[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

KR980000573A - 지지된 루테늄 촉매의 존재하에 유기 화합물을 반응시키는 방법 - Google Patents

지지된 루테늄 촉매의 존재하에 유기 화합물을 반응시키는 방법 Download PDF

Info

Publication number
KR980000573A
KR980000573A KR1019970026801A KR19970026801A KR980000573A KR 980000573 A KR980000573 A KR 980000573A KR 1019970026801 A KR1019970026801 A KR 1019970026801A KR 19970026801 A KR19970026801 A KR 19970026801A KR 980000573 A KR980000573 A KR 980000573A
Authority
KR
South Korea
Prior art keywords
catalyst
group
support
pore
metals
Prior art date
Application number
KR1019970026801A
Other languages
English (en)
Other versions
KR100464581B1 (ko
Inventor
토마스 륄
보리스 브라이차이델
콘라드 크놀
자비네 바이구니
요헴 헨켈만
파울 내걸레
헤르만 가우제폴
노르베르트 니쓰너
안드레아스 헨네
롤프 레브퀴허
Original Assignee
카르크, 메이어
바스프 악티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26026728&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR980000573(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from DE19624485A external-priority patent/DE19624485A1/de
Priority claimed from DE19624835A external-priority patent/DE19624835A1/de
Application filed by 카르크, 메이어, 바스프 악티엔게젤샤프트 filed Critical 카르크, 메이어
Publication of KR980000573A publication Critical patent/KR980000573A/ko
Application granted granted Critical
Publication of KR100464581B1 publication Critical patent/KR100464581B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerization Catalysts (AREA)

Abstract

본 발명에 따르면, 활성 금속으로서 루테늄이 단독으로 또는 1종 이상의 ⅠB족, ⅦB족, 또는 ⅧB족 금속과 함께 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30중량%의 양으로 도포되어 이루어지고, 여기서 상기 지지체의 공극 용적 중 10% 내지 50%ㄴ은 공극 직경이 50nm 내지 10,000nm범위내인 마크로 공극으로 이루어지고, 상기 지지체의 공극 용적 중 50% 내지 90%는 공극 직경이 2nm 내지 50nm범위내인 메조 공극으로 이루어지며, 상기 공극 용적의 합이 100%인 촉매를 제조할 수 있으며, 이러한 촉매의 존재하에 유기 화합물을 반응시킬 수 있다.
본 발명의 촉매는 고 반응성 (고 전환수), 고 선택성 및 장기간의 가사 시간을 나타낸다. 따라서, 본 발명의 방법에 의하면, 높은 공간 속도에서 장기간의 가사(司使)시간 동안 극히 높은 전환수로 수행될 수 있으며, 대응하는 수소화 반응 생성물은 높은 수율 및 순도로 얻어진다. 또한, 본 발명의 방법에 따르면, 촉매 내에 단지 소량의 금속 함량을 사용했을 때 매우 양호한 결과가 얻어지는 잇점이 있다.

Description

지지된 루테늄 촉매의 존재하에 유기 화합물을 반응시키는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 활성 금속으로서 루테늄이 단독으로 또는 1종 이상의 ⅠB족, ⅦB족, 또는 ⅧB족 금속과 함께 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30중량%의 양으로 도포되어 이루어지고, 여기서 상기 지지체의 공극 용적 중 10% 내지 50%는 공극 직경이 50nm 내지 10,000nm 범위내의 마크로 공극으로 이루어지고, 상기 지지체의 공극 요적 중 50% 내지 90%는 공극 직경이 2nm 내지 50nm 범위내인 메조 공극으로 이루어지며, 상기 공극 용적의 합이 100%인 촉매의 존재하에 유기 화합물을 반응시키는 방법.
  2. 촉매 지지체의 공극 용적 중 10% 내지 50%는 공극 직경이 50nm 내지 10,000nm 범위내인 마크로 공극으로 이루어지고, 상기 지지체의 공극 용적 중 50% 내지 90%는 공극 직경이 2nm 내지 50nm 범위내인 메조 공극으로 이루어지며, 상기 공극 용적의 합은 100%인, 활성 금속으로서 루테늄이 단독으로 또는 1종 이상의 ⅠB족, ⅦB족, 또는 ⅧB족 금속과 함께 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30중량%의 양으로 도포되어 이루어지는 촉매의 존재하에, 또는 활성 금속으로서 팔라듐이 단독으로 또는 1종 이상의 IB족, ⅦB족, ⅧB족 금속과 함께 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30 중량%의 양으로 도포되어 이루어지는 촉매의 존재하에, 1개 이상의 C-C다중 결합을 가지고 있는 중합체를 수소화시키는 방법.
  3. 촉매 지지체으 ㅣ공극 용적 중 10% 내지 50%는 공극 직경이 50nm 내지 10,000nm 범위내인 마크로 공극으로 이루어지고, 상기 지지체의 공극 용적 중 50% 내지 90%는 공극 직경이 2nm 내지 50nm 범위내인 메조 공극으로 이루어지며, 상기 공극 용적의 합은 100%인, 활성 금속으로서 루테늄이 단독으로 또는 1종 이상의 ⅠB족, ⅦB족, 또는 ⅧB족 금속과 함께 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30중량%의 양으로 도포되어 이루어지는 촉매, 또는 활성 금속으로서 팔라듐이 단독으로 또는 1종 이상의 ⅠB족, ⅦB족, ⅧB족 금속과 함께 상기 지지체에 촉매의 전체 중량을 기준으로 0.01 내지 30중량%의 양으로 도포되어 이루어지는 촉매.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970026801A 1996-06-19 1997-06-19 지지된루테늄촉매의존재하에유기화합물을반응시키는방법 KR100464581B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19624485A DE19624485A1 (de) 1996-06-19 1996-06-19 Verfahren zur Hydrierung einer aromatischen Verbindung in Gegenwart eines geträgerten Rutheniumkatalysators
DE19624485.4 1996-06-19
DE19624835.3 1996-06-21
DE19624835A DE19624835A1 (de) 1996-06-21 1996-06-21 Verfahren zur Hydrierung von Polymeren mit Ruthenium- oder Palladiumkatalysatoren

Publications (2)

Publication Number Publication Date
KR980000573A true KR980000573A (ko) 1998-03-30
KR100464581B1 KR100464581B1 (ko) 2005-07-04

Family

ID=26026728

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019970026801A KR100464581B1 (ko) 1996-06-19 1997-06-19 지지된루테늄촉매의존재하에유기화합물을반응시키는방법

Country Status (6)

Country Link
US (2) US6248924B1 (ko)
EP (1) EP0814098B2 (ko)
JP (1) JPH1072377A (ko)
KR (1) KR100464581B1 (ko)
CN (1) CN1095690C (ko)
DE (1) DE59711558D1 (ko)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002047814A1 (en) * 2000-12-14 2002-06-20 Samsung General Chemicals Co., Ltd. The stable catalyst for hydropurification
KR100343752B1 (ko) * 2000-04-12 2002-07-25 한국에너지기술연구원 할로겐화 휘발성 유기화합물과 일반 휘발성 유기화합물동시 제어용 고활성 복합 산화촉매와 그 제조 방법 및이를 이용한 촉매 반응 제어 방법

