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KR900003343A - Fuel composition - Google Patents

Fuel composition Download PDF

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Publication number
KR900003343A
KR900003343A KR1019890012064A KR890012064A KR900003343A KR 900003343 A KR900003343 A KR 900003343A KR 1019890012064 A KR1019890012064 A KR 1019890012064A KR 890012064 A KR890012064 A KR 890012064A KR 900003343 A KR900003343 A KR 900003343A
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South Korea
Prior art keywords
alkyl
copolymer
polymer
vinyl ether
alkyl vinyl
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KR1019890012064A
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Korean (ko)
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KR0134192B1 (en
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드라이덴 택 로버트
프랭크 앤드류스 로저
패터슨 마리
Original Assignee
로버트 프랭크 노쓰오버
엑손 케미칼 패턴츠 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/1955—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by an alcohol, ether, aldehyde, ketonic, ketal, acetal radical
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/146—Macromolecular compounds according to different macromolecular groups, mixtures thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1963—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof mono-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1966—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof poly-carboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C10L1/2364—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing amide and/or imide groups

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
  • External Artificial Organs (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
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Abstract

Cold flow properties are improved by adding in minor proportion by weight to a distillate fuel oil a polymer of a C1 to C17 alkyl vinyl ether. This polymer may be a homopolymer, a mixture of homopolymers, a copolymer of alkyl vinyl ethers of different alkyl chain length, a copolymer of one or more alkyl vinyl ethers with one or more copolymerisable monomers or a mixture of such copolymers. Typical copolymers are copolymers of alkyl vinyl ethers with alkyl acrylates, alkyl methacrylates, olefins, dialkyl fumarates or maleates, eg copolymers of n-butyl vinyl ether with di(n-tetradecyl) fumarate. Other polymers are copolymers of an alkyl vinyl ether with an ethylenically unsaturated carboxylic acid or anhydride, subsequently reacted with an alcohol or an amine or both, eg a copolymer of methyl vinyl ether and maleic anhydride reacted with n-tetradecanol, n-hexadecanol or a mixture of these alcohols.

Description

연료 조성물Fuel composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (29)

증류 연료유 대부분(증량기준) 및 하이드로카빌 비닐 에테르의 중합체(여기에서 하이드로카빌 그룹은 1 내지 17개의 탄소원자를 함유한다) 소량(중량기준)을 포함하는 연료유 조성물.A fuel oil composition comprising a majority (by weight) of distillate fuel oil and a small amount (by weight) of a polymer of hydrocarbyl vinyl ether, wherein the hydrocarbyl group contains 1 to 17 carbon atoms. 제1항에 있어서, 상기 하이드로카빌 비닐 에테르가 알킬 비닐 에테르인 조성물.The composition of claim 1 wherein said hydrocarbyl vinyl ether is an alkyl vinyl ether. 제2항에 있어서, 상기 중합체가 적어도 12개의 탄소원자를 갖는 알킬그룹 적어도 하나를 갖는 단량체로부터 유도된 조성물.The composition of claim 2 wherein the polymer is derived from a monomer having at least one alkyl group having at least 12 carbon atoms. 제2항 또는 제3항에 있어서, 상기 중합체가 C12내지 C16알킬 비닐 에테르의 단독중합체인 조성물.The composition of claim 2 or 3, wherein the polymer is a homopolymer of C 12 to C 16 alkyl vinyl ethers. 제2항 또는 3항에 있어서, 상기 중합체가, 알킬그룹에 1 내지 17개의 탄소 원자를 갖는 알킬 비닐 에테르들의 혼합물의 공중합체인 조성물.The composition of claim 2 or 3, wherein the polymer is a copolymer of a mixture of alkyl vinyl ethers having 1 to 17 carbon atoms in the alkyl group. 제2항 또는 제3항에 있어서, 상기 중합체가 하나 또는 그 이상의 알킬 비닐 에테르와 하나 또는 그 이상의 공중합가능한 단량체의 공중합체인 조성물.The composition of claim 2 or 3, wherein the polymer is a copolymer of one or more alkyl vinyl ethers with one or more copolymerizable monomers. 제6항에 있어서, 상기 공중합체가 C12내지 C16알킬 비닐 에테르와 C1내지 C18알킬 아크릴레이트, C1내지 C18알킬 메타크릴레이트, C1내지 C6올레핀 또는 디(C1내지 C10알킬) 푸마레이트 또는 말리에이트의 공중합체인 조성물.The method of claim 6, wherein the copolymer is C 12 to C 16 alkyl vinyl ether and C 1 to C 18 alkyl acrylate, C 1 to C 18 alkyl methacrylate, C 1 to C 6 olefin or di (C 1 to C 10 alkyl) is a copolymer of fumarate or maleate. 제6항에 있엇, 상기 공중합체가 C1내지 C10알킬 비닐 에테르와 디(C12내지 C18알킬) 알킬 푸마레이트 또는 말리에이트, C12내지 C18) 아크릴레이트 또는 메타크릴레이트 또는 N,N 디(C12내지 C18) 알킬 아크릴아마이드의 공중합체인 조성물.The copolymer according to claim 6, wherein the copolymer is C 1 to C 10 alkyl vinyl ether and di (C 12 to C 18 alkyl) alkyl fumarate or maleate, C 12 to C 18 ) acrylate or methacrylate or N, A composition which is a copolymer of N di (C 12 to C 18 ) alkyl acrylamide. 제2항 또는 3항에 있어서, 상기 중합체가, 차후에 알콜 또는 아민 둘 모두와 반응하는 에틸렌형 불포화 카복실산 또는 카복실 산 무수물과 C1내지 C10알킬 비닐 에테르의 공중합체인 조성물.4. The composition of claim 2 or 3, wherein the polymer is a copolymer of ethylenically unsaturated carboxylic acid or carboxylic acid anhydride with C 1 to C 10 alkyl vinyl ethers subsequently reacted with both alcohols or amines. 제1항 내지 9항중 어느 한 항에 있어서, 상기 중합체 0.0001 내지 5.0중량%를 함유하는 조성물.The composition according to any one of claims 1 to 9, which contains 0.0001 to 5.0% by weight of the polymer. 제1항 내지 10항중 어느 한 항에 있어서, 또다른 흐름 개선제를 포함하는 조성물.The composition of claim 1 comprising another flow improver. 중간 증류 연료유에서 냉각 흐름 개선제로서의 하이드로카빌 비닐 에테르의 중합체(여기에서 하이드로 카빌 그룹은 1 내지 17개의 탄소원자를 갖는다)의 용도.The use of a polymer of hydrocarbyl vinyl ether as a cooling flow improver in middle distillate fuel oils, wherein the hydrocarbyl group has 1 to 17 carbon atoms. 제12항에 있어서, 상기 하이드로카빌 비닐 에테르가 알킬 비닐 에테르인 용도.13. Use according to claim 12, wherein said hydrocarbyl vinyl ether is an alkyl vinyl ether. 제13항에 있어서, 상기 중합체가 적어도 12개의 탄소원자를 갖는 알킬 그룹 적어도 하나를 갖는 단량체로부터 유도된 용도.14. Use according to claim 13, wherein the polymer is derived from monomers having at least one alkyl group having at least 12 carbon atoms. 제13항 또는 14항에 있어서, 상기 중합체가 C12내지 C16알킬 비닐 에테르의 단독 중합체인 용도.Use according to claim 13 or 14, wherein the polymer is a homopolymer of C 12 to C 16 alkyl vinyl ethers. 제13항 또는 14항에 있어서, 상기 중합체가 C12내지 C16알킬 비닐 에테르의 단독 중합체인 용도.Use according to claim 13 or 14, wherein the polymer is a homopolymer of C 12 to C 16 alkyl vinyl ethers. 제13항 또는 14항에 있어서, 상기 중합체가 하나 또는 그 이상의 알킬 비닐 에테르와 하나 또는 그 이상의 공중합가능한 단량체의 공중합체인 용도.Use according to claim 13 or 14, wherein the polymer is a copolymer of one or more alkyl vinyl ethers with one or more copolymerizable monomers. 