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SK109397A3 - Dihaloformaldoxime carbamates as antimicrobial agents - Google Patents

Dihaloformaldoxime carbamates as antimicrobial agents Download PDF

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Publication number
SK109397A3
SK109397A3 SK1093-97A SK109397A SK109397A3 SK 109397 A3 SK109397 A3 SK 109397A3 SK 109397 A SK109397 A SK 109397A SK 109397 A3 SK109397 A3 SK 109397A3
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Slovakia
Prior art keywords
dibrómformaldoxímkarbamátu
group
compounds
dibromo
products
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SK1093-97A
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Slovak (sk)
Inventor
Adam Chi-Tung Hsu
Barry C Lange
Jemin C Hsu
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Rohm & Haas
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Publication of SK109397A3 publication Critical patent/SK109397A3/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18Nitro compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Slide Fasteners (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paper (AREA)

Description

, Dihalogénformaldoxímkarbamáty ako protimikrobálne činidláDihalogen formaldehyde carbamates as antimicrobial agents

Claims (10)

PATENTOVÉ NÁROKYPATENT CLAIMS 1. Spôsob inhibície rastu mikroorganizmov v, pri alebo na miestach vystavených mikrobálnemu napadnutiu, vyznačujúci sa tým, že sa zavedie do uvedeného miesta protimikrobálne 1 účinné množstvo aspoň jedného protimikrobálneho činidla, pričom takéto protimikrobálne činidlo sa používa v nízkych hladinách použitia, poskytuje veľkú rýchlosť zabíjania, po použití sa rýchlo rozkladá a je bezpečné pri použití pre životné prostredie a toto mikrobálne činidlo má všeobecný vzorec kde X, Y sú nezávisle vybrané z Br, C1 alebo I; a R je (Ci-C8)alkyl, aryl alebo substituovaný aryl.1. A method of inhibiting the growth of micro-organisms on, or in a place subject to microbial attack, characterized in that it is placed in the place of 1 protimikrobálne effective amount of at least one protimikrobálneho agent, wherein such agent is used protimikrobálne at low levels of use, provides a high rate of killing , it degrades rapidly after use and is safe to use in the environment, and the microbial agent has the general formula wherein X, Y are independently selected from Br, Cl or I; and R is (C 1 -C 8) alkyl, aryl or substituted aryl. 2. Spôsob použitia podľa nároku 1, vyznačujúci sa t ý m, že X=Y=Br.Use method according to claim 1, characterized in that X = Y = Br. 3. Spôsob podľa nároku 2, vyznačujúci sa tým, že protimikrobálne činidlo je vybrané zo skupiny, ktorá sa skladá z N-metyl-dibrómformaldoxímkarbamátu; N-(2-chlóretyl)-dibrómformaldoxímkarbamátu;The method of claim 2, wherein the antimicrobial agent is selected from the group consisting of N-methyl-dibromoformaldoxime carbamate; N- (2-chloroethyl) -dibrómformaldoxímkarbamátu; N-(4-chlórfe-nyl)-dibrómformaldoxímkarbamátu;N- (4-chlorophenyl-phenyl) -dibrómformaldoxímkarbamátu; N-(2,4-dichlórfenyl)-dibrómformaldoxímkarbamátu;N- (2,4-dichlorophenyl) -dibrómformaldoxímkarbamátu; l , ,l,, N-etyl-dibrómformaldoxímkarbamátu;N-ethyl-dibrómformaldoxímkarbamátu; N-(n-butyl)-dibrómformaldoxímkarbamátu;N- (n-butyl) -dibrómformaldoxímkarbamátu; N-(n-okty1)-dibróm-formaldoxímkarbamátu;N- (n-okty1) dibromo-formaldoxímkarbamátu; N-(n-hexyl)-dibrómformaldoxímkarbamátu;N- (n-hexyl) -dibrómformaldoxímkarbamátu; a N-(4-metylfenyl)-dibrómformaldoxímkarbamátu;and N- (4-methylphenyl) -dibromoformaldoxime carbamate; 4. Spôsob podľa nároku 1, vyznačujúci sa tým, že miesto je vybrané zo skupiny, ktorú tvoria:The method of claim 1, wherein the site is selected from the group consisting of: chladiace veže, práčky vzduchu, vodné ohrievače, minerálne kaly, reverzná ošetrenie odpadových vôd, okrasné osmotická filtrácia, ultrafiltrácia, fontány, záťažové vody námorných lodí, odparovacie kondenzátory, výmenníky tepla, prevádzkové kvapaliny spracovania buničiny a papierenského priemyslu, plastické hmoty, emulzie a disperzie, náterové hmoty, latexy, povlaky, lazúry, stavebné produkty, konštrukčné lepidlá, priemyselné a spotrebiteľské lepidlá, fotochemikálie, tlačiarenské kvapaliny, produkty pre domácnosť.cooling towers, air scrubbers, water heaters, mineral sludge, reverse waste water treatment, ornamental osmotic filtration, ultrafiltration, fountains, ballast water, evaporative condensers, heat exchangers, pulp and paper processing fluids, plastics, emulsions and dispersions , paints, latexes, coatings, glazes, building products, construction adhesives, industrial and consumer adhesives, photochemicals, printing fluids, household products. kozmetika a toaletné prípravky, šampóny, mydlá, detergenty, priemyselné dezinfekčné alebo sanitárne prostriedky, podlahové leštenia, bielizňové plákacie vody, kovospracovateľské kvapaliny, dopravníkové mazadlá, hydraulické kvapaliny, kože a kožiarske produkty, textílie, textilné produkty, drevo a drevárske produkty, petrolejárske procesné kvapaliny, palivá, kvapaliny pre ťažbu ropy, povrchovo aktívne konzervačné prostriedky, lekárske prostriedky, diagnostické reagenčné konzervačné prostriedky, potravinárske konzervačné prostriedky, bazény a kúpele.cosmetics and toilet preparations, shampoos, soaps, detergents, industrial disinfectants or sanitary products, floor polishing, laundry rinse water, metalworking fluids, conveyor lubricants, hydraulic fluids, leather and leather products, textiles, textile products, wood and wood products, petroleum process liquids, fuels, oil extraction fluids, surface active preservatives, medical devices, diagnostic reagent preservatives, food preservatives, swimming pools and baths. 5. Spôsob podľa nároku 1, vyznačujúci sa tým, že protimikrobálne účinné množstvo je od 0.05 do 10000 ppm, vzhľadom na hmotnosť miesta.The method of claim 1, wherein the antimicrobially effective amount is from 0.05 to 10,000 ppm, based on the weight of the site. 6. Spôsob > podľa nároku 5,vyznačujúci sa tým, že protimikrobálne účinné množstvo je od 0.1 do 5000 ppm, vzhľadom na hmotnosť miesta.The method of claim 5, wherein the antimicrobially effective amount is from 0.1 to 5000 ppm based on the weight of the site. 7. Spôsob podľa nároku 1, vyznačujúci sa tým, že:A method according to claim 1, characterized in that: (a) miesto je vybrané zo skupiny, ktorú tvoria: chladiace veže, práčky vzduchu, vodné ohrievače, minerálne kaly, ošetrenie fontány, reverzná ultrafiltrácia, záťažové odpadových vôd, okrasné osmotická filtrácia, vody námorných lodí.(a) the site is selected from the group consisting of: cooling towers, air scrubbers, water heaters, mineral sludge, fountain treatment, reverse ultrafiltration, sewage treatment, ornamental osmotic filtration, marine water. odparovacie kondenzátory, výmenníky tepla, prevádzkové kvapaliny spracovania buničiny a papierenského priemyslu, plastické hmoty, emulzie a disperzie, náterové hmoty, latexy, a povlaky;evaporating condensers, heat exchangers, pulp and paper processing fluids, plastics, emulsions and dispersions, paints, latexes, and coatings; (b) protimikrobálne účinné množstvo je od 0.1 do 5000 ppm; a tým, že (c) protimikrobálne činidlo je vybrané zo skupiny, ktorá sa skladá z(b) the antimicrobially effective amount is from 0.1 to 5000 ppm; and wherein (c) the antimicrobial agent is selected from the group consisting of N-metyl-dibróm-formaldoxímkarbamátu;N-methyl-dibromo-formaldoxímkarbamátu; N-(2-chlóretyl)-dibróm-formaldoxímkarbamátu;N- (2-chloroethyl) dibromo-formaldoxímkarbamátu; N-(4-chlórfenyl)-dibrómformaldoxímkarbamátu;N- (4-chlorophenyl) -dibrómformaldoxímkarbamátu; N-(2,4-d i chlórfeny1)-dibrómformaldoxímkarbamátu;N- (2,4-dichlorophenyl) -dibromoformaldoxime carbamate; N-etyl-dibrómformaldoxímkarbamátu;N-ethyl-dibrómformaldoxímkarbamátu; N-(n-butyl)-dibrómformaldoxímkarbamátu;N- (n-butyl) -dibrómformaldoxímkarbamátu; N-(n-okty1)-dibrómformaldoxímkarbamátu;N- (n-okty1) -dibrómformaldoxímkarbamátu; N-(n-hexyl)-dibrómformaldoxímkarbamátu;N- (n-hexyl) -dibrómformaldoxímkarbamátu; a N-(4-metylfény1)-dibróm-formaldoxímkarbamátu.and N- (4-methylphenyl) -dibromo-formaldoxime carbamate. 