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KR830001611A - Isothiourea human resources insecticide composition - Google Patents

Isothiourea human resources insecticide composition Download PDF

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KR830001611A
KR830001611A KR1019800001130A KR800001130A KR830001611A KR 830001611 A KR830001611 A KR 830001611A KR 1019800001130 A KR1019800001130 A KR 1019800001130A KR 800001130 A KR800001130 A KR 800001130A KR 830001611 A KR830001611 A KR 830001611A
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alkyl
group
substituted
phenyl
defined above
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다블유. 팬처 레웰린
벤슨 스처 허버어트
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호바트 오그덴 토마스
스타우퍼 케미칼 캄파니
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Publication of KR830001611A publication Critical patent/KR830001611A/en

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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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Abstract

내용 없음No content

Description

이소티오요소 인사류 살충제 조성물Isothiourea human resources insecticide composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this content is publicly disclosed, the full text is not included.

Claims (34)

본문에 상술한 바와 같이 하기 구조식의 화합물로 이루어지는 이소티오요소 인사류살충제 조성물.Isothiourea personnel composed of compounds of the structure: Insecticide composition. 식중, R 및 R1은 C2-C10알킬, C2-C10알콕시알킬 및 페닐로 이루어지는 그루우프로부터 독자적으로 선택되며, R 및 R1은 다같이 12-22개의 탄소원자를 함유하고,Wherein R and R 1 are independently selected from a group consisting of C 2 -C 10 alkyl, C 2 -C 10 alkoxyalkyl and phenyl, R and R 1 together contain 12-22 carbon atoms, R2는 C1-C14알킬 C3-C10알케닐, C3-C4알키닐, C2-C4하이드록시알킬, C2-C6알킬티오알킬, C2-C6알킬옥시알킬, (CH2)n[X(CH2)n]y (여기서 n은 1 또는 2, X는 0 또는 S이고 y는 1-4이다)R 2 is C 1 -C 14 alkyl C 3 -C 10 alkenyl, C 3 -C 4 alkynyl, C 2 -C 4 hydroxyalkyl, C 2 -C 6 alkylthioalkyl, C 2 -C 6 alkyloxy Alkyl, (CH 2 ) n [X(CH 2 ) n ]y (where n is 1 or 2, X is 0 or S and y is 1-4) (여기서 n은 1-10이다), 페닐 및 페닐에틸로 이루어지는 그루우프에서 선택되며, (Where n is 1-10), selected from a group consisting of phenyl and phenylethyl, R3은 카르보알콕시알킬(여기서 알킬은 C1-C4알킬이다), 알킬케토알킬(여기서 알킬은 C1-C4알킬이다) 하이드록시알케닐(여기서 알케닐은 C1-C4알킬이다), 하이드록시알킬(여기서 알킬은 C1-C12알킬이다), 포르밀하이드록시메틸, 하이드록시할로에틸(여기서 할로는 클로로, 브로모 또는 옥도이다), 치환페녹시알킬(여기서 알킬은 C1-C2알킬이며, 치환분은 P-메톡시, Cl, NO3또는 CN 이다.),{여기서 R1은 -OH, -NH2또는 -C1-C4알콕시,, (여기서 R, R1및 R2는 위에서 정의한 바와 같다.)}R 3 is carboalkoxyalkyl (where alkyl is C 1 -C 4 alkyl), alkylketoalkyl (where alkyl is C 1 -C 4 alkyl) hydroxyalkenyl (where alkenyl is C 1 -C 4 alkyl Is), hydroxyalkyl (where alkyl is C 1 -C 12 alkyl), formylhydroxymethyl, hydroxyhaloethyl (where halo is chloro, bromo or octa), substituted phenoxyalkyl (here alkyl Is C 1 -C 2 alkyl, and the substituted component is P-methoxy, Cl, NO 3 or CN.), {Where R 1 is -OH, -NH 2 or -C 1 -C 4 alkoxy, , (Where R, R 1 and R 2 are as defined above.)} (여기서 R, R1및 R2는 위에서 정의한 바와 같다),또는 -SO3.B(여기서 B는 염기이다),{여기서 R4는 -H, C1-C22알킬, 하이드록시에틸, 나프틸, 페닐, 치환페닐(여기서 치환분은 할로겐, C1-C5알킬, C1-C5알콕시, 니트로, 시아노 및 -CF3로 이루어지는 그루우프로부터 독자적으로 선택된다)로 이루어지는 그루우프로부터 선택된다.}(Where R, R 1 and R 2 are as defined above), Or -SO 3 .B (where B is the base), {Where R 4 is -H, C 1 -C 22 alkyl, hydroxyethyl, naphthyl, phenyl, substituted phenyl (where substituted is halogen, C 1 -C 5 alkyl, C 1 -C 5 alkoxy, nitro, cyan Selected from the group consisting of furnace and -CF 3 ).) (여기서 R, R1및 R2는 상기 정의와 같다),(여기서 R, R1및 R2는 상기 정의와 같다),(Where R, R 1 and R 2 are as defined above), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다),(Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다),(Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다),(Where R, R 1 and R 2 are as defined above), (여기서 X는 1∼8이며 R, R1및 R2는 상기 정의와 같다),(Where X is 1 to 8 and R, R 1 and R 2 are as defined above), (여기서 m는 2 또는 3이며, R, R1및 R2는 상기 정의와 같다),(Where m is 2 or 3, R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다),(Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다),(여기서 X는 O,S,NH 및 NR11로 이루어지는 그루우프로부터 선택되며, Y는 수소, 또는 메틸이고, R10은 -H, C1-C18알킬, C3-C4알케닐, C3-C4알키닐, C2-C6할로알킬, C3-C8시클로알킬, C7-C20폴리시클로알킬, C2-C16폴리알콕시알킬, C2-C6하이드록시알킬, C3-C10알콕시알킬, C3-C8카르보알콕시알킬, C4-C8알킬시클로알킬 C4-C8알킬시클로알킬, C4-C7시클로알킬이미노, C2-C10알킬아미노, C1-C3알킬아미노, C4-C12디알킬아미노알킬, C6-C10시클로알케닐, 페닐, 알킬페닐(여기서 알킬은 C1-C4이다), 파라클로로알킬페닐(여기서 알킬은 C1-C4이다), 나프틸, 안트라세닐, 벤즈아미도시클로알킬(여기서 알킬은 C1-C2이다), 피라닐메틸, 테트라하이드로푸르푸릴, 티오페네메틸, 벤즈하이드릴, 할로벤즈하이드릴, 폴리시클릭알코올 및 치환페닐 {여기서 치환분은 C1-C4알킬, 할로겐, 니트로, 트리플루오로메틸, 포르밀, 클로로아세틸, C1-C4알콕시, 수소, 벤질, 클로로벤질, 페네틸 및 치환페네틸(여기서 치환분은 C1-C4알킬 및 할로겐으로 이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로부터 선택되며, R11은 C1-C4알킬, C3-C6알콕시알킬 및 C3-C4알케닐로 이루어지는 그루우프로부터 선택되고, R10및 R11은 함께 복소환 화합물을 형성하며 X가 O 또는 S일 경우에는 R10이 수소 및 치환페닐(여기서 치환분은 할로겐, C1-C4알콕시, 페녹시, 트리플루오로메틸, C1-C6티오알킬, 니트로, 이소시아네이토, C2-C4폴리알콕시, C3-C7시클로알킬, C3-C10카르보알콕시알킬, C1-C4할로알킬, C3-C4알케닐, C2-C6디알킬아미노, 페닐아미노, C1-C4알킬, C3-C12하이드록시알킬아미도알킬, C5-C10N,N,-하이드록시알킬우레이도알킬, 알킬이 C1-C5인 이소시아네이토알킬, C3-C12알킬아미도알킬, 폴리알콕시부분은 3-6개의 반복 C2-C3알콕시 단위를 함유하고, 아미도알킬부분은 4-12개의 탄소원자를 함유하는 폴리알콕시아미도알킬, -SO2Cl, 폴리알콕시일부분은 3∼6개의 반복 C2-C3알콕시단위를 함유하고 아미도알킬의 일부분은 4∼12개의 탄소원자를 함유하는 -SO2폴리알콕시아미도알킬로 이루어지는 그루우프로부터 선택된다)이다}로 이루어지는 그루우프로부터 선택되며, R5는 수소, C1-C4알킬, C3-C6알콕시알킬, C3-C4알케닐, 하이드록시에틸 및 페닐로 이루어지는 그루우프로부터 선택되며, R4및 R5는 함께 복소환식화합물을 형성한다.](Where R, R 1 and R 2 are as defined above), (Where X is selected from a group consisting of O,S,NH and NR 11 , Y is hydrogen, or methyl, R 10 is -H, C 1 -C 18 alkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, C 2 -C 6 haloalkyl, C 3 -C 8 cycloalkyl, C 7 -C 20 polycycloalkyl, C 2 -C 16 polyalkoxyalkyl, C 2 -C 6 hydroxyalkyl, C 3 -C 10 alkoxyalkyl, C 3 -C 8 carboalkoxyalkyl, C 4 -C 8 alkylcycloalkyl C 4 -C 8 alkylcycloalkyl, C 4 -C 7 cycloalkylimino, C 2 -C 10 Alkylamino, C 1 -C 3 alkylamino, C 4 -C 12 dialkylaminoalkyl, C 6 -C 10 cycloalkenyl, phenyl, alkylphenyl (where alkyl is C 1 -C 4 ), parachloroalkylphenyl (Where alkyl is C 1 -C 4 ), naphthyl, anthracenyl, benzamidocycloalkyl (where alkyl is C 1 -C 2 ), pyranylmethyl, tetrahydrofurfuryl, thiophenemethyl, benz Hydryl, halobenzhydryl, polycyclic alcohol and substituted phenyl {where substituted is C 1 -C 4 alkyl, halogen, nitro, trifluoromethyl, formyl, chloroacetyl, C 1 -C 4 alkoxy, hydrogen, Selected from a group consisting of benzyl, chlorobenzyl, phenethyl and substituted phenethyl (where the substituent is selected from a group consisting of C 1 -C 4 alkyl and halogen), R 11 is C 1 -C 4 alkyl, Selected from a group consisting of C 3 -C 6 alkoxyalkyl and C 3 -C 4 alkenyl, R 10 and R 11 together form a heterocyclic compound, and when X is O or S, R 10 is hydrogen and substituted Phenyl (where substituted is halogen, C 1 -C 4 alkoxy, phenoxy, trifluoromethyl, C 1 -C 6 thioalkyl, nitro, isocyanato, C 2 -C 4 polyalkoxy, C 3 -C 7 cycloalkyl, C 3 -C 10 carboalkoxyalkyl, C 1 -C 4 haloalkyl, C 3 -C 4 alkenyl, C 2 -C 6 dialkyla Mino, phenylamino, C 1 -C 4 alkyl, C 3 -C 12 hydroxyalkylamidoalkyl, C 5 -C 10 N,N,-hydroxyalkylureidoalkyl, isoalkyl with C 1 -C 5 Cyanatoalkyl, C 3 -C 12 alkylamidoalkyl, polyalkoxy part contains 3-6 repeating C 2 -C 3 alkoxy units, and amidoalkyl part contains 4-12 carbon atoms amido alkyl, -SO 2 Cl, poly alkoxy portion contains 3 to 6 of the repeating unit of C 2 -C 3 alkoxy, and amido portion of the alkyl contains from 4 to 12 carbon atoms -SO that 2-alkoxy poly amido alkyl Is selected from the group consisting of)), R 5 is hydrogen, C 1 -C 4 alkyl, C 3 -C 6 alkoxyalkyl, C 3 -C 4 alkenyl, hydroxyethyl and Selected from a group consisting of phenyl, R 4 and R 5 together form a heterocyclic compound.] {여기서 X는 O 또는 S이며, n은 0 또는 1 이고, R6은 C1-C18알킬, C2-C6할로알킬, 페닐 및 치환페닐(여기서 n은 1이며, 치환분은 니트로, 클로로, C1-C2알킬, C4-C6폴리알콕시알킬, C3-C8시클로알킬, C3-C4알케닐, C3-C6알콕시알킬, C2-C6하이드록시알킬, C1-C3카르복시알킬 및 C5-C8트리알킬암모늄알킬염으로 이루어지는 그루우프로부터 선택되며, n=0일 경우에는 치환분은 클로로, 티오포타슘, C1-C18알킬, 벤질, C1-C2헤테로알킬, C2-C4클로로카르복시알킬, C4-C6폴리알콕시알킬 및 아세틸로 이루어진 그루우프로부터 선택된다)로 이루어진 그루우프로부터 선택된다),{여기서 R7은 -(CH2 -)n (여기서 n은 0∼8이다), -CH=CH-,(여기서 M은 H 또는 Cl이다)-CCl=CCl-, -CH2OCH-, 및 -OCH2CH2O-로 이루어지는 그루우프로부터 선택되고, d는 0 또는 1이며, d=1 일 경우에는 Y는 -O, -S 및 -NH로 이루어지는 그루우프로부터 선택되며, Z는 C1-C18알킬, 수소, C4-C16폴리알콕시알킬, C4-C8디알킬아미노알킬, C3-C5알키닐, 페닐, 치환페닐, 유기염, 무기염으로 이루어지는 그루우프로부터 선택되며, d=0 이고 Z가 Cl 또는(여기서 R, R1및 R2의 정의는 상기한 바와 같다)로 이루어지는 그루우프로부터 선택된다},(여기서 R8은 C1-C10알콕시, 아미노, C1-C10알콕시, 아미노, 하이드록시 및 유기염기로 이루어지는 그루우프로부터 선택된다), -SOWR9{여기서 w=0∼2 이며, R9은 아미노, C1-C10알킬, C1-C4할로알킬, 페닐, C1-C10디알킬아미노, C1-C10알킬아미노, C1-C10알콕시, 치환페닐(여기서 치환분은 니트로, 클로로, C1-C4알킬 및 메톡시로 이루어지는 그루우프로부터 선택된다.)