TW200833187A - Method for producing structured electrically conductive surfaces - Google Patents

Abstract

The invention relates to a method for producing structured or full-surface electrically conductive surfaces on an electrically nonconductive support (1), which comprises the following steps: (a) applying an adhesive layer (3) onto the electrically nonconductive support (1), the adhesive layer (3) having the structure of the electrically conductive surface, (b) transferring electrolessly and/or electrolytically coatable particles (41) from a transfer medium (5) onto the adhesive layer (3), the electrolessly and/or electrolytically coatable particles (41) being applied as a layer on the transfer medium (5), (c) removing the transfer medium (5), (d) at least partially drying and/or at least partially curing the adhesive of the adhesive layer (3), so that the electrolessly and/or electrolytically coatable particles (41) become bound to the adhesive layer (3) and a base layer (31) is thus formed, (e) applying a metal layer onto the electrolessly and/or electrolytically coatable particles (41), adhering on the electrically nonconductive support (1) by means of the adhesive layer (3), by electroless and/or electrolytic coating.

Description

200833187 IX. DESCRIPTION OF THE INVENTION: Field of the Invention The present invention relates to a method for producing a structural and/or full surface conductive surface on a non-conductive support.

The method of the present invention is applicable, for example, to the production of conductor tracks on printed circuit boards, RFID antennas, repeater antennas or other antenna structures, wafer card modules, flat cables, seat heaters, foil conductors, solar cells, or Conductor track in electric water screen or any form of electrolytic coating product. The b method is also suitable for producing decorative or functional surfaces on a product that are used, for example, to shield electromagnetic radiation, for heat conduction, or for use as a package. [Prior Art] In general, to produce such structural or full-surface conductive surfaces, a 'd-structured or full-surface bonding layer is first applied to the non-conductive branch. A metal/or metal powder is fixed to the bonding layer. Alternatively, it is also known to apply a metal mooring or metal layer to the support made of plastic material over the entire surface, to assist the structurally, heated stamp to press it against the support and subsequently cure it. The metal layer is structured by mechanically removing areas of the metal cancer or metal powder that are not attached to the bonding layer or support. This method is described, for example, in DE-A 101 45 749. The disadvantage of this method is that, in the coating of the substrate H, a large amount of material which is sometimes not reusable must be removed. In the case of a metal crucible, it is impossible to produce a sharp edge because the box cannot be properly transferred. However, such sharp edges are used, for example, to produce, for example, conductor tracks for printed circuit boards or RFID antennas. A flaw that is not completely cut (for example) will cause a short circuit. In the case of mechanical removal of excess metal or excess foil, the conductor track structure may be removed in part, such that the conductor tracks are no longer functional. It is known from EP-A 0 130 462 that for a layer of a thermosetting resin containing metal particles therein, at least some particles composed of a noble metal will be applied in a structured manner to a transfer surface. The transfer medium is then brought into contact with the support via the side to which the resin and the metal-containing particles are applied. In this case, in a manner such that the layer containing the metal particles is transferred from the transfer medium to the support in the form of a structural surface to be produced, a different adhesive layer is applied to: a layer having metal particles or supporting Physically. One disadvantage of this method is that the size of the metal particles used in the range of 15〇0111 to 42〇|11111 is unlikely to result in an ultrafine conductor track structure, i.e., a conductor track structure of less than 100 μηη. In addition, the proposed method requires a large amount of expensive precious metals such as silver. Another disadvantage is that it is difficult to print with high resolution using ink filled with a large proportion of metal. Further, in this case, a large amount of metal is transferred, because even if only a thin metal layer is required on the surface in the remaining process, the entire metal-filled ink layer is transferred from the intermediate carrier to the substrate. When the structural ink containing metal is transferred from the intermediate support to the substrate, the thin conductor track structures do not collectively transfer and thus the risk of defects occurring in the conductor tracks occurs. Another disadvantage of this method is that an additional contact step is required to achieve sufficient conductivity for subsequent plating before transferring the metal layer onto the substrate prior to transferring the structural layer containing the metal. & Furthermore, the chemical metallization requires a long residence time in the electroplating system, and thus results in low productivity and high cost. 125205.doc 200833187 SUMMARY OF THE INVENTION One object of the present invention is to provide a method that does not have the disadvantages of the methods known from the prior art. The object is achieved by a method for producing a structural or full-area conductive surface on a non-conductive support member, the method comprising the steps of: (4 applying an adhesive layer to the non-conductive support, the adhesive The connection of the reed to the conductive surface;

(9) transferring electroless and/or electrolytically coatable particles from the transfer medium f to the adhesive layer, wherein the electroless and/or electrolytically coatable particles are applied to the transfer medium in a layer form, preferably a two-layer form; 0) removing the transfer medium; (d) ^ a small portion of the drying agent and/or at least the curing agent of the cured adhesive layer, such that the electroless and/or electrolytically coatable particles become bonded to the adhesive layer and thereby form a The base layer; ^ a metal layer applied to the non-electrical adhesion layer of the non-conductive layer (e) by electroless and/or electrolytic coating, and/or electrolysis of the coatable particles, by means of the support. . For example, a'9 or flexible support is suitable for use as a conductive structural or support member to which the surface of the region can be applied. The support member is preferably non-conductive; This fortune resistivity is greater than 1〇9 Qxcm. Suitable supports are, for example, strong or unreinforced polymers, such as are conventionally used in printed circuit boards/isomeric materials. 5 Suitable polymers are epoxy resins or modified epoxy trees. Gentry (eg, bifunctional or polyfunctional double-anti-A or double-F resin, epoxy, acid tree sorghum/smelly oxime, aromatic polyamine reinforced or glass, fiber reinforced or 125205.doc 200833187 Paper reinforced epoxy resin (eg FR4)), glass fiber reinforced plastic, liquid crystal polymer (LCP), polyphenylene sulfide (PPS), polyoxymethylene (POM), polyaryl ether ketone (PAEK), Polyetheretherketone (PEEK), polydecylamine (PA), polycarbonate (PC), polybutylene terephthalate (PBT), polyethylene terephthalate (PET), polyfluorene Imine (PI), polyimine resin, cyanate ester, bismaleimide-triterpene resin, nylon, vinyl ester resin, polyester, polyester resin, polyamide, polyaniline (polyaniline), expectant resin, polypyrrole, polyethylene naphthalate (PEN), polymethyl methacrylate, polyethylene dioxythiophene, phenolic resin coated aromatic polyamide paper Polytetrafluoroethylene (PTFE), melamine resin, polyoxyn epoxide, fluororesin, allylated polyphenylene ether (APPE), polyether phthalimide (PEI), polyphenylene ether (PPO), polypropylene (PP) ), polyethylene (PE), polysulfone (PSU), polyethersulfone (PES), polyarylamine (PAA), polyvinyl chloride (PVC), polystyrene (PS), acrylonitrile-butadiene a mixture (blend) of styrene (ABS), acrylonitrile-styrene acrylate (ASA), styrene acrylonitrile (SAN), and two or more of the foregoing polymers, which may exist in various forms . The substrate may comprise additives known to those skilled in the art, such as flame retardants. Other substrates known in the printed circuit industry are also suitable. In addition, composites, foamed polymers, Styropor 8, Styrodur 8, polyurethane (PU), ceramic surfaces, textiles, pulp, wood, paper, polymer coated paper, wood, mineral materials, tantalum, glass , plant tissue and animal tissue are suitable substrates. The substrate can be rigid or flexible. In a first step, an I25205.doc -10- 200833187 adhesive layer having the shape of a structural or full surface base layer is applied to the non-conductive support. For example, $ 'natural and synthetic human / and eight (four) Ht " and its biological, natural resin and synthetic resin and its derivatives, natural rubber, synthetic rubber, protein and other materials suitable for the adhesive layer, σ, 卄, Just attach it to the support material. It may, but need not, be chemically or chemically cured, such as air curing, radiation curing or temperature curing. The material used for the adhesive layer is preferably a polymer or polymer blend.

