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KR940003979A - 폴리프로필렌 왁스의 제조방법 - Google Patents

폴리프로필렌 왁스의 제조방법 Download PDF

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Publication number
KR940003979A
KR940003979A KR1019930015233A KR930015233A KR940003979A KR 940003979 A KR940003979 A KR 940003979A KR 1019930015233 A KR1019930015233 A KR 1019930015233A KR 930015233 A KR930015233 A KR 930015233A KR 940003979 A KR940003979 A KR 940003979A
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호터 게르트
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벡커,바인
훽스트 아크티엔게겔샤프트
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

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  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명에 의하면 마그네슘-알콕시 화합물, 4가 티타늄 화합물, 규소 화합물 및 알루미늄유기 화합물로부터 형성된 촉매계를 중합에 사용할 경우 110℃보다 높은 온도에서 용액 중합에 의해 결정도가 높고 가공성이 양호한 폴리프로필렌 왁스가 수득될 수 있다
당해 방법에 의해 제조된 폴리프로필렌 왁스는 IR분광계로 측정한 이소택틱도가 70%보다 크며 170℃에서 측정한 용융점도가 50 내지 4000mPa. s인, 점성-경질의, 무색, 비점착성, 열안정성의 연마가 용이한 생성물이다. 당해 왁스는 예를 들어, 안료 제조, 인쇄용 잉크의 내마멸성 피니시(finish)및 염소제용 기재 매스로서, 플라스틱의 가공 보조제 (에 : 윤활제 및 이형제)로서, 사진 토우너의 제형 성분으로서 및 융점 상승제로서 적합하다.

Description

폴리프로필렌 왁스의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 하기 일반식(Ⅰ)의 마그네슘 화합물과 하기 일반식(Ⅱ)의 4가 티타늄 화합물과의 반응에 의해 제조된 티타늄-함유 성분 A, 하기 일반식(Ⅲ)의 규소-함유 성분 B및 하기 일반식(Ⅳ)의 알루미늄-유기 성분C로 이루어진 촉매계의 존재하에 110℃이상의 온도, 2 내지 100bar의 압력에서, 프로필렌을 용액중에서 단독중합화하거나 에틸렌 또는 일반식 R-CH=CH2(여기서, R은 탄소수 2내지 38의 알킬 라디칼이다)의 올레핀 0.1 내지 5중량%와 공중합화합으로써 IR 이소택틱도(isotacticity)가 70%보다 크며 용융 점도가 50 내지 4000mpa.s인 폴리프로필렌 왁스를 제조하는 방법.
    Mg(OR1)nX2-n (Ⅰ)
    Ti(OR2)mX4-m (Ⅱ)
    R3pSi(OR4)4-p (Ⅲ)
    R5qA1Cl3-q (Ⅳ)
    상기식에서, R1은 동일하거나 상이한 C1-C10-알킬 라디칼이며, X는 할로겐 원자이고, n은 1 또는 2이며, R2는 동일하거나 상이한 C1-C6-알킬 라디칼이고, m은 0 내 지 4이고, p및 q는 1,2 또는 3이며, R3동일하거나 상이한 C1-C16-알킬 라디칼이고, R4는 동일하거나 상이한 C1-C16-알킬 라디칼이거나 비치환되거나 알킬-치환된 C5-C8-사이클로알킬 라디칼, C6-C18-아릴 라디칼 또는 C7-C18-아르알킬 라디칼이며, R5는 동일하거나 상이한 C1-C30-알킬 라디칼이다.
  2. 제1항에 있어서, 일반식(Ⅰ)의 마그네슘 화합물과 일반식(Ⅱ)의 티타늄 화합물과의 반응이 에테르, 알콜 및 카복실산과 이들의 유도체를 포함하는 그룹중에서 선택된 전자공여체의 존재하에 수행되는 방법.
  3. 하기 일반식(Ⅰ)의 마그네슘 화합물과 하기 일반식 (Ⅱ)의 4가 티타늄 화합물과의 반응에 의해 제조된 티타늄-함유 성분 A, 하기 일반식(Ⅲ)의 규소-함유 성분B 및 하기 일반식(Ⅳ)의 암루미늄-유기 성분C로 이루어진, IR 이소택틱도가 70%보다 크며 170℃에서 측정한 용융 점도가 50 내지 4000mpa.s인 폴리올레핀 왁스 제조용 촉매계.
    Mg(OR1)nX2-n (Ⅰ)
    Ti(OR2)mX4-m (Ⅱ)
    R3pSi(OR4)4-p (Ⅲ)
    R5qA1Cl3-q (Ⅳ)
    상기식에서, R1은 동일하거나 상이한 C1-C10-알킬 라디칼이며, X는 할로겐 원자이고, n은 1 또는 2이며, R2는 동일하거나 상이한 C1-C6-알킬 라디칼이고, m은 0 내지 4이고, p및 q는 1,2 또는 3이며, R3동일하거나 상이한 C1-C16-알킬 라디칼이고, R4는 동일하거나 상이한 C1-C16-알킬 라디칼이거나 비치환되거나 알킬-치환된 C5-C8-사이클로알킬 라디칼, C6-C18-아릴 라디칼 또는 C7-C18-아르알킬 라디칼이며, R5는 동일하거나 상이한 C1-C30-알킬 라디칼이다.
  4. 제3항에 있어서, 성분 A가 티타늄 테트라클로라이드와 일반식 Mg(OR1)2(여기서, R1은 C1-C6-알킬 그룹이다)의 마그네슘 알콜레이트로부터 제조되며, 일반식 (Ⅳ)의 균소 화합물이 사용되는 촉매계.
  5. IR이소택틱도가 70%보다 크며 170℃에서 측정한 용융 점도가 50 내지 4000mpa.s인, 제1항에 따라 수득된 폴리올레핀 왁스
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930015233A 1992-08-08 1993-08-06 폴리프로필렌 왁스의 제조방법 KR940003979A (ko)

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DEP4226321.2 1992-08-08

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EP (1) EP0584586B1 (ko)
JP (1) JPH06157664A (ko)
KR (1) KR940003979A (ko)
AT (1) ATE152739T1 (ko)
AU (1) AU670105B2 (ko)
BR (1) BR9303275A (ko)
CA (1) CA2103694A1 (ko)
CZ (1) CZ160593A3 (ko)
DE (1) DE59306372D1 (ko)
ES (1) ES2104007T3 (ko)
HK (1) HK1006721A1 (ko)
TW (1) TW303368B (ko)

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KR20020000211A (ko) * 2000-06-24 2002-01-05 박윤구 초콜릿이 코팅된 떡의 제조방법 및 이로부터 제조된 떡
KR20030064553A (ko) * 2002-01-28 2003-08-02 박충호 다층 구조의 찰떡 및 그 제조 방법

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US6858071B2 (en) 2000-06-20 2005-02-22 Basf Aktiengesellschaft Solvent-containing pastes containing in addition polyolefin wax
US7589150B2 (en) 2000-12-12 2009-09-15 Baker Hughes Incorporated Low molecular weight isotactic polypropylene polymers, copolymers and derivatives and materials prepared therewith
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JP2006500470A (ja) 2002-09-20 2006-01-05 エクソンモービル・ケミカル・パテンツ・インク 超臨界重合方法およびこれにより製造したポリマー
CN101124235B (zh) 2004-07-08 2010-12-15 埃克森美孚化学专利公司 烯烃聚合催化剂体系及其使用方法
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CN101855249B (zh) 2007-09-13 2013-02-13 埃克森美孚研究工程公司 在线生产增塑聚合物和增塑聚合物共混物的方法
US7910637B2 (en) 2007-09-13 2011-03-22 Exxonmobil Research And Engineering Company In-line blending of plasticizers with a base polymer
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KR20020000211A (ko) * 2000-06-24 2002-01-05 박윤구 초콜릿이 코팅된 떡의 제조방법 및 이로부터 제조된 떡
KR20030064553A (ko) * 2002-01-28 2003-08-02 박충호 다층 구조의 찰떡 및 그 제조 방법

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ATE152739T1 (de) 1997-05-15
EP0584586A2 (de) 1994-03-02
HK1006721A1 (en) 1999-03-12
ES2104007T3 (es) 1997-10-01
TW303368B (ko) 1997-04-21
AU4446093A (en) 1994-02-10
JPH06157664A (ja) 1994-06-07
CA2103694A1 (en) 1994-02-09
EP0584586A3 (en) 1994-08-17
AU670105B2 (en) 1996-07-04
BR9303275A (pt) 1994-03-08
DE59306372D1 (de) 1997-06-12
EP0584586B1 (de) 1997-05-07

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