TW200815799A - Black matrix compositions and methods of forming the same - Google Patents

Abstract

Black matrix compositions, methods for forming a black matrix, and apparatus for use in forming a color filter for a flat-panel display are disclosed. The compositions, methods and apparatus use an additive including polymerizable molecules, the polymerizable molecules each including polar portions and non-polar portions. The non-polar portions are ink-phobic and migrate toward the surface of the black matrix composition upon the surface being exposed to activation energy. The polar portions of the polymerizable molecules are ink-philic relative to the non-polar portions. Numerous other features are disclosed.

Description

200815799 IX. Description of the invention: [Technical field to which the invention pertains] ^ Mainly concerned with flat panel displays, more particularly with respect to black variations for flat panel displays, and ..... ...::.. . . . . . [Previous Technology], :::, the industry of the display - directly trying to use inkjet printing to produce a display · a /, Xenon 1 ^ 1 color filter. The problem of effective ink jet printing is to accurately and accurately eject ink or other materials onto a substrate while achieving high throughput. Accurately falling into the substrate, for example, the ink droplets may not be described in the ancient soil, the pixel well. Therefore, there is still a need for methods and devices to tease W ^ 1 γ. Manufactured by high-yield inkjet printing # [Summary of the Invention] In some aspects of the present month, a method for forming a flat panel is displayed. ^ ^ ^ ^ ^ ^ , ^ f ^ ^ ^ ^ ^ ^ ^ ^ Additives for Polymeric Molecules, | ^ 7 ^ The parent polymerizable molecules include both polar and polar moieties. Non-polar entanglement 曰丄 曰丄 Ρ Ρ 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有 具有5 ^ ^ ^ ^ # ^ ^ 63⁄4 ^ ® it # 〇T ^ The extreme 丨 of the knife „ρ 分 has a ink-replenishing UnbphUiO with respect to the non-polar part. Structure of top surface and ink-retaining sidewall surface / 6 200815799 In another aspect of the present invention, a device for a color filter comprising a substrate, and a layer of a black matrix component formed on the substrate. The black matrix component includes an additive containing a polymerizable molecule, each of which includes a polar portion of a private knife. The non-polar portion has ink repellency, and when the surface is exposed to activation energy, - . . . Surface migration of the component. The polar portion of the polymerizable molecule is relative to the non-polar portion In a further aspect of the invention, there is provided a method of forming a color filter for a flat panel display, the method comprising forming a zero matrix component comprising polymerizable molecules, each polymerizable molecule comprising a polar portion And a non-polar portion; providing a substrate; forming a layer of a black matrix component on the substrate; and applying an activation energy to the black matrix component on the substrate, the non-polar portion is ink repellent, and applying activation energy to the surface of the black matrix component When the non-polar portion migrates to the surface of the black matrix component, the polar portion of the polymerizable molecule is ink-receptive with respect to the non-polar portion.

[Embodiment]

The gorge board is not good, and the color stencil material) has different colors of ink on the substrate, and the inkjet printer is suitable for 200815799 ... . . . . . . And/or other suitable materials are injected directly into the specific wells defined by the pixel array ("commonly known as the "black matrix"). Prior to ink deposition, a black matrix of photographic wells may be formed on the turbulence plate using lithography or any suitable process. , — . . . : : . . : : : The material in contact with the liquid has the composition of the reactive material that attracts or repels the liquid, the corresponding surface chemistry, and the chemical properties of the liquid. Interaction. This phenomenon is known as hydrophilicity (for example, similar to ink affinity for liquid inks) and hydrophobic material r μ, r (for example, similar to ink repellency to liquid inks). Hydrophilic, also known as hydrophilic, is a film or coating formed on the crepe of a material that exhibits affinity for water. The hydrophilic material also has a high surface H 4 surface tension value and has the ability to bond with ice, hydrophobicity, also known as hydrophobic, is a phase + fine, 疋 is opposite to water in response to hydrophilic materials. Material properties. Hydrophobic material > "Life, 'thickness (with water)" has a tendency to absorb water or not, and in the sputum from the surface of the scorpion, the water is "bead J (ie, forming discrete droplets) 〇跻★From 』t)' Water materials have low surface force values and are lacking in their surface chemicals, b-deficient shellfish lacks, and forms a bond with water. >it fi - # τ ^ # ^ ^ ^ ^ ^ for the base) can be "parental", and relative to the scale in liquid (for example, oil-based water. Surface chemistry allows these materials to wet on the surface to form liquid bears Miscellaneous 7k; (Wei Jinmu female 丄200815799 can be "beer", or vice versa. Here the smothering, hydrophobicity and ink repellency means relative terms, materials for - some ink can It is ink-repellent, but it can be in-ink for other inks. J. Another

