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SG10201810745YA - A hydroprocessing catalyst composition containing a heterocyclic polar compound, a method of making such a catalyst, and a process of using such catalyst - Google Patents

A hydroprocessing catalyst composition containing a heterocyclic polar compound, a method of making such a catalyst, and a process of using such catalyst

Info

Publication number
SG10201810745YA
SG10201810745YA SG10201810745YA SG10201810745YA SG10201810745YA SG 10201810745Y A SG10201810745Y A SG 10201810745YA SG 10201810745Y A SG10201810745Y A SG 10201810745YA SG 10201810745Y A SG10201810745Y A SG 10201810745YA SG 10201810745Y A SG10201810745Y A SG 10201810745YA
Authority
SG
Singapore
Prior art keywords
catalyst
hydroprocessing
making
composition containing
heterocyclic
Prior art date
Application number
SG10201810745YA
Inventor
John Anthony Smegal
Alexei Grigorievich Gabrielov
Ed Ganja
Theofiel Meuris
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of SG10201810745YA publication Critical patent/SG10201810745YA/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0209—Esters of carboxylic or carbonic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0245—Nitrogen containing compounds being derivatives of carboxylic or carbonic acids
    • B01J31/0247—Imides, amides or imidates (R-C=NR(OR))
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

A HYDROPROCESSING CATALYST COMPOSITION CONTAINING A HETEROCYCLIC POLAR COMPOUND, A METHOD OF MAKING SUCH A CATALYST, AND A PROCESS OF USING SUCH CATALYST A composition that comprises a support material having incorporated therein a metal component and impregnated with an additive compound that is selected from the group of heterocyclic, polar compounds of the formula CxHnNyOz; wherein: x is an integer of at least 3; y is either 0, 1, 2, or 3; z is either 0, 1, 2, or 3; and n is the number of hydrogen atoms required to fill the remaining bonds with the carbon atoms of the molecule. The composition includes the support material that is impregnated with the additive compound and is useful in the hydroprocessing of hydrocarbon feedstocks, especially in the denitrogenation and desulfurization of distillate feedstocks to make ultra low sulfur diesel. (Figure 1)
SG10201810745YA 2013-05-31 2014-05-29 A hydroprocessing catalyst composition containing a heterocyclic polar compound, a method of making such a catalyst, and a process of using such catalyst SG10201810745YA (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201361829689P 2013-05-31 2013-05-31

Publications (1)

Publication Number Publication Date
SG10201810745YA true SG10201810745YA (en) 2019-01-30

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SG10201810745YA SG10201810745YA (en) 2013-05-31 2014-05-29 A hydroprocessing catalyst composition containing a heterocyclic polar compound, a method of making such a catalyst, and a process of using such catalyst
SG11201509604QA SG11201509604QA (en) 2013-05-31 2014-05-29 A hydroprocessing catalyst composition containing a heterocyclic polar compound, a method of making such a catalyst, and a process of using such catalyst

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Country Status (10)

Country Link
US (1) US11325108B2 (en)
EP (1) EP3003554B1 (en)
KR (1) KR102297213B1 (en)
CN (1) CN105228745B (en)
BR (1) BR112015029993B1 (en)
CA (1) CA2912544C (en)
RU (1) RU2673891C2 (en)
SG (2) SG10201810745YA (en)
TW (1) TWI629100B (en)
WO (1) WO2014194033A1 (en)

