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US2060047A - Method of preparing artificial filaments - Google Patents

Method of preparing artificial filaments Download PDF

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Publication number
US2060047A
US2060047A US510844A US51084431A US2060047A US 2060047 A US2060047 A US 2060047A US 510844 A US510844 A US 510844A US 51084431 A US51084431 A US 51084431A US 2060047 A US2060047 A US 2060047A
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United States
Prior art keywords
filaments
cellulose
insoluble
salt
spinning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US510844A
Inventor
Dreyfus Camille
Whitehead William
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Corp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Corp filed Critical Celanese Corp
Priority to US510844A priority Critical patent/US2060047A/en
Priority to GB1141/32A priority patent/GB395380A/en
Application granted granted Critical
Publication of US2060047A publication Critical patent/US2060047A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof

Definitions

  • This invention relates to the preparation of artificial filaments, yarns and the like and relates more particularly to the preparation of yarns having a pleasing appearance and improved tex- 5 tile properties.
  • An object of our invention is to prepare artificial filaments having improved appearance and other desirable properties and which contain a water-insoluble soap or salt of a higher fatty acid. Other objects of our invention will appear from the following detailed description.
  • yarns containing the pigment-like materials formerly proposed are quite abrasive and cut the guides, knitting needles. and other parts of textile apparatus with which they come We have found that yarn containing the water-insoluble salts of higher fatty acids, such as zinc stearate have little or no more abrasive properties than yarn not containing such salts.
  • the filaments made or treated in accordance with this invention may be of low denier which are associated together to formyarn, or the filaments may be heavier such as bristles, artificial horsehair and straw.
  • Such filaments may be of the reconstituted. cellulose type formed by the Chardonnet, viscose or cuprammonium process, but this invention is particularly applicable to filaments containing organic derivatives of cellulose such as organic esters of cellulose and. cellulose ethers. Examples of such organic esters of cellulose are cellulose acetate, cellulose formate, cellulose propionate and cellulose butyrate, while examples of cellulose ethers are ethyl cellulose, methyl cellulose and benzyl cellulose.
  • the filaments containing the organic derivative higher fatty acid is added to the spinning dope,
  • cellulose may be prepared by dissolving the -organic derivative in a volatile solvent such as acetone and extruding such solutions through fine orifices into an evaporative atmosphere, as
  • a finely divided water-insoluble soap or salt of a higher fatty acid may be used, examples of which are the stearate, oleate, palmitate, cerotate, elaidate or carnaubate of zinc, aluminum, magnesium, calcium, strontium and barium. A mixture of two or more of these may be used.
  • the insoluble soap or salt of the higher fatty acid is incorporated in the dope or'spinning solution containing the cellulose compound.
  • theamount of such salt added is from 0.1 to 10% of the weight of the cellulose compound present in the finished 20 yarn.
  • the soap'or fatty acid salt is preferably in very fine form, the particles having a diame ter of less than 0.1 to 5 microns and preferably less than 1 or 2 microns for increased covering power. This fine size may be attained by grinding the insoluble soap either with wateror part of the spinning solution or the solvent used in the spinning solution in a ball mill or colloid mill.
  • the ground material is then added to the solution of the derivative of cellulose and to which may also be added diethylene glycol, heavy white mineral oil, olive oil, castor oil or other oils.
  • the spinning solution containing the pigment is then preferably thoroughly mixed and subjectedto the usual filtration before spinning.
  • the addition of the water-insoluble soap to the spinning dope at any stage of the filtration process or even after completion of filtration is not excluded.
  • the water-insoluble soap or salt of the 40 a soap that is not soluble in the solvent for the spinning dope is preferably selected.
  • the finely divided water-insoluble soap is incorporated in the yarns or filaments by treating such yarns or filaments after their formation either in the form of banks or in the form of woven or knitted fabric with a suspension of such soap in the presence of a swelling or penetrating agent for the cellulosic material of which such filaments are composed which causes the insoluble soap to become disseminated throughout the filaments.
  • a swelling or penetrating agent for the cellulosic material of which such filaments are composed which causes the insoluble soap to become disseminated throughout the filaments.
  • the swelling agent employed may be an aqueous solution of acetone, acetic acid, thiocy- 1 anates of sodium, potassium or ammonium, diacetone alcohol or any other suitable swelling agent.
  • Filaments or yarns made in accordance with this invention have a subdued lustre and increased opacity and covering power, the amount of which depends upon the fineness of the size of the insoluble soap or salt of higher fatty acid particles and the amount employed.
  • Yarns made in accordance with this invention have highly improved textile properties, as'is shown by the fact that they can be knitted to form circular knit or warp knit fabrics having many wales and courses and which are free of distortions and pin holes. Moreover such yarns may be woven to form fabrics which are more free of warp streaks and weft bars.
  • Yarns prepared by our method may be wound and twisted more readily and form cones or other packages which do not tend to collapse.
  • Heavier filaments such as bristles, straw and the like when made in accordance with this invention have improved knotting properties.
  • yarns prepared by our method do not cut the guides, reeds, knitting needles and other parts of apparatus with which they come in contact during textile operations.
  • Zinc stearate and the other insoluble soaps have a low specific gravity so that they do not tend to readily separate from the spinning solutions or dopes containing them, which is a great advantage in storing such dopes.
  • Example One (1) part by weight of an acetone soluble cellulose acetate is dissolved in three (3) parts by weight of acetone and to this is added one hundredth (0.01) part by weight of zinc stearate in a small amount of water or acetone preferably containing cellulose acetate.
  • This dispersion may be obtained by grinding the zinc stearate with the liquid, to which granules or fibers of cellulose acetate have preferably been added, in a colloid mill or ball mill so that the most of the particles have a size of less than 1 micron in diameter.
  • the mass is thoroughly mixed and then filtered.
  • the filtered solution is then extruded through the orifices of a. spinneret into a drying evaporative atmosphere and the filaments are drawn off and twisted together to form yarn which is wound.
  • the yarn so formed has all the desirable properties above described.
  • olive oil or diethylene glycol or a mixture of the two in amounts of 1 to 5% of the weight of the cellulose acetate present may be added to the solution of the cellulose acetate prior to spinning. Also instead of adding the finely divided zinc stearate to the spinning solution before the filtration, it may be added after such filtration.
  • Process for delustering artificial textile materials containing cellulose acetate which comprises fixing a water-insoluble zinc salt of a higher fatty acid in said materials by treating the same after their formation with a swelling agent and with a suspension of the water-insoluble zinc salt in the absence of a fixing agent.
  • Process for delustering artificial textile materials containing cellulose acetate which comprises fixing zinc stearate in said materials by treating the same after their formation with a suspension of zinc stearate in aqueous acetone.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)

