TWI685681B - Infrared diffuser - Google Patents
Infrared diffuser Download PDFInfo
- Publication number
- TWI685681B TWI685681B TW107129768A TW107129768A TWI685681B TW I685681 B TWI685681 B TW I685681B TW 107129768 A TW107129768 A TW 107129768A TW 107129768 A TW107129768 A TW 107129768A TW I685681 B TWI685681 B TW I685681B
- Authority
- TW
- Taiwan
- Prior art keywords
- infrared light
- film
- infrared
- light absorbing
- filter according
- Prior art date
Links
- 239000010408 film Substances 0.000 claims abstract description 91
- 239000002245 particle Substances 0.000 claims abstract description 51
- 239000012788 optical film Substances 0.000 claims abstract description 47
- 238000002834 transmittance Methods 0.000 claims abstract description 26
- 238000010521 absorption reaction Methods 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims description 50
- 239000011521 glass Substances 0.000 claims description 47
- 230000031700 light absorption Effects 0.000 claims description 46
- 229910010272 inorganic material Inorganic materials 0.000 claims description 9
- 239000011147 inorganic material Substances 0.000 claims description 9
- 239000004642 Polyimide Substances 0.000 claims description 7
- 229920001721 polyimide Polymers 0.000 claims description 7
- 239000011368 organic material Substances 0.000 claims description 6
- 229920000515 polycarbonate Polymers 0.000 claims description 6
- 239000004417 polycarbonate Substances 0.000 claims description 6
- 238000005452 bending Methods 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 abstract description 3
- 230000010748 Photoabsorption Effects 0.000 abstract 3
- 239000000975 dye Substances 0.000 description 36
- 239000002105 nanoparticle Substances 0.000 description 15
- 239000011347 resin Substances 0.000 description 14
- 229920005989 resin Polymers 0.000 description 14
- -1 phosphorus ions Chemical class 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 230000002452 interceptive effect Effects 0.000 description 4
- 229910001512 metal fluoride Inorganic materials 0.000 description 4
- 125000005341 metaphosphate group Chemical group 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000035515 penetration Effects 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 239000002612 dispersion medium Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000000411 transmission spectrum Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000002159 nanocrystal Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BHHYHSUAOQUXJK-UHFFFAOYSA-L zinc fluoride Chemical compound F[Zn]F BHHYHSUAOQUXJK-UHFFFAOYSA-L 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- MHABMANUFPZXEB-UHFFFAOYSA-N O-demethyl-aloesaponarin I Natural products O=C1C2=CC=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C MHABMANUFPZXEB-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- DHAHRLDIUIPTCJ-UHFFFAOYSA-K aluminium metaphosphate Chemical compound [Al+3].[O-]P(=O)=O.[O-]P(=O)=O.[O-]P(=O)=O DHAHRLDIUIPTCJ-UHFFFAOYSA-K 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- OYLGJCQECKOTOL-UHFFFAOYSA-L barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 description 1
- 229910001632 barium fluoride Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- ROPDWRCJTIRLTR-UHFFFAOYSA-L calcium metaphosphate Chemical compound [Ca+2].[O-]P(=O)=O.[O-]P(=O)=O ROPDWRCJTIRLTR-UHFFFAOYSA-L 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- LRMHFDNWKCSEQU-UHFFFAOYSA-N ethoxyethane;phenol Chemical compound CCOCC.OC1=CC=CC=C1 LRMHFDNWKCSEQU-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- MRVHOJHOBHYHQL-UHFFFAOYSA-M lithium metaphosphate Chemical compound [Li+].[O-]P(=O)=O MRVHOJHOBHYHQL-UHFFFAOYSA-M 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- RHJYKEDKMHDZBL-UHFFFAOYSA-L metaphosphoric acid (hpo3), magnesium salt Chemical compound [Mg+2].[O-]P(=O)=O.[O-]P(=O)=O RHJYKEDKMHDZBL-UHFFFAOYSA-L 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- FVRNDBHWWSPNOM-UHFFFAOYSA-L strontium fluoride Chemical compound [F-].[F-].[Sr+2] FVRNDBHWWSPNOM-UHFFFAOYSA-L 0.000 description 1
- 229910001637 strontium fluoride Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- VUDJAFZYSMINQA-UHFFFAOYSA-L zinc metaphosphate Chemical compound [Zn+2].[O-]P(=O)=O.[O-]P(=O)=O VUDJAFZYSMINQA-UHFFFAOYSA-L 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
- G02B5/223—Absorbing filters containing organic substances, e.g. dyes, inks or pigments
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Optical Filters (AREA)
Abstract
Description
本發明是有關於一種光學元件,且特別是有關於一種濾光片。The present invention relates to an optical element, and particularly to an optical filter.
目前的行動裝置,例如智慧手機與平板電腦,大多已配備影像感測器(image sensor),以使行動裝置具有影像擷取的功能。上述影像感測器通常是互補式金屬氧化物半導體(Complementary Metal-Oxide-Semiconductor,以下簡稱CMOS)影像感測器(CMOS Image Sensor,CIS),其為一種晶片封裝體(chip package)。CMOS影像感測器所具有的CMOS晶片的響應波長(wavelength of response)不僅涵蓋可見光,而且也涵蓋紅外光以及紫外光。為了避免紅外光以及紫外光干擾影像感測器所擷取的影像,一般影像感測器會加裝濾光片以濾除不必要的紅外光與紫外光。Most current mobile devices, such as smartphones and tablets, have been equipped with an image sensor to enable the mobile device to have an image capturing function. The above image sensor is usually a complementary metal-oxide semiconductor (Complementary Metal-Oxide-Semiconductor, hereinafter referred to as CMOS) image sensor (CMOS Image Sensor, CIS), which is a chip package (chip package). The wavelength of response of the CMOS chip of the CMOS image sensor covers not only visible light, but also infrared light and ultraviolet light. In order to prevent infrared light and ultraviolet light from interfering with the image captured by the image sensor, a filter is generally installed in the image sensor to filter out unnecessary infrared light and ultraviolet light.