Preferred as the material for the adhesive layer is, for example, acrylic acid acrylic; alkyd resin; silk vinyl acetate; hospital based vinyl acetate vinegar, polymer; t its methylene vinyl acetate Ester, ethylene vinyl acetate, butylene vinyl acetate; alkyl chloride copolymer; silk resin; aldehyde and ketone resin; epoxy acrylate vinegar; epoxy resin; modified epoxy resin, such as double Functional or polyfunctional bisphenol A or bisphenol F resin, epoxy-phenolic resin, brominated epoxy resin, cycloaliphatic epoxy resin; aliphatic epoxy resin, epoxy propyl ether, vinyl ether, ethylene _ Acrylic copolymer; hydrocarbon resin; melamine resin, maleic anhydride copolymer; methacrylate; natural rubber; synthetic rubber; chlorine rubber; natural resin; rosin resin; phenolic resin; , such as phenyl ester resin; polyhard; polyscale hard; polyamide; polybutadiene; polycarbonate, · polyester acrylate; poly phthalate; polyethylene; polyethylene thiophene; Ethylene glycol; polyethylene terephthalate PET); polyethylene terephthalate (PETG); polypropylene; polymethyl methacrylate (PMMA); polyphenylene ether (PPO); polystyrene (PS), polytetrahydrofuran; polyether (eg, polyethylene glycol, polypropylene glycol); polyvinyl compounds, especially polyvinyl chloride (PVC), PVC copolymer, I25205.doc 11 200833187 PVdC, polyvinyl acetate and copolymers thereof, partially hydrolyzed Polyvinyl alcohol, polyvinyl acid, polyethylene acetate, polyethylene sulfonate, I ethylene _, polyacrylic acid vinyl vinegar and methacrylate in solution and in the form of a dispersion and copolymers thereof , polyacrylate and polystyrene copolymer; polyurethane which is not crosslinked or crosslinked with isocyanate; polyurethane acrylate; styrene acrylic copolymer; styrene butadiene block Copolymers (for example, styroflex® or Styrolux® from BASF AG, K_ResinTM from cpC); proteins such as casein, styrene isoprene block copolymers; triazine resins, bismaleimide Triterpenoid resin (BT), cyanate resin (CE), allylated polyphenylene Ether (APPE). Mixtures of two or more polymers may also form a material for the adhesive layer. Particularly preferred as the material for the adhesive layer are acrylate, acrylic resin, methacrylate, methacrylic resin, melamine and amine based resin, polyolefin, polyimine, epoxy resin. Modified epoxy resin (for example, difunctional or polyfunctional bisphenol A or bisphenol F resin, epoxy-phenolic resin, brominated epoxy resin, cycloaliphatic epoxy resin); aliphatic epoxy resin , epoxidized propyl ether, vinyl ether and phenolic resin, polyurethane urethane, poly, polyacetal acetal, vinyl acetate shoulder, polystyrene copolymer, polystyrene acrylate, styrene A diene block copolymer, an alkenyl vinyl acetate and a vinyl chloride copolymer, a polydecylamine, and a copolymer thereof. As a material for the adhesive layer in the production of a printed circuit board, it is preferred to use a heat curing or radiation curing resin such as a modified epoxy resin such as a bifunctional or polyfunctional bisphenol A or bisphenol F resin, a ring. Oxygen phenolic resin, bromine 125205.doc -12- 200833187 epoxy resin, cycloaliphatic epoxy resin; aliphatic epoxy resin, epoxy propyl shrine: cyanate series, acetamidine, variegated resin, Melamine resin and amine tree sorghum, polyurethane and polyester. In order to apply the material for the adhesive layer to the non-conductive support member, a solvent or a solvent mixture may be added to adjust the viscosity suitable for the individual coating method. Suitable solvents are, for example, aliphatic and aromatic. Hydrocarbons (eg, n-octane, cyclohexane, oxime, xylene), alcohols (eg, methanol, ethanol, propanol, 2-propanol, 1-butanol, 2-butanol, pentanol), Polyvalent alcohols (such as glycerol, ethylene glycol, propylene glycol, neopentyl glycol), alkyl esters (eg, methyl acetate, ethyl acetate, propyl acetate, butyl acetate, isobutyl acetate, acetic acid) Propyl ester, 3-methylbutanol), alkoxy alcohol (eg, methoxypropanol, methoxybutanol, ethoxypropanol), alkylbenzene (eg, ethylbenzene, cumene) ), butyl glycol, dibutyl glycol, alkyl glycol acetate (eg, butyl glycol acetate, dibutyl glycol acetate | Purpose), monoacetone alcohol, diethylene glycol dialkyl squama, diethylene glycol monoalkyl sulphate, dipropylene glycol dialkyl sulphate, dipropylene glycol monoalkyl ether, Ethylene glycol alkyl ether acetate, dipropylene glycol alkyl ether acetic acid g, di 11 methane, dipropylene glycol and ether, diethylene glycol and squama, dibasic ester (DBJE), ether (for example, diethyl ether, Tetrahydrofuran), vinyl chloride, ethylene glycol, ethylene glycol acetate, ethylene glycol diester, cresol, lactone (eg, butyrolactone), ketone (eg, acetone, 2-butanone, cyclohexane) Ketone, methyl ethyl ketone (MEK), methyl isobutyl ketone (MIBK), ethylene glycol dimethyl ether, dichloromethane, methamethylene glycol, methyl glycol glycol Ester, a categorical (neighbor, arsenic, 125205.doc -13- 200833187 cresol, p-nonylphenol), copradinone (for example, N-methyl propylene glycol, propylene carbonate, tetrachlorinated ... than the state) , called aromatic smoke and mixture, aliphatic smoke and:: compound three: a (four) paste, rosin alcohol), water and these solvents: early pine mixture. Preferred solvents for the two or more are alcohols (for example, ethanol, an alkoxy alcohol (for example, methoxypropyl: 2. propanol, butanol), an alcohol, a dibutyl glycol), a lactyl alcohol Butyl glycol monoalkyl ether, dipropyl ester (for example, ethyl acetate butyl glycol acetate, base - acetic acid g, DBE), such as glycerol, ethylene glycol butane S , diethylene glycol dialkyl ether, diethyl alcohol monoalkyl _, dipropylene glycol monoalkyl ether, butyl acetate, butyl glycol acetate, di-glycol alkyl ether acetate , dipropylene glycol alkane scales (eg 'tetrahydrofuran'), polyvalent alcohols (such as _, propylene glycol, neopentyl glycol), ketones (eg, propylmethylethyl® g, methyl isobutyl hexyl, ethylbenzene, Toluene, xylene/N hexose (6), smoke (for example, a mixture of rings), methyl-2-pyrrolidone, water, and if an adhesive layer is applied to the cut member by an inkjet method, the oxyalcohol (eg, ethoxypropanol), butyl glycol, dibutyl glycol, and polyvalent drunk (such as glycerol), vinegar (eg, dibutyl glycol acetate, butyl b) Glycol acetate vinegar, dipropylene It is especially preferred to use a solvent such as diol methyl hydrazine acetate, water, cyclohexanone, butane vinegar, N-methyl-hydrazine, DM and mixtures thereof as a solvent. In the case of liquid epoxy resin, acrylate, the respective viscosity may alternatively be adjusted via the temperature during the coating period of 125205.doc -14 - 200833187 degrees or via a combination of solvent and temperature. In the second step, The electroless and/or electrolytically coatable particles are transferred from the transfer medium to the adhesive layer ±, and the electroless and/or electrolytically coatable + is applied to the transfer medium in the form of a layer, preferably in a single layer. The advantage of the layer of electroless and/or electrolytically coatable particles is that there are only electroless and/or electrolytically coatable particles on the surface of the adhesive layer of the target substrate: a thin layer. A single layer is also economical. Less electroless and/or electrolytically coatable materials. It is also preferred that these particles adhere to the adhesive layer because each transfer particle is in direct contact with the adhesive. Electroless and/or electrolytically coatable particles can be applied to it. Any hard or pullable support on the top Transfer medium. Suitable materials for the transfer medium are, for example, metal, glass, ceramic, plastic or any composite material. In the first embodiment, 'there will be a small amount of binder and, depending on the situation, other added states (eg, sub-governing agents) The electroless and/or electrolytically coatable particles of the flow control agent, the residual inhibitor, etc. are dispersed in the solvent or applied to the transfer medium, for example, by printing n-rolling, blade scraping or spraying. The material used for the subsequent adhesive layer is preferably used as a binder. In case the electroless and/or electrolytically coatable particles are transferred to the non-conductive support, the transfer medium can be easily separated. 'No electricity and/or electrolytic coating. The amount and type of binder by which the particles adhere to the transfer medium are selected such that the three electroless and/or electrolytically coatable particles adhere only weakly to the transfer medium and are transferred, and the electroless and/or electrolytically coatable particles are This is stronger than adhering to the adhesive layer of the support member on the transfer medium, so that the adhesive layer without the self-supporting member can be taken away together with the transfer medium to remove the electroless and/or electrolytically coatable particles. .doc -1 5· 200833187 Remove the transfer media. In a preferred embodiment, at least one endless belt or at least a drum running around two mechanical shafts is used as the transfer medium. The electroless and/or electrolytic coating and the dispersion of the adhesive are applied to the endless belt or drum by, for example, printing, casting tribute, blade scraping or spraying. The coated dry layer thickness is selected such that it substantially corresponds to the straight 2 of the conductive particles. The effect achieved by the method is that only the single layer particles are coated onto the transfer shell, even if the layer thickness is larger than the particle diameter L, the denier of the particle layer is low, and the cohesion of the electroless and/or electrolytically coatable particles is low, so that Only the single layer of particles is transferred during the subsequent transfer onto the substrate. After covering at least a portion of the dry dispersion, the endless belt or roller is brought into contact with the support member to which the structural or full surface adhesive layer is applied. In this case, the non-conductive support member preferably moves at the same speed as the two cylinders. The non-electrical support member on which the adhesive layer is applied is coated with the right-handed ... electric and/or electrolyzable coated particles. The sub or the drum is transferred to the non-conductive branch member. The endless belt or the anchorage can also be used as a means for supporting the transmission of the externally transmitted m cattle, but it is also possible to use the same amount of the same or on the side of the 'in this case' (d), or turn to the upper side and the lower side simultaneously. After removing the still Γ/p1 shell and the non-conductive support that has been separated again, the self-transfer medium (4) 残余 transfer medium remains at least partially dry dispersion of 125205.doc -16-200833187, such as binder and no electricity and / or electrolysis Can be coated with particles. Cleaning can be performed, for example, magnetically, mechanically, or by washing. For mechanical cleaning, for example, a doctor blade from a transfer medium to a residue that at least partially drys the dispersion is directed over the transfer medium. The scraped dispersion residue can then be used, for example, directly or after cleaning and/or separating the electroless and/or electrolytically coatable particles, as the <starter f for preparing the dispersion. ^ can be carried by, for example, a solvent in which the binder is dissolved. All of the solvents described above are suitable for this purpose, but the solvent of the dispersion is preferably such that, for example, the dispersion residue can be recycled. It is preferred to use an adhesive which is compatible or miscible with the adhesive on the non-conductive support member or which reacts with the adhesive upon curing. - preferably by means of, for example, printing, washing, rolling, blade scraping or spraying, by means of, for example, continuous coating, dispersions having electroless and/or electrolytically coatable particles, binders and/or solvents Apply to the transfer medium. As an alternative to the % belt or roller, it is also possible to provide a rigid support as a transfer medium. When the rigid support member is used as a transfer medium, a dispersion containing electroless and/or electrolytically coatable particles is first applied thereto, and the hard support member and the non-conductive support member are then used using a defined applied pressure. contact. After transferring the electroless and/or electrolytically coatable particles, the rigid support used as the transfer medium is separated from the non-conductive support such that the electroless and/or electrolytically coatable particles remain adhered to the non-conductive support. Agent. When a rigid support is used as the transfer medium, it must also be removed after the transfer of the electroless and/or electrolytically coatable particles, before the hard support is again coated with the adhesive and the electroless and/or electrolytically coatable particles. Transfer to non-125205.doc -17- 200833187 struts and particles on the bonding layer. Also, as in the case of the same, the lower cut, for example, as a transfer medium, is applied by f brushing, casting, rolling, blade scraping or spraying. The ρ transfer medium may also be a coated layer, a preferred system, a single layer of power and/or electrolytically coatable particles, and may be uncoated or uncoated from the unrolled (f〇il st〇re). And / or electrolysis can be: the most foil is uncoated and applied to the foil. If t is the first, and this is used in 4, the crucible is used for (4) tape, roller or hard support. The particles can be coated, for example, in the form of a dispersion, and the electrolyzable particles can be transferred to a non-conductive branch, ", And/or roll it up and then process it for collection. The piece is then, for example, borrowed: in another embodiment, 'electroless and/or electrolytically coatable particles are attached to the transfer medium by means of magnetic force. Under the circumstance, on the one hand, the transfer medium is long: in addition to the material made of 'but on the other hand', it is also possible to feed the transfer medium f along the magnet (for example, a water magnet or an electromagnet) to hold the smear particles on the transfer medium. S. Electrolysis may be in this condition 'the magnetic force will be selected such that during contact with the non-conductive support member = the particles remain adhered to the adhesive layer and are removed from the transfer medium - in the embodiment, there will be no electricity and / Or electrolytically coatable magnetic particles in solvent = knife solution applied to - hard f or flexible magnetic support (for example, magnetic, but without the addition of polymeric binder. In this case, coating can be (example - fine ~ by printing, washing, breast-feeding, blade scraping or spraying After the therapeutic agent, a layer of particles is obtained, and the thickness of the dried layer of the dispersion applied by magnetic bonding to the magnetic support member is selected such that its 125205.doc -18-200833187 substantially corresponds to no electricity and / or electrolytically coating the diameter of the magnetic particles. The magnetic transfer layer is then brought into contact with the adhesive layer on the non-conductive support. The electroless and/or electrolytically coatable particles are then adhered to the adhesive layer. In this embodiment, The layer of particles on the viscous support is not cohesively held together by the binder, so that only a single layer of electroless and/or electrolytically coatable particles can be transferred to the adhesive layer on the non-conductive support. When processed, after the adhesive layer has been applied, for example by means of a magnet applying an AC field or by cutting and/or removing

