US20050076927A1 - Ventilated smoking article - Google Patents
Ventilated smoking article Download PDFInfo
- Publication number
- US20050076927A1 US20050076927A1 US10/499,281 US49928104A US2005076927A1 US 20050076927 A1 US20050076927 A1 US 20050076927A1 US 49928104 A US49928104 A US 49928104A US 2005076927 A1 US2005076927 A1 US 2005076927A1
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- United States
- Prior art keywords
- filter
- grooves
- smoking article
- accordance
- plug
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/025—Final operations, i.e. after the filter rod forming process
- A24D3/0258—Means for making grooves
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/043—Tobacco smoke filters characterised by their shape or structure with ventilation means, e.g. air dilution
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
- A24D1/027—Cigars; Cigarettes with special covers with ventilating means, e.g. perforations
Definitions
- the invention relates to a smoking article, in particular but not exclusively a cigarette, incorporating a filter in which grooves are pressed into the circumference of the filter.
- U.S. Pat. No. 4,406,294 discloses a cigarette filter with a cylindrical filter plug, with an air-permeable plug wrap for the filter plug and with grooves impressed into the circumference of the filter plug extending over a part of the filter length from the mouth end of the filter.
- the grooves are, however, impermeable.
- the cylindrical filter plug and hence also the grooves are attached by an air-permeable tipping paper provided with ventilation openings.
- the filter has an uncomplicated structure and achieves an essentially normal drop in pressure over the cigarette.
- U.S. Pat. No. 4,256,122 discloses a cigarette filter with a similar structure, where, however, the circumferential surface of the filter plug, including the walls of the grooves, are impermeable by virtue of an impermeable plug wrap.
- the grooves are open at the mouth end of the filter plug.
- FIGS. 2, 3 and 5 show embodiments which also include grooves which are still open on the tobacco end.
- U.S. Pat. No. 4,649,943 shows a further modification of such a filter, in which the grooves are open at the mouth end of the filter.
- at least one perforation is provided in the area of the grooves intended for the introduction of air through the plug wrap into the filter plug, thereby providing the filter with an improved air distribution in the filter rod.
- a tipping wrapper of impermeable material which has an air-permeable region contributes to this.
- the lining paper (plug wrap) is impermeable but provided with ventilation openings.
- DE-PS 21 07 850 discloses a filter tip, the circumference of which is provided with longitudinal grooves. A plug wrap is not mentioned and the grooves are preferentially open at the mouth end of the filter.
- U.S. Pat. No. 4,343,319 discloses a similar cigarette filter with a smoke-impermeable wrapper for the filter plug and with a central tube, extending axially through the filter plug, which is located in flow connection with the opening in the grooves. In this way the smoke leaving the tobacco rod is divided into two parts. One part flows through the central pipe and the other part flows through the filter material. The presence of tubes and interconnecting passages adds to the complexity of the filter manufacture.
- a cigarette filter with an air-impermeable wrapper for the filter core and with grooves in the circumference of the filter core and which extend over the whole length of the filter core is disclosed in DE 30 48 905 A1.
- This filter can be manufactured more easily, since it is not necessary to change the production direction.
- a filter for tobacco smoke provided with grooves in its circumference which are produced by a corrugated material around the actual filter is known from GB 2102271.
- the plug wrap surrounding the filtration material is smoke-impermeable. Grooves are provided between the plug wrap and the corrugated material, and also between the tipping wrapper and the corrugated material.
- the tipping wrapper is provided with ventilation openings. This filter element should be versatile and flexibly usable.
- GB 2 089 641 A discloses a filter for a cigarette with a central, hollow tube, which extends from one end of the filter into the filter material.
- the filter core is surrounded by a non-porous wrapper and the filter plug and the wrapper have at least one groove, which extends longitudinally from one end of the filter plug. In this way a normal decrease of pressure through the cigarette is achieved for a filter with low to moderate efficiency. Formation of a hollow tube adds to the manufacturing requirements.
- GB 2 136 669 A shows a cigarette filter with a filter plug which is surrounded by a smoke-permeable material.
- the filter has longitudinal corrugations which form grooves outside of the smoke-permeable wrapper which are open at one end of the filter and extend in longitudinal direction from this end towards the other end but not over the entire length of the filter plug.
- the smoke permeable wrapper carries means, i.e. a coating, which makes it smoke-impermeable over a region which extends over only a part of the length of the grooves and separates from the corresponding end of the filter a grooved region of the wrapper which is smoke permeable.
- GB 2 095 093 A discloses a filter with a filter plug with a non-porous wrapper and with grooves which extend from one end of the filter a certain distance in the direction of the other end of the filter.
- the grooves can be open to the atmosphere and so aligned that they extend up to the mouth end of the filter or to the tobacco end of the filter. It is also possible to have an alternating arrangement of grooves which begin at the mouth end and at the tobacco end.
- the filter is fastened to the tobacco rod by a narrow strip of material in order to prevent disruption of the entry of the ventilation openings to the grooves.
- U.S. Pat. No. 3,752,165 shows a filter for a smokable article with a filter plug which is wrapped in a thin, porous wrapper paper.
- a plurality of grooves is formed in the wrapper paper and into the filter material at one end of the filter.
- the grooves extend from one end of the filter to a point shortly before the opposite end and are surrounded by a smoke-impermeable plug wrap.
- the grooves extend from one end of the filter to a point which is some distance from the other end.
- a filter is known from U.S. Pat. No. 3,910,288 with a filter plug provided around its circumference with grooves which extend from the tobacco end of the filter up to a place before the mouth end of the filter.
- the grooves are formed in a rigid plastic wrapper which surrounds the filter material. At one end of every groove an opening is provided which makes a connection to the filter material possible. Filter ventilation is not provided.
- This filter is very resistant to crushing, so that the and/or each groove can remain open during the entire smoking of the smokable article.
- U.S. Pat. No. 3,596,663 shows a filter for a smokable article with a filter plug with grooves, the length of which is not defined.
- the filter wrapper and the lining paper are in each case porous and/or provided with perforations.
- the air-permeable wrapper is corrugated in order to increase the size of the air-permeable surface and thus to simplify the path of the air which is allowed through the ventilated wrapping paper to the filter material of the filter plug.
- a ventilated filter is produced that significantly reduces the restriction of the air passage to the filtering medium.
- CO carbon monoxide
- the object of the invention is to produce a filter for a smoking article, in particular a cigarette, which enables an effective, in particular adjustable, decrease of the CO content of the smoke compared with other components, such as tar and nicotine.
- the retention of the filter material is reduced because of the well known dependency of the linear flow velocity: retention decreases with increasing flow velocity. Due to the fact that the CO level is not affected by the filtering material, the CO/tar ratio decreases.
- the ventilating air flows over the grooves toward the tobacco rod when smoking the cigarette and from there back through the filtration material into the mouth of the smoker.