The outside is not considered to be ink-repellent because the material is hydrophobic. Similarly, the material cannot be considered to be ink-retained because the material is hydrophilic. Thus, for example, the material can be both hydrophobic and ink-receptive, or both hydrophilic or ink-repellent, since, for example, the ink can be oil-based or water---: ...-::::: wettability Refers to the surface properties of the material, which produces a value for each compound. Wetting is the state of contact between the fluid and the surface when the two are in contact. When the liquid has a high surface tension value (strong internal bonding), it will form droplets, while a liquid with a low surface tension value will expand in a larger area: the upper layer (combined with the surface). The other item, '), if the surface has high surface energy (or surface tension), the droplets will stretch or wet the surface. If the surface has a low surface energy, then droplets are formed. This phenomenon is the result of minimizing the gap. If the surface is high energy, it is desirable to cover it with liquid because the interface will reduce its energy and the like. With a specific liquid, the moisture content of the material can be determined by the surface tension value of the material. By measuring the surface of the solid and the surface tension at ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ δ m ^ 〇 is the force caused by the force of the 勹 〇 , , , , , , , , , Different materials (eg, droplets on the surface of a solid crucible) contact each other to form an interface or boundary. The reason for the production of the knives is that in order to respond to the imbalance of molecular forces occurring at the point of contact at 9 200815799, all 桠 and 匁 have a tendency to reduce their surface area. The result of this force will vary with the system of different poor and solids, which will control the wettability between the droplet and the surface and the contact with the specific liquid on the solid surface, "along from the solid point of contact to the liquid The angle measurement formed between the lines of the drop radius. The contact angle is related to the surface tension of the Young's equation, and the behavior of the specific liquid-solid interaction/zero contact angle can be calculated by the bridge equation to cause wetting. The angle between zero and ninety degrees results in a keying of the liquid (due to molecular attraction). Angles greater than ninety degrees indicate that the liquid tends to shrink toward or away from the solid surface. 90. Or larger contact angles usually represent the surface. Non-wet, and an angle of less than 9 意味着 means that the surface is wettable to water and δ 'wettable surface may also be referred to as hydrophilic, while non-full surface may be hydrophobic Similarly, for inks, the wettable surface is also / ink-repellent 'non-wet surface can also be called ink-repellent.