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19651129A1 (de) * 1996-12-09 1998-06-10 Basf Ag Verfahren zur Hydrierung einer aromatischen Verbindung in Gegenwart eines Trägerkatalysators
EP1042273B1 (de) * 1997-12-19 2003-05-07 Basf Aktiengesellschaft Verfahren zur hydrierung von benzolpolycarbonsäuren oder derivaten davon unter verwendung eines makroporen aufweisenden katalysators
DE19815639A1 (de) * 1998-04-07 1999-10-14 Basf Ag Verfahren zur Herstellung von Zuckeralkoholen
DE19832087A1 (de) * 1998-07-16 2000-01-20 Basf Ag Verfahren zur Umsetzung von organischen Verbindungen mit boroxidhaltigen, makroporösen Trägerkatalysatoren
DE19832810A1 (de) * 1998-07-21 2000-01-27 Basf Ag Verfahren zur Hydrierung von ungesättigten heterocyclischen Verbindungen
DE19833094A1 (de) * 1998-07-23 2000-01-27 Bayer Ag Verfahren zur Hydrierung aromatischer Polymere in Gegenwart spezieller Katalysatoren
DE19833095A1 (de) 1998-07-23 2000-01-27 Bayer Ag Verfahren zur Hydrierung aromatischer Polymere in Gegenwart von sauerstoffenthaltenden Kohlenwasserstoffen
DE19834568A1 (de) * 1998-07-31 2000-02-03 Aventis Res & Tech Gmbh & Co Bimetallische Kupfer-Ruthenium-Trägerkatalysatoren mit hoher Sinterstabilität und Verfahren zu deren Herstellung
WO2000030744A1 (en) * 1998-11-24 2000-06-02 Michigan State University Condensed phase catalytic hydrogenation of lactic acid to propylene glycol
DE19904612A1 (de) 1999-02-05 2000-08-10 Bayer Ag Verfahren zur Hydrierung aromatischer Polymere in Gegenwart spezieller Katalysatoren
DE19927978A1 (de) * 1999-06-18 2000-12-21 Basf Ag Ausgewählte Cyclohexan-1,3- und 1,4-dicarbonsäureester
IT1317868B1 (it) 2000-03-02 2003-07-15 Eni Spa Catalizzatore a base di cobalto supportato, particolarmente utilenella reazione di fischer-tropsch.
DE10040091A1 (de) * 2000-08-16 2002-02-28 Basf Ag Verbessertes Verfahren zur Herstellung von Polytetrahydrofuran mit niedriger Farbzahl
DE10054742A1 (de) 2000-11-04 2002-05-08 Degussa Verfahren zur Konzentrierung von wässrigem Wasserstoffperoxid durch Kristallisation
DE60213898T2 (de) 2001-03-14 2007-08-30 Kuraray Co., Ltd., Kurashiki Verfahren zur Herstellung von hydrierten Polymeren
US20030032847A1 (en) * 2001-06-04 2003-02-13 Crompton Corporation Process for hydrogenating/dehalogenating polyalphaolefin polymer, the resulting polymer and lubricant containing same
DE10128242A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Hydrierung organischer Verbindungen
ES2318049T3 (es) 2001-09-25 2009-05-01 Exxonmobil Chemical Patents Inc. Poli(cloruro de vinilo) plastificado.
US7184886B1 (en) * 2001-12-21 2007-02-27 Garmin Ltd. Navigation system, method and device with detour algorithm
US6706658B2 (en) * 2001-12-21 2004-03-16 Engelhard Corporation Catalyst for purification of aromatic acids
GB2398749B (en) * 2001-12-27 2005-04-27 Daicel Chem Catalyst and process for the production of lower fatty acid esters