- a plug wrap which is inherently porous or ventilated and hence provided with ventilation openings. Some of the ventilation air then flows through this path and hence through the permeable plug wrap into the filter and to the mouth of the smoker. This portion can be adjusted by appropriate adjustment of the inherent or artificial porosity of the plug wrap, by which means the pressure drop/smoking mechanics as well as the CO/tar ratio can also be influenced.
- porous or ventilated plastic sheets or foils may be used as plug wrap material.
- on-machine laser perforation of tipping paper and impermeable plugwrap is particularly useful for low delivery products with a tar delivery of less than 3 mg, preferably less than 1 mg.
- a tar delivery of less than 3 mg, preferably less than 1 mg.
- On-line machine perforation perforates both the plug wrap and the filtration material underneath, allowing the ingress of ventilating air thereto.
- mixed ventilation occurs, i.e. through grooves and filtration material.
- Synthetic or thermoformable plugwraps such as those described in British Patent Nos. 2058543, 2056841 or 2134365 may also be especially suitable as heat mouldable plug wrap for the present invention.
- two to ten grooves are provided, since the use of only one groove leads to a very asymmetrical distribution of the ventilation air in the smoke which could impair smoking enjoyment. More than ten grooves greatly complicate the production process and also hardly leave enough space for adequate flow cross-section of the individual grooves. Good results were achieved with four grooves.
- the grooves have a V-shaped or preferably a U-shaped cross section, since this has manufacturing and Theological advantages.
- filter material may be employed as filter material where one or several of these materials can be used.
- a conventional filter tow of cellulose acetate is used.
- conventional techniques are used, for example adding triacetin or Tegda to the filter tow.
- additives such as activated charcoal, zeolites, flavour-modifiers or an ion exchange resin, such as that known as Duolite (see U.S. Pat. Nos. 3,716,500 or 3,943,832) which is a porous particulate salt of a weakly basic anion exchange resin, to the filter in order to reduce other vapour phase constituents.
- additives such as activated charcoal, zeolites, flavour-modifiers or an ion exchange resin, such as that known as Duolite (see U.S. Pat. Nos. 3,716,500 or 3,943,832) which is a porous particulate salt of a weakly basic anion exchange resin, to the filter in order to reduce other vapour phase constituents.
- the filtration material is homogeneous.
- homogeneous as applied to filtration material means there are no flow openings, tubes or other elements in the filtration material.
- a homogeneous filtration material may, though, be comprised of different filtration materials, such as in differing filtration sections, should the filter be a multiple filter.
- a homogeneous filtration material has benefits of simplicity in manufacture.
- the additive is located in a region of the filter which does not have grooves. This prevents thermal decomposition of the additive upon moulding to produce the grooves.
- the grooves extend over less than 80% of the length of the filter, where good results were obtained with about 60%.
- the depth of the grooves should be within the range 0.5 to 2 mm, preferably about 1 mm, where suitable flow volumes are achieved.
- the width of the grooves measured at the circumference of the filter, should lie between 1 and 3 mm, preferentially between 1.5 and 2.5 mm.
- the depth of the grooves along the rod axis may not necessarily be constant: It may for example increase towards the open end, the tobacco side of the filter.
- the grooves may also be non-linear, following for example a screwed or helical form around the filter.
- a further groove is added to the filter, which runs radially around the filter circumference.
- This groove shall connect the axial grooves. It is useful that this radial groove is located directly below the ventilation zone of the tipping paper, which enhances the ventilation effect. In cases of larger ventilation zones it may also be necessary to use two or more radial grooves.
- the filter of this invention may obviously be included as part of a dual or triple filtering device.
- the tipping paper serving to attach the filter to the tobacco rod may have a conventional structure, provided that it permits ventilation. This can be achieved either by use of a porous, therefore inherently air-permeable tipping paper or by producing ventilation openings by mechanical or electrostatic means or using laser beams.
- FIG. 1 shows a perspective view of a filter attached to a tobacco rod with partly wrapped tipping paper
- FIG. 2 shows a curve plotting of the CO/tar ratio as a function of the filter ventilation for a filter in accordance with the invention and a comparison filter
- FIG. 3 shows an embodiment of a filter with particulate additive therein
- FIG. 4 shows another embodiment of a filter with particulate additive therein.
- FIG. 1 shows a perspective view of a part of a proposed filter cigarette generally indicated by the reference symbol 10 with a conventional tobacco rod 12 and a filter element 14 appended to one end of the tobacco rod 12 .
- the filter element 14 consists of a cylindrical filter plug 16 of cellulose acetate tow as filtration material, which is homogeneously distributed over the entire volume of the filter plug 14 .
- no flow openings, tubes or other means are provided in the filter plug 16 .
- ‘homogeneous’ as applied to filtration material means there are no flow openings, tubes or other elements in the filtration material.
- a homogeneous filtration material may, though, be comprised of different filtration materials, such as the differing filtration sections described below with respect to FIG. 4 , none of which incorporate flow openings, tubes, etc.
- the filter plug 16 is covered with a plug wrap 18 which is air-impermeable, although in other embodiments (not shown) it can be inherently porous and/or provided with ventilation openings depending upon requirements, taking account particularly of the tobacco taste desired.
- Grooves 20 are stamped into the circumference of the filter element 14 , four grooves 20 in the embodiment shown, which are distributed symmetrically over the circumference of the filter element 14 .
- the grooves 20 extend up to the tobacco rod end of the filter element 14 , where they are open so that there is a flow connection between the grooves 20 and the tobacco rod 12 .
- the grooves 20 run over the circumference of the filter plug 16 in an axial direction and end at a rheologically adequate distance from the mouth end of the filter element 14 and hence at a distance at which neither air nor smoke from the grooves 20 can directly reach the mouth end of the filter element 14 .
- the axial length of the grooves 20 should be less than 80% of the length of the filter plug 14 . About 60% is preferred.
- the grooves 20 have a depth of approximately 1.5 mm and a U-shaped cross section and a width of approximately 2 mm at the circumference.
- the filter element 14 is surrounded in the usual way by a tipping paper 22 , which is provided in the embodiment shown with two circumferential parallel rows of ventilation holes 24 .
- a larger or smaller number of rows of ventilation holes can also be provided or the tipping paper 22 can be inherently porous. It is only necessary to ensure that the porosity and/or the number and size of the ventilation openings 22 ensure the desired degree of ventilation.
- plug wrap 18 there are in principle two possibilities, i.e. the use of an air-impermeable paper or an air-permeable paper.
- ventilation air flows through the ventilation openings 24 when smoking the cigarette into the grooves 20 and then from the grooves 20 toward tobacco rod, where the direction is reversed and the ventilation air then flows, together with the smoke from the tobacco rod 12 , through the filter plug 16 into the smoker's mouth.
- the plug wrap is air-permeable, either inherently porous or provided with ventilation openings, then an adjustable portion of ventilation air flows by this flow path through the air-permeable plug wrap into the filter and to the mouth of the smoker. This is in addition to the air flowing through the grooves 20 . In this way the dilution of the smoke can be adjusted by air ventilation in two places, i.e. firstly by ventilation through the tipping paper 22 and along the grooves 20 , and secondly by ventilation air which enters directly through the plug wrap 18 into the filter plug 16 .
- FIG. 2 shows a graph of the effect of the filter ventilation on the CO/tar ratio with a filter in accordance with the invention from conventional cellulose acetate filter tow, an air-impermeable plug wrap and four grooves 20 with the above dimensions, which are symmetrically distributed over the circumference of the filter plug 16 and which, commencing from the tobacco end, extend over 60% of the length of the filter element 14 .
- FIG. 2 the full circles indicate the measured values for a conventional filter made from monoacetate filter tow without grooves, while the squares describe the measured values for a filter element 14 in accordance with the invention with the structure and the same dimensions as the comparison filter described above.
- the filter element 14 in accordance with the invention reduces the CO content of the smoke relative to the delivered tar and hence the CO/tar ratio from about 1.4 to about 0.7, while through ventilation alone, and hence without use of grooves, the CO/tar ratio can be lowered to only to about 1.12.
- CO/tar ratio can be reduced to below the limit set by the new regulations with the filter element 14 in accordance with the invention by the appropriate selection of a suitable degree of ventilation for the tipping paper 22 .
- the filters used for these measurements had the following parameters of the grooves: 4 grooves, 17 mm long, about 1.5 mm wide and 0.5-1 mm deep.
- the plug wrap was air impermeable and not additionally ventilated.
- FIG. 3 shows in cross section a filter element 14 of the invention, where like parts are labelled in accordance with FIG. 1 , attached to a tobacco rod 12 .
- the plug wrap 18 used to overlie the filter plug 16 includes a portion that has particulate activated carbon adhered thereto in the region 26 .
- Grooves 20 are formed in the plug wrap 18 after the plug wrap is wrapped around the filter plug 16 .
- the filter element is thus an integral element.
- the filter element comprises three sections: a grooved section in which grooves 20 are formed in the surface thereof, a Dalmatian carbon section 28 comprising particles of activated carbon dispersed in cellulose acetate tow, and a conventional cellulose acetate tow section 30 .
- the three sections may be joined together by one plug wrap which is mouldable to produce the grooves of the grooved section.
- the grooves are formed in the surface of either a self-sustaining non-wrapped acetate (NWA) section or a plug wrap enwrapping a cellulose acetate section.
- NWA non-wrapped acetate
- the three sections are then aligned together and then overwrapped with a further plug wrap (not shown).
- FIGS. 3 and 4 avoid the problem of having to mould grooves into a filter section containing particulate matter, during which moulding there may be adverse effects on the particulate matter if contacted with heating elements.
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Abstract
The invention concerns a smoking article filter plug (16) for a cigarette, the filter plug being cylindrical and having a plug wrap (18), grooves (20) being impressed into the plug wrap, and a tipping paper (22) for the attachment of the filter plug to the tobacco rod (12). Some grooves are axially extending with respect to the axis of the filter plug and are open on the side of the tobacco rod and extend continuously only over a part of the length of the filter plug. All grooves are covered by a ventilated tipping paper, which allows ventilating air into the axially extending grooves only. In addition the invention concerns the use of such a filter for the reduction of the CO/tar ratio as a function of the filter ventilation.
Description
- The invention relates to a smoking article, in particular but not exclusively a cigarette, incorporating a filter in which grooves are pressed into the circumference of the filter.
- Various forms of embodiment of such filters are known. Thus U.S. Pat. No. 4,406,294 discloses a cigarette filter with a cylindrical filter plug, with an air-permeable plug wrap for the filter plug and with grooves impressed into the circumference of the filter plug extending over a part of the filter length from the mouth end of the filter. The grooves are, however, impermeable. The cylindrical filter plug and hence also the grooves are attached by an air-permeable tipping paper provided with ventilation openings. The filter has an uncomplicated structure and achieves an essentially normal drop in pressure over the cigarette.
- U.S. Pat. No. 4,256,122 discloses a cigarette filter with a similar structure, where, however, the circumferential surface of the filter plug, including the walls of the grooves, are impermeable by virtue of an impermeable plug wrap. Here, though, some of the grooves are open at the mouth end of the filter plug.
FIGS. 2, 3 and 5 show embodiments which also include grooves which are still open on the tobacco end. With this filter a strong tobacco-flavoured cigarette is obtained which retains the high reduction of the unwanted smoke constituents and the good processability on standard cigarette machines. However, some of these embodiments require precise registration of the perforated tipping wrapper with circumferential grooves, giving manufacturing and quality problems. - U.S. Pat. No. 4,649,943 shows a further modification of such a filter, in which the grooves are open at the mouth end of the filter. In addition, at least one perforation is provided in the area of the grooves intended for the introduction of air through the plug wrap into the filter plug, thereby providing the filter with an improved air distribution in the filter rod. In addition a tipping wrapper of impermeable material which has an air-permeable region contributes to this. The lining paper (plug wrap) is impermeable but provided with ventilation openings.
- Further, DE-PS 21 07 850 discloses a filter tip, the circumference of which is provided with longitudinal grooves. A plug wrap is not mentioned and the grooves are preferentially open at the mouth end of the filter.
- U.S. Pat. No. 4,362,171 discloses a cigarette filter with grooves which are open neither at the tobacco end nor at the mouth end and thus extend only over the centre of the filter plug. Each groove is provided with an opening, so that ventilation air is guided longitudinally along the filter rod in the direction of the mouth end. Thus outside air is introduced at high velocity in a simple manner into the cigarette filter, without the danger of a blockage due to lip pressure and/or a loss of pressure.
- U.S. Pat. No. 4,343,319 discloses a similar cigarette filter with a smoke-impermeable wrapper for the filter plug and with a central tube, extending axially through the filter plug, which is located in flow connection with the opening in the grooves. In this way the smoke leaving the tobacco rod is divided into two parts. One part flows through the central pipe and the other part flows through the filter material. The presence of tubes and interconnecting passages adds to the complexity of the filter manufacture.
- Further, a cigarette filter with an air-impermeable wrapper for the filter core and with grooves in the circumference of the filter core and which extend over the whole length of the filter core is disclosed in
DE 30 48 905 A1. This filter can be manufactured more easily, since it is not necessary to change the production direction. - A filter for tobacco smoke provided with grooves in its circumference which are produced by a corrugated material around the actual filter is known from GB 2102271. The plug wrap surrounding the filtration material is smoke-impermeable. Grooves are provided between the plug wrap and the corrugated material, and also between the tipping wrapper and the corrugated material. The tipping wrapper is provided with ventilation openings. This filter element should be versatile and flexibly usable.
