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KR960031541A - 폴리올 중합체의 분산액 및 에멜션의 혼합물을 기재로 하는 페인트용 조성물 및 그로부터 제조되는 도포액 - Google Patents

폴리올 중합체의 분산액 및 에멜션의 혼합물을 기재로 하는 페인트용 조성물 및 그로부터 제조되는 도포액 Download PDF

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KR960031541A
KR960031541A KR1019960004088A KR19960004088A KR960031541A KR 960031541 A KR960031541 A KR 960031541A KR 1019960004088 A KR1019960004088 A KR 1019960004088A KR 19960004088 A KR19960004088 A KR 19960004088A KR 960031541 A KR960031541 A KR 960031541A
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advantageously
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polyhydroxylated polymer
polyisocyanate
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KR100474778B1 (ko
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게렝 쥘르
랑글루와 브뤼노
뽕스 아르노
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프랑스와 리깔랑
롱-쁠랑 쉬미
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
    • C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
    • C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
    • C08G18/0866—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
    • C—CHEMISTRY; METALLURGY
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225—Polymers of esters of acrylic or methacrylic acid
    • C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
    • C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
    • C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/794—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aromatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
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    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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Abstract

본 발명은 주제는 하기 성분을 함유하는 조성물이다. : -0.1 내지 10㎛, 바람직하게는 0.2 초과 2㎛ 미만의 평균 크기 수성의 에멀션 형태에서 하나 이상의 차폐 또는 차폐되지 않은 폴리이소시아네이트, 및 -10 내지 200㎚의 평균 크기의 2차 수성의 분산액 형태인 하나 이상의 폴리히드록실화 중합체, 이롭게는 하나 이상의 폴리올.
이러한 조성물은, 혼합물에서의 폴리히드록실화 중합체의 양은 R이 폴리히드록실화 중합체, 이롭게는 폴리올 분산액의 평균 크기에 대한 그 에멀션의 평균 크기(d50)의 비와 동일할 때, 하기 두 제한중 하나를 만족시키도록 선택됨을 특징으로 한다. : -중량%로 표시되는 폴리올의 함량은 35~0.75R 이상, 이롭게는 40~0.75R 이상, 바람직하게는 45~0.75R 이상이다. ; -중량%로 표시되는 폴리히드록실화 중합체의 함량은 45~2R, 이롭게는 40~2R, 바람직하게는 35~2R을 초과하지 않는다.