MY122928A (en) * 2001-12-27 2006-05-31 Daicel Chem Catalyst and process for the production of lower fatty acid esters
US6448425B1 (en) 2002-02-19 2002-09-10 Crompton Corporation Preparation of N-substituted aminoorganosilanes
ATE422962T1 (de) 2002-05-31 2009-03-15 Evonik Degussa Gmbh Geträgerter rutheniumkatalysator und verfahren zur hydrierung eines aromatischen amins in gegenwart dieses katalysators
DE10253803A1 (de) 2002-11-18 2004-05-27 Degussa Ag Verfahren zur Herstellung von aliphatischen Isocyanaten aus aromatischen Isocyanaten
DE10253802A1 (de) * 2002-11-18 2004-06-03 Degussa Ag Verfahren zur Hydrierung von aromatischen Urethanen in Gegenwart eines geträgerten Rutheniumkatalysators
GB0227086D0 (en) * 2002-11-20 2002-12-24 Exxonmobil Res & Eng Co Hydrogenation processes
GB0227087D0 (en) * 2002-11-20 2002-12-24 Exxonmobil Chem Patents Inc Hydrogenation of benzene polycarboxylic acids or derivatives thereof
DE10361157A1 (de) * 2003-12-22 2005-07-21 Basf Ag Ruthenium-Heterogenkatalysator und Verfahren zur Herstellung eines Bisglycidylethers der Formel I
EP1699557A1 (de) * 2003-12-22 2006-09-13 Basf Aktiengesellschaft Ruthenium-heterogenkatalysator, verfahren zur hydrierung einer carbocyclischen aromatischen gruppe und kernhydrierte bisglycidylether der bisphenole a und f
JP4682157B2 (ja) * 2004-02-17 2011-05-11 エクソンモービル リサーチ アンド エンジニアリング カンパニー 高活性粉末触媒を用いる高度立体障害アミノ−エーテルアルコールおよびジアミノポリアルケニルエーテルの改良合成
ES2523657T3 (es) * 2004-02-17 2014-11-28 Exxonmobil Research And Engineering Company Preparación catalítica de amino-éter alcoholes severamente impedidos estéricamente usando un catalizador cargado de metal
US7919659B2 (en) 2004-07-09 2011-04-05 Asahi Kasei Chemicals Corporation Catalyst for cycloolefin production and process for production
US20060110308A1 (en) * 2004-09-17 2006-05-25 Puneet Gupta Silicon carbides, silicon carbide based sorbents, and uses thereof
EP1824810B1 (en) * 2004-12-16 2013-03-27 Huntsman Petrochemical LLC Co-production of cyclohexylamine and bis-(para-aminocyclohexyl)-methane
JP2008543551A (ja) * 2005-06-22 2008-12-04 ビーエーエスエフ ソシエタス・ヨーロピア 不均一系ルテニウム触媒および炭素環式芳香族基の水素化法、殊にビスフェノールａおよびｆの核水素化ビスグリシジルエーテルの製造法
DE102005029200A1 (de) * 2005-06-22 2006-12-28 Basf Ag Katalysator und Verfahren zur Hydrierung von hydrierbare Gruppen enthaltenden organischen Verbindungen
DE602006004279D1 (de) 2005-09-09 2009-01-29 Mitsubishi Gas Chemical Co Verfahren zur Herstellung von Aminoverbindungen mit einem aromatischen Ring unter Verwendung eines Schalenkatalysators
US8889936B2 (en) * 2006-07-31 2014-11-18 Basf Se Method of regenerating ruthenium catalysts for the hydrogenation of benzene
CN101522300B (zh) 2006-07-31 2012-10-10 巴斯夫欧洲公司 适用于氢化的钌催化剂的再生方法
JP5044649B2 (ja) 2006-07-31 2012-10-10 ビーエーエスエフ ソシエタス・ヨーロピア フタレートを環水素化するためのルテニウム触媒を再生する方法
US7939701B2 (en) 2007-12-12 2011-05-10 Uop Llc Aromatic isomerization catalyst and a process of use thereof