An electromagnet that removes electroless and/or electrolytically coatable particles that are still adhered to the magnetic support from the surface of the support. The electroless and/or electrolytically coatable particles can then be reused. In another embodiment, the transfer medium is a magnetic roller. The inside of the magnetic roller contains at least one magnet that does not move, and the roller rotates around the magnets. It is also possible to install two or more magnets having different magnetic field strengths, for example. The first of the magnets contained in the drum is, for example, a receiving magnet. The electroless and/or electrolytically coatable magnetic or magnetizable particles are attracted by the receiving magnet and thereby adhere to the surface of the drum. Depending on the strength of the magnetic field to be set, the effect achieved is approximately only a single layer, and the particles are transferred to the drum. By means of, for example, optical monitoring, it is possible to check for electromagnetism if necessary and/or to electrolyze the magnetizable or magnetizable particles in a single layer on the surface of the drum. For example, 'laser optics are suitable for optical monitoring. When the drum continues to rotate, it is also used as appropriate - a downstream transfer magnet that produces a weaker magnetic field than the receiving magnet causes the electroless and/or electrolytically coatable magnetic or magnetizable particles deposited on the surface of the drum by means of the receiving magnet to be deposited on the non-conductive On the adhesive layer on the support. For this purpose, a non-125205.doc -19-200833187 conductive support to which an adhesive layer is applied is guided along the surface of the drum. In this embodiment, since the particle layers on the drum are not cohesively held together by the binder, only a single layer of electroless and electrolysis-coated magnetic or magnetizable particles can be transferred to the non-conductive support. On the adhesive layer. When the treatment is continued, the adhesive layer is applied, for example, by applying a magnet of the AC field or by using a knife to the surface of the roller.

Electroless and/or electrolytically coated magnetic or magnetizable particles attached to the magnetic cylinder. The electroless and/or electrolytically coatable particles can be turned, for example, into starting materials. It can also be cleaned by washing with a solvent, preferably using the same solvent as that used to coat the electroless and/or electrolytically coatable magnetic or magnetizable particles. In the embodiment, in particular, the solvent is obtained directly from the storage container after the electrolessly and/or electrolytically coatable magnetic or magnetizable particles have been previously separated, for example, by a filter in the pumping circuit. Alternatively, the new solvent can also be used for cleaning, in which case the thus obtained electroless and/or electrolyzed magnetically or magnetizable particles and solvent mixture can be fed to a storage container as a starting material. It may not be sufficient to adjust the desired mixture if it is necessary to make up the absence of electricity and/or electrolytically coatable magnetic or magnetizable particles. In a preferred embodiment, at least one transfer magnet is present downstream of at least one of the receiving magnets. The transfer magnet has a lower magnetic field than the receiving magnet such that the electroless and/or electrolyzed magnetized #1 ± or magnetizable particles can be easily transferred from the surface of the drum to the adhesive on the non-electrical support. In order to coat the surface of the drum in the region of the receiving magnet with electroless and/or electrolytically coatable magnetic or magnetizable particles, it is preferred to immerse the magnetic cylinder in the presence of electroless and/or electrolytically coatable magnetic or magnetizable particles or such particles. In a storage container for the dispersion in a solvent. For this purpose, for example, the magnetic roller is mounted in a floating manner such that it does not store the bottom (four) of the 125205.doc 200833187 container. The mixture of at least electroless and/or electrolytically coatable particles and solvent in the storage vessel is maintained in motion by, for example, agitation or wicking. If the particles in the second layer or between the two closely-bonded bonding surfaces have been deposited, it is possible to remove the particles by non-conductive support from the non-conductive support by magnetic cleaning. The magnetic cleaning system is performed, for example, by means of a non-woven fabric that runs around the magnet. Improper particles are deposited onto the non-woven fabric by the magnetic force of the magnet and are thereby removed from the non-conductive support. • After the transfer medium is transferred to the non-conductive support, the electroless and/or electrolytically coatable particles may also move on the other side of the substrate different from the non-conductive support by an external force. The external force that moves to cause the electroless and/or electrolytically coatable particles to move in the direction of the transfer medium or to move on the other side of the base layer different from the non-conductive support member is, for example, gravity or magnetic force. The force by which the electroless and/or electrolytically coatable magnetic or magnetizable particles are moved is preferably a magnetic force. Since the magnitude of the magnetic force can be adjusted, it is possible to ensure that all of the electroless and/or electrolytically coatable magnetic or magnetizable particles are moved or moved in the direction of the transfer medium to the other side of the non-conductive support member. on. Non-conductive. Electroless and/or electrolytically coatable particles may be any non-electric and/or electrolytically coatable material, a mixture of different electroless and/or electrolytically coatable materials or electroless and/or electrolytically coatable materials with and without electricity and/or Any geometrically shaped particle of a mixture of electrolytically coatable materials. Suitable electroless and/or electrolytically coatable materials are, for example, carbon, such as carbon black, graphite, carbon nanotubes;