로 이루어지는 그루우프로부터 선택된다.} {Where X is O or S, n is 0 or 1, R 6 is C 1 -C 18 alkyl, C 2 -C 6 haloalkyl, phenyl and substituted phenyl (where n is 1, substituted is nitro, Chloro, C 1 -C 2 alkyl, C 4 -C 6 polyalkoxyalkyl, C 3 -C 8 cycloalkyl, C 3 -C 4 alkenyl, C 3 -C 6 alkoxyalkyl, C 2 -C 6 hydroxyalkyl , C 1 -C 3 carboxyalkyl and C 5 -C 8 trialkylammonium alkyl salts, and if n=0, the substitution is chloro, thiopotassium, C 1 -C 18 alkyl, benzyl, C 1 -C 2 heteroalkyl, C 2 -C 4 chlorocarboxyalkyl, C 4 -C 6 polyalkoxyalkyl and acetyl). {Wherein R 7 is - (CH 2 -) n (where n is 0~8), -CH = CH-, (Where M is H or Cl) Selected from the group consisting of -CCl=CCl-, -CH 2 OCH-, and -OCH 2 CH 2 O-, d is 0 or 1, and when d=1 Y is -O, -S and- Selected from group consisting of NH, Z is C 1 -C 18 alkyl, hydrogen, C 4 -C 16 polyalkoxyalkyl, C 4 -C 8 dialkylaminoalkyl, C 3 -C 5 alkynyl, phenyl, substitution Selected from a group consisting of phenyl, organic salt, inorganic salt, d=0 and Z is Cl or (The definitions of R, R 1 and R 2 are as described above) are selected from the group consisting of}, (Where R 8 is selected from a group consisting of C 1 -C 10 alkoxy, amino, C 1 -C 10 alkoxy, amino, hydroxy and organic bases), -SO W R 9 {where w=0-2 , R 9 is amino, C 1 -C 10 alkyl, C 1 -C 4 haloalkyl, phenyl, C 1 -C 10 dialkylamino, C 1 -C 10 alkylamino, C 1 -C 10 alkoxy, substituted phenyl ( Here, the substituted component is selected from a group consisting of nitro, chloro, C 1 -C 4 alkyl and methoxy.). R 및 R1은 C5-C9알킬, C5-C9알콕시알킬 및 페닐로 이루어지는 그루우프로부터 독자적으로 선택되고, R 및 R1은 다같이 12∼22개의 탄소원자를 함유하며, R2는 C1-C6알킬, C3-C5알케닐, C3-C4알키닐, C2-C3하이드록시알킬, C2-C4알킬티오알킬, C2-C4알킬옥시알킬, (CH2)n[X(CH2)n]y (여기서 n은 1 또는 2이며, X는 0 또는 S이고, y는 1∼2이다),(여기서 n은 1∼5이다), 페닐 및 펜에틸로 이루어지는 그루우프에서 선택되는 특허청구의 범위 1기재의 이소티오요소 인사류 살충제 조성물.R and R 1 are independently selected from a group consisting of C 5 -C 9 alkyl, C 5 -C 9 alkoxyalkyl and phenyl, R and R 1 together contain 12 to 22 carbon atoms, and R 2 is C 1 -C 6 alkyl, C 3 -C 5 alkenyl, C 3 -C 4 alkynyl, C 2 -C 3 hydroxyalkyl, C 2 -C 4 alkylthioalkyl, C 2 -C 4 alkyloxyalkyl, (CH 2 ) n [X(CH 2 ) n ]y (where n is 1 or 2, X is 0 or S, and y is 1 to 2), (Where n is 1 to 5), an isothiourea personnel insecticide composition of claim 1 selected from a group consisting of phenyl and phenethyl. R 및 R1은 C6-C8알킬, C6-C8알콕시알킬 및 페닐로 이루어지는 그루우프로부터 독자적으로 선택되고, R 및 R1은 다같이 12∼22개의 탄소원자를 함유하며, R2는 C1-C13 알킬, C2-C3알케닐, C3-C4알키닐, C2-C3하이드록시알킬, C2-C4알킬티오알킬, C2-C4알킬옥시알킬, (CH2)n[X(CH2)n] Y(여기서 n은 1 또는 2이며 X는 O 또는 S이고, Y는 1∼2이다),(여기서 n은 1-3이다), 페닐 및 펜에틸로 이루어지는 그루우프로부터 선택되는 특허청구의 범위 1기재의 이소티오요소 인사류 살충제 조성물R and R 1 are independently selected from a group consisting of C 6 -C 8 alkyl, C 6 -C 8 alkoxyalkyl and phenyl, R and R 1 all together contain 12 to 22 carbon atoms, and R 2 is C 1 -C 1 3 alkyl, C 2 -C 3 alkenyl, C 3 -C 4 alkynyl, C 2 -C 3 hydroxyalkyl, C 2 -C 4 alkylthioalkyl, C 2 -C 4 alkyloxyalkyl , (CH 2 ) n [X(CH 2 ) n ] Y (where n is 1 or 2, X is O or S, and Y is 1 to 2), (Where n is 1-3), an isothiourea human resource insecticide composition of claim 1 selected from a group consisting of phenyl and phenethyl. R3은 카르보알콕시알킬(여기서 알킬은 C1-C2알킬이다), 알킬케토 알킬(여기서 알킬은 C1-C2알킬이다), 하이드록시알케닐(여기서 알케닐은 C3-C4알킬이다), 하이드록시알킬(여기서 알킬은 C1-C6알킬이다), 포름일하이드록시메틸, 하이드록시할로에틸(여기서 알킬은 C1알킬이며, 치환분은 P-메톡시, CL, NO3또는 CN 이다),R 3 is carboalkoxyalkyl (where alkyl is C 1 -C 2 alkyl), alkylketo alkyl (where alkyl is C 1 -C 2 alkyl), hydroxyalkenyl (where alkenyl is C 3 -C 4 Alkyl), hydroxyalkyl (where alkyl is C 1 -C 6 alkyl), formylhydroxymethyl, hydroxyhaloethyl (where alkyl is C 1 alkyl, the substitution is P-methoxy, CL, NO 3 or CN), (여기서 R1은 OH, -NH2또는 메톡시이다), (Where R 1 is OH, -NH 2 or methoxy), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 B는 유기염기이다),여기서 R4는 H, -C1-C12알킬, 하이드록시에틸, 나프틸, 페닐, 치환페닐(여기서 치환분은 염소, C1-C2알킬, C1-C2알콕시, 니트로, 시아노 및 CF3로 이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로부터 선택된다. (Where B is an organic base), Where R 4 is H, -C 1 -C 12 alkyl, hydroxyethyl, naphthyl, phenyl, substituted phenyl (where substituted is chlorine, C 1 -C 2 alkyl, C 1 -C 2 alkoxy, nitro, cyano And a groove consisting of CF 3 ). (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (R, R1및 R2의 정의는 상기와 같다), (R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2의 정의는 상기와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2의 정의는 상기와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2의 정의는 상기와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 X는 1∼8이며, R, R1및 R2의 정의는 상기와 같다),(Where X is 1 to 8, and the definitions of R, R 1 and R 2 are the same as above), (여기서 m은 2 또는 3이며, R, R1및 R2의 정의는 상기와 같다),(Where m is 2 or 3, and the definitions of R, R 1 and R 2 are as above), (여기서 R, R1및 R2의 정의는 상기와 같다),(Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2의 정의는 상기와 같다),(Where R, R 1 and R 2 are as defined above), 여기서 X는 O, S, NH, NR11로 이루어지는 그루우프로부터 선택되며, Y는 수소 또는 메틸이고, R10은 H, C1-C8알킬, C3-C4알케닐, C3-C4알키닐, C2-C3할로알킬, C3-C8시클로알킬, C7-C20폴리시클로알킬, 폴리알콕시알킬, C2-C6하이드록시알킬, C3-C10알콕시알킬, C3-C8카르보알콕시알킬, C4-C8시클로알킬알킬, C6-C8알킬시클로알킬, C4-C7시클로알킬이미노, C2-C10알킬이미노, C1-C3알킬아미노, C4-C12디알킬아미노알킬, C6-C10시클로알케닐, 페닐, 알킬페닐(여기서 알킬은 C1-C4이다), 파라클로로알킬페닐(여기서 알킬은 C1-C4이다), 나프틸, 안트라세닐, 벤즈아미도시클로알킬(여기서 알킬은 C1-C2이다), 피라닐메틸, 테트라하이드로푸르푸리닐, 티오페네메틸, 벤즈하이드릴, 할로벤즈하이드릴, 폴리서클릭알코올 및 치환페닐(여기서 치환분은 C1-C4알킬, 할로겐, 니트로, 트리플루오로메틸, 포름일, 클로로아세틸, C1-C4알콕시, 수소, 벤질, 클로로벤진, 펜에틸로 이루어지는 그루우프로부터 선택된다) 및 치환펜에틸(여기서 치환분은 C1-C4알킬 및 할로겐으로 이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로부터 선택되며, R11은 C1-C4알킬, C3-C6알콕시알킬 및 C3-C4알케닐로 이루어지는 그루우프로부터 선택되고, R10 및 R11은 아제피닐 모르폴리닐, 피페르디닐 C1-C3알킬치환 피페르디닐로 이루어지는 그루우프로부터 선택되는 복소환 화합물을 형성하며, X가 O 또는 S일 경우에는 R10이 수소 또는 치환페닐 {(여기서 치환분은 수소, C1-C4알콕시, 펜옥시, 트리플루오로메틸, C1-C6티오알킬, 니트로, 이소시아네이토, C2-C4폴리알콕시, C3-C7시클로알킬, C3-C10카르보알콕시알킬, C1-C4할로알킬, C3-C4알케닐, C2-C6디알킬아미노, 페닐아미노, C1-C4알킬, C3-C12하이드록시알킬아미도알킬, C5-C10N,N-하이드록시알킬우레이도알킬, 이소시아네이토알킬(여기서 알킬은 C1-C5이다), C3-C12알킬아미도알킬, 폴리알콕시아미도알킬(여기서 폴리알콕시의 일부분은 3∼6개의 반복 C2-C3알콕시단위를 함유하며, 아미도알킬의 일부분은 4∼12개의 탄소원자를 함유한다), -SO2Cl-SO2폴리알콕시아미도알킬(여기서 폴리알콕시의 일부분은 3-6개의 반복 C2-C3알콕시단위를 함유하며, 아미도알킬의 일부분은 4∼12개의 탄소원자를 함유한다), 로 이루어지는 그루우프에서 선택된다) 이외의 것이고, R5는 수소, C1-C4알킬, C3-C6알콕시알킬, C3-C4알케닐, 하이드록시에틸 및 페닐로 이루어지는 그루우프로부터 선택되며, R4및 R5는 다같이 아제피닐, 모르폴리닐, 피페르디닐 및 C1-C3알킬치환피페르디닐로 이루어지는 그루우프로부터 선택되는 복소환화합물을 형성한다},{여기서 X 는 O 또는 S 이고, n은 0 또는 1이며, R6은 C1-C12알킬, C2-C6할로알킬, 페닐 및 치환페닐(여기서 n=1이고, 치환분은 니트로, 클로로, C1-C2알킬, C4-C6폴리알콕시알킬, C3-C8시클로알킬, C3-C4알케닐, C3-C6알콕시알킬, C2-C6하이드록시알킬, C1-C3카르복시알킬, C5-C8트리알킬암모늄알킬염으로 이루어지는 그루우프로부터 선택되며, 그리고 n=0인 경우에는 치환분은 클로로, 티오포타슘, C1-C12알킬, 벤질, C1-C2헤테로알킬, C2-C4클로로카르복시알킬, C4-C6폴리알콕시알킬 및 아세틸로 이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로부터 선택된다},{여기서 R7은 -(CH2-)n (여기서 n은 0∼8이다), -CH=CH-,(여서 M은 H 또는 CL 이다),, -CCL=CCL-, -CH2OH2-, -OCH2CH2O-로 이루어지는 그루우프로부터 선택되며, d는 0 또는 1이고, d=1인 경우에는 Y는 -O, -S 및 NH로 이루어지는 그루우프로부터 선택되며, Z는 C1-C12알킬, 수소, C4-C16 폴리알콕시알킬, C4-C8디알킬아미노알킬, C3-C5알키닐, 페닐, 치환페닐, 유기염으로 이루어지는 그루우프로부터 선택되고, d=0인 경우에는 Z는 CL 또는(여기서 R, R1및 R2의 정의는 상기와 같다)},(여기서 R8은 C1-C5알콕시아미노, 수소 및 유기염기로 이루어지는 그루우프로부터 선택된다), -SOWR9{여기서 W는 0∼2이며, R9아미노, C1-C5알킬, C1-C4할로알킬, 페닐, C1-C10디알킬아미노, C1-C10 알킬아미노, C1-C5알콕시, 치환페닐(여기서 치환분은 니트로, 클로로, C1-C4알킬 및 메톡시로 이루어지는 그루우프로부터 선택된다)}로 이루어지는 그루우프로부터 선택되는 특허청구의 범위 1,2 또는 3기재의 이소티오요소 인사류 살충제 조성물.Wherein X is selected from a group consisting of O, S, NH, NR 1 1, Y is hydrogen or methyl, R 1 0 is H, C 1 -C 8 alkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, C 2 -C 3 haloalkyl, C 3 -C 8 cycloalkyl, C 7 -C 20 polycycloalkyl, polyalkoxyalkyl, C 2 -C 6 hydroxyalkyl, C 3 -C 10 alkoxy Alkyl, C 3 -C 8 carboalkoxyalkyl, C 4 -C 8 cycloalkylalkyl, C 6 -C 8 alkylcycloalkyl, C 4 -C 7 cycloalkylimino, C 2 -C 10 alkylimino, C 1 -C 3 