manufacturing the tile installation.
  • the tile installation comprises at least two tiles bonded together with a polymeric grout on an underlayment.
  • the present disclosure also relates to a method of manufacturing the tile installation. The method comprises placing an underlayment over an existing floor and placing at least two tiles separated by a space on the underlayment. Next an uncured polymeric grout is applied in the space between the tiles and the uncured polymeric grout is then stuck to contour and then the polymeric grout is allowed to cure to form the tile installation.
  • the floating floor tile installation is simple, fast and economical compared to conventional tile installations.
  • the tile installation can be walked on within 2 to 6 hours depending upon the polymeric grout used. This is much faster than using conventional techniques which can take days before the tile can be put into service.
  • the tile installation can be manufactured where water-based installation methods are prohibited.
  • the tile installation can be completely waterproof.
  • the polymeric grout of the disclosed tile installation has much higher strength and flexibility than conventional cement grout. This provides for less unwanted cracking by isolating the floating tile floor from subfloors with high load movement.
  • FIG. 1 Physical diagram showing particle board flooring used to simulate existing flooring in the example.
  • FIG. 2 Picture showing particle board covered with 4 mil LDPE flexible water proof plastic sheet as an underlayment. Picture also shows optional pressure sensitive patches used to hold the tiles in place during installation.
  • FIG. 3 Picture showing optional tape used to expedite clean-up after applying the polymeric grout between the tiles.
  • FIG. 4 Paper showing optional decorative particles (sand) applied to uncured polymeric grout.
  • FIG. 5 Paper showing finished glazed porcelain floor tile installation with decorative sand giving the appearance of cemetatious grout.
  • FIG. 6 Paper showing close-up view of decorative sand applied to polymeric grout to give the appearance of cementations grout.
  • FIGS. 7 and 8 Pictures showing the top and bottom finished tile installation standing up illustrating the overall strength of the tile installation.
  • FIGS. 9 and 10 Picture showing 1 in 2 glass tiles with pearlescent decorative particles.
  • FIGS. 11 and 12 Picture showing 3 ⁇ 3 in glazed ceramic tile with color shifting custom paint flake.
  • FIG. 13 Picture showing 6 ⁇ 6 in engineered stone tiles with decorative sand.
  • FIG. 14 Picture showing 6 ⁇ 6 in natural slate tile with decorative sand.
  • FIG. 15 Picture showing 6 ⁇ 6 in natural marble tile with pearlescent decorative particles.
  • the tile installation comprises at least two tiles bonded with a polymeric grout and an underlayment which together form a floating floor.
  • the underlayment can be any material that can be placed between an existing floor and a tile material.
  • the underlayment can be a rigid material, a flexible material or an adhesive material. More typically, the underlayment is a moisture barrier.
  • the tiles may be bonded to the underlayment with an adhesive or an adhesive tape. Any tile material usable for flooring may be utilized in the tile installation.
  • the polymeric grout used to bond the tiles can be any type of curable polymeric material that can be applied between the spaces of the tiles.
  • the polymeric grout has higher strength, as measured by pounds of flex at the yield point using ASTM C-580, than conventional grout.
  • the polymeric grout has from about 1,000 to about 3,000 pounds of flex at the yield point compared to standard grouts which have flexural strengths of about 400 to about 600 pounds of flex at the yield point. More typically, the polymeric grout has from about 1500 to about 2500 pounds of flex and the yield point.
  • the polymeric grout is non-porous, water-proof, mildew resistant and stain resistant.
  • Non-limiting examples of the underlayment include plywood, wood particle board, wood planking, cement, a foam sheet, a fiber glass sheet, plastic sheet, a metal sheet, a composite sheet and an adhesive layer. Smaller sections of underlayment can be utilized and joined together to form a larger section.
  • Typical plastic sheets include polyethylene (PE) sheet, polypropylene (PP) sheet, PE/PP sheet, nylon sheet, polyester sheet, mylar sheet, styrenic sheet, polycarbonate sheet, acrylic sheet, acetal sheet, Delrine® sheet, Lexan® sheet, Lucite® sheet, Micarta® sheet, Perspex® sheet, Plexiglasg sheet, Acrylite® sheet, PET sheets, ABS sheet, PVC sheet, PTFE sheet, HIPS sheet, EVOH sheet, PP/EVOH sheet and Tyvek®.
  • PE polyethylene
  • PP polypropylene
  • PE/PP sheet nylon sheet
  • polyester sheet polyester sheet
  • mylar sheet mylar sheet
  • styrenic sheet polycarbonate sheet
  • acrylic sheet acetal sheet
  • Delrine® sheet Lexan® sheet
  • Lucite® sheet Micarta® sheet
  • Perspex® sheet Plexiglasg sheet
  • Acrylite® sheet PET sheets
  • ABS sheet ABS sheet
  • PVC sheet PTFE sheet
  • Typical composite sheets include a polymeric resin and a fibrous material.
  • the polymeric resin typically includes polyester resin, epoxy resin, urethane resin, polysulfone resin, polyphenylsulfone resin, polyether sulfone resin, polyphalamide resin, polyphenylene sulfide resin, aromatic polyketone resin, polyamide-imide resin, polycarbonate resin, styrenic resin, ABS resin, acrylic resin, PET resin and combinations thereof.
  • the fibrous material utilized in the composite sheets typically includes synthetic fibers such as but not limited to fiber-glass, carbon fiber, polyethylene fiber, polypropylene fiber, nylon fiber, polyester fiber, and polyamide fiber and natural fibers such as but not limited to hemp, cotton fiber, linen fiber, wool fiber, and combinations synthetic and natural fibers thereof.
  • cementatious material/fibrous material composites can be utilized.
