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US1993020A - Bimetal thermostat - Google Patents

Bimetal thermostat Download PDF

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Publication number
US1993020A
US1993020A US725116A US72511634A US1993020A US 1993020 A US1993020 A US 1993020A US 725116 A US725116 A US 725116A US 72511634 A US72511634 A US 72511634A US 1993020 A US1993020 A US 1993020A
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Prior art keywords
nickel
expansion
chromium
manganese
carbon
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Expired - Lifetime
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US725116A
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Scott Howard
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CBS Corp
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Westinghouse Electric and Manufacturing Co
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Priority to US725116A priority Critical patent/US1993020A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K5/00Measuring temperature based on the expansion or contraction of a material
    • G01K5/48Measuring temperature based on the expansion or contraction of a material the material being a solid
    • G01K5/56Measuring temperature based on the expansion or contraction of a material the material being a solid constrained so that expansion or contraction causes a deformation of the solid
    • G01K5/62Measuring temperature based on the expansion or contraction of a material the material being a solid constrained so that expansion or contraction causes a deformation of the solid the solid body being formed of compounded strips or plates, e.g. bimetallic strip
    • G01K5/64Details of the compounds system
    • G01K5/66Selection of composition of the components of the system
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H37/00Thermally-actuated switches
    • H01H37/02Details
    • H01H37/32Thermally-sensitive members
    • H01H37/52Thermally-sensitive members actuated due to deflection of bimetallic element
    • H01H2037/526Materials for bimetals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9335Product by special process
    • Y10S428/939Molten or fused coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/125Deflectable by temperature change [e.g., thermostat element]
    • Y10T428/12521Both components Fe-based with more than 10% Ni

Definitions

  • My invention relates to temperature-responsive devicesand more particularly to bimetal thermostats.
  • Anotherobiectof my invention is to provide a bimetal element that shall have good manufacturing characteristics, that is, one which may be easily cold rolled to size without acquiring appreciable curvature, twist or excessive distortion 16 from a plane surface at room temperature.
  • I provide more particularb two iron-alloys which may be welded or otherwise united with each other, the element having the high temperature coeilicient of ex- 20 pansion containing from 26% to 7% of nickel, from 2% to 6% of manganese, from 1/10% to 10% of chromium and from .05% to .25% of carbon with traces of cobalt.
  • the low expansion component is an iron alloy including from 35% 25 to 12% of nickel, from .10% to 35% of cobalt,
  • manganese from .10% to 1.0% manganese, from .10% to 8% of chromium, molybdenum, tungsten or titanium eithensingle or in combination and from .05% to .25% of carbon.
  • the single figure of the drawing illustrates one form of device which may embody the invention, namely, a bimetal strip 11 having a-hi'gh-expansion component 13 and a low-expansion component 15.
  • an alloy of the abovedescribed general composition has somewhat objectionable cold rolling characteristics in that the bimetal takes on a cross curvature or other permanent distortion because of the fact that the 5 high expansion alloy is harder than the low-expansion alloy usually associated therewith, and also because the high-expansion alloy hardens more rapidly when being cold rolled.
  • This disadvantage may be partially corrected without impairing the resistance to corrosion by substituting chromium for part of either the nickel or the manganese in the high-expansion alloy.
  • composition is governed quite closely by the following:
  • %nickel+2.5(%manganese) 2( %chromlum) +l8(%carbon) (Equation 1) should be between 32 to 36, while at the same time, the carbon content .is appreciably less than .3% and preferably is .l%, the nickel content is less than 26% and above 7%, the chromium is of %.nickel, 6% manganese, 4% chromium,
  • a high-expansion component with a low-expansion alloy contaih- Another ing nickel or nickel and cobalt, with the combined nickel and cobalt content ly xbetween 34% and 55%, the major portion of the alloy being iron.
  • Chromium, molybdenum-tungsten or titanium either singly or in combination may be substituted for a part of the nickel content in order to obtain better working qualities and greater strength of the alloy at high temperatures.
  • chromium is somewhat detrimental to the expansion properties of the low expansion component, its effect may be neutralized, at least in part, by an increase in the cobalt content by the amount that the nickel content is decreased when chromium, molybdenum,
  • Equation 2 A concurrent requirement is that, as stated above, the percentage of the nickel plus cobalt should be between 34% and 55%.
  • Table I gives a number of different compositions of ahigh-expansion component, these compositions meeting the requirements set-forth above in Equation 1.
  • Table 11 gives a number of compositions of a low-expansion component meeting the requirement of Equation 2 given above.
  • compositions 1 to 4, inclusive, in Table II will cooperate with any one of the alloys in Table I to give a maximum deilection of a bimetal element including them, at temperatures between zero to C. while alloys 5 to 8, inclusive, of Table II when combined with any one ofthe high-expansion components in Table I will have a maximum deflection over a temperature range of C. to 300 C. or even 400 C.
  • a thermostatic element comprising a pair of cooperating metallic members having diiferent temperature coeflicients of expansion, the high expansion member being an iron-nickel alloy including lesser quantities of manganese, chromium and carbon, the relation between the percentages of nickel, manganese, chromium and carbon being expressed by the formula the value of which should lie between 32 and 36, the nickel content to be between 7% and 26%, the chromium content to be between 10% and .1% and the carbon content to be between .05% and 3%, and the low expansion member being an iron-nickel-cobalt-chromium alloy including minor quantities of manganese and carbon, the relation between the percentages of iron, nickel, manganese, chromium and carbon being expressed by the formula the value of which should lie between .50 and .60
  • thermostatic element comprising a pair of cooperating metallic members having different temperature coeflicients of expansion, the high expansion member being non-magnetic and having substantially the following composition
  • a thermostatic element comprising a pair of cooperating metallic members having different temperature coefficients of expansion, the high expansion member having substantially the following composition,
  • a thermostatic element comprising a pair of cooperating metallic members having different temperature coefiicients of expansion, the high expansion member having substantially the following composition

