[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

KR960031535A - 시클로올레핀 수지조성물 - Google Patents

시클로올레핀 수지조성물 Download PDF

Info

Publication number
KR960031535A
KR960031535A KR1019960002942A KR19960002942A KR960031535A KR 960031535 A KR960031535 A KR 960031535A KR 1019960002942 A KR1019960002942 A KR 1019960002942A KR 19960002942 A KR19960002942 A KR 19960002942A KR 960031535 A KR960031535 A KR 960031535A
Authority
KR
South Korea
Prior art keywords
cycloolefin
block copolymer
resin composition
cycloolefin resin
weight
Prior art date
Application number
KR1019960002942A
Other languages
English (en)
Inventor
토시유끼 히로세
요오즈 야마모토
Original Assignee
고다 시게노리
미쓰이세키유 가가쿠고교 가부끼가이샤
게르하르트 알미히 · 노베르트 쉬엔케
훽스트 아크티엔 게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 고다 시게노리, 미쓰이세키유 가가쿠고교 가부끼가이샤, 게르하르트 알미히 · 노베르트 쉬엔케, 훽스트 아크티엔 게젤샤프트 filed Critical 고다 시게노리
Publication of KR960031535A publication Critical patent/KR960031535A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L45/00—Compositions of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

본 발명의 시클로올레핀 수지 조성물은 시클로올레핀수지(A), 특히 에틸렌/시클로올레핀 랜덤공중합체 60~90중량부 및 수평균분자량이 75,000~500,000인 방향족 비닐/공액디엔블록공중합체 및/또는 그의 수소첨가물(B), 특히 스티렌/부타디엔블록공중합체 및/또는 그의 수소첨가물 10~40중량부로 구성되며, 본 발명의 성형품은 상기 조성물로부터 형성한 것이다. 상기 조성물과 그로부터 형성된 성형품은 충격강도와 방습성이 우수하다.

Description

시클로올레핀 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. (A) (A-1) 에틸렌과 하기식(Ⅰ) 또는 (Ⅱ)으로 표시되는 시클로올레핀의 에틸렌/시클로올레핀 랜덤공중합체, (A-2) 하기식(Ⅰ) 또는 (Ⅱ)으로 표시되는 시클로올레핀의 개환(공)중합체, (A-3) 상기 (A-2)의 수소화물 (A-4) 상기 (A-1), (A-2) 또는 (A-3)의 그라프트변성물로 구성된 그룹으로부터 선택한 적어도 하나의 시클로올레핀 수지 60~90중량부와, (B) 수평균분자량이 75,000~500,000인 방향족비닐/공액디엔블록공중합체 및/또는 그의 수소첨가물 10~40중량부로 구성된 것이 특징인 시클로올레핀 수지 조성물.
    상기 식에서 n은 0 또는 1, m은 0 또는 양의 정수, q는 0 또는 1, R1~R18, Ra및 Rb각각 독립적으로 수소원자, 할로겐원자 또는 할로겐원자로 치환될 수 있는 탄화수소기를 나타내며, R15~R18이 상호결합하여 이중결합을 가질수도 있는 단환 또는 다환을 형성할 수도 있고, 또한 R15과 R16의 조합 또는 R17과 R18의 조합이 알킬리덴기를 형성할 수도 있다.
    상기 식에서, p와 q는 0 또는 1 이상의 정수, m과 n 각각은 0, 1, 또는 2, R1~R19는 각각 독립적으로 수소원자, 할로겐원자, 할로겐원자로 치환될 수 있는 탄화수소가 또는 할로겐원자로 치환될 수 있는 알콕시기를 나타내며, R9또는 R10이 결합한 탄소원자와 R13또는 R11이 결합한 탄소원자가 서로 직접 또는 탄소원자수가 1~3인 알킬렌기를 거쳐 결합할 수 있고, 또한 n=m=0일 때 R15와 R12의 조합 또는 R15와 R19의 조합이 서로 결합하여 방향족단환 또는 방향족다환을 형성할 수 있다.
  2. 제1항에 있어서, 상기 방향족비닐/공액디엔블록공중합체 및/또는 그의 수소첨가물(B)이 스티렌-에틸렌/프로필렌-스티렌블록공중합체 또는 스티렌-에틸렌/부텐-스티렌블록공중합체인 것이 특징인 시클로올레핀 수지 조성물.
  3. 제1항에 있어서, 상기 방향족 비닐/공액디엔블록공중합체 및/또는 그의 수소첨가물(B)은 수평균분자량이 90,000~200,000인 것이 특징인 시클로올레핀 수지 조성물.
  4. 제1~3 중 어느 한 항에 의한 조성물로부터 형성된 것이 특징인 성형품.
  5. 제1항의 시클로올레핀 수지(A) 60~90중량부와 수평균분자량이 50,000~500,000인 방향족 비닐/공액디엔블록공중합체 및/또는 그의 수소첨가물(B) 10~40중량부로 된 시클로올레핀 수지 조성물을 프레스성형하여 얻은 성형품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960002942A 1995-02-07 1996-02-07 시클로올레핀 수지조성물 KR960031535A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP1958895 1995-02-07
JP95-19588 1995-02-07

Publications (1)

Publication Number Publication Date
KR960031535A true KR960031535A (ko) 1996-09-17

Family

ID=12003425

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960002942A KR960031535A (ko) 1995-02-07 1996-02-07 시클로올레핀 수지조성물