제17항에 있어서, 사기 공중합체가 C12내지 C16알킬 비닐 에테르와 C1내지 C10알킬 아크릴레이트, C1내지 C10알킬 메타크릴레이트, C1내지 C6올레핀 또는 디(C1내지 C10알킬) 푸마레이트 또는 말리에이트의 공중합체인 용도.18. The method of claim 17, wherein the fraud copolymer C 12 to C 16 alkyl vinyl ether with C 1 to C 10 alkyl acrylate, C 1 to C 10 alkyl methacrylate, C 1 to C 6 olefin or a di (C 1 to C 10 alkyl) a copolymer of fumarate or maleate. 제17항에 있어서, 상기 공중합체가 C1내지 C10알킬 비닐 에테르와 디(C16내지 C18) 알킬 푸마레이트 또는 말리에이트, C12또는 C18아크릴레이트 또는 메베른하르트 베크타크릴레이트 또는 N, N 디(C12내지 C18) 알킬 아크릴 아마이드의 공중합체인 용도. 18. The method of claim 17, wherein the copolymer comprises C 1 to C 10 alkyl vinyl ethers with di (C 16 to C 18 ) alkyl fumarates or maleates, C 12 or C 18 acrylates or Möbenhardt methacrylate or N , A copolymer of N di (C 12 to C 18 ) alkyl acrylamide. 제13항 또는 14항에 있어서, 상기 중합체가, 차후에 알콜 또는 아민 또는 둘 모두와 반응하는 에틸렌형 불포화 카복실 산 또는 카복실 산 무수물과 C1내지 C10알킬 비닐 에테르의 공중합체인 용도.Use according to claim 13 or 14, wherein the polymer is a copolymer of ethylenically unsaturated carboxylic acid or carboxylic acid anhydride with C 1 to C 10 alkyl vinyl ethers which are subsequently reacted with alcohols or amines or both. 용매 및 하이드로카빌 비닐 에테르(여기에서 하이드로 카빌 그룹은 1 내지 17개의 탄소원자를 갖는다) 20 내지 90중량%를 포함하는 농축물.A concentrate comprising 20 to 90% by weight of solvent and hydrocarbyl vinyl ether, wherein the hydrocarbyl group has 1 to 17 carbon atoms. 제21항에 있어서, 상기 하이드로카빌 비닐 에테르가 알킬 비닐 에테르인 농축물.22. The concentrate of claim 21 wherein said hydrocarbyl vinyl ether is an alkyl vinyl ether. 제22항에 있어서, 상기 중합체가 적어도 12개의 탄소원자를 갖는 알킬 그룹 적어도 하나를 갖는 단량체로부터 유도된 농축물.The concentrate of claim 22 wherein said polymer is derived from monomers having at least one alkyl group having at least 12 carbon atoms. 제22항 또는 23항에 있어서, 상기 중합체가 C12내지 C16알킬 비닐 에테르의 단독 주합체인 농축물.24. The concentrate of claim 22 or 23, wherein said polymer is a homopolymer of C 12 to C 16 alkyl vinyl ethers. 제22항 또는 23항에 있어서, 상기 중합체가, 알킬 그룹에 1 내지 17개의 탄소원자를 갖는 알킬 비닐 에테르들의 혼합물의 공중합체인 농축물.24. The concentrate of claim 22 or 23 wherein the polymer is a copolymer of a mixture of alkyl vinyl ethers having 1 to 17 carbon atoms in the alkyl group. 제22항 또는 23항에 있어서, 상기 중합체가 하나 또는 그 이상의 알킬 비닐 에테르와 하나 또는 그 이상의 공중가능한 단량체의 공중합체인 농축물.24. The concentrate of claim 22 or 23, wherein said polymer is a copolymer of one or more alkyl vinyl ethers with one or more airborne monomers. 제26항에 있어서, 상기 공중합체가 C12내지 C16알킬 비닐 에테르와 C1내지 C10알킬 아크릴레이트, C1내지 C10알킬 메타크릴레이트, C1내지 C6올레핀 또는 디(C1내지 C10알킬) 푸마레이트 또는 말리에이트의 공중합체인 농축물.The method of claim 26 wherein the copolymer is C 12 to C 16 alkyl vinyl ether with C 1 to C 10 alkyl acrylate, C 1 to C 10 alkyl methacrylate, C 1 to C 6 olefin or di (C 1 to C). C 10 alkyl) Concentrate which is a copolymer of fumarate or maleate. 제26항에 있어서, 상기 공중합체가 C1내지 C10알킬 비닐 에테르와 디(C12내지 C18) 알킬 푸마레이트 또는 말리에이트, C12내지 C18아크릴레이트 또는 메타크릴레이트 또는 N,N(C12내지 C18) 알킬 아크릴 아마이드의 공중합체인 농축물.The method of claim 26, wherein the copolymer comprises C 1 to C 10 alkyl vinyl ethers with di (C 12 to C 18 ) alkyl fumarates or maleates, C 12 to C 18 acrylates or methacrylates or N, N ( C 12 to C 18 ) Concentrate which is a copolymer of alkyl acrylamide. 제22항 또는 23항에 있어서, 상기 중합체가, 차후에 알콜 또는 아민 또는 둘 모두와 반응하는 에틸렌형 불포화 카복실 산 또는 카복실 산 무수물과 C1내지 C10알킬 비닐 에테르의 공중합체인 농축물.24. The concentrate of claim 22 or 23, wherein the polymer is a copolymer of ethylenically unsaturated carboxylic acid or carboxylic acid anhydride with C 1 to C 10 alkyl vinyl ethers subsequently reacted with alcohols or amines or both. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019890012064A 1988-08-24 1989-08-24 Fuel compositions KR0134192B1 (en)

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