JP5125771B2 (ja) * 2008-05-30 2013-01-23 東ソー株式会社 脂環式アミン類の製造法
WO2010005859A2 (en) * 2008-07-07 2010-01-14 Albemarle Corporation Processes for hydrogenating aromatic amines
US8426660B2 (en) * 2008-08-21 2013-04-23 Sud-Chemie Inc. Process for purification of ethylene-containing feedstreams
ES2602116T3 (es) * 2008-12-17 2017-02-17 Basf Se Procedimiento continuo de producción de ciclohexilmetanoles sustituidos
JP5322733B2 (ja) * 2009-03-31 2013-10-23 Ｊｘ日鉱日石エネルギー株式会社 一酸化炭素の選択的酸化反応用触媒の製造方法
WO2011032877A1 (de) 2009-09-18 2011-03-24 Basf Se Verwendung eines stereoisomerengemisches von diaminomethylcyclohexan als härter für epoxidharze
US20110144398A1 (en) 2009-12-11 2011-06-16 Basf Se Process for regenerating a ruthenium-containing supported hydrogenation catalyst
US8921590B2 (en) 2009-12-15 2014-12-30 Exxonmobil Chemical Patents Inc. Oligomerisation process
WO2011082991A2 (de) 2009-12-15 2011-07-14 Basf Se Katalysator und verfahren zur hydrierung von aromaten
ES2719585T3 (es) * 2010-02-12 2019-07-11 Basf Se Procedimiento para la preparación de 4-isopropilciclohexilmetanol
CN102211979A (zh) * 2010-04-02 2011-10-12 盘锦和运新材料有限公司 一种制备2,2-二(4-羟基环己基)丙烷的方法
JP5668368B2 (ja) * 2010-08-25 2015-02-12 三菱瓦斯化学株式会社 ビスシクロヘキシルアミン類の製造方法
EP2619167B1 (en) 2010-09-20 2017-10-25 ExxonMobil Chemical Patents Inc. Process for liquid phase hydrogenation of phthalates
CN102093161B (zh) * 2010-12-31 2014-06-18 景县本源精化有限公司 一种二羟基二环己基丙烷的制备方法
WO2012152821A1 (de) 2011-05-11 2012-11-15 Basf Se Katalysatoren zur hydrierung aromatischer amine
US9180437B2 (en) * 2012-05-10 2015-11-10 Korea Institute Of Science And Technology Method of preparing magnesium oxide structure with meso-macro pores
AU2016232404B2 (en) 2015-03-17 2019-11-07 Akzo Nobel Chemicals International B.V. Process for the purification of monochloroacetic acid
WO2017009427A1 (en) * 2015-07-14 2017-01-19 Bp P.L.C. Extruded titania-based material comprising mesopores and macropores
US9956553B2 (en) 2016-06-28 2018-05-01 Chevron U.S.A. Inc. Regeneration of an ionic liquid catalyst by hydrogenation using a macroporous noble metal catalyst
US10919030B2 (en) 2016-09-30 2021-02-16 Regents Of The University Of Minnesota Forming dienes from cyclic ethers and diols, including tetrahydrofuran and 2-methyl-1,4-butanediol
TWI640498B (zh) * 2017-05-31 2018-11-11 南亞塑膠工業股份有限公司 一種產製高反／反異構物比例之氫化型丙二酚的氫化方法
KR102324239B1 (ko) 2017-11-06 2021-11-08 한화솔루션 주식회사 방향족 화합물의 수소화 반응용 촉매 및 이의 제조방법
KR102275691B1 (ko) 2017-11-21 2021-07-09 한화솔루션 주식회사 사이클로도데카트라이엔의 선택적 수소화 촉매 및 이의 제조방법
KR102174654B1 (ko) * 2018-12-19 2020-11-05 한국과학기술연구원 복합 분리막을 포함하는 암모니아 분해 분리막 반응기
PL3931175T3 (pl) 2019-02-25 2024-07-29 Basf Se Sposób przetwarzania estrów kwasu benzenopolikarboksylowego i ich zastosowanie do wytwarzania estrów kwasu cykloheksanopolikarboksylowego
CN110449151A (zh) * 2019-09-03 2019-11-15 福州大学 一种负载型Pd/ZrO2催化剂的制备方法及其应用