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Heat Treatment Of Steel (AREA)

Description

March 5, 1935. H. sco'rT 1,993,020
BIMETAL THERMOSTAT Filed May 11, 1934 WITNESSES INVENTOR Howard S0027.
' AZI'TORNE Patented Mar. 5, 1935 UNITED S'lATES PATENT OFFICE inghouse Electric a Manufacturing Company, East Pittsburgh, l'a., a corporation of Pennsylvauia Application May 11, 1934, semi No. 125,116
4Ciaims.
My invention relates to temperature-responsive devicesand more particularly to bimetal thermostats. v
It is an object of my invention to provide a I bimetal thermostat which will have optimum operating characteristics not only as to deflection under changes of temperature, but also as to the maximum temperature to which the device can be safely subjected.
Anotherobiectof my invention is to provide a bimetal element that shall have good manufacturing characteristics, that is, one which may be easily cold rolled to size without acquiring appreciable curvature, twist or excessive distortion 16 from a plane surface at room temperature.
In practicing my invention I provide more particularb two iron-alloys which may be welded or otherwise united with each other, the element having the high temperature coeilicient of ex- 20 pansion containing from 26% to 7% of nickel, from 2% to 6% of manganese, from 1/10% to 10% of chromium and from .05% to .25% of carbon with traces of cobalt. The low expansion component is an iron alloy including from 35% 25 to 12% of nickel, from .10% to 35% of cobalt,
from .10% to 1.0% manganese, from .10% to 8% of chromium, molybdenum, tungsten or titanium eithensingle or in combination and from .05% to .25% of carbon.
30 The single figure of the drawing illustrates one form of device which may embody the invention, namely, a bimetal strip 11 having a-hi'gh-expansion component 13 and a low-expansion component 15.
In my earlier Patent 1,671,490 I have disclosed and claimed a high-expansion component including 10% of nickel and 10% of manganese in combination-with iron and-other metals in minor quantities. I have found, as the result of I 40 further development work on,.bimetals of this general composition that a 10% nickel, 10% manganese iron alloy has rather a poor resistance to corrosion, as well as somewhat unsatisfactory rolling characteristics. I have found that the corrosion resistance is materially improved by an increase in the amount of nickel in the high-expansion component with an accompanying reduction in the amount of manganese present in the alloy.
I have also found that an alloy of the abovedescribed general composition has somewhat objectionable cold rolling characteristics in that the bimetal takes on a cross curvature or other permanent distortion because of the fact that the 5 high expansion alloy is harder than the low-expansion alloy usually associated therewith, and also because the high-expansion alloy hardens more rapidly when being cold rolled. This disadvantage may be partially corrected without impairing the resistance to corrosion by substituting chromium for part of either the nickel or the manganese in the high-expansion alloy.
As a result of numerous experimental compositions and tests on the same I have found that the composition is governed quite closely by the following:
%nickel+2.5(%manganese) 2( %chromlum) +l8(%carbon) (Equation 1) should be between 32 to 36, while at the same time, the carbon content .is appreciably less than .3% and preferably is .l%, the nickel content is less than 26% and above 7%, the chromium is of %.nickel, 6% manganese, 4% chromium,