Vi is a complex; a conductive organic compound or a conductive polymer or metal, preferably nickel, copper, tin, cobalt, manganese, iron, magnesium, lead, chromium, strontium, silver, octagonal, gold, 125205.doc - 21 - 200833187 Aluminum, titanium, palladium, platinum, rhodium and its alloys, or metal mixtures containing at least one of these metals. Suitable alloys are, for example, CuZn, CuSn,

CuNi, SnPb, SnBi, SnCo, NiPb, ZnFe, ZnNi, ZnCo and

ZnMn. Aluminum, iron, copper, nickel, rhodium, carbon and mixtures thereof are especially preferred as materials for electroless and/or electrolytically coatable particles. The electroless and/or electrolytically coatable particles preferably have an average particle diameter of from 0. 0 〇 1 ^ (7) to π μιη, preferably from 0.005 μηη to 50 μπι, and particularly preferably 〇 01 μηι. The average particle diameter can be determined by means of laser diffraction measurements', e.g., using a Microtrac(R) 100 device. The distribution of particle diameters depends on the method of production. The diameter distribution usually contains only one maximum value, but multiple maximum values are also possible. The surface of the electroless and/or electrolytically coatable particles may be at least partially provided with a coating. Suitable coatings can be inorganic (e.g., Si 〇 2, phosphate) or organic in nature. Of course, the electroless and/or electrolytically coatable particles can also be coated with a metal or metal oxide. The metal can also be present in at least partially oxidized form. Workers If two or more different types of electroless and/or electrolytically coatable particles are intended, this can be done using a mixture of these types. These types are particularly preferably selected from the group consisting of aluminum, iron, copper, nickel, zinc and carbon. However, the electroless and/or electrolytically coatable particles may also comprise a first metal and a second metal, wherein the second metal is in the form of an alloy (with the first metal or one or more other metals), or the electroless and/or Electrolytic coated particles can contain two different alloys. 5 If the electroless and/or electrolytically coatable particles are adhered to the transfer medium by means of a magnetic force, the material from which the electroless and/or electrolytically coatable particles are made must be magnetic or magnetizable. Suitable materials are, for example, metals such as iron, nickel cobalt, or alloys such as NiFe, NiCuC〇, AiNic®, SmC〇. The electroless and/or electrolytically coatable particles may be added to the dispersion in the form of a powder thereof. The powders (for example, metal powders) are commercially available or can be easily produced by known methods, for example, by solution electrolysis from a metal salt. Deposition or Φ Φ Γ 或 or by, for example, reducing the oxidized powder by means of hydrogen, by spraying or by chemically melting the metal (especially) in a coolant (for example, gas or water) and Metal oxide reduction is preferred. Metal powders having preferred granules can also be produced by grinding coarser metal powders. For example, a ball mill is suitable for this purpose. In addition to gas and water atomization, in the case of iron, a repellent-iron powder process for producing a few bases is preferred. This can be done by thermal decomposition of five or more base irons. This is described, for example, in ullman, s Eneyel. (iv) of —al Chemistry, 5th edition, volume A14, page 599. Soft repellent iron knives can occur, for example, at high temperatures and pressures in a heatable decomposer comprising a refractory tube such as quartz glass or V2A steel, preferably in a vertical position, for example by (for example) The heating device consisting of a heating bath, a heating wire or a heating envelope through which the heating medium flows is closed. A few base iron powders are more particularly preferred (4). This coated 基1 base-iron powder adheres to the transfer medium. In addition, no dust is formed. Attached, the coated carbonyl-iron powder can be removed without leaving a residue. This is especially important when the carbon-iron powder is held on the transfer medium by means of a magnet. The coating may be inorganic and/or organic: ,, and organically coated. I25205.doc -23- 200833187 In the case of a layer, a polymer is preferred. Suitable polymers are, for example, polyolefins (such as polyethylene and polypropylene), polyamines, polytetraethylene, polyether, polystyrene, styrene butadiene block copolymers (for example). For example, Styroflex® or Styrolux® from BASF and polyoxin polymers. Polyethylene, polypropylene, and polytetrafluoroethylene are preferred. In the case of inorganic coatings, metal oxides (such as iron oxide), phosphates and silicates are relatively rare. Soil • In addition to the selection of electroless and/or electrolytically coatable particles, the shape of the electroless and/or electrolytically coatable particles also has an effect on the properties of the dispersed dispersion. Many variations known to those skilled in the art are possible in terms of shape. The shape of the electroless and/or electrolytically coatable particles may be, for example, a needle shape, a cylindrical shape, a plate shape or a spherical shape. These particle shapes represent ideal shapes, and the actual shape, for example, may be more or less the same as it is due to production. For example, the drop shaped particles have a practical deviation from the ideal spherical shape within the scope of the present invention. Electroless and/or electrolytically coatable particles having various particle shapes are commercially available. + When using a mixture of & electric and/or electrolyzable particles, the individual mixed mate may also have different particle shapes and/or particle sizes. It is also possible to use a mixture of only one type of electroless and/or electrolytically coatable particles having different particle sizes and/or particle shapes. Metals, iron, copper, recorded words and carbon are also preferred in the case of different particle shapes and/or particle sizes. Combinations of small pieces and spheres are preferred in the case of different particle shapes. In order to obtain a mechanically stable structural or full-surface base layer on the non-conductive support member, the adhesive layer to which the electroless and/or electrolytically coatable particles adhere is preferably at least partially dried after application of 125205.doc -24-200833187 And/or at least partially cured. Depending on the material used for the bonding layer, curing and/or drying can be performed, for example, by heat, light (υν) and/or Han (eg 'infrared radiation, electron radiation, gamma-Han, χ·light shots , microwave) action to carry out. In order to initiate the curing reaction, it may sometimes be necessary to add a suitable activator or curing agent. Curing can also be achieved by a combination of different methods (e.g., '# combination of υν radiation and heat). The curing method can be combined with - _ or successively. For example, the layer can be first partially cured only by υν radiation, so that the formed structure is no longer flow separated. The layer can then be cured by thermal action. In this case, heating can occur directly after υν curing and/or after electrolytic metallization. The proportion of electroless and/or electrolytically coatable particles in the base layer is preferably in the range of from 75 to 99% by weight, particularly preferably from 85 to 99% by weight. To produce a continuous conductive surface, at least one metal layer is formed by electroless and/or electrolytic coating on a structural or full surface substrate. In this case, the coating can be carried out using any method known to those skilled in the art. In addition, any conventional metal coating can be applied using a coating method. In this case, the composition of the electrolyte solution for coating is intended to be coated with the metal of the conductive structure of the substrate ι, and in principle all metals which are more expensive or less expensive than the cheapest metal of the dispersion are available. No electricity and / or electrolytic coating. A conventional metal deposited on a conductive surface by electroless and/or electrolytic coating is, for example, gold, nickel, palladium, platinum, silver, tin, copper or chromium. The thickness of one or more of the deposited layers is within the known ranges known to those skilled in the art and is not critical to the invention. 125205.doc -25- 200833187 Suitable electrolyte solutions for coating conductive structures are known to those skilled in the art (for example, from Wemer Jillek, Gustl Keller, Handbuch der Leiterplattentechnik [Handbook of printed circuit technology].

Eugen G. Leuze Verlag, 2003, Vol. 4, pp. 332-352.) All electrolysis methods known to those skilled in the art can be used herein for electrolysis. * A plurality of grooves having different electrolyte solutions may be connected in series to deposit a plurality of different metals on the substrate to be coated. Alternatively, the metal may be first electrolessly deposited and then electrolytically deposited on the substrate. In this case, different metals or the same metal can be deposited by electroless and electrolytic deposition. The layer thickness of the metal layer deposited on the conductive structure by the method of the present invention depends on the contact time defined by the speed at which the substrate passes through the device and the number of cathodes positioned in series, and the current strength at which the device operates. Longer contact times can be achieved, for example, by connecting a plurality of devices of the present invention in series in at least one tank. In addition to applying an adhesive layer having no electricity and/or electrolytically coatable particles to one side of the non-conductive support member, it is also possible to provide by the method of the present invention. • There is no electricity on the upper side and the lower side thereof. Or electrolessly coatable non-conductive supports of structural and/or full surface substrates. By means of the penetration contacts, the structural or full surface electroless and/or electrolytically coatable substrates on the upper and lower sides of the support can be electrically connected to each other. To create a penetrating contact, for example, before or after the electroless and/or electrolytically coated aperture, holes may be formed in the support, and a conductive layer is applied to the apertures by methods known to those skilled in the art. On the wall. For a sufficiently thin support, it is not necessary to apply the hole wall individually, which is from 125205.doc -26- 200833187 for a sufficiently long coating time, and the metal layer is also in the absence of electricity and/or electrolytic coating. The metal layer is grown from the upper side and the lower side of the support member into the hole and formed inside the hole to create an electrical connection of the conductive structure or the full area surface on the upper side and the lower side of the support member. In addition to the method of the present invention, it is also possible to use other methods known from the prior art for after the pores and/or the blind via metal are at least partially dried or cured, in one embodiment of the invention, 3 in the dispersion. The electroless and/or electrolyzable coated particles are at least partially exposed such that the electroless and/or electrolytically coatable nuclei are obtained, and metal particles can be deposited between the nuclei and the electromagnet and/or the electrolyzed metal (d). ^ to form a metal layer. If the particles consist of materials that have been oxidized, then sometimes the oxide layer must be at least partially removed in advance. Depending on the method (e.g., by using an acidic electrolyte solution), removal of the oxide layer can occur while metallization has occurred without an additional processing step. One of the advantages of exposing the particles prior to electroless and/or electrolytic metallization is that, in order to obtain a continuous conductive surface, by exposing the particles, the coating need only contain about 5 to 10% by weight less than the unexposed state of the particles. / or the proportion of electrolyzable particles. Other advantages are the homogeneity and continuity of the resulting coating and high processing reliability. Electroless and/or electrolytically coatable particles can be mechanically exposed (eg, by brushing, grinding, milling, sandblasting or spraying with supercritical carbon dioxide), physical exposure (eg, by heating, laser, UV light, Corona or plasma discharge) or chemical exposure. In the case of chemical exposure, it is preferred to use a chemical or chemical mixture with the matrix material. Under the condition of chemical exposure, the material 12525.doc -27-200833187 2 can be at least partially dissolved on the surface by, for example, a solvent and the chemical structure of the material or the shellfish can be at least partially supported by means of a suitable reagent.

Was destroyed to expose no electricity and / A solved the granules? . The matrix material is expanded to expose electroless and/or electrolytically coatable particles. The expansion produces (the deposited metal particles can enter the cavity from the electrolyte solution, so that more helmet electrical and/or electrolytically coatable particles can be metallized. The subsequent adhesion, homogeneity and continuity of the metal layer without electricity and/or electrolytic deposition Sexually superior to the methods described in the prior art. The treatment rate of I Μ l and 仏 仏 属 is also substantially higher due to the greater number of exposed electroless and/or electrolytically coatable particles. Additional cost advantage. If the matrix material is €, for example, epoxy resin, modified epoxy resin, epoxy 'poly(tetra) acid g|, tick, styrene-butadiene copolymer or poly-δέ', no electricity And/or electrolytically coatable particles are preferably used by using an oxidizing agent. The oxidant destroys the bond of the matrix material so that the binder dissolves and thereby exposes the particles. The appropriate oxidant is (❹ 酸盐 酸 酸, such as back! Meng 酉夂 If Meng 酉夂 potassium, while sodium silicate, sodium hydride; hydrogen peroxide; oxygen 'in such as Meng salt, strontium salt, silk salt, crane salt Oxygen in the presence of a catalyst for salt; ozone; bismuth pentoxide; sulphur dioxide west; ammonium sulphate solution 'sulphur in the presence of ammonia or amine; oxidized violent; potassium ferrate; dichromate/sulphuric acid · Chromic acid in sulfuric acid or in acetic acid or acetic anhydride; nitric acid; hydroiodic acid; hydrobromic acid · pyridinium dichromate; chromic acid pyridine complex; chromic anhydride 'chromium oxide (VI); Moth acid; tetraacetic acid wrong; g-kun; methyl-brewed; hydrazine, bromine, chlorine, fluorine; iron (III) salt solution; disulfate solution; sodium percarbonate, oxohalic acid salt, Such as chlorate or bromate 125205.doc -28 - 200833187 or iodate; salt of per-acid, such as sodium periodate or sodium perchlorate; sodium perborate; dichromate, such as dichromate Sodium; salts of persulfate, such as potassium peroxydisulfate, peroxymonosulphate; pyridinium chlorochfomate; salt of hypohalous acid For example, sodium hypochlorite; dimethyl hydrazine in the presence of an electrophile; third butyl hydroperoxide; 3 _ gas over-formate, 2,2-dimethylpropionic acid; Des-Martin high-break ; ethylene dioxime; hydrogen peroxide urea adduct; urea hydrogen peroxide (urea hydr〇gen

Peroxide), 2-dioxyiodobenzoic acid; potassium peroxymonosulfate; m-chloroperbenzoic acid, N-methylmorpholine_N_oxide; 2-methylpropan-2-yl hydroperoxide , peracetic acid; pivalaldehyde; iron tetrachloride; potassium hydrogen persulfate; cerium (iii) salt and cerium (IV) salt; in the presence of 2,2,6,6-tetradecylpiperidinyl oxide Oxygen; triethoxy methoxy high iodine; trifluoroperacetic acid; trimethyl acetaldehyde; ammonium nitrate. It is preferred to increase the temperature during the treatment to improve the exposure treatment. The following are preferred: manganate, for example, high-acid acid unloading, potassium citrate, sodium perchlorate, sodium chlorate; hydrogen peroxide; N- Methyl 琳 · · oxide; percarbonate 'such as 'percarbonate or percarbonate unloading; permanate, : (4) sodium or over-acid acid removal; persulfate, for example, sodium (tetra)sulfate: ; sodium peroxodisulfate, peroxydisulfuric acid and peroxydisulfate = over-milk early sodium sulfate, peroxymonosulfuric acid and ammonium peroxymonosulfate; sodium sulphide; hydrogen peroxide urea adduct; Oxygen-acid oxidate or moth acid salt; Yuezhiru salt or sodium; peroxygenate, sodium periodate or peroxyacid l iron salt solution; heavy acid reading; hydrochloric acid; Chlorine; dichromate. 125205.doc -29- 200833187 The following are particularly preferred: potassium permanganate, potassium manganate, sodium permanganate, manganese strontium, hydrogen peroxide and its adducts, perborate, percarbonate, Persulfate salt, peroxodisulfate, sodium hypocarbonate and sodium percarbonate. In order to expose electroless and/or electrolytically coatable particles to a matrix material containing, for example, an ester structure such as polyester resin, polyester acrylate, polyether acrylate, polyester urethane, Preferably, for example, an acid or an assay is used for the oral and/or chemical mixture. Preferred acidic chemicals and/or chemical mixtures are, for example, concentrated or dilute acids such as hydrochloric acid, sulfuric acid, phosphoric acid or nitric acid. Depending on the matrix material, organic acids such as formic acid or acetic acid are also suitable. Suitable alkaline chemicals and/or chemical mixtures are, for example, bases such as sodium bismuth oxide, potassium hydroxide, ammonium hydroxide; or carbonates such as sodium carbonate or calcium carbonate. The temperature during the treatment may be increased as appropriate to improve the exposure treatment. The granules can also be used to expose electroless and/or electrolytically coatable particles to a matrix material. The solvent must be suitable for the matrix material since the matrix material must be dissolved in the solvent or expanded by the solvent. When a solvent in which the matrix material is dissolved is used, the base layer is only contacted with the solvent for a short period of time so that the upper layer of the matrix material is solvated and thereby dissolved. Preferred solvents are xylene, toluene, halogenated hydrocarbons, acetone, methyl ethyl ketone (MEK), mercaptoisobutyl ketone (MIBK), diethylene glycol monobutyl ether. The temperature during the dissolution treatment may be increased as appropriate to improve the dissolution behavior. In addition, it is also possible to expose electroless and/or electrolytically coatable particles by using mechanical means. Suitable mechanical methods are, for example, milling, grinding, grinding with an abrasive or pressure jetting with a water jet, sand blasting or spraying with supercritical carbon dioxide. The top layer coated particles of the cured, printed structural 125205.doc -30-200833187 layer were separately removed by this mechanical method. . Thereby, all of the abrasives known to those skilled in the art can be used as an abrasive for grinding by exposing the electroless and/or electrolytically contained in the matrix material. Suitable abrasives are, for example, pumice powder. In order to remove the top layer of the solidified dispersion by force spraying, the water jet preferably comprises: small solid particles, for example, having 40_ to 12 〇 陶, preferably 6 〇 _

The average particle size distribution of the barrier is pumice powder (Al2〇3) and the quartz powder (Si〇2) having a larger particle size. If the electroless and/or electrolytically coatable particles contain a material that is susceptible to oxidation, in a preferred method variant, the name/妁 armor is at least partially moved before the México layer is formed on the structural or full-area substrate. In addition to the oxide layer. In this case, the oxide layer can be removed, for example, by chemical and/or mechanical means. A suitable material for chemically removing the oxide layer from the self-energizing and/or electrolytically coatable particles is, for example, an acid such as concentrated sulfuric acid or dilute sulfuric acid or concentrated hydrochloric acid or dilute hydrochloric acid, citric acid, acid, amine stone. Flavinic acid, formic acid, acetic acid.

A suitable mechanical method for removing the oxide layer from the electroless and/or electrolytically coatable particles is the same as the mechanical method for exposing the particles. The inventive method for producing a conductive structural or full-area surface on a support can be operated continuously, semi-continuously or in a reduced manner. This method may also be performed continuously in individual steps, while the other steps are performed in batch mode. The method of the present invention is suitable, for example, for producing conductor tracks on a printed circuit board. The printed circuit boards are, for example, printed circuit boards having multiple layers of inner and outer layers, microchannels, on-board wafers, flexible and rigid printed circuit boards and, for example, women's clothing such as computers, telephones, televisions, electric Car group 125205.doc -31 - 200833187 pieces, keyboard, radio, video recorder Bu Xin 0), ^, 00_ to 0 ^ 1 and ] ^; 〇 player, game console, measurement and adjustment equipment, sense In the products of measuring instruments, kitchen appliances, electric toys, etc. The electrically conductive structure on the flexible circuit support can also be applied by the method of the present invention. The flexible circuit support members are, for example, plastic films made of the aforementioned materials mentioned with respect to the support member to which the conductive structure is printed. Moreover, the method of the present invention is suitable for use in the production of RFID antennas, repeater antennas or

His antenna structure, chip card module, flat cable, seat heater, foil conductor, conductor track in solar cell or LCD/plasma screen, capacitor, foil capacitor, resistor, convector, electric fuse. For example, a two dimensional or two dimensional molded interconnect device can also be produced by the method of the present invention. Furthermore, it is possible to produce an antenna having contacts for organic electronic components, and a coating on a surface composed of a non-conductive material for electromagnetic shielding. In addition, it can be used in the case of a flow field applied to a bipolar plate of a fuel cell. The scope of application of the method according to the invention allows the low-cost production of metallized, non-conducting substrates themselves (especially for use as exchangers and sensors, for electromagnetic light or gas barriers or for decorative components (especially for motor vehicles) , public toilets, toys, decorative parts of the home and office departments)), and packaging and swaying. The present invention can also be applied to the field of security printing of banknotes, credit cards, identification cards, and the like. Textiles can be electrically and magnetically functionalized by means of the method of the invention (antennas, transmitters, RFm and transponder antennas, sensing benefits, heating elements, antistatic (even for plastics), shielding, etc.) Contact points or contact welds 125205.doc -32- 200833187 塾 or interconnects are created on the integrated electronic components. The method of the present invention can also be used to metallize, for example, printed circuit boards, RFID antenna or transponder antennas, flat cables, holes in island conductors, channels, blind holes, etc., in order to penetrate the upper and lower sides of the contact. . This method also applies when other substrates are used. If the metallization member produced in accordance with the present invention comprises a magnetizable metal, it can also be used in the field of magnetizable functional components such as magnetic tables, magnetic games, magnetic surfaces on, for example, refrigerator doors. It can also be used in areas where good thermal conductivity is advantageous, for example in foils for seat heaters, floor heating and insulation. A preferred use of a metallized surface in accordance with the present invention is that the product produced in this manner is used as a printed circuit board, RFID antenna, repeater antenna, seat heater, flat cable, contactless wafer card, cladding Thin metal foil or polymer support on one or both sides, foil conductors, conductor tracks in solar cells or LCD/plasma screens or for decorative applications (for example, with φ for packaging materials). One of the advantages of the method of the present invention is that sufficient coating is possible even when materials that are susceptible to oxidation are used for electroless or electrolytically coatable particles. The invention will be explained in more detail below with the aid of the drawings. The figures show only one possible embodiment by way of example. In addition to the examples mentioned, this month comes from. It is also practiced in other embodiments or in combinations of such embodiments. [Embodiment] FIG. 1 and FIG. 1.2 show that in the first embodiment, the electroless and/or electrolytically smeared 125205.doc-33-200833187 sub-transfer to a non-conductive support member having an adhesive layer. The adhesive layer 3 is applied to the non-conductive members. The adhesive layer 3 has a structure of a conductive surface to be produced. Furthermore, a layer 7 containing electroless and/or electrolytically coatable particles is applied to the transfer medium 5, such electroless and/or electrolyzable particles are preferably contained in layer 7 in a single layer. For the non-conductive support! The upper-conducting surface is obtained such that the non-conductive support having the adhesive layer 3 and the transfer medium 5 having the layer 7 containing no electroless and/or electrolytically coatable particles are connected to each other to make it contain no electricity and/or electrolysis. The layer 7 of coated particles contacts the adhesive layer 3. Hunting is carried out by contacting the layer 7 containing the electroless and/or electrolytically coatable particles with the adhesives. The electrolessly and/or electrolytically coatable particles are transferred from the layer 7 to the adhesive layer 3. For this reason, the adhesion of the adhesive layer 3 must be greater than the adhesion of the layer 7. The electroless and/or electrolytically coatable particles in layer 7 can be adhered by means of a polymer layer which is not fully cured and/or dried. The electroless and/or electrolytically coatable particles may also be adhered to the transfer medium 5 by magnetic force like the layer 7. In order to make the adhesive layer 3 contact with the layer 7 containing the electroless and/or electrolytically coatable particles, the non-conductive branch member and the transfer medium 5 are moved to each other, so that the non-conductive electric branch member 1 and the transfer medium 5 are The alignment is such that the adhesive layer 3 and the layer 7 containing the electroless and/or electrically detachable particles face each other. The movement of the support 1 and the transfer medium 5 toward each other is indicated by arrows 9 and 11. When the non-conductive support member 丨 and the transfer medium 5 are pressed against each other, the adhesive of the adhesive layer 3 may be cured and/or dried. In this way, the ruthenium-free and/or electrolytically coatable particles from layer 7 become bonded to the adhesive layer 3. However, it is also possible to remove the transfer medium 5 from the non-conductive support member before curing the adhesive of the adhesive layer 3. Under this condition, the adhesion of the adhesive layer 3 is still greater than that of the transfer medium 5 even in the uncured state. 125205.doc -34-200833187. Figure 1.2 shows the method steps of removing the transfer medium 5 from the non-conductive support member after the layer 7 containing the electroless and/or electrolytically coatable particles has been transferred to the adhesive layer 3 of the non-conductive support member 1. The non-conductive support member and the transfer medium 5 are represented by arrows 13 and 15. As can be seen in Figure 1.2, at the location where the adhesive layer 3 is applied to the non-conductive support member 1, the layer 7 has been detached from the transfer medium 5 and adhered to the wire bond layer 3. In this manner, a substrate containing electroless and/or electrolytically coatable φ and which can be electrolessly and/or electrolytically coated is produced on the non-conductive support member. Figure 2 presents the method steps of transferring electroless and/or electrolytically coatable particles from a transfer medium to a non-conductive support in a second embodiment. In the embodiment presented in Figure 2, the transfer medium 5 is configured as an endless belt:;. In the embodiment presented herein, the endless belts are called 17, 19 operating. At least one of the mechanical shafts 17, 19 is driven to move the endless belt (10). However, it is also possible to drive two mechanical shafts 17, 19. In addition to the embodiments presented herein (in the basin, 'in the case, in the middle, the sub-b is wound around two mechanical shafts 17, operating), it is also possible to provide a single mechanical wire acting as a transfer medium instead of a mechanical winding. The shaft 17 and ^ π are swayed by the %-shaped tribute 15 . Likewise, individual mechanical axes can be arranged in series. Instead of two mechanical shafts 17, 19, it is also possible to use a circular belt 15 shaft. For the purpose of making the electroless and/or electrolytically coatable particle layer 3, it is preferable to contain the adhesive of the second electrode member 1 in a single layer, 43⁄4^j® 7 s ^ , <, , electricity and/or electrolysis can be applied to the endless belt at the 'θ ^ position. After the application of 125205.doc •35-200833187 #&# electric and/or electrolytically coatable particles are transferred from layer 7 to the adhesive layer 3. The endless belt 15 is preferably identical to the non-conductive ones.

move. The movement of the endless belt 15 is indicated by arrow 21 and the movement of the non-conductive support i is indicated by arrow 23. Removing the endless belt 15 on which the layer 7 containing the electroless and/or electrolyzed: coated particles is applied by deviating the endless belt 15 via a mechanical shaft, while the non-conductive support, for example, continues to be in and out of the endless belt 15 moves in the same direction during contact. After the endless belt 15 has been separated from the non-conductive support, the layer 7 containing the electroless and/or electrocoat particles is adhered at the position where the adhesive layer 3 is applied. In this way, the adhesive layer 3 is provided with a surface which can be electrolessly and/or electrolytically coated. After the endless belt 15 has been removed from the non-conductive support i, the portion of the layer 7 still adhering to the endless belt 15 is removed from the endless belt 15. This is done, for example, by means of a doctor blade 25 which is scraped over the endless belt 15. However, it is also possible to use any suitable device known to those skilled in the art that can remove layer 7 from endless belt 15. The residue of layer 7 must be removed from the endless belt so that when layer 7 is reapplied to the endless belt, only one layer contains electroless and/or electrolytically coatable particles 7 preferably in the form of a single layer. If the residue of layer 7 is not removed from the endless belt 15 after separation from the non-conductive support 1, the newly applied layer 7 can cover the residue of the previous cycle and thereby produce a charge-free and/or electrolytically coatable Uneven multi-layered layers of particles. A non-conductive support member having a base layer formed thereon is shown in FIG. To this end, the adhesive layer 3 having the structure of the conductive surface to be produced is applied to 125205.doc -36-200833187 to the non-conductive support member 1. A layer 33 containing electroless and/or electrolytically coatable particles is adhered to the adhesive layer 3. This layer has the same structure as the adhesive layer. The adhesive layer 3 forms a base layer 31 with a layer μ containing electroless and/or electrolytically coatable particles adhered thereto. In order to allow the base layer 31 to be electrolessly and/or electrolytically coated, it is preferred that the electroless and/or electrolytically coatable particles are held in the layer 33 such that it is located on the other side of the base layer 31 different from the non-conductive support member 1. on. Preferably, the electroless and/or electrolytically coatable particles are contained in the base layer 31 such that they are visible on the surface 35 of the base layer. If the electroless and/or electrolytically coatable particles are not visible or only visible to a small extent, they may be exposed. Exposure can be performed, for example, mechanically, physically, or chemically. The method for applying electroless and/or electrolytically coatable particles to a non-conductive support in the third embodiment is presented in Figures 4 to 3.4. In the method presented in Figures 4.1 to 4.3, the electroless and/or electrolytically coatable particles 41 are first applied to the transfer medium 5 in the form of a layer, preferably in a single layer. To this end, the electroless and/or electrolytically coatable particles are "held in the storage container 43 from the storage container 43 to supply the particles 41 to the transfer medium 5. Alternatively, it may be by means of printing, casting, blade scraping or spraying The method applies the particles 41 to the transfer medium. In order to adhere the electroless and/or electrolytically coatable particles 41 to the transfer medium 5, the magnets 45 are disposed on the transfer medium 5 differently from the electroless and/or electrolytically coatable particles 41. On the other side, the magnet may be a less permanent magnet or an electromagnet. The electroless and/or electrolytically coatable particles 41 are held on the transfer medium 5 by the magnetic force of the magnet 45. For this purpose, 'no electricity and/or electrolysis can be coated. The particles 41 must be formed of a magnetic or magnetizable material. 125205.doc -37- 200833187 After the electroless and/or electrolytically coatable particles 41 have been applied to the transfer medium 5, the latter is rendered non-conductive with the adhesive layer 3. The support member 1 is in contact. Fig. 4·2 shows a short time before the non-conductive support member on which the adhesive layer 3 is applied is contacted with the electroless and/or electrolytically coatable particles 41 on the transfer medium 5. Electroless and/or electrolytically coatable particles in contact with the adhesive layer 3 41, the self-transfer medium 5 is detached, and the magnetic force of the magnet 45 is selected to be smaller than the adhesion force of the adhesive layer 3. The adhesive of the adhesive layer 3 may also be at least partially passed after being contacted with the electroless and/or electrolytically coatable particles. Curing and/or at least partially drying, then removing the non-conductive support from the transfer medium 5 together with the adhesive layer 3 and the electroless and/or electrolytically coatable particles 41 adhered thereto. Figure 4.3 shows the short time after the transfer medium 5 has been removed from the non-conductive support 1 to which the adhesive layer 3 has been applied and to which the electroless and/or electrolytically coatable particles 4 i have been adhered. In the embodiment presented in Figures 4.1 to 4.3, for example, the transfer medium 5 can be configured as a non-conductive support! Contact the board, or configured as a braided strap as shown in Figure 2. If the transfer medium 5 is configured as an endless belt, the magnets are preferably disposed between the mechanical shafts 17, 19 around which the endless belt 15 runs. The fourth embodiment in which ..., electricity and/or electrolyzable particles are held on the transfer medium 5 by means of magnetic force is presented in FIG. In the embodiment presented in Figure 5, the transfer medium 5 is designed as an open y of the hollow mechanical shaft 1. The receiving magnet 53 and the transfer magnet 55 are housed in the hollow mechanical shaft 51. The electroless and/or electrolytically coatable particles 41 are attracted to the hollow mechanical shaft 51 and adhered thereto by means of the receiving magnets 53. The electroless and/or electrolytically coatable particles 4丨 are held on the hollow mechanical shaft 5 in summer by the magnetic % of the transfer magnet 55. However, the magnetic field of the transfer magnet 55 is selected such that the electroless and/or electrolytically coatable particles 41 in contact with the adhesive layer 3 on the non-conductive support member 125205.doc-38-200833187 1 remain attached to the adhesive layer 3 while It is not removed from the adhesive layer 3 again due to the strong magnetic field of the transfer magnet 55, and continues to adhere to the hollow mechanical shaft 51. Instead of the embodiment shown in Figure $ (with receiving magnet 53 and transfer magnet 55), it is also possible to provide only one magnet or even two or more magnets. Under such conditions, it must be ensured that the magnetic force in the region where the electroless and/or electrolytically coatable particles 41 are transferred from the hollow mechanical shaft 51 to the adhesive layer 3 on the non-conductive support member 1 is less than the adhesion of the contact layer 3. . After the electroless and/or electrolytically coatable particles 41 adhered to the hollow mechanical shaft 51 are in contact with the adhesive layer 3 on the non-conductive support member 1, the electroless and/or electrolytically coatable particles still adhere to the hollow mechanical shaft 51 "It is preferred to first remove the hollow mechanical shaft before re-accommodating on the hollow mechanical shaft 51. For example, this can be done by means of a coil 57 applying an Ac field. The hollow mechanical shaft 51 is demagnetized by the gossip field 57. In this way, the electroless and/or electrolytically coatable particles previously adhered to the hollow mechanical shaft 5" are detached from the hollow mechanical (four) or 'adhered to the hollow mechanical shaft 51 without electricity, or the electrolyzable particles can also be borrowed Removed by a scraper or by gravity. The above is: the electroless and/or electrolyzable coated particles 41 are transferred to the hollow mechanical axis η. In the embodiment presented, the hollow mechanical shaft 51 is immersed in the solid

Holding the storage container Z nanomagnet 53 of the electroless and/or electrolytically coatable particles 41, the two bamboos are inspected, and the coated, coated, and/or electrolytically coated particles 41 are attracted from the storage container 59 to the hollow mechanical shaft 51. on. "59 and no electricity and / or electrolyzable particles can be stored in the form of a final form of U dispersion: in the storage container. Stirring and marriage in the storage container in the dispersion - + ^ Jia Jiang Kung Kong (four) & heat Adjusting the electroless and/or electrolytically coatable particles 125205.doc • 39 - 200833187 41 after being received by the receiving magnet 53 and before being transferred to the bonding layer 3, may be at least partially performed, for example, by a drying step The volatile component of the dispersion is removed (not shown in Figure 5). The electroless and/or electrolytically coatable particles 41 are received on the hollow mechanical shaft 51 (for example by means of a laser optics (not shown in Figure 5)) Optical monitoring is performed. By applying a strong magnetic field, the layers of particles can be adjusted so that only a single particle layer is transferred. • The electroless and/or electrolyzable coated particles 41 have been transferred to a non-conductive support! After the adhesive layer 3 (as shown in FIG. 5), in the region where the adhesive layer is not applied, the particles adhered to the non-conductive support member 1 and may be assisted by mechanical or magnetic cleaning or Removed by washing with a suitable liquid. Magnetic cleaning is In the meantime, the hollow mechanical shaft with non-woven fabric is wound around the magnet 63. The electroless and/or electrolytically coatable particles that are not adhered to the adhesive layer 3 are attracted by the magnet 63 and then by means of a hollow mechanical shaft. 6! Non-woven material is moved, except for the mechanical axis 之中 of the magnets 53, 55, 57 with internal placement :::,: It is possible to manufacture the hollow mechanical shaft 51 from a magnetic material or use a magnetic/covering 盍After the electroless and/or electrolytically coatable particles are adhered to the hollow mechanical shaft, after transfer to the adhesive layer 3 of the non-conductive branch member 1, the hollow mechanical shaft 51 is preferably in a mechanical manner (for example, Fig. 3 shows the method steps for transferring electroless and/or electrolytically coatable particles onto the (four) electrical support in the fifth embodiment. Or the electrocoatable particles 41 are transferred from the dispersion 71 to the transfer medium 5 to form a layer. The electrolessly and/or electrolyzable particles 41 containing the 125205.doc 200833187 in the dispersion 71 are transferred to the transfer medium 5 by means of the magnet 75. Moving in the direction of the layer, thereby forming a layer of electroless and/or electrolytically coatable 4 i, wherein the electroless and/or electrolytically coatable particles 41 touch the transfer medium 5. In the second step, the non-conductive support i on which the adhesive layer 3 is applied is brought into contact with the layer 73. This step is presented in the figure In layer 2. 2, the layer 73 and/or the adhesive layer 3 may be at least partially cured and/or at least partially passed prior to contacting the layer 73 containing the electroless and/or electrolyzable particles 41 with the adhesive layer 3. Drying, but this is not necessary for φ. In order to transfer the layer 73 having electroless and/or electrolytically coatable particles 41 only to the position where the adhesive layer 3 is located on the non-conductive support member 1, there is no electricity and/or electrolysis. The adhesion of the layer 73 of the coatable particles 41 to the transfer medium 5 must be less than the adhesion of the layer 73 having the electroless and/or electrolytically coatable particles 4 to the adhesive layer 3. The effect is that when the transfer medium 5 is removed, as shown in Fig. 6.3, the layer 73 having the electroless and/or electrolytically coatable particles 41 is applied to the non-conductive support 1 at the position where the adhesive layer 3 is applied. Staying adhered to the adhesive layer 3, and at a position where the non-adhesive layer 3 is applied to the non-conductive support member, the layer 73 having no electricity and/or electrolytically coatable particles remains adhered to the transfer medium 5. . In this manner, the base layer 31 is produced having the same structure as the adhesive layer 3 previously applied to the non-conductive support member 1. After the transfer medium 5 has been removed, the adhesive layer 3 to which the layer 73 is attached and which has no electricity and/or electrolytically coatable particles 4 is at least partially cured and/or at least partially dried. Since the electroless and/or electrolytically coatable particles 41 have moved in the direction of the transfer medium 5 by means of the magnetic force of the magnet 75 during application of the layer to the transfer medium 5, according to the invention, there is no electricity and/or electrolysis The layer 73 of the coatable particles 41 has been transferred to the adhesive layer 3 of the non-conductive support. 125205.doc -41 · 200833187 After the base layer 31 is different from the non-electrical and/or electrolytically coatable particles, there is no electricity and/or electrolysis The coated particles can be coated on the other side of the 41-position conductive support member 1. Thus, no 41 can be easily electrolessly or electrolytically coated with a metal layer. BRIEF DESCRIPTION OF THE DRAWINGS FIG. U and FIG. 1.2 show that in the first embodiment, the electroless and/or electrolytically coatable particles are transferred to a non-conductive support member having an adhesive layer;

In the first example, the electroless and/or electrolytically coatable particles are transferred to a non-conductive support member having an adhesive layer; FIG. 3 shows a non-conductive support member on which a base layer is applied; 1 to 4·3 show that in the third embodiment, the electroless and/or electrolytically coatable particles are applied to the non-conductive support member having the adhesive layer; the figure shows that in the fourth embodiment, there is no electricity and/or Or electrolyzable coated particles are coated onto a non-conductive support member having an adhesive layer; FIG. 6.3 shows that in the fifth embodiment, the electroless and/or electrolytically coatable particles are coated to have-bonded On the non-conductive support of the layer. [Main component symbol description] 1 Non-conductive support member 3 Adhesive layer 5 Transfer medium 7 Layer 9 Movement of support member 11 Movement of transfer medium 5 15 Endless belt 17 Mechanical shaft 125205.doc -42- Movement of mechanical shaft endless belt The moving blade base layer of the support member 1 contains the layer of the electrolessly and/or electrolytically coatable particles. The surface of the base layer 31 is electrically non-charged and/or the electrolyzable coated particle storage container magnet hollow mechanical shaft receives the magnet transfer magnet coil storage container with non-woven hollow Mechanical shaft magnet polymer polymer layer magnet-43-

Claims (1)

200833187 X. Patent Application Range: 1. A method for producing a structural or full-surface conductive surface on a non-conductive support member (1), comprising the steps of: (4) applying an adhesive layer (3) to the non-conductive layer On the support member (1), the adhesive layer (3) has the structure of the conductive surface; (b) transferring the electroless and/or electrolytically coatable particles (9) from a transfer medium (7) to the adhesive layer (3), The electroless and/or electrolytically coatable particles (41) are applied to the transfer medium (5) in the form of a layer; (c) the transfer medium (5) is removed; (4) at least partially dried and/or at least partially cured. Bonding of the layer (7), such that the electroless and/or electrolytically coatable particles (41) become bonded to the adhesive layer (3) and thereby form a base layer (31); (4) by no electricity and/or Electrolytic coating, a metal layer is applied to the electroless and/or electrolytically coatable particles (9) by means of which the adhesive layer (7) is adhered to the non-conductive support (1). 2. The method of claim 1, wherein the electroless and/or electrolytically coatable particles (41) are fastened to the transfer medium by a mixture (7), such as the request item I, the earth, the soil β The base layer (31) contains 75 to 99.9% by weight of electroless and/or electrolytically coatable particles (41). Π4Π The method of claim 1, wherein the electroless and 7 or electrolytically coatable particles (41) are magnetic. 5. The method of claim 4, T Hai #无电, and/or electrolytically coatable particles) is attached to the transfer medium (5) by magnetic force. 6. If the request item U t , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , ) is moved on the other side of the base layer (31) different from the non-conductive support member (1) by an external force. 7. The method of claim 6, wherein the external force is a magnetic force. ^ 'A method of claim 1, wherein the electroless and/or electrolytically coatable particles (3) have Fe, Zn, Cu, Ni, Ab carbon or a mixture thereof. 9. The method of item 1, wherein the electroless and/or electrolytically coatable particles _ (41) are a few base-iron powder. 1. The method of claim 9, wherein the carbonyl-iron powder is coated with an inorganic and/or organic layer. The method of claim 1 wherein the coating of the carbonyl-iron powder comprises polyethylene, polypropylene or polytetramethylene. 12. The method of claim 1 wherein the adhesive layer (3) on the support member (1) and/or the electroless and/or electrolytically coatable particle layer on the transfer medium (5) is printed and cast by printing Apply by rolling, dipping or spraying. The method of claim 1, wherein the structural conductive surfaces are applied to the upper and lower sides of the (four) guide f support (1). The method of claim 13, wherein the structural conductive surfaces on the upper side and the lower side of the non-conductive support member (1) are connected to each other by at least one penetration contact. 15::f: The method of M, wherein at least one of the walls of the non-conductive support has a metal layer by electrolessly and/or electrolytically coating the through contact. 16 · The material of the non-conductive support (1) is produced as in t, i_^, t _ , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , . Rolled resin impregnated fabric or a thin plastic 'used to produce conductor transponder antennas or other antenna structures on printed circuit boards, wafer card seat heaters, sway conductors, 'body tracks in solar cells or To produce electricity in any form 1 7. Method of claim 1 Orbital, RFID antenna, module, flat cable, or LCD/plasma screen to decoat the product. 18 · As in the case of claim 1, the soil, / ', is used to produce a decorative or functional moon-like surface on the product, the cage surface is used to shield electromagnetic radiation, for heat conduction or for use as Package. 19 • Request for work; Xi Shi. v, Wanfa's are used to produce thin metal foil or polymer supports on one or both sides of metal clad. 125205.doc