  • the cementations materials can be any type of material containing cement in the formulation.
  • the fibrous materials can be any of those listed above for the polymeric resin/fibrous material composites.
  • the underlayment may also include an adhesive material laid down on the existing floor as a layer.
  • the adhesive material typically includes Plioseal®, epoxies and urethanes.
  • the floating floor tile installation contains tiles which typically include ceramic tile ( FIGS. 5 , 6 , 11 and 12 ), porcelain tile, terra cotta tile, marble tile ( FIG. 15 ), concrete tile, slate tile ( FIG. 14 ), granite tile, wood tile, glass tile ( FIGS. 9 and 10 ), metal tile, plastic tile, engineered stone tile ( FIG. 13 ) or combinations thereof.
  • tiles typically include ceramic tile ( FIGS. 5 , 6 , 11 and 12 ), porcelain tile, terra cotta tile, marble tile ( FIG. 15 ), concrete tile, slate tile ( FIG. 14 ), granite tile, wood tile, glass tile ( FIGS. 9 and 10 ), metal tile, plastic tile, engineered stone tile ( FIG. 13 ) or combinations thereof.
  • the polymeric grout used to bond the tiles of the floating floor tile installation is not limited and includes any structural adhesive that provides sufficient strength to the tile installation.
  • the polymeric grout provides strength as measured by pounds of flex at the yield point as measured by ASTM C-580.
  • the polymeric grout provides about 1,000 to about 3,000 pounds of flex at the yield point, and more typically, about 1500 to about 2500 pounds of flex at the yield point.
  • the polymeric grout is typically non-porous, water-proof, mildew resistant and stain resistant.
  • the polymeric grout typically contains a urethane, an epoxy, a polyester, an acrylic and combinations thereof.
  • the tile installation optionally contains decorative particles covering and bonded to the polymeric grout or dispersed into the polymeric grout.
  • the decorative particles can be any type of material that can be used in flooring.
  • the decorative particle is applied to the uncured polymeric grout and is bonded to the grout after the grout is cured.
  • the decorative particles typically include natural materials such as sand, minerals, crushed stone, crushed shell, metal flake, titanium dioxide and natural pigments and synthetic materials such as ceramic and ceramic coated particles, crushed glass, synthetic pigments and cured resin particulates such as polyester flake, and combinations of natural and synthetic materials thereof.
  • the floating floor tile installation is typically manufactured by placing an underlayment over an existing floor then placing at least two tiles separated by a space on the underlayment. Next, a polymeric grout is applied into the space between tiles and the polymeric grout is optionally struck and then allowed to cure producing the tile installation as a floating floor.
  • the tiles may be optionally placed onto the underlayment with a spacer to insure uniform spacing between the tiles.
  • the tiles may be bonded to the underlayment with an adhesive or adhesive tape prior to applying the polymeric grout.
  • Decorative particles may also be applied to the polymeric grout after applying the grout into spaces between the tiles. The particles are applied before the grout completely cures. The particles are then bonded to the polymeric grout after the grout cures.
  • the tiles may be protected with a tape or film prior to applying the polymeric grout into the space between the tiles.
  • the tape or film is then removed before the polymeric grout cures leaving a clean finish.
  • An alternative method to ease clean-up is to protect the tile surface with a release agent prior to applying the polymeric grout. After the polymeric grout has partially cured, excess grout may be peeled from the surface of the tile and the tile cleaned with a suitable solvent to remove the release agent.
  • a floating tile floor installation was manufactured using a plastic sheet moisture barrier as an underlayment and a structural adhesive as a polymeric grout.
  • a plastic sheet moisture barrier as an underlayment and a structural adhesive as a polymeric grout.
  • an approximately 16 FT 2 section of particle board nailed to 2 ⁇ 4′′ studs was constructed ( FIG. 1 ).
  • the particle board was covered with a water proof plastic 4 mil LDPE sheet as a water proof underlayment.
  • PLIOSEAL 3′′ rubber splice tape pressure sensitive patches were then applied to the plastic sheet to hold the tiles in place ( FIG. 2 ).
  • the tiles Prior to placement on the underlayment, the tiles were taped with protective, removable tape to aid in clean up after the polymeric grout is applied.
  • a 2-component urethane adhesive (polymeric grout) was mixed and applied between the tiles using a disposable plastic grout bag.
  • Alternative methods of application include dispensing the polymeric grout from a cartridge using a dispensing gun or floating the polymeric grout into the space between the tiles as with cementatious grout and cleaning the tile surface with an appropriate solvent. (This method was used to produce the tile installations in FIGS. 9 , 10 , 11 and 12 .)
  • the 2-component urethane polymeric grout was formulated as shown in Table 1.
  • the polymeric grout was then struck and a decorative sand (zircon sand, lake sand or silica sand) was applied to the uncured polymeric grout ( FIG. 4 ). Before the polymeric grout completely cured, the tape was removed. After 4 hours, the polymeric grout cured sufficiently to remove excess decorative sand and the tile could then be walked on ( FIG. 5 ). The decorative sand gives the appearance of cementious grout ( FIG. 6 ). The finished tile installation is strong enough to support itself in a vertical position ( FIGS. 7 and 8 ). With the high strength of the finished tile system, preformed tile sections can be prepared and installed as if they were individual tiles using the method described.
  • a decorative sand zircon sand, lake sand or silica sand

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Floor Finish (AREA)
  • Road Paving Structures (AREA)

Abstract

A floating floor tile installation and method of manufacturing the tile installation are provided. The floating floor tile installation contains tiles bonded together with a polymeric grout on an underlayment. The tile installation provides for a fast and economic method of installing a floating tile floor over an existing floor.

Description

    TECHNICAL FIELD
  • The present disclosure relates to a floating floor tile installation comprising tiles bonded together with polymeric grout on an underlayment. The tile installation provides for a floating floor over an existing floor. The disclosure also relates to a method of manufacturing the tile installation. The tile installation provides for a fast and economical method of manufacturing a floating floor over an existing floor.
  • BACKGROUND
  • Conventionally, floor tiles are installed by mortaring tile directly onto a wood or cement floor and then grouting the tile with a cementatious grout. In many applications, a cementations backer-board is first applied to the floor followed by mortaring the tile to the cementatious backer-board. This conventional process of laying floor tile is time-consuming and labor intensive. As a result, conventional tile floors are expensive to install owing to high labor costs. In addition, water-based cementatious mortars and grouts can not be used with flooring and tiles that are adversely affected by moisture. For example, flooring made of water swellable materials such as particle board can not be easily used with water-based cements. In addition, certain types of colored marble tiles swell when exposed to water and would not be usable with a water-based mortar or grout.
  • SUMMARY
  • The present disclosure relates to a floating floor tile installation and a method of manufacturing the tile installation. The tile installation comprises at least two tiles bonded together with a polymeric grout on an underlayment. The present disclosure also relates to a method of manufacturing the tile installation. The method comprises placing an underlayment over an existing floor and placing at least two tiles separated by a space on the underlayment. Next an uncured polymeric grout is applied in the space between the tiles and the uncured polymeric grout is then stuck to contour and then the polymeric grout is allowed to cure to form the tile installation.
  • The floating floor tile installation is simple, fast and economical compared to conventional tile installations. For example, the tile installation can be walked on within 2 to 6 hours depending upon the polymeric grout used. This is much faster than using conventional techniques which can take days before the tile can be put into service. The tile installation can be manufactured where water-based installation methods are prohibited. In addition, the tile installation can be completely waterproof. The polymeric grout of the disclosed tile installation has much higher strength and flexibility than conventional cement grout. This provides for less unwanted cracking by isolating the floating tile floor from subfloors with high load movement.
  • Other modes and various advantages of the present disclosure will become readily apparent by those skilled in the art from the following detailed description, where it is shown and described only in the preferred embodiments, simply by way of illustration of the best mode. As will be realized, the disclosure is capable of other and different embodiments and its several details are capable of modifications in various obvious respects, without departing from the disclosure. Accordingly, the description is to be regarded as illustrative in nature and not as restrictive in scope.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1—Picture showing particle board flooring used to simulate existing flooring in the example.
  • FIG. 2—Picture showing particle board covered with 4 mil LDPE flexible water proof plastic sheet as an underlayment. Picture also shows optional pressure sensitive patches used to hold the tiles in place during installation.
  • FIG. 3—Picture showing optional tape used to expedite clean-up after applying the polymeric grout between the tiles.
  • FIG. 4—Picture showing optional decorative particles (sand) applied to uncured polymeric grout.
  • FIG. 5—Picture showing finished glazed porcelain floor tile installation with decorative sand giving the appearance of cemetatious grout.
  • FIG. 6—Picture showing close-up view of decorative sand applied to polymeric grout to give the appearance of cementations grout.
  • FIGS. 7 and 8—Pictures showing the top and bottom finished tile installation standing up illustrating the overall strength of the tile installation.
  • FIGS. 9 and 10—Picture showing 1 in2 glass tiles with pearlescent decorative particles.
  • FIGS. 11 and 12—Picture showing 3×3 in glazed ceramic tile with color shifting custom paint flake.
  • FIG. 13—Picture showing 6×6 in engineered stone tiles with decorative sand.
  • FIG. 14—Picture showing 6×6 in natural slate tile with decorative sand.
  • FIG. 15—Picture showing 6×6 in natural marble tile with pearlescent decorative particles.
  • DETAILED DESCRIPTION AND VARIOUS MODES
  • The tile installation comprises at least two tiles bonded with a polymeric grout and an underlayment which together form a floating floor. The underlayment can be any material that can be placed between an existing floor and a tile material. Typically, the underlayment can be a rigid material, a flexible material or an adhesive material. More typically, the underlayment is a moisture barrier. Optionally, the tiles may be bonded to the underlayment with an adhesive or an adhesive tape. Any tile material usable for flooring may be utilized in the tile installation.
  • The polymeric grout used to bond the tiles can be any type of curable polymeric material that can be applied between the spaces of the tiles. Typically, the polymeric grout has higher strength, as measured by pounds of flex at the yield point using ASTM C-580, than conventional grout. For example, the polymeric grout has from about 1,000 to about 3,000 pounds of flex at the yield point compared to standard grouts which have flexural strengths of about 400 to about 600 pounds of flex at the yield point. More typically, the polymeric grout has from about 1500 to about 2500 pounds of flex and the yield point. Typically, the polymeric grout is non-porous, water-proof, mildew resistant and stain resistant.
  • Non-limiting examples of the underlayment include plywood, wood particle board, wood planking, cement, a foam sheet, a fiber glass sheet, plastic sheet, a metal sheet, a composite sheet and an adhesive layer. Smaller sections of underlayment can be utilized and joined together to form a larger section.
  • Typical plastic sheets include polyethylene (PE) sheet, polypropylene (PP) sheet, PE/PP sheet, nylon sheet, polyester sheet, mylar sheet, styrenic sheet, polycarbonate sheet, acrylic sheet, acetal sheet, Delrine® sheet, Lexan® sheet, Lucite® sheet, Micarta® sheet, Perspex® sheet, Plexiglasg sheet, Acrylite® sheet, PET sheets, ABS sheet, PVC sheet, PTFE sheet, HIPS sheet, EVOH sheet, PP/EVOH sheet and Tyvek®.
  • Typical composite sheets include a polymeric resin and a fibrous material. The polymeric resin typically includes polyester resin, epoxy resin, urethane resin, polysulfone resin, polyphenylsulfone resin, polyether sulfone resin, polyphalamide resin, polyphenylene sulfide resin, aromatic polyketone resin, polyamide-imide resin, polycarbonate resin, styrenic resin, ABS resin, acrylic resin, PET resin and combinations thereof.
  • The fibrous material utilized in the composite sheets typically includes synthetic fibers such as but not limited to fiber-glass, carbon fiber, polyethylene fiber, polypropylene fiber, nylon fiber, polyester fiber, and polyamide fiber and natural fibers such as but not limited to hemp, cotton fiber, linen fiber, wool fiber, and combinations synthetic and natural fibers thereof.