alkylamino, C 4 -C 12 dialkylaminoalkyl, C 6 -C 10 cycloalkenyl, phenyl, alkylphenyl (where alkyl is C 1 -C 4 ), parachloroalkylphenyl (where alkyl is C 1 -C 4 ), naphthyl, anthracenyl, benzamidocycloalkyl (where alkyl is C 1 -C 2 ), pyranylmethyl, tetrahydrofurfurinyl, thiophenemethyl, benzhydryl, Halobenzhydryl, polycyclic alcohol and substituted phenyl (where substituted is C 1 -C 4 alkyl, halogen, nitro, trifluoromethyl, formyl, chloroacetyl, C 1 -C 4 alkoxy, hydrogen, benzyl, Selected from a group consisting of chlorobenzine, phenethyl, and a group consisting of substituted phenethyl (where the substitution is selected from groups consisting of C 1 -C 4 alkyl and halogen), and R 1 1 is C 1 -C 4 alkyl, C 3 -C 6 alkoxyalkyl and C 3 -C 4 alkenyl are selected from the group consisting of alkenyl, R 1 0 and R 1 1 are azepinyl morpholinyl, piperidinyl C 1 -C 3 Alkyl-substituted form a heterocyclic compound selected from a group consisting of piperidinyl, and when X is O or S, R 1 0 is hydrogen or substituted phenyl {(where substituted is hydrogen, C 1 -C 4 alkoxy, phenoxy, trifluoromethyl, C 1 -C 6 thioalkyl, nitro, isocyanato, C 2 -C 4 polyalkoxy, C 3 -C 7 h Cloalkyl, C 3 -C 10 carboalkoxyalkyl, C 1 -C 4 haloalkyl, C 3 -C 4 alkenyl, C 2 -C 6 dialkylamino, phenylamino, C 1 -C 4 alkyl, C 3 -C 12 hydroxyalkylamidoalkyl, C 5 -C 10 N,N-hydroxyalkylureidoalkyl, isocyanatoalkyl (where alkyl is C 1 -C 5 ), C 3 -C 12 alkylami Doalkyl, polyalkoxyamidoalkyl, where part of the polyalkoxy contains 3 to 6 repeating C 2 -C 3 alkoxy units, part of the amidoalkyl contains 4 to 12 carbon atoms, -SO 2 Cl-SO 2 polyalkoxyamidoalkyl, wherein part of the polyalkoxy contains 3-6 repeating C 2 -C 3 alkoxy units, part of the amidoalkyl contains 4-12 carbon atoms, Selected from Group), R 5 is selected from a group consisting of hydrogen, C 1 -C 4 alkyl, C 3 -C 6 alkoxyalkyl, C 3 -C 4 alkenyl, hydroxyethyl and phenyl, , R 4 and R 5 together form a heterocyclic compound selected from a group consisting of azepinyl, morpholinyl, piperidinyl and C 1 -C 3 alkyl-substituted piperidinyl}, {Where X is O or S, n is 0 or 1, R 6 is C 1 -C 12 alkyl, C 2 -C 6 haloalkyl, phenyl and substituted phenyl (where n=1, substituted is nitro, Chloro, C 1 -C 2 alkyl, C 4 -C 6 polyalkoxyalkyl, C 3 -C 8 cycloalkyl, C 3 -C 4 alkenyl, C 3 -C 6 alkoxyalkyl, C 2 -C 6 hydroxyalkyl , C 1 -C 3 carboxyalkyl, C 5 -C 8 trialkylammonium alkyl salts, and selected from the group consisting of a salt, and when n=0, the substituted component is chloro, thiopotassium, C 1 -C 12 alkyl, benzyl , Selected from the group consisting of C 1 -C 2 heteroalkyl, C 2 -C 4 chlorocarboxyalkyl, C 4 -C 6 polyalkoxyalkyl and acetyl)), {Where R 7 is -(CH 2 -)n (where n is 0-8), -CH=CH-, (Where M is H or CL), , -CCL=CCL-, -CH 2 OH 2 -, -OCH 2 CH 2 O- is selected from the group consisting of, d is 0 or 1, when d = 1 Y is -O, -S and Selected from group consisting of NH, Z is C 1 -C 12 alkyl, hydrogen, C 4 -C 1 6 polyalkoxyalkyl, C 4 -C 8 dialkylaminoalkyl, C 3 -C 5 alkynyl, phenyl, Substituted phenyl, a group consisting of an organic salt, and when d=0, Z is CL or (Where R, R 1 and R 2 are as defined above)}, (Where R 8 is selected from a group consisting of C 1 -C 5 alkoxyamino, hydrogen and organic bases), -SOWR 9 {where W is 0-2, R 9 amino, C 1 -C 5 alkyl, C 1 -C 4 haloalkyl, phenyl, C 1 -C 1 0 dialkylamino, C 1 -C 1 0 alkylamino, C 1 -C 5 alkoxy, substituted phenyl (where substituted is nitro, chloro, C 1 -C 4 is selected from a group consisting of alkyl and methoxy)} is selected from the group consisting of isopropyl urea human insecticide composition based on 1,2 or 3 claims. R3은 카르보알콕시알킬(여기서 알킬은 C1-C2알킬이다), 알킬케토알킬(여기서 알킬은 C1-C2알킬이다), 하이드록시알케닐(여기서 알케닐은 C3-C4알킬이다), 하이드록시알킬(여기서 알킬은 C1-C3알킬이다), 포름일하이드록시메틸, 하이드록시할로에틸(여기서 할로는 클로로, 치환페녹시알킬(여기서 알킬은 C1, 알킬이며, 치환분은 P-메톡시, CL, NO3또는 CN이다),(R1은 -OH, -NH2또는 메톡시이다),(여기서 R, R1및 R2는 상기 정의와 같다),R 3 is carboalkoxyalkyl (where alkyl is C 1 -C 2 alkyl), alkylketoalkyl (where alkyl is C 1 -C 2 alkyl), hydroxyalkenyl (where alkenyl is C 3 -C 4 Alkyl), hydroxyalkyl (where alkyl is C 1 -C 3 alkyl), formylhydroxymethyl, hydroxyhaloethyl (where halo is chloro, substituted phenoxyalkyl (where alkyl is C 1 , alkyl is , Substituents are P-methoxy, CL, NO 3 or CN), (R 1 is -OH, -NH 2 or methoxy), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), 또는(여기서 B는로 이루어지는 그루우프로부터 선택된 유기염기이다),(여기서 R4는 -H, C1-C8알킬, 하이드록시에틸, 나프닐, 페닐 그리고 치환분이 염소 C1-C2알킬, C1-C2알콕시, 니트로, 시아노 및 -CF3로 이루어지는 그루우프로부터 독자적으로 선택되는 치환페닐로 이루어지는 그루우프로부터 선택된다), or (Where B is It is an organic base selected from the group consisting of) (Where R 4 is -H, C 1 -C 8 alkyl, hydroxyethyl, naphthyl, phenyl and substituted with chlorine C 1 -C 2 alkyl, C 1 -C 2 alkoxy, nitro, cyano and -CF 3 Is selected from a group consisting of a substituted phenyl independently selected from the group consisting of) (여기서 R, R1및 R2의 정의는 상기와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2의 정의는 상기와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2의 정의는 상기와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2의 정의 페닐, 유기염, 무기염으로 이루어지는 그루우프로부터 선택되고, d=o인 경우에는 Z는 CL 또는(R, R1및 R2의 정의는 상기와 같다),{여기서 R8은 C1-C5알콕시, 아미노, C1-C5알콕시아미노, 하이드록시 및 유기염기로 이루어지는 그루우프로부터 선택된다), -SOWR9(여기서 W는 0∼2이며, R9는 아미노, C1-C5알킬, C1-C4할로알킬, 페닐, C1-C10 디알킬아미노, C1-C5알킬아미노, C1-C5알콕시 및 치환페닐(여기서 치환분은 니트로, C1-C4알킬 및 메톡시로 이루어지는 그루우프로부터 선택된다)}로 이루어지는 그루우프로부터 선택되는 특허청구의 범위 1,2 또는 기재의 이소티오요소 인사류 살충제 조성물.(Where R, R 1 and R 2 are selected from the group consisting of phenyl, organic salts, and inorganic salts, and when d=o, Z is CL or (R, R 1 and R 2 are as defined above), {Where R 8 is selected from a group consisting of C 1 -C 5 alkoxy, amino, C 1 -C 5 alkoxyamino, hydroxy and organic bases), -SOWR 9 (where W is 0-2 and R 9 Is amino, C 1 -C 5 alkyl, C 1 -C 4 haloalkyl, phenyl, C 1 -C 1 0 dialkylamino, C 1 -C 5 alkylamino, C 1 -C 5 alkoxy and substituted phenyl (where substituted The minute is selected from a group consisting of nitro, C 1 -C 4 alkyl and methoxy)}. The isothiourea human resource insecticide composition of claim 1 or 2 of the claims. R은 -secC7H15, R1은 -C6H13이고, R2는 -C2H5이며 R3은인 특허청구의 범위 1기재의 이소티오요소 인사류살충제 조성물.R is -secC 7 H 15 , R 1 is -C 6 H 13 , R 2 is -C 2 H 5 and R 3 is Phosphorus claim 1 isothiourea human resources insecticide composition. R은 -secC7H15이고 R1은 -C8H17이며, R2는 -CH3이며 R3은인 특허청구의 범위 1기재의 이소티오요소 인사류 살충제 조성물.R is -secC 7 H 15 , R 1 is -C 8 H 17 , R 2 is -CH3 and R 3 is Phosphorus claim 1 isothiourea human resources insecticide composition. 피페르디닐로 이루지는 그루우프로부터 선택된 복소환화합물을 형성한다],[여기서 X는 O 또는 S이며, n은 0 또는 1이고, R6은 C1-C4알킬, C2-C6할로알킬, 페닐 및 치환페닐(여기서 n은 1이며, 치환분은 니트로, 클로로, C1-C2알킬, C4-C6폴리알콕시알킬, C3-C8시클로알킬, C3-C4알케닐, C3-C6알콕시알킬, C2-C6하이드록시알킬, C5-C8트리알킬암모늄알킬염으로 이루어지는 그루우프로부터 선택되며, n=0인 경우에는, 치환분은 클로로, 티오포타슘, C1-C4알킬, 벤질, C1-C2헤테로알킬, C2-C4클로로 카르복시알킬 C4-C6폴리알콕시알킬 및 아세틸로이루어지는 그루우프로부터 선택된다)},{여기서 R7은 -(CH2-)n (여기서 n은 0∼8이다), -CH=CH-,(여기서 M은 H 또는 CL 이다),, -CCL=CCL-, -CH2OCH2-, -OCH2CH2O-로 이루어지는 그루우프로부터 선택되며, d는 0 또는 1이고, d=1인 경우에는 Y는 -O, -S 및 -NH로 이루어지는 그루우프로부터 선택되며, Z는 C1-C4알킬, 수소, C4-C16폴리알콕시알킬, C4-C8디알킬아미노알킬, C3-C5알키닐, 페닐, 치환이 수소 및 치환페닐 {여기서 치환분은 수소, C1-C4알콕시, 펜옥시, 트리플루오로메틸, C1-C6티오알킬, 니트로, 이소시아네이토, C2-C4폴리알콕시, C3-C7시클로알킬, C3-C10카르보알콕시알킬, C1-C4할로알킬, C3-C4알케닐, C2-C6디알킬아미노, 페닐아미노, C1-C4알킬, C3-C12하이드록시알킬아미도알킬, C5-C10N,N-하이드록시알킬우레이도알킬, 알킬이 C1-C5인 이소시아네이토알킬, C3-C12알킬아미도알킬, 폴리알콕시아미도알킬(여기서 폴리알콕시의 부분은 3∼6개의 반복 C2-C3알콕시단위를 함유하며, 아미도알킬 부분은 4-12개의 탄소원자를 함유한다), -SO2Cl, -SO2폴리알콕시아미도알킬(여기서 폴리알콕시부분은 3∼6개의 반복 C2-C3알콕시단위를 함유하며, 아미도 알킬부분은 4∼12개의 탄소원자를 함유한다)로 이루어지는 그루우프로부터 선택된다}의 것일 경우에는 아제피닐, 모르폴리닐, 피페르디닐, C1-C3알킬치환피레리디닐로 이루어지는 그루우프로부터 선택된 복소환화합물을 형성하며, R5는 수소, C1-C4알킬, C3-C6알콕시알킬, C3-C4알케닐, 하이드록시에틸 및 페닐로 이루어지는 그루우프로부터 선택되고, R4및 R5는 다같이 아제피닐, 모르폴리닐, 피페르디닐 및 C1-C3알킬치환 선택되며, Y는 수소 또는 메틸이고, R10은 -H, C1-C2알킬, C3-C4알케닐, C3-C4알키닐, C2-C3할로알킬, C3-C8시클로알킬, C7-C20폴리시클로알킬, C2-C16폴리알콕시알킬, C2-C6하이드록시알킬, C3-C10알콕시알킬, C3-C8카르보알콕시알킬, C4-C8시클로알킬알킬, C6-C8알킬시클로알킬, C4-C7시클로알킬아미노, C2-C10알킬아미노, C1-C3알킬아미노, C4-C12디알킬아미노알킬, C6-C10시클로알케닐, 페닐, 알킬페닐, (여기서 알킬은 C1-C4이다), 파라클로로알킬페닐(여기서 알킬은 C1-C4이다), 나프틸, 안트라세닐, 벤즈아미도시클로알킬 (여기서 알킬은 