Country Status (4)

Country Link
EP (1) EP0726291A1 (ko)
KR (1) KR960031535A (ko)
CN (1) CN1134958A (ko)
CA (1) CA2168927A1 (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6090888A (en) * 1996-06-06 2000-07-18 Hoechst Celanese Corporation Cyclic olefin polymer blends exhibiting improved impact resistance and good transparency
US20020061982A1 (en) 1999-06-11 2002-05-23 Donald Robert J. Compositions comprising hydrogenated block copolymers and end-use applications thereof
US20020061981A1 (en) 1999-06-11 2002-05-23 Donald Robert J. Compositions comprising hydrogenated block copolymers and end-use applications thereof
US6426390B1 (en) 1999-06-11 2002-07-30 Dow Global Technology Inc. Hydrogenated block copolymer compositions
US6429260B1 (en) 2000-05-31 2002-08-06 The Dow Chemical Company Olefinic polymer compositions
DE602004005827T2 (de) 2003-01-28 2008-01-10 Cryovac, Inc. Cycloolefinpolymer für hochmodulige folien
CN101052569B (zh) * 2004-11-01 2011-01-12 旭化成化学株式会社 易开封袋
EP1714779A1 (en) * 2005-04-20 2006-10-25 Cellografica Gerosa S.p.A. Film for packaging applications, in particular twisted packaging applications
WO2008018951A1 (en) 2006-08-04 2008-02-14 Exxonmobil Chemical Patents Inc. Polymer compositions comprising cyclic olefin polymers, polyolefin modifiers, and fillers
US8519056B2 (en) 2007-06-01 2013-08-27 Exxonmobil Chemical Patents Inc. Blends of co-precipitated hydrogenated ethylene-dicyclpentadiene and elastomeric polymers to provide impact modified structural polyolefins
US8802063B2 (en) * 2010-12-29 2014-08-12 Avon Products, Inc. Cosmetic composition
JP2013010937A (ja) * 2011-05-31 2013-01-17 Canon Inc 組成物、光学素子、レンズ、前記組成物の製造方法
US11193030B2 (en) 2016-06-24 2021-12-07 Avient Corporation COC polymer compounds for 3D printing
US11732075B2 (en) 2017-11-29 2023-08-22 Mitsui Chemicals, Inc. Cyclic olefin-based copolymer, cyclic olefin-based copolymer composition, molded article, and medical container
CN112457617B (zh) * 2020-11-23 2022-09-13 金发科技股份有限公司 一种高透明低介电损耗增韧环状聚烯烃材料及其制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3854997T2 (de) * 1987-10-08 1996-06-13 Mitsui Petrochemical Ind Random-cycloolefin-kopolymerzusammensetzung
JP3175293B2 (ja) * 1992-04-06 2001-06-11 ジェイエスアール株式会社 延伸フィルム

Also Published As

Publication number Publication date
CA2168927A1 (en) 1996-08-08
EP0726291A1 (en) 1996-08-14
CN1134958A (zh) 1996-11-06

Similar Documents

Publication Publication Date Title
KR960031535A (ko) 시클로올레핀 수지조성물
EP0942004A3 (en) Anionic polymerization initiators for preparing branched diene rubbers
KR970705611A (ko) 폴리카보네이트와 에틸렌 중합체의 블렌드(blends of polycarbonate and ethylene polymers)
CA2444534A1 (en) Thermoplastic elastomer composition
AU6515199A (en) Semi-transparent blends of polyphenylene ether, styrenic resins, and elastomericblock copolymers
CA2178742A1 (en) Novel Resin Composition
DK0566106T3 (da) Teknisk harpiks-propylenpodepolymersammensætning
EP0831125A4 (en) THERMOPLASTIC RESIN COMPOSITION AND INJECTION MOLDING OBTAINED FROM IT
KR920702391A (ko) 폴리올레핀 수지 조성물
KR960037753A (ko) 열가소성 엘라스토머조성물
CA2120734A1 (en) Thermoformable, Chemical Resistant Polymer Blends
KR960037762A (ko) 열가소성 수지 조성물 및 그의 사출 성형품
KR870002184A (ko) 내유성 고무조성물
MX9602742A (es) Una composicion termpoplastica de moldeado compatibilizada.
AU2001263475A1 (en) Polyolefin materials having enhanced surface durability
KR930021709A (ko) 모노비닐 방향족-공역디엔 블럭 공중합체 브렌드 조성물 및 그로 구성되는 물품
KR940007121A (ko) 비튜멘 및 비튜멘의 개질용으로 적당한 중합체 조성물의 혼합물
MXPA01010060A (es) Composiciones para relleno de cables.
WO2002057364A3 (en) Poly(arylene ether)-polyolefin composition and articles derived therefrom
EP0945491A3 (en) Resin composition and molded products
CA2010319A1 (en) Foamable polymer composition and foamed article
KR910011546A (ko) 에어백 수납용 커버
DE69504864D1 (de) Zusammensetzung verwendbar für elastomere artikel und aus dieser zusammensetzung hergestellte artikel
MY128633A (en) Impact modifier having improved blocking resistance
EP0387864A3 (en) Thermoplastic resin composition

Legal Events

Date Code Title Description
PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19960207

PG1501 Laying open of application
PC1203 Withdrawal of no request for examination
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid