SE427269B - Forfarande for framstellning av dimetyleter genom omsettning av co och h?712 i nervaro av en katalysator, som stabiliserats med kiselforeningar - Google Patents

Forfarande for framstellning av dimetyleter genom omsettning av co och h?712 i nervaro av en katalysator, som stabiliserats med kiselforeningar

Info

Publication number: SE427269B
Authority: SE; Sweden
Prior art keywords: catalyst; reaction; selectivity; silicon compounds; stabilized
Prior art date: 1976-12-23

Application number

SE7714703A

Other languages

English (en)

Swedish (sv)

Inventor

G Manara

B Notari

V Fattore

Original Assignee

Snam Progetti

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-12-23

Filing date

1977-12-22

Publication date

1983-03-21

1977-12-22 Application filed by Snam Progetti filed Critical Snam Progetti

1983-03-21 Publication of SE427269B publication Critical patent/SE427269B/sv

Links

239000003054 catalyst Substances 0.000 title claims description 50
238000000034 method Methods 0.000 title claims description 11
150000003377 silicon compounds Chemical class 0.000 title claims description 9
238000002360 preparation method Methods 0.000 title claims description 5
229910052739 hydrogen Inorganic materials 0.000 title description 6
229910002091 carbon monoxide Inorganic materials 0.000 title description 3
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 35
238000006243 chemical reaction Methods 0.000 claims description 35
229910052751 metal Inorganic materials 0.000 claims description 10
239000002184 metal Substances 0.000 claims description 10
150000003839 salts Chemical class 0.000 claims description 7
229910044991 metal oxide Inorganic materials 0.000 claims description 6
150000004706 metal oxides Chemical class 0.000 claims description 6
239000011541 reaction mixture Substances 0.000 claims description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 23
239000000203 mixture Substances 0.000 description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
229940077445 dimethyl ether Drugs 0.000 description 10
239000011651 chromium Chemical class 0.000 description 8
239000010949 copper Substances 0.000 description 8
239000011701 zinc Substances 0.000 description 8
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
229910052782 aluminium Inorganic materials 0.000 description 6
239000002244 precipitate Substances 0.000 description 6
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 5
239000000243 solution Substances 0.000 description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
229910052804 chromium Inorganic materials 0.000 description 4
229910052802 copper Inorganic materials 0.000 description 4
239000001257 hydrogen Substances 0.000 description 4
230000007774 longterm Effects 0.000 description 4
150000002739 metals Chemical class 0.000 description 4
229910052725 zinc Inorganic materials 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
239000007789 gas Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
150000001242 acetic acid derivatives Chemical class 0.000 description 2
238000000889 atomisation Methods 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
238000001816 cooling Methods 0.000 description 2
238000010908 decantation Methods 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
238000002156 mixing Methods 0.000 description 2
150000002823 nitrates Chemical class 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
238000004064 recycling Methods 0.000 description 2
238000000926 separation method Methods 0.000 description 2
230000000087 stabilizing effect Effects 0.000 description 2
239000007858 starting material Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical class [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
125000005037 alkyl phenyl group Chemical group 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000007596 consolidation process Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
230000007423 decrease Effects 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
238000010304 firing Methods 0.000 description 1
-1 for example Chemical class 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000009434 installation Methods 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical class [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
239000000463 material Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
125000004351 phenylcyclohexyl group Chemical group C1(=CC=CC=C1)C1(CCCCC1)* 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000033764 rhythmic process Effects 0.000 description 1
238000005070 sampling Methods 0.000 description 1
239000013049 sediment Substances 0.000 description 1
239000005049 silicon tetrachloride Substances 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/506—Method of making inorganic composition utilizing organic compound, except formic, acetic, or oxalic acid or salt thereof

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

SE7714703A 1976-12-23 1977-12-22 Forfarande for framstellning av dimetyleter genom omsettning av co och h?712 i nervaro av en katalysator, som stabiliserats med kiselforeningar SE427269B (sv)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT30800/76A IT1065295B (it)	1976-12-23	1976-12-23	Processo per la produzione di dimetil etere e catalizzatore utilizzabile in detto processo

Publications (1)

Publication Number	Publication Date
SE427269B true SE427269B (sv)	1983-03-21

Family

ID=11232134

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE7714703A SE427269B (sv)	1976-12-23	1977-12-22	Forfarande for framstellning av dimetyleter genom omsettning av co och h?712 i nervaro av en katalysator, som stabiliserats med kiselforeningar

Country Status (37)