一般來說,影像感測器所裝設的紅外光濾光片有兩種:一種是藍玻璃紅外光吸收片,另一種是紅外光吸收樹脂薄膜。藍玻璃紅外光吸收片具有優異的光學表現,能幾乎完全吸收波長在700奈米(nm)至1100奈米範圍內的紅外光,以有效濾除紅外光,且藍玻璃紅外光吸收片還具有良好的可見光穿透率。此外,藍玻璃紅外光吸收片的主要材料為玻璃,所以也具有耐高溫的優點,即藍玻璃紅外光吸收片能夠承受迴焊(reflow)的高溫環境。然而,藍玻璃紅外光吸收片的製造需要進行多道步驟,包括熔解、成型、退火、切割、研拋以及鍍膜等,因此藍玻璃紅外光吸收片具有製造複雜以及不易量產的缺點。Generally speaking, there are two types of infrared light filters installed in the image sensor: one is a blue glass infrared light absorption sheet, and the other is an infrared light absorption resin film. The blue glass infrared light absorption sheet has excellent optical performance, and can almost completely absorb infrared light in the wavelength range of 700 nanometers (nm) to 1100 nanometers to effectively filter out infrared light, and the blue glass infrared light absorption sheet also has Good visible light transmittance. In addition, the main material of the blue glass infrared light absorption sheet is glass, so it also has the advantage of high temperature resistance, that is, the blue glass infrared light absorption sheet can withstand the high temperature environment of reflow (reflow). However, the manufacturing of the blue glass infrared light absorbing sheet requires multiple steps, including melting, forming, annealing, cutting, polishing, and coating. Therefore, the blue glass infrared light absorbing sheet has the disadvantages of complicated manufacturing and difficult mass production.
由於行動裝置所配備的影像感測器為晶片封裝體,其厚度通常小於或等於2公厘(mm),因此影像感測器所採用的紅外光濾光片必須要具有足夠薄的厚度,否則紅外光濾光片無法裝入於影像感測器中。然而,藍玻璃紅外光吸收片的加工困難,導致藍玻璃紅外光吸收片的厚度難以達到影像感測器的要求。加上,藍玻璃紅外光吸收片的主要材料為玻璃,所以藍玻璃紅外光吸收片也跟一般玻璃一樣具有易碎的缺點。縱使藍玻璃紅外光吸收片具有足夠薄的厚度而能裝設於影像感測器內,藍玻璃紅外光吸收片也會因行動裝置不慎遭到撞擊或摔落而容易碎裂。Since the image sensor equipped with the mobile device is a chip package, its thickness is usually less than or equal to 2 millimeters (mm), so the infrared light filter used in the image sensor must have a sufficiently thin thickness, otherwise The infrared filter cannot be installed in the image sensor. However, the processing of the blue glass infrared light absorbing sheet is difficult, and the thickness of the blue glass infrared light absorbing sheet is difficult to meet the requirements of the image sensor. In addition, the main material of the blue glass infrared light absorption sheet is glass, so the blue glass infrared light absorption sheet also has the disadvantage of being fragile like ordinary glass. Even if the blue glass infrared light absorbing sheet has a sufficiently thin thickness to be installed in the image sensor, the blue glass infrared light absorbing sheet may be easily broken due to accidental impact or falling of the mobile device.
紅外光吸收樹脂薄膜具有厚度薄,加工容易與易於大量生產的優點,且紅外光吸收樹脂薄膜的主要材料為高分子材料,所以紅外光吸收樹脂薄膜具有韌性。即使行動裝置不慎遭到撞擊或摔落,行動裝置內的紅外光吸收樹脂薄膜也不會碎裂。然而,紅外光吸收樹脂薄膜的光學表現卻遠不如藍玻璃紅外光吸收片。紅外光吸收樹脂薄膜無法有效吸收700奈米至1100奈米的紅外光,導致紅外光吸收樹脂薄膜會允許部分紅外光穿透,造成影像感測器的影像擷取被紅外光干擾。加上,紅外光吸收樹脂薄膜的主要材料為高分子材料,所以紅外光吸收樹脂薄膜並不具有耐高溫的優點。因此,紅外光吸收樹脂薄膜容易在高溫環境中發生變形或變質。The infrared light absorbing resin film has the advantages of thin thickness, easy processing and easy mass production, and the main material of the infrared light absorbing resin film is a polymer material, so the infrared light absorbing resin film has toughness. Even if the mobile device is accidentally hit or dropped, the infrared light absorbing resin film in the mobile device will not be broken. However, the optical performance of the infrared light absorbing resin film is far inferior to the blue glass infrared light absorbing sheet. The infrared light absorbing resin film cannot effectively absorb infrared light from 700 nanometers to 1100 nanometers. As a result, the infrared light absorbing resin film allows part of the infrared light to penetrate, causing the image capture of the image sensor to be interfered by infrared light. In addition, the main material of the infrared light absorbing resin film is a polymer material, so the infrared light absorbing resin film does not have the advantage of high temperature resistance. Therefore, the infrared light absorbing resin film is easily deformed or deteriorated in a high-temperature environment.
