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KR860007953A - Monolithic catalytic converter installation device - Google Patents

Monolithic catalytic converter installation device Download PDF

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Publication number
KR860007953A
KR860007953A KR1019860002882A KR860002882A KR860007953A KR 860007953 A KR860007953 A KR 860007953A KR 1019860002882 A KR1019860002882 A KR 1019860002882A KR 860002882 A KR860002882 A KR 860002882A KR 860007953 A KR860007953 A KR 860007953A
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KR
South Korea
Prior art keywords
ceramic fiber
layer
housing
ceramic
installation
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KR1019860002882A
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Korean (ko)
Other versions
KR930005290B1 (en
Inventor
디. 텐 아이크 죤
Original Assignee
케네코트 코포레이션
데이비드 엠. 로냑
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Publication of KR860007953A publication Critical patent/KR860007953A/en
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Publication of KR930005290B1 publication Critical patent/KR930005290B1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/88Handling or mounting catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2825Ceramics
    • F01N3/2828Ceramic multi-channel monoliths, e.g. honeycombs
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2839Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/2842Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for monolithic supports, e.g. of honeycomb type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2839Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/285Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for fibrous supports, e.g. held in place by screens

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

내용없음No content

Description

단일체 촉매 콘버터 설치 장치Monolithic catalytic converter installation device

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 본 발명을 구현하는 장치의 단편적인 등가도.1 is a fragmentary equivalent diagram of an apparatus implementing the present invention.

-도면의 주요 부분에 대한 부호의 설명 -Explanation of symbols on the main parts of the drawings

10 : 촉매 콘버터 12 : 하우징10 catalyst converter 12 housing

14 : 입구 18 : 세라믹 단일체14 entrance 18 ceramic unitary body

20 : 세라믹 섬유층 22,23 : 팽창성층.20: ceramic fiber layer 22, 23: expandable layer.

Claims (20)

내연기관으로부터 배기가스를 처리하기 위한 장치에 있어서In an apparatus for treating exhaust gas from an internal combustion engine 한쪽 단부에 입구를 그리고 다른쪽 단부에 출구를 가짐과 아울러 그곳을 통해 배기가스가 흐르는 하우징.A housing having an inlet at one end and an outlet at the other end, through which exhaust gas flows. 외측 표면을 가지며 한쪽 단부의 입구 단부 표면은 상기 하우징의 상기 입구와 연통하고 그의 반대쪽 단부의 출구 단부 표면은 상기 하우징의 상기 출구와 연통하는 상기 하우징내에 탄성적으로 설치된 부서지기 쉬운 세라믹 단일체A brittle ceramic unit having an outer surface, the inlet end surface of one end communicating with the inlet of the housing and the outlet end surface of the opposite end thereof communicating with the outlet of the housing. 상기 단일체의 상기 외부 표면 중의 적어도 일부를 덮고 이것과 접촉하는 세라믹 섬유층 : 그리고 상기 하우징과 상기 세라믹 섬유층 사이에 배치된 팽창성 층을 구비함을 특징으로 하는 단일체 촉매 콘버터 설치 장치.A ceramic fiber layer covering and in contact with at least a portion of said outer surface of said monolith; and an expandable layer disposed between said housing and said ceramic fiber layer. 제1항에 있어서,The method of claim 1, 상기 세라믹 섬유층은 세라믹 섬유 매트, 세라믹 섬유 브랭킷, 세라믹 섬유 펠트 또는 세라믹 섬유종이로 이루어진 그룹으로부터 선정되는 것을 특징으로 하는 단일체 촉매 콘버터 설치 장치.And the ceramic fiber layer is selected from the group consisting of ceramic fiber mats, ceramic fiber blankets, ceramic fiber felts or ceramic fiber paper. 제1항에 있어서,The method of claim 1, 상기 세라믹 섬유층은 질석의 무게로 30퍼센트 이하를 함유하는 것을 특징으로 하는 단일체 촉매 콘버터 설치 장치.And said ceramic fiber layer contains less than 30 percent by weight of vermiculite. 제1항에 있어서,The method of claim 1, 상기 세라믹 섬유층은 질석이 없는 세라믹 섬유종이인 것을 특징으로 하는 단일체 촉매 콘버터 설치장치.The ceramic fiber layer is a monolithic catalytic converter installation device characterized in that the ceramic fiber paper without vermiculite. 제3항에 있어서,The method of claim 3, 세라믹 섬유종이는 단일체가 계획된 최대 연속 작동 온도에 있을 때 팽창성층의 최대온도를 약 1038℃(1900℉)이하까지 제한하기에 충분한 두께로 됨을 특징으로 하는 단일체 촉매 콘버터 설치 장치.Single-piece catalytic converter installation device, characterized in that the ceramic fiber paper is thick enough to limit the maximum temperature of the expandable layer to about 1038 ° C. (1900 ° F.) or less when the monolith is at the planned maximum continuous operating temperature. 제1항에 있어서,The method of claim 1, 상기 세라믹 섬유층은 단일체가 계획된 최대 연속 작동 온도에 있을 때 팽창성층과 세라믹 섬유층 사이의 접촉영역의 최대 온도를 1010℃(1850℉) 이하까지 제한하기에 충분한 두께로 됨을 특징으로 하는 단일체 촉매 콘버터 설치 장치.Wherein the ceramic fiber layer is of sufficient thickness to limit the maximum temperature of the contact area between the expandable layer and the ceramic fiber layer to 1010 ° C. (1850 ° F.) or less when the monolith is at the intended maximum continuous operating temperature. . 제3항에 있어서,The method of claim 3, 세라믹 섬유종이는 적어도 0.889mm(0.035인치)의 설치 공칭두께와 적어도 0.64g/cm3의 설치 공칭 밀도를 가짐을 특징으로 하는 단일체 촉매 콘버터 설치 장치.And wherein the ceramic fiber paper has an installation nominal thickness of at least 0.889 mm (0.035 inch) and an installation nominal density of at least 0.64 g / cm 3 . 제4항에 있어서,The method of claim 4, wherein 팽창성층은 이온-교환 질석을 함유하며 세라믹 섬유층은 배기가스를 연속처리 중 팽창성 층의 최대온도를 기껏해야 1010℃ (1850℉)까지 제한하는 것을 특징으로 하는 단일체 촉매 콘버터 설치 장치.And wherein the expandable layer contains ion-exchange vermiculite and the ceramic fiber layer limits the exhaust gas up to 1010 ° C. (1850 ° F.) at most during the continuous treatment. 제8항에 있어서,The method of claim 8, 단일체의 계획된 작동 온도가 1038℃(1900℉)보다 큰 것을 특징으로 하는 단일체 촉매 콘버터 설치 장치.A monolithic catalytic converter installation apparatus, characterized in that the planned operating temperature of the monolith is greater than 1038 ° C. (1900 ° F.). 제8항에 있어서,The method of claim 8, 단일체의 계획된 작동 온도가 1066℃(1950℉)인 것을 특징으로 하는 단일체 촉매 콘버터 설치 장치.A monolithic catalytic converter installation apparatus, characterized in that the planned operating temperature of the monolith is 1066 ° C (1950 ° F). 내연기관의 배기가스를 정화하기 위한 촉매 콘버터에 있어서,In the catalytic converter for purifying the exhaust gas of the internal combustion engine, 내측 표면과 한쪽 단부의 입구와 다른쪽 단부의 출구를 가지는 중공 금속성 하우징 :Hollow metallic housing having an inner surface and an inlet at one end and an outlet at the other end: 상기 하우징의 상기 입구와 연통하는 입구 단부 표면과 상기 하우징의 상기 출구 단부와 연통하는 출구 단부 표면을 가지는 상기 하우징내에 탄성적으로 설치된 부서지기 쉬운 통기성 세라믹 단일체 촉매요소 :A brittle breathable ceramic unitary catalyst element resiliently installed in said housing having an inlet end surface in communication with said inlet of said housing and an outlet end surface in communication with said outlet end of said housing; 다음을 구성하는 상기 하우징으로부터 간격진 관계로 상기 촉매요소를 열적으로 절연시킴과 동시에 탄성적으로 설치하는 수단 :Means for thermally insulating and elastically installing said catalytic element in a spaced relation from said housing, comprising: 그의 단부 표면들 사이에서의 상기 촉매 요소들의 상기 외측 표면중 적어도 70퍼센트를 덮고 접촉하는 적어도 1093℃(2000℉)의 온도에 대한 연속 노출에 저항할 수 있는 세라믹 섬유층 : 그리고 상기 세라믹 섬유층을 덮고 상기 하우징과 접촉하는 팽창성 시이트 물질의 적어도 하나의 층을 구비함을 특징으로 하는 촉매 콘버터.A ceramic fiber layer capable of resisting continuous exposure to a temperature of at least 1093 ° C. (2000 ° F.) covering and contacting at least 70 percent of the outer surfaces of the catalytic elements between its end surfaces: and covering the ceramic fiber layer and And at least one layer of expandable sheet material in contact with the housing. 제11항에 있어서,The method of claim 11, 세라믹 섬유의 상기 층은 세라믹 섬유 매트, 세라믹 섬유 브랭킷, 세라믹 섬유 펠트 또는 세라믹 섬유종이를 구성하는 그룹으로부터 선정되는 것을 특징으로 하는 촉매 콘버터.Wherein said layer of ceramic fibers is selected from the group consisting of ceramic fiber mats, ceramic fiber blankets, ceramic fiber felts or ceramic fiber paper. 제11항에 있어서,The method of claim 11, 세라믹 섬유의 상기 내부층은 적어도 1.5875mm(1/16인치)의 비압축 공칭 두께와 적어도 0.19g/cm3의 비압축 공칭 밀도를 가짐을 특징으로 하는 촉매 콘버터.Said inner layer of ceramic fiber has an uncompressed nominal thickness of at least 1.5875 mm (1/16 inch) and an uncompressed nominal density of at least 0.19 g / cm 3 . 제11항에 있어서,The method of claim 11, 세라믹 섬유층은 적어도 0.762mm(0.030인치)의 설치 공칭 두께와 적어도 0.64g/cm3의 설치 공칭 밀도를 가짐을 특징으로 하는 촉매 콘버터.The catalytic converter layer is characterized in that the ceramic fiber layer has an installation nominal thickness of at least 0.762 mm (0.030 inch) and an installation nominal density of at least 0.64 g / cm 3 . 제14항에 있어서,The method of claim 14, 상기 촉매 단일체 요소는 상기 하우징으로부터 적어도 5.08mm(0.2 인치) 간격짐을 특징으로 하는 촉매 콘버터.The catalytic monolith element is at least 5.08 mm (0.2 inch) spaced from the housing. 제14항에 있어서,The method of claim 14, 상기 팽창성 사이트 물질은 약 0.4인치의 비압축 공칭 두께 약 0.64g/cm3의 비압축 공칭 밀도 및 설치세라믹 섬유층을 가지며, 팽창성 시이트 물질층은 약 6.35mm(1/4인치)의 조합된 두께 및 약 1.12g/cm3의 조합된 밀도를 가짐을 특징으로 하는 촉매 콘버터.The expandable site material has an uncompressed nominal density of about 0.64 g / cm 3 and an installation ceramic fiber layer of about 0.4 inch, and an expandable sheet material layer of about 6.35 mm (1/4 inch) combined thickness and Catalytic converter characterized by having a combined density of about 1.12 g / cm3. 제13항에 있어서,The method of claim 13, 상기 팽창성 사이트 물질은 약 6.64g/cm3의 비압축 공칭 밀도를 가짐을 특징으로 하는 촉매 콘버터.Said expandable site material having an uncompressed nominal density of about 6.64 g / cm 3 . 제17항에 있어서,The method of claim 17, 약 5.08mm(0.2인치)의 비압축 공칭 두께를 각각 가지는 팽창성 시이트 물질의 두 개의 층을 포함하는 것을 특징으로 하는 촉매 콘버너.A catalytic converter comprising two layers of expandable sheet material, each having an uncompressed nominal thickness of about 5.08 mm (0.2 inches). 제11항에 있어서,The method of claim 11, 단일체 요소는 약 70/30의 섬유 대 쇼트 비율을 가지는 약 93 중량 퍼센트 세라믹 섬유를 구비하는 세라믹 섬유 종이의 층으로 감싸이며, 상기 세라믹 섬유는 약 50중량 퍼센트의 알루미나 함유량을 가지는 알루미노-실리케이트 유리질 섬유이며, 상기 세라믹 섬유종이는 약 0.889mm(0.035인치)의 설치두께 및 약 0.69g/cm3의 설치 밀도를 가지며, 상기 팽창성층은 NH4 +카티온과의 이온교환을 실제로 완료하기 위해 수성 암모늄 용액내에서 처리된 약 40내지 약 65 중량 퍼센트의 비팽창 질석 프레이크, 약 25내지 약 50 중량 퍼센트의 무기섬유물질 및 약 5 내지 약 15퍼센트의 결합체를 구비하는 물질의 두 개의 층을 포함하고, 350℃를 초과한 열에 노출된 상기 팽창성층은 열팽창을 하게 되는 것을 특징으로 하는 촉매 콘버터.The monolithic element is wrapped in a layer of ceramic fiber paper having about 93 weight percent ceramic fibers having a fiber-to-short ratio of about 70/30, the ceramic fibers being alumino-silicate glassy having an alumina content of about 50 weight percent Fiber, the ceramic fiber paper having an installation thickness of about 0.889 mm (0.035 inch) and an installation density of about 0.69 g / cm 3 , wherein the expandable layer is aqueous to actually complete ion exchange with NH 4 + cation Comprising two layers of material having from about 40 to about 65 weight percent of unexpanded vermiculite flakes treated from ammonium solution, from about 25 to about 50 weight percent of inorganic fiber material and from about 5 to about 15 percent binder And the expandable layer exposed to heat above 350 ° C. undergoes thermal expansion. 하우징내에 입구 및 출구 단부표면을 갖는 통기성 세라믹 단일체 촉매 요소를 설치하는 방법에 있어서,A method of installing a breathable ceramic monolithic catalytic element having an inlet and an outlet end surface in a housing, the method comprising: 세라믹 섬유종이의 층이 입구 및 출구 단부 표면들 사이에서 단일체의 주위를 감싸며,A layer of ceramic fiber paper wraps around the monolith between the inlet and outlet end surfaces, 조립체를 형성하기 위해 상기 세라믹 섬유종이층이 감싸인 단일체를 팽창성 시이트 물질이 상기 단일체와 상기 하우징과의 사이에서 방사방향으로 압축되어 있는 상기 조립체의 주위에 하우징을 형성함을 특징으로하는 통기성 세라믹 단일체 촉매 요소의 설치 방법.A unitary body enclosed by the ceramic fiber paper layer to form an assembly, wherein the breathable ceramic unity forms a housing around the assembly in which the expandable sheet material is radially compressed between the unitary body and the housing. Method of installation of catalytic elements. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019860002882A 1985-04-16 1986-04-15 Arranging apparatus of monolithic catalytic converter KR930005290B1 (en)

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