TW208715B - Liquid detergent composition - Google Patents
Liquid detergent composition Download PDFInfo
- Publication number
- TW208715B TW208715B TW81107806A TW81107806A TW208715B TW 208715 B TW208715 B TW 208715B TW 81107806 A TW81107806 A TW 81107806A TW 81107806 A TW81107806 A TW 81107806A TW 208715 B TW208715 B TW 208715B
- Authority
- TW
- Taiwan
- Prior art keywords
- page
- ministry
- viscosity
- cns
- detergent composition
- Prior art date
Links
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
Afi B(i 2〇sn〇 五、發明説明(》) (諳先閲-背面之注念事項再場寫本頁) 本發明乃有關新潁清潔劑組成物,詳而言之,有關廚 房用之經濟清潔劑組成物,施於泡綿上時,會保留在泡 綿表面,而不會迅速滲入,如此可避免過量使用,由其 白濁的外觀,用目視可知擠出量。 洗盤子用之清潔劑通常是在洗物槽或提桶中泡成稀溶 液,在其内洗餐具,或在泡綿上直接沾上未稀釋之清潔 劑,擦洗餐具。其中,後一方法較常用。 大部分洗盤子用的清潔劑均有一缺點就是因為其外觀 透明,所以不容易目測得知自容器中之擠出體積。 另方面,有某些洗盤子用之清潔劑呈乳白色。此等清 潔劑之粘度通常是調成較低,以便容易擠出來。但因清 潔劑會立即滲入泡綿中,則清潔劑沾在泡綿上時,就不 易察凳擠出量。 . 如前述由於傳統的液態清潔劑不易察覺擠出量,故不 易控制使用量。如此往往導致清潔劑的過量使用,非但 不經濟,而且有時會引起手部龜裂。 因此本發明之目的乃提供液態清潔劑組成物,其擠出 量可容易用目測,故能恆定的控制使用量》 經濟部中央標準局S工消費合作社印製 有鑑於此種形勢,本案發明者進行廣泛的探討,研究 液態清潔劑的外觀及自容器中擠出之性質。結果,本案 發明者發現一種乳白的清潔劑,均能定量地自容器中擠 出,而且不會迅速滲入泡綿中,故容易目測擠出量,而 且也容易自容器中擠出.其待擻是添加’'珠白劑" 8L9.20,000 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297 釐) 經濟部中央標準局S工消費合作社印製 五、發明説明(> ) ([)e a r 1 e s c e n t . a g e n t ),而且不僅控制組成物之粘度, 也控制其"布魯克菲漶塑變值”(B r ο 〇 k f i e 1 d y i e 1 d v a 1 u e )於某一範圍内。此等發現完成本發明之目的e 因此,本發明之目的乃提供液態清潔劑組成物,外觀 不透明,在2 (TC之粘度為2 0 Q - 4 , (3 0 0厘治,而且布魯克 菲爾德塑變值為5 - 1 Q 0泊,其特徽為包含(A )界面活性劑 ,(B )珠白劑,(C )粘度調整劑。 在較佳的體条中,本發明之體条包含(A) 1-40%重量 的界面活性劑,(B ) 0 . 5 - 2 0 %重量的珠白劑及(C ) 0 · 1 - 1 0 %重量的粘度改質劑,其中B / A比值為0 . 0 5 - 1。 由以下的說明更能明白本發明的目的,優點及好處。 用於本發明之界面活性劑(A )並無特殊的限制β任何 陰離子,非離子或兩性離子性之界面活性劑均可使用。 較佳的陰離子界面活性劑有多(平均為1至7莫耳) 氣乙if Ci - 7烷基或C8 - os烯基醚硫酸酯,直鍵 C8 - is烷基或烯基苯磺酸酯,Cs - 〇sa-磺基脂肪酸 鹽,磺酸C8 — iaa-烯烴酯,磺酸C8 _ 18烷酯,硫酸 C8 - is烷酯或烯酯,磷酸C8 — a單烷酯或烯酯等。亦 可為鹼金屬,鹼土金靥,銨鹽,烷醇胺鹽等之鹽。 在此等陰離子界面活性劑中,待佳為式I所代表的多 氣乙撐烷基或烯基醚硫酸酯I : R 1 0 ( C Η 2 C Η 2 0 ) S 0 3 Μ (工) A6 ΒΓ) (請先閲-背面之注念事項#塡寫本頁) i裝· 訂· 本紙張尺Λ適用中國國家標準(CNS)甲4現格(210 X四7公釐) 81.9.20.000 ΰ ο ri 3Afi B (i 2〇sn〇 V. Description of the invention (") (know first-read the notes on the back and then write this page) This invention is about the composition of the new Ying detergent, in detail, it is related to kitchen use The economical detergent composition, when applied to the foam, will remain on the surface of the foam without rapid penetration, so that excessive use can be avoided, and its turbid appearance can be visually known to squeeze out the amount. For washing dishes The detergent is usually made into a dilute solution in the washing tank or bucket, and the dishes are washed in it, or the undiluted detergent is directly dipped on the foam to scrub the dishes. Among them, the latter method is more commonly used. Most One disadvantage of detergents used for washing dishes is that because of their transparent appearance, it is not easy to visually know the extruded volume from the container. On the other hand, some detergents used for washing dishes are milky white. The viscosity of these detergents It is usually adjusted to a low level so that it can be easily squeezed out. However, because the cleaning agent will immediately penetrate into the foam, it is difficult to detect the amount of stool squeezed when the cleaning agent is on the foam. As mentioned above, due to the traditional liquid detergent Not easy to detect the amount of extrusion, so no Easy to control the amount of use. This often leads to excessive use of cleaning agents, which is not only uneconomical, but also sometimes causes hand cracks. Therefore, the purpose of the present invention is to provide a liquid cleaning agent composition whose extrusion amount can be easily visually observed, Therefore, it is possible to control the consumption constantly. Printed by S Industry and Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. In view of this situation, the inventors of this case conducted extensive discussions to study the appearance of liquid detergents and the nature of extrusion from containers. As a result, The inventor of the present case discovered that a milky white cleaning agent can be squeezed out of the container quantitatively, and does not quickly penetrate into the foam, so it is easy to visually squeeze out the amount, and it is also easy to squeeze out of the container. '' Pearl White Agent " 8L9.20,000 This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 centimeters). Printed by the Central Bureau of Standards of the Ministry of Economy, Industry and Consumer Cooperatives V. Invention Instructions (>) ([ ) ear 1 escent. agent), and not only control the viscosity of the composition, but also control its " Brookfield ’s plastic deformation value (B r ο 〇kfie 1 dyie 1 dva 1 ue) Yumou These discoveries accomplish the object of the present invention. Therefore, the object of the present invention is to provide a liquid detergent composition with an opaque appearance and a viscosity of 2 (TC with a viscosity of 2 0 Q-4, (3 0 0 Centigrade, and Brookfield plasticity value is 5-1 Q 0 poise, and its special emblem is containing (A) surfactant, (B) beading agent, (C) viscosity modifier. In the preferred body strip, the invention The body strip contains (A) 1-40% by weight of surfactant, (B) 0.5-20% by weight of pearlescent agent and (C) 0 · 1-10% by weight of viscosity modifier, where The B / A ratio is 0. 0 5-1. The purpose, advantages and benefits of the present invention can be more clearly understood from the following description. The surfactant (A) used in the present invention is not particularly limited. Any anionic, nonionic or zwitterionic surfactants can be used. There are many preferred anionic surfactants (average 1 to 7 moles), gas if Ci-7 alkyl or C8-os alkenyl ether sulfate, straight bond C8-is alkyl or alkenyl benzene sulfonate , Cs-〇sa-sulfo fatty acid salt, sulfonic acid C8-iaa-olefin ester, sulfonic acid C8_18 alkyl ester, C8-is alkyl or alkenyl sulfate, C8-a monoalkyl or alkenyl phosphate, etc. It can also be alkali metal, alkaline earth gold, ammonium salt, alkanolamine salt, etc. Among these anionic surfactants, to be preferred is the polygaseous ethylene or alkenyl ether sulfate represented by Formula I: R 1 0 (C Η 2 C Η 2 0) S 0 3 Μ (工) A6 ΒΓ) (please read first-the note on the back # 塡 write this page) i install · order · this paper size Λ is applicable to the Chinese National Standard (CNS) A 4 current grid (210 X 4.7 mm) 81.9.20.000 ΰ ο ri 3
A B /IV 明説 明發 ,五 R. 偽 中 β 式之 傜 至 數 〇 耳胺 莫醇 均烷 平或 之銨 入 , 加颶 表金 代土 ,鹼 基 , 烯靥 或金 基鹼 烷係 1SΜ 中十 , I ,基 式基烷 面癸五 前,十 在.«, 壬基 基 辛 有 例 體 具 之 基 烷 的 表 代 所 烷烯 四 ; 十等 ,基 基烷 烷八 三十 十 , ,基 基烷 烷七 二十 十 -,基 基烷 烷六 ,基 基烯 烯五 癸十 , , 基基 烯烯 壬四 。 ,十等 基,基 烯基烯 辛烯八 指三十 基十 , ,基 基烯 烯六 ,基 基烯 烯七 (請先閱讀背面之法念事項再塡寫本頁) 有 劑 性 活 面 界 子 i 離 tr TPK 的- 8 佳 C 較撐 烷 多 數 耳 莫 均 平 氧 醚 基 烯 或 基 烷 as 多 數 耳 莫 均 平 氣 撐 8 C 乙 撐氧 烷}AB / IV specification, five R. Pseudo-β-formula to several tens of ammonium melamine are all alkane level or ammonium into, plus chrysanthemum, alkaloids, enil or alkynyl alkane series 1SΜ In the ten, I, the basic alkane surface before dec five, ten in. «, Nonyl octyl has a representative body of the alkyl alkane four alkylene four; tenth, the alkyl alkane eighty thirty, , Yl-alkyl alkane seventy to twenty-, yl-alkyl alkane six, alkyl alkene pentadecyl,, alkyl alkene four. , Tenth-grade, alkenylalkenyl octene, eighty-thirty, tenyl, ylalkenyl six, ylalkenyl seven (please read the legal matters on the back before writing this page).界 子 i away from tr TPK-8 best C than most alkylene molybdenum oxide ether alkene or alkane as most of the gas molybdenum gaseous support 8 C ethylene oxide}
多 醚 苯 基 烯 或 基 烷 1S 醚 基 烯 或 多多 數 耳 莫 均 平 數 耳 莫 均 平 3 基 3-烷 為18 數 -耳 8 莫" 均 平 撐 丙 氧 酐 醇 糖 梨 山 撐 烷 氣 數 耳 莫 均 平 /fv 多 酯 酸 肪 脂 18 醇 糖 梨 山 .裝_ 訂.Polyether phenylene or alkane 1S ether alkene or a majority of the number of moles of the number of moles of the number of three-alkane 3-alkane is 18 number-ears of 8 moles " even propylene oxide anhydride sugar sorbitane Qi Shuer Mo Junping / fv Polyester Fatty Acid 18 Alcohol Sugar Lishan. Binding_ Order.