Country	Link
US (1)	US4177167A (nl)
JP (1)	JPS5379811A (nl)
AR (1)	AR227123A1 (nl)
AT (1)	AT360498B (nl)
AU (1)	AU517513B2 (nl)
BE (1)	BE862289A (nl)
BR (1)	BR7708470A (nl)
CA (1)	CA1119147A (nl)
CH (1)	CH629682A5 (nl)
CS (1)	CS219336B2 (nl)
DD (1)	DD133662A5 (nl)
DE (1)	DE2757788C3 (nl)
DK (1)	DK572277A (nl)
EG (1)	EG14145A (nl)
ES (1)	ES466012A1 (nl)
FR (1)	FR2375175A1 (nl)
GB (2)	GB1587629A (nl)
GR (1)	GR63609B (nl)
HU (1)	HU178729B (nl)
IE (1)	IE45952B1 (nl)
IL (1)	IL53564A (nl)
IT (1)	IT1065295B (nl)
LU (1)	LU78753A1 (nl)
MW (1)	MW2977A1 (nl)
MX (1)	MX147734A (nl)
NL (1)	NL7714215A (nl)
NO (1)	NO146861C (nl)
PH (1)	PH13798A (nl)
PL (2)	PL110957B1 (nl)
PT (1)	PT67435B (nl)
RO (1)	RO81244B (nl)
SE (1)	SE427269B (nl)
SU (1)	SU913935A3 (nl)
TR (1)	TR19408A (nl)
YU (1)	YU39229B (nl)
ZA (1)	ZA777209B (nl)
ZM (1)	ZM9377A1 (nl)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS57130547A (en) *	1981-02-06	1982-08-13	Mitsubishi Gas Chem Co Inc	Catalyst for methanol synthesis
US4423155A (en) *	1981-02-20	1983-12-27	Mobil Oil Corporation	Dimethyl ether synthesis catalyst
US4375424A (en) *	1981-10-21	1983-03-01	Shell Oil Company	Catalyst for the preparation of dimethyl ether
US4507401A (en) *	1983-04-01	1985-03-26	At&T Bell Laboratories	Intermetallic catalyst preparation
US4521540A (en) *	1984-03-22	1985-06-04	Air Products And Chemicals, Inc.	Process for producing dimethyl ether form synthesis gas
US4590176A (en) *	1984-06-05	1986-05-20	Shell Oil Company	Catalyst for dimethyl ether synthesis and a process for its preparation
US4885405A (en) *	1987-12-10	1989-12-05	Horst Dornhagen	Process for the production of pure dimethylether and a catalyst used in the process
ATE83475T1 (de) *	1988-05-04	1993-01-15	Rwe Dea Ag	Verbessertes verfahren zur herstellung von reinem dimethylether.
GB8824382D0 (en) *	1988-10-18	1988-11-23	British Petroleum Co Plc	Chemical process & catalyst therefor
US5106810A (en) *	1989-06-29	1992-04-21	E. I. Du Pont De Nemours And Company	Methanol dissociation catalysts
DE3938835A1 (de) *	1989-11-23	1991-05-29	Sued Chemie Ag	Verfahren zur oxidation von organischen verunreinigungen in abwaessern
US5831116A (en) *	1996-12-18	1998-11-03	Northeastern University	Catalytic process for making ethers, aldehydes esters and acids from alcohols using a supercritical fluid mobile
US5753716A (en) *	1997-02-21	1998-05-19	Air Products And Chemicals, Inc.	Use of aluminum phosphate as the dehydration catalyst in single step dimethyl ether process
JP3232326B2 (ja) *	1997-03-11	2001-11-26	経済産業省産業技術総合研究所長	銅系触媒およびその製造法
DK173614B1 (da)	1999-02-02	2001-04-30	Topsoe Haldor As	Fremgangsmåde til fremstilling af methanol/dimethyletherblanding fra syntesegas
KR100812099B1 (ko) *	2006-11-28	2008-03-12	한국가스공사	디메틸에테르 제조용 혼합촉매, 이의 제조방법 및 이를 이용한 디메틸에테르 제조방법
FR2909666B1 (fr) *	2006-12-08	2009-03-06	Centre Nat Rech Scient	Deshydratation du methanol en dimethyl ether employant des catalyseurs a base d'une zeolithe supportee sur du carbure de silicium
JP5592250B2 (ja) *	2007-04-27	2014-09-17	サウディベーシックインダストリーズコーポレイション	二酸化炭素の合成ガスへの接触水素化
EP2072491A1 (en)	2007-12-17	2009-06-24	BP p.l.c.	Process for the conversion of alcohol(s) into alcohol(s) with increased carbon-chain
EP2072492A1 (en)	2007-12-17	2009-06-24	BP p.l.c.	Process for the conversion of hydrocarbons to ethanol
EP2072486A1 (en)	2007-12-17	2009-06-24	BP p.l.c.	Process for the conversion of hydrocarbons to ethanol
CA3104271A1 (en) *	2018-06-29	2020-01-02	Dow Global Technologies Llc	Hybrid catalysts comprising a zeolite and a mixed metal oxide component for converting syngas into c2 and c3 olefins
US11446642B2 (en)	2018-06-29	2022-09-20	Dow Global Technologies Llc	Hybrid catalysts comprising a mixed metal oxide component for production of C2 and C3 hydrocarbons
CN111250098B (zh) *	2020-03-11	2023-03-31	上海兖矿能源科技研发有限公司	一种用于费托合成反应水加氢催化剂及其制备方法和应用

