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KR870005962A - 톨루엔 디아민의 이성체 분리 방법 - Google Patents

톨루엔 디아민의 이성체 분리 방법 Download PDF

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Publication number
KR870005962A
KR870005962A KR860011158A KR860011158A KR870005962A KR 870005962 A KR870005962 A KR 870005962A KR 860011158 A KR860011158 A KR 860011158A KR 860011158 A KR860011158 A KR 860011158A KR 870005962 A KR870005962 A KR 870005962A
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KR
South Korea
Prior art keywords
desorbent
toluene diamine
process according
adsorbent
toluene
Prior art date
Application number
KR860011158A
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English (en)
Other versions
KR900000868B1 (ko
Inventor
알버트 지넨 헬만
Original Assignee
원본미기재
유오피 인코오포레이티드
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Publication of KR870005962A publication Critical patent/KR870005962A/ko
Application granted granted Critical
Publication of KR900000868B1 publication Critical patent/KR900000868B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/26—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing at least one six-membered aromatic ring
    • C07C211/27—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing at least one six-membered aromatic ring having amino groups linked to the six-membered aromatic ring by saturated carbon chains
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/82—Purification; Separation; Stabilisation; Use of additives
    • C07C209/86—Separation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

내용 없음

Description

톨루엔 디아민의 이성체 분리방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1-5도는 실시예 2-6에서 산출된 다른 지올라이트(Zeolite)흡착제와 탈착제를 사용하여 펄스방법으로 톨루엔 디아민의 이성질체의 분리를 나타내는 크로토마토 그래프의 기록이다.

Claims (10)

  1. 흡착상태에서 Ni, Ca, Ba, K 및 Na 그룹으로부터 선택된 양이온으로 치환된 X 타입 지올라이트 또는 Ca 및 Ni 양이온으로부터 선택되어 양이온으로 치환된 Y타입 지올라이트 또는 K 양이온으로부터 치환된 L타입 지올라이트를 합유한 흡착제로 상기의 혼합물을 접촉시켜 상기의 톨루엔 다아민 이성체중의 하나를 선택적으로 흡착하여, 혼합물의 나머지를 흡착제로부터 제거시킨 다음, 탈착 상태에서 저급 알코올 또는 아민을 함유한 탈착제로 흡착제를 제거시키는 것에 의해 흡착 톨루엔 디아민을 회수하여 2, 4-톨루엔 디아민 및 2, 6-톨루엔 디아민을 포함한 급송 혼합물을 분리하는 공정.
  2. 제1항에 있어서 상기의 흡착 및 탈착 조건이 약 20℃에서 200℃까지의 온도 범위를 가지며 액상을 유지하는데 충분한 압력을 포함한 것을 특징으로 하는 공정.
  3. 제1항에 있어서 상기의 공정이 그와 유사한 이동상(simulated moving bed) 흐름 시스템의로 특징 짓는 공정.
  4. 제1항에 있어서 상기의 공정이 정적상 시스템으로 특징짓는 공정.
  5. 제1항에 있어서 상기의 탈착제가 저급 알코올을 포함한 것을 특징으로 하는 공정.
  6. 제1항에 있어서 상기의 탈착제가 알킬아민을 포함한 것을 특징으로 하는 공정.
  7. 제6항에 있어서 상기의 탈착제가 부가적으로 톨루엔을 포함한 것을 특징으로 하는 공정.
  8. 제1항에 있어서 상기의 탈착제가 n-부틸아민 및 메탄올 그리고 에탄올을 구성하고 있는 그룹으로부터 선택된 것을 특징으로 하는 공정.
  9. 제8항에 있어서 상기의 탈착제가 부가적으로 에탄올을 포함한 것을 특징으로 하는 공정.
  10. 제1항에 있어서 상기의 흡착제가 Ba로 이온치환된 지올라이트 또는 K 로 치환된 L 지올라이트인 공정과 선택적으로 흡착된 톨루엔 디아민 이성체가 2, 6-톨루엔 다아민인 공정.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860011158A 1985-12-20 1986-12-20 톨루엔 디아민의 이성체 분리방법 KR900000868B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US811623 1985-12-20
US06/811,623 US4633018A (en) 1985-12-20 1985-12-20 Process for separating isomers of toluenediamine

Publications (2)