酯 酸 肪 脂 1S 酸含 肪是 脂如 as例 - 劑 8 性 C活 ’面 界 之 子 性 兩 等 胺 醯 醇 烷 基 烯 或 基 烷 18 氧 化 胺 叔 之 含 0 菜 甜 -羰- 3 之 C 基含 烯 , 或險 基菜 烷甜 18磺 - 之 8 基 r J 烯 或 基 烷 18 含Ester fatty acid 1S The fatty acid is a fat, such as as an example-agent 8 sex C active 'sub-level second-class amine acetyl alcohol alkylene or alkane 18 amine oxide tertiary containing 0 Cetyl-carbonyl-3 C The base contains alkene, or alkanoyl sweet 18 sulfonium-the 8 base r J alkene or alkane 18 contains
基 烯 或 基 烷 1S 合 化 為 佳 恃 中 劑 性 活 面 界 子 隹 雜 性 兩 〇 或 等子 鹼離 菜非 甜等 銼此 咪在 之 經濟部中央標準局®:工消費合作社印製 物Alkene or alkane 1S is combined into a good Chinese medicinal agent. The active surface boundary is as low as 20% or the isotope alkali is off the dish. It is not sweet, etc. File this Mi Central Economic Bureau of the Ministry of Economy®: Printed by Industrial and Consumer Cooperatives
X 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 81.9.20.000X The size of this paper is in accordance with Chinese National Standard (CNS) Grade A (210 X 297 mm) 81.9.20.000
ObU^) Λ6 B6 五、發明説明(今)ObU ^) Λ6 B6 V. Description of the invention (present)
R 3 R1-(OR2 jm—N-»> O R4R 3 R1- (OR2 jm—N-»> O R4
Rl_〇_(-CH2CH2〇-)n-HRl_〇 _ (-CH2CH2〇-) n-H
RR
R l_〇_(-CH2CHO-)p-(-CH2CH2〇-)q-H ch3 1_0_(-CH2CH2〇-)r-(-CH2CHO-)g-H CH〇R l_〇 _ (-CH2CHO-) p-(-CH2CH2〇-) q-H ch3 1_0 _ (-CH2CH2〇-) r-(-CH2CHO-) g-H CH〇
5 R5 R
Ν I CIOΝ I CIO
R6 Z R1-N+-CH2CHCH2S〇3* R7 r1-n+-ch2co〇· 經濟部中央標準局WJC.消費合作社印製R6 Z R1-N + -CH2CHCH2S〇3 * R7 r1-n + -ch2co〇 Printed by WJC. Consumer Cooperative
°+7 RINIR - 2 Η C 2 Η c2 Ηc Η Ν-c — o- 5 R ch2coo (II)(III) (IV)(V) (VI) (VII) (VIII) (IX) (諳先閲‘;\!背面之;±*.事項再塡寫本頁) .裝. 訂° + 7 RINIR-2 Η C 2 Η c2 Ηc Η Ν-c — o- 5 R ch2coo (II) (III) (IV) (V) (VI) (VII) (VIII) (IX) (訙 先 读'; \! On the back; ± *. Matters will be written on this page). Pack. Order
本紙張尺度適用中.國國家標準(CNS)甲4規格(210 X 297 X釐) 81.9.20,000 五、發明説明(f )This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 X PCT) 81.9.20,000 V. Description of the invention (f)
R5-C / -ch2 .-ch2R5-C / -ch2 .-ch2
Α6 BGΑ6 BG
X 經濟部中央標準局we工消費合作社印製 ch2ch2oh cH2cocr 式中R1偽C8 - is烷基或烯基; R 2傜c 2 - 3烷撐; R3及R4傺相同或不同Ci - 3烷基,或- (R2〇)A Η ,其中Jl為1至7 ,R2如前述; R 5傜C 7 - 17烷基或烯基; R6及R7相同或不同,偽甲基或乙基; X傷C. 1 - 3院醇基; Y ^ C 1 - 3烷醇基或氫原子; Z係羥基或氫原子; m係0至30,代表加入之平均莫耳數; η係3至20,代表加入之平均莫耳數; Ρ及s各傜1至20,代表加入之平均莫耳數; q及r各偽3至30,代表加入之平均莫耳數。 在本發明之液態清潔劑組成物中,界面活性劑之用量 為1 - 4 0 % ,較佳為1 〇 - 4 Q %,最好是1 5 - 3 5 °/。重量,可單 獨使用,或以兩種或以上混合使用。若加入量少於1 % ,則組成物沒有基本的清潔功能及起泡能力。另方面, 7 - 本紙張尺茂適用中國國家棵準(CNS)甲4規格(210 X 297公釐) 81.9.20,000 (請先閲讀背面之'注念事項再塡寫本頁) 裝. 訂. ς〇8:η〇 Α6 ΒΓ> 五、發明説明() 為損 因受 ,性 佳定 不安 亦的 ,液 % 溶 ο 、―' 4 2 於 , 大大 量增 用幅 若大 會 度 粘 之 劑 潔 青 •Vi 態 液 組為 明佳 發較 本量 為入 劑加 性之 活中 面物 界成 子組 離在 陰 , ,分 中成 劑性 性活 活潔 面清 界要 等主 此之 在物 成 為足 佳不 尤能 ..功 量泡 重起 %及 30潔 5-清 量 fl S % 量 S % ο 3 於 大 量 用 若 則 , ,好 % 不 5 亦 於' 少’ 量 用 若 出 擠 中 器 容 自 易 不 成 造 高 提 Φ 大 〇 會損 度受 粘性 之定 物安 成的 組液 為溶 因或 子活 離的 陰虜 用皮 配對 劑和 性緩 活 , 面力 ΘΓ 老 子潔 離清 性污 兩油 及強 子加 非則 若 , ,劑 面性 方活 另面 界 性佔 兩量 及用 子 , 離用 非使 等合 此混 。上 糙以 粗或 虜種 皮兩 或或 裂獨 龜單 部可 手劑 免性 避活 是面 於界 ,子 性離 2 於 為大 佳量 尤用 ,若 70, 10足 1-不 的果 量效 重則 物 , 成量 Rn Umil 绍 S 部% 全 1 於 少 量 用 若 % 欲 所 非 亦 量 S S % 於 液 化 溶U為 : *ϊ 製 .1: I 損 佳 X 有Μ較 物 為 或)?, 合 Β - J ,{ 之 化 加劑言 之 增白而 上 幅珠詳 以 大之。 或 度物物 Ρ 粘成合 3 之組化 為 物明性。點 成發溶III熔 Μ本不Β-Ι) 為於水及-Ι 因用之 Π(Β ) 上 Β 性 定 安 的 以 或 °c 物 合 (請先閱讀背面之;;!*事項#-塡寫本頁) —裝. 訂. 經濟部中央標準局w工消費合作社印製 物 合 , 〇 化 基數之 烯整上 或之以 基卩或 烷至 P 231 3 - 偽為 15t 點 fee, 偽 ) 子 5 Π R 原 I 中氫(B 式或X printed by ch2ch2oh cH2cocr of the Central Standards Bureau of the Ministry of Economic Affairs and Wealth Consumer Cooperatives where R1 pseudo C8-is alkyl or alkenyl; R 2 傜 c 2-3 alkylene; R3 and R4 傺 are the same or different Ci-3 alkyl, Or-(R2〇) A Η, wherein J1 is 1 to 7, R2 is as described above; R 5 傜 C 7-17 alkyl or alkenyl; R6 and R7 are the same or different, pseudo-methyl or ethyl; X hurt C . 1-3 house alcohol group; Y ^ C 1-3 alkanol group or hydrogen atom; Z is a hydroxyl group or hydrogen atom; m is 0 to 30, representing the average number of moles added; η is 3 to 20, representing the addition The average number of moles; P and s are each 1 to 20, representing the average number of moles added; q and r are each pseudo 3 to 30, representing the average number of moles added. In the liquid detergent composition of the present invention, the amount of the surfactant is 1-40%, preferably 10-4Q%, and most preferably 15-35 ° /. The weight can be used alone or in combination of two or more. If the added amount is less than 1%, the composition has no basic cleaning function and foaming ability. On the other hand, 7-This paper ruler is suitable for China National Standard (CNS) Grade 4 (210 X 297 mm) 81.9.20,000 (please read the "Notes on the back before writing this page"). Order. ς〇8: η〇Α6 ΒΓ > Fifth, the description of the invention () is a cause of damage, good quality and uneasy, liquid dissolves ο, ― '4 2 Yu, a large increase in the use of a wide range of sticky agent clean The Qing • Vi state liquid group is Mingjiafa. The sub-group of the active middle-faced material world, which is additive to the dosage, is separated from the yin. Jia Bu Youneng .. Energy bubble recovery% and 30 Jie 5-clear volume fl S% 量 S% ο 3 For a large amount of use, then, good% not 5 is also used in the "less" amount if out of the squeeze Rong Ziyi can't make a high Φ. Large group will damage the viscous fixed substance. The group liquid is a dermal agent for the cause of dissolution or detachment. The skin matching agent and sexual slowness are used. Facial force ΘΓ Lao Zijie separation If the two oils and the hadrons are added to the non-negative, then the surface area and the surface area account for two quantities and their use, This mixed together with a non-enabled and the like. Coarse or thicker coats or two or split solitary tortoises can be used as a hand-free agent to avoid sex. It is suitable for a large amount of fruit, if the fruit is 70, 10 feet 1-no fruit. The effective weight is the amount, the amount of Rn Umil is S% of the whole part 1 is used in a small amount. If the% is what you want to do SS% in the liquefied solution U is: * ϊ system. 1: I is good. X is better than or is it?) , 合 Β-J , {The color of the chemical additives is brightened and the size of the beads is larger. Or the degree of object Ρ stick to the combination of 3 into physical properties. Dianchengfalian III melting Μ 本 不 B-I) is a combination of B-type stability and ° C on the Π (Β) used in water and -Ι (please read the back side first ;;! * 事 #- (Write this page) — installed. Ordered. Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and Industry and Consumer Cooperatives, olefins with a base of 0 or P to 231 3-Pseudo 15t point fee, pseudo ) Sub 5 Π R Original I Hydrogen (Formula B or
A 16 基 0 族 脂 本紙張尺度適用中國國家標準(CNS)甲4規恪(210 X 297公货〉 81.9.20,000 五、發明説明(7)A 16 base 0 family fat This paper scale is applicable to China National Standard (CNS) A 4 regulations (210 X 297 public goods) 81.9.20,000 V. Description of invention (7)
/B A6 ΒΓ, R5-C-N;II 0/ B A6 ΒΓ, R5-C-N; II 0