- GB 2 089 641 A discloses a filter for a cigarette with a central, hollow tube, which extends from one end of the filter into the filter material. The filter core is surrounded by a non-porous wrapper and the filter plug and the wrapper have at least one groove, which extends longitudinally from one end of the filter plug. In this way a normal decrease of pressure through the cigarette is achieved for a filter with low to moderate efficiency. Formation of a hollow tube adds to the manufacturing requirements.
- Further, GB 2 136 669 A shows a cigarette filter with a filter plug which is surrounded by a smoke-permeable material. The filter has longitudinal corrugations which form grooves outside of the smoke-permeable wrapper which are open at one end of the filter and extend in longitudinal direction from this end towards the other end but not over the entire length of the filter plug. The smoke permeable wrapper carries means, i.e. a coating, which makes it smoke-impermeable over a region which extends over only a part of the length of the grooves and separates from the corresponding end of the filter a grooved region of the wrapper which is smoke permeable.
- GB 2 095 093 A discloses a filter with a filter plug with a non-porous wrapper and with grooves which extend from one end of the filter a certain distance in the direction of the other end of the filter. The grooves can be open to the atmosphere and so aligned that they extend up to the mouth end of the filter or to the tobacco end of the filter. It is also possible to have an alternating arrangement of grooves which begin at the mouth end and at the tobacco end. The filter is fastened to the tobacco rod by a narrow strip of material in order to prevent disruption of the entry of the ventilation openings to the grooves.
- U.S. Pat. No. 3,752,165 shows a filter for a smokable article with a filter plug which is wrapped in a thin, porous wrapper paper. A plurality of grooves is formed in the wrapper paper and into the filter material at one end of the filter. The grooves extend from one end of the filter to a point shortly before the opposite end and are surrounded by a smoke-impermeable plug wrap. The grooves extend from one end of the filter to a point which is some distance from the other end. A high efficiency for the removal of the tar from the tobacco smoke with an acceptable decrease of pressure can be achieved with this filter.
- Further, a filter is known from U.S. Pat. No. 3,910,288 with a filter plug provided around its circumference with grooves which extend from the tobacco end of the filter up to a place before the mouth end of the filter. The grooves are formed in a rigid plastic wrapper which surrounds the filter material. At one end of every groove an opening is provided which makes a connection to the filter material possible. Filter ventilation is not provided.
- This filter is very resistant to crushing, so that the and/or each groove can remain open during the entire smoking of the smokable article. By gradually changing the portion of the smoke which flows through the groove from a previously defined value to a value of 0, the filter achieves an almost homogeneous delivery of particulate material per puff with a relatively constant increase of the degree of efficiency of the filter.
- Finally, U.S. Pat. No. 3,596,663 shows a filter for a smokable article with a filter plug with grooves, the length of which is not defined. The filter wrapper and the lining paper are in each case porous and/or provided with perforations. The air-permeable wrapper is corrugated in order to increase the size of the air-permeable surface and thus to simplify the path of the air which is allowed through the ventilated wrapping paper to the filter material of the filter plug. Thus a ventilated filter is produced that significantly reduces the restriction of the air passage to the filtering medium.
- It can thus be stated in summary that for many years cigarette filters have been provided with grooves which permit smoke and/or air to be directed differently as a function of the position and the length of the grooves and the porosity and/or ventilation of the tipping or filter-wrapping paper. In this way it is possible to achieve a dilution of the smoke, turbulence of the smoke in the mouth area, and the separate guidance of ventilation air and smoke, as well as some other effects.
- In recent years attention has been directed to one smoke component, i.e. carbon monoxide (CO), for which no effective, economical filter is yet known. Particularly in view of the new legal requirements which prescribe a maximum CO quantity in the tobacco smoke of a cigarette, attempts are being made to reduce the CO content of the smoke to below a given maximum value.
- The object of the invention is to produce a filter for a smoking article, in particular a cigarette, which enables an effective, in particular adjustable, decrease of the CO content of the smoke compared with other components, such as tar and nicotine.
- This is achieved in accordance with the invention by the features of claim 1.
- Appropriate embodiments are defined by the characteristics of the subordinate claims.
- Due to the flow mechanics in the filter of this invention, the retention of the filter material is reduced because of the well known dependency of the linear flow velocity: retention decreases with increasing flow velocity. Due to the fact that the CO level is not affected by the filtering material, the CO/tar ratio decreases.
- If an air-impermeable plug wrap is used with the filter in accordance with invention then the ventilating air flows over the grooves toward the tobacco rod when smoking the cigarette and from there back through the filtration material into the mouth of the smoker.
- As an alternative it is possible to employ a plug wrap which is inherently porous or ventilated and hence provided with ventilation openings. Some of the ventilation air then flows through this path and hence through the permeable plug wrap into the filter and to the mouth of the smoker. This portion can be adjusted by appropriate adjustment of the inherent or artificial porosity of the plug wrap, by which means the pressure drop/smoking mechanics as well as the CO/tar ratio can also be influenced.
- As a further alternative, porous or ventilated plastic sheets or foils may be used as plug wrap material.
- The use of on-machine laser perforation of tipping paper and impermeable plugwrap is particularly useful for low delivery products with a tar delivery of less than 3 mg, preferably less than 1 mg. For such low delivery products it may be advantageous to provide two rows of ventilation holes, one row located above the axially extending grooves and another row located downstream of those holes. On-line machine perforation perforates both the plug wrap and the filtration material underneath, allowing the ingress of ventilating air thereto. Thus, mixed ventilation occurs, i.e. through grooves and filtration material.
- Synthetic or thermoformable plugwraps such as those described in British Patent Nos. 2058543, 2056841 or 2134365 may also be especially suitable as heat mouldable plug wrap for the present invention.
- Experiments have shown that the CO/tar ratio attainable changes as a function of the filter ventilation, i.e. the CO/tar ratio is reduced by increasing the filter ventilation, providing a further correcting variable for the CO/tar ratio.
- In a preferred embodiment two to ten grooves are provided, since the use of only one groove leads to a very asymmetrical distribution of the ventilation air in the smoke which could impair smoking enjoyment. More than ten grooves greatly complicate the production process and also hardly leave enough space for adequate flow cross-section of the individual grooves. Good results were achieved with four grooves.
- The grooves have a V-shaped or preferably a U-shaped cross section, since this has manufacturing and Theological advantages.
- By choosing the appropriate number of grooves, their appropriate depth, width and length it is possible to adjust the filter properties to the target properties of the cigarette to be produced.
