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KR960029364A - 폴리에스테르 폴리올 및 2성분계 폴리우레탄 코팅 조성물 중의 결합제 성분으로서의 그의 용도 - Google Patents

폴리에스테르 폴리올 및 2성분계 폴리우레탄 코팅 조성물 중의 결합제 성분으로서의 그의 용도 Download PDF

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KR960029364A
KR960029364A KR1019960000187A KR19960000187A KR960029364A KR 960029364 A KR960029364 A KR 960029364A KR 1019960000187 A KR1019960000187 A KR 1019960000187A KR 19960000187 A KR19960000187 A KR 19960000187A KR 960029364 A KR960029364 A KR 960029364A
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mol
alcohol
aliphatic
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KR1019960000187A
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KR100404553B1 (ko
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밤프레히트 크리스티안
존타크 미카엘
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로타르 스타일링ㆍ뤼디거 드로페
바이엘 악티엔게젤샤프트
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/20Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67Unsaturated compounds having active hydrogen
    • C08G18/68Unsaturated polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/06Polyurethanes from polyesters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 (a) 3개 이상의 히드록실기 및 3 내지 8개의 탄소 원자를 갖는 1종 이상의 지방족 또는 시클로지방족 알콜을 함유하는 알콜 성분과 (b) 이타콘산, 말레산, 이들의 무수물 및/또는 푸마르산을 함유하는 카르복실산 성분(단, 성분 (a) 또는 성분 (b)의 10몰%이상이 1내지 18개의 탄소 원자를 갖는 포화 또는 불포화 지방족 또는 시클로지방족 모노알콜 또는 모노카르복실산임)의 에스테르화 생성물이며, 60 내지 400의 히드록실 수를 갖는 폴리에스테르 폴리올에 관한 것이다.
본 발명은 또한 결합제로서 상기 폴리에스테르 폴리올 및 래커 폴리이소시아네이트를 함유하는 2성분계 폴리 우레탄 코팅 조성물, 및 코팅 기재, 특히 자동차용 기재를 위한 이들의 용도에 관한 것이다.

