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RU2019110727A - Двухкомпонентные адгезивные композиции без растворителей и способы их получения - Google Patents

Двухкомпонентные адгезивные композиции без растворителей и способы их получения Download PDF

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RU2019110727A
RU2019110727A RU2019110727A RU2019110727A RU2019110727A RU 2019110727 A RU2019110727 A RU 2019110727A RU 2019110727 A RU2019110727 A RU 2019110727A RU 2019110727 A RU2019110727 A RU 2019110727A RU 2019110727 A RU2019110727 A RU 2019110727A
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polyol
component
phosphate
composition according
isocyanate
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RU2019110727A
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RU2739841C2 (ru
RU2019110727A3 (ru
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Чэньянь БАЙ
Май ЧЭНЬ
Амира Аврил МАРИН
Джозеф Джеймс ЦУПАНЧИК
Иньчжун ГО
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Дау Глоубл Текнолоджиз Ллк
Ром Энд Хаас Компани
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
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    • C08G18/40High-molecular-weight compounds
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    • C08G18/4833Polyethers containing oxyethylene units
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/50Polyethers having heteroatoms other than oxygen
    • C08G18/5075Polyethers having heteroatoms other than oxygen having phosphorus
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/721Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
    • C08G18/725Combination of polyisocyanates of C08G18/78 with other polyisocyanates
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
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    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
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    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
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    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
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Claims (15)

1. Двухкомпонентная адгезивная композиция без растворителей, содержащая
полиольный компонент, содержащий соединение с фосфатной функциональной группой и по меньшей мере один полиол, выбранный из сложного полиэфира, простого полиэфира и их комбинаций; и
изоцианатный компонент, содержащий изоцианатный форполимер, который является продуктом реакции по меньшей мере одного изоцианатного мономера и по меньшей мере одного полиола, выбранного из сложного полиэфира, простого полиэфира и их комбинаций.
2. Композиция по п. 1, отличающаяся тем, что соединение с фосфатной функциональной группой имеет структуру I
Figure 00000001
3. Композиция по п. 2, отличающаяся тем, что соединение с фосфатной функциональной группой представляет собой полиол с фосфатной функциональной группой, содержащий две или более гидроксильные группы и одну или более структур I.
4. Композиция по п. 3, отличающаяся тем, что полиол с фосфатной функциональной группой является продуктом реакции полиола и полифосфорной кислоты.
5. Композиция по п. 3, отличающаяся тем, что полиол с фосфатной функциональной группой имеет молекулярную массу по меньшей мере 90, и она не должна превышать 4000 г/моль.
6. Композиция по п. 1, отличающаяся тем, что количество соединения с фосфатной функциональной группой в полиольном компоненте составляет по меньшей мере 0,2% мас. и не должно превышать 10% мас. относительно массы полиольного компонента.
7. Композиция по п. 1, отличающаяся тем, что изоцианатный мономер выбирают из ароматических изоцианатов, алифатических изоцианатов, модифицированных карбодиимидом изоцианатов и их комбинаций.
8. Композиция по п. 1, отличающаяся тем, что по меньшей мере один компонент из изоцианатного компонента и полиольного компонента дополнительно содержит биополиол.
9. Композиция по п. 8, отличающаяся тем, что биополиол является касторовым маслом.
10. Композиция по п. 1, отличающаяся тем, что массовое отношение изоцианатного компонента к полиольному компоненту составляет от 1:1 до 5:1.
11. Адгезивная композиция, которая является продуктом реакции отверждения полиольного компонента и изоцианатного компонента по п. 1.
12. Слоистая пленка, содержащая слой адгезивной композиции по п. 11.
RU2019110727A 2016-09-19 2016-09-19 Двухкомпонентные адгезивные композиции без растворителей и способы их получения RU2739841C2 (ru)

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US (1) US11608457B2 (ru)
EP (1) EP3516004A4 (ru)
JP (1) JP7030111B2 (ru)
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AR (1) AR109638A1 (ru)
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EP3774973A1 (en) * 2018-03-28 2021-02-17 Dow Global Technologies LLC Two-component adhesive compositions based on phosphate ester modified isocyanates, and methods for making same
WO2020068584A1 (en) 2018-09-28 2020-04-02 Dow Global Technologies Llc Process for forming a laminate
WO2020102402A1 (en) * 2018-11-16 2020-05-22 Dow Global Technologies Llc Solventless adhesive composition and process for making and use in forming a laminate
US20240240068A1 (en) * 2018-11-22 2024-07-18 Dow Global Technologies Llc Adhesive composition
CN113825816B (zh) * 2019-05-15 2023-11-24 陶氏环球技术有限责任公司 双组分粘合剂组合物、用其制备的制品及其制备方法
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