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SU478842A1 - The method of obtaining modified phenol-formaldehyde resins - Google Patents

The method of obtaining modified phenol-formaldehyde resins

Info

Publication number
SU478842A1
SU478842A1 SU1834576A SU1834576A SU478842A1 SU 478842 A1 SU478842 A1 SU 478842A1 SU 1834576 A SU1834576 A SU 1834576A SU 1834576 A SU1834576 A SU 1834576A SU 478842 A1 SU478842 A1 SU 478842A1
Authority
SU
USSR - Soviet Union
Prior art keywords
formaldehyde resins
modified phenol
obtaining modified
resin
phenol
Prior art date
Application number
SU1834576A
Other languages
Russian (ru)
Inventor
Иван Васильевич Каменский
Светлана Борисовна Скубина
Татьяна Петровна Кислова
Original Assignee
Московский Ордена Ленина И Ордена Трудового Красного Знамени Химикотехнологический Институт Им.Д.И. Менделеева
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Московский Ордена Ленина И Ордена Трудового Красного Знамени Химикотехнологический Институт Им.Д.И. Менделеева filed Critical Московский Ордена Ленина И Ордена Трудового Красного Знамени Химикотехнологический Институт Им.Д.И. Менделеева
Priority to SU1834576A priority Critical patent/SU478842A1/en
Application granted granted Critical
Publication of SU478842A1 publication Critical patent/SU478842A1/en

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Description

При нагрузке 0,05 кгс/см деформационна  теплостойкость полимера, определенна  на приборе Цетлина, равна 480°С.Under a load of 0.05 kgf / cm, the deformation heat resistance of the polymer, determined on a Zetlin device, is 480 ° C.

Физико-механические показатели пресс-издели  на основе фенолформальдегидной смолы , модифицированной поливинилфурфуралем , приведены ниже. В качестве наполнител  используетс  кокс.The physicomechanical characteristics of a press product based on a phenol-formaldehyde resin modified with polyvinyl furfural are given below. Coke is used as a filler.

Плотность, г/см 1,35- 1,62 в зависимостиDensity, g / cm 1.35-1.62 depending

от давлени  прессовани . Предел прочности при 1100-1200from pressing pressure. Strength at 1100-1200

сжатии, кг/см Твердость по Бринеллю,25-36.compression, kg / cm Brinell hardness, 25-36.

кг/ммkg / mm

Совмещенную смолу испытывают в качестве кле . Склеивают стальные пластины при удельном давлении 1 кг/см.The combined resin is tested as an adhesive. Steel plates are glued at a specific pressure of 1 kg / cm.

Результаты испытаний на предел прочности при сдвиге следующие:The test results for shear strength are as follows:

Режим отверждени  при 150°С, час2Curing mode at 150 ° С, hour2

Температура испытани , °С20Test Temperature, ° C

Предел прочности при сдвиге, «г/см 69 Клеевой шов, прогретый при 300°С в течение 15 мин, имеет предел прочности при сдвиге 25 кг/см, а протретый при 500°С в течение 15 мин 7 кг/см.Shear strength, “g / cm 69” The adhesive joint heated at 300 ° C for 15 minutes has a shear strength of 25 kg / cm, and 7 kg / cm cured at 500 ° C for 15 minutes.

Предмет изобретени Subject invention

Способ получени  модифицированных фенолформальдегидных смол путем конденсации фенол-форМальдегидных смол с поливинилацеталем , отличающийс  тем, что, с целью упрощени  способа и повышеии  теплостойкости отвержденного материала, в качестве смолы используют водорастворимую фенолформальдегидную смолу и в качестве ацетал  - поливинилфурфураль, причем конденсацию провод т в водной среде при комнатной температуре и весовом соотношении компонентов 1 : 0,5-2 по сухому остатку соответственно .The method of obtaining modified phenol-formaldehyde resins by condensation of phenol-formaldehyde resins with polyvinyl acetal, characterized in that, in order to simplify the process and increase the heat resistance of the cured material, a water-soluble phenol-formaldehyde resin is used as the resin and as an acetal-polyvinyl surfure resin, a template, a maritime resin, is used. at room temperature and weight ratio of components 1: 0.5-2 on the dry residue, respectively.

SU1834576A 1972-10-04 1972-10-04 The method of obtaining modified phenol-formaldehyde resins SU478842A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU1834576A SU478842A1 (en) 1972-10-04 1972-10-04 The method of obtaining modified phenol-formaldehyde resins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU1834576A SU478842A1 (en) 1972-10-04 1972-10-04 The method of obtaining modified phenol-formaldehyde resins

Publications (1)

Publication Number Publication Date
SU478842A1 true SU478842A1 (en) 1975-07-30

Family

ID=20528752

Family Applications (1)

Application Number Title Priority Date Filing Date
SU1834576A SU478842A1 (en) 1972-10-04 1972-10-04 The method of obtaining modified phenol-formaldehyde resins

Country Status (1)

Country Link
SU (1) SU478842A1 (en)

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