RO83714B - Process for preparing n-(halogen-methyl)-acylamide - Google Patents
Process for preparing n-(halogen-methyl)-acylamideInfo
- Publication number
- RO83714B RO83714B RO105905A RO10590581A RO83714B RO 83714 B RO83714 B RO 83714B RO 105905 A RO105905 A RO 105905A RO 10590581 A RO10590581 A RO 10590581A RO 83714 B RO83714 B RO 83714B
- Authority
- RO
- Romania
- Prior art keywords
- carbon atoms
- radical
- phenyl
- alkyl
- halogen
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
- C07D277/62—Benzothiazoles
- C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D521/00—Heterocyclic compounds containing unspecified hetero rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Inventia se refera la un procedeu pentru prepararea unor N-(halogenmetil)-acilamide cu formula generala I: (vezi formula) în care X reprezinta hidrogen, un radical alchil sau halogenalchil cu 1...6 atomi de carbon, un radical cicloalchil cu 3...7 atomi de carbon, fenil sau benzil sau oricare din radicalii mentionati este substituit cu halogen, NO2, CF3, alchil cu 6 atomi de carbon sau alcoxi cu 1...6 atomi de carbon, fenil, sau benzil, X' reprezinta clor, brom sau iod, R reprezinta un radical 1-alchen-1-il aciclic cu pîna la 10 atomi de carbon, un radical 1-cicloalchen-1-il cu 5...7 atomi de carbon, un radical fenil sau radicalii 1-cicloalchen-1-il sau fenil substituiti cu una sau mai multe grupe alchil cu 1...6 atomi de carbon alcoxi cu 1...6 atomi de carbon, alchenil cu 2...4 atomi de carbon sau alchiloxi cu 3...4 atomi de carbon, grupe NO2 sau CF3 sau halogen, si anume, un compus cu formula generala II: (vezi formula generala) în care X si R au semnificatiile indicate mai sus, iar R' reprezinta un radical alchil cu 1...10 atomi de carbon, se trateaza cu o solutie de acid halogenhidric, la o temperatura cuprinsa între temperatura camerei si 45 degree C, în mediu de solvent inert, ales dintre hidrocarburi alifatice halogente, hidrocarburi aromatice halogenate.The invention relates to a process for the preparation of N- (halomethyl) -acyl amides of the general formula I wherein X represents hydrogen, an alkyl or haloalkyl radical of 1-6 carbon atoms, a cycloalkyl radical 3 to 7 carbon atoms, phenyl or benzyl, or any of said radicals being substituted with halogen, NO2, CF3, C1-6 alkyl or C1-6alkoxy, phenyl, or benzyl, X R represents a 1-alkenyl-1-yl acyclic radical of up to 10 carbon atoms, a 1-cycloalken-1-yl radical of 5 to 7 carbon atoms, a phenyl radical or 1-cycloalkenyl-1-yl or phenyl radicals substituted by one or more alkyl groups of 1-6 carbon atoms of alkoxy of 1-6 carbon atoms, alkenyl of 2-4 carbon atoms or C1-C4alkyloxy, NO2 or CF3 or halogen, i.e., a compound of general formula II wherein X and R have the meanings indicated above, R 'represents an alkyl radical of 1 to 10 carbon atoms, treated with a solution of hydrogen halide at a temperature between room temperature and 45 ° C in an inert solvent medium chosen from halogenated aliphatic hydrocarbons, halogenated aromatic hydrocarbons.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/211,608 US4311858A (en) | 1980-12-01 | 1980-12-01 | Process for producing N-(halomethyl) acyl-amides |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO83714A RO83714A (en) | 1984-04-12 |
| RO83714B true RO83714B (en) | 1984-05-30 |
Family
ID=22787633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO105905A RO83714B (en) | 1980-12-01 | 1981-11-30 | Process for preparing n-(halogen-methyl)-acylamide |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US4311858A (en) |
| EP (1) | EP0053495B1 (en) |
| JP (1) | JPS57120557A (en) |
| KR (1) | KR850001601B1 (en) |
| AR (1) | AR229168A1 (en) |
| AT (1) | ATE8877T1 (en) |
| AU (1) | AU542134B2 (en) |
| BR (1) | BR8107773A (en) |
| CA (1) | CA1178614A (en) |
| CS (1) | CS231186B2 (en) |
| DD (1) | DD201885A5 (en) |
| DE (1) | DE3165449D1 (en) |
| ES (1) | ES8207131A1 (en) |
| GB (1) | GB2088865B (en) |
| HU (1) | HU188159B (en) |
| IL (1) | IL64402A (en) |
| MX (1) | MX6900E (en) |
| NO (1) | NO153100C (en) |
| NZ (1) | NZ199109A (en) |
| PL (1) | PL130528B1 (en) |
| RO (1) | RO83714B (en) |
| YU (1) | YU277881A (en) |
| ZA (1) | ZA818300B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4731451A (en) * | 1980-03-25 | 1988-03-15 | Monsanto Company | N-((2-oxo-3(2H)benzothiazolyl)methyl)-2-chloroacetanilides |
| DE3123731A1 (en) * | 1981-06-15 | 1982-12-30 | Basf Ag, 6700 Ludwigshafen | CHLORIC ACETIC CYCLOHEXYLAMIDES, THEIR PRODUCTION, THEIR USE FOR CONTROLLING HERBICIDES, AND A MEDIUM FOR THIS |
| AT382870B (en) * | 1982-02-09 | 1987-04-27 | Sandoz Ag | Process for the preparation of novel chloroacetamides |
| DE3206660A1 (en) * | 1982-02-25 | 1983-09-01 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING O-ACYLAMIDOMETHYLBENZYL HALOGENIDES |
| JP3449435B2 (en) * | 1993-12-24 | 2003-09-22 | 富士写真フイルム株式会社 | Processing method of silver halide color photographic light-sensitive material |
| CN111302968B (en) * | 2020-03-20 | 2021-06-08 | 中国科学院上海有机化学研究所 | Synthesis method of amide nitrogen trifluoromethyl compound |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3259540A (en) * | 1961-02-13 | 1966-07-05 | Murphy Chemical Ltd | Stabilized insecticidal composition containing an o, o-dimethyl s-(n-alkoxymethyl) carbamoylmethyl phosphorothiolothionate |
| US3574746A (en) * | 1967-06-05 | 1971-04-13 | Monsanto Co | N-(cycloalken-1-yl) alpha-haloacetamides |
| US3637847A (en) * | 1969-09-03 | 1972-01-25 | Monsanto Co | N-haloalkyl-anilides |
| DE2351297A1 (en) * | 1973-10-12 | 1975-04-24 | Bayer Ag | Di-chloromethyl-acrylamide and -methacrylamide prepn - by reacting acrylamides with formaldehyde or formaldehyde precursors and acid chlorides |
| ES465723A1 (en) * | 1976-12-29 | 1978-10-01 | Monsanto Co | Process for the production of haloacylamides |
| DE2854599A1 (en) * | 1978-12-18 | 1980-06-26 | Basf Ag | SUBSTITUTED N-HALOGEN METHYLANILIDES AND METHOD FOR THE PRODUCTION AND USE THEREOF |
-
1980
- 1980-12-01 US US06/211,608 patent/US4311858A/en not_active Expired - Lifetime
-
1981
- 1981-11-26 YU YU02778/81A patent/YU277881A/en unknown
- 1981-11-27 AT AT81305618T patent/ATE8877T1/en not_active IP Right Cessation
- 1981-11-27 ES ES507500A patent/ES8207131A1/en not_active Expired
- 1981-11-27 EP EP81305618A patent/EP0053495B1/en not_active Expired
- 1981-11-27 DD DD81235203A patent/DD201885A5/en unknown
- 1981-11-27 DE DE8181305618T patent/DE3165449D1/en not_active Expired
- 1981-11-30 ZA ZA818300A patent/ZA818300B/en unknown
- 1981-11-30 BR BR8107773A patent/BR8107773A/en unknown
- 1981-11-30 HU HU813593A patent/HU188159B/en unknown
- 1981-11-30 GB GB8136035A patent/GB2088865B/en not_active Expired
- 1981-11-30 AR AR287624A patent/AR229168A1/en active
- 1981-11-30 NZ NZ199109A patent/NZ199109A/en unknown
- 1981-11-30 RO RO105905A patent/RO83714B/en unknown
- 1981-11-30 AU AU78110/81A patent/AU542134B2/en not_active Ceased
- 1981-11-30 KR KR1019810004641A patent/KR850001601B1/en active
- 1981-11-30 PL PL1981234036A patent/PL130528B1/en unknown
- 1981-11-30 IL IL64402A patent/IL64402A/en unknown
- 1981-11-30 MX MX819795U patent/MX6900E/en unknown
- 1981-11-30 CA CA000391187A patent/CA1178614A/en not_active Expired
- 1981-11-30 CS CS818833A patent/CS231186B2/en unknown
- 1981-11-30 NO NO814074A patent/NO153100C/en unknown
- 1981-11-30 JP JP56190946A patent/JPS57120557A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| MX6900E (en) | 1986-10-10 |
| DE3165449D1 (en) | 1984-09-13 |
| EP0053495A1 (en) | 1982-06-09 |
| GB2088865B (en) | 1985-06-12 |
| JPS57120557A (en) | 1982-07-27 |
| DD201885A5 (en) | 1983-08-17 |
| IL64402A0 (en) | 1982-02-28 |
| ATE8877T1 (en) | 1984-08-15 |
| ZA818300B (en) | 1983-01-26 |
| ES507500A0 (en) | 1982-09-01 |
| CS231186B2 (en) | 1984-10-15 |
| KR830007513A (en) | 1983-10-21 |
| EP0053495B1 (en) | 1984-08-08 |
| NZ199109A (en) | 1985-12-13 |
| NO153100C (en) | 1986-01-15 |
| CS883381A2 (en) | 1984-02-13 |
| KR850001601B1 (en) | 1985-10-24 |
| HU188159B (en) | 1986-03-28 |
| GB2088865A (en) | 1982-06-16 |
| AR229168A1 (en) | 1983-06-30 |
| AU542134B2 (en) | 1985-02-07 |
| IL64402A (en) | 1984-11-30 |
| RO83714A (en) | 1984-04-12 |
| US4311858A (en) | 1982-01-19 |
| CA1178614A (en) | 1984-11-27 |
| PL130528B1 (en) | 1984-08-31 |
| ES8207131A1 (en) | 1982-09-01 |
| AU7811081A (en) | 1982-06-10 |
| YU277881A (en) | 1983-09-30 |
| NO814074L (en) | 1982-06-02 |
| PL234036A1 (en) | 1982-07-05 |
| NO153100B (en) | 1985-10-07 |
| BR8107773A (en) | 1982-08-31 |
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