本發明提供一種紅外光濾光片,其不僅能有效濾除波長700奈米至1100奈米範圍內的紅外光,而且還具有足夠薄的厚度,從而適合裝設於現有行動裝置所使用的影像感測器內。The invention provides an infrared light filter, which can not only effectively filter infrared light in the wavelength range of 700 nanometers to 1100 nanometers, but also has a sufficiently thin thickness so as to be suitable for installation in images used in existing mobile devices Inside the sensor.
本發明所提供的紅外光濾光片包括光吸收膜以及第一光學膜(first optical film)。光吸收膜包括結合材料(binder)以及多個紅外光吸收粒子。這些紅外光吸收粒子分布於結合材料內,且皆為無機材料,其中這些紅外光吸收粒子的平均凝聚粒徑(mean agglomerate particle size)小於80奈米。第一光學膜形成於光吸收膜的一側(side),其中紅外光濾光片的厚度介於10微米至500微米之間,而紅外光濾光片的紅外光截通波長(infrared cut-on wavelength)介於600奈米至650奈米之間。紅外光濾光片在波長700奈米至1100奈米範圍內的平均穿透率小於1%,而在波長430奈米至580奈米範圍內的平均穿透率大於75%。The infrared light filter provided by the present invention includes a light absorption film and a first optical film. The light-absorbing film includes a binder and a plurality of infrared light-absorbing particles. These infrared light absorbing particles are distributed in the bonding material, and are all inorganic materials, wherein the average agglomerate particle size of these infrared light absorbing particles is less than 80 nanometers. The first optical film is formed on the side of the light absorbing film, wherein the thickness of the infrared filter is between 10 microns and 500 microns, and the infrared cut-off wavelength of the infrared filter is (infrared cut- on wavelength) between 600 nm and 650 nm. The average transmittance of the infrared filter in the wavelength range of 700 nm to 1100 nm is less than 1%, and the average transmittance in the wavelength range of 430 nm to 580 nm is greater than 75%.
在本發明的一實施例中,這些紅外光吸收粒子為非晶相顆粒(amorphous particle)。In an embodiment of the invention, the infrared light absorbing particles are amorphous particles.
在本發明的一實施例中,這些紅外光吸收粒子與結合材料之間的重量百分比介於1%至80%。In an embodiment of the invention, the weight percentage between the infrared light absorbing particles and the bonding material is between 1% and 80%.
在本發明的一實施例中,這些紅外光吸收粒子為藍玻璃顆粒。In an embodiment of the invention, the infrared light absorbing particles are blue glass particles.
在本發明的一實施例中,光吸收膜還包括紅外光吸收染料,而紅外光吸收染料分布於結合材料內。In an embodiment of the invention, the light absorbing film further includes an infrared light absorbing dye, and the infrared light absorbing dye is distributed in the bonding material.
在本發明的一實施例中,光吸收膜還包括紫外光吸收染料,而紫外光吸收染料分布於結合材料內。In an embodiment of the present invention, the light absorbing film further includes an ultraviolet light absorbing dye, and the ultraviolet light absorbing dye is distributed in the bonding material.
在本發明的一實施例中,光吸收膜還包括紅外光吸收染料與紫外光吸收染料,而紅外光吸收染料與紫外光吸收染料皆分布於結合材料內。In an embodiment of the invention, the light absorbing film further includes infrared light absorbing dye and ultraviolet light absorbing dye, and both the infrared light absorbing dye and the ultraviolet light absorbing dye are distributed in the bonding material.
在本發明的一實施例中,結合材料包括有機材料。In an embodiment of the invention, the bonding material includes an organic material.
在本發明的一實施例中,結合材料包括無機材料。In an embodiment of the invention, the bonding material includes an inorganic material.
在本發明的一實施例中,紅外光濾光片還包括形成於光吸收膜一側的第二光學膜。In an embodiment of the invention, the infrared light filter further includes a second optical film formed on one side of the light absorption film.
在本發明的一實施例中,光吸收膜位於第一光學膜與第二光學膜之間。In an embodiment of the invention, the light absorption film is located between the first optical film and the second optical film.
在本發明的一實施例中,這些紅外光吸收粒子的熔點小於850℃。In an embodiment of the invention, the melting point of these infrared light absorbing particles is less than 850°C.
在本發明的一實施例中,結合材料包括聚醯亞胺(Polyimide,PI)或聚碳酸酯(Polycarbonate,PC)。In an embodiment of the invention, the bonding material includes polyimide (Polyimide, PI) or polycarbonate (Polycarbonate, PC).
在本發明的一實施例中,紅外光濾光片的紫外光截通波長介於410奈米至420奈米之間。In an embodiment of the invention, the ultraviolet cut-off wavelength of the infrared filter is between 410 nm and 420 nm.
在本發明的一實施例中,光吸收膜的熱收縮率小於或等於0.15%。In an embodiment of the present invention, the thermal shrinkage of the light-absorbing film is less than or equal to 0.15%.
在本發明的一實施例中,光吸收膜的熱軟化溫度大於或等於160℃。In an embodiment of the present invention, the thermal softening temperature of the light-absorbing film is greater than or equal to 160°C.
在本發明的一實施例中,光吸收膜的抗彎折強度(bending strength)介於90兆帕(MPa)至110兆帕之間。In an embodiment of the present invention, the bending strength of the light-absorbing film is between 90 MPa and 110 MPa.
在本發明的一實施例中,光吸收膜在波長350奈米至395奈米範圍內的平均穿透率小於或等於0.15%,而光吸收膜在波長430奈米至450奈米範圍內的平均穿透率大於78%。In an embodiment of the present invention, the average transmittance of the light absorption film in the wavelength range of 350 nm to 395 nm is less than or equal to 0.15%, and the light absorption film in the wavelength range of 430 nm to 450 nm The average penetration rate is greater than 78%.
在本發明的一實施例中,光吸收膜在波長700奈米至725奈米範圍內的平均穿透率小於1.8%。In an embodiment of the invention, the average transmittance of the light-absorbing film in the wavelength range of 700 nm to 725 nm is less than 1.8%.
基於上述,利用這些無機的紅外光吸收粒子,本發明至少一實施例所提供的紅外光濾光片不僅能有效濾除波長700奈米至1100奈米範圍內的紅外光,而且還具有介於10微米至500微米之間的厚度。因此,上述紅外光濾光片不僅具有足夠薄的厚度而能夠裝設於現有行動裝置的影像感測器內,而且還能有效濾除紅外光,避免紅外光干擾影像感測器的影像擷取,提升影像品質。Based on the above, using these inorganic infrared light absorbing particles, the infrared light filter provided in at least one embodiment of the present invention can not only effectively filter infrared light in the wavelength range of 700 nm to 1100 nm, but also has Thickness between 10 microns and 500 microns. Therefore, the infrared light filter not only has a sufficiently thin thickness to be installed in the image sensor of the existing mobile device, but also can effectively filter out infrared light to avoid infrared light from interfering with the image capture of the image sensor To improve image quality.
為讓本發明之上述和其他目的、特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式,作詳細說明如下。To make the above and other objects, features, and advantages of the present invention more comprehensible, embodiments are described below in conjunction with the accompanying drawings, which are described in detail below.
圖1A是本發明一實施例的紅外光濾光片的剖面示意圖。請參閱圖1A,紅外光濾光片100包括光吸收膜110以及第一光學膜121,其中第一光學膜121形成於光吸收膜110的一側,即光吸收膜110與第一光學膜121彼此堆疊。第一光學膜121可以是抗反射層或干涉式濾光膜。當第一光學膜121為抗反射層時,第一光學膜121能降低紅外光濾光片100的反射率,其中第一光學膜121可以是多層膜或次波長結構(sub-wavelength structure)。當第一光學膜121為干涉式濾光膜時,第一光學膜121能提升濾除不可見光(例如紅外光或紫外光)的能力。FIG. 1A is a schematic cross-sectional view of an infrared light filter according to an embodiment of the invention. Referring to FIG. 1A, the
光吸收膜110包括結合材料111以及多個紅外光吸收粒子112,其中這些紅外光吸收粒子112分布於結合材料111內,且皆為無機,即這些紅外光吸收粒子112都是無機材料。也就是說,這些紅外光吸收粒子112是由無機材料所構成,並且可以是藍玻璃顆粒,其中這些紅外光吸收粒子112的熔點可小於850℃。這些紅外光吸收粒子112為非晶相顆粒,其中這裡所述的非晶相顆粒不僅涵蓋非晶態(amorphous state),而且也涵蓋奈米晶體(nanocrystal)。換句話說,紅外光吸收粒子112也可以是奈米晶體。此外,紅外光吸收粒子112與結合材料111之間的重量百分比可介於1%至80%。The
這些紅外光吸收粒子112可由多顆奈米粒子所構成,其中這些奈米粒子例如是藍玻璃奈米粒子,即上述藍玻璃顆粒可由奈米粒子所形成。藍玻璃奈米粒子可以是由藍玻璃板經破碎與研磨之後而產生,其中此藍玻璃板本身已具有濾除紅外光的功能。這些紅外光吸收粒子112的平均凝聚粒徑小於80奈米,因此這些紅外光吸收粒子112基本上皆為奈米粒子。結合材料111包括有機材料與無機材料至少一者。也就是說,結合材料111可以是有機材料或無機材料,或是有機材料與無機材料的兩者結合。上述有機材料可包括聚醯亞胺(PI)或聚碳酸酯(PC),即結合材料111可包括聚醯亞胺或聚碳酸酯。The infrared
紅外光濾光片100的紅外光截通波長介於600奈米至650奈米之間,而紅外光濾光片100的紫外光截通波長介於410奈米至420奈米之間,其中本說明書在此所述的截通波長(不論是紅外光截通波長與紫外光截通波長)乃是指濾光片在其穿透率為50%時所對應的波長。舉例來說,當某一紅外光的波長為濾光片(例如紅外光濾光片100)的紅外光截通波長時,濾光片對應此紅外光的穿透率基本上是50%。同理,當某一紫外光的波長為濾光片(例如紅外光濾光片100)的紫外光截通波長時,濾光片對應此紫外光的穿透率基本上是50%。The infrared cut-off wavelength of the
紅外光濾光片100的厚度T1介於10微米至500微米之間,其中光吸收膜110的厚度T2可以大於或等於5微米,但小於500微米,例如100微米。因此,紅外光濾光片100具有足夠薄的厚度T1,以使紅外光濾光片100能夠裝入於現有行動裝置所使用的影像感測器內。其次,光吸收膜110的抗彎折強度介於90兆帕至110兆帕之間,所以紅外光濾光片100具有足夠的結構強度而不易彎折或碎裂。顯然,紅外光濾光片100沒有現有的藍玻璃紅外光吸收片易碎的缺點。The thickness T1 of the infrared
在光學表現方面,紅外光濾光片100在波長700奈米至1100奈米範圍內的平均穿透率小於1%,且紅外光濾光片100在波長430奈米至580奈米範圍內的平均穿透率大於75%。因此,紅外光濾光片100不僅能有效濾除紅外光(例如波長在700奈米至1100奈米之間),而且還能讓大部分的可見光(例如波長在430奈米至580奈米之間)穿透。如此,應用於行動裝置的紅外光濾光片100能有效防止紅外光干擾影像感測器的影像擷取,並讓影像感測器能接收大部分的可見光,從而維持或提升影像感測器的影像品質。In terms of optical performance, the average transmittance of the