C1-C2이다), 피라닐메틸, 테트라하이드로프르푸릴, 티오페네메틸, 벤즈하이드릴, 할로벤즈하이드릴, 폴리시클릭알코올 및 치환페닐 여기서 치환분은 C1- C4알킬, 할로겐, 니트로, 트리플루오로메틸, 포름일, 클로로아세틸, C1-C4알콕시, 수소, 벤질, 클로로벤질, 펜에틸 및 치환펜에틸(여기서 치환분은 C1-C4알킬 및 할로겐으로 이루어지는 그루우프로부터 선택된다)}로 이루어지는 그루우프로부터 선택되며, R11은 C1-C4알킬, C3-C6알콕시알킬 및 알케닐로 이루어지는 그루우프로부터 선택되며, R10 및 R11은, 만약 X가 0 또는 S 인 동시에 R10는 상기와 같다)Form a heterocyclic compound selected from a group consisting of piperidinyl], [Where X is O or S, n is 0 or 1, R 6 is C 1 -C 4 alkyl, C 2 -C 6 haloalkyl, phenyl and substituted phenyl (where n is 1, substituted is nitro, Chloro, C 1 -C 2 alkyl, C 4 -C 6 polyalkoxyalkyl, C 3 -C 8 cycloalkyl, C 3 -C 4 alkenyl, C 3 -C 6 alkoxyalkyl, C 2 -C 6 hydroxyalkyl , C 5 -C 8 It is selected from a group consisting of a trialkylammonium alkyl salt, and when n=0, the substitution is chloro, thiopotassium, C 1 -C 4 alkyl, benzyl, C 1 -C 2 heteroalkyl , C 2 -C 4 chloro carboxyalkyl C 4 -C 6 polyalkoxyalkyl and acetylated group)), {Where R 7 is -(CH 2 -)n (where n is 0-8), -CH=CH-, (Where M is H or CL), , -CCL=CCL-, -CH 2 OCH 2 -, -OCH 2 CH 2 O- is selected from a group consisting of, d is 0 or 1, when d = 1, Y is -O, -S and Is selected from a group consisting of -NH, Z is C 1 -C 4 alkyl, hydrogen, C 4 -C 1 6 polyalkoxyalkyl, C 4 -C 8 dialkylaminoalkyl, C 3 -C 5 alkynyl, phenyl , Substituted hydrogen and substituted phenyl {where substituted is hydrogen, C 1 -C 4 alkoxy, phenoxy, trifluoromethyl, C 1 -C 6 thioalkyl, nitro, isocyanato, C 2 -C 4 poly Alkoxy, C 3 -C 7 cycloalkyl, C 3 -C 10 carboalkoxyalkyl, C 1 -C 4 haloalkyl, C 3 -C 4 alkenyl, C 2 -C 6 dialkylamino, phenylamino, C 1 -C 4 alkyl, C 3 -C 12 hydroxyalkylamidoalkyl, C 5 -C 10 N,N-hydroxyalkylureidoalkyl, isocyanatoalkyl with alkyl being C 1 -C 5 , C 3- C 12 alkylamidoalkyl, polyalkoxyamidoalkyl (where the part of the polyalkoxy contains 3 to 6 repeating C 2 -C 3 alkoxy units, and the amidoalkyl part contains 4-12 carbon atoms), -SO 2 Cl, -SO 2 polyalkoxyamidoalkyl (where the polyalkoxy portion contains 3 to 6 repeating C 2 -C 3 alkoxy units, and the amido alkyl portion contains 4 to 12 carbon atoms) Is selected from a group consisting of azepinyl, morpholinyl, piperidinyl, C 1 -C 3 alkyl-substituted pyreridinyl to form a heterocyclic compound selected from the group, R 5 is hydrogen , C 1 -C 4 alkyl, C 3 -C 6 alkoxyalkyl, C 3 -C 4 alkenyl, hydroxyethyl and a group consisting of phenyl, R 4 and R 5 together are azepinyl, mor Polyyl, piperidinyl and C 1 -C 3 alkyl substituted, Y is hydrogen or methyl, R 1 0 is -H, C 1 -C 2 alkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl , C 2 -C 3 haloalkyl, C 3 -C 8 cycloalkyl, C 7 -C 20 polycycloalkyl, C 2 -C 16 polyalkoxyalkyl, C 2 -C 6 hydroxyalkyl, C 3 -C 10 alkoxy Alkyl, C 3 -C 8 carboalkoxyalkyl, C 4 -C 8 cycloalkylalkyl, C 6 -C 8 alkylcycloalkyl, C 4 -C 7 cycloalkylamino, C 2 -C 10 alkylamino, C 1- C 3 alkylamino, C 4 -C 12 dialkylaminoalkyl, C 6 -C 10 cycloalkenyl, phenyl, alkylphenyl, where alkyl is C 1 -C 4 , parachloroalkylphenyl (where alkyl is C 1 -C 4 ), naphthyl, anthracenyl, benzamidocycloalkyl (where alkyl is C 1 -C 2 ), pyranylmethyl, tetrahydrofurfuryl, thiophenemethyl, benzhydryl, halobenz Hydryl, polycyclic alcohol and substituted phenyl wherein the substituted is C 1 -C 4 alkyl, halogen, nitro, trifluoromethyl, formyl, chloroacetyl, C 1 -C 4 alkoxy, hydrogen, benzyl, chlorobenzyl, pen Ethyl and substituted phenethyl (where the substitution is selected from a group consisting of C 1 -C 4 alkyl and halogen)), R 1 1 is C 1 -C 4 alkyl, C 3 -C 6 selected from a group consisting of alkoxyalkyl and alkenyl, R 1 0 and R 1 1, if X is 0 or S and R 1 0 are the same as above) (여기서 R, R1및 R2의 정의는 상기와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 X는 1∼8이며, R, R1및 R2의 정의는 상기와 같다),(Where X is 1 to 8, and the definitions of R, R 1 and R 2 are the same as above), (여기서 m는 2 또는 3이며, R, R1및 R2의 정의는 상기와 같다),(Where m is 2 or 3, and the definitions of R, R 1 and R 2 are as above), (여기서 R, R1및 R2의 정의는 상기와 같다),(Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2의 정의는 상기와 같다),(Where R, R 1 and R 2 are as defined above), 여기서 X는 O, S, NH, NR11로 이루어지는 그루우프로부터Where X is from a group consisting of O, S, NH, NR 1 1 R은 -secC7H15이고, R1은 -C8H17이며, R2는 -C2H5이고, R3은인 특허청구의 범위 1기재의 이소티오요소 인사류 살충제 조성물.R is -secC 7 H 15 , R 1 is -C 8 H 17 , R 2 is -C 2 H 5 , R 3 is Phosphorus claim 1 isothiourea human resources insecticide composition. R은 -secC7H15이고, R1은 -C8H17이고, R2는 -C2H5이고, R3은인 특허청구의 범위 1기재의 이소티오요소 인사류 살충제 조성물.R is -secC 7 H 15 , R 1 is -C 8 H 17 , R 2 is -C 2 H 5 , R 3 is Phosphorus claim 1 isothiourea human resources insecticide composition. 특허청구의 범위 1기재의 화합물과 부동담체로 이루어지는 이소티오요소 인사류(鱗(스캔 작업)類)살충제 조성물.Isothiourea human resources (鱗(scanning work)類) pesticide composition consisting of the compound of claim 1 and the floating carrier. 특허청구의 범위 2기재의 화합물과 부동담체로 이루어지는 이소티오요소 인사류 살충제 조성물.Isothiourea personnel insecticide composition composed of a compound and a floating carrier based on the scope of the claims. 특허청구의 범위 3기재의 화합물과 부동담체로 이루어지는 이소티오요소 인사류 살충제 조성물.Isothiourea personnel insecticide composition consisting of a compound and a floating carrier of the three bases of the claims. R3은 카르보알콕시알킬(여기서 알킬은 C1-C2알킬이다), 알킬케토알킬(여기서 알킬은 C1-C2알킬이다), 하이드록시알케닐(여기서 알케닐은 C3-C4알킬이다) 하이드록시알킬(여기서 알킬은 C1-C6알킬이다), 포름일하이드록시메틸, 하이드록시알로에틸(여기서 할로는 클로로 또는 브로모이다), 치환페녹시알킬(여기서 알킬은 C1알킬이며, 치환분은 P-메톡시, CL, NO3또는 CN이다),R 3 is carboalkoxyalkyl (where alkyl is C 1 -C 2 alkyl), alkylketoalkyl (where alkyl is C 1 -C 2 alkyl), hydroxyalkenyl (where alkenyl is C 3 -C 4 Alkyl) hydroxyalkyl (where alkyl is C 1 -C 6 alkyl), formylhydroxymethyl, hydroxyalloethyl (where halo is chloro or bromo), substituted phenoxyalkyl (where alkyl is C 1 alkyl , And the substituted component is P-methoxy, CL, NO 3 or CN), (여기서 R1은 -OH, -NH2또는 메톡시이다), (Where R 1 is -OH, -NH 2 or methoxy), (여기서 R, R1및 R2의 정의는 상기와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2의 정의는 상기와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 B는 유기 염기이다),{여기서 R4는 -H, C1-C12알킬, 하이드록시에틸, 나프틸, 페닐, 치환페닐(여기서 치환분은 수소, 할로겐, C1-C5알킬, C1-C5알콕시니트로, 시이노 및 -CF3로 이루어지는 그루우프로부터 선택된다), (Where B is an organic base), {Where R 4 is -H, C 1 -C 12 alkyl, hydroxyethyl, naphthyl, phenyl, substituted phenyl (where substituted is hydrogen, halogen, C 1 -C 5 alkyl, C 1 -C 5 alkoxynitro, Cyno and -CF 3 ). (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 X는 1∼8이며, R, R1및 R2는 상기 정의와 같다),(Where X is 1 to 8, R, R 1 and R 2 are as defined above), (여기서 m은 2 또는 3이며, R, R1및 R2는 상기 정의와 같다),(Where m is 2 or 3, R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다),(Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), [여기서 X는 O, S, NH, NR11로 이루어지는 그루우프로부터 선택되며, Y는 수소 또는 메틸이고, R10은 -H, C1-C8알킬, C3-C4알케닐, C3-C4알키닐, C2-C3할로알킬, C3-C8시클로알킬, C7-C20폴리시클로알킬, C2-C16폴리알콕시알킬, C2-C6하이드록시알킬, C3-C10알콕시알킬, C3-C8카르보알콕시알킬, C4-C8시클로알킬알킬, C6-C8알킬시크로알킬, C4-C7시클로알킬아미노, C2-C10알킬아미노, C1-C3알킬아미노, C4-C12디알킬아미노알킬, C6-C10시클로알케닐, 페닐, 알킬페닐(알킬은 C1-C4이다) 파라클로로알킬페닐(여기서 알킬은 C1-C4이다), 나프틸, 안트라아세닐, 벤즈아미도시클로알킬(여기서 알킬은 C1-C2이다), 피라닐메틸, 테트리히드로푸르푸릴, 티오페네메틸벤, 즈하이드릴, 할로벤즈하이드릴, 폴리시클로알코올 및 치환페닐 {여기서 치환분은 C1-C4알킬, 할로겐, 니트로, 트리플루오로메틸, 포름일, 클로로아세틸, C1-C4알콕시, 수소, 클로로벤질, 펜에틸 및 치환펜에틸(여기서 치환분은 C1-C4알킬, 할로겐으로 이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로부터 선택되며, R11은 C1-C4알킬, C3-C6알콕시알킬 및 C3-C4알케닐로 이루어지는 그루우프로부터 선택되고, R11은 C1-C4알킬, C3-C6알콕시알킬 및 C3-C4알케닐로 이루어지는 그루우프로부터 선택되고, R10 및 R11은, X 가 0 또는 S인 동시에 R10이 수소 및 치환페닐(여기서 치환분은 할로겐, C1-C4알콕시, 페녹시, 트리플루오로메틸, C1-C6티오알킬, 니트로, 이소시아네이도, C2-C4폴리알콕시, C3-C7시클로알킬, C3-C10카르보알콕시알킬, C1-C4할로알킬, C3-C4알케닐, C2-C6디알킬아미노, 페닐아미노, C1-C4알킬, C3-C12하이드록시알킬아미도알킬, C5-C10N,N,-하이드록시알킬우레이도알킬, 알킬이 C1-C5인 이소시아네이토알킬 C3-C12알킬아미도알킬, 폴리알콕시부분은 3∼6개의 반복 C2-C3알콕시 단위를 함유하고 아미도알킬부분은 4-12개의 탄소원자를 함유하는 폴리알콕시아미도알킬, -SO2Cl, 폴리알콕시부분은 3∼6개의 반복 C2-C3알콕시단위를 함유하고 아미도알킬부분은 4-12개의 탄소원자를 함유하는 -SO2폴리알콕시 아미도알킬로 이루어지는 그루우프로부터 선택된다)}]로 이루어지는 그루우프로부터 선택되며, B5는 수소, C1-C4알킬, C3-C6알콕시알킬, C3-C4알케닐, 하이드록시에틸 및 페닐로 이루어지는 그루우프로부터 선택되며, R4및 R5는 아제피닐, 도르폴리닐, 피레르디닐, 및 C1-C3알킬치환페닐페르디닐로이루어지는 그루우프로부터 선택되는 복소환식화합물을 형성한다],{여기서 X는 0 또는 S이며, n은 0 또는 1이고, R6은 C1-C12알킬, C2-C6할로알킬, 페닐 및 치환페닐여기서 n은 1이며, 치환분은 니트로, 