XII Ή 經濟部中央標準局8工消費合作社印製 式中 Β 傺-CH2 CH2 OH, -CH2 CH(CH3 )0H或 -CH2 ch2 CH2 〇H,而 R5 如前述。 (B - III )衍生自含羥基之化合物:甘油,多甘油(縮合 度2-10),山梨糖醇,季戊四醇,葡萄糖,果糖,麥芽 糖或蔗糖和C 16 - 24長鏈飽和脂族酸之部分酯,熔點為 3 0°C或以上。 (B - I )之例子有乙二醇單硬脂酸酯,乙二醇二硬脂酸 酯,二甘醇二硬脂酸酯等。(B - II)之例子有硬脂酸單乙 醇醯胺,山¥酸單乙醇醯胺,氫化牛脂脂肪酸單乙醇醯 胺,氫化棕櫚油脂肪單乙醇醯胺等。較佳的(B - ΠΙ )例如 甘油和長鐽脂肪酸之部分酯,持佳為脂肪酸殘基具 C π - 24 ,及含7 5 %或以上之甘油單酸酯者。此種脂肪 酸甘油酯包含甘油和長鏈脂肪酸,如硬脂酸,山¥酸, 氫化豬油脂肪酸,氫化菜子油脂肪酸,氫化棕櫊油脂肪 酸等之酯。 雖然組成物中珠白劑(Β )之摻入量無特殊限制,但必 須能使清潔劑組成物變成不透明(白濁),而且可控制 組成物之拈度及布魯克菲爾德塑變值於前述之範圍内; 較佳為0 . 5至2 0 % ,最好是I - 1 0 %重量。若珠白劑用量 (請先閱讀背面之注意事項再塡寫本頁) —裝. 訂· 本紙張又度適用中國國家標準(CNS)甲4規格(210 X的7父釐) 81.9.20,000 經濟部中央標準局員工消費合作社印製 2〇δ:Πί> Α6 ___m_ 五、發明説明(Η ) 低於0 . 5 %重量,則不透明度不夠,若大於2 ϋ %重量則 會使溶液安定性劣化,亦不利。 此等珠白劑(Β )可各別使用或混合兩種或以上使用β 若(Β - I )或(Β - II )配用(Β - III ),則可改善珠白劑的分散 安定性,使得珠.白劑能維持均勻的分散狀態,長期後亦 不會分離或沉澱。為獲致改良之分善性,珠白劑(B-I ) 或(B - II ) / Β - III之比值較佳為在0 · 1 - 1 . 0之範圍内。調 配此等清潔劑組成物時,可配用不同種類的珠白劑,成 分Β-I或Β - II之用量較佳為佔全組成物之0.5-10 %重量 ,尤佳為1 - 5 %重量,而成分B - IH之用量為1 - 2 Q %重量 ,尤佳為3 - 1 0 %重量。 本發明之液態清潔劑組成物之外觀必須是不透明的。 所欲之不透明是在2Q°C之料溫,光線距離1厘米,420 X 10 — 9米波長之可見光之透光率小於1%。 本發明液態清潔劑組成物之粘度必須是2 0 0 - 4,Q G 0厘 泊(2 0 °C料溫),布魯克菲爾德塑變值為5 - 1 0 0泊。較 佳之粘度為2 0 0 - 1 , 0 0 0厘泊,較佳之布魯克菲爾德塑變 值為5 - 5 0泊》若粘度及布魯克菲爾德塑變值太低,則 清潔劑擠在泡綿上時會迅速被吸入,則擠出體積無法目 測察覺。若粘度及布魯克菲雨德塑變值太高,則因不易 自容器中擠出清潔劑也非所欲。 為獲致適當的粘度及布魯克菲爾德塑變值,成分(B ) 對成(A )之比值[(B ) / ( Λ ) j較佳為0 . 0 5 - 1。 -1 I)- (請先閱^背面之';±-念事項*'塡寫本頁) -裝. 訂. .線( 本紙張尺度適用中國國家棵準(CNS)甲4規格(210 X 297公穿) 81.9.20,000 經濟部中央標準局8工消費合作社印製 ΑΓ) ___Bfi_ 五、發明説明(9 ) 用於本發明之粘度調節劑(C )包含粘度增加劑,如部 分架橋之聚丙烯酸,羥乙基纖維素,羧甲基纖維素,阽 噸膠,蒙脱石,浬滎脱石,皂石,蛭石,綠脱石,鋅滎 脱石,拉帕蒙脱石等;粘度降低劑如乙醇,丙醇,異丙 醇,乙二醇,丙二醇,甘油,多甘油(縮合度2 - 1 0 ), 山梨糖醇,季戊四醇,磺酸苯酯,磺酸(Ci - 4低级 烷)苯酯等。此等粘度調節劑佔本發明液態組成物重量 的0.卜10%,較佳為0.1-8%。 本組成物中除有成分(A), (B)及(C),若添加成分(D) :平均分子量為3Q0至4,000之聚醇和多烷撐氣之加合物 或其鹽,則所得液態清潔劑組成物會有美麗的珠白光澤 或乳白色的外觀,仍保持大量的起泡,均勻的分散,長 久儲存亦不會分離及沉澱。成分(D)例如是聚氧乙撐化 氧或聚丙撐氧對乙二醇或甘油之加合物;其硫酸鹽酯或 磷酸鹽酯。若為鹽,則較佳為鹼金屬鹽,鹼土金屬鹽, 銨鹽,烷醇胺鹽。成分(D)佔全部組成物重量的1-10 % ,較佳為1 - 5 %。 除前述成分外,尚可在本發明組成物中加入其他成分 ,只要不妨害所欲效果即可。此等任意之成分包含例如 香料,染料,顔料,防腐劑,殺®劑,PH調整劑等。 本發明之清潔劑組成物可依常法在室溫或高溫混合及 攪拌前述成分,並調整粘度及布魯克菲雨德塑變值而得 本紙張尺度適用中國國家標準(CNS)甲4规格UU) X 297公釐) 81.9.20,000 ------------------^-----裝 ------,玎------線( (請屯閲"背面之·;±-念事項#塡寫本頁)XII Ή Printed by the Central Standards Bureau of the Ministry of Economic Affairs, the 8th Industrial Consumer Cooperative, where Β 傺 -CH2 CH2 OH, -CH2 CH (CH3) 0H or -CH2 ch2 CH2 〇H, and R5 is as described above. (B-III) Derived from hydroxyl-containing compounds: glycerin, polyglycerol (degree of condensation 2-10), sorbitol, pentaerythritol, glucose, fructose, maltose or sucrose and C 16-24 long-chain saturated aliphatic acids Ester with a melting point of 30 ° C or above. Examples of (B-I) are ethylene glycol monostearate, ethylene glycol distearate, diethylene glycol distearate and the like. Examples of (B-II) are stearic acid monoethanolamide, behenic acid monoethanolamide, hydrogenated tallow fatty acid monoethanolamide, hydrogenated palm oil fatty monoethanolamide and the like. Preferred (B-ΠΙ) are, for example, partial esters of glycerin and long fatty acids, preferably with fatty acid residues having C π-24, and containing 75% or more of monoglycerides. Such fatty acid glycerides include esters of glycerin and long-chain fatty acids such as stearic acid, behenic acid, hydrogenated lard fatty acid, hydrogenated rapeseed oil fatty acid, hydrogenated palm olein fatty acid and the like. Although there is no particular limitation on the blending amount of pearl whitening agent (B) in the composition, it must be able to make the detergent composition opaque (white turbid), and can control the degree of the composition and the Brookfield plastic deformation value in the aforementioned range Within; preferably 0.5 to 20%, most preferably I-10% by weight. If the amount of bead white agent (please read the precautions on the back before writing this page)-Pack. Order · This paper is again applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 7%) 81.9.20,000 Economy Printed by the Employees ’Cooperative of the Central Bureau of Standards of the Ministry 2〇δ: Πί> Α6 ___m_ Fifth, the invention description (Η) is less than 0.5% by weight, the opacity is not enough, if more than 2 ϋ% by weight will deteriorate the stability of the solution , Also unfavorable. These pearlescent agents (B) can be used separately or in combination of two or more. If (Β-I) or (Β-II) is used with (Β-III), the dispersion stability of the pearlescent agent can be improved So that the beads. Whitener can maintain a uniform dispersion state, and will not separate or precipitate after a long time. In order to obtain improved goodness, the ratio of pearlescent agent (B-I) or (B-II) / B-III is preferably in the range of 0.1-1.0. When blending these detergent compositions, different types of pearlescent agents can be used. The amount of component B-I or B-II is preferably 0.5-10% by weight of the total composition, particularly preferably 1-5% Weight, and the amount of component B-IH is 1-2 Q% by weight, particularly preferably 3-10% by weight. The appearance of the liquid detergent composition of the present invention must be opaque. The desired opacity is at a material temperature of 2Q ° C, the light distance is 1 cm, and the transmittance of visible light with a wavelength of 420 X 10-9 meters is less than 1%. The viscosity of the liquid detergent composition of the present invention must be 200-4, Q G 0 centipoise (20 ° C material temperature), Brookfield plastic value is 5-100 poise. The preferred viscosity is 2 0 0-1, 0 0 0 centipoise, and the preferred Brookfield plasticity value is 5-5 0 poise. "If the viscosity and Brookfield plasticity value are too low, the cleaner will squeeze on the foam Will be quickly inhaled, the extrusion volume can not be visually detected. If the viscosity and Brookfield's plasticity value are too high, it is undesirable because it is not easy to squeeze out the detergent from the container. In order to obtain an appropriate viscosity and Brookfield plastic deformation value, the ratio of component (B) to component (A) [(B) / (Λ)) j is preferably from 0.05 to 1. -1 I)-(please read the ^ on the back of the ^; ± -memory matters * 'to write this page) -install. Order. Line (this paper standard applies to China National Standard (CNS) A 4 specifications (210 X 297 public wear) 81.9.20,000 Printed by the Ministry of Economic Affairs, Central Standards Bureau, 8 Industrial and Consumer Cooperatives (AΓ) ___Bfi_ V. Description of the invention (9) The viscosity modifier (C) used in the present invention contains a viscosity-increasing agent, such as partially bridged polyacrylic acid , Hydroxyethyl cellulose, carboxymethyl cellulose, gelatin, montmorillonite, ocherite, saponite, vermiculite, nontronite, zinc montmorillonite, lapata montmorillonite, etc .; viscosity reduction Agents such as ethanol, propanol, isopropanol, ethylene glycol, propylene glycol, glycerin, polyglycerin (degree of condensation 2-10), sorbitol, pentaerythritol, phenyl sulfonate, sulfonic acid (Ci-4 lower alkane) Phenyl esters, etc. These viscosity modifiers account for 0.1 to 10% by weight of the liquid composition of the present invention, preferably 0.1 to 8%. In addition to the components (A), (B) and (C) in this composition, if the component (D) is added: the adduct of polyalcohol and polyalkylene oxide with an average molecular weight of 3Q0 to 4,000 or its salt, the liquid state is obtained The detergent composition will have a beautiful pearly white gloss or milky white appearance, and still maintain a large amount of blistering, evenly dispersed, and will not separate and precipitate after long-term storage. The component (D) is, for example, an adduct of polyoxyethylene oxide or polypropylene oxide to ethylene glycol or glycerin; its sulfate ester or phosphate ester. If it is a salt, it is preferably an alkali metal salt, alkaline earth metal salt, ammonium salt, or alkanolamine salt. Component (D) accounts for 1-10% by weight of the total composition, preferably 1-5%. In addition to the aforementioned components, other components may be added to the composition of the present invention as long as the desired effect is not hindered. These arbitrary ingredients include, for example, perfumes, dyes, pigments, preservatives, biocides, and pH adjusters. The detergent composition of the present invention can be mixed and stirred at room temperature or high temperature according to the usual method, and the viscosity and Brookfield plastic deformation value can be adjusted to obtain the paper size applicable to the Chinese National Standard (CNS) A4 (UU) X 297mm) 81.9.20,000 ------------------ ^ ----- installed ------, 玎 ------ line (( Please read " the back of the; ±-念 事 # 塡 write this page)
Afi B6 cOSVio 五、發明説明(《”) 如此所得之清潔劑組成物適用於廚房及家用品,如洗 餐具,廚房器皿,浴室,地板,牆壁,傢俱,廁所,蔬 菜,水果等。 本發明之清潔劑組成物擠在泡綿上後不會迅速被吸入 ,擠出量容易察覺。容易定量地自容器中擠出,可經濟 地避免過量使用,亦可防止手部龜裂或皮虜粗糙。 Η以非限制本發明範圍之實施例説明本發明,其他特 色亦可得悉》 甯旆例: 實施例中採用下列試法: ⑴不透明度 使試樣裝在1厘米厚之玻璃瓶中,利用雙射分光光度 計,測定4 2 Q X 1 0 _ 9米波長之透光率,以脱離子水為 100% 0 ⑵粘度 在2 0 °C恆溫水浴中之燒杯中放入試樣,以Β Μ型粘度計 測定粘度,測定時利用3號轉子依6 0轉/分鐘旋轉,但 若粘度超過2,0 Q 0厘泊,則改用4號轉子。 ⑶布魯克菲爾德塑變值 在2 (3 °C恆溫水浴中之燒杯中放入試樣。採用Β 8 Η型粘 度計,測定每種試樣在〇 · 5鞞/分鐘(3號轉子)及1轉 /分鐘(3號轉子)之表觀粘度。布魯克菲爾德塑變值 可由下列方程式計算搰之: -12- 本紙張又度適用中國國家標準(CNS)甲4規格(210 X 297公釐) (請先閲讀背面之注意事項再填寫本頁) —裝· 訂· 經濟部中央標準局®:工消費合作社印製 81.9.20,000 ,03拟 A6 B(i 五、發明説明(“ 「表觀粘度((3 · 5轉Ί 「表觀粘度(1轉 /分鐘,3號轉 L子,Β 8 Η粘度計 /分鐘,3號轉 i子,Β8Η粘度計- 布魯克菲爾德塑變值 10 0 經濟部中央標準局8工消費合作社印製 ⑷可擠性及可視性 將試樣倒入廚房用之市售清潔劑瓶(3 5 0毫升,裝有 推拉蓋中,將約5克試樣擠在泡綿(市售之聚胺基甲酸 酯泡線)1依照下列標準評估可擠性(自瓶中擠出液態 試樣之容易性)及液體體積在泡綿上之可視性: 可擠性: AAA :容易擠出 C C C :不易擠出 可視性: A A A :液體體積可清楚察覺, CCC:液體迅速滲入泡綿中,體積多寡無法確知》 ⑸可稱量性 將3 5 0克試樣倒入廚房用之市售清潔劑瓶(3 5 Q毫升, 装有推拉蓋)^由1〇位家庭主婦自瓶中擠出三次於泡綿 上,液體量約2 Q克。檢視每種擠出試樣之重量分佈。 例1 製備表1所列之清潔劑組成物,並按照前述性質⑴一 ⑸評估之。結果亦列於表1中。 13 本紙張又度適用中國國家標準(CNS)甲4規格(21ϋ X 297公釐) 81.9.20,000 (請先間-背面之注-事項再塡寫本頁) 五、發明説明(l: 01 01 01 _ ΟΖ 01 张|----Afi B6 cOSVio V. Description of the invention ("") The detergent composition thus obtained is suitable for kitchen and household items, such as dishwashing, kitchen utensils, bathrooms, floors, walls, furniture, toilets, vegetables, fruits, etc. The detergent composition will not be quickly inhaled after being squeezed on the foam, and the amount of squeezing is easy to detect. It is easy to squeeze out of the container quantitatively, which can avoid excessive use economically, and can also prevent hand cracks or rough skin. Η The invention is illustrated by an example that does not limit the scope of the invention, and other features can also be learned "Ning Bang Example: The following test methods are used in the examples: (1) Opacity makes the sample in a 1 cm thick glass bottle, using double shot Spectrophotometer to measure the light transmittance of 4 2 QX 1 0 _ 9 meters wavelength, with deionized water as 100% 0 ⑵ Viscosity Put the sample in a beaker in a constant temperature water bath at 2 0 ° C, the viscosity of B Μ type The viscosity is measured by using a No. 3 rotor at 60 rpm, but if the viscosity exceeds 2, 0 Q 0 centipoise, the No. 4 rotor is used. (3) Brookfield plastic deformation value is 2 (3 ° C constant temperature) Put it in the beaker in the water bath 。 Using Β 8 Η type viscometer, determine the apparent viscosity of each sample at 0. 5 鞞 / minute (rotor No. 3) and 1 rpm (rotor No. 3). Brookfield plastic deformation value can be calculated by the following equation搰 之 : -12- This paper is again applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) (please read the precautions on the back and then fill out this page) — Binding · Order · Central Standards Bureau of the Ministry of Economic Affairs ®: Printed by the Industrial and Consumer Cooperative Society 81.9.20,000, 03 to be A6 B (i V. Description of invention (““ Apparent viscosity ((3.5 5 turns Ί ”Apparent viscosity (1 turn / min, No. 3 turn L, Β 8 Η viscometer / minute, No. 3 rotor, Β8Η viscometer-Brookfield plastic deformation value 10 0 Printed by the Ministry of Economic Affairs, Central Standards Bureau, 8 industrial and consumer cooperatives ⑷ squeezability and visibility Pour the sample into the kitchen A commercially available detergent bottle (350 ml, fitted with a push-pull lid, squeeze about 5 grams of sample into foam (commercially available polyurethane foam line) 1) Evaluate the squeezability according to the following criteria ( Ease of squeezing liquid sample from bottle) and visibility of liquid volume on foam: Squeezability: AAA: easy Out of CCC: Not easy to squeeze out Visibility: AAA: The volume of the liquid can be clearly discerned, CCC: The liquid quickly penetrates into the foam, and the amount of the volume cannot be determined "⑸ Weighability Pour 3 500 grams of the sample into the kitchen for commercial use Cleaner bottle (35Qml, with a sliding lid) ^ 10 housewives squeezed from the bottle three times on the foam, the amount of liquid is about 2Qg. Examine the weight distribution of each extruded sample. Example 1 Prepare the detergent composition listed in Table 1 and evaluate it according to the aforementioned properties ⑴ 一 ⑸. The results are also listed in Table 1. 13 This paper is again applicable to the Chinese National Standard (CNS) A 4 specifications (21ϋ X 297 Mm) 81.9.20,000 (please first-note on the back-matters and then write this page) 5. Description of the invention (l: 01 01 01 _ ΟZO 01 Zhang | ----
0Z 01 Λ6 Β6 mm 9Z OSIo 3m 03 OSo vvv m ogooIo m mo寸 0002 0 02 01 經濟部中央標準局貝工消費合作社印製 (__%) 3链 —_怨— 书 妄« 丨 -S氍si枨fr-菰 丨 - ISHK 丨 - SUM - - (3)s- 避«in餸 ΙΒ®» (8)农链 S 赇^glfruisn +000踪氍漯趣歧 n+2il2w啾(ν)φ« 4 本紙張又度適用中國國家標準(CNS)甲4規格OUO X 297公釐) vvv § Oil 05 0 333m 0 ooco 001 9·+ι1ζ9·0+ι0ζ 0·Ι+Ι6ΐ 9·0+ι0ζ 0‘+|93 0·9+ι0ε {职)坦晒雄IP劫蹈!Μ铝链1?(芘)班細剧灘睡羝职.轉桕 (^圖)《淀 (次)肼米哟 81.9.20,000 f請先閱讀背面之注&事項再塡寫本頁) 丨裝· 訂. 五、發明説明(I* ) 物 成 組 〇 劑中 潔 2 清表 之於 列列 所亦 2 果 表結 備 -製估 評 質 性 之 述 前 按 (請先閱請背面之注悉事項再塡寫本頁) 經濟部中央標準局貝工消費合作社印製 本紙張尺度適用中國國家標準(CNS)甲4規格ΟΗϋ X 297公釐) 81.9.20,000 五、發明説明(4 ) 01 01 g· 咖0Z 01 Λ6 Β6 mm 9Z OSIo 3m 03 OSo vvv m ogooIo m mo inch 0002 0 02 01 Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (__%) 3 chains —_grievous — 曍 ── «丨 -S 氍 si 枨fr- 菰 丨-ISHK 丨-SUM--(3) s- Avoid «in 餸 ΙΒ®» (8) Agricultural chain S 赇 ^ glfruisn +000 Trace 氍 漯 氯 氯 氯 抯 愯 + 2il2w 啾 (ν) φ «4 books The paper is again applicable to the Chinese National Standard (CNS) Grade 4 (OUO X 297 mm) vvv § Oil 05 0 333m 0 ooco 001 9 · + ι1ζ9 · 0 + ι0ζ 0 · Ι + Ι6ΐ 9 · 0 + ι0ζ 0 '+ | 93 0 · 9 + ι0ε (job) Tan Xianxiong IP robbery! Μ Aluminum chain 1? (Pyrenee) class fine drama beach sleepy job. Transfer to the base (^ picture) `` Yodo (time) hydrazine 81.9.20,000 f Please read the note on the back & matters before writing this page) 丨Binding · Order. V. Description of the invention (I *) Group of things ○ Agents in the cleaning agent 2 The clear table is listed in the table 2 The preparation of the table-before the evaluation of the qualitative statement (please read the back page first (Notes to be written on this page) The paper printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs should be compliant with the Chinese National Standard (CNS) A 4 specifications (ΟΗϋ X 297 mm) 81.9.20,000 V. Description of the invention (4) 01 01 g · coffee
A6 BG νννννν 5 0SοA6 BG νννννν 5 0Sο
ννν ννν 0Μ OOSI 01 9.0 一 νννννν 9ΐ 008ο 01 S.0 τ οι 01 333 VVV Ο S Ο §νννο 001ο 333νννο 96 ΟΟί •ΉΤ2 0·Ι+,6Ι 9·ο+,οζ 0-+ιπ 0-+,οε Q.g+lQg (請先間汸背面之汰念事項再塡.'"本頁) •窣_ •11· 絰濟部中央標準局®:工消費合作社印製 (__%) 3璲 --ss §8ssnj®^ib® is^slsslellUM 0^sns^ ^^_屮农邳降) 振题Is枨歧《w(v)^链 (8)φ 堪 {3)次链 钽« (职)起_雄它 tl蹈151 坦S5151 (洛)班璐劄鹅膣«踩|«桕 (9i)鲥淀 (96) Μ^^ί l@omsaaA^阳ynqspsA ·Ι·Η ST3s?:nBs 陌名ΙΪΪ2 @-2dTui^^Dgs 阳-撕 HauTunune 6 本紙張尺度適用中國國家if準(CNS)甲4峴格(21ϋ X 2D7公釐) 81.9.20,000 經濟部中央標準局員工消費合作社印製ννν ννν 0Μ OOSI 01 9.0-ννννννν 9Ι 008ο 01 S.0 τ οι 01 333 VVV Ο S Ο §νννο 001ο 333νννο 96 ΟΟί • ΉΤ2 0 · Ι +, 6Ι 9 · ο +, οζ 0- + ιπ 0- +, οε Q.g + lQg (Please read the information on the back of the book first, then "." This page) • 窣 _ • 11 · Central Standards Bureau of the Ministry of Economy and Economy®: Printed by the industrial and consumer cooperative (__%) 3 璲--ss §8ssnj® ^ ib® is ^ slsslellUM 0 ^ sns ^ ^^ _ 屮 农 邳 降) Vibration question Is 抨 抨 《w (v) ^ chain (8) φ kan (3) secondary chain tantalum ) From _xiong it tl dance 151 tan S5151 (Luo) Banluza Goose «Tread |« 桕 (9i) Yundian (96) Μ ^^ ί l @ omsaaA ^ 阳 ynqspsA · Ι · Η ST3s ?: nBs Mo Name ΙΪΪ2 @ -2dTui ^^ Dgs Yang-Tear HauTunune 6 This paper scale is applicable to China National Standards (CNS) A 4 Dange (21ϋ X 2D7mm) 81.9.20,000 Printed by the Employees Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs
Ad Β(; 五、發明説明(tr ) 由例L及2可知惟有外觀不透明,而且粘度及布魯克 菲雨德塑變值在本發明標示之範圍内,矿能滿足性質⑴一 (5)之所有要求。 Μ 3 製備表3所列之清潔劑組成物。依下法檢視每種組成 物製妥之外觀及儲存安定性。諸組成物是由表3所列之 成分A及其他成分混合及加熱至8 Q°C而得。然後溶解成 分(B )及(C ),攪拌冷卻混合物至3 Q°C歷2小時。結果列 於表3中。 表3所列之所有本發明組成物均合乎本發明的先決條 件:亦即外觀不透明,2 0°C料溫之粘度為2 0 0至4 , 0 0 0厘 泊,布魯克菲爾德塑變值為5 - 1 0 Q泊。 ⑴外觀之觀察 將試樣倒入1 〇 〇毫升透明玻璃瓶中,以肉視觀察外觀 (珠白光澤)。包有氣泡之試樣則離心處理以去除氣泡 。評估之標準如下: AAA:均句珠白光澤, BBB:珠白光澤不均勻,有分離層(透明或類似乳化 液),或在瓶底有沉澱, C C C :無珠白光澤,像透明溶液,或像乳化液。 ⑵儲存安定性 將諸試樣倒入1 Q 0毫升透明玻璃瓶中,分別放入-5 °C ,室溫,3 (TC及4 0°C之恆溫浴中,儲存1個月。儲存後 ,按照前面⑴中之評估標準對諸試樣分级^ -1 7 - 本紙張又度適用中國國家標準(CNS)甲4現格(210 X 297公釐) 81.9.20,000 ------------------f-----裝II----ΤΓ------線( (請先閱治背面之注-事項再塡寫本頁) r 〇Βνϊ1° 五、發明説明(4 ) A6 ΒΓ> 經濟部中央標準局貝工消費合作社印製Ad Β (; V. Description of invention (tr) From examples L and 2 it can be seen that only the appearance is opaque, and the viscosity and Brookfield plastic deformation value are within the scope of the present invention, the mine can satisfy all of the properties (1) (5) Requirements. Μ 3 Prepare the detergent composition listed in Table 3. Check the appearance and storage stability of each composition according to the following method. The components are mixed and heated by ingredient A and other ingredients listed in Table 3. It was obtained at 8 Q ° C. Then, the components (B) and (C) were dissolved, and the mixture was stirred and cooled to 3 Q ° C for 2 hours. The results are listed in Table 3. All the compositions of the invention listed in Table 3 are in accordance with The prerequisite of the present invention: namely, the appearance is opaque, the viscosity of the material temperature at 20 ° C is 200 to 4, 0 0 centipoise, and the Brookfield plastic value is 5-10 Q poise. ⑴ The observation of the appearance will be The sample is poured into a 100-ml transparent glass bottle, and the appearance is visually observed (bead white gloss). The sample with bubbles is centrifuged to remove bubbles. The evaluation criteria are as follows: AAA: Even sentence beads white gloss, BBB: Pearl white gloss is uneven, with a separation layer (transparent or similar emulsion), or in the bottle There is precipitation, CCC: no pearl white gloss, like a transparent solution, or like an emulsion. ⑵ Storage stability Pour the samples into 1 Q 0 ml transparent glass bottles, put them at -5 ° C, room temperature, 3 (Stored for 1 month in a constant temperature bath at TC and 40 ° C. After storage, the samples are graded according to the evaluation criteria in (1) above -1 -7-This paper is again applicable to China National Standard (CNS) A4 Cash (210 X 297 mm) 81.9.20,000 ------------------ f ----- installed II ---- ΤΓ ------ line ((Please read the note on the back of the rule-matters before writing this page) r 〇Βνϊ1 ° V. Description of the invention (4) A6 ΒΓ > Printed by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs
表 3 本 發明組成 物 成 分 (% 重 量 ) 8 9 10 成 分 (A) 多 氣 乙撐 ⑶ 月 桂 醚硫酸納 2 0 - 10 直 鏈 烷苯 磺 酸 納 (分子量3 4 4 ) - 18 - 月 桂 酸二 乙 醇 醯 胺 - 4 8 多 氧 乙撐 (1 2)月 桂醚 - 2 - 月 桂 二甲 胺 化 氣 5 - - 成 分 m 乙 二 醇二 硬 脂 酸 酯 2 - 2 硬 脂 酸單 乙 醇 酵 胺 - 3 - 甘 油 硬脂 酸 酯 5 5 8 (甘油單酸酯含量9 0 % ) 分 (C) 乙 醇 5 5 5 其 他 成分 脱 離 子化 水 -餘 量- --- 剛 製 妥時 之 外 觀 AA A AAA AAA 儲 存 安定 性 -5 °C AAA AAA AAA 室 溫 AAA AAA AAA 3 0 rc AAA AAA AAA 4 0 rc Λ A A AAA AAA (請先閲¾背面之注念事項再塡寫本頁) -裝. 訂 本紙張又度適用中國囷家標準(CNS)甲4規格Ono X 297公釐) 81.9.20,000 五、發明説明(9 3 A6 B(i 有外 所即 。亦 估, 評求 並要 ,之 物明 成發 組本 劑乎 潔合 清均 的物 列成 所組 4 明 表發 備本 製之 3 列 例所 仿 4 表 為 度 粘^0 白 之、0? 溫10 料5-°c為 20值 在變 ,塑 明德 透爾 不菲 觀克 魯 布 泊 厘 (諳先聞讀背面之注-事項再填寫本頁) •裝· 訂 " 經濟部中央標準局R工消費合作社印製 本紙張尺度適用中國國家標準(CNS)屮4彡見格(210 X 2D7公釐) 81.9.20,000 Α6 Bfi 五、發明説明(》分) 經濟部中央標準局貝工消費合作社印製Table 3 Composition of the present invention (% by weight) 8 9 10 Component (A) Multi-gaseous ethylene ⑶ sodium lauryl ether sulfate 2 0-10 sodium linear alkane benzene sulfonate (molecular weight 3 4 4)-18-lauric acid Ethanolamide-4 8 Polyoxyethylene (1 2) lauryl ether-2-Lauryl dimethylamine gas 5--Ingredient m Ethylene glycol distearate 2-2 Stearic acid monoethanolase-3 -Glycerin stearate 5 5 8 (monoglyceride content 9 0%) Min (C) Ethanol 5 5 5 Other ingredients Deionized water-balance---- Appearance immediately after preparation AA A AAA AAA Storage stability -5 ° C AAA AAA AAA Room temperature AAA AAA AAA 3 0 rc AAA AAA AAA 4 0 rc Λ AA AAA AAA (Please read ¾ Notes on the back before writing this page)-Pack. Order paper Also applicable to China ’s Standards (CNS) A 4 specifications Ono X 297 mm) 81.9.20,000 V. Description of the invention (9 3 A6 B (i has something outside. It is also estimated, evaluated and demanded, and the matter is obvious The composition is almost clean and clear The material is listed in the group 4. The table 3 is issued by the system. The table 3 is copied. The table 4 is degree sticky ^ 0 white, 0? Temperature 10 material 5- ° c is 20. The value is changing. Philippine Krubberi (keep reading the note on the back-fill in this page before filling in the matter) • Binding · Order & Printed by R & C Cooperative Society of the Central Standards Bureau of the Ministry of Economic Affairs. The paper standard is applicable to the Chinese National Standard (CNS). 4 彡 见 格 (210 X 2D7mm) 81.9.20,000 Α6 Bfi V. Description of the invention ("sub) Printed by Beigong Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs
表 4 本發 明組成物 成 分 ( % 重 量 ) 11 12 13 成 分 (A ) 多 氣 乙 撐 ⑷ 月 桂 醚 硫 酸 酯 三 乙 醇胺 10 10 10 棕 櫊 油 脂 肪 酸 二 乙 醇 m 胺 10 10 10 成 分 m 二 乙 二 醇 二 硬 脂 酸 酯 5 5 5 脂 肪 酸 殘 基 甘 油 θα 単 酸 酯 含 量 之 m 原 子 數 ( % 重 量 ) 12 9 0 - 5 - 18 9 0 - - 5 2 2 9 0 5 - - 成 分 (C ) 乙 醇 5 5 5 其 他 成 分 脱 離 子 水 -- -餘量 — 剛 製 妥 時 外 觀 A A A AAA AAA 儲 存 安 定 性 -5°C AAA AAA AAA 室 溫 AAA AAA AAA 3 0 丨。C AAA AAA AAA 4 0 "C AAA AAA AAA (請先閲讀背面之注意事項再塡寫本頁) --裝· 訂. .嫁( 本紙張尺71適用中國國家標準(CNS>甲4覘格(210 X 297公釐) 81.9.20,000Table 4 Composition of the present invention (% by weight) 11 12 13 Component (A) Multi-gaseous ethylene ⑷ Lauryl ether sulfate triethanolamine 10 10 10 Palm oil fatty acid diethanol m amine 10 10 10 Component m Diethylene glycol di Stearic acid ester 5 5 5 Fatty acid residue glycerol θα m ester content m Atom number (% weight) 12 9 0-5-18 9 0--5 2 2 9 0 5--Ingredient (C) Ethanol 5 5 5 Other ingredients deionized water--balance-appearance immediately after preparation AAA AAA AAA Storage stability -5 ° C AAA AAA AAA Room temperature AAA AAA AAA 3 0 丨. C AAA AAA AAA 4 0 " C AAA AAA AAA (please read the precautions on the back before writing this page)-Binding · Order ... Marry (This paper ruler 71 is applicable to the Chinese National Standard (CNS> A4 觇 格(210 X 297 mm) 81.9.20,000
經濟部中央標準局員工消費合作社印製 五、發明説明(*9 ) 製備表5所列之清潔劑組成物,依下述方法評估清潔 ,起泡能力,使用感覺及手部龜裂趨勢,結果列於表5 中。所有表5所列之本發明組成物均滿足本發明之要求 ,亦即外觀不透明,在2 (TC料溫之粘度為2 0 0 - 4 , 0 0 0厘 泊,布魯克菲爾德塑變值5 - 1 0 0泊。 ⑴起泡試驗 在0.5%重量清潔劑之水溶液(所用水之硬度為3·5° D Η)中加入0 . 1 %重量市售牛油做為污物成分,測定諸 組成物之起泡能力。在5厘米直徑玻璃圓筒中倒入40毫 升含牛油之清潔劑溶液,在2 (TC攪拌1 5分鐘。停止攪拌 後,立即測定起泡高度。 ⑵清潔試驗 在每個直徑25厘米的磁盤中加入2.5克牛脂,其中含 有0 . 1 %重量蘇丹红(紅色染料)做為指示劑《在2 0 °C ,以浸入3克水及27克清潔劑溶液之泡綿一値接一値擦 洗諸磁盤。重覆清潔步驟,直到泡綿無法清除磁盤上的 牛脂。以有效的洗淨之盤子數目做為清潔能力之分數。 ⑶使用時之感覺試測 製備5 %清潔劑組成物溶液,保持在3 Q °C ^將手浸人 溶液中1 0分鐘後,以3 (TC水洗。然後充分以乾毛巾擦拭 後,放開5分鐘。依下列標準評估手部皮虜: ΛΑΑ :手部皮膚覺得爽快, -2 1 - 本紙張又度適用中國國家標準(CNS)甲4規格(210 X 2D7公釐) 81.9.20,000 ------------------f----裝——----·玎------線『- (請先閱讀背面之注念事項再塡寫本頁) A6 B6 五、發明説明(>°) C C C :手部皮虜覺得相當緊绷, ⑷對手部皮》的刺激性 製備5 %的清潔劑組成物溶液,保持在3 G °C。將手浸 入溶液中2 Q分鐘後,充分以水洗。連缠三天重覆此步驟 。在第四天,以目測五位試驗者的手部狀態,依下列標 準評估諸組成物之分數: (請先閲讀背面之注念事項再填寫本頁) 裝- 訂‘ 經濟部中央標準局®:工消費合作社印製 -22- 5分 皮 廣 並 未 粗 粮 化 4分 皮 虜 略 有 粗 m 化 3分 皮 ft 粗 糙 化 2分 皮 虜 有 點 m 重 地 粗糙化 1分 皮 虜 嚴 重 地 粗 m 化。 81.9.20,000 本紙張尺度適用中國國家掙準(CNS)甲4規格(210 X 297公釐) 五、發明説明( >丨) 001t-t-Hgl-lsPrinted by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (* 9) Prepare the detergent composition listed in Table 5 and evaluate the cleaning, foaming ability, use feeling and hand cracking tendency according to the following methods, the results It is listed in Table 5. All the compositions of the present invention listed in Table 5 meet the requirements of the present invention, that is, the appearance is opaque, the viscosity at 2 (TC material temperature is 200-4, 0 0 0 centipoise, Brookfield plastic value 5- 1 0 0 poises. (1) Foaming test Add 0.1% by weight of commercially available beef tallow as a soil component to a 0.5% by weight aqueous solution of detergent (the hardness of the water used is 3.5 ° D Η), and determine the composition The foaming capacity of the substance. Pour 40 ml of the detergent solution containing tallow into a 5 cm diameter glass cylinder and stir at 2 ° C for 15 minutes. After stopping the stirring, immediately measure the foaming height. ⑵Cleaning test is performed on each Add 2.5 grams of tallow to a 25-cm-diameter disk, which contains 0.1% by weight of Sudan Red (red dye) as an indicator "at 20 ° C, soaked in 3 grams of water and 27 grams of detergent solution. Scrub the disks one by one. Repeat the cleaning steps until the foam cannot remove the tallow from the disks. Take the number of effectively cleaned dishes as a fraction of the cleaning ability. (3) Prepare a 5% cleaning agent by using the feel test during use Composition solution, keep at 3 Q ° C ^ After immersing hands in solution for 10 minutes Wash with 3 (TC water. Then wipe with a dry towel, and let go for 5 minutes. Evaluate hand skin according to the following criteria: ΛΑΑ: Hand skin feels refreshing, -2 1-This paper is again applicable to the Chinese National Standard (CNS ) A 4 specifications (210 X 2D7 mm) 81.9.20,000 ------------------ f ---- installed -------- · 玎 ---- --Line 『-(please read the notes on the back before writing this page) A6 B6 V. Description of the invention (> °) CCC: The skin of the hand feels very tight, ⑷ the irritation of the skin of the hand '' Prepare a 5% solution of the detergent composition and keep it at 3 G ° C. After immersing your hand in the solution for 2 Q minutes, wash it thoroughly with water. Repeat this step for three days in a row. On the fourth day, test with five digits According to the following criteria, the scores of the constituents are evaluated according to the following criteria: (Please read the notes on the back before filling out this page) Binding-Order 'Central Standards Bureau of the Ministry of Economy®: Printed by the Industrial and Consumer Cooperatives-22- 5 The wide skin is not coarse grained. 4 points are slightly roughened. 3 points are thickened. Ft roughened. 2 points are thickened. 1 point is thickened. 1 point is thickened. 8 1.9.20,000 This paper scale is applicable to China National Accreditation Standard (CNS) Grade 4 (210 X 297 mm) V. Description of the invention (> 丨) 001t-t-Hgl-ls
ocsaSocsaS
0Z 02 0 Η ΛΓ) B(i ;—_怨 _錐! S.S 5·βο.9 〇·9 0_s ο·ιη33。 vvv m vvv vvv m 000s 000◦00000000 ^ iiococoio {請"閲"背面之’注念事項再場寫本頁) 丨裝. 經濟部中央標準局R工消費合作社印製 (1WW%) Φ堪 关 专« liKJG)农链 (%S6_40®趑》爱.&)遐题鋰囤*扭(9)衣瑶 豳歧 n + ul)fcK3w 舐 (92e_ir农祀降)塚氍assi装-β (01〇^〇_屮农毋降)ssfr-BWlsssas- β (πε _屮衣驭降)sil鸹枨歧濺_ 避题潺菡歧π + (ε)ιί2κ嫩(V)农链 -23 — 本紙張又茂適用中國國家標準(CNS)甲4規格(210 X 297公釐) (米W)邺傩 (舔雜)只铟Mls 81.9.20,000 Α6 Β(; 五、發明説明(》>) 例6 仿例5製備列於表6之清潔劑組成物,並評估之。結 果亦列於表6中。所有的表6所列的本發明組成物均滿 足本發明的要求,亦即外觀不透明,在2 (TC料溫之粘度 為2 Ο ϋ - 4 , 0 0 0厘泊,布魯克菲爾德塑變值為5 - 1 (] 0泊。 請 先 閱 面 士 事 項 再 塡 寫 本 頁 裝 訂 經濟部中央標準局WT工消費合作社印製 本紙張又度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 81.9.20,000 經濟部中央標準局員工消費合作杜印製 2〇ϋ 丄 3 Α6 B(i 五、發明説明(4 ) 表 6 本發 明 組成物 成 分 ( % 重 量 ) 19 2 0 成 分 (ή ) 直 鏈 烷 苯 磺 酸 納 (平 均 分 子 量 3 4 4 ) 2 0 2 0 十 二 院 酸 二 乙 醇 m 胺 8 8 成 分 (Β ) 在 脂 肪 酸 殘 基 甘 油 ασ 早 酸 酯 含 量 中 之 碩 原 子 數 ( % 重 量 ) 1 6 95 8 - 2 2 9 0 - 8 成 分 (C) 乙 醇 5 5 其 他 成 分 脱 離 子 水 — 餘 s --- 清 潔 能 力 ( f盤 « JlDn 數 ) 6 6 起 泡 高 度 (毫 米 ) 9 0 9 0 使 用 覺 A ΑΑ A A A 對 手 部 皮 慮 的 刺 激 性 5 .0 5 . 0 ------------------^-----裝丨 —----TT------ (請先閲讀背面之;±-意事項再塡寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4規格CUO X 297公釐) 81.9.20,000 r 〇BU^> A6 ΒΓ) 五、發明説明 7 例 結 Ο 之 估 評 並 物 成 組 劑 潔 青 •7— 的 MU 歹 所 7 表 備 製 5 例 仿 白 'VT· 。’厘 中求0Γ 7 要 ο 表之4’ 於 明 ο 列發20 果本為 乎度 合.粘'ο 均之泊 物度 CU 成溫-1 組料纟 明 P 發20 本在 有 , 所明 之透 列不 所觀 中外 7 即 表亦 為 值 變 塑 德 爾 菲 克 魯 布 (請先閲讀背面之注意事項再塡寫本頁) -裝· 訂· 經濟部中央標準曷Β工消费合作社印製 本紙張又度適用中國國家標準(CNS)甲4规格(2i0 X 297公釐) 81.9.20,000 S ο rl ά0Z 02 0 Η ΛΓ) B (i; —_ complain_cone! SS 5 · βο.9 〇 · 9 0_s ο · ιη33. Vvv m vvv vvv m 000s 000◦00000000 ^ iiococoio {Please " Read " 'Remember the matter and write this page again). Installed. Printed by R Industry and Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs (1WW%) ΦKanguan Special «liKJG) Agricultural Chain (% S6_40® 趑》 Love. &Amp;) Lithium hoarding (9) Yi Yao Yao Qi n + ul) fcK3w 舐 (92e_ir Nongsi Jiang) Tsukaji assi equipment-β (01〇 ^ 〇_ 屮 农 不 降) ssfr-BWlsssas- β (πε _ 屮 衣Yu Jiang) sil 鹹 渨 湨 splash _ Avoid problems 揺 菡 π + (ε) ιί2κNen (V) Agricultural Chain-23 — This paper is also applicable to China National Standards (CNS) A 4 specifications (210 X 297 mm) (Meter W) Ye Nuo (Licking) Indium Mls 81.9.20,000 Α6 Β (; V. Description of the Invention (》>)) Example 6 In Example 5, the detergent compositions listed in Table 6 were prepared and evaluated. Results It is also listed in Table 6. All the compositions of the present invention listed in Table 6 meet the requirements of the present invention, that is, the appearance is opaque, and the viscosity at 2 (TC material temperature is 2 Ο ϋ-4, 0.000 centipoise , Brookfield plastic deformation value is 5-1 (] 0 berth. Please read the noodles first塡 Write this page to bind the paper printed by the WT Industrial and Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. The paper is also applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 81.9.20,000. Preparation 2〇ϋ 丄 3 Α6 B (i V. Description of the invention (4) Table 6 Composition of the invention (% weight) 19 2 0 Composition (ή) Sodium linear alkane benzene sulfonate (average molecular weight 3 4 4) 2 0 2 0 Dodecanoic acid diethanol m amine 8 8 Composition (B) The number of atoms in the fatty acid residue glycerin ασ early acid ester content (% weight) 1 6 95 8-2 2 9 0-8 Composition (C ) Ethanol 5 5 Other components deionized water-I s --- cleaning ability (f plate «JlDn number) 6 6 Foaming height (mm) 9 0 9 0 Use of A ΑΑ AAA irritating hand skin 5. 0 5. 0 ----- ------------- ^ ----- install 丨 ------ TT ------ (please read the back first; ± -precautions before writing this page) This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications CUO X 297 mm) 81.9.20,000 r 〇BU ^> A6 ΒΓ) V. Description of the invention 7 cases of the evaluation of 〇. 7—The MU Office 7 table prepared 5 cases of imitation white 'VT ·. 'Centre for 0Γ 7 to ο 4 of the table' Yu Ming ο publish 20 The fruit is almost the same degree. Sticky 'ο The average poise degree CU Cheng Wen -1 Group material Ming Ming P hair 20 originally exists, it is known Throughout the world, Chinese and foreign 7 means that the table is also a value-changing Delphi Kruber (please read the precautions on the back before writing this page) -installed, ordered, printed by the Central Standard of the Ministry of Economic Affairs, Cooperative Consumer Cooperatives The paper is again applicable to the Chinese National Standard (CNS) A 4 specifications (2i0 X 297 mm) 81.9.20,000 S ο rl ά
AA
6 B 明 説 明 發 、 五 L· 0 s sCOCSJ^ 126 B Ming explanation hair, 5 L · 0 s sCOCSJ ^ 12
SI SIιητ-ΗSI SIιητ-Η
SISI
SISI
SI _雄---- ιη.ε s^o.s o.s 0-s 0-S 333 vvv vvv m vvv m000s 000000◦00s ^ iioiocoto (請先閱堵背面之注念事項再填寫本頁) .裝. 經濟部中央標準局8工消费合作社印製 (__%)衣堪 关 宰« 豳2{3)农钐 (96106酬舶®题跚茺扭)避氍鋰钽劳扭(8)农链 wq> 逛Ε-π^π + (9lnco«rf^^15l·)振雞?s钹 (09e_dt^irzb) yllefr氍 SIB 糊继-β (HesN-^irzb) S 饀玴淋歧濺岫 S题渥趙歧u + sliKIlM% (¥)求堪 7 2 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) SH菊蝱㈧樾挞聒砟菰 瑯挺¢¾ (米W)邺蛔街靼 (舔麴)<¥遐Μ« 81.9.20,000 訂 .線、 -SI _ 雄 ---- ιη.ε s ^ os os 0-s 0-S 333 vvv vvv m vvv m000s 000000 ◦ 00s ^ iioiocoto (please read the notes on the back and then fill out this page). Pack. Economy Printed by the Central Standards Bureau of the Ministry of Industry (8%) of the Consumer Cooperatives (__%). The clothing is worthy of customs. «豳 2 {3) Agricultural samarium (96106 rewards®). Lithium tantalum labor twisting (8) Agricultural chain wq > Ε-π ^ π + (9lnco «rf ^^ 15l ·) Zhenji? S cymbals (09e_dt ^ irzb) yllefr 氍 SIB paste-β (HesN- ^ irzb) S u + sliKIlM% (¥) Qiukan 7 2 The size of the paper is in accordance with Chinese National Standard (CNS) Grade 4 (210 X 297 mm). Street tartar (麗 麴) < ¥ ya «81.9.20,000 order. Line,-
- A6 I3G 〇b< 五、發明説明(a) 例ft 仿例5製備表8所列之清潔劑組成物並評估之。結果 亦列於表8中。所有表8所列之本發明組成物均合乎本 發明之要求,亦即外觀不透明,在2 (TC料溫之粘度為 2 0 0 - 4 , Q 0 0厘泊,布魯克菲爾德塑變值為5 - 1 0 G泊。 ------------------(-----裝-------#-------^( (請先閱讀背面之·;±-念事項再塡寫本頁) 經濟部中央標準局B工消費合作社印製 81.9.20,000 衣紙張尺度適用中國國家標準(CNS)甲4現格(210 X 297公釐) 五、發明説明(>?)-A6 I3G 〇b < V. Description of the invention (a) Example ft Example 5 Prepare the detergent composition listed in Table 8 and evaluate it. The results are also listed in Table 8. All the compositions of the present invention listed in Table 8 meet the requirements of the present invention, that is, the appearance is opaque, the viscosity at 2 (TC material temperature is 200-4, Q 0 0 centipoise, Brookfield plastic value is 5 -1 0 G parking. ------------------ (----- installed ------- # ------- ^ ((please Read the back first; ± -read the matter, and then write this page) 81.9.20,000 printed on the clothing and paper standard printed by the Central Bureau of Standards, Ministry of Economic Affairs, B Industry and Consumer Cooperative Society is applicable to the Chinese National Standard (CNS) A 4 cash (210 X 297 mm ) 5. Description of the invention (>?)
A6 BG 請 閱 表 8 本發明之 組成物 成 分 ( % 重 量) 2 6 2 7 成 分 JLA1. 多 氣 乙 it (2 .5)十二烷醚 20 20 十 四 院 二 甲 胺化 氣 5 5 成 分 JJ_L 在 脂 肪 酸 殘 基 甘 油 早 酸酯含量 中 之 磺 原 子 數 ( % 重量) 1 6 9 5 8 - 2 2 9 0 - 8 成 分 (C) 乙 醇 5 5 其 他 成 分 脱 離 子 水 --- 清 潔 能 力 (盤數 ) 6 6 起 泡 高 度 (毫米 ) 9 0 90 使 用 感 覺, • A AA ΑΛΑ 對 手 部 皮 1» 之剌 激 性 5 . 0 5 . 0 面I. 意 事 項 再 塡 寫 本 頁 經濟部中央標準局员工消費合作社印製 本紙張又度適用中园國家標準(CNS)甲4規格(210 X 297公釐) 81.9.20,000 經濟部中央標準局S工消費合作社印黎 Α6A6 BG Please refer to Table 8. The composition of the present invention Ingredients (% by weight) 2 6 2 7 Composition JLA1. Multi-gas ethyl (2.5) dodecane ether 20 20 The dimethylamine gas of the 14th House 5 5 Composition JJ_L Number of sulfon atoms in the content of fatty acid residue glycerol early ester (% by weight) 1 6 9 5 8-2 2 9 0-8 Ingredient (C) Ethanol 5 5 Other ingredients Deionized water --- Cleaning ability (number of plates ) 6 6 Bubbling height (mm) 9 0 90 Feel of use, • A AA ΑΛΑ Irritation of hand skin 1 »5. 0 5. 0 Face I. Remarks will be written on this page Employees of Central Bureau of Standards, Ministry of Economic Affairs The paper printed by the consumer cooperative is again applicable to the Central Park National Standards (CNS) A4 specification (210 X 297 mm) 81.9.20,000 The Central Standards Bureau of the Ministry of Economic Affairs S Industrial and Consumer Cooperatives Yinli A6
Bfi 五、發明説明) 例9 製 備 表 9 所 列 之 組 成 物 〇 撿 視 諸 組 成 物 製 妥 時 之外 觀 t 儲 存 安 定 性 及 起 泡 能 力 , 結 果 亦 列 於 表 9 中 〇 m 法 : 加 熱 混 合 表 9 中 所 列 之 成 分 A > D 及 其 他 成 分 ,然 後 在 8 0 °C溶人成分 B 〇 冷 卻 混 合 物 至 3 0 °C 歷 2 小 時 ,並 繼 鑛 m 拌 〇 It 估 方 法 ⑴ 外 觀 之 觀 察 將試樣倒入1 〇 〇毫升透明玻璃瓶中,以肉眼觀察外觀 ,依下列標準評估之: AAA:均句珠白光澤 CCC:珠白光澤不均勻,有分離層(透明或乳化液狀 )〇 ⑵儲存安定性 將諸試樣倒入1 〇 〇毫升透明玻璃瓶中,分別放在-5 °C ,3 0 °C及4 (TC恆溫浴中儲存1個月。儲存後,按照⑴之 標準評估之。 ⑶起泡能力 在0 . 5 °/。重量清潔劑水溶液(所用水之硬度為3 . 5 ° D Η )中,加入〇 . 1 %重量市售牛油,測定諸組成物之起泡 能力。將4 0毫升含牛油之清潔劑溶液倒入5厘米直徑之 玻璃圓筒中。此外,在圓筒中加入2 0個1厘米直徑的橡 -30- 本紙張又度適用中國园家標準(CNS)甲4規格〇UO X 297公釐) 81.9.20,000 -------------------(----裝-------訂------線4 (請先閱讀背面之注念事項再塡寫本頁) 五、發明説明(>9 )Bfi 5. Description of the invention) Example 9 Preparation of the components listed in Table 9 ○ Look at the appearance of the components when they are prepared t Storage stability and foaming ability, the results are also listed in Table 9 〇m method: heating mixing table 9 listed ingredients A > D and other ingredients, and then dissolve the ingredients B at 80 ° C. Cool the mixture to 30 ° C for 2 hours, and continue to mix. It is estimated. ⑴ The observation of the appearance will be The sample was poured into a 100-ml transparent glass bottle, and the appearance was observed with the naked eye, and evaluated according to the following criteria: AAA: uniform sentence bead white gloss CCC: bead white gloss uneven, with a separation layer (transparent or emulsified liquid). ⑵ Storage stability Pour the samples into a 100ml transparent glass bottle and store them at -5 ° C, 30 ° C and 4 (TC constant temperature bath for 1 month. After storage, follow the standards of ⑴ Evaluate. ⑶ Foaming capacity is 0.5 ° /. Weight of detergent aqueous solution (the hardness of the water used is 3.5 ° D Η), add 0.1% by weight of the city Tallow, measure the foaming ability of the components. Pour 40 ml of the detergent solution containing tallow into a 5 cm diameter glass cylinder. In addition, add 20 1 cm diameter oak-30- to the cylinder This paper is again applicable to China Yuanjia Standard (CNS) A 4 specifications (UU X 297 mm) 81.9.20,000 ------------------- (---- installed ------- Subscribe ------ Line 4 (Please read the notes on the back before writing this page) 5. Description of the invention (> 9)
ΑΓ) BG 鐘 分 5 1X 拌 攪 °c ο 2 在 0 量 〇 力度 械高 機泡 之起 需量 所测 泡卽 起立 強後 加拌 ,Μ 球止 _ 停 求 要 . ο 之 ο 明4’ 發0-本20 乎為 合度 均粘h 白 物之 W 成溫10 組料 ΙΓ3 明°c為 發20值 本在變 之,塑 列明德 所透爾 中不菲 9 觀克 表外魯 有即布 所亦 , -泊 厘 (諳先閲讀背面之注悫事項再塡寫本頁) —裝· 訂. 經濟部中央標準曷I®工消費合作社印製 本紙張尺Λ適用中國國家標準(CNS)甲4規格(21ϋ X 297公釐) 81.9.20,000 經濟部中央標準局8工消費合作社印製 五、發明説明(糾) 表 9 本發明 組成物 成 分 (% 重 量 ) 28 2 9 3 0 3 1 成 分 (A) 多 氣 乙撐 ⑶ 月 桂 醚 硫 酸 鈉 15 15 2 0 2 0 月 桂 二 甲 胺 化 氣 5 5 3 3 多 氣 乙撐 ⑻ 月 桂 醚 3 2 - - 月 桂 酸二 乙 醇 m 胺 - 1 5 5 成 分 (B) 硬 脂 酸単 乙 醇 醯 胺 3 - 2 9 甘 油 單山 ¥ 酸 酯 - 5 - - 成 分 (C) 乙 醇 5 5 5 5 成 分 (D) 多 環 氧乙 烷 對 乙 二 醇 之 加 4 4 4 4 合 物 (平 均 分 子 量 10 0 0 ) 其 他 成分 脫 離 子水 - ---餘、 s---- 剛 製 妥時 之 外 觀 A AA AAA AAA AAA 儲 存 安定 性 -5 °C AAA AAA AAA AAA 3 0 °c AAA AAA AAA AAA 4 0 °c Λ A A AAA AAA AAA 起 泡 高度 (毫米) 10 0 10 0 10 0 10 0 (請先閲讀背面之注&:^項再塡寫本頁) 本紙張又度適用中國國家標準(CNS)甲4峴格CMO X 297公釐) 81.9.20,000 五、發明説明(々I ) Μ A6 妥 製 剛 估 評 並 物 成 組 劑 潔 清 之 列 所 ο »1 - 表 備 製 9 例 仿 所即 〇 亦 中 , 11求 表要 於之 列明 果發 結本 〇 乎 力合 能均 泡物 起成 及組 性明 定發 安本 存之 儲列 ,所 觀 1 外表 之有 為 度 粘 之 溫 料 1 Ρ5-20值 在變 ,塑 明德 透爾 不菲 觀克 外魯 泊 布 泊 厘 (諳先閲讀背面之注悫事項再塡..^本頁) 丨裝· 訂 經濟部中央標準局3工消費合作社印製 本紙張又度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 81.9.20,000 A6 B6 五、發明説明(★*)表 10 成 分 (A) 多 氣 乙if ⑷ 月 桂 醚 硫 酸 鈉 1 8 % 十 四 烷二 甲 胺 化 氧 2 多 氧 乙撐 (1 2 )烷 醚 4 月 桂 羥磺 基 甜 菜 鹼 嫌 2 成 分 m 乙 二 醇單 硬 脂 酸 酯 3 成 分 (C) 乙 醇 5 成 分 (D ) 多 烷 撐氧 對 多 醇 之 加 合 物 見表1 1 其 他 成分 脱 離 子水 餘量 CH〇 OH 1+ I C12H25-N -CH2CHCH2S〇3 ch3 (請先閱"背面之注念^·項再塡寫本頁) 經濟部中央標準局員工消费合作社印製 -34- 本紙張尺度適用中國國家攆準(CNS)甲4规格(210 X 297公;¥ ) 81.9.20,000 經濟部中央標準曷wf工消費合作社印製 一 Afi ΒΓ> 五、發明説明(Ο ) 表 11 本 發明站 [成物 成 分 ( % 重 量 ) 3 2 3 3 3 4 3 5 多 烷 if 氣 對 多 醇 平均分 子量 之 加 合 物 多 乙 撐 氧 對 甘 油 10 0 0 5 - - - 之 加 合 物 2 0 0 0 - 5 - - 多 丙 if 氧 對 乙 二 7 0 0 - - 3 - 醇 之 加 合 物 15 0 0 - - - 3 剛 製 妥 時 之 外 觀 A A A AAA AAA AAA 儲 存 安 定 性 -5°C AAA AAA AAA AAA 3 0 10C AAA AAA AAA AAA 4 0 1 °c AAA AAA AAA AAA 起 泡 高 度 (毫米) 10 0 1 0 0 10 0 10 0 -35- (請先閲讀背面之注意奪項再塡寫本頁) 丨裝- 訂. .線( 本紙張又度適用中國國家棵準(CNS)甲4規格(210 X 297公釐) 81.9.20,000 ο .X' .7 β οclΑΓ) BG minutes 5 1X Stirring ° c ο 2 After measuring the starting demand of the bubble at 0 volume 〇Strength of the machine, the bubble is added after the standing strength is strong, Μ Ball stop _ Stop asking. Ο 之 ο Ming 4 ' Hair 0-Ben 20 is the same degree of uniform sticky h White matter W Cheng Wen 10 ingredients ΙΓ3 Ming ° C is hair 20 value is changing, the plastic is worth a lot of money 9 out of appearance That is also the cloth, -Boli (know first read the notes on the back and then write this page)-Binding · Order. The central standard of the Ministry of Economic Affairs I I Industrial and Consumer Cooperatives printed this paper ruler Λ China National Standards (CNS ) A4 specifications (21ϋ X 297mm) 81.9.20,000 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs, 8 Industrial and Consumer Cooperatives V. Description of the invention (correction) Table 9 Composition of the invention (% weight) 28 2 9 3 0 3 1 Ingredients (A) Polygaseous ethylene ⑶ Sodium lauryl ether sulfate 15 15 2 0 2 0 Lauryl dimethylamine gas 5 5 3 3 Polygaseous ethylene ⑻ Lauryl ether 3 2--Lauryl diethanol mamine-1 5 5 Ingredients (B) Stearic acid ethanolamide 3-2 9 Gan Shanshan ¥ Ester-5--Component (C) Ethanol 5 5 5 5 Component (D) Polyethylene oxide plus ethylene glycol 4 4 4 4 compound (average molecular weight 10 0 0) Other components deionized Water---- Yu, s ---- Appearance when just made A AA AAA AAA AAA Storage stability -5 ° C AAA AAA AAA AAA 3 0 ° c AAA AAA AAA AAA 4 0 ° c Λ AA AAA AAA AAA Bubbling height (mm) 10 0 10 0 10 0 10 0 (Please read the note &: ^ item on the back to write this page) This paper is also applicable to the Chinese National Standard (CNS) A4 Dange CMO X 297 mm) 81.9.20,000 V. Description of the invention (々I) Μ A6 Prepared and just evaluated and listed as a grouping agent for cleansing. Ο »1-Table preparation 9 cases imitated i.e. 11 seeking The table should list the fruit hairpin. The storage of the formation of the homogenous homogenous bubble and the composition of the set of the hair and the safety of the deposit. Observation 1 The appearance of the temperature is very sticky. The temperature 1 Ρ5-20 value is in Change, make Mindtur not Fibonacci Rupert Bourbury (Be sure to read the notes on the back and then .. ^ this page) 丨 Installation and ordering The paper printed by the Central Bureau of Standards of the Ministry of Economic Affairs, 3 Industrial and Consumer Cooperatives, is also applicable to the Chinese national standards ( CNS) A 4 specifications (210 X 297 mm) 81.9.20,000 A6 B6 V. Description of the invention (★ *) Table 10 Composition (A) Multi-gas ethyl if ⑷ Sodium lauryl ether sulfate 18% Tetradecane dimethyl amination Oxygen 2 Polyoxyethylene (1 2) Alkyl ether 4 Lauryl sulfobetaine 2 Ingredient m Ethylene glycol monostearate 3 Ingredient (C) Ethanol 5 Ingredient (D) Polyalkylene oxide to polyol The adducts are shown in Table 1 1 Other components deionized water balance CH〇OH 1+ I C12H25-N -CH2CHCH2S〇3 ch3 (Please read " Notes on the back ^ · Item and then write this page) Central Ministry of Economic Affairs Printed by the Bureau of Standards and Employee Consumer Cooperatives-34- This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 g; ¥) 81.9.20,000 Printed by the Ministry of Economic Affairs Central Standards Industry and Consumer Cooperatives Afi ΒΓ > Fives Description of the invention (Ο) Table 11 The present invention station [composition components (% by weight) 3 2 3 3 3 4 3 5 polyalkylene if gas to polyol average molecular weight adduct polyethylene oxide to glycerol 10 0 0 5 ---The adduct 2 0 0 0-5--Polypropylene if oxo ethylene 7 0 0--3-The adduct of alcohol 15 0 0---3 Appearance immediately after preparation AAA AAA AAA AAA Storage stability -5 ° C AAA AAA AAA AAA 3 0 10C AAA AAA AAA AAA 4 0 1 ° c AAA AAA AAA AAA Bubble height (mm) 10 0 1 0 0 10 0 10 0 -35- (please read first Note on the back and write this page again) 丨 Binding-Order ... Line (This paper is also applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm) 81.9.20,000 ο .X '.7 β οcl
A 听説 明發 、五 果本 結乎 C 合 之均 估物 評成 並組 物之 成明 組發 劑本 潔列 清所 之中 列12 所表 2 , 1 有 表所 備 〇 製12 9 表 例於 仔 歹 亦 在 明 透 不 觀 外 即 亦 求 要 之 明 發 為 值 變 塑 德 爾 菲 克 魯 布 泊 厘 為 度· ο 粘泊 之00 溫7 料 p (請先閲功背面之;-1-意事項再塡寫本頁) •丨裝. 訂. .線; 經濟部中央標準局8工消費合作社印製 本紙張尺度適用中囷國家標準(CNS)甲4規格(210 X 297公釐) 81.9.20,000 A6 ΒΓ> 五、發明説明(^Γ) 經濟部中央標準局員工消費合作社印製 表 12 本發明 組成物 成 分 ( % 重 量 ) 3 6 3 7 38 3 9 分 (A ) 多 氣 乙 if ⑶ 月 桂 醚 硫 酸鈉 15 15 2 0 2 0 月 桂 二 甲 胺 化 氣 5 5 3 3 多 氧 乙 if ⑻ 月 桂 醚 3 2 - - 月 桂 酸 二 乙 醇 m 胺 - 1 5 5 成 分 (B ) 硬 脂 酸 art 早 乙 醇 m 胺 3 - 2 9 甘 油 單 山 ¥ 酸 酯 - 5 - - 成 分 (〇 乙 醇 5 5 5 5 成 分 (D) 多 乙 撐 氣 對 乙 二 醇 之 加 4 4 4 4 合 物 (平 均 分 子 量 15 0 0) 其 他 成 分 脱 離 子 水 ----餘 量 剛製 妥 時 之 外 觀 A A A AAA AAA AAA 儲 存 安 定 性 一 5 .°c AAA AAA AAA AAA 3 0 °c AAA AAA AAA AAA 4 0 t°C AAA AAA AAA AAA 起 泡 高 度 (毫米) 10 0 10 0 10 0 10 0 -37- 間 背 之 注· 事 項 再. 塡 寫 本 頁 裝 訂 線 ^•4 本紙張尺度適用中國國家棵準(CNS)甲4峴格(210 X 297公釐) 81.9.20,000 A6 B(; J ’·、 五、發明説明(斗) ΆΑΙ^ 仿例9製備表1 3中所列之清潔劑組成物,並評估之。 结果列於表1 4中。所有表1 4所列之本發明組成物均合乎 本發明之要求,亦即外觀不透明,在2 0°C料溫之粘度為 2 0 0至4,0 0 0厘泊,而布魯克菲爾德塑變值為5 - 1 0 0泊。 表 13 (請先閲讀背面之.;±-念事項再塡寫本頁) 經 濟 部 中 央 標 準 8 工 消 # 合 作 社 印 製 成分(Α) 多氧乙撐⑷月桂醚硫酸納 十四烷二甲胺化氧 多氧乙撐(12)烷醚 月桂羥磺基甜菜鹼 成分(Β) 乙二醇單硬脂酸酯 成分(η 乙醇 成分(Π) 多烷if氧對多醇加合物之硫酸酯納 苴他成分 脱離子水 1 8 % 2 4 2 見表14 餘量A Listening to the instructions, the results of the evaluation of the combined results of the five fruits of the combination of C and the combination of the Chengming group hair agent Benjie listed in the clearing house are listed in 12 tables 2 and 1 is prepared by the table. For example, Yuzai is also indifferent and transparent, that is to say, the value of the hair is changed. Delphi Krubber is in degrees. Ο Sticky 00 temperature 7 materials p (please read the back of the first;- 1-Information will be written on this page) • Installed. Ordered. Thread; Printed by the Central Standards Bureau of the Ministry of Economic Affairs of the 8th Industrial and Consumer Cooperatives. The paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm ) 81.9.20,000 A6 ΒΓ > V. Description of the invention (^ Γ) Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 12 The composition of this invention (% weight) 3 6 3 7 38 3 9 points (A) if ⑶ sodium lauryl ether sulfate 15 15 2 0 2 0 lauryl dimethylamine gas 5 5 3 3 polyoxyethylene if ⑻ lauryl ether 3 2--lauric acid diethanol m amine-1 5 5 ingredient (B) stearic acid art Early ethanol m amine 3-2 9 glycerol monoshan ¥ Ester- 5--Ingredient (〇ethanol 5 5 5 5 Ingredient (D) Polyethylene gas to ethylene glycol 4 4 4 4 compound (average molecular weight 15 0 0) Other ingredients deionized water --- -Appearance when the balance is just made AAA AAA AAA AAA Storage stability 1 5. ° c AAA AAA AAA AAA 3 0 ° c AAA AAA AAA AAA 4 0 t ° C AAA AAA AAA AAA Bubble height (mm) 10 0 10 0 10 0 10 0 -37- Note to the back · Matters again. 塡 Write this page binding line ^ • 4 This paper size is suitable for China National Standard (CNS) Jia 4 Dange (210 X 297 mm) 81.9. 20,000 A6 B (; J '·, V. Description of the invention (bucket) ΆΑΙ ^ Example 9 Prepare the detergent compositions listed in Table 13 and evaluate them. The results are shown in Table 14. All the compositions of the present invention listed in Table 14 meet the requirements of the present invention, that is, the appearance is opaque, and the viscosity at a material temperature of 20 ° C is 200 to 4,000 centipoise, while Brookfield plastic deformation The value is 5-100 poise. Table 13 (Please read the back side first .; ± -read the matter before writing this page) Ministry of Economic Affairs Central Standard 8 工 消 # Cooperative prints (A) Polyoxyethylene ⑷Lauryl ether sodium tetradecane dimethylamine sulfate Oxidized polyoxyethylene (12) alkyl ether lauryl hydroxy sulfobetaine component (B) ethylene glycol monostearate component (η ethanol component (Π) sulfate of polyalkylene oxide to polyol adduct Na Tupeta component deionized water 18% 2 4 2 see table 14
本紙張又度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 81.9.20,000 裝 訂 線 13 B' οThis paper is again applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 81.9.20,000 binding line 13 B 'ο
A B 五、發明説明U7 ) 經濟部中央標準局员工消費合作社印製 表 14 本 發明 組成 物 成 分 ( % 重 量 ) 5 6 7 8 多 院 撐 氧 對 多 醇 加 平 均 合 物 之 硫 酸 酯 鹽 分子量β 多 乙 撐 氧 對 甘 油 加 1 0 0 0 5 - - - 合 物 今硫 酸 酯 三 鈉 二 2 0 0 0 ' 5 一 — 多 丙 撐 氣 對 乙 二 醇 加 7 0 0 - - 3 - 合 物 之 二 硫 酸 酯 二 鈉 1 5 0 0 - - - 3 剛 製 妥 時 外 觀 ΑΑΑ AA A A ΑΛ A A A 儲 存 安 定 性 -5°C AA A AAA AAA AAA 3 0°C AAA AAA AAA AAA 4 0 丨。C AAA AAA AAA AAA 起 泡 高 度 (毫米) 10 0 10 0 10 0 10 0 氺 多 烷 撐 氣 對 多 醇 加 合 物 之 平 均 分子 量 顯 地 依 前 面 的 教 導 可 做 許 多 種修 改 及變 化, 凡 此種 種 均 屬 於 所 附 之 本 發 明 之 申 請 專 利範 圍 内, 亦即 本 發明 可 在 實 施 例 以 外 之 方 式 實 施 〇 3 !) (諳先閱讀背面之注念事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)甲4規格(2i0 X 2ί>7公釐) 81.9.20,000AB V. Description of Invention U7) Printed by the Consumers ’Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 14 Composition of the composition of the invention (% by weight) 5 6 7 8 The molecular weight of the sulfate salt molecular weight β of the polyoxygen-to-polyol addition compound Ethylene oxide to glycerol plus 1 0 0 0 0 5---compound present sodium sulfate trisodium di 2 0 0 0 0 '5-polypropylene gas to ethylene glycol plus 7 0 0--3-compound of the second Disodium sulfate 1 5 0 0---3 Appearance immediately after preparation ΑΑΑ AA AA ΑΛ AAA Storage stability -5 ° C AA A AAA AAA AAA 3 0 ° C AAA AAA AAA AAA 4 0 丨. C AAA AAA AAA AAA Foaming height (mm) 10 0 10 0 10 0 10 0 The average molecular weight of polyalkylene oxide adducts to polyols can obviously be modified and varied according to the previous teachings. All belong to the scope of the attached patent application for the present invention, that is, the present invention can be implemented in ways other than the embodiment. (3) Please read the notes on the back and then fill out this page. This paper standard is applicable to Chinese national standards (CNS) A 4 specifications (2i0 X 2ί> 7mm) 81.9.20,000
Claims (1)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25670091A JPH0598290A (en) | 1991-10-03 | 1991-10-03 | Emulsified detergent composition for hard surface |
JP25670391A JPH0598287A (en) | 1991-10-03 | 1991-10-03 | Emulsified detergent composition for hard surface |
JP27753891A JPH05117687A (en) | 1991-10-24 | 1991-10-24 | Liquid detergent composition |
JP17701892A JP3018129B2 (en) | 1992-07-03 | 1992-07-03 | Liquid detergent composition |
JP4190809A JP2979275B2 (en) | 1992-07-17 | 1992-07-17 | Liquid detergent composition |
Publications (1)
Publication Number | Publication Date |
---|---|
TW208715B true TW208715B (en) | 1993-07-01 |
Family
ID=51356889
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW81107806A TW208715B (en) | 1991-10-03 | 1992-10-01 | Liquid detergent composition |
Country Status (1)
Country | Link |
---|---|
TW (1) | TW208715B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI787368B (en) * | 2017-10-17 | 2022-12-21 | 日商花王股份有限公司 | Liquid cleaner composition for hard surfaces |
-
1992
- 1992-10-01 TW TW81107806A patent/TW208715B/en active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI787368B (en) * | 2017-10-17 | 2022-12-21 | 日商花王股份有限公司 | Liquid cleaner composition for hard surfaces |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE3533977C2 (en) | Highly foaming nonionic surfactant-based liquid cleaner | |
EP0535693B1 (en) | Liquid detergent composition | |
US4620937A (en) | All purpose cleaner containing D-Limonene | |
US3326808A (en) | Antiseptic detergent composition | |
DE68920112T2 (en) | Detergent composition. | |
PT88977B (en) | Process for the preparation of a composition in the form of a stable micro-emulsion, for cleaning, containing organic synthettic detersive | |
US6267976B1 (en) | Skin cleanser with photosensitive dye | |
JPH078991B2 (en) | Neutral liquid detergent composition | |
AT394204B (en) | CLEAR, SINGLE-PHASE, LIQUID, CLEANING AGENT SUITABLE FOR CLEANING HARD SURFACES | |
CN100543125C (en) | Solid soap composition and bar soap | |
TW208715B (en) | Liquid detergent composition | |
US6720297B2 (en) | Cleaning composition | |
US4261851A (en) | Low-irritating detergent composition | |
DE69007774T2 (en) | Process for protecting hard surfaces. | |
JPH0438797B2 (en) | ||
JP5536086B2 (en) | Liquid skin cleanser composition | |
CN105452434B (en) | Wiping washes agent by liquid | |
JPH02123195A (en) | Detergent composition | |
WO2012066917A1 (en) | Cleaning agent composition | |
JPH0575039B2 (en) | ||
JPH04213398A (en) | Transparent soap composition | |
US2773834A (en) | Shampoo compositions containing monomethylol dimethyl hydantoin | |
JPH02182793A (en) | Detergent composition | |
CN109125104B (en) | Detergent composition | |
DE363374C (en) | Process for the production of floor cleaning oil emulsions |