RU98116373A - Способ уменьшения общего кислотного числа сырой нефти - Google Patents
Способ уменьшения общего кислотного числа сырой нефтиInfo
- Publication number
- RU98116373A RU98116373A RU98116373/04A RU98116373A RU98116373A RU 98116373 A RU98116373 A RU 98116373A RU 98116373/04 A RU98116373/04 A RU 98116373/04A RU 98116373 A RU98116373 A RU 98116373A RU 98116373 A RU98116373 A RU 98116373A
- Authority
- RU
- Russia
- Prior art keywords
- hydrogen
- reducing
- crude oil
- acid number
- total acid
- Prior art date
Links
- 239000002253 acid Substances 0.000 title claims 2
- 239000003054 catalyst Substances 0.000 claims 3
- 239000010779 crude oil Substances 0.000 claims 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims 3
- 239000007789 gas Substances 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims 3
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims 3
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 239000000969 carrier Substances 0.000 claims 2
- 229910000428 cobalt oxide Inorganic materials 0.000 claims 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 230000002378 acidificating Effects 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims 1
- 239000003870 refractory metal Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 1
- 229910001929 titanium oxide Inorganic materials 0.000 claims 1
- 229910001930 tungsten oxide Inorganic materials 0.000 claims 1
Claims (9)
1. Способ уменьшения общего кислотного числа кислой сырой нефти, включающий контактирование сырой нефти с катализатором гидроочистки при температуре примерно 200 - 370°С в присутствии водородсодержащего обрабатывающего газа, содержащего сероводород, при общем давлении примерно 239 - 13900 кПа и мольном содержании сероводорода в обрабатывающем газе 0,05 - 25.
2. Способ по п. 1, в котором катализатором является оксид кобальта/молибдена, оксид никеля/молибдена или оксид никеля/вольфрама на тугоплавком носителе металла.
3. Способ по п.2, в котором тугоплавкий носитель включает оксид кремния, оксид алюминия, оксид титана или их смеси.
4. Способ по п.1, в котором температура составляет 232 - 316°С.
5. Способ по п.1, в котором парциальное давление водорода составляет 446 - 3550 кПа.
6. Способ по п.1, в котором часовая объемная скорость жидкости составляет 0,1 - 10.
7. Способ по п.1, в котором соотношение потоков водород : сырая нефть составляет 5,34 - 266,98 (30 - 1500 scf/В).
8. Способ по п. 1, в котором количество сероводорода в обрабатывающем газе составляет 1 - 15% мольн.
9. Способ по п. 1, в котором катализатором является оксид кобальта/молибдена на носителе из оксида алюминия.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US920,701 | 1992-07-28 | ||
| US08/920,701 US5910242A (en) | 1997-08-29 | 1997-08-29 | Process for reduction of total acid number in crude oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU98116373A true RU98116373A (ru) | 2000-05-20 |
| RU2178450C2 RU2178450C2 (ru) | 2002-01-20 |
Family
ID=25444242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU98116373/04A RU2178450C2 (ru) | 1997-08-29 | 1998-08-27 | Способ уменьшения общего кислотного числа сырой нефти |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5910242A (ru) |
| EP (1) | EP0899319B1 (ru) |
| JP (1) | JP4077948B2 (ru) |
| CA (1) | CA2242394C (ru) |
| DE (1) | DE69818770T2 (ru) |
| MY (1) | MY116198A (ru) |
| NO (1) | NO317451B1 (ru) |
| RU (1) | RU2178450C2 (ru) |
| SG (1) | SG67533A1 (ru) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6673238B2 (en) * | 2001-11-08 | 2004-01-06 | Conocophillips Company | Acidic petroleum oil treatment |
| US20100098602A1 (en) * | 2003-12-19 | 2010-04-22 | Opinder Kishan Bhan | Systems, methods, and catalysts for producing a crude product |
| BRPI0405565A (pt) * | 2003-12-19 | 2005-08-30 | Shell Int Research | Métodos de produzir um produto de petróleo bruto e combustìvel de transporte, combustìvel de aquecimento, lubrificantes ou substâncias quìmicas, e, produto de petróleo bruto |
| US8025791B2 (en) | 2003-12-19 | 2011-09-27 | Shell Oil Company | Systems and methods of producing a crude product |
| US7745369B2 (en) | 2003-12-19 | 2010-06-29 | Shell Oil Company | Method and catalyst for producing a crude product with minimal hydrogen uptake |