8. Spôsob podľa nároku 1, vyznačujúci sa tým, že ďalej obsahuje druhé protimikrobálne činidlo, vybrané zo skupiny, ktorú tvoria:The method of claim 1, further comprising a second antimicrobial agent selected from the group consisting of: metylénbis(tiokyanát); izotiazolóny; karbamáty;methylene bis (thiocyanate); isothiazolones; carbamates; heterocyklické zlúčeniny; oxidanty; amónne a fosfóniové soli; aldehydy, ketóny a formaldehydové separátory; halogenované aromatické zlúčeniny; halogenované , I alifatické zlúčeniny; alkény; anorganické zlúčeniny; enzýmy; a povrchovo aktívne činidlá.heterocyclic compounds; oxidants; ammonium and phosphonium salts; aldehydes, ketones and formaldehyde separators; halogenated aromatic compounds; halogenated, aliphatic compounds; alkenes; inorganic compounds; enzymes; and surfactants. 9. Spôsob podľa nároku 1, vyznačujúci sa tým, že druhé protimikrobálne činidlo je vybrané zo skupiny, ktorú tvoria:The method of claim 1, wherein the second antimicrobial agent is selected from the group consisting of: 5-chlór-2-metyl-4-izotiazolín-3-ón;5-chloro-2-methyl-4-isothiazolin-3-one; 2-metyl-4-izotiazolίη-3-όη;2-methyl-4-izotiazolίη-3-όη; 2- n-oktyl-4-izotiazolín-3-ón;2-n-octyl-4-isothiazolin-3-one; 4, 5-dichlór-2-n-oktyl-4-izotiazolίη-3-όη;4,5-dichloro-2-n-octyl-4-isothiazol-3-one; 1.2- benzizotiazolín-3-ón; zinkio-2-pyridíntiol-l-oxid; natrio-2-pyridíntiol-l-oxid;1,2-benzisothiazolin-3-one; zinkio-2-pyridine thiol-l-oxide; sodio 2-pyridine thiol-l-oxide; N'-[3,4-dichlórfenyl]-N,N-dimety1-močovina;N '- [3,4-dichlorophenyl] -N, N-dimety1-urea; 3- jódpropargyl-N-butylkarbamát;3-iodopropargyl-N-butylcarbamate; 10,10 '-oxybis-fenoxyarzín;10,10'-oxybis-phenoxyarzine; 2- (tiokyanometyltio)benzotiazol;2- (thiocyanomethylthio) benzothiazole; 3- bróm-l-chlór-5,5-dimetylhydantoín;3-bromo-1-chloro-5,5-dimethylhydantoin; 2.2- dibróm-3-nitrilopropiónamid; pentam-1,5-dial;2,2-dibromo-3-nitrilopropionamide; penta-1,5-dial; a 2-bróm-2-nitro-1,3-propándiol.and 2-bromo-2-nitro-1,3-propanediol. 10. Protimikrobálny prostriedok, vyznačujúci sa t ý m, že sa skladá z (a) protimikrobálneho činidla so všeobecným vzorcom I:10. An antimicrobial composition comprising (a) an antimicrobial agent of formula I: O kde X, Y sú nezávisle vybrané z Br, C1 alebo I; a R je (Ci-Ca)alkyl, aryl alebo substituovaný aryl; a (b) druhého protimikrobálneho činidla, vybraného zo skupiny, ktorú tvoria: metylénbis(tiokyanát);O wherein X, Y are independently selected from Br, Cl or I; and R is (C 1 -C 6) alkyl, aryl or substituted aryl; and (b) a second anti-microbial agent selected from the group consisting of: methylenebis (thiocyanate); * izotiazolóny; karbamáty; heterocyklické zlúčeniny; oxidanty; amónne a fosfóniové soli; aldehydy, ketóny * a formaldehydové separátory; halogenované aromatické* isothiazolones; carbamates; heterocyclic compounds; oxidants; ammonium and phosphonium salts; aldehydes, ketones and formaldehyde separators; halogenated aromatic I . I zlúčeniny; halogenované alifatické Zlúčeniny; alkény; anorganické zlúčeniny; enzýmy; a povrchovo aktívne činidlá.I. I compounds; halogenated aliphatic Compounds; alkenes; inorganic compounds; enzymes; and surfactants.
SK1093-97A 1996-08-14 1997-08-08 Dihaloformaldoxime carbamates as antimicrobial agents SK109397A3 (en)

