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KR930002408A - 표피 합체 성형 발포체의 제조방법 - Google Patents

표피 합체 성형 발포체의 제조방법 Download PDF

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Publication number
KR930002408A
KR930002408A KR1019920012203A KR920012203A KR930002408A KR 930002408 A KR930002408 A KR 930002408A KR 1019920012203 A KR1019920012203 A KR 1019920012203A KR 920012203 A KR920012203 A KR 920012203A KR 930002408 A KR930002408 A KR 930002408A
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South Korea
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weight
component
amount
reaction mixture
primary
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KR1019920012203A
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English (en)
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베버 크리스티안
그라메스 하르트비그
Original Assignee
만프레드 조벨, 요아힘 그렘
바이엘 아크티엔게젤샤프트
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Publication of KR930002408A publication Critical patent/KR930002408A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/34—Chemical features in the manufacture of articles consisting of a foamed macromolecular core and a macromolecular surface layer having a higher density than the core
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0033—Foam properties having integral skins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0066—≥ 150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

내용 없음.

Description

표피 합체 성형 발포체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. a)방향족과 결합한 이소시아네이트 그룹을 갖는 하나 이상의 폴리이소시아네이트, b)분자량이 500 내지 12,000이 고알콜설 하이드록실 그룹을 2 내지 4개 함유하는 하나 이상의 폴리에테르 폴리올 및 c)분자량이 62 내지 499이고 1급 및/또는 2급 하이드록실 그룹을 함유하는 하나 이상의 2가 또는 3가 알콜을 포함하는 반응 혼합물을 밀폐식 주형 속에서 발포시켜 최대 총 밀도가 500kg/㎡인 표피 합체 발포체(integral skin foam)를 제조하는 방법에 있어서, 반응 혼합물이 추가의 성분으로서 d)d1)분자량이 131 내지 500이고 1급, 2급 및/또는 3급 아민 질소원자수가 총 2 내지 4인 지방족 폴리아민 40 내지 200중량부 중의 d2)탄소수가 8 내지 24인 직쇄 또는 측쇄의 포화 또는 불포화 지방산의 아연 염 100중량부의 용액 및 e)물을 함유하고, 당해 성분들의 총량이 이소시아네이트 지수가 70 내지 150이 되도록 함을 특징으로 하는 방법.
  2. 제1항에 있어서, 반응 혼합물이 f)분자량이 108 내지 350인 하나 이상의 방향고 디아민(둘 다 1급임)을 추가로 포함하며, 여기서 둘 다 1급인 방향족 디아민이 당해 반응 혼합물 중에 별개의 성분으로서 포함되고/되거나 당해 용액 중에 포함될 수 있는 방법.
  3. 제2항에 있어서, 성분 f)가 당해 용액 중에 200중량부 이하의 양으로 포함되는 방법.
  4. 제3항에 있어서, 성분 f)가 별개로 첨가되는 성분으로서 당해 반응 혼합물 중에 포함되는 방법.
  5. 제2항에 있어서, 아연 염의 총량이 성분 b)의 중량을 기준으로 하여 0.2 내지 2.5중량%인 방법.
  6. 제2항에 있어서, 성분 d1) 및 f)의 총량이 성분 c)의 중량을 기준으로 하여 20중량% 이하인 방법.
  7. 제2항에 있어서, 성분 c)가 성분 b)의 중량을 기준으로 하여 2 내지 15중야%의 양으로 사용되는 방법.
  8. 제2항에 있어서, 성분 e)가 성분 b)의 중량을 기준으로 하여 0.5 내지 1.5중량%의 양으로 사용되는 방법.
  9. 제4항에 있어서, 성분 c)가 성분 b)의 중량을 기준으로 하여 2 내지 15중량%의 양으로 사용되고, 성분 d2)가 성분 b)의 중량을 기준으로 하여 0.2 내지 2.5중량%의 양으로 사용되며, 성분 d1) 및 성분 f)가 성분 c(의 중량을 기준으로 하여 20중량% 이하의 양으로 사용되고, 성분 e)가 성분 b)의 중량을 기준으로 하여 0.5 내지 1.5중량%의 양으로 사용되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920012203A 1991-07-11 1992-07-09 표피 합체 성형 발포체의 제조방법 KR930002408A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4122872.3 1991-07-11
DE4122872A DE4122872A1 (de) 1991-07-11 1991-07-11 Formschaumstoffe

Publications (1)

Publication Number Publication Date
KR930002408A true KR930002408A (ko) 1993-02-23

Family

ID=6435855

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920012203A KR930002408A (ko) 1991-07-11 1992-07-09 표피 합체 성형 발포체의 제조방법

Country Status (8)

Country Link
US (1) US5342856A (ko)
EP (1) EP0522394A3 (ko)
JP (1) JPH05209037A (ko)
KR (1) KR930002408A (ko)
BR (1) BR9202577A (ko)
CA (1) CA2073294A1 (ko)
DE (1) DE4122872A1 (ko)
MX (1) MX9204032A (ko)

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Publication number Priority date Publication date Assignee Title
DE19519335A1 (de) * 1995-05-26 1996-11-28 Basf Ag Verfahren zur Herstellung von Ester- und Urethangruppen enthaltenden Formkörpern, estergruppenhaltige Isocyanat-Semipräpolymere hierfür und ihre Verwendung
US5889068A (en) * 1997-07-24 1999-03-30 Bayer Corporation Water blown polyurethane soling systems
NO20061768L (no) * 2006-04-21 2007-10-22 Nor X Industry As Blanding av tilsetningsmidler til bruk ved fremstilling termoplaster
WO2017204345A1 (ja) * 2016-05-26 2017-11-30 積水化学工業株式会社 ポリウレタン組成物

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Also Published As

Publication number Publication date
US5342856A (en) 1994-08-30
JPH05209037A (ja) 1993-08-20
EP0522394A2 (de) 1993-01-13
DE4122872A1 (de) 1993-01-14
CA2073294A1 (en) 1993-01-12
BR9202577A (pt) 1993-03-16
EP0522394A3 (en) 1993-03-31
MX9204032A (es) 1993-01-01

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WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid