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SG11201610495QA - Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene - Google Patents

Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene

Info

Publication number
SG11201610495QA
SG11201610495QA SG11201610495QA SG11201610495QA SG11201610495QA SG 11201610495Q A SG11201610495Q A SG 11201610495QA SG 11201610495Q A SG11201610495Q A SG 11201610495QA SG 11201610495Q A SG11201610495Q A SG 11201610495QA SG 11201610495Q A SG11201610495Q A SG 11201610495QA
Authority
SG
Singapore
Prior art keywords
oligomerization
octene
hexene
ethylene
produce
Prior art date
Application number
SG11201610495QA
Inventor
Mohammed H Al-Hazmi
Abdullah Alqahtani
Uwe Rosenthal
Bernd H Muller
Normen N Peulecke
Marco Harff
Anina Wohl
Andreas Meiswinkle
Heinz Bolt
Wolfgang Muller
Original Assignee
Sabic Global Technologies Bv
Linde Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sabic Global Technologies Bv, Linde Ag filed Critical Sabic Global Technologies Bv
Publication of SG11201610495QA publication Critical patent/SG11201610495QA/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B01J31/187Amide derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/34Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/30Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/32Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/36Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20Olefin oligomerisation or telomerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62Chromium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22Organic complexes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24Phosphines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SG11201610495QA 2014-07-24 2015-07-22 Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene SG11201610495QA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201462028558P 2014-07-24 2014-07-24
PCT/IB2015/055532 WO2016012948A1 (en) 2014-07-24 2015-07-22 Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene

Publications (1)

Publication Number Publication Date
SG11201610495QA true SG11201610495QA (en) 2017-01-27

Family

ID=54199271

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201610495QA SG11201610495QA (en) 2014-07-24 2015-07-22 Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene

Country Status (14)

Country Link
US (1) US10421064B2 (en)
EP (1) EP3171974B1 (en)
JP (1) JP6598846B2 (en)
KR (1) KR20170035889A (en)
CN (1) CN106573236B (en)
AR (1) AR101298A1 (en)
BR (1) BR112017001004A2 (en)
CA (1) CA2954836C (en)
ES (1) ES2676354T3 (en)
MX (1) MX2017000799A (en)
RU (1) RU2665551C1 (en)
SG (1) SG11201610495QA (en)
TW (1) TWI615380B (en)
WO (1) WO2016012948A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190322965A1 (en) * 2015-12-04 2019-10-24 Sabic Global Technologies B.V. Process for flushing an oligomerization reactor and oligomerization of an olefin
EP3266757B1 (en) * 2016-07-08 2019-12-25 Evonik Operations GmbH Producing at least 1-hexene and octen from ethene
US20200122131A1 (en) * 2016-12-30 2020-04-23 Sabic Global Technologies B.V. Methods of Producing Linear Alpha Olefins
US10407358B2 (en) 2017-03-14 2019-09-10 Saudi Arabian Oil Company Process for ethylene oligomerization to produce alpha-olefins
CN113242764B (en) * 2018-11-12 2023-10-20 沙特基础全球技术有限公司 Ligand for producing 1-octene in chromium-assisted ethylene oligomerization process
EP3880359A1 (en) * 2018-11-12 2021-09-22 SABIC Global Technologies B.V. Ligands for production of 1-hexene in chromium assisted ethylene oligomerization process
WO2020188476A1 (en) 2019-03-19 2020-09-24 Sabic Global Technologies B.V. Ligands for production of 1-octene in chromium assisted ethylene oligomerization process
CN110801864B (en) * 2019-10-23 2022-08-19 迈瑞尔实验设备(上海)有限公司 Ethylene tetramerization catalyst composition and application thereof
CN118804799A (en) 2021-12-23 2024-10-18 Sabic环球技术有限责任公司 For oligomerization reactions catalyst composition

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0016895D0 (en) 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
JP4266827B2 (en) 2001-12-20 2009-05-20 サソル テクノロジー (ピーティーワイ)リミテッド Trimerization and oligomerization of olefins using a chromium-based catalyst
BRPI0317516B1 (en) 2002-12-20 2019-12-17 Sasol Tech Pty Ltd olefin tetramerization
KR100752372B1 (en) * 2006-04-10 2007-08-27 희성엥겔하드주식회사 A catalyst containing zeolite for reducing h2s from the exhaust gas
EP2114967A1 (en) * 2006-12-22 2009-11-11 Shell Internationale Research Maatschappij B.V. Ligands and catalyst systems for the oligomerization of olefinic monomers
JP5456482B2 (en) 2006-12-22 2014-03-26 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ Ligands and their catalytic systems for the catalytic oligomerization of olefinic monomers
CA2583007C (en) 2007-03-29 2015-03-31 Nova Chemicals Corporation Amino phosphine
ES2686594T3 (en) * 2007-05-28 2018-10-18 Sasol Technology (Pty) Limited Two-stage activation of oligomerization catalyst and oligomerization of olefinic compounds in the presence of an oligomerization catalyst thereby activated
MY148675A (en) * 2007-07-11 2013-05-31 Linde Ag Catalyst composition and process for di-, tri-and/or tetramerization of ethylene
JP5462179B2 (en) * 2007-11-28 2014-04-02 リンデ アーゲー Catalyst composition and process for oligomerization of ethylene
ES2371218T3 (en) * 2009-04-09 2011-12-28 Saudi Basic Industries Corporation COMPOSITION OF CATALYST AND PROCEDURE FOR THE OLIGOMERIZATION OF ETHYLENE.
CA2716714C (en) 2010-10-06 2017-05-16 Nova Chemicals Corporation Tetramerization ligands
KR101471156B1 (en) * 2011-06-14 2014-12-10 주식회사 엘지화학 Ethylene oligomerization catalyst systems having enhanced selectivity
KR101846031B1 (en) * 2012-03-16 2018-04-05 에스케이이노베이션 주식회사 Catalyst Systems for Preparing 1-Hexene and/or 1-Octene from Ethylene

Also Published As

Publication number Publication date
CA2954836C (en) 2018-10-09
CN106573236B (en) 2020-05-29
CA2954836A1 (en) 2016-01-28
RU2665551C1 (en) 2018-08-31
ES2676354T3 (en) 2018-07-18
EP3171974B1 (en) 2018-04-18
US20170203288A1 (en) 2017-07-20
TW201619097A (en) 2016-06-01
TWI615380B (en) 2018-02-21
JP2017523908A (en) 2017-08-24
AR101298A1 (en) 2016-12-07
EP3171974A1 (en) 2017-05-31
JP6598846B2 (en) 2019-10-30
KR20170035889A (en) 2017-03-31
BR112017001004A2 (en) 2017-11-14
CN106573236A (en) 2017-04-19
MX2017000799A (en) 2017-05-04
WO2016012948A1 (en) 2016-01-28
US10421064B2 (en) 2019-09-24

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