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Publication number	Priority date	Publication date	Assignee	Title
US2852473A (en) *	1955-06-08	1958-09-16	Grace W R & Co	Method of preparing alumina and hydroforming catalyst thereon
US3502595A (en) *	1965-10-28	1970-03-24	Sinclair Research Inc	Preparation of silica-alumina,titania-alumina,and phosphorous oxide-alumina catalysts
US3770618A (en) *	1967-06-26	1973-11-06	Exxon Research Engineering Co	Hydrodesulfurization of residua
US3840477A (en) *	1972-08-03	1974-10-08	Nalco Chemical Co	Hydrotreating catalyst
US3944503A (en) *	1972-12-22	1976-03-16	Exxon Research & Engineering Co.	Catalyst for conversion of heavy hydrocarbon oils
US3941819A (en) *	1973-12-14	1976-03-02	Exxon Research And Engineering Company	Catalytic formation of hydrocarbons from CO hydrogen mixtures

1976
- 1976-12-23 IT IT30800/76A patent/IT1065295B/it active
1977
- 1977-12-02 GR GR54908A patent/GR63609B/el unknown
- 1977-12-05 AU AU31201/77A patent/AU517513B2/en not_active Expired
- 1977-12-05 ZA ZA00777209A patent/ZA777209B/xx unknown
- 1977-12-07 IL IL53564A patent/IL53564A/xx unknown
- 1977-12-08 CA CA000292649A patent/CA1119147A/en not_active Expired
- 1977-12-14 CH CH1538577A patent/CH629682A5/it not_active IP Right Cessation
- 1977-12-15 MX MX171741A patent/MX147734A/es unknown
- 1977-12-15 MW MW29/77A patent/MW2977A1/xx unknown
- 1977-12-16 AR AR270404A patent/AR227123A1/es active
- 1977-12-19 GB GB52815/77A patent/GB1587629A/en not_active Expired
- 1977-12-19 BR BR7708470A patent/BR7708470A/pt unknown
- 1977-12-19 GB GB34587/79A patent/GB1587630A/en not_active Expired
- 1977-12-19 RO RO92530A patent/RO81244B/ro unknown
- 1977-12-20 IE IE2582/77A patent/IE45952B1/en unknown
- 1977-12-20 TR TR19408A patent/TR19408A/xx unknown
- 1977-12-20 CS CS778596A patent/CS219336B2/cs unknown
- 1977-12-20 US US05/862,575 patent/US4177167A/en not_active Expired - Lifetime
- 1977-12-20 ZM ZM93/77A patent/ZM9377A1/xx unknown
- 1977-12-21 EG EG710/77A patent/EG14145A/xx active
- 1977-12-21 DD DD7700202852A patent/DD133662A5/xx unknown
- 1977-12-21 NL NL7714215A patent/NL7714215A/nl active Search and Examination
- 1977-12-21 PH PH20582A patent/PH13798A/en unknown
- 1977-12-21 DK DK572277A patent/DK572277A/da not_active Application Discontinuation
- 1977-12-21 PT PT67435A patent/PT67435B/pt unknown
- 1977-12-21 NO NO774404A patent/NO146861C/no unknown
- 1977-12-22 PL PL1977211562A patent/PL110957B1/pl unknown
- 1977-12-22 SU SU772556955A patent/SU913935A3/ru active
- 1977-12-22 HU HU77SA3084A patent/HU178729B/hu unknown
- 1977-12-22 LU LU78753A patent/LU78753A1/xx unknown
- 1977-12-22 PL PL1977203247A patent/PL110505B1/pl unknown
- 1977-12-22 SE SE7714703A patent/SE427269B/sv not_active IP Right Cessation
- 1977-12-22 FR FR7738886A patent/FR2375175A1/fr active Granted
- 1977-12-22 AT AT923177A patent/AT360498B/de not_active IP Right Cessation
- 1977-12-23 DE DE2757788A patent/DE2757788C3/de not_active Expired
- 1977-12-23 BE BE183817A patent/BE862289A/xx not_active IP Right Cessation
- 1977-12-23 YU YU03069/77A patent/YU39229B/xx unknown
- 1977-12-23 ES ES466012A patent/ES466012A1/es not_active Expired
- 1977-12-23 JP JP15460877A patent/JPS5379811A/ja active Granted

Also Published As

Publication number	Publication date
IL53564A (en)	1982-07-30
GB1587629A (en)	1981-04-08
PL110957B1 (en)	1980-08-30
NO146861C (no)	1982-12-22
DE2757788A1 (de)	1978-06-29
MX147734A (es)	1983-01-10
TR19408A (tr)	1979-03-01
NL7714215A (nl)	1978-06-27
EG14145A (en)	1983-09-30
IE45952B1 (en)	1983-01-12
PL203247A1 (pl)	1978-07-31
IT1065295B (it)	1985-02-25
DK572277A (da)	1978-06-24
DE2757788C3 (de)	1980-02-14
MW2977A1 (en)	1978-08-09
GB1587630A (en)	1981-04-08
YU306977A (en)	1982-10-31
AU517513B2 (en)	1981-08-06
PT67435A (en)	1978-01-01
AU3120177A (en)	1979-06-14
IE45952L (en)	1978-06-23
NO146861B (no)	1982-09-13
HU178729B (en)	1982-06-28
RO81244B (ro)	1983-02-28
NO774404L (no)	1978-06-26
US4177167A (en)	1979-12-04
DE2757788B2 (de)	1979-06-21
PH13798A (en)	1980-10-01
SU913935A3 (en)	1982-03-15
ZM9377A1 (en)	1979-11-21
IL53564A0 (en)	1978-03-10
LU78753A1 (nl)	1978-04-17
BE862289A (fr)	1978-06-23
ATA923177A (de)	1980-06-15
FR2375175B1 (nl)	1980-06-06
BR7708470A (pt)	1978-08-08
FR2375175A1 (fr)	1978-07-21
GR63609B (en)	1979-11-26
JPS6143332B2 (nl)	1986-09-26
YU39229B (en)	1984-08-31
RO81244A (ro)	1983-02-15
AT360498B (de)	1981-01-12
ZA777209B (en)	1978-10-25
ES466012A1 (es)	1978-10-01
PT67435B (en)	1979-05-23
CS219336B2 (en)	1983-03-25
DD133662A5 (de)	1979-01-17
CA1119147A (en)	1982-03-02
AR227123A1 (es)	1982-09-30
PL110505B1 (en)	1980-07-31
JPS5379811A (en)	1978-07-14
CH629682A5 (it)	1982-05-14

Publication	Publication Date	Title
SE427269B (sv)	1983-03-21	Forfarande for framstellning av dimetyleter genom omsettning av co och h?712 i nervaro av en katalysator, som stabiliserats med kiselforeningar
SU1731040A3 (ru)	1992-04-30	Способ получени алифатических спиртов С @ -С @ и катализатор дл его осуществлени
US4149009A (en)	1979-04-10	Process for producing methyl formate
US6071433A (en)	2000-06-06	Method of hydrocarbon reforming and catalyst precursor
KR20010049394A (ko)	2001-06-15	복합 산화물 촉매 및 (메트)아크롤레인과(메트)아크릴산의 제조 방법
US5728894A (en)	1998-03-17	Method for producing methacrolein
US3961037A (en)	1976-06-01	Process for forming hydrogen and carbon dioxide using a catalyst consisting essentially of oxides of copper, zinc and aluminum or magnesium
US4319037A (en)	1982-03-09	Process for producing methyl formate
EP0548679A1 (en)	1993-06-30	Process for the preparation of synthetic gases
US5508246A (en)	1996-04-16	Catalysts for iso-alcohol synthesis from CO+H2
US3546140A (en)	1970-12-08	Low temperature shift reactions
US4210597A (en)	1980-07-01	Preparation of oxygenates from carbon monoxide and hydrogen
US4843101A (en)	1989-06-27	Catalyst and method for producing methanol
CA1182797A (en)	1985-02-19	Dimethylether production process
US4994498A (en)	1991-02-19	Tantalum-containing catalyst useful for producing alcohols from synthesis gas
US4272410A (en)	1981-06-09	Catalyst for preparation of oxygenates from carbon monoxide and hydrogen
US3968166A (en)	1976-07-06	Catalytic process for the preparation of acrolein
US4943551A (en)	1990-07-24	Catalyst for synthesis of mixtures of methanol and higher alcohols
US4826798A (en)	1989-05-02	Carbon dioxide calcination of methanol dissociation catalysts
US5021233A (en)	1991-06-04	Water gas shift reaction with alkali-doped catalyst
US5102845A (en)	1992-04-07	Tantalum-containing catalyst useful for producing alcohols from synthesis gas
US4238371A (en)	1980-12-09	Methanation catalyst
GB2121412A (en)	1983-12-21	Process for preparing alcohols
KR800001030B1 (ko)	1980-09-26	디메틸 에테르의 제조방법
EP0180933A2 (en)	1986-05-14	Process for preparing oxygen-containing organic compounds

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