.l% carbon, the remainder being iron and incldental elements normal in steel. These alloys are non-magnetic.
I prefer to combine such a high-expansion component with a low-expansion alloy contaih- Another ing nickel or nickel and cobalt, with the combined nickel and cobalt content ly xbetween 34% and 55%, the major portion of the alloy being iron. Chromium, molybdenum-tungsten or titanium, either singly or in combination may be substituted for a part of the nickel content in order to obtain better working qualities and greater strength of the alloy at high temperatures. Although chromium is somewhat detrimental to the expansion properties of the low expansion component, its effect may be neutralized, at least in part, by an increase in the cobalt content by the amount that the nickel content is decreased when chromium, molybdenum,
tungsten or titanium or combinations thereof are added. v
I have found that the relation between the amount of chromium or its equivalents and nickel in the low expansion alloy may be set forth in the following equation:
% Fe .50 to .60
(Equation 2) A concurrent requirement is that, as stated above, the percentage of the nickel plus cobalt should be between 34% and 55%.
Table I gives a number of different compositions of ahigh-expansion component, these compositions meeting the requirements set-forth above in Equation 1.
Table I.-Hiah-expanston component Ni 0 M y o 7 o H o n r approxa 0 mum 1 20 Traces 2 o 1 0.1 71.8 2 Z; Traces 3 1 .1 72.9 a 20 Traces 2 4 .1 70.0 4 11s Traces 4 4 .1 10.0 5 1o Traces o 4 .1 10.0 6 7 Traces 6 5 1 81.9
Table 11 gives a number of compositions of a low-expansion component meeting the requirement of Equation 2 given above.
Table IILow-e:cpansion component Mo, W, T1 or e Ni C0 Mn 01' 0 (approximately) 1 a5. 0.1 o. 1 0.1 0.1 64. 0 2 31.9 4.1 .5 .1 .1 63.3 3 20. 12.0 .5 2.0 .1 50.0 4 18.0 2?. 0 .5 s. o 1 54. o 5 28.6 13.4 .s .1 .1 57.3 0 2s. 0 20. 0 s 2. 0 1 54 o 7 17.0 as. 0 s 4 o 1 so. 0 s 12.0 34. 0 .5 0.0 .1 41.0
It may be noted that compositions 1 to 4, inclusive, in Table II will cooperate with any one of the alloys in Table I to give a maximum deilection of a bimetal element including them, at temperatures between zero to C. while alloys 5 to 8, inclusive, of Table II when combined with any one ofthe high-expansion components in Table I will have a maximum deflection over a temperature range of C. to 300 C. or even 400 C.
Various modifications may be made in the device embodying my invention without departing from the spirit and scope thereof, and I desire, therefore, that only such limitations shall be placed thereon as are imposed by the prior art or are set forth in the appended claims.
I claim as my invention:
1. A thermostatic element comprising a pair of cooperating metallic members having diiferent temperature coeflicients of expansion, the high expansion member being an iron-nickel alloy including lesser quantities of manganese, chromium and carbon, the relation between the percentages of nickel, manganese, chromium and carbon being expressed by the formula the value of which should lie between 32 and 36, the nickel content to be between 7% and 26%, the chromium content to be between 10% and .1% and the carbon content to be between .05% and 3%, and the low expansion member being an iron-nickel-cobalt-chromium alloy including minor quantities of manganese and carbon, the relation between the percentages of iron, nickel, manganese, chromium and carbon being expressed by the formula the value of which should lie between .50 and .60
