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KR930023344A - 티오세미카바자이드 - Google Patents

티오세미카바자이드 Download PDF

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Publication number
KR930023344A
KR930023344A KR1019930009185A KR930009185A KR930023344A KR 930023344 A KR930023344 A KR 930023344A KR 1019930009185 A KR1019930009185 A KR 1019930009185A KR 930009185 A KR930009185 A KR 930009185A KR 930023344 A KR930023344 A KR 930023344A
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South Korea
Prior art keywords
hydrogen
formula
alkyl
thiosemicarbazide
cycloalkyl
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KR1019930009185A
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English (en)
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호이에르 루쯔
쿠글러 마르틴
파우루스 빌프리이드
로렌짼 엔스-페터
데에네 하인쯔-빌헬름
에르델렌 크리스토프
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만프레드 자펠, 요하임 그렘
바이엘 악티엔게젤샤프트
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Publication of KR930023344A publication Critical patent/KR930023344A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/36—Radicals substituted by singly-bound nitrogen atoms
    • C07D213/42—Radicals substituted by singly-bound nitrogen atoms having hetero atoms attached to the substituent nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/74—Amino or imino radicals substituted by hydrocarbon or substituted hydrocarbon radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products

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  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

본 발명은 공업용 재료를 보호하기 위한 하기 일반식(Ⅰ)의 티오세미카바자이드의 용도, 및 신규한 티오세미카바자이드, 그의 제조방법 및 재료 보호 및 식물 보호에 있어서의 살미생물체로서의 그의 용도에 관한 것이다.
상기식에서, R1,R2,R3및 R4는 명세서에 기재된 바와 같다.

Description

티오세미카바자이드
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 공업용 재료를 보호하기 위한 일반식 (Ⅰ)의 화합물 및 그의 금속염 착물 및 산부가염의 용도.
    상기식에서,R1및 R2는 각 경우에 서로 독립적으로 수소, 알킬, 알콕시, 티오알킬, 할로겐, 할로게노알킬, 할로게노알콕시 또는 할로게노티오알킬을 나타내거나, 함께 벤젠 또는 시클로알킬환을 형성하고, R3는 수소, 알킬, 시클로알킬, 아릴 , 아르알킬, 헤트아릴 또는 헤트아르알킬을 나타내며, R4는 SR5, NR6R7또는 OR5그룹을 나타내고, 여기에서, R5는 알킬, 시클로알킬, 시클로알케닐, 아르알킬 또는 아릴을 나타내며, R6및 R7은 각 경우에 서로 독립적으로 수소, R5또는 -CH2-R3그룹을 나타내거나, 질소원자와 함께는 포화되거나 불포화된 임의로 치환된 헤테로사이클을 형성한다.
  2. 제 1항에 있어서,R1및 R2가 서로 독립적으로 수소, 할로겐,C1-C6-알킬, -알콕시, -티오알킬, -할로게노알킬, -할로게노알콕시 또는 -할로게노티오알킬을 나타내거나, 함께 벤젠, 시클로펜탄 또는 시클로헥산환을 형성하고, R3는 수소, C1-C10-알킬, C3-C8-시클로알킬, 페닐, 나프틸, 벤젠, 피리딜, 피리미딜, 티에닐, 푸르푸릴 또는 피릴을 나타내며, R4는 SR5,NR6R7또는 OR5그룹을 나타내고, 여기에서 R5는 C1-C6-알킬, C3-C8-시클로알킬, C3-C8-시클로알케닐, 벤질 또는 페닐을 나타내며, R6및 R7은 각 경우에 서로 독립적으로 수소, R5또는 -CH2-R3그룹을 나타내거나, 질소 원자와 함께는 추가의 질소, 황 및/또는 산소원자에 의해 임의로 차단되고 알킬 그룹에 의해 임의로 일치환되거나 이치환된, 포화 또는 부분-불포화된 5 내지 7원환을 형성하는 일반식 (Ⅰ)의 화합물의 용도.
  3. 제 1항에 있어서,R1및 R2가 서로 독립적으로 수소, 불소, 염소, 브롬, 메틸, 에틸, 메톡시, 에톡시, 트리플루오로메틸 또는 트리플루오로메톡시를 나타내고, R3는 수소, 메틸, 에틸, n- 및 i- 프로필, n-, i-, s- 및 t-부틸 및 임의로 치환된 시클로펜틸, 시클로헥실, 시클로헵틸, 시클로프로필, 페닐, 나프틸, 벤질, 피리딜, 피리미딜, 티에닐, 푸르푸릴 또는 피릴을 나타내며, R4는 SR5, NR6R7또는 OR5그룹을 나타내고, 여기에서 R5는 메틸, 에틸, n- 및 i- 프로필, n-, i-, s- 및 t-부틸, 시클로프로필, 시클로부틸, 시클로펜틸, 시클로헥실, 벤질 또는 페닐을 나타내며, R6및 R7은 각 경우에 서로 독립적으로 수소, R5또는 -CH2-R3그룹을 나타내거나, 질소 원자와 함께는 하나 또는 두 개의 메틸그룹에 의해 임의로 치환된 피롤리딘, 피롤린,옥사졸리딘, 옥사졸린, 이소옥사졸리딘, 이소옥사졸린, 피라졸린, 피라졸딘, 이미다졸리딘, 이미다졸린, 트리아졸리딘, 트리아졸린, 피페리딘, 모폴린, 티오모폴린, N-메틸피페라진 또는 피페라진환을 형성하는 일반식 (Ⅰ)의 화합물의 용도.
  4. 일반식 (Ia)의 티오세미카바자이드 및 그의 금속염 착물 및 산부가염.
    상기식에서, R1,R2,R4는 제 1항내지 3항에 언급된 의미를 가지며, RS'는 시클로알킬, 아릴, 아르알킬, 헤트아릴 또는 헤트아르알킬을 나타낸다.
  5. 일반식(Ⅱ)의 하이드라존을 용매의 존재하에 나트륨보로하이드리드로 환원시킴을 특징으로 하여 제4항에 따른 일반식 (Ia)의 화합물을 제조하는 방법.
    상기식에서, R1,R2,R3'및 R4는 상기 언급한 의미를 갖는다.
  6. 제 4항에 따른 일반식(Ia)의 티오세미카바자이드를 적어도 하나 함유함을 특징으로 하는 농약.
  7. 해충을 구제하기 위한 제 4항에 따른 일반식(Ia)의 티오세미카바자이드의 용도.
  8. 제 4항에 따른 일반식(Ia)의 티오세미카바자이드를 해충 및/또는 그들의 환경에 적용시킴을 특징으로 하여 해충을 구제하는 방법.
  9. 제 4항에 따른 일반식(Ia)의 티오세미카바자이드를 중량제 및/ 또는 계면활성제와 혼합물을 특징으로 하여 농약을 제조하는 방법.
  10. 제 1항 내지 제 4항에 따른 일반식 (I) 또는 (Ia)의 티오세미카바자이드를 적어도 하나 함유함을 특징으로 하는, 공업용 재료를 보호하기 위한 살미생물체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930009185A 1992-05-29 1993-05-26 티오세미카바자이드 KR930023344A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4217723A DE4217723A1 (de) 1992-05-29 1992-05-29 Thiosemicarbazide
DEP4217723.5 1992-05-29