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US2437996P 1996-08-14 1996-08-14

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SK109397A3 true SK109397A3 (en) 1998-06-03

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JP (1) JPH10279409A (en)
KR (1) KR19980018695A (en)
CN (1) CN1191073A (en)
BR (1) BR9704364A (en)
PL (1) PL321621A1 (en)
SG (1) SG53039A1 (en)
SK (1) SK109397A3 (en)
ZA (1) ZA977083B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3649136B2 (en) * 2001-02-22 2005-05-18 栗田工業株式会社 Slime control method in neutral papermaking process
TWI305554B (en) * 2004-08-11 2009-01-21 Formosa Taffeta Co Ltd Yarns and fabrics having long-lasting mosquito repellent or antibacterial effect and their preparation
KR101230109B1 (en) * 2006-01-25 2013-02-05 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Air filter having antimicrobial property
CA2632160C (en) * 2007-06-21 2011-10-11 Rohm And Haas Company Microbicidal composition comprising n-methyl-1,2-benzisothiazolin-3-one and 2,2-dibromo-3-nitrilopropionamide
JP5643740B2 (en) * 2010-12-27 2014-12-17 ローム アンド ハース カンパニーRohm And Haas Company Stabilized microbicidal composition
CN104397055A (en) * 2014-10-19 2015-03-11 无棣华信石油技术服务有限公司 Oilfield compound type bactericide and preparation method thereof

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Publication number Publication date
JPH10279409A (en) 1998-10-20
CN1191073A (en) 1998-08-26
PL321621A1 (en) 1998-02-16
KR19980018695A (en) 1998-06-05
SG53039A1 (en) 1998-09-28
ZA977083B (en) 1998-04-14
MX9706052A (en) 1998-07-31
BR9704364A (en) 1999-05-11

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