由此可知,相較於現有的藍玻璃紅外光吸收片,紅外光濾光片100不僅可裝入於現有行動裝置所使用的影像感測器內,而且還具有足夠的結構強度。如此,在行動裝置不慎遭到撞擊或摔落之後,裝設於行動裝置內的紅外光濾光片100不易發生碎裂的情形。其次,紅外光濾光片100在波長700奈米至1100奈米範圍內的平均穿透率小於1%,而這接近於現有藍玻璃紅外光吸收片的平均穿透率(在700奈米至1100奈米的波長範圍內)。與現有的紅外光吸收樹脂薄膜相比,顯然紅外光濾光片100能更有效地濾除紅外光,即紅外光濾光片100具有比現有紅外光吸收樹脂薄膜更好的光學表現。It can be seen that, compared with the existing blue glass infrared light absorption sheet, the infrared
在圖1A所示的實施例中,光吸收膜110還可包括紅外光吸收染料113與紫外光吸收染料114,而紅外光吸收染料113與紫外光吸收染料114皆分布於結合材料111內。紅外光吸收染料113可幫助提升紅外光濾光片100濾除紅外光的能力。紫外光吸收染料114能吸收紫外光,以使光吸收膜110在波長350奈米至395奈米範圍內的平均穿透率能小於或等於0.15%。如此,紅外光濾光片100不僅能濾除紅外光,且也能濾除紫外光 ,以使紅外光濾光片100能同時有效防止紅外光與紫外光干擾影像感測器的影像擷取。In the embodiment shown in FIG. 1A, the
特別一提的是,在圖1A所示的實施例中,光吸收膜110包括紅外光吸收染料113與紫外光吸收染料114,但在其他實施例中,端看紅外光濾光片100的用途或需求,光吸收膜110可以包括紅外光吸收染料113與紫外光吸收染料114其中一者,甚至都不包括紅外光吸收染料113與紫外光吸收染料114。因此,圖1A所示的紅外光吸收染料113與紫外光吸收染料114僅用來做為實施例說明,並不限定光吸收膜110一定要包括紅外光吸收染料113與紫外光吸收染料114。In particular, in the embodiment shown in FIG. 1A, the
紅外光濾光片100的光吸收膜110可依據紅外光吸收粒子112與結合材料111之間的不同重量百分比而具有不同的光學表現、抗彎折強度以及熱學特性,如以下表(一)所示的光吸收膜110樣品1至樣品6。特別說明的是,樣品1至樣品6只是紅外光濾光片100的其中多種例子,並不限定紅外光吸收粒子112與結合材料111之間的重量百分比一定要如表(一)所揭示。 表(一)
請參閱圖1B以及表(一),其中圖1B是表(一)中樣品1至6的穿透光譜示意圖,而圖1B中的曲線S1、S2、S3、S4、S5與S6依序代表樣品1、2、3、4、5與6的穿透光譜。從圖1B與表(一)可得知,光吸收膜110在波長350奈米至395奈米範圍內的平均穿透率能小於0.15%,所以紅外光濾光片100能有效濾除紫外光。光吸收膜110在波長700奈米至725奈米範圍內的平均穿透率小於1.8%,因此光吸收膜110能有效濾除波長在700奈米至725奈米範圍內的紅外光。紅外光濾光片100在波長430奈米至580奈米範圍內的平均穿透率大於75%,其中光吸收膜110在波長430奈米至450奈米範圍內的平均穿透率大於78%,因此光吸收膜110可允許大部分的可見光通過,以維持或提升影像感測器的影像品質。此外,就抗彎折強度以及熱學特性而言,表(一)揭露光吸收膜110的熱收縮率可小於或等於0.15%,而光吸收膜110的熱軟化溫度可大於或等於160℃。與現有的紅外光吸收樹脂薄膜相比,光吸收膜110具有較好的耐熱性。Please refer to FIG. 1B and table (1), where FIG. 1B is a schematic diagram of the transmission spectra of samples 1 to 6 in table (1), and the curves S1, S2, S3, S4, S5, and S6 in FIG. 1B represent the samples in order. 1, 2, 3, 4, 5 and 6 transmission spectra. As can be seen from FIG. 1B and Table (1), the average transmittance of the
以上主要敘述紅外光濾光片100的結構、材料以及特性。接下來,將說明紅外光濾光片100的製造方法。詳細而言,首先,製造光吸收膜110。待光吸收膜110製造完成之後,再形成第一光學膜121於光吸收膜110上,其中第一光學膜121可以採用物理氣相沉積(Physical Vapor Deposition,PVD)來形成,例如蒸鍍(evaporation deposition)或濺鍍(sputtering)。The above mainly describes the structure, materials, and characteristics of the infrared
光吸收膜110的製造方法可採用以下步驟。首先,製作藍玻璃。具體而言,此藍玻璃可選用偏磷酸鹽類材料、金屬氧化物與金屬氟化物來製作,其中偏磷酸鹽類材料、金屬氧化物以及金屬氟化物在混合均匀之後,置入坩堝中。之後,在大氣環境或是還原氣氛爐中,加熱置入於坩堝內的這些材料,其中還原氣氛爐可提供氧氣氛圍的環境,以使這些材料能在氧氣氛圍的環境下加熱。此外,上述還原氣氛爐的温度可控制在700℃與1000℃之間。The manufacturing method of the
關於藍玻璃所選用的材料,偏磷酸鹽類材料例如包括偏磷酸鋁、偏磷酸鎂、偏磷酸鋰、偏磷酸鋅及偏磷酸鈣,碳酸鹽類,如碳酸鈣、碳酸鋇及碳酸鍶其中至少一種材料,即偏磷酸鹽類材料可以是這些材料的任意組成。金屬氧化物例如包括氧化銅、氧化鋁、氧化鋅及氧化鎂其中至少一種材料,即金屬氧化物可以是這些材料的任意組成。金屬氟化物例如包括氟化鋁、氟化鎂、氟化鈣、氟化鍶、氟化鋇及氟化鋅其中至少一種材料,即金屬氟化物可以是這些材料的任意組成。Regarding the materials selected for the blue glass, metaphosphate materials include, for example, aluminum metaphosphate, magnesium metaphosphate, lithium metaphosphate, zinc metaphosphate and calcium metaphosphate, and carbonates such as calcium carbonate, barium carbonate and strontium carbonate are at least A material, that is, a metaphosphate material may be any composition of these materials. The metal oxide includes, for example, at least one of copper oxide, aluminum oxide, zinc oxide, and magnesium oxide, that is, the metal oxide may be any composition of these materials. The metal fluoride includes, for example, at least one of aluminum fluoride, magnesium fluoride, calcium fluoride, strontium fluoride, barium fluoride, and zinc fluoride, that is, the metal fluoride may be any composition of these materials.
上述藍玻璃的成分組成例如包含莫爾百分率(mol %)35~55%的磷離子、莫爾百分率0~18%的鋁離子、莫爾百分率5~40%的鹼金屬離子、莫爾百分率5~30%的鹼土族離子及二價金屬離子、莫爾百分率5~25%的銅離子,其中銅離子與磷離子兩者的莫爾百分率比例可介於0.1至0.5之間,而氟離子與氧離子兩者的莫爾百分率比例可介於0.01至0.48之間。The composition of the above blue glass includes, for example, phosphorus ions with a molar percentage (mol%) of 35 to 55%, aluminum ions with a molar percentage of 0 to 18%, alkali metal ions with a molar percentage of 5 to 40%, and a molar percentage of 5 ~30% alkaline earth ions and divalent metal ions, 5~25% copper ions with a molar ratio of 5 to 25%, wherein the molar ratio of copper ions and phosphorus ions can be between 0.1 and 0.5, and the fluoride ion is The ratio of mole percentages of both oxygen ions can be between 0.01 and 0.48.
將上述材料混合與熔融之後,冷卻這些材料,以得到藍玻璃。之後,粉碎藍玻璃,得到藍玻璃奈米粒子,其中各個藍玻璃奈米粒子的粒徑可介於20奈米至200奈米之間,較佳為100奈米。粉碎藍玻璃的手段可使用濕式或乾式粉碎法,或是這兩種粉碎法,並可採用球磨機與撞擊粉碎裝置(nanomizer)來進行。在粉碎藍玻璃的過程中,可以使用例如水、醇、酮、醚、酯與醛至少一種液態材料來作為分散介質,其中分散介質的質量百分比可介於50%至60%之間。之後,可以利用離心機,將分散介質與這些藍玻璃奈米粒子分離。然後,可以進行清洗、乾燥以及乾式粉碎。After mixing and melting the above materials, these materials are cooled to obtain blue glass. Afterwards, the blue glass is crushed to obtain blue glass nanoparticles, wherein the particle size of each blue glass nanoparticle can be between 20 nanometers and 200 nanometers, preferably 100 nanometers. The method of crushing the blue glass can be wet or dry crushing method, or both crushing methods, and can be carried out using a ball mill and impact crushing device (nanomizer). In the process of pulverizing the blue glass, at least one liquid material such as water, alcohol, ketone, ether, ester and aldehyde can be used as the dispersion medium, wherein the mass percentage of the dispersion medium can be between 50% and 60%. After that, a centrifuge can be used to separate the dispersion medium from these blue glass nanoparticles. Then, washing, drying and dry crushing can be performed.
此外,還可使用表面活性劑來分散藍玻璃奈米粒子,以削弱藍玻璃奈米粒子的凝聚,讓紅外光吸收粒子112的平均凝聚粒徑能控制在小於80奈米,以達到良好的红外光吸收效果。表面活性劑可為陰離子性表面活性劑(例如特殊聚羧酸型高分子表面活性劑與烷基磷酸酯至少一種)、非離子性表面活性劑(例如聚氧乙烯烷基醚、聚氧乙烯烷基酚醚、聚氧乙烯羧酸酯與脫水山梨糖醇高級羧酸酯至少一種)、陽離子性表面活性劑(例如聚氧化烯烷基胺羧酸酯、烷基胺與烷基按鹽至少一種)或兩性表面活性劑(例如聞級烷基甜菜喊)。In addition, surfactants can also be used to disperse blue glass nanoparticles to weaken the agglomeration of blue glass nanoparticles, so that the average agglomerated particle size of infrared
之後,將這些藍玻璃奈米粒子與結合材料111加入於溶劑中,並讓藍玻璃奈米粒子溶解於溶劑中,以形成均勻混合的溶液,其中溶劑例如是甲苯或二甲基乙醯胺(Dimethylacetamide, DMAC,別名 N,N-二甲基乙醯胺)。在藍玻璃奈米粒子與結合材料111加入於溶劑的過程中,可以加入紅外光吸收染料113與紫外光吸收染料114至少一者於溶劑中,以在後續中能形成包括紅外光吸收染料113與紫外光吸收染料114至少一者的光吸收膜110。After that, the blue glass nanoparticles and the
之後,將溶液鑄膜(casting)於平滑的基板上,其中此基板例如是玻璃板。然後,乾燥基板上的溶液,以形成光吸收膜110,其中溶液可採用陰乾或加熱烘乾的手段來乾燥。接著,將光吸收膜110與基板分離,以完成光吸收膜110的製造,其中分離光吸收膜110與基板的過程可在水中進行。此外,在藍玻璃奈米粒子與結合材料111加入於溶劑的過程中,也可加入紅外光吸收染料113與紫外光吸收染料114至少一者於溶劑中,以形成包括紅外光吸收染料與紫外光吸收染料至少一者的光吸收膜110。After that, the solution is cast on a smooth substrate, where the substrate is, for example, a glass plate. Then, the solution on the substrate is dried to form the
圖2與圖3是本發明其他實施例的紅外光濾光片的剖面示意圖,其中圖2與圖3所示的紅外光濾光片200與300皆相似於前述實施例中的紅外光濾光片100。惟紅外光濾光片200與300兩者不同於紅外光濾光片100之處在於:紅外光濾光片200與300皆包括前述實施例所未揭露的第二光學膜122。2 and 3 are schematic cross-sectional views of infrared light filters in other embodiments of the present invention, wherein the infrared
第二光學膜122可以是抗反射層或干涉式濾光膜,且也可以是多層膜。不過,第二光學膜122的功能卻不同於第一光學膜121的功能。也就是說,當第二光學膜122為抗反射層時,第一光學膜121為干涉式濾光膜,其中第二光學膜122也可以是次波長結構。反之,當第二光學膜122為干涉式濾光膜時,第一光學膜121為抗反射層。The second
第二光學膜122可以形成在光吸收膜110的其中一側。以圖2為例,第一光學膜121與第二光學膜122皆形成在光吸收膜110的同一側,其中第一光學膜121可位於第二光學膜122與光吸收膜110之間。不過,圖2中的第一光學膜121與第二光學膜122兩者可以對調。換句話說,在其他未繪示的實施例中,第二光學膜122可以位於第一光學膜121與光吸收膜110之間。此外,光吸收膜110也可以位於第一光學膜121與第二光學膜122之間,即第一光學膜121與第二光學膜122可分別形成於光吸收膜110的相對兩側,如圖3所示。The second
雖然本發明已以實施例揭露如上,然其並非用以限定本發明,本發明所屬技術領域中具有通常知識者,在不脫離本發明精神和範圍內,當可作些許更動與潤飾,因此本發明保護範圍當視後附的申請專利範圍所界定者為準。Although the present invention has been disclosed as above with examples, it is not intended to limit the present invention. Those with ordinary knowledge in the technical field to which the present invention belongs can make some modifications and retouching without departing from the spirit and scope of the present invention. The scope of protection of invention shall be subject to the scope defined in the appended patent application.
100、200、300‧‧‧紅外光濾光片100, 200, 300 ‧‧‧ infrared filter
110‧‧‧光吸收膜110‧‧‧Light absorbing film
111‧‧‧結合材料111‧‧‧Combined materials
112‧‧‧紅外光吸收粒子112‧‧‧Infrared light absorbing particles
113‧‧‧紅外光吸收染料113‧‧‧Infrared absorption dye
114‧‧‧紫外光吸收染料114‧‧‧Ultraviolet absorption dye
121‧‧‧第一光學膜121‧‧‧First optical film
122‧‧‧第二光學膜122‧‧‧Second optical film
S1、S2、S3、S4、S5、S6‧‧‧曲線S1, S2, S3, S4, S5, S6‧‧‧‧curve
T1、T2‧‧‧厚度T1, T2‧‧‧thickness
圖1A是本發明一實施例的紅外光濾光片的剖面示意圖。 圖1B是表(一)中的光吸收膜樣品1至6的穿透光譜示意圖。 圖2是本發明另一實施例的紅外光濾光片的剖面示意圖。 圖3是本發明另一實施例的紅外光濾光片的剖面示意圖。FIG. 1A is a schematic cross-sectional view of an infrared light filter according to an embodiment of the invention. FIG. 1B is a schematic diagram of the transmission spectra of the light-absorbing film samples 1 to 6 in Table (1). 2 is a schematic cross-sectional view of an infrared light filter according to another embodiment of the present invention. 3 is a schematic cross-sectional view of an infrared light filter according to another embodiment of the present invention.