Publication Number Publication Date
KR870005962A true KR870005962A (ko) 1987-07-08
KR900000868B1 KR900000868B1 (ko) 1990-02-17

Family

ID=25207072

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019860011158A KR900000868B1 (ko) 1985-12-20 1986-12-20 톨루엔 디아민의 이성체 분리방법

Country Status (13)

Country Link
US (1) US4633018A (ko)
EP (1) EP0231496B1 (ko)
JP (1) JPS6310747A (ko)
KR (1) KR900000868B1 (ko)
CN (1) CN1008814B (ko)
AR (1) AR242774A1 (ko)
AU (1) AU590038B2 (ko)
BR (1) BR8606382A (ko)
CA (1) CA1262360A (ko)
DE (1) DE3672247D1 (ko)
ES (1) ES2015872B3 (ko)
IN (2) IN166969B (ko)
ZA (1) ZA869511B (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3724018A1 (de) * 1987-07-21 1989-02-02 Bayer Ag Verfahren zur trennung von anilin-derivaten
EP0320879A1 (en) * 1987-12-14 1989-06-21 Air Products And Chemicals, Inc. Separating toluenediamine from N-tertiarybutyl toluenediamine
US4996322A (en) * 1989-05-15 1991-02-26 Air Products And Chemicals, Inc. Separation of amides with molecular sieves
US5174979A (en) * 1989-10-06 1992-12-29 Uop Mixed ion-exchanged zeolites and processes for the use thereof in gas separations
FR2789914B1 (fr) 1999-02-22 2001-04-06 Ceca Sa Adsorbants zeolitiques agglomeres a faible taux de liant inerte, leur procede d'obtention et leurs utilisations
US6469212B1 (en) 2000-03-20 2002-10-22 Albemarle Corporation Separation of 2,4-toluenediamine from an isomeric mixture of toluenediamines
US6359177B1 (en) * 2000-12-15 2002-03-19 Bayer Corporation Process for separating mixtures of materials having different boiling points
CN101875614A (zh) * 2009-12-10 2010-11-03 甘肃银达化工有限公司 一种二硝基甲苯氢化焦油中回收间位二氨基甲苯的方法
KR20160044473A (ko) * 2013-08-19 2016-04-25 코베스트로 도이칠란트 아게 이소시아네이트 제조로부터의 증류 잔류물로부터 유기 이소시아네이트를 수득하는 방법
DE102017207817A1 (de) * 2017-05-09 2018-11-15 Clariant International Ltd Zeolithhaltiges Adsorbens zur selektiven Abtrennung von Isomeren aus aromatischen Kohlenwasserstoffgemischen, seine Herstellung und Verwendung

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3069470A (en) * 1958-07-21 1962-12-18 Union Oil Co Separation of toluidine isomers
US4371721A (en) * 1978-12-14 1983-02-01 Mobil Oil Corporation Selective cracking of disubstituted benzenes having polar substituents
US4246187A (en) * 1979-07-17 1981-01-20 E. I. Du Pont De Nemours And Company Separation of 2,4-tolylene diisocyanate from mixtures of 2,4- and 2,6-tolylene diisocyanate
US4270013A (en) * 1979-10-19 1981-05-26 Uop Inc. Process for the separation of nitrotoluene isomers
DE3213876A1 (de) * 1982-04-15 1983-11-17 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von o-toluidin und/oder m-toluidin und/oder p-toluidin
US4467126A (en) * 1983-07-18 1984-08-21 Uop Inc. Process for the separation of di-substituted benzene
US4480129A (en) * 1983-09-29 1984-10-30 Uop Inc. Process for separating isomers of toluidine

Also Published As

Publication number Publication date
ZA869511B (en) 1987-08-26
IN167120B (ko) 1990-09-01
AU6676786A (en) 1987-06-25
AU590038B2 (en) 1989-10-26
JPS6310747A (ja) 1988-01-18
US4633018A (en) 1986-12-30
CN86108766A (zh) 1987-08-05
EP0231496A1 (en) 1987-08-12
BR8606382A (pt) 1987-10-13
IN166969B (ko) 1990-08-11
AR242774A1 (es) 1993-05-31
EP0231496B1 (en) 1990-06-27
DE3672247D1 (de) 1990-08-02
KR900000868B1 (ko) 1990-02-17
ES2015872B3 (es) 1990-09-16
CA1262360A (en) 1989-10-17
CN1008814B (zh) 1990-07-18

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