KR940009364A - 철 도금 알루미늄 합금 부품 및 그 도금 방법 - Google Patents
철 도금 알루미늄 합금 부품 및 그 도금 방법 Download PDFInfo
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- KR940009364A KR940009364A KR1019930021084A KR930021084A KR940009364A KR 940009364 A KR940009364 A KR 940009364A KR 1019930021084 A KR1019930021084 A KR 1019930021084A KR 930021084 A KR930021084 A KR 930021084A KR 940009364 A KR940009364 A KR 940009364A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/48—Coating with alloys
- C23C18/50—Coating with alloys with alloys based on iron, cobalt or nickel
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
- C25D5/42—Pretreatment of metallic surfaces to be electroplated of light metals
- C25D5/44—Aluminium
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1646—Characteristics of the product obtained
- C23C18/165—Multilayered product
- C23C18/1651—Two or more layers only obtained by electroless plating
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1646—Characteristics of the product obtained
- C23C18/165—Multilayered product
- C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/54—Contact plating, i.e. electroless electrochemical plating
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/615—Microstructure of the layers, e.g. mixed structure
- C25D5/617—Crystalline layers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/923—Physical dimension
- Y10S428/924—Composite
- Y10S428/926—Thickness of individual layer specified
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/934—Electrical process
- Y10S428/935—Electroplating
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
- Y10T428/12722—Next to Group VIII metal-base component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12736—Al-base component
- Y10T428/1275—Next to Group VIII or IB metal-base component
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Metallurgy (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Chemically Coating (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
390 알루미늄 합금 피스톤(12)와 같은 알루미늄 합금 기판(10)을 철로 도금하는 방법은 (가) 알루미늄 기판상에 아연산염 조로부터 아연산염 층을 도금하는 단계와, (나) 아연산염 층상에 무전해 니켈조로부터 니켈 층(14)를 도금하는 단계와, (다) 니켈 층상에 황상암모늄 철조로부터 철 층(16)을 도금하는 단계와, (라) 철 층상에 알칼리 주석 조로부터 주석 층(18)을 도금하는 단계로 이루어진다. 아래에 놓인 알루미늄을 산화로부터 보호하는 아연층은 무전해 도금중에 소멸된다. 이들 조 모두를 시안화물 및 염화물보다 훨씬 더 안전하다. 또한 이들은 가격면에서 유리하고 전체적으로 폐쇄된 루우프 도금 시스템에서 이용될 수 있다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따라 코팅된 알루미늄 피스톤의 구조를 도시하는 개략도.
Claims (10)
- 철 도금 알루미늄 합금 부품에 있어서, 상기 알루미늄 합금 부품은 상기 부품의 표면 상의 니켈의 제1층(14)와 상기 니켈의 제1층 상의 철의 제2층(16)과, 상기 철의 제2층상의 주석의 제3층(18)을 갖는 것을 특징으로 하는 철 도금 알루미늄 합금 부품.
- 제1항에 있어서, 상기 니켈 층이 두께는 약 0.000005 내지 0.0038cm(0.000002 내지 0.0015인치)이고, 상기 철 층의 두께는 약 0.00051 내지 0.0038cm(0.0002 내지 0.0015인치)이고, 상기 주석 층의 두께는 약 0.000012 내지 0.00025cm(0.000005 내지 0.0001 인치)인 것을 특징으로 하는 철 도금 알루미늄 합금 부품.
- 제2항에 있어서, 상기 니켈 층의 두께가 약 0.0000076 내지 0.000127cm(0.000003 내지 0.000005인치)인 것을 특징으로 하는 철 도금 알루미늄 합금 부품.
- 제2항에 있어서, 상기 철 층의 두께가 약 0.0025cm(0.001인치)인 것을 특징으로 하는 철 도금 알루미늄 합금 부품.
- 제2항에 있어서, 상기 주석 층의 두께가 약 0.0000178 내지 0.0000038cm(0.000007 내지 0.000015 인치)인 것을 특징으로 하는 철 도금 알루미늄 합금 부품.
- 제1항에 있어서, 상기 부품은 390 알루미늄 합금 피스톤(12)로 이루어진 것을 특징으로 하는 철 도금 알루미늄 합금 부품.
- 제1항의 상기 알루미늄 합금 부품들을 도금하는 방법에 있어서, (가) 상기 알루미늄 기판상에 아연산염 조로부터 아연산염 층을 도금하는 단계와, (나) 상기 아연산염 층상에 무전해 니켈 조로부터 니켈 층을 도금하는 단계와, (다) 상기 니켈 층상에 황산철 조로부터 철 층을 도금하는 단계와, (라) 상기 철 층상에 알칼리성 주석 조로부터 주석 층을 도금하는 단계를 포함하는 것을 특징으로 하는 철 도금 알루미늄 합금 부품 도금 방법.
- 제7항에 있어서, 상기 니켈은 무전해 니켈 도금조로부터 도금되는 것을 특징으로 하는 철 도금 알루미늄 합금 부품.
- 제7항에 있어서, 상기 철온 황산 암모늄 제1철의 수용액으로 이루어진 철 도금조로부터 도금되는 것을 특징으로 하는 철 도금 알루미늄 합금 부품.
- 제9항에 있어서, 상기 도금조는 pH가 약 2.0 내지 2.9로 유지되는 황산 암모늄 제1철 약 250 내지 400g/L의 수용액으로 이루어진 것으로 특징으로 하는 철 도금 알루미늄 합금부품.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US95988192A | 1992-10-13 | 1992-10-13 | |
US959,881 | 1992-10-13 |
Publications (2)
Publication Number | Publication Date |
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KR940009364A true KR940009364A (ko) | 1994-05-20 |
KR960006592B1 KR960006592B1 (ko) | 1996-05-20 |
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Application Number | Title | Priority Date | Filing Date |
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KR1019930021084A KR960006592B1 (ko) | 1992-10-13 | 1993-10-12 | 철 도금 알루미늄 합금 부품 및 그 도금 방법 |
Country Status (5)
Country | Link |
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US (2) | US5534358A (ko) |
EP (1) | EP0592946A1 (ko) |
JP (1) | JPH06212454A (ko) |
KR (1) | KR960006592B1 (ko) |
CA (1) | CA2107866A1 (ko) |
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US6656606B1 (en) | 2000-08-17 | 2003-12-02 | The Westaim Corporation | Electroplated aluminum parts and process of production |
US6606983B2 (en) | 2001-09-18 | 2003-08-19 | Federal-Mogul World Wide, Inc. | Ferrous pistons for diesel engines having EGR coating |
DE10159890B4 (de) * | 2001-12-06 | 2006-02-16 | Federal-Mogul Burscheid Gmbh | Verfahren für das Beschichten von Aluminiumwerkstoffen mit Funktionsschichten aus Eisen |
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EP0172002A3 (en) * | 1984-08-13 | 1986-12-30 | Ae Plc | The treatment of pistons |
US4746412A (en) * | 1986-07-03 | 1988-05-24 | C. Uyemura & Co., Ltd. | Iron-phosphorus electroplating bath and electroplating method using same |
US4808279A (en) * | 1986-10-02 | 1989-02-28 | The University Of Toronto Innovations Foundation | Process for preparing magnetic recording material |
US4781799A (en) * | 1986-12-08 | 1988-11-01 | Xerox Corporation | Electroforming apparatus and process |
US4908280A (en) * | 1989-07-10 | 1990-03-13 | Toyo Kohan Co., Ltd. | Scratch and corrosion resistant, formable nickel plated steel sheet, and manufacturing method |
JPH049493A (ja) * | 1990-04-27 | 1992-01-14 | Permelec Electrode Ltd | 鋼板の電気錫メッキ方法 |
DD294512A5 (de) * | 1990-05-16 | 1991-10-02 | Werkzeugmaschinenbau Fz | Verfahren zum herstellen hartmetallaehnlicher oberflaechen auf substraten mit niedrigen werkstoffschmelztemperaturen |
US5129378A (en) * | 1991-09-27 | 1992-07-14 | Brunswick Corporation | Two-cycle marine engine having aluminum-silicon alloy block and iron plated pistons |
US5167791A (en) * | 1991-12-20 | 1992-12-01 | Xerox Corporation | Process for electrolytic deposition of iron |
US5397652A (en) * | 1992-03-27 | 1995-03-14 | The Louis Berkman Company | Corrosion resistant, colored stainless steel and method of making same |
US5368719A (en) * | 1993-05-12 | 1994-11-29 | Hughes Aircraft Company | Method for direct plating of iron on aluminum |
-
1993
- 1993-10-06 CA CA002107866A patent/CA2107866A1/en not_active Abandoned
- 1993-10-07 EP EP93116222A patent/EP0592946A1/en not_active Ceased
- 1993-10-12 KR KR1019930021084A patent/KR960006592B1/ko not_active IP Right Cessation
- 1993-10-13 JP JP5256177A patent/JPH06212454A/ja active Pending
-
1994
- 1994-02-02 US US08/190,816 patent/US5534358A/en not_active Expired - Lifetime
- 1994-02-03 US US08/191,137 patent/US6258415B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US5534358A (en) | 1996-07-09 |
JPH06212454A (ja) | 1994-08-02 |
CA2107866A1 (en) | 1994-04-14 |
EP0592946A1 (en) | 1994-04-20 |
KR960006592B1 (ko) | 1996-05-20 |
US6258415B1 (en) | 2001-07-10 |
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