201109475 六、發明說明： 【發明所屬之技術領域】 本發明涉及一種以綿走盔 .g ’ 為原料的膜電極電解皇啻麻 生心屬於電解臭氧發生器技術領域。 電解臭乳發 【先前技術】 目前，以純水為原料的電解 構’例如：本發明人向中國專利局楛屮的有夕種結 ⑽〇52〇113829_9的實用新型名稱為=的專利號為 -種陽極結構，，的實用新型專利 皇軋發生器 明專利。 稱為電解式臭氧發生裝置，，的發 上述結構，有如下缺點： 臭氧具有㈣的氧化腐钮性，在 大體積的密封裝置與臭氧直接 ° ’ a Λ 軋直接接觸，因表面積較大更容 易X到臭氧的氧化腐蝕， ^ ^^^ 丄過長日守間運行之後，導致密 封裝置物理特性發生老化， U 在訂〖生此下降，進而密封失 ,，使其產生的氣體與原料水的洩漏。 計L採用多處密封裝置方式密封’不但增加成本或 都術變的複雜’且無論與臭氧接觸面積多麼細小 …、法兀王避免被臭氧氧化腐蝕，而導致密封失效。 3、 、在經過長時間的運行之後，矽橡膠材質的密封 、置無法抵抗高濃度臭氧的氧化腐韻’將快速的老化變 硬、失去彈性，而導致密封失效。 4、 在緊固之後，緊固力同時提供密封裝置變形密 、/、陽極催化劑層壓緊質子交換膜所需要的兩個壓力， 201109475 由於使密封裝置變形密封所需要的力與陽極催化劑層壓 緊質子交換膜所需要的力並不相同，將導致另一方二受 力過大或過小，使岔封性能或陽極催化劑層與質子交換 膜壓緊力受到影響，導致膜電極電解臭氧發生器性能不 穩定，進而臭氧產生量下降。 5、 在經過運行之後，陽極催化劑層的厚度會逐漸 變薄，而厚度變薄後，緊固壓板無法繼續提供足夠的壓 力，也無法快速的補償因厚度變薄後所失去的壓力，直 • 接使電解臭氧發生器的陽極結構鬆散，陽極催化劑層與 質子交換膜壓緊力不足，使膜電極電解臭氧發生器的臭 氧產生量下降。 ' 6、 常規陰極結構具有陰極固定板' 防腐片、框 架、導流板、密封裝置、陽極微孔板、陰極催化劑層等， 因此，零件種類繁多，增加生產與組裝複雜，進而影響 產品可靠性’導致生產成本提高。 曰 • 【發明内容】 本發明的目的在於克服上述已有技術的不足而提供 一種結構簡單，成本低、密封性能良好，容易實現工業 化規模生產，確保電解臭氧發生器經長時間運行，仍能 保持優良的密封性，使電解臭氧發生器產生穩定的臭氧 產生量，而達成性能穩定的膜電極電解臭氧發生器。 本發明可以透過如下措施來達到：一種膜電極電解 臭氧發生器，其包括質子交換膜、陽極催化劑層、陽極 微孔板、導流板、陰極結構，其特徵在於其設有框體， 框體内設框體密封槽，框體密封槽内設密封裝置，框體 201109475 藉螺絲與陰極結構緊固在一起，使密封裝置與質子交換 膜、陽極催化劑層及框體完全緊密接觸密封。 為了進一步實現本發明的目的，所述的框體通過螺 絲與陰極結構緊固在一起使密封裝置與質子交換膜、陽 極催化劑層、陽極微孔板及框體完全緊密接觸密封。 為了進一步實現本發明的目的，所述的框體通過螺 絲與陰極結構緊固在一起使密封裝置與質子交換膜、陽 極催化劑層、導流板及框體完全緊密接觸密封。 為了進一步實現本發明的目的，所述的框體通過螺 絲與陰極結構緊固在一起使密封裝置與質子交換膜、陽 極催化劑層、陽極微孔板'導流板及框體完全緊密接觸 密封。 為了進一步實現本發明之目的，所述的密封裝置為 —氟塑料包覆〇型圈。 為了進一步實現本發明的目的，所述的框體密封槽 為斜面槽。 、 為了進—步實現本發明的目的，所述的框體由框體 、邊'專壁體和導電柱包覆體連為一體構成，導電柱包 覆體中的導電柱上設有緊固壓板，緊固壓板通過螺絲與 陰極結構緊固在一起。 為了進一步實現本發明的目的，所述的薄壁體為弧 里、v型或平面型。 為了進一步實現本發明的目的，所述的導電柱鎮皮 在導電柱包覆體内。 進步貫現本發明的目的，所述的陰極結構設有陰 極固定板’陰極固定板上設有螺絲孔、排水孔，陰極 201109475 固定板上設有導流槽，導流槽之間通過溝槽連通，並 與排水孔連通’陰極固定板上設有陰極微孔板’陰極 微孔板上設有陰極催化劑層。 為了進一步實現本發明的目的，所述的導流槽為環 形導流槽。 馮了進一步實現本發明的目的 採用金屬鈦材料製成 本發明與已有技術相比具有如下積極效果：201109475 VI. Description of the Invention: [Technical Field] The present invention relates to a membrane electrode electrolysis, which is a raw material of a walking helmet. Electrolytic odor milk [Prior Art] At present, the electrolysis structure using pure water as a raw material is, for example, the patent number of the utility model name of the present invention to the Chinese Patent Office (10) 〇52〇113829_9 is = - A kind of anode structure, the patent of the utility model patent Huanghuang generator. The above-mentioned structure, which is called an electrolytic ozone generating device, has the following disadvantages: Ozone has (4) oxidative corrosion resistance, and direct contact with ozone directly in a large-volume sealing device is possible because of a large surface area. Oxidation and corrosion of X to ozone, ^ ^^^ After the long-term stagnation operation, the physical properties of the sealing device are aging, U is reduced in the order, and then the seal is lost, so that the gas and raw water are generated. leakage. The meter L is sealed by multiple sealing devices. 'It not only increases the cost or the complexity of the process', but no matter how small the contact area with ozone..., the king of the law avoids oxidation by ozone, which leads to seal failure. 