  • In addition to polymeric resin/fibrous material composites, cementatious material/fibrous material composites can be utilized. The cementations materials can be any type of material containing cement in the formulation. The fibrous materials can be any of those listed above for the polymeric resin/fibrous material composites.
  • The underlayment may also include an adhesive material laid down on the existing floor as a layer. The adhesive material typically includes Plioseal®, epoxies and urethanes.
  • The floating floor tile installation contains tiles which typically include ceramic tile (FIGS. 5, 6, 11 and 12), porcelain tile, terra cotta tile, marble tile (FIG. 15), concrete tile, slate tile (FIG. 14), granite tile, wood tile, glass tile (FIGS. 9 and 10), metal tile, plastic tile, engineered stone tile (FIG. 13) or combinations thereof.
  • The polymeric grout used to bond the tiles of the floating floor tile installation is not limited and includes any structural adhesive that provides sufficient strength to the tile installation. Typically, the polymeric grout provides strength as measured by pounds of flex at the yield point as measured by ASTM C-580. Typically, the polymeric grout provides about 1,000 to about 3,000 pounds of flex at the yield point, and more typically, about 1500 to about 2500 pounds of flex at the yield point. The polymeric grout is typically non-porous, water-proof, mildew resistant and stain resistant.
  • The polymeric grout typically contains a urethane, an epoxy, a polyester, an acrylic and combinations thereof.
  • The tile installation optionally contains decorative particles covering and bonded to the polymeric grout or dispersed into the polymeric grout. The decorative particles can be any type of material that can be used in flooring. The decorative particle is applied to the uncured polymeric grout and is bonded to the grout after the grout is cured. The decorative particles typically include natural materials such as sand, minerals, crushed stone, crushed shell, metal flake, titanium dioxide and natural pigments and synthetic materials such as ceramic and ceramic coated particles, crushed glass, synthetic pigments and cured resin particulates such as polyester flake, and combinations of natural and synthetic materials thereof.
  • The floating floor tile installation is typically manufactured by placing an underlayment over an existing floor then placing at least two tiles separated by a space on the underlayment. Next, a polymeric grout is applied into the space between tiles and the polymeric grout is optionally struck and then allowed to cure producing the tile installation as a floating floor. The tiles may be optionally placed onto the underlayment with a spacer to insure uniform spacing between the tiles. In addition, the tiles may be bonded to the underlayment with an adhesive or adhesive tape prior to applying the polymeric grout. Decorative particles may also be applied to the polymeric grout after applying the grout into spaces between the tiles. The particles are applied before the grout completely cures. The particles are then bonded to the polymeric grout after the grout cures. In order to expedite clean-up, the tiles may be protected with a tape or film prior to applying the polymeric grout into the space between the tiles. The tape or film is then removed before the polymeric grout cures leaving a clean finish. An alternative method to ease clean-up is to protect the tile surface with a release agent prior to applying the polymeric grout. After the polymeric grout has partially cured, excess grout may be peeled from the surface of the tile and the tile cleaned with a suitable solvent to remove the release agent.
  • The following examples are for illustrate purposes only and are not intended to limit the scope of the claims.
  • A floating tile floor installation was manufactured using a plastic sheet moisture barrier as an underlayment and a structural adhesive as a polymeric grout. First, an approximately 16 FT2 section of particle board nailed to 2×4″ studs was constructed (FIG. 1). Next, the particle board was covered with a water proof plastic 4 mil LDPE sheet as a water proof underlayment. PLIOSEAL 3″ rubber splice tape pressure sensitive patches were then applied to the plastic sheet to hold the tiles in place (FIG. 2). Prior to placement on the underlayment, the tiles were taped with protective, removable tape to aid in clean up after the polymeric grout is applied. Next, 16-1 FT2 glazed ceramic tiles were placed onto the underlayment with a space between the tiles using the pressure sensitive tape to hold the tile in place (FIG. 3). Next, a 2-component urethane adhesive (polymeric grout) was mixed and applied between the tiles using a disposable plastic grout bag. Alternative methods of application include dispensing the polymeric grout from a cartridge using a dispensing gun or floating the polymeric grout into the space between the tiles as with cementatious grout and cleaning the tile surface with an appropriate solvent. (This method was used to produce the tile installations in FIGS. 9, 10, 11 and 12.) The 2-component urethane polymeric grout was formulated as shown in Table 1. The polymeric grout was then struck and a decorative sand (zircon sand, lake sand or silica sand) was applied to the uncured polymeric grout (FIG. 4). Before the polymeric grout completely cured, the tape was removed. After 4 hours, the polymeric grout cured sufficiently to remove excess decorative sand and the tile could then be walked on (FIG. 5). The decorative sand gives the appearance of cementious grout (FIG. 6). The finished tile installation is strong enough to support itself in a vertical position (FIGS. 7 and 8). With the high strength of the finished tile system, preformed tile sections can be prepared and installed as if they were individual tiles using the method described.
  • TABLE 1
    Polymer grout (2-component urethane) formulation used in the example
    Prepolymer Curative
    Material Weight % Material Weight %
    Methylene phenylene 35.0 Polyether polyol 39.0–43.0
    isocyanate
    Urethane prepolymer 19.0–23.0 Polyol 25.0–29.0
    MDI Homopolymer 12.0–16.0 Talc 21.0–25.0
    Calcium sodium  8.0–12.0 Urethane prepolymer 1.0–5.0
    aluminosilicate
    Talc  8.0–12.0 Clay 1.0–5.0
    Urethane prepolymer 3.0–7.0 Amorphous silica 1.0–5.0
    Amorphous silica 2.0–6.0 Quartz 0.1–0.9
    100.00 100.00
  • The term “comprising” (and its grammatical variations) as used herein is used in the inclusive sense of “having” or “including” and not in the exclusive sense of “consisting only of”. The term “a” and “the” as used herein are understood to encompass the plural as well as the singular.
  • The foregoing description illustrates and describes the present disclosure. Additionally, the disclosure shows and describes only the preferred embodiments of the disclosure, but, as mentioned above, it is to be understood that it is capable of changes or modifications within the scope of the concept as expressed herein commensurate with the above teachings and/or skill or knowledge of the relevant art. The embodiments described hereinabove are further intended to explain best modes know of practicing the invention and to enable others skilled in the art to utilize the disclosure in such, or other, embodiments and with the various modification required by the particular applications or uses disclosed herein. Accordingly, the description is not intended to limit the invention to the form disclosed herein. Also, it is intended that the appended claims be construed to include alternative embodiments.
  • All publications, patents and patent applications cited in this specification are herein incorporated by reference, and for any and all purposes, as if each individual publication, patent or patent application were specifically and individually indicated to be incorporated by reference. In the case of inconsistencies, the present disclosure will prevail.

Claims (23)

1. A tile installation comprising an underlayment and at least two tiles bonded with a polymeric grout to produce a floating floor.
2. The tile installation as claimed in claim 1, wherein the underlayment is a rigid material, a flexible material or an adhesive material and wherein the underlayment is optionally a moisture barrier.
3. The tile installation as claimed in claim 1, wherein the at least two tiles bonded with a polymeric grout are bonded to the underlayment with a polymeric grout, an adhesive or an adhesive tape.
4. The tile installation as claimed in claim 1, wherein the at least two tiles bonded with a polymeric grout are not bonded to the underlayment.
5. The tile installation as claimed in claim 1, wherein the polymeric grout is non-porous, water-proof, mildew resistant and stain resistant.
6. The tile installation as claimed in claim 1, wherein the polymeric grout is at least one selected from the group consisting of a urethane grout, an epoxy grout, a polyester grout or an acrylic grout.
7. The tile installation as claimed in claim 1, wherein the at least two tiles are selected from the group consisting of ceramic tiles, porcelain tile, terra cotta tile, marble tiles, concrete tile, metal tile, plastic tile, granite tile, slate tile, wood tile, glass tile, engineered stone tile and combinations thereof.
8. The tile installation as claimed in claim 1, wherein the underlayment is at least one selected from the group consisting of plywood, wood particle board, wood planking, a metal sheet, cement, a fiber glass sheet, a plastic sheet, a foam sheet, a composite sheet and combinations thereof.
9. The tile installation as claimed in claim 8, wherein the underlayment is a composite comprising a polymeric resin and a fibrous material.
10. The tile installation as claimed in claim 9, wherein the polymeric resin is at least one selected from the group consisting of polyester resin, epoxy resin, urethane resin, polysulfone resin, polyphenylsulfone resin, polyethersulfone resin, polyphthalamide resin, polyaryiamide resin, polyphenylene sulfide resin, aromatic polyketone resin, polyamide-imide resin, polycarbonate resin, styrenic resin, ABS resin, acrylic resin and PET resin.
11. The tile installation as claimed in claim 9, wherein the fibrous material is at least one selected from the group consisting of synthetic fibers such as but not limited to fiber-glass, carbon fiber, polyethylene fiber, polypropylene fiber, nylon fiber, polyester fiber, and polyamide fiber and natural fibers such as but not limited to hemp, cotton fiber, linen fiber, wool fiber, and combinations synthetic and natural fibers thereof.
12. The tile installation as claimed in claim 1, wherein the underlayment is a composite comprising a cement material and a fibrous material.
13. The tile installation as claimed in claim 1, further comprising a decorative particle covering and bonded to or dispersed in to the polymeric grout.
14. The tile installation as claimed in claim 13, wherein the decorative particle is at least one selected from the group consisting natural materials such as sand, minerals, crushed stone, crushed shell, metal flake, titanium dioxide and natural pigments and synthetic materials such as ceramic and ceramic coated particles, crushed glass, synthetic pigments and cured resin particulates such as polyester flake, and combinations of natural and synthetic materials thereof.
15. The tile installation as claimed in claim 2, wherein the underlayment is an adhesive and the adhesive is at least one selected from the group consisting of Plioseal®, urethane adhesives and epoxy adhesives.
16. A method of manufacturing the tile installation as claimed in claim 1, comprising:
placing an underlayment over an existing floor;
placing at least two tiles separated by a space on the underlayment;
applying an uncured polymeric grout in the space between at least two tiles;
optionally striking the polymeric grout to give a desired contour and allowing the uncured polymeric grout to cure to produce the tile installation as a floating floor.
17. The method of manufacturing the tile installation as claimed in claim 16, wherein a spacer is utilized to provide the space separating the at least two tiles.
18. The method of manufacturing the tile installation as claimed in claim 16, further comprising bonding the at least two tiles to the underlayment prior to applying the polymeric grout.
19. The method of manufacturing the tile installation as claimed in claim 16, wherein the underlayment and the at least two tiles are not bonded together.
20. The method of manufacturing the tile installation as claimed in claim 16, further comprising applying a decorative particle to the uncured polymeric grout in the space between the at least two tiles wherein the decorative particle is bonded to the polymeric grout after curing.
21. The method of manufacturing the tile installation as claimed in claim 16, further comprising taping or applying a flexible film to the surface of at least two tiles prior to applying the uncured polymeric grout and removing the tape or film after the polymeric grout is applied into the space between the at least two tiles before the polymeric grout cures.
22. The method of manufacturing the tile installation as claimed in claim 16, further comprising application of a release agent to the tile surface prior to applying the uncured polymeric grout and then removing the excess partially cured polymeric grout from the surface of the tile followed by removal of the release agent after the polymeric grout is completely cured.
23. The method of manufacturing the tile installation as claimed in claim 16, further comprising of preformed tile sections manufactured according to the method in claim 16.
US11/639,338 2006-12-15 2006-12-15 Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture Abandoned US20080141603A1 (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
US11/639,338 US20080141603A1 (en) 2006-12-15 2006-12-15 Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture
PCT/US2007/086758 WO2008076670A2 (en) 2006-12-15 2007-12-07 Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture
CNA2007800461909A CN101600840A (en) 2006-12-15 2007-12-07 Be used to make and make the polymer mortar that brick bonds mutually and the device and the manufacture method thereof of bed course comprising of floating floor
BRPI0720030-7A BRPI0720030A2 (en) 2006-12-15 2007-12-07 FLOOR INSTALLATION, AND METHOD FOR MANUFACTING FLOOR INSTALLATION.
MX2009006364A MX2009006364A (en) 2006-12-15 2007-12-07 Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture.
CA002672480A CA2672480A1 (en) 2006-12-15 2007-12-07 Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture
EP07855016A EP2092137A2 (en) 2006-12-15 2007-12-07 Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture
AU2007334096A AU2007334096A1 (en) 2006-12-15 2007-12-07 Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture
JP2009541490A JP2010513752A (en) 2006-12-15 2007-12-07 Equipment and manufacturing method including polymer grout for bonding tiles to each other and underlaying for manufacturing floating floor
TW096147965A TW200835834A (en) 2006-12-15 2007-12-14 Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture
CO09073662A CO6231059A2 (en) 2006-12-15 2009-07-15 INSTALLATION THAT INCLUDES A POLYMERIC MILK TO ADHER TILES BETWEEN YES AND A BASE TO PRODUCE A FLOATING FLOOR AND MANUFACTURING METHOD

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/639,338 US20080141603A1 (en) 2006-12-15 2006-12-15 Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture

Publications (1)

Publication Number Publication Date
US20080141603A1 true US20080141603A1 (en) 2008-06-19

Family

ID=39525462

Family Applications (1)

Application Number Title Priority Date Filing Date
US11/639,338 Abandoned US20080141603A1 (en) 2006-12-15 2006-12-15 Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture

Country Status (11)

Country Link
US (1) US20080141603A1 (en)
EP (1) EP2092137A2 (en)
JP (1) JP2010513752A (en)
CN (1) CN101600840A (en)
AU (1) AU2007334096A1 (en)
BR (1) BRPI0720030A2 (en)
CA (1) CA2672480A1 (en)
CO (1) CO6231059A2 (en)
MX (1) MX2009006364A (en)
TW (1) TW200835834A (en)
WO (1) WO2008076670A2 (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090193746A1 (en) * 2008-01-29 2009-08-06 Ludowici Roof Tile 2/3rds width flat interlocking tiles
US20100287877A1 (en) * 2008-01-14 2010-11-18 Perae-Rouhu Yrjoe J Arrangement for Covering a Floor
US20110059318A1 (en) * 2009-09-04 2011-03-10 Raymond Scott Harvey Structural urethane adhesives comprising amide polyols
US8001744B1 (en) * 2009-06-18 2011-08-23 John Squitieri Method of grouting commercial kitchen floors using a two-part reactive epoxy grout
ITMI20112193A1 (en) * 2011-12-01 2013-06-02 Basilico S R L METHOD FOR COATING SURFACES, PARTICULARLY FOR THE NAVAL SECTOR
US8740152B1 (en) * 2008-05-01 2014-06-03 Textron Innovations, Inc. Rivetless nutplates for aircraft
CN105002918A (en) * 2015-07-17 2015-10-28 中标建设集团股份有限公司 Construction method for environment-friendly light concrete cushion
US20190226215A1 (en) * 2018-01-25 2019-07-25 Daniel Selton Pattern Tile
US20200199889A1 (en) * 2018-12-19 2020-06-25 Gordon Neustaeter Deck system and method of installing
US11168232B2 (en) * 2018-02-23 2021-11-09 Ardex Group Gmbh Methods of installing tile using a reactivatable tile bonding mat

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8070558B2 (en) * 2009-03-04 2011-12-06 David Young Porcelain epoxy flooring and method for producing the same
KR102616611B1 (en) * 2023-08-02 2023-12-20 주식회사 쌍 곰 The high-performance adhesive for ceramic and porcelain tile, and a tiling method using the tile addhesive

Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4041200A (en) * 1975-12-11 1977-08-09 Gaf Corporation Stack of tiles which have a release layer on one major face and an adhesive layer on the opposed major face does not require disposable release interlayers
US4567704A (en) * 1977-05-03 1986-02-04 Tile Council Of America, Inc. Resilient ceramic tile flooring
US5238721A (en) * 1989-08-08 1993-08-24 Kabushiki Kaisha Pc Planning Title structure and method for applying title
US5255482A (en) * 1989-11-08 1993-10-26 Loretta A. Whitacre Tile flooring structure
US5418036A (en) * 1991-11-25 1995-05-23 Fukuyi Chemical Industry Co., Ltd. Tile application backing material and tile application execution method
US5584950A (en) * 1993-11-12 1996-12-17 The Noble Company Sound insulating membrane
US5590500A (en) * 1993-10-20 1997-01-07 Mccue; David L. Tile system
US5705250A (en) * 1993-06-28 1998-01-06 Hudson, Jr.; Thomas C. Resilient shock resistant ceramic panel
US6151854A (en) * 1997-07-24 2000-11-28 Gutjahr; Walter Profiled web for venting and draining floor tiles, particularly ceramic tiles, laid in a thin retaining layer
US20020062625A1 (en) * 2000-12-11 2002-05-30 Jack Foden Access floor panel and system
US20020071930A1 (en) * 1999-04-23 2002-06-13 Oakey David D. Modular floor covering edge treatment
US6413618B1 (en) * 1999-05-11 2002-07-02 Congoleum Corporation Laminated glass floor tile and flooring made therefrom and method for making same
US20040241387A1 (en) * 2001-09-17 2004-12-02 Frank Lian Adhesive tape used as an aid when applying cualk or grout in ceramic tile corners
US6854241B1 (en) * 1999-09-13 2005-02-15 Frank Pelosi, Jr. Dimensionally stable adhesive floor covering system
US6881768B2 (en) * 2003-01-09 2005-04-19 Laticrete International, Inc. Water-based epoxy grout
US20060079600A1 (en) * 2004-10-13 2006-04-13 Gopalratnam Usha S Anti-stick coating for surfaces
US7546707B1 (en) * 2006-08-29 2009-06-16 California Portable Dance Floor Company, Inc. Portable floor

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4041200A (en) * 1975-12-11 1977-08-09 Gaf Corporation Stack of tiles which have a release layer on one major face and an adhesive layer on the opposed major face does not require disposable release interlayers
US4567704A (en) * 1977-05-03 1986-02-04 Tile Council Of America, Inc. Resilient ceramic tile flooring
US5238721A (en) * 1989-08-08 1993-08-24 Kabushiki Kaisha Pc Planning Title structure and method for applying title
US5255482A (en) * 1989-11-08 1993-10-26 Loretta A. Whitacre Tile flooring structure
US5418036A (en) * 1991-11-25 1995-05-23 Fukuyi Chemical Industry Co., Ltd. Tile application backing material and tile application execution method
US5705250A (en) * 1993-06-28 1998-01-06 Hudson, Jr.; Thomas C. Resilient shock resistant ceramic panel
US5590500A (en) * 1993-10-20 1997-01-07 Mccue; David L. Tile system
US5584950A (en) * 1993-11-12 1996-12-17 The Noble Company Sound insulating membrane
US6151854A (en) * 1997-07-24 2000-11-28 Gutjahr; Walter Profiled web for venting and draining floor tiles, particularly ceramic tiles, laid in a thin retaining layer
US20020071930A1 (en) * 1999-04-23 2002-06-13 Oakey David D. Modular floor covering edge treatment
US6413618B1 (en) * 1999-05-11 2002-07-02 Congoleum Corporation Laminated glass floor tile and flooring made therefrom and method for making same
US6854241B1 (en) * 1999-09-13 2005-02-15 Frank Pelosi, Jr. Dimensionally stable adhesive floor covering system
US20020062625A1 (en) * 2000-12-11 2002-05-30 Jack Foden Access floor panel and system
US20040241387A1 (en) * 2001-09-17 2004-12-02 Frank Lian Adhesive tape used as an aid when applying cualk or grout in ceramic tile corners
US6881768B2 (en) * 2003-01-09 2005-04-19 Laticrete International, Inc. Water-based epoxy grout
US20060079600A1 (en) * 2004-10-13 2006-04-13 Gopalratnam Usha S Anti-stick coating for surfaces
US7546707B1 (en) * 2006-08-29 2009-06-16 California Portable Dance Floor Company, Inc. Portable floor

