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KR900003123A - 살충 화합물 - Google Patents

살충 화합물 Download PDF

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Publication number
KR900003123A
KR900003123A KR1019890012092A KR890012092A KR900003123A KR 900003123 A KR900003123 A KR 900003123A KR 1019890012092 A KR1019890012092 A KR 1019890012092A KR 890012092 A KR890012092 A KR 890012092A KR 900003123 A KR900003123 A KR 900003123A
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KR1019890012092A
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존 부쉘 마이클
아써 에리스 카 로빈
워릭 모즐리 돈
캐서린 실라 난
Original Assignee
그레엄 도날드 아놀드
임페리알 케미칼 인더스트리스 피엘씨
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Publication of KR900003123A publication Critical patent/KR900003123A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/22—Sulfonamides, the carbon skeleton of the acid part being further substituted by singly-bound oxygen atoms
    • C07C311/29—Sulfonamides, the carbon skeleton of the acid part being further substituted by singly-bound oxygen atoms having the sulfur atom of at least one of the sulfonamide groups bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/02—Sulfinic acids; Derivatives thereof
    • C07C313/06—Sulfinamides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C313/00—Sulfinic acids; Sulfenic acids; Halides, esters or anhydrides thereof; Amides of sulfinic or sulfenic acids, i.e. compounds having singly-bound oxygen atoms of sulfinic or sulfenic groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C313/08—Sulfenic acids; Derivatives thereof
    • C07C313/18—Sulfenamides
    • C07C313/26—Compounds containing any of the groups, X being a hetero atom, Y being any atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/70—Sulfur atoms
    • C07D213/71—Sulfur atoms to which a second hetero atom is attached