- All conventionally used filter materials may be employed as filter material where one or several of these materials can be used. Preferably a conventional filter tow of cellulose acetate is used. For hardening the filters, conventional techniques are used, for example adding triacetin or Tegda to the filter tow.
- It is also possible to add additives, such as activated charcoal, zeolites, flavour-modifiers or an ion exchange resin, such as that known as Duolite (see U.S. Pat. Nos. 3,716,500 or 3,943,832) which is a porous particulate salt of a weakly basic anion exchange resin, to the filter in order to reduce other vapour phase constituents.
- Preferably the filtration material is homogeneous. As used herein ‘homogeneous’ as applied to filtration material means there are no flow openings, tubes or other elements in the filtration material. A homogeneous filtration material may, though, be comprised of different filtration materials, such as in differing filtration sections, should the filter be a multiple filter. A homogeneous filtration material has benefits of simplicity in manufacture.
- Preferably the additive is located in a region of the filter which does not have grooves. This prevents thermal decomposition of the additive upon moulding to produce the grooves.
- In accordance with a preferred embodiment the grooves extend over less than 80% of the length of the filter, where good results were obtained with about 60%.
- The depth of the grooves should be within the range 0.5 to 2 mm, preferably about 1 mm, where suitable flow volumes are achieved.
- Taking this criterion into consideration the width of the grooves, measured at the circumference of the filter, should lie between 1 and 3 mm, preferentially between 1.5 and 2.5 mm.
- The depth of the grooves along the rod axis may not necessarily be constant: It may for example increase towards the open end, the tobacco side of the filter. The grooves may also be non-linear, following for example a screwed or helical form around the filter.
- In some cases it may be necessary that a further groove is added to the filter, which runs radially around the filter circumference. This groove shall connect the axial grooves. It is useful that this radial groove is located directly below the ventilation zone of the tipping paper, which enhances the ventilation effect. In cases of larger ventilation zones it may also be necessary to use two or more radial grooves.
- The filter of this invention may obviously be included as part of a dual or triple filtering device.
- The tipping paper serving to attach the filter to the tobacco rod may have a conventional structure, provided that it permits ventilation. This can be achieved either by use of a porous, therefore inherently air-permeable tipping paper or by producing ventilation openings by mechanical or electrostatic means or using laser beams.
- In order that the invention may be clearly understood and readily carried into effect, reference will now be made, by way of example, to the following diagrammatic drawings, in which:
-
FIG. 1 shows a perspective view of a filter attached to a tobacco rod with partly wrapped tipping paper, -
FIG. 2 shows a curve plotting of the CO/tar ratio as a function of the filter ventilation for a filter in accordance with the invention and a comparison filter, -
FIG. 3 shows an embodiment of a filter with particulate additive therein, and -
FIG. 4 shows another embodiment of a filter with particulate additive therein. -
FIG. 1 shows a perspective view of a part of a proposed filter cigarette generally indicated by thereference symbol 10 with aconventional tobacco rod 12 and afilter element 14 appended to one end of thetobacco rod 12. Thefilter element 14 consists of a cylindrical filter plug 16 of cellulose acetate tow as filtration material, which is homogeneously distributed over the entire volume of thefilter plug 14. Thus, no flow openings, tubes or other means are provided in thefilter plug 16. As used herein ‘homogeneous’ as applied to filtration material means there are no flow openings, tubes or other elements in the filtration material. A homogeneous filtration material may, though, be comprised of different filtration materials, such as the differing filtration sections described below with respect toFIG. 4 , none of which incorporate flow openings, tubes, etc. - The filter plug 16 is covered with a
plug wrap 18 which is air-impermeable, although in other embodiments (not shown) it can be inherently porous and/or provided with ventilation openings depending upon requirements, taking account particularly of the tobacco taste desired. -
Grooves 20 are stamped into the circumference of thefilter element 14, fourgrooves 20 in the embodiment shown, which are distributed symmetrically over the circumference of thefilter element 14. Thegrooves 20 extend up to the tobacco rod end of thefilter element 14, where they are open so that there is a flow connection between thegrooves 20 and thetobacco rod 12. - The
grooves 20 run over the circumference of thefilter plug 16 in an axial direction and end at a rheologically adequate distance from the mouth end of thefilter element 14 and hence at a distance at which neither air nor smoke from thegrooves 20 can directly reach the mouth end of thefilter element 14. - Investigations have shown that the axial length of the
grooves 20 should be less than 80% of the length of thefilter plug 14. About 60% is preferred. - The
grooves 20 have a depth of approximately 1.5 mm and a U-shaped cross section and a width of approximately 2 mm at the circumference. - The
filter element 14 is surrounded in the usual way by a tippingpaper 22, which is provided in the embodiment shown with two circumferential parallel rows of ventilation holes 24. A larger or smaller number of rows of ventilation holes can also be provided or the tippingpaper 22 can be inherently porous. It is only necessary to ensure that the porosity and/or the number and size of theventilation openings 22 ensure the desired degree of ventilation. - For the arrangement of the plug wrap 18 there are in principle two possibilities, i.e. the use of an air-impermeable paper or an air-permeable paper. In the case of use of an air-impermeable paper as
plug wrap 18, ventilation air flows through theventilation openings 24 when smoking the cigarette into thegrooves 20 and then from thegrooves 20 toward tobacco rod, where the direction is reversed and the ventilation air then flows, together with the smoke from thetobacco rod 12, through thefilter plug 16 into the smoker's mouth. - If the plug wrap is air-permeable, either inherently porous or provided with ventilation openings, then an adjustable portion of ventilation air flows by this flow path through the air-permeable plug wrap into the filter and to the mouth of the smoker. This is in addition to the air flowing through the
grooves 20. In this way the dilution of the smoke can be adjusted by air ventilation in two places, i.e. firstly by ventilation through the tippingpaper 22 and along thegrooves 20, and secondly by ventilation air which enters directly through theplug wrap 18 into thefilter plug 16. - If necessary, further short grooves open only to the mouth side of the
filter 14 can be impressed into the exterior surface of the tippingpaper 22. These have no rheological function, since they are not connected with theventilation zone 24, but only alert the smoker to the presence of grooves in thefilter element 14. -
FIG. 2 shows a graph of the effect of the filter ventilation on the CO/tar ratio with a filter in accordance with the invention from conventional cellulose acetate filter tow, an air-impermeable plug wrap and fourgrooves 20 with the above dimensions, which are symmetrically distributed over the circumference of thefilter plug 16 and which, commencing from the tobacco end, extend over 60% of the length of thefilter element 14. - In experiments the ventilation of the
filter element 14 was varied, namely from zero to a maximum ventilation degree of 70%. For products of 3 mg or less it is necessary, in order to obtain the required ventilation level, to use additional on machine laser perforation, as well as pre-perforated tipping. This increased ventilation level also helps reduce cigarette pressure drop. The reduction in CO/tar ratio obtained is balanced with the level of ventilation used. - In
FIG. 2 the full circles indicate the measured values for a conventional filter made from monoacetate filter tow without grooves, while the squares describe the measured values for afilter element 14 in accordance with the invention with the structure and the same dimensions as the comparison filter described above. - One can recognise very well that the
filter element 14 in accordance with the invention reduces the CO content of the smoke relative to the delivered tar and hence the CO/tar ratio from about 1.4 to about 0.7, while through ventilation alone, and hence without use of grooves, the CO/tar ratio can be lowered to only to about 1.12. - Thus the CO/tar ratio can be reduced to below the limit set by the new regulations with the
filter element 14 in accordance with the invention by the appropriate selection of a suitable degree of ventilation for the tippingpaper 22. - Additional investigations of cigarettes with filters according to this invention showed that these results were confirmed also for different tobacco blends in the tobacco section of the cigarette. In Tables 1-3 the results are shown for the tobacco column of three commercially available cigarettes to which the filter of this invention was added. The corresponding cigarettes with conventional filters gave tar levels of about 10 mg, 6 mg and 3 mg respectively. The measurements were done following DIN and ISO standards.