Family Cites Families (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2456428A (en) 1944-10-11 1948-12-14 Shell Dev Polyallyl amine and related polymeric amines
US2647146A (en) 1949-07-01 1953-07-28 Du Pont Process for the preparation of diprimary diamines
US2585583A (en) 1949-08-01 1952-02-12 Du Pont Hydrogenated butadiene-acrylonitrile copolymer
US2606925A (en) 1949-12-15 1952-08-12 Du Pont Ruthenium catalyzed hydrogenation process for obtaining aminocyclohexyl compounds
US2822392A (en) 1954-09-20 1958-02-04 Abbott Lab Process for producing cyclohexylamine
US2927127A (en) 1958-04-08 1960-03-01 Ameringen Haebler Inc Van Process for producing para tertiary butyl cyclohexanyl esters and the intermediate alcohol therefor
US3122526A (en) 1960-04-29 1964-02-25 American Cyanamid Co Compositions containing a plurality of amine groups
US3333024A (en) 1963-04-25 1967-07-25 Shell Oil Co Block polymers, compositions containing them and process of their preparation
US3636108A (en) 1965-12-23 1972-01-18 Du Pont Catalytic hydrogenation of aromatic nitrogen containing compounds over alkali moderated ruthenium
US3520928A (en) 1967-08-25 1970-07-21 Koppers Co Inc Hydrogenation of phenylprimary amines to cyclohexyl amines
US3591635A (en) 1968-09-25 1971-07-06 Upjohn Co Catalytic hydrogenation process for preparing di(4 - aminocyclohexyl) methane
US3595942A (en) 1968-12-24 1971-07-27 Shell Oil Co Partially hydrogenated block copolymers
US3595295A (en) 1969-04-11 1971-07-27 Kenneth D Curry Tire tread trimming and truing apparatus
US3810957A (en) 1970-08-10 1974-05-14 Shell Oil Co Selectively hydrogenated block copolymer-polystyrene blends
US3697449A (en) 1970-12-14 1972-10-10 Du Pont Alkali moderation of supported ruthenium catalysts
US3700633A (en) 1971-05-05 1972-10-24 Shell Oil Co Selectively hydrogenated block copolymers
FR2254542B1 (ko) * 1973-12-13 1976-05-14 Inst Francais Du Petrole
US3898155A (en) * 1973-12-19 1975-08-05 Gulf Research Development Co Heavy oil demetallization and desulfurization process
LU74570A1 (ko) * 1976-03-16 1977-09-27
US4218308A (en) * 1976-05-26 1980-08-19 Toa Nenryo Kogyo Kabushiki Kaisha Hydrogenation catalyst
GB2011911B (en) * 1977-10-20 1982-09-15 Johnson Matthey Co Ltd Production of stable polymers
GB2087403B (en) 1977-10-20 1983-01-19 Johnson Matthey Co Ltd Hydrogenation of polymers
JPS5548392A (en) 1978-02-17 1980-04-07 Toyo Jozo Co Ltd Novel immobilizing material combined with biologically active substance, its preparation, device comprising it, method, and preparation of support
JPS54122253A (en) 1978-03-13 1979-09-21 Shin Etsu Chem Co Ltd Preparation of cis-alkylcyclohexanol
DE2823165A1 (de) † 1978-05-26 1979-11-29 Bayer Ag Verfahren zur herstellung von cycloaliphatischen carbonsaeureestern
DE3045719A1 (de) 1980-12-04 1982-07-08 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von cycloaliphatischen und/oder aromatischen aminen
US4384142A (en) 1981-06-09 1983-05-17 Monsanto Company Production of cyclohexylamine