Description

in contact.
Patented Nov. 10, 1936 UNITED, STATES PATENT OFFICE METHOD OF PREPARING ARTIFICIAL FILAMENTS tion of Delaware No Drawing. Application January 23, 1931, Serial No. 510,844
3 Claims. (Cl. 28-1) This invention relates to the preparation of artificial filaments, yarns and the like and relates more particularly to the preparation of yarns having a pleasing appearance and improved tex- 5 tile properties.
An object of our invention is to prepare artificial filaments having improved appearance and other desirable properties and which contain a water-insoluble soap or salt of a higher fatty acid. Other objects of our invention will appear from the following detailed description.
It has been previously proposed to incorporate inorganic pigment-like material in artificial yarn to subdue the lustre and increase the opacity thereof. In commercial. processes involving the use of such pigments, many considerations enter so that the choice of a commercially suitable pigment is quite difiicult. We have found that such pigment must grind easily, must have a low specific gravity so that it does not tend to separate out readily from the spinning solution to which it is added, and preferably should be of light color. We have found that the water-insoluble salts of the higher fatty acids, such as zinc stearate, meet these requirements.
Moreover yarns containing the pigment-like materials formerly proposed are quite abrasive and cut the guides, knitting needles. and other parts of textile apparatus with which they come We have found that yarn containing the water-insoluble salts of higher fatty acids, such as zinc stearate have little or no more abrasive properties than yarn not containing such salts.
In accordance with our invention we prepare artificial filaments containing cellulosic materials which have improved properties by incorporating therein a finely divided water-insoluble soap or salt of a higher fatty acid.
The filaments made or treated in accordance with this invention may be of low denier which are associated together to formyarn, or the filaments may be heavier such as bristles, artificial horsehair and straw. Such filaments may be of the reconstituted. cellulose type formed by the Chardonnet, viscose or cuprammonium process, but this invention is particularly applicable to filaments containing organic derivatives of cellulose such as organic esters of cellulose and. cellulose ethers. Examples of such organic esters of cellulose are cellulose acetate, cellulose formate, cellulose propionate and cellulose butyrate, while examples of cellulose ethers are ethyl cellulose, methyl cellulose and benzyl cellulose. The filaments containing the organic derivative higher fatty acid is added to the spinning dope,
of cellulose may be prepared by dissolving the -organic derivative in a volatile solvent such as acetone and extruding such solutions through fine orifices into an evaporative atmosphere, as
in dry spinning, or into a precipitating bath, as 5 in wet spinning.
As stated, we incorporate in the filaments a finely divided water-insoluble soap or salt of a higher fatty acid. Any suitable insoluble soap or salt of a higher fatty acid may be used, examples of which are the stearate, oleate, palmitate, cerotate, elaidate or carnaubate of zinc, aluminum, magnesium, calcium, strontium and barium. A mixture of two or more of these may be used.
In one form of. our invention the insoluble soap or salt of the higher fatty acid is incorporated in the dope or'spinning solution containing the cellulose compound. Generally theamount of such salt added is from 0.1 to 10% of the weight of the cellulose compound present in the finished 20 yarn. The soap'or fatty acid salt is preferably in very fine form, the particles having a diame ter of less than 0.1 to 5 microns and preferably less than 1 or 2 microns for increased covering power. This fine size may be attained by grinding the insoluble soap either with wateror part of the spinning solution or the solvent used in the spinning solution in a ball mill or colloid mill. The ground material is then added to the solution of the derivative of cellulose and to which may also be added diethylene glycol, heavy white mineral oil, olive oil, castor oil or other oils. The spinning solution containing the pigment is then preferably thoroughly mixed and subjectedto the usual filtration before spinning. However the addition of the water-insoluble soap to the spinning dope at any stage of the filtration process or even after completion of filtration is not excluded. When the water-insoluble soap or salt of the 40 a soap that is not soluble in the solvent for the spinning dope is preferably selected.
In another form of our invention, the finely divided water-insoluble soap is incorporated in the yarns or filaments by treating such yarns or filaments after their formation either in the form of banks or in the form of woven or knitted fabric with a suspension of such soap in the presence of a swelling or penetrating agent for the cellulosic material of which such filaments are composed which causes the insoluble soap to become disseminated throughout the filaments. Thusif the filaments are made of cellulose acetate, the swelling agent employed may be an aqueous solution of acetone, acetic acid, thiocy- 1 anates of sodium, potassium or ammonium, diacetone alcohol or any other suitable swelling agent.
Filaments or yarns made in accordance with this invention have a subdued lustre and increased opacity and covering power, the amount of which depends upon the fineness of the size of the insoluble soap or salt of higher fatty acid particles and the amount employed. Yarns made in accordance with this invention have highly improved textile properties, as'is shown by the fact that they can be knitted to form circular knit or warp knit fabrics having many wales and courses and which are free of distortions and pin holes. Moreover such yarns may be woven to form fabrics which are more free of warp streaks and weft bars.
Yarns prepared by our method may be wound and twisted more readily and form cones or other packages which do not tend to collapse. Heavier filaments such as bristles, straw and the like when made in accordance with this invention have improved knotting properties.
Moreover yarns prepared by our method, unlike yarn containing the pigment-like material previously employed, do not cut the guides, reeds, knitting needles and other parts of apparatus with which they come in contact during textile operations. Zinc stearate and the other insoluble soaps have a low specific gravity so that they do not tend to readily separate from the spinning solutions or dopes containing them, which is a great advantage in storing such dopes.
In order further to illustrate our invention, but without being limited thereto, the following specific example is given.
Example One (1) part by weight of an acetone soluble cellulose acetate is dissolved in three (3) parts by weight of acetone and to this is added one hundredth (0.01) part by weight of zinc stearate in a small amount of water or acetone preferably containing cellulose acetate. This dispersion may be obtained by grinding the zinc stearate with the liquid, to which granules or fibers of cellulose acetate have preferably been added, in a colloid mill or ball mill so that the most of the particles have a size of less than 1 micron in diameter. The mass is thoroughly mixed and then filtered. The filtered solution is then extruded through the orifices of a. spinneret into a drying evaporative atmosphere and the filaments are drawn off and twisted together to form yarn which is wound. The yarn so formed has all the desirable properties above described.
If desired olive oil or diethylene glycol or a mixture of the two, in amounts of 1 to 5% of the weight of the cellulose acetate present may be added to the solution of the cellulose acetate prior to spinning. Also instead of adding the finely divided zinc stearate to the spinning solution before the filtration, it may be added after such filtration.
It is to be understood that the foregoing description is given merely by way of illustration and that many variations may be made therein without departing from the spirit of our invention.
Having described our invention, what we desire and claim to secure by Letters Patent is:
1. Process for delustering artificial textile materials containing cellulose acetate, which comprises fixing a water-insoluble zinc salt of a higher fatty acid in said materials by treating the same after their formation with a swelling agent and with a suspension of the water-insoluble zinc salt in the absence of a fixing agent.
2. Process for delustering artificial textile materials containing cellulose acetate, which comprises fixing zinc stearate in said materials by treating-the same after their formation with a swelling agent and with a suspension of zinc stearate in the absence of a fixing agent.
3. Process for delustering artificial textile materials containing cellulose acetate, which comprises fixing zinc stearate in said materials by treating the same after their formation with a suspension of zinc stearate in aqueous acetone.
CAL/ELLE DREYFUS. WILLIAM WHI'IEHEAD.
US510844A 1931-01-23 1931-01-23 Method of preparing artificial filaments Expired - Lifetime US2060047A (en)