- The filters used for these measurements had the following parameters of the grooves: 4 grooves, 17 mm long, about 1.5 mm wide and 0.5-1 mm deep. The plug wrap was air impermeable and not additionally ventilated.
- The findings show clearly that the filters of this invention (named EF) made it possible to produce cigarettes with comparable pressure drops to the cigarettes with standard filters (named SF) by adjusting the ventilation level, but with clearly reduced CO/tar ratios.
TABLE 1 SF EF EF EF EF EF Pressure drop filter 72 76 76 74 73 72 in mm(H2O) Filter ventilation 22.6 0.0 12.0 51.8 57.2 62.1 tar in mg 10.25 12.4 11.7 8.8 7.2 5.7 CO in mg 11.21 13.3 12.1 6.7 4.5 2.9 Pressure drop 117 137 121 104 93 93 cigarette in mm(H2O) CO/tar 1.09 1.07 1.03 0.76 0.63 0.51 -
TABLE 2 SF EF EF EF EF Pressure drop filter 108 90 89 91 89 in mm(H2O) Filter ventilation 43.0 0.0 50.6 58.3 69.1 tar in mg 5.6 11.4 7.8 6.1 4.3 CO in mg 6.7 13.1 5.8 3.5 1.8 Pressure drop cigarette 112 144 114 110 107 in mm(H2O) CO/tar 1.19 1.15 0.74 0.57 0.42 -
TABLE 3 SF EF EF EF EF Pressure drop filter 124 100 98 99 98 in mm(H2O) Filter ventilation 56.7 0.0 45.2 51.1 62.5 tar in mg 3.33 8.8 6.3 5.2 4.4 CO in mg 4.24 11.3 5.4 3.6 2.6 Pressure drop cigarette 107 144 125 121 120 in mm(H2O) CO/tar 1.27 1.28 0.86 0.69 0.59 -
FIG. 3 shows in cross section afilter element 14 of the invention, where like parts are labelled in accordance withFIG. 1 , attached to atobacco rod 12. The plug wrap 18 used to overlie thefilter plug 16 includes a portion that has particulate activated carbon adhered thereto in theregion 26.Grooves 20 are formed in theplug wrap 18 after the plug wrap is wrapped around thefilter plug 16. The filter element is thus an integral element. - An alternative embodiment along the same theme is shown in
FIG. 4 . However, in this embodiment the filter element comprises three sections: a grooved section in whichgrooves 20 are formed in the surface thereof, aDalmatian carbon section 28 comprising particles of activated carbon dispersed in cellulose acetate tow, and a conventional celluloseacetate tow section 30. The three sections may be joined together by one plug wrap which is mouldable to produce the grooves of the grooved section. Alternatively, the grooves are formed in the surface of either a self-sustaining non-wrapped acetate (NWA) section or a plug wrap enwrapping a cellulose acetate section. The three sections are then aligned together and then overwrapped with a further plug wrap (not shown). - The embodiments of
FIGS. 3 and 4 avoid the problem of having to mould grooves into a filter section containing particulate matter, during which moulding there may be adverse effects on the particulate matter if contacted with heating elements. However, it is possible to thermally form grooves in a carbon-containing section, particularly if use is made of a thermoformable plugwrap, and such is an option open to the cigarette designer. - In addition, the presence of additive material affects other vapour phase constitutents and can be particularly advantageous for the selective removal of some of those compounds on the Hoffmann analyte list (see Hoffmann, D., Hoffmann, I., “Tobacco Smoke Components”, Beitrage ziir Tabakforschung International 18 (1998) 49).
Claims (24)
1. A smoking article incorporating a filter element (14) comprising a filter plug (16) of homogeneous filtration material, a plug wrap (18) overwrapping the filter plug (16), circumferentially spaced grooves extending longitudinally of the filter plug (16) wherein said grooves run over the circumference of the filter plug (16), and a ventilating tipping paper interconnecting the filter element (14) to a tobacco rod (12), a number of grooves (20) being open on the side of the tobacco rod (12) and extending continuously only over a part of the length of the filter element (14), and hence not up to the mouth end of the filter element (14), which grooves (20) are axially aligned with respect to the filter axis, in to which axially extending grooves (20) ventilating air enters via overlying ventilating tipping paper, and any mouth end extending groove not being ventilated.
2. A smoking article in accordance with claim 1 , characterised in that the filtration material of filter plug (16) is homogeneous over the full length of the filter plug (16).
3. A smoking article in accordance with claim 1 , characterised in that the grooves (20) extend over a maximum of 80% of the length of the filter plug (16).
4. A smoking article in accordance with claim 1 , characterised in that the length of the grooves (20) amounts to about 40 to 70%, in particular about 55 to 65% of the length of the filter plug (16).
5. A smoking article in accordance with claim 4 , characterised in that the length of the grooves (20) amounts to 55 to 65% of the length of the filter plug (16).
6. A smoking article in accordance with claim 1 , characterised in that two to ten grooves (20) are provided.
7. A smoking article in accordance with claim 6 , characterised in that three to five grooves are provided.
8. A smoking article in accordance with claim 7 , characterised in that four grooves are provided.
9. A smoking article in accordance with claim 1 , characterised in that the grooves (20) are distributed symmetrically over the circumference of the filter plug (16).
10. A smoking article in accordance with claim 1 , characterised in that the grooves (20) are V-shaped or U-shaped.
11. A smoking article in accordance with claim 1 , characterised in that the grooves have a depth from 0.5 to 2 mm.
12. A smoking article in accordance with claim 1 , characterised in that the grooves (20) at the circumference have a width of 1 to 3 mm.
