1328046 七、指定代表圖： (一） 本案指定代表圖為：第（2 )圖。 (二） 本代表圖之元件符號簡單說明·· 20 :提供一奈米粒子溶液； 22 :以超音波振盪奈米粒子溶液； 24 :奈米粒子溶液產生多個氣泡； 26 :提供一基板；1328046 VII. Designated representative map: (1) The representative representative of the case is: (2). (2) A brief description of the symbol of the representative figure·· 20: providing a nanoparticle solution; 22: ultrasonically oscillating the nanoparticle solution; 24: the nanoparticle solution generates a plurality of bubbles; 26: providing a substrate;
28 :讓氣泡從下往上碰撞基板； 八、本案若有化學式時，請揭示最能顯示發明特徵的化學式： 九、發明說明： 【發明所屬之技術領域】 本發明是有關於一種鍍膜技術，特別是有關於一種奈米 薄膜鍍法及其製造奈米抗菌紙的綠色方法。 【先前技術】 使用和未使用機機械進行塗佈的鍍膜技術，例如浸、刷、 機械葉片、塗佈器台、輾壓、噴刷、簾（curtain)、旋轉(spin)、 喷灑(spray)、撥製(extruded)、印刷、洗鑄......等塗佈方法已 經廣為使用。 然而，上述中的某些技術，尤其是會接觸到被鑛物的機 1328046 具㈣常會導致網狀破裂、表面缺陷等缺點，或是如 的習知賴技術的塗層示意圖所示，在基材1〇上具 表面i时層12(厚度不均扑亦或者為了填獅狀破裂或 的溶，造成Λ空隙而耗費過多材料’而需要使用過多 所:此里......等等，又或者因為填補空隙而影響表面性 貝先澤或亮度。28: Let the bubble collide with the substrate from bottom to top; 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: IX. Description of the invention: [Technical field of the invention] The present invention relates to a coating technique, In particular, there is a nano film plating method and a green method for producing nano antibacterial paper. [Prior Art] Coating techniques for coating with and without machine machinery, such as dip, brush, mechanical blade, applicator table, rolling, spray, curtain, spin, spray (spray) Coating methods such as extruded, printing, and washing have been widely used. However, some of the above techniques, especially those that come into contact with minerals, 1328046 (4) often cause defects such as reticular cracks, surface defects, etc., or as shown in the coating schematic of the conventional technology, on the substrate. 1〇When the surface i is on the surface layer 12 (the thickness is not uniform, or in order to fill the lion-like crack or dissolve, causing the void to be used and excessive material), and need to use too much: here...etc. Or because of the filling of the gap, it affects the surface of the skin or the brightness.
^非碰撞錢為基礎的㈣技術，通常具有避免網狀破 ‘ C等缺點’且在耐久性和表面性質方面具有某些 昂l但疋以非碰撞喷塗為基礎的此類鍍m技術，通常費用 要維護機械錢需耗㈣多溶_介㈣持黏性及 於多上述所提出的改善韻技術的需求。本發明人基 討，與諸多實務經驗，經多方研究設計與專題探 綠色出—種奈米薄麟法及其製造奈米抗菌紙的 去’以作為刖述期望一實現方式與依據。 【發明内容】 有總於上述課題，本發明之目的為提供一 士 ’在綠色化學及奈米科技的基礎上開發链 ㉟未翻鑛 米薄膜製程。 又犋技術，建立綠色奈 菌纸之另—目的為提供—種奈料膜鍍法製造太什 圏/、氏的綠色方法，隨著對綠色化學越來越多的重視， 不未抗 少有毒化學物質、溶劑以及能源的使用，採用 發明以減 —層奈米粒子薄膜，並產生抗菌活性。 Ή 丁在紙張錢上 緣是，為達上述目的，依本發明之奈米薄膜 ' 、又法’首先 1328046 提供一奈米粒子溶液，再以超音波振盪此奈米粒 粒子溶液產生多個氣泡（bubbles);以及再提供一二，不米 下往上碰撞基板。 捉供基板，讓氣泡從 本發明再提出-種以奈米薄膜鍍法製造夺 =’至少包含:提供多個奈米粒子，使奈米 1半广f備奈米粒子溶液；再以超音波振I奈米粒子溶f 保溶 使 奈米粒子溶液產生多個氣泡(bubbles) 提供美:: :氣泡碰梅板；《觸 學的二 =的態使用的溶劑和減‘ 此=::==製=米抗菌紙具有抗 明之方法不_知技術_===)之魏，且本發 =匕真補空隙而耗費過多材料、能原;:陷也= 因此衫響表面性質、光澤或亮度。 .·孚專也不會 功效^二步貴:瞭查;特徵及所達成之 ;;關圖式_佐之用；詳細丄說 1328046 【實施方式】 ▲ ▲以下將參照相關圖式，說明依本發明較佳實施例之奈米 薄膜鍍法及其製造奈米抗菌紙騎色方法，其中相同的元件將 以相同的參照符號加以說明。 Λ r你不赞明之奈米薄膜鍍法及其製造奈米抗菌紙的綠色 f法之較佳實施例，為使便於理解，下述實施例中之元件符 號係沿用與前一實施例中相同元件之符號來說明。^ Non-collision-based (4) technology, usually with the disadvantage of avoiding mesh breaks and other defects in durability and surface properties, but based on non-collision coating. Usually, the cost of maintaining mechanical money is required. (4) Multi-dissolution (4) Viscosity and the need for improved rhythm technology proposed above. The inventor has discussed and developed a variety of practical experience, through a variety of research and design and thematic exploration of green - a kind of nano thin lining method and its manufacture of nano antibacterial papers as a way to explain the realization and basis. SUMMARY OF THE INVENTION In view of the above problems, it is an object of the present invention to provide a process for developing a chain 35 untransparent ore film based on green chemistry and nanotechnology. Another technology, the establishment of green neat paper is another purpose - to provide a green method for the production of Taishi 、 /, a green film, with more and more attention to green chemistry, not less resistant to less toxic The use of chemicals, solvents, and energy sources uses the invention to reduce the thickness of the nanoparticle film and produce antibacterial activity. In the paper money, in order to achieve the above purpose, according to the nano film of the present invention, the method of first method 1328046 provides a nanoparticle solution, and then ultrasonically oscillates the nanoparticle solution to generate a plurality of bubbles (bubbles). ); and provide one or two, not to hit the substrate upside down. Capturing the substrate, allowing the bubbles to be re-proposed from the present invention - the nano-film plating method is used to produce the following: 'At least: providing a plurality of nano particles, so that the nanometer 1 half wide f nanoparticle solution; and then ultrasonic Zhen I nanoparticle dissolves f solubilization so that the nanoparticle solution produces a plurality of bubbles (bubbles) to provide beauty::: bubble touches the board; "the solvent used in the touch of the two = state and subtracts" This =::= = system = rice antibacterial paper has anti-light method does not know the technology _ = = =) Wei, and this hair = 匕 really fill the gap and consume too much material, energy;; also sink = so the shirt surface properties, luster or brightness. .. Fu will not work ^ two steps expensive: check; characteristics and achieved;; off-plan _ Zuozhi; detailed 丄 1328046 [Implementation] ▲ ▲ The following will refer to the relevant schema, explain The nano film plating method of the preferred embodiment of the present invention and the method for manufacturing the nano antibacterial paper riding color, wherein the same elements will be denoted by the same reference numerals. Λ r you do not like the nano film coating method and the green f method for manufacturing the nano antibacterial paper. For ease of understanding, the symbology of the following embodiments is the same as in the previous embodiment. The symbol of the component is used to illustrate.
第2圖為本發明之奈米薄膜鍍法的較佳實施例的流程 圖。如第2 ®所示，首先提供—奈米粒子溶液(步驟•奈米 粒子溶液例如為含衫個二氧化鈦_2)、氧化鋅、氧化銘 (ai2o3)、二氧化矽(Si〇2)或其他視塗層需要的奈米粒子溶液，之後 =超音波振盪奈米粒子溶液(步驟22)，使奈米粒子溶液產生多個 f包(步驟24);叹概供—基板(辣26)，魏·下往上碰 撞基板(步驟28) ’基板即可社奈米_。在本發明t，夺米薄 膜的厚度與顧時間或是超音波織奈餘子溶液_的長触 關’並不是顧時間或超音波振盪奈米粒子溶㈣間越長，奈米、 =膜的厚魏會越厚，奈米_的厚度是與高速縣基板㈣中 不米粒子表_官能基數量以及基板表_官能基數量有關。 以本發明之方法所鑛上的奈米薄膜，並不會像 台或喷塗此等技術的奈米薄膜—樣填滿基板的空隙，造 弟1圖所示’習知技術造成可變的塗層(厚 月了法所鍍上的奈米薄膜，可以隨著基板:面的凹 凸二隙鑛上一層厚度均勻的奈米薄膜。 上述之基板的材質可以是—般物質，包括不财熱物質如紙。 尤其當要社二氧化鈦(Ti〇2)魏鱗_)奈練子時，目前一 般的做法例如化學法、加熱法⑽ernxd methGd)、旋轉塗佈、 喷霧熱裂解(spray Pyr〇lysis)、脈衝雷射積覆㈣⑽丨· deposition)......料，此些方法所需之基板材f為金屬、金屬 氧化物、玻璃或其他熱穩定的材f，然而本發明之方法除可 以適用上述基板外’亦^以適用於例如紙或是其他不耐熱物質 之基板，此為本發明符合專利要件之優點。 上述之奈米粒子溶液之酸驗性可以調整至與基板之酸驗性 相近例如田基板之材板為紙時，奈米粒子溶液之酸驗性可以調 整至與與紙-制_性阳=8，不縣將奈錄子溶液之酸驗 性調整至pH’時也不會有不好的影響，而配製奈米粒子溶液 之溶劑可以為水或其他適合之溶劑。 第3圖為本發明以奈米薄膜鍍法製造奈米抗菌紙的綠色方 法之較佳實施例的裝置示意圖。如第3圖所示，在容器3〇〇 申以例如超音波產生器330產生的超音波332使多個奈米粒子分 散於環保溶劑中，以製備奈米粒子溶液31〇 ;再以例如超音波產 生器330產生的超音波332振盪奈米粒子溶液31〇，使奈米粒子 溶液310產生多個氣泡312 ;之後，提供紙基板35〇，在本實施 例中以一调控裝置37〇控制紙基板350的高度，以讓氣泡312可 以碰撞到紙基板350 ;以及乾燥紙基板350。雖然在本實施例中 是以調控裝置370控制紙基板350的高度來控制氣泡312碰撞紙 基板350的程度’但是在其他的狀況下，是可以設計不同的設備 裝置，以控制氣泡312碰撞紙基板35〇的程度。 在上述實施例中，本發明以調控裝置37()控制紙基板35〇 的高度:以調控氣泡312碰撞紙基板35〇的程度’當紙基板35〇 I觸碰到不米粒子/谷液31〇表面時，可以只在紙基板现觸碰 到奈米粒子溶液31〇的那一面錢上奈米薄膜，如此可以減少奈 ^粒子及溶_使職，料由於本㈣之方法賴上的奈米 =可以隨著紙基板表面的凹凸空隙，鑛上—層厚度均勻的奈米 、：因此可以讓紙基板仍保有其表面之粗才造度，卩幫助擦拭 或書寫等料表面特性’也不影·板表面光澤或其他特性。 上述之奈米粒子當為二氧化鈦⑺⑹或氧化辞(Zn〇)奈米粒 時，以本發明之奈米薄膜鍍法可製得具有抗菌活性的紙，例 =以抵抗大腸桿邮⑺Η 11634)，而且使用環縣劑例如水 =他適合的溶劑時’更不會有如其他使用有機溶劑的製程 $環境科，此本發明時_飾練造奈米抗菌紙， 付σ作為綠色化學的環保方法。 上述之奈米粒子溶液之酸驗性可以調整至與基板之酸驗性 才目近’例如當基板之材質為紙時，奈米粒子溶液之酸雜可以利 崎加氫氧倾_獨難至與錢—樣㈣鹼性ρ胁不過 =將奈米粒子溶液之酸鹼性調整至ρΗ，時，對於鑛膜效率也無 “、者的影響，⑽有-點值得注意的是，由於氫氧化錢卿〇η) 1328046 會解離成而4 H 0Η·，其巾_+會吸附於二氧化鈦(Ti⑹或氧化 辞(ZnO)奈米粒子上，可以避免後繼的奈来粒子繼續鍍上，因此 可以維持一定的臈膜。 此外在刀政奈米粒子於環保溶劑中的步驟前，更可以先將 奈米粒子做預處理，例如先在45〇。€溫度做預熱處理，此做法可 以去除吸附於奈米粒子表面的有機污染物。再者 ’這些附著於Fig. 2 is a flow chart showing a preferred embodiment of the nano film plating method of the present invention. As shown in the 2nd ®, first provide a nanoparticle solution (step • nanoparticle solution such as a titanium dioxide containing _2), zinc oxide, oxidized indium (ai2o3), cerium oxide (Si〇2) or other Depending on the nanoparticle solution required for the coating, followed by the ultrasonically oscillating nanoparticle solution (step 22), the nanoparticle solution is subjected to a plurality of f-packages (step 24); the sigh is supplied to the substrate (spicy 26), Wei · Bumping the substrate up and down (step 28) 'The substrate can be sina _. In the present invention t, the thickness of the rice film and the time or the long-touch of the ultrasonic woven nano solution _ is not the time or the ultrasonic vibration of the nanoparticle solution (four), the nanometer, = film The thicker the thicker Wei, the thickness of the nanometer is related to the number of non-rice particles in the high-speed county substrate (four), the number of functional groups, and the number of substrates. The nano film deposited by the method of the present invention does not fill the gap of the substrate like a nano film of the same or sprayed technology, and the conventional technology causes the variable to be changed. The coating (the nano-film coated by the thick moon method can be coated with a uniform thickness of nano-film on the surface of the substrate: the surface of the substrate can be a general substance, including no heat Substance such as paper. Especially when it is required to use titanium dioxide (Ti〇2) Wei scale _), the current general practice such as chemical method, heating method (10) ernxd methGd), spin coating, spray pyrolysis (spray Pyr〇lysis) ), pulsed laser accumulation (4) (10) 丨 · deposition) ... material, the substrate f required for such methods is metal, metal oxide, glass or other thermally stable material f, however, the method of the present invention In addition to the above-mentioned substrate, it is also suitable for substrates such as paper or other heat-resistant materials, which is an advantage of the invention in accordance with the patent requirements. The acidity of the above-mentioned nanoparticle solution can be adjusted to be close to the acidity of the substrate. For example, when the substrate of the substrate is paper, the acidity of the nanoparticle solution can be adjusted to be compatible with paper-based cations. 8, the county will not have a bad influence on the acidity of the Naizi solution to pH', and the solvent for preparing the nanoparticle solution may be water or other suitable solvent. Fig. 3 is a schematic view showing the apparatus of the preferred embodiment of the green method for producing nano antibacterial paper by nano film plating. As shown in FIG. 3, the ultrasonic wave 332 generated by, for example, the ultrasonic generator 330 is applied to the container 3 to disperse a plurality of nano particles in an environmentally friendly solvent to prepare a nanoparticle solution 31; The ultrasonic wave 332 generated by the sound wave generator 330 oscillates the nanoparticle solution 31〇, and causes the nanoparticle solution 310 to generate a plurality of bubbles 312. Thereafter, the paper substrate 35 is provided, and in this embodiment, the paper is controlled by a regulating device 37〇. The height of the substrate 350 is such that the bubbles 312 can collide with the paper substrate 350; and the paper substrate 350 is dried. Although in the present embodiment, the height of the paper substrate 350 is controlled by the regulating device 370 to control the extent to which the bubble 312 collides with the paper substrate 350, but in other cases, different device devices can be designed to control the bubble 312 to collide with the paper substrate. 35 degrees. In the above embodiment, the present invention controls the height of the paper substrate 35〇 by the regulating device 37(): to adjust the extent to which the bubble 312 collides with the paper substrate 35. 'When the paper substrate 35〇I touches the non-rice/grain 31 When the surface of the crucible is on the surface of the paper, it is possible to touch the surface of the nanoparticle solution 31 〇 on the paper, so that the nano-particles and the solution can be reduced, so that the method depends on the method of (4) m = can be along with the concave and convex gaps on the surface of the paper substrate, the mineral layer - uniform thickness of the nano, so that the paper substrate can still retain the thickness of its surface, 卩 help wipe or write surface characteristics of the material ' Shadow plate surface gloss or other characteristics. When the above-mentioned nano particles are titanium dioxide (7) (6) or oxidized (Zn) nanoparticles, the paper having antibacterial activity can be obtained by the nano film plating method of the present invention, for example, to resist the large intestine (7) Η 11634), and When using a ring-age agent such as water = a solvent suitable for him, 'there is no other process such as the use of an organic solvent, the environmental department. In the present invention, the nano-antibacterial paper is reinforced, and σ is used as an environmentally friendly method for green chemistry. The acidity of the above-mentioned nanoparticle solution can be adjusted to be close to the acidity of the substrate. For example, when the material of the substrate is paper, the acid particles of the nanoparticle solution can be hydrolyzed by Lisaki. And the money-like (four) alkaline ρ 不过 = = = to adjust the acidity and alkalinity of the nanoparticle solution to ρ Η, when there is no effect on the membrane efficiency, (10) Yes - note that due to oxidization钱卿〇η) 1328046 will dissociate into 4 H 0Η·, its towel _+ will be adsorbed on titanium dioxide (Ti(6) or oxidized (ZnO) nanoparticles, which can prevent subsequent Nailai particles from continuing to plate, so it can be maintained A certain ruthenium film. In addition, before the step of Kyoko nanoparticles in an environmentally friendly solvent, the nanoparticles can be pretreated first, for example, at a temperature of 45 〇. Organic pollutants on the surface of nanoparticles. Again, these are attached to
奈米粒子表面的有機污染物，已知會影響光學性及催化特性， 但是去除有機污染物需要高溫處理，此一製程步驟並不適用於 例如紙類等不耐熱的物質，因此本發明可以先以例如45〇〇c 的溫度做預熱處理’以去除或減少吸附於奈米粒子表面的有機 污染物，再繼續進行後續鍍膜的製程步驟，因此本發明可以 使用紙類等不耐熱的物質作為基板材質。 以上所述僅為舉例性，而非為限制性者。任何未脫離本 發明之精神與範疇，而對其進行之等效修改或變更，均應包 含於後附之申請專利範圍中。 【圖式簡單說明】 第1圖為習知缝膜技術的塗層示意圖； 第2圖為本發明之奈米薄膜鍍法的較佳實施例的流程圖；以 及 第3圖為本發明以奈米薄膜鍍法製造奈米抗菌紙的綠色方法 之較佳實施例的骏置示意圖。 1328046 【主要元件符號說明】 10 :基材； 12 :塗層； 20 :提供一奈米粒子溶液； 22 :以超音波振盪奈米粒子溶液； 24 :奈米粒子溶液產生多個氣泡； 26 :提供一基板；Organic contaminants on the surface of nanoparticles are known to affect optical and catalytic properties, but high temperature treatment is required to remove organic contaminants. This process step is not suitable for heat-labile substances such as paper. Therefore, the present invention can be For example, the temperature of 45 〇〇c is pre-heat treated to remove or reduce the organic pollutants adsorbed on the surface of the nanoparticles, and the subsequent coating process is continued. Therefore, the present invention can use a heat-resistant substance such as paper as a substrate. Material. The above is intended to be illustrative only and not limiting. Any equivalent modifications or alterations to the spirit and scope of the invention are intended to be included in the scope of the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view of a coating of a conventional slit film technique; Fig. 2 is a flow chart of a preferred embodiment of a nanofilm plating method of the present invention; and Fig. 3 is a view of the present invention A schematic diagram of a preferred embodiment of a green method for producing nano antibacterial paper by rice film plating. 1328046 [Description of main component symbols] 10: substrate; 12: coating; 20: providing one nanoparticle solution; 22: ultrasonically oscillating nanoparticle solution; 24: nanoparticle solution generating multiple bubbles; 26: Providing a substrate;
28 :讓氣泡碰撞基板； 300 :容器； 310 :奈米粒子溶液； 312 :氣泡； 330 :超音波產生器； 332 :超音波； 350 :紙基板；以及 370 :調控裝置。28: let the bubble collide with the substrate; 300: container; 310: nanoparticle solution; 312: bubble; 330: ultrasonic generator; 332: ultrasonic; 350: paper substrate; and 370: regulating device.