100‧‧‧紅外光濾光片 100‧‧‧Infrared filter
110‧‧‧光吸收膜 110‧‧‧Light absorbing film
111‧‧‧結合材料 111‧‧‧Combined materials
112‧‧‧紅外光吸收粒子 112‧‧‧Infrared light absorbing particles
113‧‧‧紅外光吸收染料 113‧‧‧Infrared absorption dye
114‧‧‧紫外光吸收染料 114‧‧‧Ultraviolet absorption dye
121‧‧‧第一光學膜 121‧‧‧First optical film
T1、T2‧‧‧厚度 T1, T2‧‧‧thickness
Claims (19)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW107129768A TWI685681B (en) | 2018-08-27 | 2018-08-27 | Infrared diffuser |
CN201811019762.0A CN110865430A (en) | 2018-08-27 | 2018-09-03 | Infrared light filter |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW107129768A TWI685681B (en) | 2018-08-27 | 2018-08-27 | Infrared diffuser |
Publications (2)
Publication Number | Publication Date |
---|---|
TWI685681B true TWI685681B (en) | 2020-02-21 |
TW202009528A TW202009528A (en) | 2020-03-01 |
Family
ID=69651571
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW107129768A TWI685681B (en) | 2018-08-27 | 2018-08-27 | Infrared diffuser |
Country Status (2)
Country | Link |
---|---|
CN (1) | CN110865430A (en) |
TW (1) | TWI685681B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111427112A (en) * | 2020-03-31 | 2020-07-17 | 苏州市联超光电科技有限公司 | Infrared light filter and preparation process thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW201439295A (en) * | 2013-04-11 | 2014-10-16 | Fujifilm Corp | Near infrared absorptive composition, near infrared cut filter using the same, method for manufacturing the same, and camera module and method for manufacturing the same |
WO2016171219A1 (en) * | 2015-04-23 | 2016-10-27 | 旭硝子株式会社 | Optical filter and imaging device |
WO2017018419A1 (en) * | 2015-07-28 | 2017-02-02 | Jsr株式会社 | Optical filter and environment light sensor provided with optical filter |
TW201800550A (en) * | 2016-04-21 | 2018-01-01 | 日本板硝子股份有限公司 | Infrared-absorbing composition, infrared-cut filter, optical system for imaging |
WO2018021496A1 (en) * | 2016-07-28 | 2018-02-01 | 京セラ株式会社 | Optical filter and package for optical element |
TWM572996U (en) * | 2018-08-27 | 2019-01-11 | 白金科技股份有限公司 | Infrared diffuser |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100932409B1 (en) * | 2002-02-25 | 2009-12-17 | 미쓰비시 마테리알 가부시키가이샤 | Compositions, coatings, polymer films and optical filters containing metal nanorods |
KR102056613B1 (en) * | 2012-08-23 | 2019-12-17 | 에이지씨 가부시키가이샤 | Near-infrared cut filter and solid-state imaging device |
CN107686238A (en) * | 2014-01-16 | 2018-02-13 | 成都光明光电股份有限公司 | Glass composition |
CN106883541B (en) * | 2015-12-16 | 2021-04-02 | 张家港康得新石墨烯应用科技有限公司 | Blue film composition, uncured adhesive, blue base film, preparation method and application thereof |
JP6848477B2 (en) * | 2017-01-25 | 2021-03-24 | Jsr株式会社 | Optical filters and their uses |
-
2018
- 2018-08-27 TW TW107129768A patent/TWI685681B/en active
- 2018-09-03 CN CN201811019762.0A patent/CN110865430A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW201439295A (en) * | 2013-04-11 | 2014-10-16 | Fujifilm Corp | Near infrared absorptive composition, near infrared cut filter using the same, method for manufacturing the same, and camera module and method for manufacturing the same |
TWI640610B (en) * | 2013-04-11 | 2018-11-11 | 日商富士軟片股份有限公司 | Near infrared absorptive composition, near infrared cut filter using the same, method for manufacturing the same, and camera module and method for manufacturing the same |
WO2016171219A1 (en) * | 2015-04-23 | 2016-10-27 | 旭硝子株式会社 | Optical filter and imaging device |
WO2017018419A1 (en) * | 2015-07-28 | 2017-02-02 | Jsr株式会社 | Optical filter and environment light sensor provided with optical filter |
TW201800550A (en) * | 2016-04-21 | 2018-01-01 | 日本板硝子股份有限公司 | Infrared-absorbing composition, infrared-cut filter, optical system for imaging |
TWI636128B (en) * | 2016-04-21 | 2018-09-21 | 日本板硝子股份有限公司 | Infrared absorbing composition, infrared cut filter, and photographic optical system |
WO2018021496A1 (en) * | 2016-07-28 | 2018-02-01 | 京セラ株式会社 | Optical filter and package for optical element |
TWM572996U (en) * | 2018-08-27 | 2019-01-11 | 白金科技股份有限公司 | Infrared diffuser |
Also Published As
Publication number | Publication date |
---|---|
CN110865430A (en) | 2020-03-06 |
TW202009528A (en) | 2020-03-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106662686B (en) | Optical filter, ambient light sensor, and electronic device | |
US9304236B2 (en) | Optical member, near infrared cut filter, solid-state imaging element, lens for imaging device, and imaging/display device using the same | |
US9570490B2 (en) | Infrared transmission filter and imaging device | |
TWI598641B (en) | Infrared light cut filter and photographing device | |
JP2008051985A (en) | Near infrared ray absorbing filter | |
JP2019525878A5 (en) | ||
CN109641442A (en) | The glass assembly and preparation method thereof of component distribution with customization | |
TWI685681B (en) | Infrared diffuser | |
TWM572996U (en) | Infrared diffuser | |
KR101410962B1 (en) | Glass, device and light filter for absorbing near infra-red ray | |
KR20180137021A (en) | A low temperature tellurite glass mixture for vacuum compression at a temperature of 450 DEG C or less | |
JP6646179B2 (en) | Optical filter | |
US12071542B2 (en) | Light-absorbing composition and optical filter | |
US20220112121A1 (en) | Near-infrared cut filter glass and optical filter | |
JP2024096865A (en) | Optical filter | |
JP6395489B2 (en) | Glass composition and method for producing the same, glass member and imaging device | |
TWI522331B (en) | Near infrared light absorption glass, components and filters | |
KR102405325B1 (en) | Laser induced transfer film | |
JP2013105846A (en) | Optical component having antifogging film and semiconductor device | |
CN104007596A (en) | Silver-gold binary simple-substance metal nanoparticle dispersion aluminium oxide non-linear optical thin film and preparation method | |
TW202126666A (en) | Organometallic complex dispersion, near-infrared absorption film and near-infrared cut-off filter prepared using the same | |
JP2013246266A (en) | Optical filter | |
TWI643830B (en) | Near infrared cut-off filter and manufacturing method thereof | |
TW202421597A (en) | Optical glass, optical element, glass preform for press molding, and optical device | |
JP6645732B2 (en) | Near-infrared absorbing alumina material, near-infrared absorbing alumina porcelain, and method of manufacturing near-infrared absorbing alumina porcelain |