13. A smoking article in accordance with claim 12 , characterised in that the grooves (20) at the circumference have a width of from 1.5 to 2.5 mm.
14. A smoking article in accordance with claim 1 , characterised in that the filter plug (16) consists of filter tow made of cellulose acetate.
15. A smoking article in accordance with claim 14 , characterised in that the filter plug (16) contains additives such as activated charcoal, zeolites, Duolite or flavour-altering additives.
16. A smoking article in accordance with claim 1 , characterised in that the plug wrap (18) is air impermeable.
17. A smoking article in accordance with claim 1 , characterised in that the plug wrap is porous and/or provided with ventilation holes.
18. A smoking article in accordance with claim 1 , characterised in that the tipping paper (22) is porous.
19. A smoking article in accordance with claim 1 , characterised in that the tipping paper (22) is provided with ventilation openings (24) by mechanical or electrostatic means or by laser beams.
20. A smoking article in accordance with claim 1 , characterised in that the degree of ventilation of the tipping paper (22) lies between 30 and 80%, more particularly between 40 and 70%.
21. A smoking article in accordance with claim 20 , characterised in that the degree of ventilation of the tipping paper (22) lies between 40 and 70%.
22. A smoking article in accordance with claim 1 , characterised in that additional, short grooves intended as indication for the existence of the grooves (20) are provided on the mouth side of the filter plug (16).
23. A smoking article comprising a cylindrical filter plug (16) of homogeneous filtration material, a plug wrap (18) for the filter plug (16), grooves (20) extending longitudinally along the filter plug (16) also impressed into the plug wrap (18), and a tipping paper for connecting the filter plug (16) to a tobacco rod (12), characterised in that all grooves (20) are open on the side of the tobacco rod (12) and extend continuously only over a part of the length of the filter plug (16), and hence not up to the mouth end of the filter plug (16) and that all grooves (20) are covered with the ventilated tipping paper (22).
24. Use of a smoking article in accordance with claim 1 for the reduction of the CO/tar ratio as a function of the filter ventilation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/870,166 US20100319718A1 (en) | 2001-12-18 | 2010-08-27 | Ventilated smoking article |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01129382.6 | 2001-12-18 | ||
EP01129382A EP1321050B1 (en) | 2001-12-18 | 2001-12-18 | Filter for a smoking article |
PCT/GB2002/005603 WO2003051144A1 (en) | 2001-12-18 | 2002-12-11 | Ventilated smoking article |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/870,166 Division US20100319718A1 (en) | 2001-12-18 | 2010-08-27 | Ventilated smoking article |
Publications (1)
Publication Number | Publication Date |
---|---|
US20050076927A1 true US20050076927A1 (en) | 2005-04-14 |
Family
ID=8179494
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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US10/499,281 Abandoned US20050076927A1 (en) | 2001-12-18 | 2002-12-11 | Ventilated smoking article |
US12/870,166 Abandoned US20100319718A1 (en) | 2001-12-18 | 2010-08-27 | Ventilated smoking article |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/870,166 Abandoned US20100319718A1 (en) | 2001-12-18 | 2010-08-27 | Ventilated smoking article |
Country Status (30)
Country | Link |
---|---|
US (2) | US20050076927A1 (en) |
EP (2) | EP1321050B1 (en) |
JP (1) | JP4015999B2 (en) |
KR (1) | KR100737573B1 (en) |
CN (1) | CN100379364C (en) |
AP (1) | AP1915A (en) |
AR (1) | AR037903A1 (en) |
AT (1) | ATE341234T1 (en) |
AU (1) | AU2002350932C1 (en) |
BR (1) | BR0215033B1 (en) |
CA (1) | CA2470198C (en) |
CO (1) | CO5590868A2 (en) |
DE (1) | DE50111161D1 (en) |
DK (1) | DK1321050T3 (en) |
EA (1) | EA007110B1 (en) |
EG (1) | EG23225A (en) |
ES (1) | ES2269284T3 (en) |
GE (1) | GEP20063756B (en) |
HK (1) | HK1076686A1 (en) |
HR (1) | HRP20040509A2 (en) |
HU (1) | HUP0402618A3 (en) |
IL (1) | IL162446A0 (en) |
MX (1) | MXPA04006078A (en) |
OA (1) | OA12741A (en) |
PL (1) | PL197771B1 (en) |
RS (1) | RS50890B (en) |
TW (1) | TWI323646B (en) |
UA (1) | UA76567C2 (en) |
WO (1) | WO2003051144A1 (en) |
ZA (1) | ZA200404588B (en) |
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US20100059075A1 (en) * | 2008-09-09 | 2010-03-11 | Steve Woodson | Ventilated smoking material perforation apparatus and method |
US20100059072A1 (en) * | 2008-09-09 | 2010-03-11 | Steve Woodson | Ventilated smoking material perforation apparatus, method and product |
US7874296B1 (en) * | 2006-07-26 | 2011-01-25 | Mohammad Said Saidi | Cigarette gas filter |
US20110232655A1 (en) * | 2010-03-26 | 2011-09-29 | Philip Morris Usa Inc. | Smoking article including alkanoylated glycoside and method of making |
RU2472401C2 (en) * | 2010-08-30 | 2013-01-20 | Владимир Владимирович Сарычев | Cigarette filter with variable filtration degree |
KR20150119863A (en) * | 2013-02-27 | 2015-10-26 | 필립모리스 프로덕츠 에스.에이. | Smoking article with colour shifting marking |
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US20150351451A1 (en) * | 2012-10-03 | 2015-12-10 | British American Tobacco (Investments) Limited | Smoking article and a method of manufacturing a smoking article |
US9497991B2 (en) | 2011-11-07 | 2016-11-22 | Philip Morris Products S.A. | Smoking article with colour change segment |
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GB0715172D0 (en) | 2007-08-03 | 2007-09-12 | British American Tobacco Co | Filter and method for making a filter for a cigarette |
US8079369B2 (en) | 2008-05-21 | 2011-12-20 | R.J. Reynolds Tobacco Company | Method of forming a cigarette filter rod member |
WO2009143338A2 (en) | 2008-05-21 | 2009-11-26 | R.J. Reynolds Tobacco Company | Apparatus and associated method for forming a filter component of a smoking article and smoking articles made therefrom |
