SG11201912126PA - Molecular sieve SCM-14, a preparation process and use thereof - Google Patents
Molecular sieve SCM-14, a preparation process and use thereofInfo
- Publication number
- SG11201912126PA SG11201912126PA SG11201912126PA SG11201912126PA SG11201912126PA SG 11201912126P A SG11201912126P A SG 11201912126PA SG 11201912126P A SG11201912126P A SG 11201912126PA SG 11201912126P A SG11201912126P A SG 11201912126PA SG 11201912126P A SG11201912126P A SG 11201912126PA
- Authority
- SG
- Singapore
- Prior art keywords
- molecular sieve
- preparation process
- sieve scm
- scm
- molecular
- Prior art date
Links
- 239000002808 molecular sieve Substances 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/047—Germanosilicates; Aluminogermanosilicates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/86—Borosilicates; Aluminoborosilicates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
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- C—CHEMISTRY; METALLURGY
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/007—Borosilicates
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
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- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
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- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
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- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
- C07C4/12—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
- C07C4/14—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene splitting taking place at an aromatic-aliphatic bond
- C07C4/18—Catalytic processes
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- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
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- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
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- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
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- C01P2006/12—Surface area
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- C01P2006/14—Pore volume
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710440330 | 2017-06-13 | ||
PCT/CN2017/108461 WO2018227849A1 (en) | 2017-06-13 | 2017-10-31 | Molecular sieve scm-14, synthesis method therefor and use thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
SG11201912126PA true SG11201912126PA (en) | 2020-01-30 |
Family
ID=64660543
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SG11201912126PA SG11201912126PA (en) | 2017-06-13 | 2017-10-31 | Molecular sieve SCM-14, a preparation process and use thereof |
Country Status (10)
Country | Link |
---|---|
US (1) | US11097256B2 (en) |
EP (1) | EP3640208B1 (en) |
JP (1) | JP7045401B2 (en) |
KR (1) | KR102359047B1 (en) |
CN (1) | CN109081360B (en) |
DK (1) | DK3640208T3 (en) |
ES (1) | ES2910830T3 (en) |
PT (1) | PT3640208T (en) |
SG (1) | SG11201912126PA (en) |
WO (1) | WO2018227849A1 (en) |
Families Citing this family (15)
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SG11201912140XA (en) * | 2017-06-13 | 2020-01-30 | China Petroleum & Chem Corp | Molecular Sieve SCM-15, A Process of Preparing Same and Use Thereof |
CN111099612B (en) * | 2018-10-25 | 2021-11-30 | 中国石油化工股份有限公司 | Molecular sieve SCM-23, its synthesis method and use |
CN112206807B (en) * | 2019-07-09 | 2023-06-06 | 中国石油化工股份有限公司 | SCM-25 molecular sieve based on silicon and germanium, preparation method and application thereof |
CN112520755B (en) * | 2019-09-19 | 2022-07-12 | 中国石油化工股份有限公司 | SCM-28 molecular sieve, and preparation method and application thereof |
CN112573535B (en) * | 2019-09-29 | 2022-07-12 | 中国石油化工股份有限公司 | SCM-32 molecular sieve and preparation method and application thereof |
CN112707883B (en) * | 2019-10-25 | 2022-07-08 | 中国石油化工股份有限公司 | Preparation method of epsilon-caprolactone |
CN113831271B (en) * | 2020-06-24 | 2023-10-31 | 中国石油化工股份有限公司 | Method for preparing caprolactam by catalyzing cyclohexanone oxime gas phase rearrangement |
CN114180597B (en) * | 2020-09-14 | 2023-06-06 | 中国石油化工股份有限公司 | SCM-34 molecular sieve and preparation method and application thereof |
CN115231584B (en) * | 2021-04-22 | 2023-10-31 | 中国石油化工股份有限公司 | AFI molecular sieve and preparation method and application thereof |
CN114426293B (en) * | 2020-09-27 | 2023-09-29 | 中国石油化工股份有限公司 | SCM-35 molecular sieve, preparation method and application thereof |
TW202311206A (en) | 2021-05-21 | 2023-03-16 | 大陸商中國石油化工科技開發有限公司 | Method for preparing p-xylene by biomass conversion |
CN115368200B (en) * | 2021-05-21 | 2024-03-26 | 中国石油化工股份有限公司 | Method for preparing paraxylene by biomass conversion |
CN115385771B (en) * | 2021-05-21 | 2024-05-28 | 中国石油化工股份有限公司 | Preparation method of paraxylene |
CN115882163A (en) | 2021-09-28 | 2023-03-31 | 中国石油化工股份有限公司 | Molecular sieve modified diaphragm and preparation method and application thereof |
EP4421039A1 (en) * | 2021-10-20 | 2024-08-28 | China Petroleum & Chemical Corporation | Scm-38 molecular sieve, preparation method therefor, and use thereof |
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SG11201404057XA (en) | 2012-02-21 | 2014-08-28 | Exxonmobil Chem Patents Inc | Molecular sieve material, its synthesis and use |
CN104445263B (en) * | 2013-09-24 | 2016-02-10 | 中国石油化工股份有限公司 | SCM-3 molecular sieve and preparation method thereof |
CN104445247B (en) * | 2013-09-24 | 2016-06-08 | 中国石油化工股份有限公司 | SCM-4 molecular sieve and preparation method thereof |
CN104445246B (en) * | 2013-09-24 | 2017-01-04 | 中国石油化工股份有限公司 | SCM-5 molecular sieve and preparation method thereof |
CN105217651B (en) * | 2014-07-03 | 2017-07-14 | 中国石油化工股份有限公司 | Si-Al molecular sieve SCM 6, its preparation method and use |
CN105460953B (en) * | 2014-09-09 | 2017-08-11 | 中国石油化工股份有限公司 | Molecular sieves of SCM 8 and preparation method thereof |
KR102680057B1 (en) | 2015-06-01 | 2024-06-28 | 캘리포니아 인스티튜트 오브 테크놀로지 | Novel crystalline germanosilicate material of CIT-13 topology and method for producing the same |
BR102016026128B1 (en) | 2015-11-09 | 2022-10-04 | Shanghai Research Institute Of Petrochemical Technology, Sinopec | SCM-11 MOLECULAR SIEVES, PROCESS FOR THE PRODUCTION OF THE SAME, THEIR USES AND COMPOSITION OF THE MOLECULAR SIEVE |
BR102016026121B1 (en) | 2015-11-09 | 2021-09-14 | China Petroleum & Chemical Corporation | SCM-10 MOLECULAR SIEVE, PROCESS FOR ITS PRODUCTION, COMPOSITION AND USE |
ES2650083B1 (en) * | 2016-06-16 | 2018-10-29 | Consejo Superior De Investigaciones Científicas (Csic) | ITQ-62 MATERIAL, ITS PROCESSING PROCEDURE AND ITS USE |
SG11201912140XA (en) | 2017-06-13 | 2020-01-30 | China Petroleum & Chem Corp | Molecular Sieve SCM-15, A Process of Preparing Same and Use Thereof |
CN111099612B (en) | 2018-10-25 | 2021-11-30 | 中国石油化工股份有限公司 | Molecular sieve SCM-23, its synthesis method and use |
-
2017
- 2017-10-31 SG SG11201912126PA patent/SG11201912126PA/en unknown
- 2017-10-31 JP JP2019568317A patent/JP7045401B2/en active Active
- 2017-10-31 EP EP17913991.0A patent/EP3640208B1/en active Active
- 2017-10-31 CN CN201711060307.0A patent/CN109081360B/en active Active
- 2017-10-31 PT PT179139910T patent/PT3640208T/en unknown
- 2017-10-31 DK DK17913991.0T patent/DK3640208T3/en active
- 2017-10-31 ES ES17913991T patent/ES2910830T3/en active Active
- 2017-10-31 WO PCT/CN2017/108461 patent/WO2018227849A1/en unknown
- 2017-10-31 KR KR1020207001008A patent/KR102359047B1/en active IP Right Grant
- 2017-10-31 US US16/622,806 patent/US11097256B2/en active Active
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WO2018227849A1 (en) | 2018-12-20 |
CN109081360A (en) | 2018-12-25 |
BR112019026294A2 (en) | 2020-06-30 |
KR102359047B1 (en) | 2022-02-08 |
JP2020523272A (en) | 2020-08-06 |
US11097256B2 (en) | 2021-08-24 |
CN109081360B (en) | 2020-10-27 |
KR20200017482A (en) | 2020-02-18 |
PT3640208T (en) | 2022-04-11 |
EP3640208A4 (en) | 2021-03-03 |
DK3640208T3 (en) | 2022-04-11 |
EP3640208B1 (en) | 2022-01-19 |
ES2910830T3 (en) | 2022-05-13 |
US20200188892A1 (en) | 2020-06-18 |
JP7045401B2 (en) | 2022-03-31 |
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