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US510844A US2060047A (en) 1931-01-23 1931-01-23 Method of preparing artificial filaments
GB1141/32A GB395380A (en) 1931-01-23 1932-01-14 Improvements in the treatment of artificial filaments, yarns and the like

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2857291A (en) * 1955-04-13 1958-10-21 Rhone Poulenc Sa Treatment of paper
US2966428A (en) * 1956-04-05 1960-12-27 Celanese Corp Heat stable saponified cellulose ester filamentary material and process of making

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4185637A (en) * 1978-05-30 1980-01-29 Ethicon, Inc. Coating composition for sutures
US4532929A (en) * 1984-07-23 1985-08-06 Ethicon, Inc. Dry coating of surgical filaments
US5213236A (en) * 1991-12-06 1993-05-25 Liquid Molding Systems, Inc. Dispensing valve for packaging
US5839614A (en) 1991-12-06 1998-11-24 Aptar Group, Inc. Dispensing package
US5409144A (en) * 1991-12-06 1995-04-25 Liquid Molding Systems Inc. Dispensing valve for packaging
US6079594A (en) * 1997-08-21 2000-06-27 Seaquist Closures Foreign, Inc. Dispensing package with a self-sealing closure constructed from a thermoplastic material
US6530504B2 (en) 2001-03-02 2003-03-11 Seaquist Closures Foreign, Inc. Multiple orifice valve

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2857291A (en) * 1955-04-13 1958-10-21 Rhone Poulenc Sa Treatment of paper
US2966428A (en) * 1956-04-05 1960-12-27 Celanese Corp Heat stable saponified cellulose ester filamentary material and process of making

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Publication number Publication date
GB395380A (en) 1933-07-14

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