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100287877A1 (en) * 2008-01-14 2010-11-18 Perae-Rouhu Yrjoe J Arrangement for Covering a Floor
US20090193746A1 (en) * 2008-01-29 2009-08-06 Ludowici Roof Tile 2/3rds width flat interlocking tiles
US8740152B1 (en) * 2008-05-01 2014-06-03 Textron Innovations, Inc. Rivetless nutplates for aircraft
US8001744B1 (en) * 2009-06-18 2011-08-23 John Squitieri Method of grouting commercial kitchen floors using a two-part reactive epoxy grout
US8317967B2 (en) 2009-09-04 2012-11-27 Ashland Licensing And Intellectual Property Llc Structural urethane adhesives comprising amide polyols
EP2473540A1 (en) * 2009-09-04 2012-07-11 Ashland Licensing And Intellectual Property LLC Structural urethane adhesives comprising amide polyols
WO2011028586A1 (en) * 2009-09-04 2011-03-10 Ashland Licensing And Intellectual Property Llc Structural urethane adhesives comprising amide polyols
US20110059318A1 (en) * 2009-09-04 2011-03-10 Raymond Scott Harvey Structural urethane adhesives comprising amide polyols
EP2473540A4 (en) * 2009-09-04 2014-12-03 Ashland Licensing & Intellectu Structural urethane adhesives comprising amide polyols
ITMI20112193A1 (en) * 2011-12-01 2013-06-02 Basilico S R L METHOD FOR COATING SURFACES, PARTICULARLY FOR THE NAVAL SECTOR
CN105002918A (en) * 2015-07-17 2015-10-28 中标建设集团股份有限公司 Construction method for environment-friendly light concrete cushion
US20190226215A1 (en) * 2018-01-25 2019-07-25 Daniel Selton Pattern Tile
US11168232B2 (en) * 2018-02-23 2021-11-09 Ardex Group Gmbh Methods of installing tile using a reactivatable tile bonding mat
US20200199889A1 (en) * 2018-12-19 2020-06-25 Gordon Neustaeter Deck system and method of installing

Also Published As

Publication number Publication date
CO6231059A2 (en) 2010-12-20
JP2010513752A (en) 2010-04-30
CA2672480A1 (en) 2008-06-26
WO2008076670A3 (en) 2008-12-18
WO2008076670A2 (en) 2008-06-26
TW200835834A (en) 2008-09-01
BRPI0720030A2 (en) 2013-12-17
CN101600840A (en) 2009-12-09
EP2092137A2 (en) 2009-08-26
MX2009006364A (en) 2009-07-17
AU2007334096A1 (en) 2008-06-26

Similar Documents

Publication Publication Date Title
US20080141603A1 (en) Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floating floor and method of manufacture
US9194131B2 (en) Exterior finish system
US8317967B2 (en) Structural urethane adhesives comprising amide polyols
US20110036035A1 (en) Compositions and methods for coating surfaces
EP3233752B1 (en) Multicomponent adhesive system and its use as adhesive in building and construction
KR101586035B1 (en) Complex waterproofing structure for reinforcing connection using the waterproofing sheet and Construction method thereof
US20100005743A1 (en) Flexible Cement Veneer
KR100968117B1 (en) Construction method of the outer wall for forming waterproof and insulation layer
US4324605A (en) Tiling arrangement and method
US20110225918A1 (en) Construction Plate Suitable for a Tile Support
KR101778261B1 (en) Complex waterproof structure for building and forming method thereof
WO2004022879A1 (en) A composite tile
US20140342147A1 (en) Covering material for flooring and walls
CA2710834A1 (en) Cementitious boards with reinforced edges that resist impact damage
KR102484066B1 (en) Waterproof coating system multilayered with permeable polymer waterproof material and wet curable polymer mortar and the contruction method thereof
JP2008008137A (en) Repair structure of slate tile roof
WO2009075906A2 (en) Installation comprising a polymeric grout for bonding tiles to each other and an underlayment to produce a floor and method of manufacture
KR101453983B1 (en) stone sheet for construction and method
CN116290653A (en) Composite floor containing fiber layer
AU2006200975A1 (en) A block for use in the construction of a wall
JP2000054609A (en) Floor tile panel and its executing adhesive agent
JPH04360951A (en) Tile floor finishing method
TR201703892A2 (en) Fiber Polymer Material Anchor Method

Legal Events

Date Code Title Description
AS Assignment

Owner name: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC, O

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:HARVEY, RAYMOND S.;MOY, THOMAS M.;TUFTS, TIMOTHY A.;AND OTHERS;REEL/FRAME:018818/0263

Effective date: 20061120

AS Assignment

Owner name: BANK OF AMERICA, N.A. AS ADMINISTRATIVE AGENT, CAL

Free format text: SECURITY AGREEMENT;ASSIGNORS:ASHLAND LICENSING AND INTELLECTUAL PROPERTY...;AQUALON COMPANY;HERCULES INCORPORATED;REEL/FRAME:021924/0001

Effective date: 20081113

Owner name: BANK OF AMERICA, N.A. AS ADMINISTRATIVE AGENT,CALI

Free format text: SECURITY AGREEMENT;ASSIGNORS:ASHLAND LICENSING AND INTELLECTUAL PROPERTY...;AQUALON COMPANY;HERCULES INCORPORATED;REEL/FRAME:021924/0001

Effective date: 20081113

AS Assignment

Owner name: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC,OH

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BANK OF AMERICA, N.A., AS COLLATERAL AGENT;REEL/FRAME:024218/0928

Effective date: 20100331

Owner name: AQUALON COMPANY,DELAWARE

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BANK OF AMERICA, N.A., AS COLLATERAL AGENT;REEL/FRAME:024218/0928

Effective date: 20100331

Owner name: HERCULES INCORPORATED,DELAWARE

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BANK OF AMERICA, N.A., AS COLLATERAL AGENT;REEL/FRAME:024218/0928

Effective date: 20100331

Owner name: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC, O

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BANK OF AMERICA, N.A., AS COLLATERAL AGENT;REEL/FRAME:024218/0928

Effective date: 20100331

Owner name: AQUALON COMPANY, DELAWARE

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BANK OF AMERICA, N.A., AS COLLATERAL AGENT;REEL/FRAME:024218/0928

Effective date: 20100331

Owner name: HERCULES INCORPORATED, DELAWARE

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BANK OF AMERICA, N.A., AS COLLATERAL AGENT;REEL/FRAME:024218/0928

Effective date: 20100331

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION