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TW201717662A - Loudspeaker component including an accommodating room, a diaphragm, a screening element, and a plurality of porous granules - Google Patents

Loudspeaker component including an accommodating room, a diaphragm, a screening element, and a plurality of porous granules Download PDF

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Publication number
TW201717662A
TW201717662A TW104137237A TW104137237A TW201717662A TW 201717662 A TW201717662 A TW 201717662A TW 104137237 A TW104137237 A TW 104137237A TW 104137237 A TW104137237 A TW 104137237A TW 201717662 A TW201717662 A TW 201717662A
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Taiwan
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chamber
particles
porous particles
porous
speaker element
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TW104137237A
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Chinese (zh)
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Bo-Yu Chen
Chen-Mao Yang
yi-lin Xie
Hong-Ping Lin
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Merry Electronics Co Ltd
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Priority to TW104137237A priority Critical patent/TW201717662A/en
Publication of TW201717662A publication Critical patent/TW201717662A/en

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Abstract

A loudspeaker component includes an accommodating room, a diaphragm, a screening element, and a plurality of porous granules. The accommodating room is defined into two chambers by the diaphragm. The chamber in which the screening element is located is segmented into a filling space. The plurality of porous granules are filled in the filling space according to a filling ratio. A single porous granule includes a plurality of porous particles and is formed by combining the plurality of porous particles through a granulation procedure. As such, the porous granule can absorb air so as to allow the loudspeaker component to keep a miniature size and provide a superior electroacoustic feature.

Description

揚聲器元件 Speaker component

本發明涉及一種揚聲器元件,特別是一種微機電揚聲器元件,具有微型尺寸與優越的電聲性質。 The present invention relates to a speaker component, and more particularly to a microelectromechanical speaker component having a miniature size and superior electroacoustic properties.

因應消費性電子產品微型化的市場需求,微機電(Micro Electro Mechanical Systems,以下簡稱MEMS)技術因應而生,在電聲領域發展有聲波轉換至電訊號的MEMS揚聲器;MEMS揚聲器在保持微型尺寸的同時,也有較佳的性躁比、靈敏度、溫度穩定性等等特性,因此廣受消費者青睞。然而,微型化既是MEMS揚聲器的優勢,也相對有先天的限制。如MEMS揚聲器晶片中前腔與背腔的空間相當狹小,在有限空間的情況下空氣阻力過大將影響振膜振動,尤其背腔(back chamber)是使外部音波形成共振的空間,而低頻段音波相對其他頻段又需要更大的共振空間,因此對背腔空間的擴增,以取得MEMS揚聲器晶片具有較佳的靈敏度、頻率響應曲,為業界追求的目標之一。 In response to the market demand for miniaturization of consumer electronics, Micro Electro Mechanical Systems (MEMS) technology has evolved to develop MEMS speakers with acoustic waves converted to electrical signals in the field of electro-acoustics; MEMS speakers are maintaining miniature dimensions. At the same time, it also has better characteristics such as sex ratio, sensitivity, temperature stability, etc., so it is widely favored by consumers. However, miniaturization is both an advantage of MEMS speakers and a relatively innate limitation. For example, in the MEMS speaker chip, the space between the front cavity and the back cavity is quite narrow. In the case of limited space, the air resistance is too large, which will affect the vibration of the diaphragm. In particular, the back chamber is a space for the external sound waves to resonate, and the low frequency sound wave. It requires a larger resonance space than other frequency bands. Therefore, it is one of the goals pursued by the industry to amplify the back cavity space to obtain a better sensitivity and frequency response of the MEMS speaker chip.

因此,業界提出一種改善背腔共振的方式,在背腔內設有多孔材料,孔洞可以吸附空氣,被多孔材料所吸附的空氣在振動時同時帶動多孔材料振動,因此可改變背腔內部的共振頻率,其效果相當於增加背腔體積,進而達到有限的尺寸內虛擬出一個擴增的背腔。 Therefore, the industry proposes a way to improve the back cavity resonance. A porous material is arranged in the back cavity, and the hole can adsorb air. The air adsorbed by the porous material simultaneously drives the porous material to vibrate when vibrating, thereby changing the resonance inside the back cavity. The frequency, the effect is equivalent to increasing the volume of the back cavity, thereby achieving an enlarged back cavity within a limited size.

2012年12月18日公告之美國專利號US 8,335,333 B2,專利名 稱「LOUDSPEAKER SYSTEM」,申請人松下電器(Panasonic Corporation)公開在背腔內設有複數粒子,粒子間以黏著劑相連結以保持粒子間距,且粒子可以選用自帶多孔特性的材料,如碳、二氧化矽、沸石等。因此,單一粒子本身的孔隙、以及粒子與粒子間的空隙都可充填空氣。 US Patent No. 8,335,333 B2, published on December 18, 2012, patent name The so-called "LOUDSPEAKER SYSTEM", the applicant Panasonic Corporation disclosed that there are a plurality of particles in the back cavity, the particles are connected by an adhesive to maintain the particle spacing, and the particles can be selected from materials with porous properties, such as carbon, Ceria, zeolite, etc. Therefore, the pores of the single particles themselves, as well as the voids between the particles and the particles, can be filled with air.

2013年7月4日公告之美國專利「LOUDSPEAKER SYSTEM WITH IMPROVED SOUND」,其公告號US 2013/0170687 A1,申請人樓氏(Knowles Corporation)公開一種麥克風裝置在背腔設有沸石(Zeolite)材料,沸石材料呈微粒狀且沸石微粒的矽/鋁之質量比大於200,沸石微粒的粒徑分布為0.2mm~0.9mm,由沸石材料的自身特性以及製程設計,可形成大小不一的孔洞,其孔徑分布在0.7μm~30μm。充滿在沸石孔洞的空氣同時帶動沸石在背腔內振動,改變了背腔的共振頻率,進而虛擬出擴增的背腔。 U.S. Patent "LOUDSPEAKER SYSTEM WITH IMPROVED SOUND", published on July 4, 2013, the disclosure of which is incorporated herein by reference in its entirety by its its its its its The zeolitic material is in the form of particles and the mass ratio of cerium/aluminum of the zeolite particles is more than 200, and the particle size distribution of the zeolite particles is 0.2 mm to 0.9 mm. The granule material has its own characteristics and process design, and can form pores of different sizes. The pore size distribution is from 0.7 μm to 30 μm. The air filled in the pores of the zeolite simultaneously drives the zeolite to vibrate in the back cavity, changing the resonance frequency of the back cavity, thereby virtualizing the amplified back cavity.

類似的概念在2014年4月1日美國專利「LOUDSPEAKER SYSTEM」公告之專利號為US 8,687,836 B2也有提及。申請人博士音響(Bose Corporation)公開一種以矽為基礎的沸石材料,並至少混合金屬鋁,且矽/鋁之莫耳比在200~400之間;同樣的,此材料也是放在一個可以形成共振的空間。 A similar concept is also mentioned in US Patent No. 8,687,836 B2, issued on April 1, 2014, to the US patent "LOUDSPEAKER SYSTEM". Applicant Bose Corporation discloses a cerium-based zeolitic material with at least metal aluminum mixed with a 矽/aluminum molar ratio between 200 and 400; likewise, this material is also placed in one that can be formed The space of resonance.

2014年7月1日專利公告號為US 8767998 B2之美國專利「PRESSURE ADJUSTOR AND METHOD OF MANUFACTURING THE SAME,SPEAKER DEVICE USING THE PRESSURE ADJUSTOR,ELECTRONIC DEVICE,AND VEHICLE」,申請人松下電器(Panasonic Corporation)則公開在背腔裡設有一片狀的織材,織材以黏著劑附著有複數微小碳粒,藉此創造出可以吸附空氣的織材。 U.S. Patent "PRESSURE ADJUSTOR AND METHOD OF MANUFACTURING THE SAME, SPEAKER DEVICE USING THE PRESSURE ADJUSTOR, ELECTRONIC DEVICE, AND VEHICLE" of US Pat. No. 8,767,998 B2, issued on July 1, 2014, the disclosure of which is filed by the applicant Panasonic Corporation A piece of woven material is placed in the back cavity, and the woven material is adhered with a plurality of tiny carbon particles by an adhesive to create a woven material that can absorb air.

然而,儘管在背腔設有多孔材料的先前技術已前仆後繼,產業上卻仍然有改善的空間,例如碳本身的孔隙不易形成,吸附效果不佳;沸石為晶矽材料,成晶製程仍要求相當的精密度與時間,使製作成本提高;此外,具有氣體吸附功能的結晶材料有明顯的老化衰退現象,導致產品使用壽命較短。因此,兼顧優越的微型尺寸與電聲性質的同時,進一步追求製程效率與降低成本,還是為業界亟待克服的議題。 However, although the prior art in which the porous material is provided in the back cavity has been preceded, there is still room for improvement in the industry, for example, the pores of carbon itself are not easily formed, and the adsorption effect is not good; the zeolite is a crystalline material, and the crystal forming process still requires considerable The precision and time make the production cost increase; in addition, the crystalline material with gas adsorption function has obvious aging degradation, resulting in a short service life. Therefore, while taking into account the superior micro-size and electro-acoustic properties, further pursuit of process efficiency and cost reduction is still an urgent issue for the industry.

本發明之目的在於提供一種揚聲器元件,在不受揚聲器種類的限制下,可保持優越的微型尺寸與電聲性質的同時,能進一步達到較高的製程效率與較低的製程/原料成本。 SUMMARY OF THE INVENTION It is an object of the present invention to provide a speaker element which, while being limited by the type of speaker, can maintain superior micro-size and electroacoustic properties while further achieving higher process efficiency and lower process/feedstock costs.

為此,本發明提供一種揚聲器元件,包括一容室、一振膜、一過篩元件、與複數個多孔隙顆粒。容室由振膜定義出第一與第二腔室,其中,振膜間隔出與出音方向相同之第一腔室為前聲腔室,振膜間隔出另一個相對於前聲腔室的第二腔室則為後聲腔室,過篩元件設置於該後聲腔室且區隔出一填充空間,使填充空間與振膜分別位於過篩元件相對二側。複數個多孔隙顆粒按一填充比例填充於後聲腔室之填充空間內,其中,各該多孔隙顆粒由複數個多孔的微粒結合而成,而於所在後聲腔室內的填充空間振動。 To this end, the present invention provides a speaker component comprising a chamber, a diaphragm, a screen element, and a plurality of porous particles. The chamber defines first and second chambers by a diaphragm, wherein the diaphragm is separated from the first chamber in the same direction as the sound exiting chamber, and the diaphragm is spaced apart from the second chamber relative to the front chamber The chamber is a rear sound chamber, and the screen element is disposed in the rear sound chamber and a filling space is partitioned so that the filling space and the diaphragm are respectively located on opposite sides of the screen element. A plurality of porous particles are filled in a filling space of the rear acoustic chamber in a filling ratio, wherein each of the porous particles is formed by combining a plurality of porous particles, and the filling space in the acoustic chamber is vibrated.

因此,本發明所提供的揚聲器元件,特別是應用於訴求輕巧、省電的耳機或手持式裝置內的微型揚聲器上,在較小的機構空間內,使得聲音的共振頻率往中低頻移動,且在擴大頻寬範圍下,導致其聲音細節的表現才能被完整呈現;除此之外,本發明的揚聲器元件在有限的腔室 結構空間下,藉由多孔隙顆粒於所在後聲腔室內的填充空間彼此獨立而能自由振動,透過顆粒各自振動的過程來加大顆粒的比表面積(specific area)的總量,以達到虛擬擴大背腔之效果,進而提升聲音的低頻表現,以維持在較小的尺寸與優異的聲學性質。復又,該等微粒可以由多孔性的非晶質材料所構成,相較於其他晶質材料,非晶質材料更容易藉由製程調整多孔隙顆粒或微粒的粒徑尺寸大小,以及其於所在腔室之填充空間內的填充比率,提高揚聲器元件的可靠度,並維持較低的製程成本。 Therefore, the speaker component provided by the present invention, particularly for use in a compact, power-saving earphone or a micro-speaker in a hand-held device, causes the resonance frequency of the sound to move to the middle and low frequencies in a small mechanism space, and In the extended bandwidth range, the performance of its sound details can be fully presented; in addition, the speaker elements of the present invention are in a limited chamber In the structural space, the porous particles can be freely vibrated independently of each other in the filling space in the rear acoustic chamber, and the total amount of specific areas of the particles is increased by the vibration of the particles to achieve a virtual enlarged back. The effect of the cavity, which in turn enhances the low frequency performance of the sound, to maintain a small size and excellent acoustic properties. Further, the particles may be composed of a porous amorphous material, and the amorphous material is more likely to adjust the particle size and size of the porous particles or particles by the process than the other crystalline materials, and The fill ratio in the fill space of the chamber increases the reliability of the speaker components and maintains low process costs.

10‧‧‧容室 10‧‧‧ Room

11‧‧‧第一腔室 11‧‧‧ first chamber

12‧‧‧第二腔室 12‧‧‧Second chamber

121‧‧‧非填充空間 121‧‧‧Unfilled space

122‧‧‧填充空間 122‧‧‧filled space

20‧‧‧振膜 20‧‧‧Densor

30‧‧‧過篩元件 30‧‧‧ Screening elements

40‧‧‧多孔隙顆粒 40‧‧‧Porous particles

50、50a、50b‧‧‧微粒 50, 50a, 50b‧‧‧ particles

R‧‧‧粒徑 R‧‧‧ particle size

S100、S200、S300、S101~S104、S201~S202‧‧‧步驟 S100, S200, S300, S101~S104, S201~S202‧‧‧ steps

60a‧‧‧懸浮溶液 60a‧‧‧suspension solution

60b‧‧‧膠質流體 60b‧‧‧colloidal fluid

70a‧‧‧霧化器 70a‧‧‧ atomizer

70b‧‧‧快速冷凍容室 70b‧‧‧Quick Freezer Room

71b‧‧‧攪拌機構 71b‧‧‧Agitating mechanism

70c‧‧‧真空室 70c‧‧‧vacuum room

70d‧‧‧冷凝室 70d‧‧‧Condensing room

71d‧‧‧冷凝管 71d‧‧‧Condenser

第1圖為本發明揚聲器元件之第一實施例之結構示意圖;第2為揚聲器元件之背腔產生共振之示意圖;第3圖為本發明揚聲器元件之第二實施例之結構示意圖;第4圖為第1圖之多孔隙顆粒之示意圖;第5圖為本發明揚聲器元件之製作流程圖;第6圖為第3圖步驟S200之製程示意圖;第7圖為相同填充空間的容積、不同填充比例下的阻抗曲線圖;第8圖為顆粒不同粒徑分布下的阻抗曲線圖;以及第9圖為相同填充比例、不同填充空間的容積的阻抗曲線表。 1 is a schematic structural view of a first embodiment of a speaker component of the present invention; 2 is a schematic diagram of resonance of a back cavity of a speaker component; and FIG. 3 is a schematic structural view of a second embodiment of a speaker component of the present invention; FIG. 5 is a schematic diagram of the fabrication of the speaker elements of FIG. 1; FIG. 6 is a schematic diagram of the process of step S200 of FIG. 3; FIG. 7 is a volume of the same filling space, and different filling ratios. The impedance curve is shown below; Figure 8 is the impedance curve of the particle size distribution; and Figure 9 is the impedance curve of the volume with the same filling ratio and different filling spaces.

請參閱第1~2圖,係本發明之一種揚聲器元件的第一實施例,包括:一容室10、一振膜20、一過篩元件30、與複數個大小概略均勻的多孔隙顆粒40。振膜20設於容室10間隔並定義出一第一腔室11及一第二 腔室12;第一腔室11為與出音方向S相同之前聲腔室,第二腔室12為相對於前聲腔室的後聲腔室。過篩元件30則設於第二腔室12內區隔且定義出一非填充空間121與一填充空間122;詳而言之,填充空間122與振膜20分別位於過篩元件30之相對二側,因此填充空間122藉過篩元件30與振膜20間存在的非填充空間121,而相距振膜20一預定距離d;而容室10根據一容積比例決定填充空間122在容室10所佔的容積,填充空間122根據一填充比例決定該等多孔隙顆粒40在填充空間122所填充的容積。 Referring to FIGS. 1-2, a first embodiment of a speaker component of the present invention includes a chamber 10, a diaphragm 20, a screen element 30, and a plurality of uniformly sized porous particles 40. . The diaphragm 20 is disposed at the chamber 10 and defines a first chamber 11 and a second The chamber 12; the first chamber 11 is the same acoustic chamber as the sounding direction S, and the second chamber 12 is the rear acoustic chamber with respect to the front acoustic chamber. The sieving element 30 is disposed in the second chamber 12 and defines an unfilled space 121 and a filling space 122; in detail, the filling space 122 and the diaphragm 20 are respectively located opposite to the sifting element 30. On the side, the filling space 122 is separated from the diaphragm 20 by a predetermined distance d between the screen element 30 and the diaphragm 20, and the chamber 10 determines the filling space 122 in the chamber 10 according to a volume ratio. The volume occupied by the filling space 122 determines the volume filled by the porous particles 40 in the filling space 122 according to a filling ratio.

其中,第一腔室11之開口僅概示而不拘束本實施例;其中,多孔隙顆粒40本身是由複數個多孔的非晶質的微粒50以黏著劑結合而成,而該等多孔隙顆粒40彼此各自獨立,而可於所在第二腔室12內的填充空間122中振動。 Wherein, the opening of the first chamber 11 is merely illustrative and not limited to the embodiment; wherein the porous particles 40 themselves are formed by combining a plurality of porous amorphous particles 50 with an adhesive, and the porous The particles 40 are independent of one another and can vibrate in the fill space 122 located within the second chamber 12.

由於非晶質材料是不具有晶界與長程規律性的非結晶態,不必具備穩定的長晶環境與足夠的長晶時程,因此非晶質材料對於製作時程的要求較短、成本也較低;前述的非晶質的微粒50便是由非結晶態(不具有晶界與長程規律性,僅具有短程規律性)的多孔性的非晶質材料所製成。前述材料可選自多孔性材料如:活性碳(activated carbon)、沸石(Zeolite)、二氧化矽(SiO2)、氧化鋁(Al2O3)、氧化鋯(ZrO2)、氧化鎂(MgO)、四氧化三鐵(Fe3O4)、分子篩(Molecular sieve)、富勒烯(Fullerene)與奈米碳管(Carbon Nanotude)其中之一及其所構成之群組;而前述粘著劑則可以使用粉末狀樹脂材料(Powdery Resin Material)或是纖維狀樹脂材料(Fibrous Resin Material)。在本實施例中,多孔隙顆粒40的粒徑R分布為100μm~500μm;微粒50是由非晶質的二氧化矽所製成,其粒徑範圍可以為10nm~100μm;此 外,多孔隙顆粒40彼此各自獨立並隨機堆疊,不按照一定空間順序排列,於所在的第二腔室12(後聲腔室)的填充空間122內獨立且自由振動,產生如第2圖所示充滿於填充空間122內的產生自由振動現象。 Since the amorphous material is amorphous without grain boundary and long-range regularity, it is not necessary to have a stable growth environment and sufficient crystal growth time, so the amorphous material requires less time and cost. Lower; the aforementioned amorphous particles 50 are made of a porous amorphous material having an amorphous state (having no grain boundary and long-range regularity, and having only a short-range regularity). The foregoing materials may be selected from porous materials such as activated carbon, Zeolite, SiO 2 , alumina (Al 2 O 3 ), zirconia (ZrO 2 ), magnesium oxide (MgO). , one of triiron tetroxide (Fe 3 O 4 ), molecular sieve (Molecular sieve), fullerene (Fullerene) and carbon nanotube (Carbon Nanotude) and a group thereof; and the aforementioned adhesive A powdered resin material (Powdery Resin Material) or a fibrous resin material (Fibrous Resin Material) can be used. In the present embodiment, the particle diameter R of the porous particles 40 is 100 μm to 500 μm; the particles 50 are made of amorphous ceria, and the particle diameter may range from 10 nm to 100 μm; in addition, the porous particles 40 are independently and randomly stacked, are not arranged in a certain spatial order, and are independently and freely vibrated in the filling space 122 of the second chamber 12 (rear sound chamber) in which they are located, resulting in being filled in the filling space 122 as shown in FIG. The phenomenon of free vibration inside.

本發明的過篩元件30設於該等多孔隙顆粒40所在第二腔室12的填充空間122內,使該等多孔隙顆粒40相距振膜20有前述的預定距離d,以避免振膜20振動時,受到多孔隙顆粒40的干擾而產生異音。過篩元件30是由透氣材料組成,以達到保持透氣順暢,又可阻擋多孔隙顆粒40與振膜20接觸造成元件損壞。過篩元件30具有複數網目31,而該等網目31之尺寸小於該等多孔隙顆粒40之粒徑,且該等網目31之尺寸至少於100μm以上,使得過篩元件30透氣順暢,空氣仍可在第二腔室12各角落不受拘束並自由振動。 The screening element 30 of the present invention is disposed in the filling space 122 of the second chamber 12 in which the porous particles 40 are located, such that the porous particles 40 are spaced apart from the diaphragm 20 by a predetermined distance d as described above to avoid the diaphragm 20 When vibrating, it is disturbed by the porous particles 40 to generate an abnormal sound. The sieving element 30 is composed of a gas permeable material to maintain a smooth venting, and to block the contact of the porous particles 40 with the diaphragm 20 to cause component damage. The sieving element 30 has a plurality of meshes 31, and the size of the meshes 31 is smaller than the particle size of the porous particles 40, and the size of the meshes 31 is at least 100 μm or more, so that the sieving element 30 is ventilated smoothly, and the air can still be The corners of the second chamber 12 are unconstrained and free to vibrate.

影響第二腔室12的共振頻率,至少取決於多孔隙顆粒40本身的多孔性、多孔性顆粒40本身的粒徑分布、多孔性顆粒40於填充空間122內的填充比例、填充空間122於容室10的容積比例等因素。 The resonance frequency affecting the second chamber 12 depends at least on the porosity of the porous particles 40 itself, the particle size distribution of the porous particles 40 itself, the filling ratio of the porous particles 40 in the filling space 122, and the filling space 122. Factors such as the volume ratio of the chamber 10.

由於多孔隙顆粒40本身的多孔性則取決於微粒50、以及微粒50與微粒50間的堆疊方式與成形狀態,而本發明之微粒50與多孔隙顆粒40的實現方式、以及揚聲器元件具備前述多孔隙顆粒40的實現方式,請參閱第5圖之步驟如下:步驟S100,製成多孔的非晶質二氧化矽微粒50;步驟S200,對多孔的非晶質二氧化矽微粒50進行造粒使成為多孔隙顆粒40;以及步驟S300,將眾多的多孔隙顆粒40填充至第二腔室12。其中,於步驟S100中,發明人係採用凝膠法合成多孔的非晶質的二氧化矽,不同的濃度與時間會產出不同的孔徑與比例,其過程概述如下: 首先,步驟S101,置備三種溶液,其一為聚乙二醇(Polyethylene Glycol,PEG)溶液,在本實施例係由4克(g)的PEG溶於水中並攪拌溶解所形成;次為矽酸鈉(Sodium Silicate,S.S.)溶液,在本實施例係由16g的S.S.溶於水中所形成;以及酸型緩衝溶液(Acid Buffer Solution),在本實施例係由檸檬酸(Citric Acid)與氫氧化鈉(Sodium hydroxide)混合而成的溶液。接著執行步驟S102,混合前述三種溶液並靜置數小時,其較佳為2小時。然後進入步驟S103,對前述的混和溶液進行水熱處理(Hydrothermal treatment),其較佳為置於環境溫度為攝氏100度之下反應數小時,以調整反應物的物化性質而不破壞反應物結構。最後進行步驟S104,將前述反應物過濾後並經過不同溫度的鍛燒(至少一次),取得粉末態的非晶質二氧化矽微粒,且每一個非晶質二氧化矽微粒50均佈滿大小不一的孔徑。 Since the porosity of the porous particles 40 itself depends on the particles 50 and the manner in which the particles 50 and the particles 50 are stacked and formed, the implementation of the particles 50 and the porous particles 40 of the present invention, and the speaker elements are provided as described above. For the implementation of the pore particles 40, refer to the steps of FIG. 5 as follows: in step S100, porous amorphous cerium oxide particles 50 are formed; and in step S200, the porous amorphous cerium oxide particles 50 are granulated. The porous particles 40 are formed; and in step S300, a plurality of porous particles 40 are filled into the second chamber 12. Wherein, in step S100, the inventors synthesize porous amorphous ceria by a gel method, and different concentrations and times produce different pore sizes and ratios, and the process is summarized as follows: First, in step S101, three solutions are prepared, one of which is a polyethylene glycol (PEG) solution, which is formed by dissolving 4 g (g) of PEG in water and stirring and dissolving in this embodiment; A sodium (Sodium Silicate, SS) solution, which is formed by dissolving 16 g of SS in water in this embodiment; and an Acid Buffer Solution, in this embodiment, citric acid and hydrogen peroxide. A solution of sodium hydroxide mixed. Next, in step S102, the above three solutions are mixed and allowed to stand for several hours, which is preferably 2 hours. Then, proceeding to step S103, the aforementioned mixed solution is subjected to a hydrothermal treatment, which is preferably placed at an ambient temperature of 100 degrees Celsius for several hours to adjust the physicochemical properties of the reactants without destroying the reactant structure. Finally, in step S104, the reactants are filtered and subjected to calcination at different temperatures (at least once) to obtain amorphous cerium oxide particles in a powder state, and each of the amorphous cerium oxide particles 50 is covered in size. Different apertures.