클로로, C1-C2알킬, C4-C6폴리알콕시알킬아미도알킬, C5-C10N,N-하이드록시알킬우레이도알킬, 알킬이 C1-C5인 이소시아네이트알킬, C3-C12알킬아미도알킬, 폴리알콕시부분은 3-6개의 반복 C2-C3알콕시단위를 함유하고, 아미도알킬부분은 4∼12개의 탄소원자를 함유하는 폴리알콕시 아미도알킬, -SO2Cl, 폴리알콕시일부분은 3∼6개의 반복 C2-C3알콕시단위를 함유하고 아미도알킬의 일부분은 4∼12개의 탄소원자를 함유하는 -SO2폴리알콕시아미도알킬로 이루어지는 그루우프로부터 선택된다)이다}]로 이루어지는 그루우프로부터 선택되며, R5는 수소, C1-C4알킬, C3-C6알콕시알킬, C3-C4알케닐, 하이드록시에틸 및 페닐로 이루어지는 그루우프로부터 선택되며, R4및 R5는 함께 복소환식 화합물을 형성한다.],{여기서 X는 O 또는 S이며, n은 0 또는 1이고, R6는 C1-C4알킬, C2-C6할로알킬, 페닐 및 치환페닐(여기서 n은 1이며, 치환분은 니트로, 클로로, C1-C2알킬, C4-C6폴리알콕시알킬, C3-C8시클로알킬, C3-C4알케닐, C3-C6알콕시알킬, C2-C6하이드록시알킬, C1-C3카르복시알킬 및 C5-C8트리알킬암모늄알킬염으로 이루어지는 그루우프로부터 선택되며, n-0일 경우에는 치환분은 클로로, 티오포타슘, C1-C4알킬, 벤질, C1-C2헤테로알킬, C2-C4클로로카르복시알킬, C4-C6폴리알콕시알킬 및 아세틸로 이루어진 그루우프로부터 선택된다)로 이루어 알킬시클로알킬, C4-C7시클로알킬아미노, C2-C10알킬아미노, C1-C3알킬아미노, C4-C12디알킬아미노알킬, C6-C10시클로알케닐, 페닐, 알킬페닐 여기서 알킬은 C1-C4이다), 파라클로로알킬페닐 (여기서 알킬은 C1-C4이다), 나프틸, 안트라세닐, 벤즈아미도시클로알킬(여기서 알킬은 C1-C2이다), 피라닐메틸, 테트라하이드로푸르푸릴, 티오페네메틸, 벤즈하이드릴, 할로벤즈하이드릴, 폴리시클릭알코올 및 치환페닐 {여기서 치환분은 C1-C4알킬, 할로겐, 니트로, 트리플루오로메틸, 표르밀, 클로로아세틸, C1-C4알콕시, 수소, 벤질, 클로로벤질, 페네틸 및 치환페네틸 (여기서 치환분은 C1-C4알킬 및 할로겐으로 이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로부터 선택되며, R11은 C1-C4알킬, C3-C6알콕시알킬 및 C3-C4알케닐로 이루어지는 그루우프로부터 선택되고, R10 및 R11은 바람직하게는 아제피닐, 모르폴리닐, 피페르디닐, C1-C3알킬치환피페르디닐로 이루어지는 그루우프로부터 선택되는 복소환화합물을 함께 형성하며, X가 0 또는 S일경우에는 R10이 수소 및 치환페닐(여기서 치환분은 할로겐, C1-C4알콕시, 페녹시, 트리플루오로메틸, C1-C6티오알킬, 니트로, 이소시아네이트, C2-C4폴리알콕시, C3-C7시클로알킬, C3-C10카르보알콕시알킬, C1-C4할로알킬, C3-C4알케닐, C2-C6디알킬아미노, 페닐아미노, C1-C4알킬, C3-C12하이드록시 (여기서 R, R1및 R2는 상기 정의와 같다),[Where X is selected from a group consisting of O, S, NH, NR 1 1, Y is hydrogen or methyl, R 1 0 is -H, C 1 -C 8 alkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, C 2 -C 3 haloalkyl, C 3 -C 8 cycloalkyl, C 7 -C 20 polycycloalkyl, C 2 -C 16 polyalkoxyalkyl, C 2 -C 6 hydroxyalkyl , C 3 -C 10 alkoxyalkyl, C 3 -C 8 carboalkoxyalkyl, C 4 -C 8 cycloalkylalkyl, C 6 -C 8 alkylcycloalkyl, C 4 -C 7 cycloalkylamino, C 2- C 10 alkylamino, C 1 -C 3 alkylamino, C 4 -C 12 dialkylaminoalkyl, C 6 -C 10 cycloalkenyl, phenyl, alkylphenyl (alkyl is C 1 -C 4 ) parachloroalkylphenyl (Where alkyl is C 1 -C 4 ), naphthyl, anthracenyl, benzamidocycloalkyl (where alkyl is C 1 -C 2 ), pyranylmethyl, tetrihydrofurfuryl, thiophenemethyl Ben, zhydryl, halobenzhydryl, polycycloalcohol and substituted phenyl {where substituted is C 1 -C 4 alkyl, halogen, nitro, trifluoromethyl, formyl, chloroacetyl, C 1 -C 4 alkoxy , Hydrogen, chlorobenzyl, phenethyl and substituted phenethyl (where the substituted is selected from a group consisting of C 1 -C 4 alkyl, halogen), R 1 1 is selected from C 1 -C 4 Alkyl, C 3 -C 6 alkoxyalkyl and C 3 -C 4 alkenyl, selected from group, R 1 1 is C 1 -C 4 alkyl, C 3 -C 6 alkoxyalkyl and C 3 -C 4 al R 1 0 and R 1 1 are selected from a group consisting of kenyl, and X is 0 or S, while R 1 0 is hydrogen and substituted phenyl (where substituted is halogen, C 1 -C 4 alkoxy, phenoxy, Trifluoromethyl, C 1 -C 6 thioalkyl, nitro, isocyanado, C 2 -C 4 polyalkoxy, C 3 -C 7 cycloalkyl, C 3 -C 10 carboalkoxy Alkyl, C 1 -C 4 haloalkyl, C 3 -C 4 alkenyl, C 2 -C 6 dialkylamino, phenylamino, C 1 -C 4 alkyl, C 3 -C 12 hydroxyalkylamidoalkyl, C 5 -C 10 N,N,-hydroxyalkylureidoalkyl, isocyanatoalkyl with alkyl of C 1 -C 5 C 3 -C 12 alkylamidoalkyl, polyalkoxy moiety 3 to 6 repeats C 2 -C 3 alkoxy units, the amidoalkyl moiety contains 4-12 carbon atoms, polyalkoxyamidoalkyl, -SO 2 Cl, and the polyalkoxy moiety contains 3 to 6 repeating C 2 -C 3 alkoxy units And the amidoalkyl moiety is selected from a group consisting of -SO 2 polyalkoxy amidoalkyl containing 4-12 carbon atoms)}], B5 is hydrogen, C 1 -C 4 alkyl , C 3 -C 6 alkoxyalkyl, C 3 -C 4 alkenyl, hydroxyethyl and a group consisting of phenyl, R 4 and R 5 are azepinyl, dopollinyl, pyrerdinyl, and C Forms a heterocyclic compound selected from a group consisting of 1 -C 3 alkyl-substituted phenylperdinyl], {Where X is 0 or S, n is 0 or 1, R 6 is C 1 -C 12 alkyl, C 2 -C 6 haloalkyl, phenyl and substituted phenyl, where n is 1 and the substituted is nitro, chloro , C 1 -C 2 alkyl, C 4 -C 6 polyalkoxyalkylamidoalkyl, C 5 -C 10 N,N-hydroxyalkylureidoalkyl, isocyanate alkyl with alkyl being C 1 -C 5 , C 3- The C 12 alkylamidoalkyl, polyalkoxy portion contains 3-6 repeating C 2 -C 3 alkoxy units, and the amidoalkyl portion contains polyalkoxy amidoalkyl containing 4 to 12 carbon atoms, -SO 2 Cl , Part of the polyalkoxy is selected from the group consisting of -SO 2 polyalkoxyamidoalkyl containing 3 to 6 repeating C 2 -C 3 alkoxy units and part of the amidoalkyl containing 4 to 12 carbon atoms) Is selected from the group consisting of], R 5 is selected from a group consisting of hydrogen, C 1 -C 4 alkyl, C 3 -C 6 alkoxyalkyl, C 3 -C 4 alkenyl, hydroxyethyl and phenyl. And R 4 and R 5 together form a heterocyclic compound.], {Where X is O or S, n is 0 or 1, R 6 is C 1 -C 4 alkyl, C 2 -C 6 haloalkyl, phenyl and substituted phenyl (where n is 1, substituted is nitro, Chloro, C 1 -C 2 alkyl, C 4 -C 6 polyalkoxyalkyl, C 3 -C 8 cycloalkyl, C 3 -C 4 alkenyl, C 3 -C 6 alkoxyalkyl, C 2 -C 6 hydroxyalkyl , C 1 -C 3 carboxyalkyl and C 5 -C 8 trialkyl ammonium alkyl salts are selected from a group consisting of a salt, and in the case of n-0, the substitution is chloro, thiopotassium, C 1 -C 4 alkyl, benzyl, C 1 -C 2 heteroalkyl, C 2 -C 4 chlorocarboxyalkyl, C 4 -C 6 polyalkoxyalkyl and a group consisting of acetyl) alkylcycloalkyl, C 4 -C 7 cycloalkylamino, C 2 -C 10 alkylamino, C 1 -C 3 alkylamino, C 4 -C 12 dialkylaminoalkyl, C 6 -C 10 cycloalkenyl, phenyl, alkylphenyl where alkyl is C 1 -C 4 ), Parachloroalkylphenyl (where alkyl is C 1 -C 4 ), naphthyl, anthracenyl, benzamidocycloalkyl (where alkyl is C 1 -C 2 ), pyranylmethyl, tetrahydrofurfuryl, thiope Nemethyl, benzhydryl, halobenzhydryl, polycyclic alcohol and substituted phenyl {where substituted is C 1 -C 4 alkyl, halogen, nitro, trifluoromethyl, pyrryl, chloroacetyl, C 1 -C 4 Selected from a group consisting of alkoxy, hydrogen, benzyl, chlorobenzyl, phenethyl and substituted phenethyl, wherein the substituent is selected from a group consisting of C 1 -C 4 alkyl and halogen, R 1 1 is C 1 -C 4 alkyl, C 3 -C 6 alkoxyalkyl and C 3 -C 4 alkenyl is selected from a group consisting of R 1 0 and R 1 1 preferably azepinyl, morpholinyl, piperidinyl , C 1 -C 3 To form a heterocyclic compound selected from a group consisting of alkyl-substituted piperidinyl, X is 0 or In the case of S, R 1 0 is hydrogen and substituted phenyl (where substituted is halogen, C 1 -C 4 alkoxy, phenoxy, trifluoromethyl, C 1 -C 6 thioalkyl, nitro, isocyanate, C 2 -C 4 polyalkoxy, C 3 -C 7 cycloalkyl, C 3 -C 10 carboalkoxyalkyl, C 1 -C 4 haloalkyl, C 3 -C 4 alkenyl, C 2 -C 6 dialkylamino, phenylamino, C 1 -C 4 alkyl, C 3 -C 12 hydroxy (where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다)(Where R, R 1 and R 2 are as defined above) (여기서 R, R1및 R2는 상기 정의와 같다),(Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다)(Where R, R 1 and R 2 are as defined above) (여기서 X는 1∼8이며, R, R1및 R2는 상기 정의와 같다),(Where X is 1 to 8, R, R 1 and R 2 are as defined above), (여기서 m은 2 또는 이며, R, R1및 R2는 상기 정의와 같다),(Where m is 2 or R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다)(Where R, R 1 and R 2 are as defined above) (여기서 R, R1및 R2는 상기 정의와 같다)(Where R, R 1 and R 2 are as defined above) [여기서 X는 O, S, NH 및 NR11로 이루어지는 그루우프로부터 선택되며, Y는 수소 또는 메틸이고, R10은 -H, C1-C2알킬, C3-C4알케닐, C3-C4알키닐, C2-C3할로알킬, C3-C8시클로알킬, C7-C20폴리시클로알킬, C2-C16폴리알콕시알킬, C2-C6하이드록시알킬, C3-C10(알콕시알킬, C3-C8카르보알콕시알킬, C4-C8시클로알킬알킬, C6-C8알시, 치환페닐 (여기서 치환분은 니트로, 클로로, C1-C4알킬 및 메톡시로이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로부터 선택된다}로 이루어지는 그루우프로부터 선택된다.