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CN102144811B (en) * | 2011-04-13 | 2013-04-03 | 南通烟滤嘴有限责任公司 | Cigarette filter containing patterned groove cellulose paper and preparation method thereof |
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TWI629008B (en) * | 2012-10-22 | 2018-07-11 | 菲利浦莫里斯製品股份有限公司 | Filter segment comprising an acetate salt and glycerine |
ITBO20130640A1 (en) * | 2013-11-25 | 2015-05-26 | Gd Spa | FILTERING ELEMENT AND SMOKE ARTICLE INCLUDING THIS FILTER ELEMENT. |
BR112018073024B1 (en) * | 2016-06-09 | 2022-12-20 | Philip Morris Products S.A. | APPARATUS AND METHOD FOR PRODUCING A SEMI-FINISHED TIE PAPER TEMPLATE FOR MAKING TIE PAPER FOR COLUMN-SHAPED ARTICLES SUCH AS SMOKING ARTICLES |
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-
2001
- 2001-12-18 AT AT01129382T patent/ATE341234T1/en active
- 2001-12-18 EP EP01129382A patent/EP1321050B1/en not_active Expired - Lifetime
- 2001-12-18 ES ES01129382T patent/ES2269284T3/en not_active Expired - Lifetime
- 2001-12-18 DK DK01129382T patent/DK1321050T3/en active
- 2001-12-18 DE DE50111161T patent/DE50111161D1/en not_active Expired - Lifetime
-
2002
- 2002-11-12 UA UA20040705881A patent/UA76567C2/en unknown
- 2002-12-11 EA EA200400786A patent/EA007110B1/en not_active IP Right Cessation
- 2002-12-11 HU HU0402618A patent/HUP0402618A3/en unknown
- 2002-12-11 AP APAP/P/2004/003057A patent/AP1915A/en active
- 2002-12-11 IL IL16244602A patent/IL162446A0/en unknown
- 2002-12-11 GE GE5660A patent/GEP20063756B/en unknown
- 2002-12-11 US US10/499,281 patent/US20050076927A1/en not_active Abandoned
- 2002-12-11 CA CA002470198A patent/CA2470198C/en not_active Expired - Fee Related
- 2002-12-11 EP EP02785645A patent/EP1458253A1/en not_active Withdrawn
- 2002-12-11 BR BRPI0215033-6A patent/BR0215033B1/en not_active IP Right Cessation
- 2002-12-11 PL PL370700A patent/PL197771B1/en unknown
- 2002-12-11 MX MXPA04006078A patent/MXPA04006078A/en active IP Right Grant
- 2002-12-11 KR KR1020047009377A patent/KR100737573B1/en not_active IP Right Cessation
- 2002-12-11 WO PCT/GB2002/005603 patent/WO2003051144A1/en active Application Filing
- 2002-12-11 CN CNB028253051A patent/CN100379364C/en not_active Expired - Fee Related
- 2002-12-11 RS YUP-509/04A patent/RS50890B/en unknown
- 2002-12-11 AU AU2002350932A patent/AU2002350932C1/en not_active Revoked
- 2002-12-11 OA OA1200400168A patent/OA12741A/en unknown
- 2002-12-11 JP JP2003552083A patent/JP4015999B2/en not_active Expired - Fee Related
- 2002-12-17 TW TW091136325A patent/TWI323646B/en not_active IP Right Cessation
- 2002-12-18 AR ARP020104947A patent/AR037903A1/en active IP Right Grant
- 2002-12-18 EG EG2002121371A patent/EG23225A/en active
-
2004
- 2004-06-07 HR HR20040509A patent/HRP20040509A2/en not_active Application Discontinuation
- 2004-06-09 ZA ZA2004/04588A patent/ZA200404588B/en unknown
- 2004-06-18 CO CO04057551A patent/CO5590868A2/en active IP Right Grant
-
2005
- 2005-10-03 HK HK05108757A patent/HK1076686A1/en not_active IP Right Cessation
-
2010
- 2010-08-27 US US12/870,166 patent/US20100319718A1/en not_active Abandoned
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US7874296B1 (en) * | 2006-07-26 | 2011-01-25 | Mohammad Said Saidi | Cigarette gas filter |
US20100059075A1 (en) * | 2008-09-09 | 2010-03-11 | Steve Woodson | Ventilated smoking material perforation apparatus and method |
US20100059072A1 (en) * | 2008-09-09 | 2010-03-11 | Steve Woodson | Ventilated smoking material perforation apparatus, method and product |
US10226067B2 (en) * | 2010-03-26 | 2019-03-12 | Philip Morris Usa Inc. | Smoking article including alkanoylated glycoside and method of making |
JP2013523113A (en) * | 2010-03-26 | 2013-06-17 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Smoking articles containing alkanoylated glycosides and methods of making |
US9034106B2 (en) * | 2010-03-26 | 2015-05-19 | Philip Morris Usa Inc. | Smoking article including alkanoylated glycoside |
US20150223518A1 (en) * | 2010-03-26 | 2015-08-13 | Philip Morris Usa Inc. | Smoking article including alkanoylated glycoside and method of making |
US20110232655A1 (en) * | 2010-03-26 | 2011-09-29 | Philip Morris Usa Inc. | Smoking article including alkanoylated glycoside and method of making |
RU2472401C2 (en) * | 2010-08-30 | 2013-01-20 | Владимир Владимирович Сарычев | Cigarette filter with variable filtration degree |
US9497991B2 (en) | 2011-11-07 | 2016-11-22 | Philip Morris Products S.A. | Smoking article with colour change segment |
RU2605054C2 (en) * | 2012-10-03 | 2016-12-20 | Бритиш Америкэн Тобэкко (Инвестментс) Лимитед | Smoking article and method for manufacturing thereof |
US20150351451A1 (en) * | 2012-10-03 | 2015-12-10 | British American Tobacco (Investments) Limited | Smoking article and a method of manufacturing a smoking article |
US9861123B2 (en) * | 2012-10-03 | 2018-01-09 | British American Tobacco (Investments) Limited | Smoking article and a method of manufacturing a smoking article |
KR20150119863A (en) * | 2013-02-27 | 2015-10-26 | 필립모리스 프로덕츠 에스.에이. | Smoking article with colour shifting marking |
US20160007647A1 (en) * | 2013-02-27 | 2016-01-14 | Philip Morris Products, S.A. | Smoking article with colour shifting marking |
KR20150119864A (en) * | 2013-02-27 | 2015-10-26 | 필립모리스 프로덕츠 에스.에이. | Smoking article having hidden indicia |
KR102273259B1 (en) | 2013-02-27 | 2021-07-07 | 필립모리스 프로덕츠 에스.에이. | Smoking article having hidden indicia |
KR102275293B1 (en) | 2013-02-27 | 2021-07-13 | 필립모리스 프로덕츠 에스.에이. | Smoking article with colour shifting marking |
US12114691B2 (en) * | 2013-02-27 | 2024-10-15 | Philip Morris Products S.A. | Smoking article with colour shifting marking |
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Legal Events
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AS | Assignment |
Owner name: BRITISH AMERICAN TOBACCO (INVESTMENTS) LIMTED, UNI Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SCHLUTER, ADOLF;GRZONKA, HORST;REEL/FRAME:017953/0508;SIGNING DATES FROM 20040625 TO 20040705 |
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STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |