Федеральное государственное унитарное предприятие "Российский научный центр "Прикладная химия" Пермский филиал
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Organic Low-Molecular-Weight Compounds And Preparation Thereof
(AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts
(AREA)
Abstract
FIELD: organic chemistry, chemical technology.SUBSTANCE: invention relates to a method for synthesis of perfluoropolyoxaethylene dicarboxylic acid difluoroanhydrides of the general formula: FOC(CFOCF)COF wherein n = 1-10 in using tetrafluoroethylene oxide in the presence of catalyst in solvent at temperature (-15)-(-40)°C. In aim for simplifying the process tetrafluoroethylene oxide is added for interaction with fluorosulfonyloxydifluoroacetyl fluoride, and potassium fluoride or cesium fluoride is used a catalyst.EFFECT: improved method of synthesis.3 tbl, 2 ex
SU3074833/04A1983-10-041983-10-04Method for preparing perfluoropolyoxaethylene dicarboxylic acid difluoroanhydrides
SU1840588A1
(en)
Process for the preparation of 2-thiocyanomethylthiobenzothiazole and process for the preparation of 2-thiocyanomethylthiobenzothiazole as a glycol ether solution