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FR3035601B1 (en) * 2015-04-30 2017-04-21 Ifp Energies Now A CATALYST BASED ON Y-VALEROLACTONE AND / OR ITS HYDROLYSIS PRODUCTS AND ITS USE IN A HYDROTREATMENT AND / OR HYDROCRACKING PROCESS
FR3050659B1 (en) 2016-04-29 2021-09-03 Ifp Energies Now COBALT CATALYST BASED ON A SUPPORT CONTAINING A MIXED OXIDE PHASE CONTAINING COBALT AND / OR NICKEL PREPARED BY THE USE OF AN ESTER COMPOUND
FR3050660B1 (en) 2016-04-29 2021-09-03 Ifp Energies Now COBALT CATALYST BASED ON A SUPPORT CONTAINING A MIXED OXIDE PHASE CONTAINING COBALT AND / OR NICKEL PREPARED BY THE USE OF A COMPONENT CONTAINING TWO CARBOXYL ACID FUNTIONS AND AT LEAST THREE CARBON ATOMS
FR3054554B1 (en) 2016-07-28 2018-07-27 IFP Energies Nouvelles CATALYST BASED ON 2-ACETYLBUTYROLACTONE AND / OR ITS HYDROLYSIS PRODUCTS AND USE THEREOF IN A HYDROTREATMENT AND / OR HYDROCRACKING PROCESS
CA3033204A1 (en) * 2016-08-23 2018-03-01 Shell Internationale Research Maatschappij B.V. A polar additive-containing hydroprocessing catalyst, its preparation and use
FR3057472B1 (en) 2016-10-17 2018-11-16 IFP Energies Nouvelles COBALT CATALYST BASED ON A SUPPORT CONTAINING A MIXED OXIDE PHASE CONTAINING COBALT AND / OR NICKEL PREPARED BY USING A HYDROGENOCARBON COMPOUND
FR3073753B1 (en) 2017-11-22 2022-03-11 Ifp Energies Now CATALYST BASED ON A FURANIC COMPOUND AND ITS USE IN A HYDROTREATMENT AND/OR HYDROCRACKING PROCESS
FR3083137A1 (en) 2018-06-27 2020-01-03 IFP Energies Nouvelles CATALYST BASED ON A BETA-SUBSTITUTED ESTER AND ITS USE IN A HYDROTREATMENT AND / OR HYDROCRACKING PROCESS
FR3083140B1 (en) 2018-06-27 2020-06-05 IFP Energies Nouvelles CATALYST BASED ON A C5 OR C6 ACID ESTER AND ITS USE IN A HYDROPROCESSING AND / OR HYDROCRACKING PROCESS
FR3083130B1 (en) 2018-06-27 2022-11-04 Ifp Energies Now CATALYST BASED ON AN ALKYL LACTATE AND ITS USE IN A HYDROTREATING AND/OR HYDROCRACKING PROCESS
FR3083138A1 (en) 2018-06-27 2020-01-03 IFP Energies Nouvelles CATALYST BASED ON ASCORBIC ACID DERIVATIVES AND ITS USE IN A HYDROPROCESSING AND / OR HYDROCRACKING PROCESS
FR3083133A1 (en) 2018-06-27 2020-01-03 IFP Energies Nouvelles CATALYST BASED ON A BETA-OXYGEN ESTER AND ITS USE IN A HYDROPROCESSING AND / OR HYDROCRACKING PROCESS
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FR3087673B1 (en) * 2018-10-25 2022-12-02 Ifp Energies Now COBALT CATALYST BASED ON A SUPPORT COMPRISING A MIXED OXIDE PHASE CONTAINING COBALT AND/OR NICKEL PREPARED FROM A DILACTONE COMPOUND
FR3105931A1 (en) 2020-01-06 2021-07-09 IFP Energies Nouvelles CATALYST BASED ON 2-HYDROXY-BUTANEDIOIC ACID OR 2-HYDROXY-BUTANEDIOIC ACID ESTERS AND ITS USE IN A HYDROTREATMENT AND / OR HYDROCRACKING PROCESS
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MX2022003972A (en) * 2022-03-31 2023-10-02 Mexicano Inst Petrol Process for the activation and start-up of deep hydrodesulfurization catalysts of intermediate distillates.

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Also Published As

Publication number Publication date
US11325108B2 (en) 2022-05-10
EP3003554A1 (en) 2016-04-13
SG11201509604QA (en) 2015-12-30
RU2015156054A3 (en) 2018-04-25
WO2014194033A1 (en) 2014-12-04
CN105228745A (en) 2016-01-06
US20140353213A1 (en) 2014-12-04
RU2673891C2 (en) 2018-12-03
EP3003554B1 (en) 2022-04-06
BR112015029993A2 (en) 2017-07-25
KR20160016783A (en) 2016-02-15
KR102297213B1 (en) 2021-09-02
CA2912544C (en) 2021-11-02
RU2015156054A (en) 2017-07-06
CN105228745B (en) 2018-08-07
CA2912544A1 (en) 2014-12-04
TW201501792A (en) 2015-01-16
TWI629100B (en) 2018-07-11
BR112015029993B1 (en) 2021-08-31

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