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SG11201600536WA - Regeneration of a titanium containing zeolite - Google Patents

Regeneration of a titanium containing zeolite

Info

Publication number
SG11201600536WA
SG11201600536WA SG11201600536WA SG11201600536WA SG11201600536WA SG 11201600536W A SG11201600536W A SG 11201600536WA SG 11201600536W A SG11201600536W A SG 11201600536WA SG 11201600536W A SG11201600536W A SG 11201600536WA SG 11201600536W A SG11201600536W A SG 11201600536WA
Authority
SG
Singapore
Prior art keywords
regeneration
containing zeolite
titanium containing
titanium
zeolite
Prior art date
Application number
SG11201600536WA
Inventor
Andrei-Nicolae Parvulescu
Ulrich Müller
Joaquim Henrique Teles
Bianca Seelig
Philip Kampe
Markus Weber
Peter Resch
Christian Bartosch
Dominic Riedel
Daniel Urbanczyk
Alexander Schröder
Ulrike Wegerle
Original Assignee
Basf Se
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Dow Global Technologies Llc filed Critical Basf Se
Publication of SG11201600536WA publication Critical patent/SG11201600536WA/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/7088MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0203Impregnation the impregnation liquid containing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06Washing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/10Heat treatment in the presence of water, e.g. steam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30Ion-exchange
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/02Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/06Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using steam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/04Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10Infrared [IR]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/70Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/70Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77Compounds characterised by their crystallite size
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
SG11201600536WA 2013-07-24 2014-07-16 Regeneration of a titanium containing zeolite SG11201600536WA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13177916 2013-07-24
PCT/EP2014/065256 WO2015010994A1 (en) 2013-07-24 2014-07-16 Regeneration of a titanium containing zeolite

Publications (1)

Publication Number Publication Date
SG11201600536WA true SG11201600536WA (en) 2016-02-26

Family

ID=48832828

Family Applications (2)

Application Number Title Priority Date Filing Date
SG10201803792UA SG10201803792UA (en) 2013-07-24 2014-07-16 Regeneration of a titanium containing zeolite
SG11201600536WA SG11201600536WA (en) 2013-07-24 2014-07-16 Regeneration of a titanium containing zeolite

Family Applications Before (1)

Application Number Title Priority Date Filing Date
SG10201803792UA SG10201803792UA (en) 2013-07-24 2014-07-16 Regeneration of a titanium containing zeolite

Country Status (14)

Country Link
US (1) US9943838B2 (en)
EP (1) EP3024581B1 (en)
JP (1) JP6581577B2 (en)
KR (1) KR102254371B1 (en)
CN (1) CN105579138B (en)
BR (1) BR112016001518B1 (en)
ES (1) ES2970242T3 (en)
HU (1) HUE065342T2 (en)
MX (1) MX2016001031A (en)
MY (1) MY182811A (en)
RU (1) RU2673798C9 (en)
SG (2) SG10201803792UA (en)
WO (1) WO2015010994A1 (en)
ZA (1) ZA201601175B (en)

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WO2016016070A1 (en) * 2014-07-29 2016-02-04 Evonik Degussa Gmbh Process for the epoxidation of an olefin
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US10556801B2 (en) 2015-02-12 2020-02-11 Basf Se Process for the preparation of a dealuminated zeolitic material having the BEA framework structure
ES2877670T3 (en) * 2015-02-13 2021-11-17 Basf Se Regeneration procedure of a titanium zeolite catalyst for the epoxidation of propylene
MY189272A (en) * 2015-02-13 2022-01-31 Dow Global Technologies Llc Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation
CN107735392B (en) 2015-05-04 2021-12-03 巴斯夫欧洲公司 Method for preparing cucumis melo aldehyde
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US10385033B2 (en) 2015-07-22 2019-08-20 Basf Se Process for preparing furan-2,5-dicarboxylic acid
MX2018007405A (en) 2015-12-16 2018-08-15 Basf Se Process for the epoxidation of propene to propylene oxide.
JP2019194283A (en) * 2018-05-01 2019-11-07 旭化成株式会社 Polyelectrolyte solution and polyelectrolyte membrane
US11413605B2 (en) * 2019-08-28 2022-08-16 King Fahd University Of Petroleum And Minerals Molybdenum based catalyst supported on titania-modified zeolite
EP3812375A1 (en) * 2019-10-21 2021-04-28 Evonik Operations GmbH Process for the epoxidation of propene
JP7327758B2 (en) * 2019-10-29 2023-08-16 株式会社ダイセル Method for producing epoxy compound
KR20220157483A (en) * 2020-03-23 2022-11-29 바스프 에스이 Zeolite materials with a framework structure comprising Si, O and Ti
CN113877625B (en) * 2020-07-01 2023-10-31 中国石油化工股份有限公司 Method for regenerating molecular sieve catalyst and application thereof
CN114425456B (en) * 2020-10-09 2023-10-31 中国石油化工股份有限公司 Regeneration method and application of olefin reduction catalyst
CN113333033B (en) * 2021-04-13 2024-10-22 青岛科技大学 Regeneration method and application of supported ketoamine reduction alkylation catalyst
CN113333034B (en) * 2021-04-13 2024-10-11 青岛科技大学 Regeneration method and application of chloronitroaromatic hydrocarbon selective hydrogenation catalyst
CN115196652A (en) * 2022-08-04 2022-10-18 南京工业大学 Titanium-containing zeolite nanosheet for olefin oxidation and preparation method thereof
CN115448323B (en) * 2022-10-26 2024-02-20 河北农业大学 Tin-silicon molecular sieve and preparation method and application thereof
WO2024115737A1 (en) 2022-12-02 2024-06-06 Basf Se Process for regeneration of an epoxidation reactor
CN116174031B (en) * 2023-02-15 2024-08-06 四川九天五洋新材料有限责任公司 Catalyst and preparation method and application thereof

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Also Published As

Publication number Publication date
WO2015010994A1 (en) 2015-01-29
MX2016001031A (en) 2016-11-10
JP6581577B2 (en) 2019-09-25
RU2673798C9 (en) 2019-04-08
EP3024581B1 (en) 2023-11-15
MY182811A (en) 2021-02-05
RU2673798C2 (en) 2018-11-30
BR112016001518B1 (en) 2020-12-29
ES2970242T3 (en) 2024-05-27
EP3024581A1 (en) 2016-06-01
SG10201803792UA (en) 2018-06-28
CN105579138A (en) 2016-05-11
ZA201601175B (en) 2023-09-27
RU2016105804A (en) 2017-08-28
HUE065342T2 (en) 2024-05-28
JP2016525446A (en) 2016-08-25
RU2016105804A3 (en) 2018-05-08
CN105579138B (en) 2019-07-05
KR20160039223A (en) 2016-04-08
US20160332152A1 (en) 2016-11-17
US9943838B2 (en) 2018-04-17
BR112016001518A2 (en) 2019-12-17
KR102254371B1 (en) 2021-05-24

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