The (superphobic) surface has a diameter of about 150. The contact angle is generally expressed as no contact between the droplet and the surface. This condition is sometimes referred to as the "Lotus effect," > the property of the soil J spread over a large area is sometimes referred to as the "wetting effect." -. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . The cross-sectional profile (eg, distribution) of the ink droplets in the well may not be the most embarrassing for forming a color. In some cases, the uneven distribution of ink in the alizarin well may result in a color filter 10 200815799 t 13⁄4 ^ m ο • _ : · · ' · . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (for example, ~ ash, early body, etc.), dry resin, epoxy solvent. The black matrix component provided by the method and apparatus of the present invention and the method and apparatus of the present invention include, in one step, a wetting additive which improves the properties of the lining, the turret, and the wetting of the matrix. For example, in one embodiment, the addition of ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ two additives can increase the top flat surface of the black matrix 铕 * ^ ^ ^ ^ ^ ^ t ^ ^ ^ ^ ^ ^ ^ ^ ( ; black moment _ defined each pixel well (four) a change (for example, increase) ink affinity). The black matrix component can reduce the mixing of color inks during ink jetting and improve each (four) distribution: (4) (10) Inadvertently falling on the top surface of the halogen matrix, it will fall into the halogen well and better wet the sidewalls The tendency of the ink of the present invention to fall into a sapphire well and unfold in a sputum well reduces the accuracy or precision required for the printer when dispensing ink. In one or more embodiments, the wetting additive can comprise any material having a polymerizable molecule, wherein each polymerizable molecule has a relatively inotropic polar portion and a relatively ink-repellent non-polar portion. For example, the material may comprise a plurality of hydrophobic group-containing monomers and/or oligomers such as fluoropropionic acid S precursors and/or oligomers, silicone-group-contained acrylic acid. Ester monomers and / or oligomers, 200815799 Other prosthetic acid (IV) is in the process of reaction of military money - dimensional network structure or polymer chain process. As described in one step, the oleoyl group of the additive molecule can be concentrated at the top surface of the matrix by curing (CM-) step (iv). In the pattern I, a black matrix having a surface of the pixel surface of the ink-repellent polar pixel well (1 ο relative to the top flat surface of the black matrix) can be formed. Referring to FIGS. 1 to 12, the black matrix of the present invention will be described. A method of forming a black matrix component and an example of a method of manufacturing a black matrix. As shown in Fig. 1, a method 101 of fabricating a matrix on a substrate in accordance with an embodiment of the present invention is illustrated. Referring to the figure, in step 1〇5, a black matrix component containing a wetting additive can be defined. For example, the black matrix component fly includes a wetting additive such as a hydrophobic group-containing monomer or oligomer (eg, a gas acrylate monomer or oligomer, a sulphur-containing acrylate monomer, and 7 or 4 poly , other propylene ester ester monomers and / or oligomers, etc.). The black matrix component may include other components such as, for example, a pigment dispersant, a starter (for example, a photoinitiator), a polymerizable monomer, a binder resin, and a pigment dispersant contained in the solution for the pigment (for example, , carbon black) is divided into yellow throughout the black matrix composition. The initiators contained are used to aid in the polymerization of the reverse shoulders (e.g., 'photopolymerization, thermal polymerization, or other feasible reactions). The work may include polymerizing a monomer (or oligomer) to polymerize the component, thereby forming 12 200815799 ' . . , L - . . . . . . . . . . . . . . . - : _ - Γ , .',.-. . ' •... , . . . y : ' -- . . . . . . . . - ' ' - - · ...-.L . . . : . ' r : '; ;. ' · ; ; I.. :' .. .: - . , : · ·. . ...- ...- / · ' ^ ' . . I .: ... .. .. ' :. . ...:. . . 1 .' . : :- ' ................. into... ---.. ..: ... ·, - : ........ .- . ·. . : -V . . . . : . Black matrix. Examples of the molecule include a acrylate monomer/rice.. ' _ _ . . . -- body/oligomer, and the like.可良. ···'.' '* . : - . . ' ' . ' Degree and intensity. Talking about the dry mixture tree deer: implementation 舛^ - · ' ..... . . '-.· - '.· - . may include solvents to temporarily reduce the dryness of the composition (eg r I ^ ^ , . , ' -- · ..... ? . : . - . - : . - - - Ether acetate (PGME A ) or other suitable solvent such as organic solvent 1 _ In at least some embodiments, the black matrix component may comprise A total of about 100 ppm to about 10,000 ppm by weight of the wetting additive (which includes a polymerizable molecule having an ink-sensitive polar portion and a non-polar non-polar portion), and the foregoing total components are in the absence of a solvent. In some embodiments, the concentration of the wetting additive may preferably be selected from the range of about 500 ppm to 5,000 ppm by weight of the total component (without solvent). Additives. Additional examples of wetting additive σ agents include one or more manufactured by Sartomer Ltd. of Exton, Minn.

CN4000, CN9800, CN990' by Dusseldorf, Germany

TEGO® Rad 2000 series manufactured by Degussa^AG (eg 2200η, 23 50 and/or etc.), TEGO® Glide series and / or TEGO® Flow series, etc. However, one or more additional and/or different additives may be employed. The choice of a suitable wetting additive can be based, for example, on the molecular weight of the wetting additive, the hydrophobic base concentration, the reactivity, and the like. In some embodiments, 13 - ..-.--- - - - - · · . -' ...-/ '.. . ..: :- ' -...':..〆: , : - ., ...... - , : V - ι ::·- " . .... ' , ' - - ' · ; : , 1 . , · . · · ······ . . - · · ·..,'-··,.·· ', ·- · :.:...1 ': .·.. ....... ..... ,. - - - - ' . - '· ...... '. : - .-'ι ... The wetting additive can have from about 1 00 MW to about 10 〇ν〇〇〇Mw^

'· * :-. . . · · · .... -:: molecular weight in the range of average molecular weight). Complex I 500 MW to 1 〇, within the range of 〇〇〇. Although it can be: rubber or smaller and / or different molecular weight wetting additives. /

- ' Λ'' V- :- ' - ' ; - -V . :, . . . : : ' . ,; ' Λ:...... ^ ^ ^ ^ % . " : ..... . . :. Triacetate (TAC), polycarbonate ( ?〇1^

Polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyvinyl chloride (PVC) 'polymethyl methacrylate (PMMA), cyclic olefin copolymer (COP) and / or other Suitable materials. Fig. 2 is a side cross-sectional view of the substrate 201 which can be processed according to the method ι〇ι . . . - In step 109, a layer 203 of the black matrix component 2〇5 can be formed on the substrate 201 (Fig. 2). The black matrix composition layer 203 may be formed on the substrate 201 by an immersion method, a spray method, a rotation method, a spin coating method, or other suitable methods. As such, the substrate 201 can be coated by the black matrix component 2〇5. The substrate 201 can be heated to dry the black matrix component 205. Thereby, the falling agent in the black matrix component 205 can be evaporated. This method of post-coating heating can be referred to as a "soft-bake" process. In step 111, activation energy can be applied to the black matrix component 205 to polymerize the wetting additive, thereby polarizing the molecules of the wetting additive such that the ink-repellent portion of the molecule migrates toward the activation energy, depending on the composition 205, using any feasible The activated energy completes the polymerization. For example, ultraviolet light, electron east, lasers, and/or lamps can be used as an activating energy source. Other sources of activation energy can also be used or used in combination. 14 200815799 In some embodiments, in step 111, the black matrix can be patterned into : : - : - ' . - \ '. For example, as shown in Fig. 3, the mask 301 can be placed at (or . . . . . . . ' ; - / . :.v - - .;

It is formed on the upper portion of the black matrix composition layer 203. Thereafter, UV or other wavelength light or energy 3 03 can be used to relocate 2 0 3 . The energy 3 0 3 may expose a portion of the black matrix composition layer 2 0 3 3 5 , - - . , - / . ' 1 .. - : . . . but the other portion 307 of the black matrix composition layer 203 is not exposed. It is noted that in its embodiment, a negative mask capable of exposing the opposite of the black matrix composition layer 203 to the energy 303 may be employed. When light (or other energy) having a suitable wavelength strikes a portion of the black matrix composition layer 203, the initiator in the black matrix composition layer 205 absorbs light 303 (energy) to form radical molecules in the exposed portion. The initiator can be used as a polymerization initiator for the exposed portion of the black matrix component layer 203, as follows: Polymerization of a monomer which can be polymerized. Therefore, the exposed portion of the black matrix component layer 203 may include a polymer obtained by polymerizing a polymerizable monomer. At the lithography exposure, the polymerizable monomer of the wetting additive is able to lock (lock

After the exposure, a development step can be performed on the substrate 201. For example, a developer may be employed to develop exposed or unexposed portions of the black matrix component layer 203 to remove the portion. For example, the binder resin included in the exposed portion can be reacted with the developer. Fig. 4 is an embodiment of a cross-sectional view of the substrate 201 after development. In the formation of the color filter, by using the 15 200815799 space generated by the removal of the developing portion, it is used as a pixel area or a well, and by means of + shame, the device injects ink into it, thereby defining The black matrix is 4 0 3 . ...... : 1. . : : * . . . . . . . . . . . . . The substrate 2〇1 can be further cured. For example, the substrate 201 may be modified by "s," or exposed to ultraviolet light, electron beam ray, laser, or the like to cure and crosslink the black matrix components in the layer 203, and in the black matrix composition layer 203. Forming a crosslinked resin. As shown in Fig. 5, when the black matrix component layer 2 〇3 is energized, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . When the non-polar portion of the wetting additive molecule can rise to the top surface 503 of the black matrix composition layer 203, an ink repellent layer is formed on the top surface 503 near the black matrix. 505. The ink repellent layer 505 is relatively ink-repellent (for example, compared with a black short-form material containing a lower concentration or no wetting additive. . . . . . . . . . . In this manner, the top surface 503 of the black matrix 403 may be ink-repellent' and formed on the sidewall surface 507 of each of the pixel wells in the black matrix (eg, adjacent to the pixel region 401). Surface 503, in some embodiments, is even ink-repellent. Thus, the top surface of the black matrix is 5 0 3 < leakage between the adjacent wells of the soil Ink, and can mix the color of the anti-soil ink during the jetting process, and help to improve the filling profile of the pixel well (for example, make the filling of the pixel well more consistent and complete), and then produce improved ♦ color filters For example, FIG. 6 is a cross-sectional view of the ink 601 in the halogen region 401 of the base 201 according to an embodiment of the present invention. According to FIG. 6, after curing, the black matrix is concentrated. The wetting additive of the top surface 503 causes the top surface 503 to be ink-repellent, while the sidewall surface 507 is protected. 2008 200899799 . . . . . .:: . . . - / ' ' . ' - ' -, - . :- '-. ... . / :' ' - . - - · ·· . 1 · • : . . . · . ... , ..... , - ' ... · - · · - · · · ' . .-.: - - . . : ^ ·. . . '. Holds less ink repellency, even ink retention. So ^ ink 60 1 can be integrated. .. . - Beads away from the top surface 503 of the black matrix 403, so that the ink 601 does not exceed .....' - ' ' ' " . - · The pixel area 401 spreads. In fact, the migration of the moisturizing additive May be during the entire formation process of the wells (eg, on the substrate) Dynamic procedure component layer during the black matrix is formed, during the soft bake, during the UV curing process of any other), it occurred. In at least one embodiment, at a temperature of 1051, the soft roasting time can be .... - - . . .

It is about 1.5 minutes (in the air). 11 ¥curing (exposure) can be about 30-60 seconds in air and about 10 minutes in air. According to its ... : . . . ‘ :. ' He can bake and/or cure the gas environment (eg, gas, argon) with other soft bake, UV cure and/or final solidification time. Figure 7 shows an example of the use as a wetting additive molecule 701: in accordance with an embodiment of the present invention. Referring to Figure 7, molecular 701, by way of example, can include a first end 703 that is inked and/or reactive. Additionally, the example molecule 701 can include a second end 705 that is ink repellent. Figure 8 illustrates the orientation 801 of the example breakout 701 of Figure 7 in the black matrix component 205 prior to curing (e.g., prior to applying activation energy), in accordance with an embodiment of the present invention. Referring to Fig. 8, in the position 801 » · · · · before curing, the first and second ends 7 〇 3, 7 〇 5 of the molecules may be approximately randomly oriented, and the molecules are substantially uniformly distributed throughout the black matrix component 205 in. Figure 9 illustrates the position of Figure 17 200815799, after the curing (e.g., after application of activation energy), in the black matrix composition 205, in accordance with an embodiment of the present invention. The reference room 'minus: 701 liters to the black matrix in the sub-molecule 7P1's sparse end exposed to the surface, the surface of the energy), in order to form the former I Ling, the top face 593 than any hole shape, ink repellency :-. .;'.. ' :' . . - . . .. ' ' . . . '.; . : : - - . . . . . . . Please refer to Figure 10 to Figure I2' depicts three exemplary structural formulas for polymerizable molecules suitable for wetting additives in accordance with this statement. The first schematic depicts the wetted additive molecule 1000 having a non-polar tail portion 1002 having a structural formula wherein the non-polar tail portion 1002 contains an ink-repellent CF2 chain. The polar portion 1004 includes a 版 版 # 厌 厌 厌 以 以 以 以 以 以 以 以 以 以 是 是 是 是 是 是 是 是 是 是 是 是 是 是 是 是 是 是 是The molecule 1000 further includes a polymerized portion 1〇〇6 which is also directly attached to a few base plate atoms of the polar portion 10〇4. ζ ^.^ 1006 ^ 〇 r n - Describes the structural formula of the sample gentleman's additive molecule u with a non-polar body moiety. The 12th prince depicts the example of the stone 人 几 矽 矽 矽 矽 1200 1200 1200 ^ ' 黑 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ ▲ Photoinitiators, pigments, solvents, etc.. In this case, the ink on the love gland material usually produces an ink contact angle of less than about 5 households on the top of the black matrix "., moment drop". Conversely, The additive contained in this hair, ^5 degree month can be in black 18

;: : . . '.二_:.v .. · . ,- :- '' 'v .: , ,. :' - ' ·.. ' . ' ; - . - - ' / .:·. >-..:' - ;-:;'; ';; :·;;νΛ·":'';'.';;V;:vv:;-;;;V^·.',;; V :. ;·····,Λ:.;^ ; .' ·:······.-;'v:. . ''...;.;-; -::;' ;,;: .''.: — . - ;.'τ — . .Λ ' I:. . . '- Τ ' : . I . : .-厂:...I: ' ..厂_ ' - .':''.'./··--· .' Γ\. - - J ^ ; :' - ' ;' : I". ' ;' : ;.* ' - - . '

: I. ....:, : . - - ^ - ; . ' I ' , · ' . / / : - : ' : ' ^ 4 Li: Now ':: .; ':.: .. : ; : ;'- ' '. · /-; ' "·, -. ^ ;,· ; ;-.,.; ·. ·.'. - "';" .: / -V '- ' *'' : ; : ; . . . change, preferably from about 25 to about 60 degrees. The concentration of the additive used is .;;.; - ;:: -.;; :' ;:-; \^ ' . . . V : · : : ; ; ; ; ; : - : ; ; ; ; ; The process conditions (for example, the activation/exposure time and the amount of energy used to adjust the contact angle to a more defined value within the above range (1 -; . : ., :, for example, about 28 degrees, about 3 5 degrees, etc. The descriptions are merely illustrative of the embodiments of the invention. For those skilled in the art, the aforementioned devices _'..; The improvement of the method is obvious. For example, it can be changed in the black moment P composition * pigment dispersant, initiator, polymer monomer, dry resin and/or solvent concentration. Similarly, in some implementations In an example, a black matrix can be directly formed on a thin transistor (TFT) layer of a flat panel display. For example, the present invention is also applied to a process of spacer formation, polarizer coating, and nanoparticle circuit formation. The embodiments have been presented to illustrate the invention, but other embodiments may fall within the spirit and scope of the invention as follows. [Description of the scope of the patent application] [Simplified description of the drawings] ...., ... Figure 1 is a flow chart showing an example of the method according to some aspects of the present invention, the second BRIEF DESCRIPTION OF THE DRAWINGS FIG. 3 is a schematic enlarged cross-sectional view showing a portion of a substrate coated with a black matrix component according to some aspects of the present invention; a film which can be modified and exemplified can be processed. 19 200815799 FIG. 3 is a view of some aspects according to the present invention, Covered and covered with Λ..· '1 part of the substrate of the black matrix component, which is exposed to the energy: quantity: put the meaning of the figure. - V: . Figure 4 is some according to the invention State of the art;; ': ·' . ^ '; ·; ν ·; ^: ι. The enlarged cross section is not intended, and Fig. 5 is a view of the top surface of the ink absorbing surface according to some aspects of the present invention. - . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Figure 6 is a schematic enlarged cross-sectional view of a portion of a black matrix halogen well filled with ink in accordance with some aspects of the present invention; - - : Figure 7 is a view of some aspects of the invention in accordance with the present invention. An enlarged schematic view of a polar portion and a non-polar portion of a non-polar portion of a polymerizable additive molecule; Figure 8 is an enlarged schematic view of a polymerizable additive molecule in a black matrix component prior to application of activation energy, in accordance with some aspects of the present invention; - Figure 9 is an enlarged schematic view of a polymerizable additive molecule in a black matrix component after application of activation energy in accordance with some aspects of the present invention; Figure 10 is a view of some aspects of the present invention, a structural formula of a wetting additive having a non-polar tail; - Figure 11 is a structural formula of a wetting additive having a non-polar body portion according to some aspects of the invention; Figure 12 is a structural formula of a ruthenium polymer wetting additive in accordance with some aspects of the present invention. 20 200815799 [Main component symbol description 101 method 105 step 107 step 109 step 111 step 2 01 substrate 203 layer 205 black moment bee component 301 mask 3 03 energy 3 05 partial layer 3 07 partial layer 401 well 403 black matrix 501 energy 503 top Surface 5 05 ink-repellent layer 5 07 sidewall surface ο 7 end-end water one or two Xiao Mo points first 200815799 1 . . ..; .V ': / ;' V - . 901 to 1000 molecules 1002 non-polar tail Part 1004 polar part... 1006 polymerized part: 1100 wetting additive molecule... - 1200 wetting additive molecule

Claims (1)

200815799 .... .. ' . .i . . ::.., . : ' :' : , ... ' ' . ' Two:.: - ' · ,..-.w. .. - /"·:.:·'- ... ': \ 二:丨' ..- .-.. * ' . . . . . . - .. . .. - .:: ...... 1 · A color filter used to form a flat panel display. • • • • .... - ... · .... · -. ' An additive σ agent, the additive comprises a polymerizable molecule, and - J . . . . . . . J · Molecular molecule comprises a polar portion and a non-polar portion, wherein the non-polarity has ink repellency. 2/ The black matrix component as described in claim 1 of the patent scope ..., . . . V When the surface of the black matrix component is exposed to activation energy, the polymerizable non-polar portion migrates toward the surface. 3. The black matrix component of claim 1, wherein the polar portion of the polymerizable molecule is linear with respect to the non-polar moiety. 4. The black matrix component additive according to claim 1, comprising at least one of the following: a fluoropropionate monoester oligomer, a mercapto group-containing acrylate monomer, and a mercapto group-containing low Polymer, hydrophobic group-containing acrylic acid vinegar monomer, hydrophobic group-containing oligomer, reactive wax, and fluorodecane. 5. The matrix of the black matrix component I according to claim 1 of the patent application, wherein each of the polymerizable portions has a glycerin, wherein the fluoropropionate acrylate is acrylated. , including 23 200815799 .— -. - ; - r . . ...... - -;' - .. ' :: . . V:. -... . . - - _ ' J ' L .. . - ., --.- ......I I. . - V . , . . -I _ I'.人.:. - : .:. .,:. ... - .: .... ... at least one of the following: ”::v ^ - : -; ; ' -v ,. ^ -- . ' ;'; :- - - ·. : pigment dispersion to start a starter; - : - i : _ _ " - - _ a polymerizable monomer or oligomer; :- V:- -.. ; - · _ ' - : a binder resin; and ... - - . -. 丨.. .. ...-. · . . ' - . . A solvent. 6. The black matrix component of claim 1, wherein the circle: .* - - - .- . * - - the black matrix component comprises an additive, and the black matrix component does not include any, ' ' . : ' " - - . - .. , . : - _ . -. - ' ·· , . . - . · . . . In the case of solvent, the concentration of the added force is the shame The color matrix component is the weight of the turtle. - , ' . ' · · ·. . - . · The amount is about 100 ppm to about 10,000 ppm. 7. The black matrix component of claim 1, wherein the molecular weight of the additive is from about 1 〇〇 Mw to about 1 000,000 Mw weight average. " · · · · - · · - * Within the molecular weight range. . . . ; . . . , ' : ' . : ; · ..' • ': . . : - · . ·. ' ' 1 . . - ' - - ' .. - : . . -' ' . - '8' - a coated substrate for forming a color filter of a flat panel display, comprising: ....----. . . . . : a substrate; and - ..' - . . - : a black matrix component layer formed on the substrate, wherein the black matrix component comprises a polymerizable molecule, each of the polymerizable molecules including a polar portion 24 '. * -- - ; , , -/. ^ .. .. ... . Λν; ;'; . .,: ;, ; . ;- :;-;,':. ..- - : ;:·-;·',·;;·· ::ν - ·;ν '; - ':.:'::·:-^ ,:: ;. .: , .; ., - .·. '.: ':: ••'v - - - " : ' ' ;, -..:_ ',": ' · . ".: ' :, , ' . .. '..· ,. '"'·· -· . · - - · _ ' . ' : / ·. · : - ^ - - . - - * - ^ ' . . -,-; ,;; : - - ' ' :; .- :.';. ...; ^ and the non-polar part, which: the non-polar part of the talk has a wide range of ink-repellent.. - Λ. -., . . ' - ' .; '.' ..... .. ' :'; :;-. -. .....,',*,_ . .:. . ·. : ... " - . , :/ .V·- : ' -:' : : ': ^ : - .- ..... . . - In the non-polar 9 of the coated substrate as described in claim 8 of the patent application, -.; :' .Λ . ; .. When the surface of the black matrix component is exposed to the activation energy, the polymerizable component ... -1 . . . . The sexual portion migrates toward the surface. 10. The coated substrate of claim 8, wherein the polar portion of the polymerizable molecule is linear with respect to the non-polar portion. . . . " .'.... .' / . - - : , , -• . . . - _ . . ' "· : 11· The coated substrate as described in claim 8 is polymerizable. The molecule includes at least one of the following: a fluoroacrylate acrylate acrylate oligomer, a thiol-containing acrylate monomer, a phthalic acid-containing vinegar oligomer, a hydrophobic group-containing propylene vinegar monomer, ... · ; / - ;-. _ Acid S is an oligomer, active soil, and fluorite. 12. The coated substrate according to item 8 of the patent application. . . . . . . . * The black matrix component further comprises at least one of the following: a pigment dispersant a starter; a polymerized monomer or oligomer; wherein the propylene having the ink, the fluorine, and the propylene, wherein the 25 200815799 one: the binder resin r and: 丨- · ' ':: ..·ϊ ·:·:·· "' - .一::溶'剂: ;. _ · . ' * ·, -.- : • ' _ · · · ·· · ' - · · · · .-. -, - ;.- :-ν-:ΛΛ, - . - ' . . . : · · · · · · · · · ························································· In the case of any falling agent, the total weight of the bismuth component is about 1 00 ppm to about]. ' -:·' ' : , :. · ·: ' . - · ', : ; ' .... . . . The coated substrate of claim 8, wherein the polymerizable molecule has a molecular weight in the range of from about 100 Mw to about 100,000 Mw weight average molecular weight. 5. A method of forming a color filter for a flat panel display, comprising: forming a black matrix component comprising a polymerizable molecule, each polymerizable molecule comprising a polar portion and a non-polar portion, wherein the non-polar portion has an ink repellency Sex; .. ί : .;- . ' :- ... ...... ' Provide a substrate; ... ' ............. :· . . . ^ - V _ a layer forming the black matrix component per Qin plate; and applying activation energy to the black matrix component on the substrate. 26 ..·.:·.; .. ...:-: . -, · : :·'^:^-·:.·.-.:.-:.. ' ^- ' '..』 :..:'·..... .... : ' ..., : .. - . .... - ...... - *- ; -: . ' . r. * * ' . -. - ' -. ... . - - ...-,.. • ' ' . .- .: .. . :--i' . ..-:: ' ——.:.. ..: .' . ' -'V: - · ' . . , '. ' ' ' .-.. -· . ' -: ' ·, :- . - . . ' ..... - - - ^ \ : - -. .〆-. 1 6. The method described in Article 15 of the patent application -, -.::. wide---... : - ;.--.;.: _· - .;.' : The matrix component further includes forming a black matrix component, and the portion of the polymerizable molecule in the black matrix component moves toward the surface of the black matrix component when the activation energy is applied thereto. . -' . - / ' - - : ..-- - ... ' .- . - . .__ .'.- V.':..':. :, · -. .... .. ..-. - ..... - . ··· 17· The method described in claim 15 of the patent application v. '...' 'The matrix component further includes forming a black matrix component, and the recruitment · . . . . . . . 1 The polar part of the polymerizable molecule, relative to the non-polar part: ... ...... _.. ν'::. .... 'Sex': 18. The method of claim 15, wherein the matrix component further comprises forming a black matrix component, and the black matrix polymerizable molecule comprises at least one of the following: a fluoroacrylic acid propionate oligomer, A mercapto group-containing acrylate monomer, an acid ester-containing oligomer, a hydrophobic group-containing propionate monomer, an acid-containing vinegar oligomer, a reactive wax, and a gas sulfoxide. 19. The method of claim 15, wherein the matrix component further comprises forming a black matrix component, and the black matrix..... :\ .... ... ' .... At least one of: - a pigment dispersant; an initiator; wherein the non-polar portion of the black matrix component is formed, wherein the fraction forming the black matrix component has an ink-repellent aceton monomer in which a black matrix component is formed, and fluorite The basis of the B-whole water-based B-women in which the black matrix component is formed. 27 200815799 • .....:.ν' .. ' . . - .- . ' .. - - -.'...: Two:.;' ........; a polymerized monomer or oligomer; a binder resin; and a solvent. ::. _ . - - Factory........- ---- ' . / ·. . ; Λ,··/: ;: ,;:;.; '/ J:. ;;; : '. .' . , -. - ; ' . - : ;' - : ";;.;,. 2 0. For example, the method described in the patent specification, item 15, which forms the black matrix component Further including forming a black matrix component, and in the case where the black matrix component does not include any solvent, the iT degree of the polymerizable molecule is the black The total weight of the matrix component is about 1 〇 〇 P P m to about 1 0,0 0 0 p pm. 21. The method of claim 15, wherein forming the black matrix component further comprises forming a black matrix component, and wherein the molecular weight of the polymerizable molecule in the black matrix component is between about 1000 Mw to about 10 0,0 0 0 MW weight average molecular weight range. The method of claim 15, wherein applying the activation energy to the black matrix component comprises applying an electron beam to the black matrix component. 23. The method of claim 15 further includes A matrix in the black matrix component is patterned. 28 200815799 24. The method of claim 23, wherein applying the activation energy to the matrix component comprises polymerizing the black matrix component such that the top surface of the matrix has ink repellency and the side surface of the matrix has ink receptivity. 29