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SG11201912126PA - Molecular sieve SCM-14, a preparation process and use thereof - Google Patents

Molecular sieve SCM-14, a preparation process and use thereof

Info

Publication number
SG11201912126PA
SG11201912126PA SG11201912126PA SG11201912126PA SG11201912126PA SG 11201912126P A SG11201912126P A SG 11201912126PA SG 11201912126P A SG11201912126P A SG 11201912126PA SG 11201912126P A SG11201912126P A SG 11201912126PA SG 11201912126P A SG11201912126P A SG 11201912126PA
Authority
SG
Singapore
Prior art keywords
molecular sieve
preparation process
sieve scm
scm
molecular
Prior art date
Application number
SG11201912126PA
Inventor
Weimin Yang
Zhendong Wang
Yi Luo
Hongmin Sun
Bin Zhang
Original Assignee
China Petroleum & Chem Corp
Shanghai Research Institute Of Petrochemical Technology Sinopec
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum & Chem Corp, Shanghai Research Institute Of Petrochemical Technology Sinopec filed Critical China Petroleum & Chem Corp
Publication of SG11201912126PA publication Critical patent/SG11201912126PA/en

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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/047Germanosilicates; Aluminogermanosilicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/18Synthetic zeolitic molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/86Borosilicates; Aluminoborosilicates
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    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
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    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/031Precipitation
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    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04Mixing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
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    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
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    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
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    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
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    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
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    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/12Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
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    • C07C4/12Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
    • C07C4/14Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
SG11201912126PA 2017-06-13 2017-10-31 Molecular sieve SCM-14, a preparation process and use thereof SG11201912126PA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710440330 2017-06-13
PCT/CN2017/108461 WO2018227849A1 (en) 2017-06-13 2017-10-31 Molecular sieve scm-14, synthesis method therefor and use thereof

Publications (1)

Publication Number Publication Date
SG11201912126PA true SG11201912126PA (en) 2020-01-30

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SG11201912126PA SG11201912126PA (en) 2017-06-13 2017-10-31 Molecular sieve SCM-14, a preparation process and use thereof

Country Status (10)

Country Link
US (1) US11097256B2 (en)
EP (1) EP3640208B1 (en)
JP (1) JP7045401B2 (en)
KR (1) KR102359047B1 (en)
CN (1) CN109081360B (en)
DK (1) DK3640208T3 (en)
ES (1) ES2910830T3 (en)
PT (1) PT3640208T (en)
SG (1) SG11201912126PA (en)
WO (1) WO2018227849A1 (en)

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CN111099612B (en) * 2018-10-25 2021-11-30 中国石油化工股份有限公司 Molecular sieve SCM-23, its synthesis method and use
CN112206807B (en) * 2019-07-09 2023-06-06 中国石油化工股份有限公司 SCM-25 molecular sieve based on silicon and germanium, preparation method and application thereof
CN112520755B (en) * 2019-09-19 2022-07-12 中国石油化工股份有限公司 SCM-28 molecular sieve, and preparation method and application thereof
CN112573535B (en) * 2019-09-29 2022-07-12 中国石油化工股份有限公司 SCM-32 molecular sieve and preparation method and application thereof
CN112707883B (en) * 2019-10-25 2022-07-08 中国石油化工股份有限公司 Preparation method of epsilon-caprolactone
CN113831271B (en) * 2020-06-24 2023-10-31 中国石油化工股份有限公司 Method for preparing caprolactam by catalyzing cyclohexanone oxime gas phase rearrangement
CN114180597B (en) * 2020-09-14 2023-06-06 中国石油化工股份有限公司 SCM-34 molecular sieve and preparation method and application thereof
CN115231584B (en) * 2021-04-22 2023-10-31 中国石油化工股份有限公司 AFI molecular sieve and preparation method and application thereof
CN114426293B (en) * 2020-09-27 2023-09-29 中国石油化工股份有限公司 SCM-35 molecular sieve, preparation method and application thereof
TW202311206A (en) 2021-05-21 2023-03-16 大陸商中國石油化工科技開發有限公司 Method for preparing p-xylene by biomass conversion
CN115368200B (en) * 2021-05-21 2024-03-26 中国石油化工股份有限公司 Method for preparing paraxylene by biomass conversion
CN115385771B (en) * 2021-05-21 2024-05-28 中国石油化工股份有限公司 Preparation method of paraxylene
CN115882163A (en) 2021-09-28 2023-03-31 中国石油化工股份有限公司 Molecular sieve modified diaphragm and preparation method and application thereof
EP4421039A1 (en) * 2021-10-20 2024-08-28 China Petroleum & Chemical Corporation Scm-38 molecular sieve, preparation method therefor, and use thereof

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CN105217651B (en) * 2014-07-03 2017-07-14 中国石油化工股份有限公司 Si-Al molecular sieve SCM 6, its preparation method and use
CN105460953B (en) * 2014-09-09 2017-08-11 中国石油化工股份有限公司 Molecular sieves of SCM 8 and preparation method thereof
KR102680057B1 (en) 2015-06-01 2024-06-28 캘리포니아 인스티튜트 오브 테크놀로지 Novel crystalline germanosilicate material of CIT-13 topology and method for producing the same
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BR102016026121B1 (en) 2015-11-09 2021-09-14 China Petroleum & Chemical Corporation SCM-10 MOLECULAR SIEVE, PROCESS FOR ITS PRODUCTION, COMPOSITION AND USE
ES2650083B1 (en) * 2016-06-16 2018-10-29 Consejo Superior De Investigaciones Científicas (Csic) ITQ-62 MATERIAL, ITS PROCESSING PROCEDURE AND ITS USE
SG11201912140XA (en) 2017-06-13 2020-01-30 China Petroleum & Chem Corp Molecular Sieve SCM-15, A Process of Preparing Same and Use Thereof
CN111099612B (en) 2018-10-25 2021-11-30 中国石油化工股份有限公司 Molecular sieve SCM-23, its synthesis method and use

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EP3640208A4 (en) 2021-03-03
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US20200188892A1 (en) 2020-06-18
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