Description

폴리에스테르 폴리올 및 2성분계 폴리우레탄 코팅 조성물 중의 결합제 성분으로서의 그의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. (a) 다음의 성분들 (a1) 3개 이상의 히드록실기 및 3 내지 8개의 탄소 원자를 갖는 1종 이상의 지방족 또는 시클로지방족 알콜, (a2) 임의로, 2개의 히드록실기 및 2 내지 18개의 탄소 원자를 갖는 1종 이상의 지방족 또는 시클로지방족 알콜 및 (a3) 임의로 1개의 히드록실기 및 1 내지 18개의 탄소 원자를 갖는 1종 이상의 포화 또는 불포화 지방족 또는 시클로지방족 알콜로 이루어지는 알콜 성분과 (b) 다음의 성분들 (b1) 이타콘산, 말레산, 이들의 무수물 및/또는 푸마르산, (b2) 임의로, 2개 이상의 탄소 원자를 갖는 1종 이상의 포화또는 불포화 지방족 또는 시클로지방족 디카르복실산 및/또는 상기 (b1) 하에 설명된 것 이외의 이들의 무수물과 (b3) 임의로, 1 내지 18개의 탄소 원자를 갖는 1종 이상의 포화 또는 불포화 지방족 또는 시클로지방족 모노카르복실산 및/또는 이들의 무수물로 이루어지는 카르복실산 성분(단, 성분 (a3)가 성분(a)전체 몰에 기초하여 10몰%이상의 양으로 사용되거나 또는 성분(b3)가 성분(b)의 전체 몰에 기초하여 10몰% 이상의 양으로 사용됨)의 에스테르화 생성물이며, 60 내지 400의 히드록실수를 갖는 폴리에스테르 폴리올.
  2. 제1항에 있어서, (a) 성분 (a1) 30내지 90몰%, 성분 (a2) 0 내지 60몰%및 성분 (a3) 10 내지 50몰%를 함유하는 알콜 성분의 53.5 내지 65.8당량%와 (b) 성분 (b1) 10 내지 100몰% 및 성분 (b2) 0 내지 90몰%를 함유하는 카르복실산 성분의 34.2 내지 46.5당량% (여기서, 성분 (a)와 (b), (a1) 내지 (a3) 및 (b1)과 (b2)의 백분율은 각각의 경우에 총합이 100임)의 에스테르화 생성물이며, 80 내지 350의 히드록실 수를 갖는 폴리에스테르 폴리올.
  3. 제1항에 있어서, (a) 성분 (a1) 30내지 100몰% 및 성분 (a2) 0 내지 70몰%를 함유하는 알콜성분의 53.5 내지 65.8당량%와 (b) 성분 (b1) 10 내지 90몰%, 성분 (b2) 0 내지 80몰% 및 성분 (b3) 10 내지 50몰%를 함유하는 카르복실산 성분의 34.2 내지 46.5당량% (여기서, 성분 (a)와 (b), (a1)과 (a2), 및 (b1)내지 (b3)의 백분율은 각각의 경우에 총합이 100임)의 에스테르화 생성물이며, 80 내지 350의 히드록실수를 갖는 폴리에스테르 폴리올.
  4. 결합제로서 래커 폴리이소시아네이트 및 제1항의 폴리에스테르 폴리올을 함유하며, 임의로 다른 유기 폴리히드록실 화합물과 혼합된 2성분계 폴리우레탄 코팅 조성물.
  5. 결합제로서 래커 폴리이소시아네이트 및 제1항의 폴리에스테르 폴리올을 함유하며, 임의로 폴리아크릴레이트 폴리올, 제1항의 폴리에스테르 폴리올 이외의 폴리에스테르 폴리올, 폴리카르보네이트 폴리올, 우레탄 기를 갖는 폴리올 및 이들의 혼합물로 이루어지는 군으로부터 선택된 다른 폴리히드록실 화합물을 전체 히드록실 당량에 기초하여 90 히드록실 당량% 이상으로 혼합시킨 2성분계 폴리우레탄 코팅 조성물.
  6. 제4항의 코팅 조성물로 코팅시킨 코팅된 기재.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960000187A 1995-01-09 1996-01-08 폴리에스테르폴리올및2성분계폴리우레탄코팅조성물중의결합제성분으로서의그의용도 KR100404553B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19500358.6 1995-01-09
DE19500358A DE19500358A1 (de) 1995-01-09 1995-01-09 Polyesterpolyole und ihre Verwendung in Zweikomponenten-Polyurethanlacken

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KR960029364A true KR960029364A (ko) 1996-08-17
KR100404553B1 KR100404553B1 (ko) 2004-04-28

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US (1) US6423816B1 (ko)
EP (1) EP0720996B1 (ko)
JP (1) JP3406761B2 (ko)
KR (1) KR100404553B1 (ko)
AT (1) ATE224415T1 (ko)
AU (1) AU701525B2 (ko)
CA (1) CA2166656A1 (ko)
DE (2) DE19500358A1 (ko)
ES (1) ES2183850T3 (ko)

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EP0720996A2 (de) 1996-07-10
ES2183850T3 (es) 2003-04-01
DE59510379D1 (de) 2002-10-24
KR100404553B1 (ko) 2004-04-28
US6423816B1 (en) 2002-07-23
DE19500358A1 (de) 1996-07-11
EP0720996B1 (de) 2002-09-18
ATE224415T1 (de) 2002-10-15
AU701525B2 (en) 1999-01-28
EP0720996A3 (de) 1997-09-17
JPH08239458A (ja) 1996-09-17
CA2166656A1 (en) 1996-07-10
AU4068295A (en) 1996-07-18
JP3406761B2 (ja) 2003-05-12

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