3. After a long period of operation, the seal of the rubber material and the oxidation rot that cannot resist the high concentration of ozone will harden the rapid aging and lose the elasticity, resulting in seal failure. 4. After tightening, the tightening force simultaneously provides the two pressures required for the sealing device to be deformed tightly, and the anode catalyst is laminated to the proton exchange membrane. 201109475 The force required to deform the sealing device is laminated with the anode catalyst. The force required for the tight proton exchange membrane is not the same, which will cause the other two to be too large or too small, so that the sealing performance or the pressing force of the anode catalyst layer and the proton exchange membrane are affected, resulting in the performance of the membrane electrode electrolytic ozone generator. Stable, and thus the amount of ozone produced decreases. 5. After the operation, the thickness of the anode catalyst layer will gradually become thinner, and after the thickness becomes thinner, the fastening platen cannot continue to provide sufficient pressure, and cannot quickly compensate for the pressure lost due to the thinning of the thickness. The anode structure of the electrolytic ozone generator is loosened, and the pressing force of the anode catalyst layer and the proton exchange membrane is insufficient, so that the ozone generation amount of the membrane electrode electrolytic ozone generator is decreased. '6. Conventional cathode structure has cathode fixed plate' anti-corrosion sheet, frame, deflector, sealing device, anode microporous plate, cathode catalyst layer, etc. Therefore, there are many kinds of parts, which increases the complexity of production and assembly, and thus affects product reliability. 'Increased production costs.曰• 【Abstract】 The object of the present invention is to overcome the above-mentioned deficiencies of the prior art and to provide a simple structure, low cost, good sealing performance, easy industrial scale production, and ensure that the electrolytic ozone generator can be maintained for a long time. The excellent sealing property enables the electrolytic ozone generator to generate a stable amount of ozone generation, and achieves a stable membrane electrode electrolytic ozone generator. The present invention can be achieved by the following measures: a membrane electrode electrolytic ozone generator comprising a proton exchange membrane, an anode catalyst layer, an anode microplate, a baffle, a cathode structure, characterized in that it is provided with a frame, a frame There is a frame sealing groove inside, a sealing device is arranged in the frame sealing groove, and the frame body 201109475 is fastened together with the cathode structure by screws, so that the sealing device is completely in close contact with the proton exchange membrane, the anode catalyst layer and the frame body. In order to further achieve the object of the present invention, the frame is fastened together with the cathode structure by a screw to seal the sealing device in close contact with the proton exchange membrane, the anode catalyst layer, the anode microplate and the frame. In order to further achieve the object of the present invention, the frame is fastened together with the cathode structure by a screw to seal the sealing device in close contact with the proton exchange membrane, the anode catalyst layer, the baffle and the frame. In order to further achieve the object of the present invention, the frame is fastened together with the cathode structure by a screw to seal the sealing device in close contact with the proton exchange membrane, the anode catalyst layer, the anode microplate 'baffle and the frame. In order to further achieve the object of the present invention, the sealing device is a fluoroplastic coated crucible ring. In order to further achieve the object of the present invention, the frame sealing groove is a bevel groove. In order to achieve the object of the present invention, the frame body is integrally formed by the frame body, the side wall and the conductive column covering body, and the conductive column in the conductive column covering body is fastened. The pressure plate and the fastening plate are fastened together with the cathode structure by screws. In order to further achieve the object of the present invention, the thin-walled body is of an arc, a v-shape or a flat type. In order to further achieve the object of the present invention, the conductive column skin is covered in a conductive column. According to the object of the present invention, the cathode structure is provided with a cathode fixing plate. The cathode fixing plate is provided with a screw hole and a drainage hole, and the cathode 201109475 is provided with a guiding groove on the fixing plate, and the guiding groove passes through the groove. Connected and connected to the drain hole 'The cathode fixed plate is provided with a cathode microplate>> The cathode microplate is provided with a cathode catalyst layer. In order to further achieve the object of the present invention, the flow guiding groove is an annular flow guiding groove. The purpose of further realizing the present invention is made of a metal titanium material. The present invention has the following positive effects as compared with the prior art:
1、由於本發明密封裝置採用氟塑料包覆〇型圈： 因氟塑料基本不受臭氧所氧化腐钱，且完整嚴密的在 型圈外層包覆’在電解臭氧發生器長時間運作後，仍負 料優&㈣封性’將不會因其產生的臭氧氣體氧化力 姓’而造成密封裝置失效’導致產生的氣體與原料水, :漏’使膜電極電解臭氧發生器產生穩定的臭氧產: I ’而達成性能穩定。 y 2在框體通過機械緊固與陰極結構緊固為一負 =框體的密封槽將密封裝置通過框體密封槽使其定男 疋位的二壓變形，其斜面槽將使密封裝置四周產生I 力’使岔封裝置與質子交換膜、陽極催化劑層、陽極嶺 孔板、導流板、框體緊密接觸，進而達到完全密封作用 3、纟發明將框體和緊固壓板均通過螺絲以機械零 固方式與陰極結構緊因太 在一起’並由緊固壓板將緊固乂 傳導至導電柱，由於宋 、在封裝置又力變形後内圈為平直鴻 順，緊固力將藉由導電杈順剎、3 w道a " 值道s B 冤柱順利通過導流板、陽極微孔板： 緊力。另外，由於導電主：：換膜’“所需穩定的塵 由於V電柱文力，加上與導流板存在配合 201109475 間隙’其周邊與外側必然產生變形，通過薄壁體產生變 形，吸收此變形量，使薄壁體外側完全不受螺絲及緊固 壓板衫響，進而密封裝置變形量與密封性能不發生變 化’因此，薄壁體使密封裝置變形密封與陽極催化劑層 壓緊質子交換膜所需要的兩個不同壓力完全獨立，保持 電解臭氧發生器的性能穩定。 4'在經過運行之後，陽極催化劑層的厚度會逐漸 變薄，當厚度變薄後’緊固壓板及時將緊固力藉由導電 _ 柱透過薄壁體使導電柱向下位移，快速且敏捷的補償陽 極催化劑層因厚度變薄後所失去的壓力，避免陽極催化 劑層與質子交換膜壓緊力不足，使膜電極電解臭氧發生 器的臭氧產生量下降。 5、本發明陰極結構的陰極固定板上設有螺絲孔， 用來緊固膜電極臭氧發生器整體與連接直流電源的陰極 電極’與常規陰極固定板有相同功能。本發明的陰極固 定板上設有導流槽’可容納原料水，在溝槽内原料水和 •:體產物對流、擴散’具有導電與冷卻功能，與常規導 流板相同功能。本發明的陰極固定板上設有排水孔，可 將陰極的水和氣體產物由排水孔順利排出。本發明的陰 極固定板採用金屬鈦材料製成，防止其腐蝕，不需要任 何防腐的材料與防腐的處理工藝。因此陰極固定板具有 緊，、導流、冷卻、水氣排出的功能，結合了常規陰極 固疋板:防腐月、框架、導流板的所有功能，與現有技 術的臭氧發生器相比，具有製備工藝簡單、組裝方便， 進而降低成本20〜30%。 201109475 【實施方式】 從謹就本發明「密封 結構組成，及其所產生之 較佳實施例詳細說明如下 式獏電極電解臭氧發生 功效，配合圖式，舉一 器」之 本案之1. Since the sealing device of the invention adopts fluoroplastic coated 〇-shaped ring: fluoroplastic is basically not oxidized by ozone, and is completely and tightly coated on the outer layer of the ferrule. Negative material & (4) sealing property will not cause the failure of the sealing device due to the ozone gas oxidizing power generation caused by it's resulting in the gas and raw water, : leakage' causes the membrane electrode to generate stable ozone by the ozone generator. Production: I' and achieved stable performance. y 2 is fixed in the frame by mechanical fastening and the cathode structure is a negative = frame sealing groove, the sealing device is passed through the frame sealing groove to make the two-pressure deformation of the male position, and the inclined groove will cause the sealing device to be generated around the frame. I force 'the sealing device is in close contact with the proton exchange membrane, the anode catalyst layer, the anode ridge orifice plate, the baffle plate and the frame body, thereby achieving a complete sealing effect. 3. The invention has the frame body and the fastening pressure plate passed through the screw. The mechanical zero-solid method and the cathode structure are too tight together' and the fastening 乂 is transmitted to the conductive column by the fastening platen. Since the inner ring is straight and straight after the deformation of the sealing device, the fastening force will be borrowed. From the conductive 杈 brake, 3 w road a " value s B 冤 column smoothly through the baffle, anode microplate: tight. In addition, due to the conductive main:: changing the membrane 'the required stable dust due to the V electric column literacy, plus the presence of the 201109475 gap with the deflector', the periphery and the outside will inevitably deform, through the thin wall body deformation, absorb this The amount of deformation is such that the outer side of the thin-walled body is completely unaffected by the screw and the fastening platen, and the deformation amount and the sealing performance of the sealing device are not changed. Therefore, the thin-walled body deforms the sealing device and seals the anode catalyst to the proton exchange membrane. The two different pressures required are completely independent, and the performance of the electrolytic ozone generator is kept stable. 4' After the operation, the thickness of the anode catalyst layer will gradually become thinner, and when the thickness is thinned, the tightening pressure plate will tighten the fastening force in time. The conductive column is displaced downward through the thin-walled body, and the pressure lost by the thickness of the anode catalyst layer is compensated quickly and agilely, and the pressing force of the anode catalyst layer and the proton exchange membrane is prevented from being insufficient, so that the membrane electrode is The amount of ozone generated by the electrolytic ozone generator is decreased. 5. The cathode fixing plate of the cathode structure of the present invention is provided with a screw hole for fastening the membrane electrode. The ozone generator as a whole and the cathode electrode connected to the DC power source have the same function as the conventional cathode fixing plate. The cathode fixing plate of the present invention is provided with a guide groove 'capable of accommodating raw water, raw water in the groove and: body product Convection, diffusion 'has the function of conduction and cooling, and has the same function as the conventional baffle. The cathode fixing plate of the invention is provided with a drainage hole, which can smoothly discharge the water and gas products of the cathode from the drainage hole. The cathode fixing plate of the invention It is made of metal titanium material to prevent corrosion and does not require any anti-corrosion materials and anti-corrosion treatment process. Therefore, the cathode fixed plate has the functions of tightness, diversion, cooling and water vapor discharge, and combines the conventional cathode solid-state plate: Compared with the prior art ozone generator, all functions of the anti-corrosion month, the frame and the baffle plate have the advantages of simple preparation process and convenient assembly, thereby reducing the cost by 20 to 30%. 201109475 [Embodiment] The structural composition, and the preferred embodiment thereof, are described in detail below, and the effect of the electrode electrolysis ozone generation is as follows: "The case of
臭氧：第/广第四圖為—種「密封式膜電極電解 固。」、、陰極結構1設有陰極固定板卜5,陰極 口/板卜5採用金屬鈦材料製&，陰極固定板卜5的周 邊均勻設有螺絲孔Η，陰極固定板卜5上設有環形導 抓才曰1 2 ’ ％料流槽卜2的巾部設有橫向溝槽卜4，環 形導卜2之間通過溝槽卜4相通，並與排水孔卜3 連、$極固疋板卜5上放上陰極微孔板1 -7，陰極微 孔板卜7放上陰極催化劑層卜8,其層厚在（M〜5mm， W 4層U上放上質子交換膜2 (杜邦 Nafionm)。在質子交換膜2與電解臭氧發生器陰極結 構相對的另一面放上陽極催化騎3,其層厚在。」二 5_ ’陽極催化劑層3為二氧化敍材料製作的膜層。 其製作方式可以是將陽極催化劑顆粒自由舖放在質 子乂換膜2上’然後將陽極微孔板4 (陽極微孔板4表 面經處理設有導電耐蝕保護層）蓋在陽極催化劑層3 上及陽極微孔板4為多孔鈦板，陽極微孔板4的孔徑 為10〜500#m，將導流板5壓在陽極微孔板4上，導流 板5的一面與陽極微孔板4緊密接觸，用密封裝置7將 V /’ο·板5陽極微孔板4和陽極催化劑層3周邊封繞， 密封裝置為氟塑料包覆〇型密封圈。再將框體6置於密 封裝置7上方，框體6内設有框體密封槽u，框體密封 槽11為斜面槽，密封裝置7置於框體密封槽】】内，將 201109475 框體6通過螺絲9以機械緊固方式與陰極結構1的陰極 固定板1-5緊固在一起’密封裝置7通過框體密封槽i j 使其定形定位的擠壓變形，達到與質子交換膜2、陽極 催化劑層3、陽極微孔板4、導流板5、框體6緊密接觸， 進而達到完全密封。 框體6由框體週邊6-3、薄壁體6-2和導電柱包覆 體6-1連為一體構成，薄壁體6_2設在框體週邊6 —3和 導電柱包覆體6-1之間，導電柱包覆體6—丨的中心鑲嵌Ozone: The fourth/wide picture is a kind of "sealed membrane electrode electrolysis solid". The cathode structure 1 is provided with a cathode fixing plate 5, and the cathode port/plate 5 is made of a metal titanium material & The periphery of Bu 5 is evenly provided with a screw hole Η, and the cathode fixing plate is provided with a circular guide pin 曰 1 2 '% of the material flow groove 2 is provided with a lateral groove 4, and a circular guide 2 Through the groove Bu 4, and connected to the drainage hole 3, the $ extremely solid plate 5 put the cathode microplate 1 -7, the cathode microplate 7 put the cathode catalyst layer 8, the layer thickness The proton exchange membrane 2 (DuPont Nafionm) was placed on (M~5 mm, W 4 layer U. The anode catalytic ride 3 was placed on the other side of the proton exchange membrane 2 opposite to the cathode structure of the electrolytic ozone generator, and the layer thickness was set. The second 5_' anode catalyst layer 3 is a membrane layer made of a dioxide dioxide material. It can be prepared by freely depositing anode catalyst particles on the proton enthalpy membrane 2 and then placing the anode microplate 4 (anode microplate). 4 surface treated with a conductive corrosion protection layer) on the anode catalyst layer 3 and the anode microplate 4 is a porous titanium plate, yang The microporous plate 4 has a pore diameter of 10 to 500 #m, and the deflector 5 is pressed against the anode microplate 4, and one side of the deflector 5 is in close contact with the anode microplate 4, and the sealing device 7 is used to V/ 'ο· plate 5 anode microplate 4 and anode catalyst layer 3 are sealed around, and the sealing device is a fluoroplastic coated 〇-type sealing ring. The frame 6 is placed above the sealing device 7, and the frame 6 is provided with a frame. The body sealing groove u, the frame sealing groove 11 is a bevel groove, the sealing device 7 is placed in the frame sealing groove, and the 201109475 frame 6 is mechanically fastened by the screw 9 to the cathode fixing plate 1 of the cathode structure 1 5 fastened together 'the sealing device 7 is deformed by the frame sealing groove ij to be positioned and positioned to reach the proton exchange membrane 2, the anode catalyst layer 3, the anode microplate 4, the deflector 5, and the frame 6 Close contact, and then complete sealing. The frame 6 is integrally formed by the frame periphery 6-3, the thin wall body 6-2 and the conductive column covering body 6-1, and the thin wall body 6_2 is disposed at the periphery of the frame 6 3 and the conductive pillar covering body 6-1, the center pillar of the conductive pillar covering body 6-丨
有導電柱13，薄壁體6-2可以為弧型、V型或平 彈性的或可伸縮的結構。 千面型等 將緊固壓板8放置在導電柱13上，將緊固壓板8通 過螺絲10以機械緊固方式與陰極結構i的陰極固定板 卜5緊固在—起，由緊固壓板8將緊固力傳導至框體6 中心，通過薄壁體6 —2產生變形，使其密封裝置7不受 螺絲1〇緊固緊固壓板8的影響，導致密封性能發生變化： 此結構的臈電極電解臭氧發生器的壽命長於1〇_There are conductive posts 13, which may be arcuate, V-shaped or flat elastic or telescopic. The kneading type or the like places the fastening platen 8 on the conductive post 13, and the fastening platen 8 is fastened to the cathode fixing plate 5 of the cathode structure i by a screw 10 by a screw 10, and the fastening platen 8 is fastened. The fastening force is transmitted to the center of the frame 6, and the deformation is caused by the thin-walled body 6-2, so that the sealing device 7 is not affected by the fastening of the fastening plate 8 by the screw 1〇, resulting in a change in the sealing performance: Electrode Ozone Generator has a lifetime longer than 1〇_
氧發生器 法第二十 一項、第 第四項等 申請前未 技術。再 並達成相 並非能輕 用性i、「 仏判八联萆極電^r六. 」，依現行專利法第四十四條規定，未有違反同 -條至第二十四條、第二十六條、第三十條第 一：、弟三十—條、第三十二條或第四十九條 規疋之情事。本案在產業上確實得以利用，於 曾見於刊物或公開使用’且非為公眾所知悉之 本案有效解決先前技術中長期存在的問題 關使用者與消費者再& 月賈者長期的需求’得佐證本發明 案完全符合專利法規定之「產業利 201109475 新穎性」與「進步性」等要件，爰依法提請專利，懇請 鈞局詳查，並儘早為准予專利之審定’以保護申請人之 智慧財產權，俾勵創新。 本發明雖藉由前述實施例來描述，但仍可變化其升< 態與細節’於不脫離本發明之精神而達成，並由熟悉此 項技藝之人士可了解。前述本案之較佳實施例，僅係藉 本案原理可以具體實施的方式之一，但並不以此為限： ，應依後附之申請專利範圍所界定為準。 【圖式簡單說明】 第一圖：係為本發明之結構示意圖。 第一圖·係為第一圖框體之結構示意圖。 第三圖：係為第一圖陰極結構之結構示意圖。 第四圖.係為第二圖陰極固定板之結構示意圖。 【主要元件符號說明】 (1) —陰極結構 (1 -1)--螺絲孔 (1-2)--導流槽 (1 - 3 )--排水孔 (1-4)--溝槽 (1-5)--陰極固定板 (1-6)--陰極微孔板 U-7)--陰極催化劑層 (2) 質子交換臈 (3 ) 陽極催化劑層 10 201109475 (4 )----陽極微孔板 (5 )----導流板 (6) ----框體 (6-1 )--導電柱包覆體 (6-2).--薄壁體 (6-3)--框體週邊 (7) ——密封裝置 (8) ----緊固壓板 (9 )----螺絲 (10 )---螺絲 (11 )---框體密封槽 (13)---導電柱 11Oxygen generator method No. 20, item 4, etc. No prior application. In addition, it is not possible to use the lightness i, "consultation of the eight-in-one 萆 电 ^ ^ 六.", according to the provisions of Article 44 of the current Patent Law, there is no violation of the same - Article to Article 24, Article 26, Article 30: First, the content of the rules of the thirty-third, thirty-two or forty-ninth. The case has indeed been used in the industry. It has been seen in publications or publicly used, and the case that is not known to the public effectively solves the long-standing problems in the prior art, and the long-term needs of users and consumers. It is corroborated that the invention is in full compliance with the requirements of the "Profits 201109475 Novelty" and "Progressiveness" as stipulated in the Patent Law. The patents are submitted in accordance with the law, and the Bureau is required to investigate in detail and approve the patents as soon as possible to protect the wisdom of the applicants. Property rights, encourage innovation. The present invention has been described in terms of the foregoing embodiments, but may be modified by the spirit and scope of the invention, and may be understood by those skilled in the art. The preferred embodiment of the present invention is only one of the ways in which the present invention can be implemented, but it is not limited thereto: it should be determined by the scope of the appended patent application. BRIEF DESCRIPTION OF THE DRAWINGS The first figure is a schematic view of the structure of the present invention. The first figure is a schematic diagram of the structure of the first frame. The third figure is a schematic structural view of the cathode structure of the first figure. The fourth figure is a schematic structural view of the cathode fixing plate of the second figure. [Explanation of main component symbols] (1) - Cathode structure (1 -1) - Screw hole (1-2) - Drainage groove (1 - 3) - Drain hole (1-4) - Groove ( 1-5)--cathode fixed plate (1-6)--cathode microplate U-7)--cathode catalyst layer (2) proton exchange enthalpy (3) anode catalyst layer 10 201109475 (4)---- Anode microplate (5)----baffle (6) ---- frame (6-1)--conductive column coating (6-2).--thin wall body (6-3 )--Block around (7) - Sealing device (8) ---- Fastening plate (9)----screw (10)---screw (11)---frame sealing groove (13 )---conductive column 11