the combined percentage of nickel and cobalt be ing between 34 and 55.
2. A thermostatic element comprising a pair of cooperating metallic members having different temperature coeflicients of expansion, the high expansion member being non-magnetic and having substantially the following composition,
Per cent. Nickel 26. to '7. Manganese 2. to 8. Chr 0.1 to 5. Cobalt Traces Carbon 0.1 Iron and impurities Remainder and the low expansion member having substantially the following composition,
Per cent. Nickel 35. to 12.0 Manganese 0.1 to 1.0 Chromium, tungsten, molybdenum or titanium 0.1 to 8.0 Cobalt 0.1 to 35.0 Carbon 0.05 to 0.25 Iron and impurities Remainder 3. A thermostatic element comprising a pair of cooperating metallic members having different temperature coefficients of expansion, the high expansion member having substantially the following composition,
Per cent. NickeL Manganese 2. Chromium 4 Carbon 0.1 Cobal Traces Iron and impurities-.. Remainder and the low expansion member having substantially the following composition,
Per cent. Nickel 26.0 Cobalt 12.0 Chromium, tungsten, molybdenum.
titanium 2.0 Manganese .5 Carbon .1 Iron and impurities Remainder 4. A thermostatic element comprising a pair of cooperating metallic members having different temperature coefiicients of expansion, the high expansion member having substantially the following composition,
Per cent. Nickel Manganese 6. Chromium 5. Carbon .1 Co Traces Iron and impurities Remainder and the low expansion member having substan- HOWARD SCOTT.
US725116A 1934-05-11 1934-05-11 Bimetal thermostat Expired - Lifetime US1993020A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2516227A (en) * 1945-03-10 1950-07-25 Westinghouse Electric Corp Electroplating of chromiummolybdenum alloys
US2700627A (en) * 1951-07-20 1955-01-25 Harold R Nelson Treatment for commercial bimetals
US3779718A (en) * 1972-10-02 1973-12-18 Chace W M Co Corrosion resistant thermostatic laminate
FR2346812A1 (en) * 1976-04-01 1977-10-28 Rau Fa G HIGH-USE LIMIT BILAME AND PROCESS FOR MANUFACTURING IT
US4366210A (en) * 1980-11-14 1982-12-28 Hood And Co., Inc. Corrosion resistant thermostat metal compositions
US4585707A (en) * 1983-04-29 1986-04-29 Carpenter Technology Corporation High expansion alloy for bimetal strip
EP0659548A1 (en) * 1993-12-27 1995-06-28 Sumitomo Special Metal Co., Ltd. Bimetal

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2516227A (en) * 1945-03-10 1950-07-25 Westinghouse Electric Corp Electroplating of chromiummolybdenum alloys
US2700627A (en) * 1951-07-20 1955-01-25 Harold R Nelson Treatment for commercial bimetals
US3779718A (en) * 1972-10-02 1973-12-18 Chace W M Co Corrosion resistant thermostatic laminate
FR2346812A1 (en) * 1976-04-01 1977-10-28 Rau Fa G HIGH-USE LIMIT BILAME AND PROCESS FOR MANUFACTURING IT
US4131720A (en) * 1976-04-01 1978-12-26 G. Rau Heavy-duty heat-responsive bimetallic material
US4366210A (en) * 1980-11-14 1982-12-28 Hood And Co., Inc. Corrosion resistant thermostat metal compositions
US4585707A (en) * 1983-04-29 1986-04-29 Carpenter Technology Corporation High expansion alloy for bimetal strip
EP0659548A1 (en) * 1993-12-27 1995-06-28 Sumitomo Special Metal Co., Ltd. Bimetal

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