Publications (1)

Publication Number Publication Date
KR930023344A true KR930023344A (ko) 1993-12-18

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KR1019930009185A KR930023344A (ko) 1992-05-29 1993-05-26 티오세미카바자이드

Country Status (5)

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EP (1) EP0571857A1 (ko)
JP (1) JPH0656779A (ko)
KR (1) KR930023344A (ko)
BR (1) BR9302091A (ko)
DE (1) DE4217723A1 (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4430690A1 (de) * 1994-08-30 1996-03-07 Bayer Ag Thiosemicarbazide
CA2515027A1 (en) * 2003-02-05 2004-08-19 Unisearch Limited Metal ion chelators and therapeutic use thereof
CA2710039C (en) 2007-12-26 2018-07-03 Critical Outcome Technologies, Inc. Semicarbazones, thiosemicarbazones and related compounds and methods for treatment of cancer
EP2318406B1 (en) 2008-07-17 2016-01-27 Critical Outcome Technologies, Inc. Thiosemicarbazone inhibitor compounds and cancer treatment methods
CA2999435A1 (en) 2010-04-01 2011-10-06 Critical Outcome Technologies Inc. Compounds and method for treatment of hiv
WO2013169361A1 (en) * 2012-05-09 2013-11-14 Howard University Iron chelators as hiv-1 inhibitors

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK165284A (da) * 1984-03-23 1985-09-24 Cheminova As Biocidt, navnlig fungicidt og/eller bactericidt middel

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EP0571857A1 (de) 1993-12-01
JPH0656779A (ja) 1994-03-01
DE4217723A1 (de) 1993-12-02
BR9302091A (pt) 1993-12-07

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