[Where X is selected from a group consisting of O, S, NH and NR 1 1, Y is hydrogen or methyl, R 1 0 is -H, C 1 -C 2 alkyl, C 3 -C 4 alkenyl, C 3 -C 4 alkynyl, C 2 -C 3 haloalkyl, C 3 -C 8 cycloalkyl, C 7 -C 20 polycycloalkyl, C 2 -C 16 polyalkoxyalkyl, C 2 -C 6 hydroxyalkyl , C 3 -C 10 (alkoxyalkyl, C 3 -C 8 carboalkoxyalkyl, C 4 -C 8 cycloalkylalkyl, C 6 -C 8 acyl, substituted phenyl (where the substituted is nitro, chloro, C 1- C 4 alkyl and methoxy, which are selected from the group consisting of). R3은 카르보알알콕시알킬(여기서 알킬은 C1-C2알킬이다), 알킬케토알킬(여기서 알킬은 C1-C2알킬이다), 하이드록시알케닐(여기서 알케닐은 C3-C4알킬이다), 하이드록시알킬(여기서 알킬은 C1-C3알킬이다), 포르밀하이드록시메틸, 하이드록시할로에틸(여기서 할로는 클로로이다), 치환페녹시알킬(여기서 알킬은 C1알킬이며, 치환분은 P-메톡시, C1, NO2 또는 CN이다.),{여기서 R1은 -OH, -NH2또는 메톡시,(여기서 R, R1및 R2는 위에서 정의한 바와 같다)},{여기서 R, R1및 R2는 상기 정의와 같다)}.B (여기서 B는 그루우프(CH3)3에서 선택되는 유기염이다),{여기서 R4는 -H, C1-C8알킬, 하이드록시에틸, 나프틸, 페닐, 치환페닐(여기서 치환분은 클로라인, C1-C2알킬, C1-C2알콕시, 니트로, 시아노 및 -CF3로 이루어지는 그루우프로부터 독자적으로 선택된다.)로 이루어지는 그루우프로부터 선택된다.(여기서 R, R1및 R2는 상기 정의와 같다)시알킬, C3-C8시클로알킬, C3-C6알케닐, C2-C6알콕시알킬, C2-C6하이드록시알킬, C1-C3카르복시알킬, C5-C8트리알킬암모늄알킬염으로 이루어지는 그루우프로부터 선택되며, n=0인 경우에는 치환분은 클로로, 티오포타슘, C1-C12알킬, 벤질, C1-C2헤트로알킬, C2-C4클로로카르복시알킬, C4-C6폴리알콕시알킬 및 아세틸로 이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로로부터 선택된다.},{여기서 R7은 1(CH2-)n (여기서 n은 0∼8이다), -CH=CH(여기서 M은 H 또는 CL 이다),-CCL=CCL-, CH2OCH2, -OCH2CHO-로 이루어지는 그루우프로부터 선택되고, d는 0 또는 1이며, d=1인 경우에는 Y는 -0, -S 및 -NH로 이루어지는 그루우프로부터 선택되며, Z는 C1-C12알킬, 수소, C4-C16 폴리알콕시알킬, C4-C8디알킬아미노알킬, C3-C5알키닐, 페닐, 치환페닐, 유기염으로 이루어지는 그루우프로부터 선택되며, d=0이고 Z가 CL 또는, (여기서 R, R1및 R2는 상기 정의와 같다)로 이루어지는 그루우프로부터 선택된다},(여기서 R8은 C1-C5알콕시, 아미노, C1-C5알콕시아미노, 수소 및 유기염기로 이루어지는 그루우프로부터 선택된다), -SOWR9{여기서 W=0∼2이며, R9는 아미노, C1-C5알킬, C1-C4할로알킬, 페닐, C1-C10 디알킬아미노, C1-C10 알킬아미노, C1-C5알콕진 그루우프로부터 선택된다.},{여기서 R7은 -(CH2-)n(여기서 n은 0∼8이다), -CH=CH-,(여기서 M은 H 또는 Cl이다),, -CCl=CCl-, -CH2OCH2- 및 OCH2CH2O-로 이루어지는 그루우프로부터 선택되고, d는 0 또는 1이며, d=1일 경우에는 Y는 -0, -S 및 -NH로 이루어지는 그루우프로부터 선택되며, Z는 C1-C4알킬, 수소, C4-C16 폴리알콕시알킬, C4-C8디알킬아미노알킬, C3-C5알키닐, 페닐, 치환페닐, 유기염, 무기염으로 이루어지는 그루우프로부터 선택되며, d=0이고 Z가 Cl 또는, (여기서 R, R1및 R2의 정의는 상기한 바와 같다)로 이루어지는 그루우프로부터 선택된다.},(여기서 R8은 C1-C5알콕시, 아미노, C1-C5알콕시아미노, 하이드록시 및 유기염기로 이루어지는 그루우프로부터 선택된다.), -SOWR9{여기서 W=0∼2이며, R9은 아미노, C1-C5알킬, C1-C4할로알킬, 페닐, C1-C10 디알킬아미노, C1-C10 알킬아미노, C1-C5알콕시, 치환페닐(여기서 치환분은 니트로, 클로로, C1-C4알킬 및 메톡시로 이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로부터 선택된다}로 이루어지는 그루우프로부터 선택된다.R 3 is carboalalkoxyalkyl (where alkyl is C 1 -C 2 alkyl), alkylketoalkyl (where alkyl is C 1 -C 2 alkyl), hydroxyalkenyl (where alkenyl is C 3 -C 4 Alkyl), hydroxyalkyl (where alkyl is C 1 -C 3 alkyl), formylhydroxymethyl, hydroxyhaloethyl (where halo is chloro), substituted phenoxyalkyl (where alkyl is C 1 alkyl , And the substituted component is P-methoxy, C 1 , NO2 or CN.), {Where R 1 is -OH, -NH 2 or methoxy, (Where R, R 1 and R 2 are as defined above)}, {Where R, R 1 and R 2 are as defined above)}. B (where B is the groove (CH3)3 It is an organic salt selected from), {Where R 4 is -H, C 1 -C 8 alkyl, hydroxyethyl, naphthyl, phenyl, substituted phenyl (where substituted is chlorine, C 1 -C 2 alkyl, C 1 -C 2 alkoxy, nitro, It is independently selected from the group consisting of cyano and -CF 3 ). (Where R, R 1 and R 2 are as defined above) Cyalkyl, C 3 -C 8 cycloalkyl, C 3 -C 6 alkenyl, C 2 -C 6 alkoxyalkyl, C 2 -C 6 hydroxyalkyl, C 1 -C 3 carboxyalkyl, C 5 -C 8 tree It is selected from a group consisting of alkyl ammonium alkyl salts, and when n=0, the substituted component is chloro, thiopotassium, C 1 -C 12 alkyl, benzyl, C 1 -C 2 hetroalkyl, C 2 -C 4 chloro. Selected from a group consisting of carboxyalkyl, C 4 -C 6 polyalkoxyalkyl and acetyl). {Where R 7 is 1(CH 2 -)n (where n is 0 to 8), -CH=CH (Where M is H or CL), -CCL=CCL-, CH 2 OCH 2 , -OCH 2 CHO- is selected from a group consisting of, d is 0 or 1, and when d=1, Y is -0, -S and -NH Selected from loops, Z is C 1 -C 12 alkyl, hydrogen, C 4 -C 1 6 polyalkoxyalkyl, C 4 -C 8 dialkylaminoalkyl, C 3 -C 5 alkynyl, phenyl, substituted phenyl, organic Selected from the group consisting of salts, d=0 and Z is CL or , (Where R, R 1 and R 2 are as defined above) are selected from the group consisting of}, (Where R 8 is selected from a group consisting of C 1 -C 5 alkoxy, amino, C 1 -C 5 alkoxyamino, hydrogen and organic bases), -SOWR 9 {where W=0 to 2, R 9 is Amino, C 1 -C 5 alkyl, C 1 -C 4 haloalkyl, phenyl, C 1 -C 1 0 dialkylamino, C 1 -C 1 0 alkylamino, C 1 -C 5 alkoxygin group .}, {Where R 7 is -(CH 2 -)n (where n is 0 to 8), -CH=CH-, (Where M is H or Cl), , -CCl=CCl-, -CH 2 OCH 2 -and OCH 2 CH 2 O- is selected from the group consisting of, d is 0 or 1, when d = 1 Y is -0, -S and- Selected from group consisting of NH, Z is C 1 -C 4 alkyl, hydrogen, C 4 -C 1 6 polyalkoxyalkyl, C 4 -C 8 dialkylaminoalkyl, C 3 -C 5 alkynyl, phenyl, Selected from a group consisting of substituted phenyl, organic salt, and inorganic salt, d=0 and Z is Cl or , (Where R, R 1 and R 2 are as defined above). (Where R 8 is selected from a group consisting of C 1 -C 5 alkoxy, amino, C 1 -C 5 alkoxyamino, hydroxy and organic bases.), -SOWR 9 {where W=0-2, R 9 is amino, C 1 -C 5 alkyl, C 1 -C 4 haloalkyl, phenyl, C 1 -C 1 0 dialkylamino, C 1 -C 1 0 alkylamino, C 1 -C 5 alkoxy, substituted phenyl ( Here, the substituted component is selected from a group consisting of nitro, chloro, C 1 -C 4 alkyl, and a group consisting of methoxy). R은 -secC7H15이며 R1은 -C6H13이고, R2는 -C2H5이며, R3은인 특허청구의 범위 10 기재의 이소티오요소 인사류 살충제 조성물.R is -secC 7 H 15 , R 1 is -C 6 H 13 , R 2 is -C 2 H 5 , R 3 is Isothiourea personnel insecticide composition according to claim 10 of the phosphorus claim. R은 -secC7H15이며 R1은 -C8H17이고, R2는 -CH3이며, R3은인 특허청구의 범위 10 기재의 이소티오요소 인사류 살충제 조성물.R is -secC 7 H 15 , R 1 is -C 8 H 17 , R 2 is -CH3, and R 3 is Isothiourea personnel insecticide composition according to claim 10 of the phosphorus claim. R은 -secC7H15이며 R1은 -C8H17이고, R2는 -C2H5이며, R3은인 특허청구의 범위 10 기재의 이소티오요소 인사류 살충제 조성물.R is -secC 7 H 15 , R 1 is -C 8 H 17 , R 2 is -C 2 H 5 , R 3 is Isothiourea personnel insecticide composition according to claim 10 of the phosphorus claim. R은 -secC7H15이며 R1은 -C8H17이고, R2는 -C2H5이며, R3은인 특허청구의 범위 10 기재의 이소티오요소 인사류 살충제 조성물.R is -secC 7 H 15 , R 1 is -C 8 H 17 , R 2 is -C 2 H 5 , R 3 is Isothiourea personnel insecticide composition according to claim 10 of the phosphorus claim. 특허청구의 범위 1 기재의 이소티오요소 인사류 살충제의 유효량을 인사류해충자체 또는 그 서식처 및 사료에 적용함으로써 이루어지는 인사류 해충 억제방법.A method for inhibiting human insect pests by applying an effective amount of the isothiourea human insecticide described in the scope 1 of the claims to the human insect pest itself or its habitat and feed. 특허청구의 범위 2 기재의 이소티오요소 인사류 살충제의 유효량을 인사류해충자체 또는 그 서식처 및 사료에 적용함으로써 이루어지는 인사류 해충 억제방법.A method for inhibiting human insect pests by applying an effective amount of the isothiourea human insecticide described in the scope 2 of the claims to the human insect pest itself or its habitat and feed. 특허청구의 범위 3 기재의 이소티오요소 인사류 살충제의 유효량을 인사류해충자체 또는 그 서식처 및 사료에 적용함으로써 이루어지는 인사류 해충 억제방법.A method for inhibiting human insect pests by applying an effective amount of the isothiourea human insecticide described in the scope 3 of the claims to the human insect pest itself or its habitat and feed. R3은 카르보알콕시알킬(여기서 알킬은 C1-C2알킬이다), 알킬케로알킬(여기서 알킬은 C1-C2알킬이다), 하이드록시알케닐(여기서 알케닐은 C3-C4알킬이다), 하이드록시알킬(여기서 알킬은 C1-C8알킬이다), 포르밀하이드록시메틸, 하이드록시 할로에틸(여기서 할로는 클로로 또는 브로로이다), 치환페녹시알킬(여기서 알킬은 C1알킬이며, 치환분은 P-메톡시, Cl, NO3또는 CN 이다),{여기서 R1은 -OH, -NH2또는 메톡시,, (여기서 R, R1및 R2는 위에서 정의한 바와 같다),(여기서 R, R1및 R2는 위에서 정의한 바와 같다),또는 -SO3·B (여기서 B는 염기이다),{여기서 R5는 -H, C1-C12알킬, 하이드록시에틸, 나프틸, 페닐, 치환페닐(여기서 치환분은 할로겐, C1-C5알킬, C1-C5알콕시, 니트로, 시아노 및 -CF3로 이루어지는 그루우프로부터 독자적으로 선택된다)로 이루어지는 그루우프로부터 선택된다.