TWI539651B - Non-stationary seawater battery - Google Patents
Non-stationary seawater battery Download PDFInfo
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- TWI539651B TWI539651B TW104133997A TW104133997A TWI539651B TW I539651 B TWI539651 B TW I539651B TW 104133997 A TW104133997 A TW 104133997A TW 104133997 A TW104133997 A TW 104133997A TW I539651 B TWI539651 B TW I539651B
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/30—Deferred-action cells
- H01M6/32—Deferred-action cells activated through external addition of electrolyte or of electrolyte components
- H01M6/34—Immersion cells, e.g. sea-water cells
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Description
本發明為有關一種海水電池，尤指一種非固定式海水電池。The invention relates to a seawater battery, in particular to a non-fixed seawater battery.
隨著全球人口不斷增加以及科技的進步，使人們對能源的需求不斷上升，傳統的化石能源如石油、煤炭等已逐漸供不應求，因此使得可再生的能源逐漸受到重視，而由於海水約佔地表百分之七十的面積，因此，利用海水來發電亦成為一發展重點。With the continuous increase of the global population and the advancement of science and technology, people's demand for energy is rising. Traditional fossil energy sources such as oil and coal are gradually in short supply. Therefore, renewable energy is gradually gaining attention, and because seawater accounts for about 100% of the earth's surface. With an area of 70%, the use of seawater to generate electricity has also become a development priority.
而利用海水來發電的方式主要為潮汐發電、海水溫差發電以及海水電池，其中，海水電池為利用海水做為電解液，只要將電極浸入海水即可發電，使其在應用上格外受到矚目，而為能獲得更大的電力輸出，大部分之應用係將多個海水電池設計為串聯或並聯之結構，如中國大陸專利第CN 1543001號之「鎂海水電池」，其包含有一陽極，複數個並聯的惰性陰極、複數個電池框架以及一圍繞該陽極的網子，該些電池框架均勻設置於該網子上，該些惰性陰極則設置於該些電池框架相鄰於該陽極之一端，當海水與該陽極以及該些惰性陰極接觸而可發電。The way of using seawater to generate electricity is mainly tidal power generation, seawater temperature difference power generation, and seawater batteries. Among them, seawater batteries use seawater as an electrolyte, so that the electrodes can be immersed in seawater to generate electricity, which makes them particularly attractive for applications. In order to obtain greater power output, most of the applications are to design a plurality of seawater batteries in a series or parallel configuration, such as the "magnesium seawater battery" of the Chinese Patent No. CN 1543001, which includes an anode, a plurality of parallel An inert cathode, a plurality of battery frames, and a net surrounding the anode, the battery frames are evenly disposed on the net, and the inert cathodes are disposed on the battery frame adjacent to one end of the anode, when the seawater Power is generated by contact with the anode and the inert cathodes.
然而，為了使該陽極與該些惰性陰極保持一距離，而需要設置該些電池框架固定該些惰性陰極，使結構較為複雜，進而使該陽極與該些惰性陰極不易更換，因此，如何解決海水電池組裝結構複雜以及電極不易更換的問題，實為一大課題。However, in order to keep the anode at a distance from the inert cathodes, it is necessary to provide the battery frames to fix the inert cathodes, so that the structure is complicated, and the anode and the inert cathodes are not easily replaced. Therefore, how to solve the seawater The problem of complicated battery assembly structure and difficulty in replacing the electrodes is a major issue.
本發明的主要目的，在於解決海水電池組裝結構複雜以及電極不易更換的問題。The main object of the present invention is to solve the problem that the seawater battery assembly structure is complicated and the electrodes are not easily replaced.
為達上述目的，本發明提供一種非固定式海水電池，包含有一第一電池、一設置於該第一電池上的第二電池以及一導電組件，該第一電池包含有一第一槽體、一容置於該第一槽體內的第一海水電解液以及一與該第一海水電解液接觸的第一電極組件，該第一電極組件包括一設置於該第一槽體之底部的第一陽極以及一與該第一陽極相距並懸浮於該第一海水電解液上的第一陰極，該第二電池包含有一第二槽體、一容置於該第二槽體內的第二海水電解液以及一與該第二海水電解液接觸的第二電極組件，該第二電極組件包括一設置於該第二槽體之底部的第二陽極以及一與該第二陽極相距並懸浮於該第二海水電解液上的第二陰極，該導電組件電性連接於該第一電極組件與該第二電極組件。In order to achieve the above object, the present invention provides a non-fixed seawater battery, comprising a first battery, a second battery disposed on the first battery, and a conductive component, the first battery including a first cavity, and a first battery a first seawater electrolyte disposed in the first tank and a first electrode assembly in contact with the first seawater solution, the first electrode assembly including a first anode disposed at a bottom of the first tank And a first cathode spaced apart from the first anode and suspended on the first seawater solution, the second battery includes a second tank body, a second seawater electrolyte contained in the second tank body, and a second electrode assembly in contact with the second seawater solution, the second electrode assembly includes a second anode disposed at a bottom of the second tank body and a distance from the second anode and suspended in the second seawater a second cathode on the electrolyte, the conductive component being electrically connected to the first electrode component and the second electrode component.
綜上所述，本發明具有以下特點：In summary, the present invention has the following features:
一、 藉由將該第一陽極與該第二陽極設置於該第一槽體與該第二槽體之底部、將該第一陰極與該第二陰極懸浮於該第一海水電解液與該第二海水電解液上，而可防止該第一陽極與該第一陰極相觸、該第二陽極與該第二陰極相觸而發生短路的問題。1. The first anode and the second anode are disposed at the bottom of the first tank and the second tank, and the first cathode and the second cathode are suspended in the first seawater solution. The second seawater electrolyte prevents the first anode from coming into contact with the first cathode and the second anode contacting the second cathode to cause a short circuit.
二、 僅需將該第一陽極與該第二陽極設置於該第一槽體與該第二槽體之底部，而使該第一陰極與該第二陰極任意懸浮，而可降低結構的複雜度以及製造成本。2. The first anode and the second anode need to be disposed at the bottom of the first tank body and the second tank body, so that the first cathode and the second cathode are randomly suspended, thereby reducing the complexity of the structure. Degree and manufacturing cost.
三、 只需要重新投入新的該第一陽極與該第二陽極，即可持續進行發電，因此具有容易置換的優點。3. It is only necessary to re-inject the new first anode and the second anode, that is, to continuously generate electricity, and thus has the advantage of being easily replaced.
關本發明的詳細說明及技術內容，現就配合圖式說明如下：The detailed description and technical contents of the present invention will now be described as follows:
請參閱「圖1」所示，為本發明一較佳實施例的剖面結構示意圖。本發明為一種非固定式海水電池，包含有一第一電池10、一設置於該第一電池10上的第二電池20以及一導電組件30，該第一電池10包含有一第一槽體11、一第一海水電解液12以及一第一電極組件13，該第一海水電解液12容置於該第一槽體11內，該第一電極組件13與該第一海水電解液12接觸，並包含有一設置於該第一槽體11之底部的第一陽極131以及一與該第一陽極131相距並懸浮於該第一海水電解液12上的第一陰極132，該第二電池20包含有一第二槽體21、一第二海水電解液22以及一第二電極組件23，該第二海水電解液22容置於該第二槽體21內，該第二電極組件23與該第二海水電解液22接觸並包含有一設置於該第二槽體21之底部的第二陽極231以及一與該第二陽極231相距並懸浮於該第二海水電解液22上的第二陰極232，該導電組件30電性連接於該第一電極組件13與該第二電極組件23。Please refer to FIG. 1 for a schematic cross-sectional view of a preferred embodiment of the present invention. The present invention is a non-stationary seawater battery, comprising a first battery 10, a second battery 20 disposed on the first battery 10, and a conductive component 30. The first battery 10 includes a first slot body 11, a first seawater electrolyte 12 and a first electrode assembly 13 , the first seawater electrolyte 12 is received in the first tank body 11 , the first electrode assembly 13 is in contact with the first seawater electrolyte 12 , and The first battery 131 disposed at the bottom of the first tank body 11 and the first cathode 132 spaced apart from the first anode 131 and suspended on the first seawater solution 12, the second battery 20 includes a second tank body 21, a second seawater solution 22, and a second electrode assembly 23, the second seawater solution 22 is received in the second tank body 21, the second electrode assembly 23 and the second seawater The electrolyte 22 is in contact with and includes a second anode 231 disposed at the bottom of the second tank 21 and a second cathode 232 spaced from the second anode 231 and suspended on the second seawater solution 22, the conductive The component 30 is electrically connected to the first electrode assembly 13 and the second electrode group Item 23.
其中，該第一陰極132與該第二陰極232的材料可以為碳、石墨稀、碳黑、奈米碳管或碳纖維等碳材料，並具有一多孔隙特性，因此可以使氣體充滿於孔隙之中，而可懸浮在該第一海水電解液12、該第二海水電解液22之上，且該第一陰極132與該第二陰極232的厚度介於1毫米(mm)至10毫米(mm)之間，最佳為介於3毫米(mm)至10毫米(mm)之間，而該第一陽極131與該第二陽極231的材料可以為鋁、鎂及其組合所形成的合金。The material of the first cathode 132 and the second cathode 232 may be carbon materials such as carbon, graphite thin, carbon black, carbon nanotubes or carbon fibers, and has a multi-porosity characteristic, so that the gas can be filled in the pores. The first cathode 132 and the second cathode 232 may have a thickness of between 1 mm (mm) and 10 mm (mm). Preferably, between 3 mm (mm) and 10 mm (mm), and the material of the first anode 131 and the second anode 231 may be an alloy formed of aluminum, magnesium, and a combination thereof.
因此，藉由將該第一陽極131與該第二陽極231設置於該第一槽體11與該第二槽體21之底部，而可防止該第一陽極131與懸浮在該第一海水電解液12上的該第一陰極132相觸以及防止該第二陽極231與懸浮在該第二海水電解液22上的該第二陰極232相觸而發生短路的問題，且由於僅需將該第一陽極131與該第二陽極231分別設置於該第一槽體11與該第二槽體21之底部，而不需設置該第一陰極132與該第二陰極232的位置，可以降低結構的複雜度以及製造成本。Therefore, by disposing the first anode 131 and the second anode 231 at the bottom of the first tank body 11 and the second tank body 21, the first anode 131 can be prevented from being suspended in the first seawater electrolysis. The first cathode 132 on the liquid 12 contacts and prevents the second anode 231 from coming into contact with the second cathode 232 suspended on the second seawater solution 22 to cause a short circuit, and since only the first An anode 131 and the second anode 231 are respectively disposed at the bottoms of the first tank body 11 and the second tank body 21, and the positions of the first cathode 132 and the second cathode 232 are not required, and the structure can be reduced. Complexity and manufacturing costs.
於本實施例中，更包含有一設置於該第一槽體11之側邊的第一穿孔40，以及一設置於該第二槽體21之側邊的第二穿孔41，而該第一穿孔40與該第二穿孔41可以供該導電組件30穿過，使該第一陽極131電性連接於該第二陰極232、該第二陽極231電性連接於該第一陰極132，並於該第一陽極131與該第二陰極232間串聯一負載80，形成一電池串聯結構，使輸出的電壓增大，但亦可形成並聯之結構，不以本實施例之舉例為限。In this embodiment, the first through hole 40 is disposed on a side of the first groove body 11, and the second hole 41 is disposed on a side of the second groove body 21, and the first hole is formed. The second through hole 41 is electrically connected to the second cathode 232, and the second anode 231 is electrically connected to the first cathode 132. A load 80 is connected in series between the first anode 131 and the second cathode 232 to form a battery series structure, so that the output voltage is increased, but a parallel structure can also be formed, which is not limited to the example of the embodiment.
且該第一電池10更包含有一設置於該第一槽體11之側邊以供該第一海水電解液12輸入的第一輸入口14以及一設置於該第一槽體11之側邊以供該第一海水電解液12輸出的第一輸出口15，而本實施例中，該第一輸入口14與該第一輸出口15設置於該第一電池10之相對兩側，但可配合使用者的需求而設置在不同的位置，不以此為限，而該第二電池20則更包含有一設置於該第二槽體21之側邊以供該第二海水電解液22輸入的第二輸入口24以及一設置於該第二槽體21之側邊以供該第二海水電解液22輸出的第二輸出口25，同樣的，該第二輸入口24以及該第二輸出口25的位置亦可配合使用者的需求而設置。而藉由該第一海水電解液12與該該第二海水電解液22持續的流入以及流出，可以維持該第一海水電解液12於該第一槽體11中以及該第二海水電解液22於該第二槽體21中的離子濃度，穩定所產生的電流。The first battery 10 further includes a first input port 14 disposed on a side of the first slot 11 for inputting the first seawater solution 12 and a side disposed on the side of the first slot 11 The first output port 15 for outputting the first seawater electrolyte 12, and in the embodiment, the first input port 14 and the first output port 15 are disposed on opposite sides of the first battery 10, but can be matched The second battery 20 further includes a side disposed on the side of the second tank 21 for inputting the second seawater electrolyte 22, which is not limited thereto. a second input port 24 and a second output port 25 disposed on a side of the second tank body 21 for outputting the second seawater solution 22, and similarly, the second input port 24 and the second output port 25 The location can also be set to match the needs of the user. The first seawater solution 12 in the first tank body 11 and the second seawater electrolyte 22 can be maintained by the continuous inflow and outflow of the first seawater solution 12 and the second seawater solution 22 . The ion concentration in the second tank 21 stabilizes the generated current.
當進行放電後，該第一陽極131與該第二陽極231會分別與該第一海水電解液12、該第二海水電解液22進行反應而產生副產物，而副產物會被流動的該第一海水電解液12、該第二海水電解液22帶走，最後，當該第一陽極131與該第二陽極231消耗殆盡之後，只要取出舊的該第一陽極131與該第二陽極231，再重新投入新的該第一陽極131與該第二陽極231，即可持續進行發電，因此具有容易置換的優點。After the discharge, the first anode 131 and the second anode 231 react with the first seawater solution 12 and the second seawater solution 22 to generate by-products, and the by-products are flowed. A seawater electrolyte 12, the second seawater electrolyte 22 is carried away, and finally, after the first anode 131 and the second anode 231 are exhausted, the old first anode 131 and the second anode 231 are taken out. Then, the new first anode 131 and the second anode 231 are newly reintroduced, that is, power generation can be continued, and thus there is an advantage that it is easy to replace.
綜上所述，本發明具有以下特點：In summary, the present invention has the following features:
一、 藉由將該第一陽極與該第二陽極設置於該第一槽體與該第二槽體之底部，而可防止該第一陽極與懸浮在該第一海水電解液上的該第一陰極相觸以及防止該第二陽極與懸浮在該第二海水電解液上的該第二陰極相觸而發生短路的問題。1. The first anode and the first suspension suspended on the first seawater solution are prevented by the first anode and the second anode being disposed at the bottom of the first tank body and the second tank body. A problem occurs when a cathode touches and prevents the second anode from coming into contact with the second cathode suspended on the second seawater solution.
二、 僅需將該第一陽極與該第二陽極設置於該第一槽體與該第二槽體之底部，而不需設置該第一陰極與該第二陰極的位置，可以降低結構的複雜度以及製造成本。Secondly, the first anode and the second anode need to be disposed at the bottom of the first tank body and the second tank body, and the position of the first cathode and the second cathode need not be provided, and the structure can be reduced. Complexity and manufacturing costs.
三、 當該第一陽極與該第二陽極消耗殆盡之後，只要再重新投入新的該第一陽極與該第二陽極，即可持續進行發電，因此具有容易置換的優點。3. After the first anode and the second anode are exhausted, the power generation can be continued as long as the new first anode and the second anode are newly reintroduced, so that there is an advantage that the replacement is easy.
四、 藉由設置該第一輸入口、該第一輸出口、該第二輸入口以及該第二輸出口，使該第一海水電解液與該第二海水電解液持續的流入以及流出，可以維持該第一海水電解液於該第一槽體中以及該第二海水電解液於該第二槽體中的離子濃度，穩定所產生的電流。4. The first seawater electrolyte and the second seawater electrolyte are continuously flowed in and out by the first input port, the first output port, the second input port, and the second output port. The ion concentration of the first seawater solution in the first tank and the second seawater solution in the second tank is maintained to stabilize the generated current.
以上已將本發明做一詳細說明，惟以上所述者，僅爲本發明的一較佳實施例而已，當不能限定本發明實施的範圍。即凡依本發明申請範圍所作的均等變化與修飾等，皆應仍屬本發明的專利涵蓋範圍內。The present invention has been described in detail above, but the foregoing is only a preferred embodiment of the present invention, and is not intended to limit the scope of the invention. That is, the equivalent changes and modifications made by the scope of the present application should remain within the scope of the patent of the present invention.
10‧‧‧第一電池
11‧‧‧第一槽體
12‧‧‧第一海水電解液
13‧‧‧第一電極組件
131‧‧‧第一陽極
132‧‧‧第一陰極
14‧‧‧第一輸入口
15‧‧‧第一輸出口
20‧‧‧第二電池
21‧‧‧第二槽體
22‧‧‧第二海水電解液
23‧‧‧第二電極組件
231‧‧‧第二陽極
232‧‧‧第二陰極
24‧‧‧第二輸入口
25‧‧‧第二輸出口
30‧‧‧導電組件
40‧‧‧第一穿孔
41‧‧‧第二穿孔
80‧‧‧負載10‧‧‧First battery
11‧‧‧ first trough
12‧‧‧First seawater electrolyte
13‧‧‧First electrode assembly
131‧‧‧First anode
132‧‧‧first cathode
14‧‧‧ first input
15‧‧‧ first output
20‧‧‧Second battery
21‧‧‧Second trough
22‧‧‧Second seawater electrolyte
23‧‧‧Second electrode assembly
231‧‧‧Second anode
232‧‧‧second cathode
24‧‧‧second input
25‧‧‧second output
30‧‧‧ Conductive components
40‧‧‧First perforation
41‧‧‧Second perforation
80‧‧‧load
圖1，為本發明一較佳實施例的剖面結構示意圖。1 is a schematic cross-sectional view of a preferred embodiment of the present invention.
10‧‧‧第一電池 10‧‧‧First battery
11‧‧‧第一槽體 11‧‧‧ first trough
12‧‧‧第一海水電解液 12‧‧‧First seawater electrolyte
13‧‧‧第一電極組件 13‧‧‧First electrode assembly
131‧‧‧第一陽極 131‧‧‧First anode
132‧‧‧第一陰極 132‧‧‧first cathode
14‧‧‧第一輸入口 14‧‧‧ first input
15‧‧‧第一輸出口 15‧‧‧ first output
20‧‧‧第二電池 20‧‧‧Second battery
21‧‧‧第二槽體 21‧‧‧Second trough
22‧‧‧第二海水電解液 22‧‧‧Second seawater electrolyte
23‧‧‧第二電極組件 23‧‧‧Second electrode assembly
231‧‧‧第二陽極 231‧‧‧Second anode
232‧‧‧第二陰極 232‧‧‧second cathode
24‧‧‧第二輸入口 24‧‧‧second input
25‧‧‧第二輸出口 25‧‧‧second output
30‧‧‧導電組件 30‧‧‧ Conductive components
40‧‧‧第一穿孔 40‧‧‧First perforation
41‧‧‧第二穿孔 41‧‧‧Second perforation
80‧‧‧負載 80‧‧‧load
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW104133997A TWI539651B (en) | 2015-10-16 | 2015-10-16 | Non-stationary seawater battery |
| JP2016002976A JP6200005B2 (en) | 2015-10-16 | 2016-01-08 | Non-fixed seawater battery |
| CN201610463268.8A CN106602098B (en) | 2015-10-16 | 2016-06-23 | Non-fixed seawater battery |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW104133997A TWI539651B (en) | 2015-10-16 | 2015-10-16 | Non-stationary seawater battery |
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| TWI539651B true TWI539651B (en) | 2016-06-21 |
| TW201715779A TW201715779A (en) | 2017-05-01 |
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| TW104133997A TWI539651B (en) | 2015-10-16 | 2015-10-16 | Non-stationary seawater battery |
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| JP (1) | JP6200005B2 (en) |
| CN (1) | CN106602098B (en) |
| TW (1) | TWI539651B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI731827B (en) * | 2020-12-22 | 2021-06-21 | 國立高雄科技大學 | Seawater battery reactant pumping device |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2019000905A (en) | 2016-07-22 | 2019-10-02 | Nantenergy Inc | Mist elimination system for electrochemical cells. |
| EP3491690B1 (en) | 2016-07-22 | 2020-07-15 | NantEnergy, Inc. | Moisture and carbon dioxide management system in electrochemical cells |
| CN112805868A (en) * | 2018-06-29 | 2021-05-14 | 福恩能源公司 | Metal air electrochemical cell frame |
| CN110034321B (en) * | 2019-02-21 | 2024-07-19 | 浙江海洋大学 | Microbial fuel cell device for degrading mariculture wastewater |
| KR102526366B1 (en) * | 2019-12-11 | 2023-05-02 | 한국기계연구원 | Generator sustainably generating power |
| CN111910198B (en) * | 2020-07-28 | 2022-12-27 | 山西师范大学 | Gradient electric field synthesis device of metal-graphene composite material and preparation method thereof |
| CN114672826B (en) * | 2022-03-04 | 2024-01-12 | 化学与精细化工广东省实验室 | Double cathode electrolytic tank capable of producing hydrogen peroxide or hydrogen in switching mode |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3914813A (en) * | 1974-09-18 | 1975-10-28 | Yardney Electric Corp | Emergency light means |
| JPS54137733U (en) * | 1978-03-09 | 1979-09-25 | ||
| JPS57203502U (en) * | 1981-06-23 | 1982-12-24 | ||
| CN1393950A (en) * | 2001-07-04 | 2003-01-29 | 张道光 | Method and product for using seawater to provide electric energy |
| CN1543001A (en) * | 2003-11-06 | 2004-11-03 | 李华伦 | Magnesium sea water battery |
| JP5412977B2 (en) * | 2009-06-16 | 2014-02-12 | トヨタ自動車株式会社 | Metal gas battery |
| CN102479961B (en) * | 2010-11-29 | 2014-01-01 | 中国科学院大连化学物理研究所 | Oxygen dissolving type seawater battery |
| CN202333035U (en) * | 2011-12-05 | 2012-07-11 | 中国电子科技集团公司第十八研究所 | Compound electrode seawater battery |
| TWI469435B (en) * | 2013-04-17 | 2015-01-11 | Taiwan Carbon Nanotube Technology Corp | Seawater battery |
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2015
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI731827B (en) * | 2020-12-22 | 2021-06-21 | 國立高雄科技大學 | Seawater battery reactant pumping device |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106602098A (en) | 2017-04-26 |
| CN106602098B (en) | 2019-05-24 |
| TW201715779A (en) | 2017-05-01 |
| JP6200005B2 (en) | 2017-09-20 |
| JP2017076595A (en) | 2017-04-20 |
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