| US7628908B2 (en) * | 2003-12-19 | 2009-12-08 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
| CA2455011C (en) * | 2004-01-09 | 2011-04-05 | Suncor Energy Inc. | Bituminous froth inline steam injection processing |
| CA2455149C (en) * | 2004-01-22 | 2006-04-11 | Suncor Energy Inc. | In-line hydrotreatment process for low tan synthetic crude oil production from oil sand |
| BRPI0609416A2 (pt) | 2005-04-11 | 2011-10-11 | Shell Int Research | método para produzir um produto bruto |
| RU2424275C2 (ru) | 2005-04-11 | 2011-07-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения полуфабриката с пониженным содержанием микроуглеродного остатка и катализатор для его осуществления |
| US20080083650A1 (en) | 2006-10-06 | 2008-04-10 | Bhan Opinder K | Methods for producing a crude product |
| US8389782B2 (en) | 2010-08-31 | 2013-03-05 | Chevron U.S.A. Inc. | Biofuel production through catalytic deoxygenation |
| US8815085B2 (en) | 2010-09-24 | 2014-08-26 | Chevron U.S.A. Inc. | Process for reducing the total acid number of a hydrocarbon feed |
| CN102443417B (zh) * | 2010-10-13 | 2014-03-05 | 中国石油化工股份有限公司 | 一种高酸烃油的加氢处理方法 |
| KR101898289B1 (ko) * | 2011-01-10 | 2018-09-13 | 에스케이이노베이션 주식회사 | 탄화수소류 유분 내의 유기산을 저감하는 방법 |
| CN103842480B (zh) | 2011-07-29 | 2016-03-30 | 沙特阿拉伯石油公司 | 用于降低炼厂原料中总酸值的方法 |
| CN102380397B (zh) * | 2011-09-16 | 2013-07-31 | 中国海洋石油总公司 | 一种馏分油加氢脱酸催化剂的制法 |
| CN103102953B (zh) * | 2011-11-10 | 2015-02-18 | 中国石油化工股份有限公司 | 一种润滑油原料预处理的方法 |
| CN103980935A (zh) * | 2014-05-20 | 2014-08-13 | 王荣超 | 加氢处理的补硫工艺 |
| AR103709A1 (es) * | 2015-03-31 | 2017-05-31 | Ecopetrol Sa | Proceso mejorado para la reducción de acidez en crudos con alto contenido de ácidos nafténicos a través de hidrogenación catalítica |
| CN104946300A (zh) * | 2015-05-28 | 2015-09-30 | 王荣超 | 加氢处理的补硫装置 |
| US10385282B2 (en) | 2016-11-14 | 2019-08-20 | Korea Institute Of Energy Research | Method and system for upgrading and separating hydrocarbon oils |
| CA3024814C (en) * | 2018-01-20 | 2023-04-25 | Indian Oil Corporation Limited | A process for conversion of high acidic crude oils |
| EP4112702A1 (en) | 2021-06-29 | 2023-01-04 | Indian Oil Corporation Limited | Pre-treatment process for conversion of residual oils in a delayed coker unit |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL103285C (ru) * | 1900-01-01 | |||
| US2914470A (en) * | 1955-12-05 | 1959-11-24 | Sun Oil Co | Hydrorefining of petroleum |
| US2921023A (en) * | 1957-05-14 | 1960-01-12 | Pure Oil Co | Removal of naphthenic acids by hydrogenation with a molybdenum oxidesilica alumina catalyst |
| US3488716A (en) * | 1967-10-03 | 1970-01-06 | Exxon Research Engineering Co | Process for the removal of naphthenic acids from petroleum distillate fractions |
| US3617501A (en) * | 1968-09-06 | 1971-11-02 | Exxon Research Engineering Co | Integrated process for refining whole crude oil |
| US3876532A (en) * | 1973-02-27 | 1975-04-08 | Gulf Research Development Co | Method for reducing the total acid number of a middle distillate oil |
| US3850744A (en) * | 1973-02-27 | 1974-11-26 | Gulf Research Development Co | Method for utilizing a fixed catalyst bed in separate hydrogenation processes |
| US5397459A (en) * | 1993-09-10 | 1995-03-14 | Exxon Research & Engineering Co. | Process to produce lube oil basestock by low severity hydrotreating of used industrial circulating oils |
| NO303837B1 (no) * | 1994-08-29 | 1998-09-07 | Norske Stats Oljeselskap | FremgangsmÕte for Õ fjerne hovedsakelig naftensyrer fra en hydrokarbonolje |
-
1997
- 1997-08-29 US US08/920,701 patent/US5910242A/en not_active Expired - Lifetime
-
1998
- 1998-08-06 SG SG1998002911A patent/SG67533A1/en unknown
- 1998-08-13 DE DE69818770T patent/DE69818770T2/de not_active Expired - Fee Related
- 1998-08-13 EP EP98115246A patent/EP0899319B1/en not_active Expired - Lifetime
- 1998-08-14 CA CA002242394A patent/CA2242394C/en not_active Expired - Fee Related
- 1998-08-25 JP JP23854698A patent/JP4077948B2/ja not_active Expired - Fee Related
- 1998-08-27 MY MYPI98003920A patent/MY116198A/en unknown
- 1998-08-27 RU RU98116373/04A patent/RU2178450C2/ru not_active IP Right Cessation
- 1998-08-28 NO NO19983979A patent/NO317451B1/no not_active IP Right Cessation
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