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

내용 없음

Description

살충 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. 다음 구조식(Ⅰ)을 갖는 화합물
    식중, X는 수소를 갖는 탄소 또는 질소이고; Ra는 R1및 R2가 독립적으로 수소, C1-8알킬, C1-6할로알킬, C1-6알콕시, C2-6알콕시알킬, 포르밀, C2-6알카노일, C2-8알케닐, C2-8알키닐, 임의로 치환된 C3-6시클로알킬, 임의로 치환된 C3-6시클로알킬메틸, 임의로 치환된 페닐 및 임의로 치환된 벤질로부터 선택되고 n은 0.1 또는 2인 (R1)(R2)NS(O)n-구조식의 그룹이며; Rb는 R3가 C1-6알킬, 임의로 치환된 페닐 그룹에 의해 치환된 C1-4알킬, C1-8할로알킬, C2-6알케닐, 임의로 치환된 페닐 그룹에 의해 치환된 C2-4알케닐, 임의로 치환된 아릴, 및 R4및 R5가 독립적으로 수소 및 C1-4알킬로부터 선택되는 -N(R4)(R5)구조식의 그룹으로부터 선택되는 -OSO2R3구조식의 그룹이고 Ra및 Rb그룹은 X가 수소를 갖는 탄소일때 환상에서 서로에 대해 1,3위치를 차지하거나 또는 X가 질소일때 X그룹에 대해 2,4 또는 2,6위치를 차지함.
  2. 제1항에 있어서, R1및 R2각 그룹이 독립적으로 수소, C1-7알킬, C1-4할로알킬, C1-4알콕시, C2-4알콕시알킬, 포르밀, C2-4알카노일, C2-4알케닐, 임의로 치환된 C3-6시클로알킬, 임의로 치환된 C3-6시클로알킬메틸, 임의로 치환된 페닐 및 임의로 치환된 벤질로부터 선택되는 화합물.
  3. 제1항 또는 제2항에 있어서, R3그룹이 C1-4알킬, 임의로 치환된 페닐 그룹으로 치환된 C1-2알킬, C1-6할로알킬, C2-4알케닐, 임의로 치환된 페닐그룹으로 임의 치환된 에테닐, 임의로 치환된 페닐, 임의로 치환된 피리딜, 2-티에닐, 3-티에닐 또는 R4및 R5가 독립적으로 수소 및 C1-4알킬로부터 선택되는 -N(R4)(R5)구조식의 그룹인 화합물.
  4. 전기한 어떤 항에 있어서, n값이 2인 화합물.
  5. 전기한 어떤 항에 있어서, x그룹이 질소인 화합물.
  6. 제5항에 있어서, Ra및 Rb그룹이 x그룹에 대해 2,6위치를 차지하는 그룹.
  7. 제1항에 있어서, 다음 구조식(IA)을 갖는 화합물.
    식중, R1및 R2는 독립적으로 수소, C1-6알킬, C1-6할로알킬, C1-6알콕시, C1-6알콕시알킬, 포르밀, C2-6알카노일, C3-6시클로알킬, 임의로 치환된 페닐 및 임의로 치환된 벤질로부터 선택되고 R3는 C1-6알킬, C1-6할로알킬 및 R4및 R5가 독립적으로 수소 및 C1-6알킬로부터 선택되는 -N(R4)(R5)구조식 그룹으로부터 선택되고;n은 0,1 및 2로부터 선택됨.
  8. 다음 구조식(ⅡA)의 피리돈 다음 구조식(ⅡB)의
    피리돈을 임의로 연기가 존재하는 상태에서 Hal이 할로겐인 구조식 R3-SO2-Hal의 설포닐 할라이드와 반응시키는 것으로 구성되는, R1,R2및 R3가 제1항에 기재된 바와 같고 n은 2이며 X는 질소인 제1항 화합물의 제조방법.
  9. (i)다음 구조식(IXA)을 갖는 화합물과 설퍼릴 클로라이드를 반응시켜 설페닐 클로라이드 중간물을 얻고
    (ⅱ)중간물인 설페닐 클로라이드를 (R1)(R2) NH구조식을 갖는 아민과 반응시켜 다음 구조식을 갖는 당해 화합물을 얻으며
    임의적으로 (ⅲ) 이것의 산화를 조절하여 다음 구조식을 갖는 당해 화합물을 얻는 단계로 구성되는,
    R1,R2및 R3가 제1항에 기재된 바와같고, X가 질소이고 n은 0 또는 1이며 Ra및 Rb그룹이 X그룹에 대해 2,6위치를 차지하는 제1항 화합물 제조방법.
  10. 다음 구조식(XI)을 갖는 화합물을
    임의적으로 염기가 존재하는 상태에서 Hal이 할로겐인 구조식 R3-SO2-Hal의 설포닐 할라이드와 반응시키는 것으로 구성되는, R1,R2및 R3가 제1항에 기재된 바와 같고 n은 2이며 X는 수소를 갖는 탄소인 제1항 화합물 제조방법.
  11. 다음 구조식(Ⅱ)을 갖는 2-피리돈
    식중, R1및 R2는 제1항에 기재된 바와같고, (R1)(R2)NSO2-그룹은 환의 질소에 대해 4 또는 6위치에 있음.
  12. 다음 구조식(Ⅲ)을 갖는 2-할로피리딘
    식중, Hal이 할로겐이고, R1및 R2는 제1항에 기재된 바와 같으며 구조식 (R1)(R2)NSO2-그룹은 환의 질소에 대해 4 또는 6위치에 있음.
  13. 다음 구조식(Ⅳ)을 갖는 2-벤질옥시피리딘
    식중, R1및 R2는 제1항에 기재된 바와같고, (R1)(R2)NSO2-그룹은 환의 질소에 대해 4 또는 6위치에 있음.
  14. 다음 구조식(Ⅹ)을 갖는 화합물
    식중, R1및 R2는 제1항에 기재된 바와 같음.
  15. 다음 구조식(XI)을 갖는 화합물
    식중, R1및 R2는 제1항에 기재된 바와 같음.
  16. 살충적으로 불활성인 희석제 또는 담체와 함께 살충적으로 효과적인 양의 제1항부터 제7항의 어떤 한 항의 화합물로 구성된 살충조성물.
  17. 제16항에 정의된 바와같은 조성물의 살충적으로 효과적인 양을 소재지에 사용하는 것으로 구성되는, 해충을 조절하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890012092A 1988-08-24 1989-08-24 살충 화합물 KR900003123A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB888820115A GB8820115D0 (en) 1988-08-24 1988-08-24 Insecticidal compounds
GB8820115.7 1988-08-24

Publications (1)

Publication Number Publication Date
KR900003123A true KR900003123A (ko) 1990-03-23

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US (1) US4987141A (ko)
EP (1) EP0356029A3 (ko)
JP (1) JPH02111755A (ko)
KR (1) KR900003123A (ko)
CN (1) CN1042144A (ko)
AU (1) AU622468B2 (ko)
GB (2) GB8820115D0 (ko)
MY (1) MY104174A (ko)

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GB2222157B (en) 1992-08-19
US4987141A (en) 1991-01-22
AU622468B2 (en) 1992-04-09
GB8917494D0 (en) 1989-09-13
GB2222157A (en) 1990-02-28
GB8820115D0 (en) 1988-09-28
JPH02111755A (ja) 1990-04-24
EP0356029A3 (en) 1991-03-27
CN1042144A (zh) 1990-05-16
EP0356029A2 (en) 1990-02-28
AU3946889A (en) 1990-03-01
MY104174A (en) 1994-02-28

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