JPS5817103A (ja) 1981-07-24 1983-02-01 Nippon Zeon Co Ltd 共役ジエン系重合体の水素化方法
US4424162A (en) * 1981-08-31 1984-01-03 Uop Inc. Selective hydrogenation of fatty materials
JPS59196843A (ja) 1983-04-21 1984-11-08 Sumitomo Chem Co Ltd シクロヘキシルアミン類の製造方法
US4419155A (en) 1983-04-29 1983-12-06 The United States Of America As Represented By The Secretary Of The Navy Method for preparing ternary mixtures of ethylenediamine dinitrate, ammonium nitrate and potassium nitrate
DE3401343A1 (de) 1983-10-22 1985-05-09 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von 2- und 4-tert.-butylcyclohexanol mit hohen anteilen an cis-isomeren durch katalytische hydrierung der entsprechenden tert.-butylphenole
US4560817A (en) 1984-03-02 1985-12-24 Phillips Petroleum Company Hydrogenation catalyst
JPS6470446A (en) 1987-06-24 1989-03-15 New Japan Chem Co Ltd Production of cyclohexylamine
DE3801755A1 (de) * 1988-01-22 1989-07-27 Bayer Ag Ruthenium-traegerkatalysator, seine herstellung und sein einsatz bei der herstellung von gegebenenfalls substituiertem cyclohexylamin und gegebenenfalls substituiertem dicyclohexylamin
DE3801756A1 (de) * 1988-01-22 1989-08-03 Bayer Ag Ruthenium-katalysator, verfahren zu seiner herstellung und verfahren zur herstellung eines gemisches aus cyclohexylamin und dicyclohexylamin unter einsatz des ruthenium-katalysators
US5110779A (en) 1989-01-09 1992-05-05 The Dow Chemical Company Polymer hydrogenation catalysts
US5028665A (en) * 1989-01-09 1991-07-02 The Dow Chemical Company Polymer hydrogenation catalysts
JPH0822378B2 (ja) * 1989-07-07 1996-03-06 財団法人石油産業活性化センター 炭化水素の水蒸気改質用触媒
JP2814711B2 (ja) * 1990-07-13 1998-10-27 三菱化学株式会社 シクロオレフィンの製造法
DE4106543A1 (de) 1991-03-01 1992-09-03 Bayer Ag Edelmetall-traegerkatalysator, verfahren zu seiner herstellung und verfahren zur herstellung eines gemisches aus cyclohexylamin und dicyclohexylamin unter einsatz dieses katalysators
US5322965A (en) 1991-03-01 1994-06-21 Bayer Aktiengesellschaft Process for the preparation of a mixture of cyclohexylamine and dicyclohexylamine using a supported noble metal catalyst
US5399259A (en) * 1992-04-20 1995-03-21 Texaco Inc. Hydroconversion process employing catalyst with specified pore size distribution
JPH0649203A (ja) * 1992-06-01 1994-02-22 Asahi Chem Ind Co Ltd ポリアルコール製造方法
DE4339138A1 (de) 1993-11-16 1995-05-18 Basf Ag Trägerkatalysatoren
EP0659718B1 (en) * 1993-12-24 1997-06-18 Mitsubishi Chemical Corporation Method for producing a cycloolefin
US5565092A (en) 1994-03-16 1996-10-15 Exxon Chemical Patents Inc. Halogen resistant hydrogenation process and catalyst
DE19533718A1 (de) * 1995-09-12 1997-03-13 Basf Ag Verfahren zur Hydrierung von aromatischen Verbindungen, in denen mindestens eine Aminogruppe an einen aromatischen Kern gebunden ist
DE19610545A1 (de) * 1996-03-18 1997-09-25 Bayer Ag Verfahren zur Herstellung eines Gemisches von Aminomethylcyclohexanen und Diamino-methyl-cyclohexanen

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100343752B1 (ko) * 2000-04-12 2002-07-25 한국에너지기술연구원 할로겐화 휘발성 유기화합물과 일반 휘발성 유기화합물동시 제어용 고활성 복합 산화촉매와 그 제조 방법 및이를 이용한 촉매 반응 제어 방법
WO2002047814A1 (en) * 2000-12-14 2002-06-20 Samsung General Chemicals Co., Ltd. The stable catalyst for hydropurification

Also Published As

Publication number Publication date
EP0814098B1 (de) 2004-04-28
CN1095690C (zh) 2002-12-11
EP0814098A2 (de) 1997-12-29
US6388149B2 (en) 2002-05-14
EP0814098B2 (de) 2013-09-04
US20010000035A1 (en) 2001-03-15
KR100464581B1 (ko) 2005-07-04
DE59711558D1 (de) 2004-06-03
EP0814098A3 (de) 1999-11-10
JPH1072377A (ja) 1998-03-17
US6248924B1 (en) 2001-06-19
CN1174753A (zh) 1998-03-04

Similar Documents

Publication Publication Date Title
KR980000573A (ko) 지지된 루테늄 촉매의 존재하에 유기 화합물을 반응시키는 방법
KR980000572A (ko) 지지된 루테늄 촉매의 존재하에 유기 화합물을 반응시키는 방법
KR970014834A (ko) 탄화수소 스트림 내 아세틸렌의 선택적 접촉 수소화에 사용되는 지지된 팔라듐 촉매
EP1109767B1 (en) Two-stage process for the production of 1,3-propanediol by catalytic hydrogenation of 3-hydroxypropanal
US5734070A (en) Hardening of unsaturated fats, fatty acids or fatty acid esters
MXPA03008976A (es) Proceso para hidrogenacion selectiva de alquinos y catalizador del mismo.
BR9000066A (pt) Composicao catalisadora,processo para sua sintese e processo para a hidrogenacao de materiais polimericos insaturados
MY145567A (en) Method for producing ethylene and propylene
EP1799630A4 (en) PROCESS FOR OBTAINING DIMETHYL ETHER FROM RAW METHANOL IN AN ADIABATIC REACTOR
RU2008135327A (ru) Катализатор для производства ароматических углеводородных соединений
KR970033027A (ko) 선택적인 수소첨가반응 촉매 및 그 촉매를 사용하는 방법
CA2197109A1 (en) Hydrogenation of aromatic compounds in which at least one hydroxyl group is bonded to an aromatic ring
US6392062B1 (en) Method for carrying out homogeneously catalyzed reactions
CA2306801A1 (en) Process for the production of n-butanol
EP1935864A4 (en) PROCESS FOR THE PRODUCTION OF ETHYLENE AND PROPYLENE
TW200709849A (en) Heterogeneous ruthenium catalyst and process for hydrogenating a carbocyclic aromatic group, in particular for preparing ring-hydrogenated bisglycidyl ethers of bisphenols a and F
KR940009058A (ko) 수소 제조법과 그에 사용되는 촉매
WO2010005859A3 (en) Processes for hydrogenation
HUP0202902A2 (hu) Metatézis-katalizátorok
GR3006268T3 (ko)
ES2153292A1 (es) Procedimiento para producir alcohol alfa-feniletilico.
AU2544600A (en) Method for hydrogenating aromatic polymers in the presence of special catalysts
BR9912352A (pt) Processo para hidrogenação de polìmeros aromáticos na presença de catalisadores especiais
Coman et al. Low metal loading Ru-MCM-41 stereocontrolled hydrogenation of prostaglandin intermediates
Zhu et al. A comparative study of the catalytic behavior of SBA-15 supported heteropoly acid H3PW12O40 and HY catalysts in the alkylation of benzene with 1-dodecene

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20121206

Year of fee payment: 9

FPAY Annual fee payment

Payment date: 20131217

Year of fee payment: 10

FPAY Annual fee payment

Payment date: 20141126

Year of fee payment: 11

FPAY Annual fee payment

Payment date: 20151217

Year of fee payment: 12

FPAY Annual fee payment

Payment date: 20161215

Year of fee payment: 13

EXPY Expiration of term