}R 3 is carboalkoxyalkyl (where alkyl is C 1 -C 2 alkyl), alkylkeroalkyl (where alkyl is C 1 -C 2 alkyl), hydroxyalkenyl (where alkenyl is C 3 -C 4 Alkyl), hydroxyalkyl (where alkyl is C 1 -C 8 alkyl), formylhydroxymethyl, hydroxy haloethyl (where halo is chloro or broro), substituted phenoxyalkyl (where alkyl is C 1 alkyl, and the substituted component is P-methoxy, Cl, NO 3 or CN), {Where R 1 is -OH, -NH 2 or methoxy, , (Where R, R 1 and R 2 are as defined above), (Where R, R 1 and R 2 are as defined above), Or -SO 3B (where B is a base), {Where R 5 is -H, C 1 -C 12 alkyl, hydroxyethyl, naphthyl, phenyl, substituted phenyl (where substituted is halogen, C 1 -C 5 alkyl, C 1 -C 5 alkoxy, nitro, cyan Selected from the group consisting of furnace and -CF 3 ).) (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 X는 1∼8이며, R, R1및 R2는 상기 정의와 같다), (Where X is 1 to 8, R, R 1 and R 2 are as defined above), (여기서 m은 2 또는 3이며 R, R1및 R2는 상기 정의와 같다), (Where m is 2 or 3 and R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), [여기서 X는 O,S,NH 및 NR11로 이루어지는 그루우프로부터 선택되며, Y는 수소, 또는 메틸이고, R10은 -H, C1-C18알킬, C3-C4알케닐, C3-C4알키닐, C2-C3할로알킬, C3-C8시클로알킬, C7-C20폴리시클로알킬, C2-C16폴리알콕시알킬, C2-C6하이드록시알킬, C3-C10알콕시알킬, C3-C8카로보알콕시알킬, C4-C8시클로알킬알킬, C6-C8시알킬시클로알킬, C4-C7시클로알킬아미노, C2-C10알킬아미노, C1-C3알킬아미노, C4-C12디알킬아미노알킬, C6-C10시클로알케닐, 페닐, 알킬페닐(여기서 알킬은 C1-C4이다), 파라클로로알킬페닐(여기서 알킬은 C1-C4이다), 나프틸, 안트라세닐, 벤즈아미도시클로알킬(여기서 알킬은 C1-C2이다), 피라닐메틸, 테트라하이드로푸르푸틸, 티오페네메틸, 벤즈하이드릴, 할로벤조하이드릴, 폴리시클릭알코올 및 치환페닐 {여기서 치환분은 C1-C4알킬, 할로겐, 니트로, 트리플루로로메틸, 포르밀, 클로로아세틸, C1-C4알콕시, 수소, 벤질, 클로로벤질, 페네틸 및 치환페네틸(여기서 치환분은 C1-C4알킬 및 할로겐으로 이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로부터 선택되며, R11은 C1-C4알킬, C3-C6알콕시알킬 및 C3-C4알케닐로 이루어지는 그루우프로부터 선택되고, R10 및 R11은 함께 아제피닐, 모르폴리닐, 피페르디닐, C1-C3알킬치환피페르디닐로 이루어지는 그루우프로부터 선택된 복소환 화합물을 형성하며 X가 0 또는 S일 경우에는 R10이 수소 및 치환페닐(여기서 치환분은 할로겐, C1-C4알콕시, 페녹시, 트리폴루오로메틸, C1-C6티오알킬, 니트로, 이소시아네이토, C2-C4폴리알콕시, C3-C7시클로알킬, C3-C10카르보알콕시알킬, C1-C4할로알킬, C3-C4알케닐, C2-C6디알킬아미노, 페닐아미노, C1-C4알킬, C3-C12하이드록시알킬아미도알킬, C5-C10N,N,-하이드록시알킬우레이도알킬, 알킬이 C1-C5인 이소시아네이토알킬, C3-C12알킬아미도알킬 폴리알콕시 부분은 3∼6개의 반복 C2-C3알콕시단위를 함유하고, 아미도 알킬부분은 4-12개의 탄소원자를 함유하는 폴리알콕시아미도알킬, -SO2Cl, 폴리알콕시일부분은 3∼6개의 반복 C2-C3알콕시단위를 함유하고 아미도알킬의 일부분은 4∼12개의 탄소원자를 함유하는 -SO2폴리알콕시아미도알킬로 이루어지는 그루우프로부터 선택된다)이다}로 이루어지는 그루우프로부터 선택되며, R5는 수소, C1-C4알킬, C3-C6알콕시알킬, C3-C4알케닐, 하이드록시에틸 및 페닐로 이루어지는 그루우프로부터 선택되며, R4및 R5는 함께 아제피닐, 모트폴리닐, 피페르디닐 및 C1-C3알킬 치환피페르디닐로 이루어지는 복소환식화합물을 형성한다.] [Where X is selected from a group consisting of O,S,NH and NR 1 1, Y is hydrogen or methyl, R 1 0 is -H, C 1 -C 18 alkyl, C 3 -C 4 alkenyl , C 3 -C 4 alkynyl, C 2 -C 3 haloalkyl, C 3 -C 8 cycloalkyl, C 7 -C 20 polycycloalkyl, C 2 -C 16 polyalkoxyalkyl, C 2 -C 6 hydroxy Alkyl, C 3 -C 10 alkoxyalkyl, C 3 -C 8 carboalkoxyalkyl, C 4 -C 8 cycloalkylalkyl, C 6 -C 8 cycloalkylcycloalkyl, C 4 -C 7 cycloalkylamino, C 2 -C 10 alkylamino, C 1 -C 3 alkylamino, C 4 -C 12 dialkylaminoalkyl, C 6 -C 10 cycloalkenyl, phenyl, alkylphenyl (where alkyl is C 1 -C 4 ), para Chloroalkylphenyl (where alkyl is C 1 -C 4 ), naphthyl, anthracenyl, benzamidocycloalkyl (where alkyl is C 1 -C 2 ), pyranylmethyl, tetrahydrofurfurtyl, thiophene Methyl, benzhydryl, halobenzohydryl, polycyclic alcohol and substituted phenyl {where substituted is C 1 -C 4 alkyl, halogen, nitro, trifluoromethyl, formyl, chloroacetyl, C 1 -C 4 alkoxy , Hydrogen, benzyl, chlorobenzyl, phenethyl and substituted phenethyl (where the substituted is selected from a group consisting of C 1 -C 4 alkyl and halogen), R 1 1 is C 1- Selected from a group consisting of C 4 alkyl, C 3 -C 6 alkoxyalkyl and C 3 -C 4 alkenyl, R 1 0 and R 1 1 together are azepine, morpholinyl, piperidinyl, C 1 -C 3 It forms a heterocyclic compound selected from the group consisting of alkyl-substituted piperidinyl, and when X is 0 or S, R 1 0 is hydrogen and substituted phenyl (where substituted is halogen, C 1 -C 4 alkoxy, Phenoxy, tripoluromethyl, C 1 -C 6 thioalkyl, nitro, isocyanato, C 2 -C 4 polyalkoxy, C 3 -C 7 cycloalkyl, C 3 -C 10 carboalkoxyalkyl, C 1 -C 4 haloalkyl, C 3 -C 4 alkenyl, C 2 -C 6 dialkylamino, phenylamino, C 1 -C 4 alkyl, C 3 -C 12 hydroxy Hydroxyalkylamidoalkyl, C 5 -C 10 N,N,-hydroxyalkylureidoalkyl, isocyanatoalkyl where alkyl is C 1 -C 5 , C 3 -C 12 alkylamidoalkyl polyalkoxy moieties Polyalkoxyamidoalkyl containing 3 to 6 repeating C 2 -C 3 alkoxy units, the amido alkyl moiety containing 4 to 12 carbon atoms, -SO 2 Cl, and the polyalkoxy moiety having 3 to 6 repeating C 2 -C 3 alkoxy unit and a part of the amidoalkyl is selected from a group consisting of -SO 2 polyalkoxyamidoalkyl containing 4 to 12 carbon atoms)), R 5 is selected from a group consisting of hydrogen, C 1 -C 4 alkyl, C 3 -C 6 alkoxyalkyl, C 3 -C 4 alkenyl, hydroxyethyl and phenyl, R 4 and R 5 together azepinyl , To form a heterocyclic compound consisting of morpholinyl, piperidinyl and C 1 -C 3 alkyl substituted piperidinyl.] {여기서 X는 0 또는 S이며, n은 0 또는 1이고, R6은 C1-C12알킬, C2-C6할로알킬, 페닐 및 치환페닐(여기서 n은 1이며, 치환분은 니트로, 클로로, C1-C2알킬, C4-C6폴리알콕시알킬, C3-C8시클로알킬, C3-C4알케닐, C3-C6알콕시알킬, C2-C6하이드록시알킬, C1-C3카르복시알킬 및 C5-C8트리알킬암모늄염으로 이루어지는 그루우프로부터 선택되며, n=0일 경우에는 치환분은 클로로, 티오포타슘, C1-C12알킬, 벤질, C1-C4클로로 카르복시알킬, C4-C6폴리알콕시알킬 및 아세틸로 이루어진 그루우프로부터 선택된다)로 이루어진 그루우프로부터 선택된다},{여기서 n은 0∼8이다), -CH=CH-(여기서 M은 H 또는 Cl 이다)-CCl=CCl-, -CH2OCH2-, 및 -OCH2CH2O-로 이루어지는 그루우프로부터 선택되고, d는 0 또는 1 이며, d=1일 경우에는 Y는 -0, -S 및 -NH로 이루어지는 그루우프로부터 선택되며, Z는 C1-C18알킬, 수소, C4-C16 폴리알콕시알킬, C4-C8디알킬아미노알킬, C3-C5알키닐, 페닐, 치환페닐, 유기염, 무기염으로 이루어지는 그루우프로부터 선택되며, d=0 이고 Z가 Cl 또는(여기서 R, R1및 R2의 정의는 상기한 바와 같다)로 이루어지는 그루우프로부터 선택된다},(여기서 R8은 C1-C5알콕시, 아미노, C1-C5알콕시아미노, 하이드록시 및 유기염기로 이루어지는 그루우프로부터 선택된다), -SOWR9{여기서 w=0∼2이며, R9은 아미노, C1-C5알킬, C1-C4할로알킬, 페닐, C1-C10 디알킬아미노, C1-C10 알킬아미노, C1-C5알콕시, 치환페닐(여기서 치환분은 니트로, 클로로, C1-C4알킬 및 메록시로 이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로부터 선택된다}로 이루어지는 특허청구의 범위 19,20,21 기재의 인사류 해충 억제방법. {Where X is 0 or S, n is 0 or 1, R 6 is C 1 -C 12 alkyl, C 2 -C 6 haloalkyl, phenyl and substituted phenyl (where n is 1, substituted is nitro, Chloro, C 1 -C 2 alkyl, C 4 -C 6 polyalkoxyalkyl, C 3 -C 8 cycloalkyl, C 3 -C 4 alkenyl, C 3 -C 6 alkoxyalkyl, C 2 -C 6 hydroxyalkyl , C 1 -C 3 carboxyalkyl, and C 5 -C 8 tree is selected from the loop consisting of alkyl ammonium salts, n = 0, is replaced minutes, chloro, potassium thio, C 1 -C 12 alkyl, benzyl, C 1 -C 4 chloro carboxyalkyl, C 4 -C 6 polyalkoxyalkyl and acetyl group)), (Where n is 0 to 8), -CH=CH- (Where M is H or Cl) It is selected from a group consisting of -CCl=CCl-, -CH 2 OCH 2 -, and -OCH 2 CH 2 O-, d is 0 or 1, and when d=1, Y is -0, -S and Is selected from a group consisting of -NH, Z is C 1 -C 18 alkyl, hydrogen, C 4 -C 1 6 polyalkoxyalkyl, C 4 -C 8 dialkylaminoalkyl, C 3 -C 5 alkynyl, phenyl , Substituted phenyl, an organic salt, a group consisting of an inorganic salt, d=0 and Z is Cl or (The definitions of R, R 1 and R 2 are as described above) are selected from the group consisting of}, (Where R 8 is selected from a group consisting of C 1 -C 5 alkoxy, amino, C 1 -C 5 alkoxyamino, hydroxy and organic bases), -SOWR 9 {where w=0-2, R 9 Silver amino, C 1 -C 5 alkyl, C 1 -C 4 haloalkyl, phenyl, C 1 -C 1 0 dialkylamino, C 1 -C 1 0 alkylamino, C 1 -C 5 alkoxy, substituted phenyl (where Method for inhibiting human insect pests as described in claims 19,20,21, wherein the substituted component is selected from a group consisting of nitro, chloro, C 1 -C 4 alkyl and methoxy). . R3은 카르보알콕시알킬, 여기서 알킬은 C1-C2알킬이다), 알킬케로알킬(여기서 알킬은 C1-C2알킬이다), 하이드록시알케닐(여기서 알케닐은 C3-C4알킬이다), 하이드록시알킬(여기서 알킬은 C1-C3알킬이다), 포르밀 하이드록시메틸, 하이드록시 할로에틸(여기서 할로는 클로로이다), 치환페녹시알킬(여기서 알킬은 C1알킬이며, 치환분은 P-메톡시, Cl, NO3또는 CN이다),R 3 is carboalkoxyalkyl, where alkyl is C 1 -C 2 alkyl), alkylkeroalkyl (where alkyl is C 1 -C 2 alkyl), hydroxyalkenyl (where alkenyl is C 3 -C 4 Alkyl), hydroxyalkyl (where alkyl is C 1 -C 3 alkyl), formyl hydroxymethyl, hydroxy haloethyl (where halo is chloro), substituted phenoxyalkyl (where alkyl is C 1 alkyl , The substituted component is P-methoxy, Cl, NO 3 or CN), {여기서 R1은 -OH, -NH2또는 메톡시,, (여기서 R,R1및 R2는 위에서 정의한 바와 같다)},(여기서 R,R1및 R2는 위에서 정의한 바와 같다)},(여기서 B 는이루어지는 그루우프로부터 선택되는 염기이다),{여기서 R4는 -H, C1-C8알킬, 하이드록시에틸, 나프틸, 페닐, 치환페닐(여기서 치환분은 클로라인, C1-C2알킬, C1-C2알콕시, 니트로, 시아노 및 -CF3로 이루어지는 그루우프로부터 독자적으로 선택된다)로 이루어지는 그루우프로부터 선택된다}. {Where R 1 is -OH, -NH 2 or methoxy, , (Where R, R 1 and R 2 are as defined above)}, (Where R, R 1 and R 2 are as defined above)}, (Where B is Is a base selected from the group consisting of) {Where R 4 is -H, C 1 -C 8 alkyl, hydroxyethyl, naphthyl, phenyl, substituted phenyl (where substituted is chlorine, C 1 -C 2 alkyl, C 1 -C 2 alkoxy, nitro, Selected from a group consisting of cyano and -CF 3 ). (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다), (Where R, R 1 and R 2 are as defined above), (여기서 X는 1∼8이며, R, R1및 R2는 상기 정의와 같다),(Where X is 1 to 8, R, R 1 and R 2 are as defined above), (여기서 m은 2 또는 3이며, R, R1및 R2는 