Description

폴리올 중합체의 분산액 및 에멀션의 혼합물을 기재로 하는 페인트용 조성물 및 그로부터 제조되는 도포액
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 성분 : -0.1 내지 10㎛, 바람직하게는 0.2 초과 2㎛ 미만의 평균 크기의 수성 에멀션 형태인 하나 이상의 차폐 또는 차폐되지 않은 폴리이소시아네이트, 및 -10 내지 200㎚의 평균 크기의 수성 분산액 형태인 하나 이상의 폴리히드록실화 중합체, 유리하게는 폴리올을 함유하는 조성물에 있어서, 혼합물에서는 폴리히드록실화 중합체(들)의 양은 R이 폴리히드록실화 중합체, 이롭게는 폴리올 분산액의 평균 크기에 대한 에멀션의 평균 크기(d50)의 비와 동일할 때, 하기 두 제한중 하나를 만족시키도록 선택됨을 특징으로 하는 조성물 : -중량%로 표시되는 폴리히드록실화 중합체(들)의 함량은 35~0.75R 이상, 이롭게는 40~0.75R 이상, 바람직하게는 45~0.75R 이상 이다. ; -중량%로 표시되는 폴리히드록실화 중합체(들)의 함량은 45~2R, 이롭게는 40~2R, 바람직하게는 35~2R을 초과하지 않는다.
  2. 제1항에 있어서, 상기 차폐된 또는 차폐되지 않은 폴리이소시아네이트는 (d90-d10)/d50으로 정의되는 다분산성 지료가 2를 초과하지 않고, 이롭게는 1임을 특징으로 하는 조성물.
  3. 제1항 또는 2항에 있어서, 상기 폴리히드록실화 중합체는 다분산성 지표(Ⅰ=(d90-d10)/d50으로 정의)가 2를 초과하지 않고, 이롭게는 1임을 특징으로 하는 조성물.
  4. 제1항 내지 3항 중 어느 한 항에 있어서, 잠복 또는 잠복되지 않은, 차폐된 이소시아네이트 방출의 하나 이상의 촉매, 특별히 주석 기재 촉매를 더 함유함을 특징으로 하는 조성물.
  5. 제1항 내지 4항 중 어느 한 항에 있어서, 상기 조성물의 수 함량이 조성물 중량의 1/3, 이롭게는 2/5 이상임을 특징으로 하는 조성물.
  6. 제1항 내지 5항 중 어느 한 항에 있어서, 상기 폴리이소시아네이트(들)은 하나 이상의 이소시아누릭 고리를 가지며, 및/또는 비우렛 또는 이량체 형의 하나 이상의 작용기를 가짐을 특징으로 하는 조성물.
  7. 제1항 내지 6항 중 어느 한 항에 있어서, 상기 폴리이소시아네이트가 하나 이상의 이소시아네이트 작용기의 질소가 이롭게는 하나, 바람직하게는 두개의 수소원자를 갖는 sp3혼성화로 탄소에 부착된 것으로부터 선택됨을 특징으로 하는 조성물.
  8. 제1항 내지 7항 중 어느 한 항에 있어서, 상기 폴리이소시아네이트는 페놀, 케톤 옥심 및 특별하게는 메틸 에틸 케톤 옥심 및 다양한 피라졸과 같은 그 자체가 공지된 차폐제로 특별히 차폐된 것으로부터 선택됨을 특징으로 하는 조성물.
  9. 제1항 내지 8항에 따른 조성물을 가교 결합함으로 수득될 수 있음을 특징으로 하는 도포액.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960004088A 1995-02-21 1996-02-21 폴리올중합체의분산액및에멜션의혼합물을기재로하는페인트용조성물및그로부터제조되는도포액 KR100474778B1 (ko)

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FR95-02000 1995-02-21
FR9502000A FR2730737B1 (fr) 1995-02-21 1995-02-21 Composition utile pour la peinture a base de melange d'emulsion(s) et de dispersion(s) de polymere polyol et revetement(s) qui en sont issus

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FR2730737A1 (fr) 1996-08-23
US5945165A (en) 1999-08-31
CN1134439A (zh) 1996-10-30
US5994460A (en) 1999-11-30
FR2730737B1 (fr) 1997-06-06
HU9600387D0 (en) 1996-04-29
US20030181577A1 (en) 2003-09-25
EP0728787A1 (fr) 1996-08-28
DE69624856T2 (de) 2003-08-28
HUP9600387A2 (en) 1997-04-28
ZA961201B (en) 1996-08-23
US7244782B2 (en) 2007-07-17
BR9600769A (pt) 1997-12-23
DK0728787T3 (da) 2003-03-17
HU217797B (hu) 2000-04-28
JPH08253730A (ja) 1996-10-01
HUP9600387A3 (en) 1997-11-28
CN1077587C (zh) 2002-01-09
DE69624856D1 (de) 2003-01-02
ATE228149T1 (de) 2002-12-15
US5853807A (en) 1998-12-29
JP3983891B2 (ja) 2007-09-26
CA2169896A1 (fr) 1996-08-22
CA2169896C (fr) 2000-08-22
US20010004652A1 (en) 2001-06-21
JP2987095B2 (ja) 1999-12-06
ES2187626T3 (es) 2003-06-16
US20050234188A1 (en) 2005-10-20
JPH10310623A (ja) 1998-11-24
EP0728787B1 (fr) 2002-11-20
US5739206A (en) 1998-04-14
AU720398B2 (en) 2000-06-01
KR100474778B1 (ko) 2005-07-21
MX9600667A (es) 1997-02-28
US6972308B2 (en) 2005-12-06
AU4441296A (en) 1996-08-29

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