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PE20171029A1 - Sintesis de fischer-tropsch - Google Patents

Sintesis de fischer-tropsch

Info

Publication number
PE20171029A1
PE20171029A1 PE2017000890A PE2017000890A PE20171029A1 PE 20171029 A1 PE20171029 A1 PE 20171029A1 PE 2017000890 A PE2017000890 A PE 2017000890A PE 2017000890 A PE2017000890 A PE 2017000890A PE 20171029 A1 PE20171029 A1 PE 20171029A1
Authority
PE
Peru
Prior art keywords
fischer
tropsch
catalyst
synthesis reactor
moving bed
Prior art date
Application number
PE2017000890A
Other languages
English (en)
Inventor
Richard Neil Walsh
Jean Louis Gauche
Hendrik Wilhelmus Joubert
Wyk Albertus Maritz Van
Johannes Henning Viljoen
Marcel Juergen Krause
Original Assignee
Sasol Tech Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Tech Pty Ltd filed Critical Sasol Tech Pty Ltd
Publication of PE20171029A1 publication Critical patent/PE20171029A1/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/18—Treating with free oxygen-containing gas with subsequent reactive gas treating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/72—Regeneration or reactivation of catalysts, in general including segregation of diverse particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/045—Regeneration
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts
    • C10G2/343—Apparatus, reactors with moving solid catalysts according to the "moving-bed" method
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/62—Catalyst regeneration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Se refiere a un metodo (10) para sintetizar productos de Fischer-Tropsch (20) incluye alimentar un gas de sintesis (30) a un reactor de sintesis de Fischer-Tropsch de lecho movil (16) que contiene un catalizador de Fischer-Tropsch en un lecho de catalizador movil y convertir cataliticamente por lo menos una porcion del gas de sintesis (30) en el lecho de catalizador de movil a productos de Fischer-Tropsch (20). Los productos de Fischer-Tropsch (20) se retiran del reactor de sintesis de Fischer-Tropsch de lecho movil (16). El metodo (10) incluye ademas, mientras que el reactor de sintesis de Fischer-Tropsch de lecho movil (16) esta en linea, retirar una porcion (50) del catalizador de Fischer-Tropsch del reactor de sintesis de Fischer-Tropsch de lecho movil (16), anadir un catalizador de Fischer-Tropsch reactivado (57, 58) al reactor de sintesis de Fischer-Tropsch de lecho movil (16), y anadir un catalizador fresco de Fischer-Tropsch (60, 58) ademas del catalizador reactivado (57, 58), al reactor de sintesis de Fischer-Tropsch de lecho movil (16)
PE2017000890A 2014-11-20 2015-10-26 Sintesis de fischer-tropsch PE20171029A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ZA201408551 2014-11-20

Publications (1)

Publication Number Publication Date
PE20171029A1 true PE20171029A1 (es) 2017-07-17

Family

ID=55443346

Family Applications (1)

Application Number Title Priority Date Filing Date
PE2017000890A PE20171029A1 (es) 2014-11-20 2015-10-26 Sintesis de fischer-tropsch

Country Status (9)

Country Link
US (1) US10190057B2 (es)
CN (1) CN107207969B (es)
AU (1) AU2015349653B2 (es)
BR (1) BR112017010259B1 (es)
CA (1) CA2968237C (es)
EA (1) EA034262B1 (es)
PE (1) PE20171029A1 (es)
WO (1) WO2016081956A1 (es)
ZA (1) ZA201703886B (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107987907B (zh) * 2016-10-26 2020-07-10 中国石油天然气股份有限公司 一种由合成气制备富含甲烷气体的方法
CN107987906A (zh) * 2016-10-26 2018-05-04 中国石油天然气股份有限公司 一种生产甲烷的方法
US20210238484A1 (en) * 2018-06-05 2021-08-05 Sabic Global Technologies B.V. Bulk-metal crystalline transition metal based heterogeneous catalysts, methods of making and uses thereof
US11045793B1 (en) 2020-07-24 2021-06-29 Qatar University Controlled on-pot design of mixed copper/zinc oxides supported aluminum oxide as an efficient catalyst for conversion of syngas to heavy liquid hydrocarbons and alcohols under ambient conditions feasible for the Fischer-Tropsch synthesis

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5260239A (en) 1992-12-18 1993-11-09 Exxon Research & Engineering Company External catalyst rejuvenation system for the hydrocarbon synthesis process
US6201030B1 (en) 1999-09-22 2001-03-13 Syntroleum Corporation Process and apparatus for regenerating a particulate catalyst
US6486220B1 (en) 1999-11-17 2002-11-26 Conoco Inc. Regeneration procedure for Fischer-Tropsch catalyst
US6869978B2 (en) 1999-11-17 2005-03-22 Conocophillips Company Pressure swing catalyst regeneration procedure for Fischer-Tropsch catalyst
US6812179B2 (en) 2001-04-25 2004-11-02 Syntroleum Corporation Process for regenerating a slurry fischer-tropsch catalyst
US6900151B2 (en) 2001-11-13 2005-05-31 Exxonmobil Research And Engineering Company In situ catalyst regeneration/activation process
US6458857B1 (en) * 2001-11-20 2002-10-01 Exxonmobil Research And Engineering Company Process for maximizing 371° C.+ production in fischer-tropsch process
US6800579B2 (en) 2002-01-29 2004-10-05 Exxonmobil Research And Engineering Company Catalyst regeneration
US6753354B2 (en) 2002-01-29 2004-06-22 Exxonmobil Research And Engineering Company Fischer-tropsch catalyst enhancement
US6838487B1 (en) 2003-12-04 2005-01-04 Rentech, Inc. Method and apparatus for regenerating an iron-based Fischer-Tropsch catalyst
CN101505867A (zh) 2006-08-25 2009-08-12 新日铁工程技术株式会社 从合成气体制造烃的催化剂、催化剂的制造方法、催化剂的再生方法以及从合成气体制造烃的方法
US9168501B2 (en) * 2007-09-10 2015-10-27 Res Usa, Llc Commercial Fischer-Tropsch reactor
GB2482905B (en) 2010-08-19 2016-01-13 Gtl F1 Ag Fischer-tropsch catalyst regeneration
BR112013008579B1 (pt) 2010-10-27 2019-04-16 Sasol Technology (Proprietary) Limited Método de operação de processo para converter cataliticamente um ou mais reagentes para formar um ou mais produtos usando reator de leito fluido contendo catalisador que se desativa ao longo do tempo
GB201107070D0 (en) * 2011-04-27 2011-06-08 Davy Process Techn Ltd FT process using can reactor
FR2998812B1 (fr) 2012-12-05 2014-11-21 IFP Energies Nouvelles Injection d'additif dans une unite de synthese d'hydrocarbures a partir de gaz de synthese permettant de controler et maintenir une concentration homogene en catalyseur

Also Published As

Publication number Publication date
CA2968237C (en) 2021-10-26
CN107207969B (zh) 2019-05-07
CN107207969A (zh) 2017-09-26
ZA201703886B (en) 2019-02-27
US10190057B2 (en) 2019-01-29
WO2016081956A1 (en) 2016-05-26
AU2015349653A1 (en) 2017-06-08
BR112017010259A2 (pt) 2018-07-03
AU2015349653B2 (en) 2020-06-04
EA201791087A1 (ru) 2018-01-31
BR112017010259B1 (pt) 2020-12-01
CA2968237A1 (en) 2016-05-26
US20170321126A1 (en) 2017-11-09
EA034262B1 (ru) 2020-01-22

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