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RU2011135580A - METHOD FOR PRODUCING OLIGOMERS OF HIGHER LINEAR α-OLEFINS - Google Patents

METHOD FOR PRODUCING OLIGOMERS OF HIGHER LINEAR α-OLEFINS Download PDF

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Publication number
RU2011135580A
RU2011135580A RU2011135580/04A RU2011135580A RU2011135580A RU 2011135580 A RU2011135580 A RU 2011135580A RU 2011135580/04 A RU2011135580/04 A RU 2011135580/04A RU 2011135580 A RU2011135580 A RU 2011135580A RU 2011135580 A RU2011135580 A RU 2011135580A
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RU
Russia
Prior art keywords
olefins
catalyst
zeolite
producing oligomers
higher linear
Prior art date
Application number
RU2011135580/04A
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Russian (ru)
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RU2483053C2 (en
Inventor
Усеин Меметович Джемилев
Борис Иванович Кутепов
Нелля Геннадиевна Григорьева
Сергей Владимирович Бубённов
Михаил Леонардович Павлов
Альфира Наилевна Хазипова
Анастасия Анатольевна Маяк
Original Assignee
Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран
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Priority to RU2011135580/04A priority Critical patent/RU2483053C2/en
Publication of RU2011135580A publication Critical patent/RU2011135580A/en
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Publication of RU2483053C2 publication Critical patent/RU2483053C2/en

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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Способ получения олигомеров высших α-олефинов взаимодействием линейных α-олефинов C-Cс катализатором на основе цеолита структурного типа FAU, отличающийся тем, что в качестве катализатора используют гранулированный без связующих веществ цеолит Y-БС в Н-форме, подвергнутый термопаровой обработке и последующему ионному обмену, и реакцию проводят при массовом содержании катализатора 10-30% по отношению к α-олефину и 130-200°С.A method of producing oligomers of higher α-olefins by the interaction of linear α-olefins C-C with a catalyst based on a structural type FAU zeolite, characterized in that the catalyst is granulated without binders, Y-BS zeolite in H-form, subjected to thermocouple treatment and subsequent ion exchange, and the reaction is carried out at a mass content of catalyst of 10-30% with respect to the α-olefin and 130-200 ° C.

Claims (1)

Способ получения олигомеров высших α-олефинов взаимодействием линейных α-олефинов C6-C14 с катализатором на основе цеолита структурного типа FAU, отличающийся тем, что в качестве катализатора используют гранулированный без связующих веществ цеолит Y-БС в Н-форме, подвергнутый термопаровой обработке и последующему ионному обмену, и реакцию проводят при массовом содержании катализатора 10-30% по отношению к α-олефину и 130-200°С. The method of producing oligomers of higher α-olefins by the interaction of linear α-olefins C 6 -C 14 with a catalyst based on a zeolite of structural type FAU, characterized in that the catalyst is granulated without binders zeolite Y-BS in H-form, subjected to thermocouple processing and subsequent ion exchange, and the reaction is carried out with a mass content of the catalyst of 10-30% with respect to the α-olefin and 130-200 ° C.
RU2011135580/04A 2011-08-25 2011-08-25 METHOD OF PRODUCING OLIGOMERS OF HIGHER LINEAR α-OLEFINS RU2483053C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2011135580/04A RU2483053C2 (en) 2011-08-25 2011-08-25 METHOD OF PRODUCING OLIGOMERS OF HIGHER LINEAR α-OLEFINS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2011135580/04A RU2483053C2 (en) 2011-08-25 2011-08-25 METHOD OF PRODUCING OLIGOMERS OF HIGHER LINEAR α-OLEFINS

Publications (2)

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RU2011135580A true RU2011135580A (en) 2013-02-27
RU2483053C2 RU2483053C2 (en) 2013-05-27

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2659790C2 (en) * 2014-02-25 2018-07-04 Мицубиси Кемикал Корпорейшн Method for producing low alpha-olefin polymer

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4417088A (en) * 1981-09-25 1983-11-22 Chevron Research Company Oligomerization of liquid olefins
RU2384559C1 (en) * 2008-08-27 2010-03-20 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран Method of producing 1-alkoxy-1-phenylethanes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2659790C2 (en) * 2014-02-25 2018-07-04 Мицубиси Кемикал Корпорейшн Method for producing low alpha-olefin polymer
US10221109B2 (en) 2014-02-25 2019-03-05 Mitsubishi Chemical Corporation Method for producing alpha-olefin low polymer

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Publication number Publication date
RU2483053C2 (en) 2013-05-27

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MM4A The patent is invalid due to non-payment of fees

Effective date: 20130826