採用凝膠法產出粉末態的多孔的非晶質二氧化矽微粒50至少可達到兩種效果:一、製程便捷與效率;二、矽原料的純度不必過度要求。因此原料取得較容易,取得價格也較合理,原料的成本可大幅降低。 The use of the gel method to produce the porous amorphous ceria particles 50 in a powder state can achieve at least two effects: first, the process is convenient and efficient; and the purity of the raw material of the crucible is not excessively required. Therefore, the raw materials are easier to obtain, the prices are reasonable, and the cost of raw materials can be greatly reduced.

於步驟S200中,造粒(Granulation)過程採噴塗冷凍製程(Spray Freezing Process)與低溫乾燥製程(Freeze Drying Process)進行造粒;在步驟S200中,粉末態的非晶質二氧化矽微粒50每經過一個程序,都有可能因為黏著劑與其他的微粒50結合而逐漸變大;現概述過程如下:步驟S201,將粉末態的非晶質二氧化矽微粒50先與黏著劑、分散劑混合成一懸浮溶液60a,暫時稱此時的微粒為中間態的非晶質二氧化矽微粒50a;再混以施壓的氣體(Air),使懸浮溶液60a通過一霧化器70a以霧化態噴灑進一快速冷凍容室70b;此時,懸浮溶液60a膠質化為一膠質 流體60b,而可使中間態的非晶質二氧化矽微粒50a通過冷凍環境與黏著劑的充分作用之下,彼此結合呈較大微粒的非晶質二氧化矽微粒50b。快速冷凍容室70b於底部設有攪拌機構71b,可以攪拌容室內膠質流體60b,以提高中間態的非晶質二氧化矽微粒50a彼此接觸的機會,使中間態的非晶質二氧化矽微粒50a更容易形成呈較大的非晶質二氧化矽微粒50b的半成品。 In step S200, the granulation process is granulated by a spray freezing process and a freeze drying process (Freeze Drying Process); in step S200, the powdered amorphous cerium oxide particles 50 are each After a procedure, it is possible that the adhesive gradually becomes larger due to the bonding of the other particles 50; the process is as follows: in step S201, the amorphous amorphous ceria particles 50 are first mixed with an adhesive and a dispersant. Suspension solution 60a, temporarily called the particles in the intermediate state of amorphous ceria particles 50a; mixed with a pressurized gas (Air), so that the suspension solution 60a is sprayed into the atomized state through an atomizer 70a Quickly freezing the chamber 70b; at this time, the suspension solution 60a is gelatinized into a gel The fluid 60b allows the amorphous ceria particles 50a in the intermediate state to be combined with the amorphous ceria particles 50b which are larger particles by the sufficient action of the freezing environment and the adhesive. The quick freezing chamber 70b is provided with a stirring mechanism 71b at the bottom, which can stir the colloidal fluid 60b in the chamber to increase the chance of the intermediate amorphous cerium oxide particles 50a contacting each other, and the intermediate amorphous cerium oxide particles. 50a is more likely to form a semi-finished product having larger amorphous ceria particles 50b.

接著進行步驟S202進行冷凍乾燥,將半成品的非晶質二氧化矽微粒50b置入一真空室70c,藉由低溫與真空環境而讓水分發生昇華,水分從真空室70c被帶至冷凝室70d,藉由冷凝管71d進行冷凝,而原本的非晶質二氧化矽微粒50b與膠質流體60b則在冷凍乾燥之後形成多孔隙顆粒40。其中,真空室70c的溫度要介於快速冷凍容室70b與冷凝室70d的溫度之間,使膠質流體60b的水分在進入真空室70c時能發生氣化。快速冷凍容室70b以充填液態氮使容室內溫度保持在相當於液態氮沸點的攝氏零下196度(-196℃),而冷凝室80則控制在攝氏零下30度(-30℃)。造粒後的成品為外型不規則的多孔隙顆粒40,其粒徑為100μm~500μm不等;其中,粉末態的非晶質二氧化矽微粒50與微粒50之間的結合是以黏著劑結合,並且該等微粒50彼此粒徑可能不一、微粒50與微粒50間的間距也可能不一。 Next, the step S202 is performed to freeze-dry, and the semi-finished amorphous ceria particles 50b are placed in a vacuum chamber 70c, and the moisture is sublimated by the low temperature and the vacuum environment, and the moisture is taken from the vacuum chamber 70c to the condensation chamber 70d. The condensation is carried out by the condenser 71d, and the original amorphous ceria particles 50b and the colloidal fluid 60b form the porous particles 40 after freeze-drying. The temperature of the vacuum chamber 70c is between the temperature of the rapid freezing chamber 70b and the condensation chamber 70d, so that the moisture of the colloidal fluid 60b can be vaporized when entering the vacuum chamber 70c. The fast freezing chamber 70b is filled with liquid nitrogen to maintain the chamber temperature at 196 degrees Celsius (-196 ° C) below the boiling point of liquid nitrogen, while the condensation chamber 80 is controlled at minus 30 degrees Celsius (-30 ° C). The granulated product is an irregular irregular porous particle 40 having a particle diameter ranging from 100 μm to 500 μm; wherein the binding between the powdered amorphous cerium oxide microparticle 50 and the microparticle 50 is an adhesive. In combination, and the particles 50 may have different particle sizes from one another, the spacing between the particles 50 and the particles 50 may also vary.

值得說明的是,該等微粒50是呈粉末態的非晶質二氧化矽,正因為微粒50的為非晶質材料製作而成,其粒徑尺寸較晶質材料更容易控制、且成本更低;而且由多個粒徑均勻的微粒50組合的多孔隙顆粒40,因為其堆疊較穩定也較密,從而提高比表面積(Specific Surface Area),因此其吸附空氣的效果更好。具體而言,在本實施例中粉末態的非晶質二氧化矽微粒50的粒徑分布在2μm以下或分布在1~2μm,或者在同一的多孔隙顆粒40 中,該等微粒50係可以區辨出一最大微粒與一最小微粒,而最大微粒與最小微粒間的粒徑差異在1μm以下,或者,前述兩條件並存。前述對微粒50的粒徑所加諸的具體限制,便是為提供由粒徑相近的微粒50組合的多孔隙顆粒40,使之具有較大的比表面積,提供較佳的氣體吸附功能;此外,也可使造粒時,粒徑均勻的微粒50彼此堆疊可形成較密堆積,使得各個多孔隙顆粒40的結構與尺寸都較為均勻,除比表面積提高之外也更容易堆疊產生顆粒40呈球體形態的結果。另外,通過前述製程所形成的多孔隙顆粒40,黏著劑於所在的多孔隙顆粒40的重量比為5%~10%。 It should be noted that the particles 50 are amorphous cerium oxide in a powder state, and the particles 50 are made of an amorphous material, and the particle size is easier to control and cost more than the crystalline material. Low; and the porous particles 40 combined by a plurality of particles 50 having a uniform particle diameter are more effective in adsorbing air because the stacking is more stable and denser, thereby increasing the specific surface area. Specifically, in the present embodiment, the powdery amorphous ceria particles 50 have a particle size distribution of 2 μm or less or a distribution of 1 to 2 μm, or the same porous particles 40. The particles 50 can distinguish between a maximum particle and a minimum particle, and the difference in particle size between the largest particle and the smallest particle is less than 1 μm, or both of the foregoing conditions coexist. The foregoing specific limitation imposed on the particle size of the particles 50 is to provide the porous particles 40 combined by the particles 50 having similar particle diameters to have a larger specific surface area, thereby providing a better gas adsorption function; In the granulation, the particles 50 having uniform particle diameters can be stacked on each other to form a dense packing, so that the structures and sizes of the respective porous particles 40 are relatively uniform, and the particles 40 are more easily stacked in addition to the specific surface area. The result of the shape of the sphere. Further, by the porous particles 40 formed by the foregoing process, the weight ratio of the adhesive to the porous particles 40 is 5% to 10%.

於步驟S300中,將複數個多孔隙顆粒40填充入揚聲器元件第二腔室12的填充空間122中。由於非晶質微粒50不存在結晶材料的缺陷,故不容易產生形變,其物理性質與化學性質也不具有方向性,所以具備比結晶材料更高的強度與耐受性,使得填充非晶質微粒50的揚聲器元件具有更高的產品可靠度。 In step S300, a plurality of porous particles 40 are filled into the filling space 122 of the second chamber 12 of the speaker element. Since the amorphous fine particles 50 do not have defects in the crystalline material, they are not easily deformed, and their physical properties and chemical properties are not directional, so that they have higher strength and resistance than crystalline materials, so that the amorphous particles are filled. The speaker elements of the particles 50 have a higher product reliability.

請同時參閱第7~9圖,為申請人對前列影響第二腔室12的共振頻率的其他因素所提供相關實驗的佐證。如第7圖,在相同填充空間122的容積比例下,多孔隙顆粒40佔據填充空間122的填充比例至少50%,可以提供較佳的共振頻率;並從第7圖可進一步獲知,在其他可能的情況下,多孔隙顆粒40也可以佔據填充空間122的填充比例在70%~90%,填充比例在80%的共振頻率為最佳;即,使振膜20推動時在固定的機構空間內,能使聲音的共振頻率往中低頻移動,達到擴大頻寬範圍之效益,並且在阻尼增加情況下,總諧波失真(Total Harmonic Distortion)降低,振動系統之耐功率也可被提升。換句話說,在本發明之揚聲器元件中,相同填充空間122的容積 比例且相同尺寸(規格)的多孔隙顆粒40的情況下,填充比例50%以上能有效地使共振頻率往中低頻移動。根據前述,多孔隙顆粒40只要可吸附氣體、並於填充空間122各自獨立而自由振動,即能加大該等多孔隙顆粒40的比表面積的總量,若進一步佔據填充空間122的填充比例達50%以上,便能如第7圖中使共振頻率往中低頻移動,進而達到虛擬地擴大第二腔室12(後聲腔室)的技術效果。 Please also refer to Figures 7-9 for the applicant's evidence of the other experiments provided by the other factors affecting the resonant frequency of the second chamber 12. As shown in Fig. 7, at the volume ratio of the same filling space 122, the porous particles 40 occupy at least 50% of the filling space 122, which can provide a better resonance frequency; and it can be further seen from Fig. 7 that other possibilities are possible. In the case of the porous particles 40, the filling ratio of the filling space 122 may be 70% to 90%, and the resonance frequency of the filling ratio of 80% is optimal; that is, the diaphragm 20 is pushed in a fixed mechanism space. The resonance frequency of the sound can be moved to the middle and low frequencies to achieve the benefit of widening the bandwidth range, and the total harmonic distortion (Total Harmonic Distortion) is reduced, and the power consumption of the vibration system can be improved. In other words, in the speaker element of the present invention, the volume of the same filling space 122 In the case of the porous particles 40 of the same size and the same size (specification), the filling ratio of 50% or more can effectively move the resonance frequency to the middle and low frequencies. According to the foregoing, the porous particles 40 can increase the total surface area of the porous particles 40 as long as they can adsorb the gas and are free to vibrate independently of the filling space 122, and further occupy the filling ratio of the filling space 122. More than 50%, the resonance frequency can be shifted to the middle and low frequencies as shown in Fig. 7, thereby achieving the technical effect of virtually expanding the second chamber 12 (the rear sound chamber).

如參閱第8圖,在本發明之揚聲器元件中,相同容積比例與填充比例的情況下,填充不同尺寸(規格)的多孔隙顆粒40亦會影響共振頻率;當所填充的多孔隙顆粒40,其粒徑分布在180μm以上時能有效地獲取較低的共振頻率。值得說明的是,過篩元件30的網目31與多孔隙顆粒40的粒徑存在著一定關係。例如:當該等多孔隙顆粒40之粒徑分布在500μm,該等網目31之尺寸分布於300μm~350μm;當該等多孔隙顆粒40之粒徑分布可在180μm~420μm,該等網目31之尺寸分布於100μm~350μm,只要保持該等網目31之尺寸小於該等多孔隙顆粒40之粒徑即可。 As shown in Fig. 8, in the speaker element of the present invention, in the case of the same volume ratio and filling ratio, filling the different sizes (specifications) of the porous particles 40 also affects the resonance frequency; when the filled porous particles 40, When the particle size distribution is above 180 μm, a lower resonance frequency can be effectively obtained. It is worth noting that the mesh 31 of the screening element 30 has a certain relationship with the particle size of the porous particles 40. For example, when the particle size distribution of the porous particles 40 is 500 μm, the size of the meshes 31 is distributed between 300 μm and 350 μm; and when the particle size distribution of the porous particles 40 is between 180 μm and 420 μm, the meshes 31 The size is distributed from 100 μm to 350 μm as long as the size of the mesh 31 is kept smaller than the particle size of the porous particles 40.

另,在多孔隙顆粒40所在填充空間122之相同填充比例下,不同填充空間122的容積比例也會獲取不同的共振頻率。當填充空間122在容室10的容積比例過大時,如第9圖,揚聲器單體聲音的共振頻率將會受到自由聲場(free field)的影響,此時填充多孔隙顆粒40已沒有太明顯降低共振頻率的效益;因此,多孔隙顆粒40所在的填充空間122,佔據容室10整體的容積比例在15%~25%較佳。 In addition, under the same filling ratio of the filling space 122 where the porous particles 40 are located, the volume ratios of the different filling spaces 122 also acquire different resonance frequencies. When the volume ratio of the filling space 122 in the chamber 10 is excessively large, as shown in Fig. 9, the resonance frequency of the speaker single sound will be affected by the free field, and the filling of the porous particles 40 is not too obvious at this time. The benefit of reducing the resonance frequency; therefore, the filling space 122 in which the porous particles 40 are located preferably occupies 15% to 25% of the volume ratio of the entire chamber 10.

由於本發明所提供的揚聲器元件,特別是應用於訴求輕巧、省電的耳機或手持式裝置內的微型揚聲器上,在較小的機構空間內,使得 聲音的共振頻率往中低頻移動,且在擴大頻寬範圍下,導致其聲音細節的表現才能被完整呈現。因此,透過前述相關實驗的佐證,本發明的確可以在有限的腔室結構下來虛擬擴大第二腔室12的效果,提升聲音的低頻表現,進而提供優越的聲學性能。 Since the speaker element provided by the present invention is particularly applied to a compact speaker, a power-saving earphone or a micro-speaker in a hand-held device, in a small mechanism space, The resonant frequency of the sound moves toward the mid-low frequency, and in the extended bandwidth range, the performance of its sound details can be fully presented. Therefore, through the above-mentioned related experiments, the present invention can virtually expand the effect of the second chamber 12 in a limited chamber structure, improve the low frequency performance of the sound, and thereby provide superior acoustic performance.

復參閱第2圖,為本發明之揚聲器的第二實施例,多孔隙顆粒40所在第二腔室12的填充空間122,係不侷限單一構形的腔室,例如,本實施例中第二腔室12的填充空間122包括一主腔空間1221、一副腔空間1222、以及連接前述兩個次空間1221、1222的橋部1223。第二腔室12的構形並非本發明所問,重點在於:多孔隙顆粒40在第二腔室12內填充空間122中的填充比例、多孔隙顆粒40與微粒50本身的粒徑要求、以及填充空間122佔容室10整體的容積比例,以達到可產生虛擬的擴大背腔的技術效果。因此,本發明之揚聲器元件不局限於微機電揚聲器的種類,亦不侷限於第二腔室12之填充空間122,只要具備有可使多孔隙顆粒產生自由振動的腔室,均為本發明之創作概念所及。 Referring to FIG. 2, a second embodiment of the speaker of the present invention, the filling space 122 of the second chamber 12 in which the porous particles 40 are located is not limited to a single configuration chamber, for example, the second in this embodiment. The filling space 122 of the chamber 12 includes a main cavity space 1221, a sub-cavity space 1222, and a bridge portion 1223 connecting the two sub-spaces 1221, 1222. The configuration of the second chamber 12 is not the subject of the present invention, but focuses on the packing ratio of the porous particles 40 in the filling space 122 in the second chamber 12, the particle size requirements of the porous particles 40 and the particles 50 themselves, and The filling space 122 occupies the volume ratio of the entire volume of the chamber 10 to achieve the technical effect of creating a virtual enlarged back cavity. Therefore, the speaker element of the present invention is not limited to the type of the microelectromechanical speaker, nor is it limited to the filling space 122 of the second chamber 12, as long as it has a chamber capable of freely vibrating the porous particles, which are all of the present invention. The concept of creation is at the same time.

綜上所述,本發明能在保持優越的電聲性質的同時,能進一步達到較低的製程效率與較低的製程/原料成本。本發明及其具體實施例係不侷限於上述例示,其概念透過申請專利範圍的概念與範疇下可為替代或變換。 In summary, the present invention can further achieve lower process efficiency and lower process/feedstock costs while maintaining superior electroacoustic properties. The present invention and its specific embodiments are not limited to the above-described examples, and the concepts may be substituted or changed by the concept and scope of the claims.

10‧‧‧容室 10‧‧‧ Room

11‧‧‧第一腔室 11‧‧‧ first chamber

12‧‧‧第二腔室 12‧‧‧Second chamber

121‧‧‧非填充空間 121‧‧‧Unfilled space

122‧‧‧填充空間 122‧‧‧filled space

20‧‧‧振膜 20‧‧‧Densor

30‧‧‧過篩元件 30‧‧‧ Screening elements

40‧‧‧多孔隙顆粒 40‧‧‧Porous particles

50‧‧‧微粒 50‧‧‧ particles

Claims (21)

一種揚聲器元件,包括:一容室;一振膜,設於該容室內;該容室由該振膜定義出一第一腔室及一第二腔室;一過篩元件,設於該第二腔室內,且區隔出一填充空間,該填充空間與該振膜分別位於該過篩元件之相對二側;以及複數個多孔隙顆粒,依一填充比例填充於該填充空間內;其中,各個多孔隙顆粒由複數個多孔的微粒結合而成。 A speaker component includes: a chamber; a diaphragm disposed in the chamber; the chamber defines a first chamber and a second chamber by the diaphragm; a screening element is disposed in the chamber a chamber, and a filling space is defined, the filling space and the diaphragm are respectively located on opposite sides of the screening element; and a plurality of porous particles are filled in the filling space according to a filling ratio; wherein Each of the porous particles is formed by combining a plurality of porous particles. 如請求項1之揚聲器元件,其中:該等多孔隙顆粒佔據所在該第二腔室之該填充空間容積的50%以上。 The speaker element of claim 1, wherein: the porous particles occupy more than 50% of the volume of the filling space of the second chamber. 如請求項1之揚聲器元件,其中:該等多孔隙顆粒佔據所在該第二腔室之該填充空間的容積之該填充比例在70%~90%。 The speaker element of claim 1, wherein: the porous particles occupy the volume of the filling space of the second chamber at a filling ratio of 70% to 90%. 如請求項1之揚聲器元件,其中:該等多孔隙顆粒之粒徑分布在1mm以下。 The speaker element of claim 1, wherein: the porous particles have a particle size distribution of 1 mm or less. 如請求項4之揚聲器元件,其中:該等多孔隙顆粒之粒徑分布在180μm~420μm。 The speaker element of claim 4, wherein: the porous particles have a particle size distribution of from 180 μm to 420 μm . 如請求項1之揚聲器元件,其中:該等微粒的其粒徑分布在10nm~100μm。 The speaker element of claim 1, wherein: the particles have a particle size distribution of 10 nm to 100 μm. 如請求項6之揚聲器元件,其中:該等多孔的微粒之粒徑分布在2μm以下。 The speaker element of claim 6, wherein: the porous particles have a particle size distribution of 2 μm or less. 如請求項7之揚聲器元件,其中:該等多孔的微粒之粒徑分布在1~2μm。 The speaker element of claim 7, wherein: the porous particles have a particle size distribution of 1 to 2 μm. 如請求項1揚聲器元件,其中:單一多孔隙顆粒中的該等微粒,係區辨出一最大微粒與一最小微粒,而最大微粒與最小微粒間的粒徑差異在1μm以下。 The speaker element of claim 1, wherein: the particles in the single porous particle, the region distinguishes between a maximum particle and a minimum particle, and the difference in particle size between the largest particle and the smallest particle is less than 1 μm. 如請求項1之揚聲器元件,其中:該等微粒是由多孔性非晶質二氧化矽材料所構成。 A speaker element according to claim 1, wherein the particles are composed of a porous amorphous ceria material. 如請求項10之揚聲器元件,其中:該等非晶質二氧化矽微粒為粉末形態。 The speaker element of claim 10, wherein: the amorphous ceria particles are in powder form. 如請求項1之揚聲器元件,其中:該等多孔隙顆粒填充空間佔據所在該容室的容積比例在15%~25%。 The speaker component of claim 1, wherein: the porous particle filling space occupies a volume ratio of the chamber of 15% to 25%. 如請求項1之揚聲器元件,其中:該等多孔的微粒是利用一黏著劑加以結合而形成該等多孔隙顆粒,該黏著劑於所在該多孔隙顆粒的重量比為5%~10%。 The speaker element of claim 1, wherein the porous particles are combined by an adhesive to form the porous particles, and the weight ratio of the adhesive to the porous particles is 5% to 10%. 如請求項13之揚聲器元件,其中:該粘著劑為粉末狀樹脂材料或是纖維狀樹脂材料。 The speaker element of claim 13, wherein the adhesive is a powdery resin material or a fibrous resin material. 如請求項1之揚聲器元件,其中:該等多孔隙顆粒彼此各自獨立,而於所在第二腔室之該填充空間內振動。 The speaker element of claim 1, wherein: the plurality of porous particles are independent of each other and vibrate within the filling space of the second chamber. 如請求項1之揚聲器元件,其中:該過篩元件是由透氣材料組成。 The speaker element of claim 1, wherein: the screening element is comprised of a gas permeable material. 如請求項16之揚聲器元件,其中,該透氣材料包含有複數網目,該等網目之尺寸小於該等多孔隙顆粒之粒徑。 The speaker element of claim 16, wherein the gas permeable material comprises a plurality of meshes having a size smaller than a particle size of the plurality of porous particles. 如請求項17之揚聲器元件,其中:該等網目之尺寸分布於100μm~350μm。 The speaker element of claim 17, wherein: the mesh size is distributed between 100 μm and 350 μm. 如請求項1之揚聲器元件,其中:該等多孔隙顆粒之粒徑分布在180μm~420μm,且該等多孔隙顆粒佔據所在第二腔室之該填充空間的容積的70%~90%,且該填充空間佔據該容室的容積比例在15%~25%。 The speaker element of claim 1, wherein: the porous particles have a particle size distribution of 180 μm to 420 μm, and the porous particles occupy 70% to 90% of the volume of the filling space of the second chamber, and The filling space occupies a volume ratio of the chamber of 15% to 25%. 如請求項1之揚聲器元件,其中:該第一腔室為前聲腔室,該第二腔室為後聲腔室。 The speaker element of claim 1, wherein: the first chamber is a front sound chamber and the second chamber is a rear sound chamber. 如請求項1之揚聲器元件,其中:該等多孔隙顆粒呈球體形態。 The speaker element of claim 1, wherein: the porous particles are in the form of spheres.
TW104137237A 2015-11-11 2015-11-11 Loudspeaker component including an accommodating room, a diaphragm, a screening element, and a plurality of porous granules TW201717662A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10440466B2 (en) 2017-12-07 2019-10-08 Acer Incorporated Speaker module
TWI678932B (en) * 2017-12-07 2019-12-01 宏碁股份有限公司 Speaker module

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10440466B2 (en) 2017-12-07 2019-10-08 Acer Incorporated Speaker module
TWI678932B (en) * 2017-12-07 2019-12-01 宏碁股份有限公司 Speaker module

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