상기 정의와 같다),(Where m is 2 or 3, R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다),(Where R, R 1 and R 2 are as defined above), (여기서 R, R1및 R2는 상기 정의와 같다),[여기서 X는 0,S,NH 및 NR11로 이루어지는 그루우프로부터 선택되며, Y는 수소, 또는 메틸이고, R10은 -H, C1-C2알킬, C3-C4알케닐, C3-C4알키닐, C2-C3할로알킬, C3-C8시클로알킬, C7-C20폴리시클로알킬, C2-C16폴리알콕시알킬, C2-C6하이드록시알킬, C3-C10알콕시알킬, C3-C8카르보알콕시알킬, C4-C8시클로알킬알킬, C6-C8알킬시클로알킬, C4-C7시클로알킬아미노, C2-C10알킬아미노, C1-C3알킬아미노, C4-C12디알킬아미노알킬, C6-C10시클로알케닐, 페닐, 알킬페닐(여기서 알킬은 C1-C4이다), 파라클로로알킬페닐(여기서 알킬은 C1-C4이다), 나프틸, 안트라세닐, 벤즈아미도시클로알킬(여기서 알킬은 C1-C2이다), 피라닐메틸, 테트라하이드로푸르푸릴, 티오페네메틸, 벤즈하이드릴, 할로벤즈하이드릴, 폴리시클릭알코올 및 치환페닐 {여기서 치환분은 C1-C4알킬, 할로겐, 니트로, 트리플루오로메틸, 포르밀, 클로로아세틸, C1-C4알콕시, 수소, 벤질, 클로로벤질, 페네틸 및 치환페네틸(여기서 치환분은 C1-C4알킬 및 할로겐으로 이루어지는 그루우프로부터 선택된다)로 이루어지는 그루우프로부터 선택되며, R11은 C1-C4알킬, C3-C6알콕시알킬 및 C3-C4알케닐로 이루어지는 그루우프로부터 선택되고 R10 및 R11은 함께 복소환 화합물, 바람직하게는 아제피닐, 모르폴리닐, 피페르디닐, C1-C3알킬치환피페르디닐로로 이루어지는 복소환 화합물을 형성하며 X가 0 또는 S일 경우에는 R10이 수소 및 치환메닐(여기서 치환분은 할로겐, C1-C4알콕시, 페녹시, 트리플루오로메틸, C1-C6티오알킬, 니트로, 이소시아네이로, C2-C4폴리알콕시, C3-C7시클로알킬, C3-C10카르보알콕시알킬, C1-C4할로알킬, C3-C4알케닐, C2-C6디알킬아미노, 페닐아미노, C1-C4알킬, C3-C12하이드록시 알킬아미도알킬, C5-C10N,N,-하이드록시알킬우레이도알킬, 알킬이 C1-C5인 이소시아네이로 알킬, C3-C12알킬아미도알킬, 폴리알콕시 부분은 3∼6개의 반복 C2-C3알콕시단위를 함유하고, 아미도 알킬부분은 4-12개의 탄소원자를 함유하는 폴리알콕시아미도알킬, -SO2Cl, 폴리알콕시일부분은 3∼6개의 반복 C2-C3알콕시단위를 함유하고 아미도알킬의 부분은 4∼12개의 탄소원자를 함유하는 -SO2폴리알콕시아미도알킬로 이루어지는 그루우프로부터 선택된다)이다}로 이루어지는 그루우프로부터 선택되며, R5는 수소, C1-C4알킬, C3-C6알콕시알킬, C3-C4알케닐, 하이드록시에틸 및 페닐로 이루어지는 그루우프로부터 선택되며, R4및 R5는 함께 아제피닐, 모르폴리닐, 피페르디닐 및 C1-C3알킬치환피페르디닐로 이루어지는 복소환식화합물을 형성한다.]{여기서 X는 0 또는 S이며, n은 0 또는 1이고, R6은 C1-C4알킬, C2-C6할로알킬, 페닐 및 치환페닐(여기서 n은 1이며, 치환분은 니트로, 클로로, C1-C2알킬, C4-C6폴리알콕시알킬, C3-C8시클로알킬, C3-C4알케닐, C3-C6알콕시알킬, C2-C6하이드록시알킬, C1-C3카르톡시알킬 및 C5-C8트리알킬알모늄 알킬염으로 이루어지는 그루우프로부터 선택되며, n=0일 경우에는 치환분은 클로로, 티오포타슘, C1-C4알킬, 벤질, C1-C2헤테로알킬, C2-C4클로로카르복시알킬, C4-C6폴리알콕시알킬 및 아세틸로 이루어진 그루우프로부터 선택된다)로 이루어진 그루우프로부터 선택된다},{여기서 R7은 -(CH2 -)n (여기서 n은 0∼8이다), -CH=CH-(여기서 M은 H 또는 Cl이다)-CCl=CCl-, -CH2OCl2-, 및 -OCH2CH2O-로 이루어지는 그루우프로부터 선택되고, d는 0 또는 1이며, d=1일 경우에는 Y는 -0, -S 및 -NH로 이루어지는 그루우프로부터 선택되며, Z는 C1-C4알킬, 수소, C4-C16 폴리알콕시알킬, C4-C8디알킬아미노알킬, C3-C5알키닐, 페닐, 치환페닐, 유기염, 무기염으로 이루어지는 그루우프로부터 선택되며, d=0 이고 Z가 Cl 또는(여기서 R,R1및 R2의 정의는 상기한 바와 같다)로 이루어지는 그루우프로부터 선택된다},(여기서 R8은 C1-C5알콕시, 아미노, C1-C5알콕시아미노, 하이드록시 및 유기염기로 이루어지는 그루우프로부터 선택된다), -SOWR9{여기서 W=0∼2이며, R9은 아미노, C1-C5알킬, C1-C4할로알킬, 페닐, C1-C10 디알킬아미노, C1-C10 알킬아미노, C1-C5알콕시, 치환페닐(여기서 치환분은 니트로, 클로로, C1-C4알킬 및 메톡시로 이루어지는 그루우프로부터 선택된다.)로 이루어지는 그루우프로부터 선택된다}로 이루어진 그루우프로부터 선택되는 특허청구의 범위 19, 20 및 21기재의 인사류 해충억제방법.(Where R, R 1 and R 2 are as defined above), [Where X is selected from a group consisting of 0,S,NH and NR 1 1, Y is hydrogen or methyl, R 1 0 is -H, C 1 -C 2 alkyl, C 3 -C 4 alkenyl , C 3 -C 4 alkynyl, C 2 -C 3 haloalkyl, C 3 -C 8 cycloalkyl, C 7 -C 20 polycycloalkyl, C 2 -C 16 polyalkoxyalkyl, C 2 -C 6 hydroxy Alkyl, C 3 -C 10 alkoxyalkyl, C 3 -C 8 carboalkoxyalkyl, C 4 -C 8 cycloalkylalkyl, C 6 -C 8 alkylcycloalkyl, C 4 -C 7 cycloalkylamino, C 2- C 10 alkylamino, C 1 -C 3 alkylamino, C 4 -C 12 dialkylaminoalkyl, C 6 -C 10 cycloalkenyl, phenyl, alkylphenyl (where alkyl is C 1 -C 4 ), parachloro Alkylphenyl (where alkyl is C 1 -C 4 ), naphthyl, anthracenyl, benzamidocycloalkyl (where alkyl is C 1 -C 2 ), pyranylmethyl, tetrahydrofurfuryl, thiophenemethyl , Benzhydryl, halobenzhydryl, polycyclic alcohol and substituted phenyl {where substituted is C 1 -C 4 alkyl, halogen, nitro, trifluoromethyl, formyl, chloroacetyl, C 1 -C 4 alkoxy, Selected from a group consisting of hydrogen, benzyl, chlorobenzyl, phenethyl and substituted phenethyl (where the substitution is selected from a group consisting of C 1 -C 4 alkyl and halogen), R 1 1 is C 1 -C 4 alkyl, C 3 -C 6 alkoxyalkyl and C 3 -C 4 alkenyl, and R 1 0 and R 1 1 together are a heterocyclic compound, preferably azepinyl, morpholinyl, pi Ferdinyl, C 1 -C 3 Alkyl-substituted form a heterocyclic compound consisting of piperidin, and when X is 0 or S, R 1 0 is hydrogen and substituted menyl (where substituted is halogen, C 1 -C 4 Alkoxy, phenoxy, trifluoromethyl, C 1 -C 6 thioalkyl, nitro, isocyanaro, C 2 -C 4 polyalkoxy, C 3 -C 7 cycloalkyl, C 3 -C 10 carboalkoxyalkyl, C 1 -C 4 haloalkyl, C 3 -C 4 alkenyl, C 2 -C 6 dialkylamino, phenylamino, C 1 -C 4 alkyl, C 3 -C 12 Hydroxy alkylamidoalkyl, C 5 -C 10 N,N,-hydroxyalkylureidoalkyl, isocyanaro alkyl where alkyl is C 1 -C 5 , C 3 -C 12 alkylamidoalkyl, polyalkoxy The part contains 3 to 6 repeating C 2 -C 3 alkoxy units, the amido alkyl part contains 4-12 carbon atoms, polyalkoxyamidoalkyl, -SO 2 Cl, and the polyalkoxy part contains 3 to 6 Repeat C 2 -C 3 alkoxy units, and the portion of the amidoalkyl is selected from a group consisting of -SO 2 polyalkoxyamidoalkyl containing 4 to 12 carbon atoms)) , R 5 is selected from a group consisting of hydrogen, C 1 -C 4 alkyl, C 3 -C 6 alkoxyalkyl, C 3 -C 4 alkenyl, hydroxyethyl and phenyl, R 4 and R 5 together Forms a heterocyclic compound consisting of gepinyl, morpholinyl, piperidinyl and C 1 -C 3 alkyl substituted piperidinyl.] {Where X is 0 or S, n is 0 or 1, R 6 is C 1 -C 4 alkyl, C 2 -C 6 haloalkyl, phenyl and substituted phenyl (where n is 1, substituted is nitro, Chloro, C 1 -C 2 alkyl, C 4 -C 6 polyalkoxyalkyl, C 3 -C 8 cycloalkyl, C 3 -C 4 alkenyl, C 3 -C 6 alkoxyalkyl, C 2 -C 6 hydroxyalkyl , C 1 -C 3 Cartoxyalkyl and C 5 -C 8 trialkylalmonium alkyl salts are selected from a group consisting of a salt, and when n=0, the substituted component is chloro, thiopotassium, C 1 -C 4 alkyl, Selected from a group consisting of benzyl, C 1 -C 2 heteroalkyl, C 2 -C 4 chlorocarboxyalkyl, C 4 -C 6 polyalkoxyalkyl and acetyl)), {Wherein R 7 is - (CH 2 -) n (where n is 0~8), -CH = CH- (Where M is H or Cl) It is selected from a group consisting of -CCl=CCl-, -CH 2 OCl2-, and -OCH 2 CH 2 O-, d is 0 or 1, and when d=1, Y is -0, -S and- Selected from group consisting of NH, Z is C 1 -C 4 alkyl, hydrogen, C 4 -C 1 6 polyalkoxyalkyl, C 4 -C 8 dialkylaminoalkyl, C 3 -C 5 alkynyl, phenyl, Selected from a group consisting of substituted phenyl, organic salt, and inorganic salt, d=0 and Z is Cl or (The definitions of R, R 1 and R 2 are as described above) are selected from the group consisting of}, (Where R 8 is selected from a group consisting of C 1 -C 5 alkoxy, amino, C 1 -C 5 alkoxyamino, hydroxy and organic bases), -SOWR 9 {where W=0 to 2, R 9 Silver amino, C 1 -C 5 alkyl, C 1 -C 4 haloalkyl, phenyl, C 1 -C 1 0 dialkylamino, C 1 -C 1 0 alkylamino, C 1 -C 5 alkoxy, substituted phenyl (where Substituents are selected from a group consisting of nitro, chloro, C 1 -C 4 alkyl, and methoxy.) A group selected from a group consisting of}), claims 19, 20 and 21. Human pest control method. R은 -secC7H15이며, R1은 -C8H17이고, R2는 -CH3이며, R3는로 이루어진 특허청구의 범위 19기재의 인사류해충 억제방법.R is -secC 7 H 15 , R 1 is -C 8 H 17 , R 2 is -CH3, R 3 is The scope of claims for patents consisting of 19 methods for suppressing human pests. R은 -secC7H15이며, R1은 -C8H17이고, R2는 -CH3이며, R3는로 이루어진 특허청구의 범위 19기재의 인사류해충 억제방법.R is -secC 7 H 15 , R 1 is -C 8 H 17 , R 2 is -CH3, R 3 is The scope of claims for patents consisting of 19 methods for suppressing human pests. R은 -secC7H15이며, R1은 -C8H17이고, R2는 -C2H5이며, R3는로 이루어진 특허청구의 범위 19기재의 인사류해충 억제방법.R is -secC 7 H 15 , R 1 is -C 8 H 17 , R 2 is -C 2 H 5 , R 3 is The scope of claims for patents consisting of 19 methods for suppressing human pests. R은 -secC7H15이며, R1은 -C8H17이고, R2는 -C2H5이며, R3는로 이루어진 특허청구의 범위 19기재의 인사류해충 억제방법.R is -secC 7 H 15 , R 1 is -C 8 H 17 , R 2 is -C 2 H 5 , R 3 is The scope of claims for patents consisting of 19 methods for suppressing human pests. R, R1, R2및 R3그루우프는 인사류해충의 사료 또는 서식처에 0.05중량%의 하기 살충제조성물용액을 접촉하였을 때에 실질적으로 비식물동성이며 인사류 해충에 대하여 LD50의 효과를 나타낼 수 있도록 선택되는 특허청구의 범위 1기재의 이소티오요소 인사류 살충제 조성물.The R, R 1 , R 2 and R 3 grooves are substantially non-physical and exhibit the effect of LD 50 on human pests when 0.05% by weight of the following pesticidal composition solution is contacted with the feed or habitat of the human pest. The isothiourea human resources insecticide composition of claim 1, which is selected so as to be possible. R, R1, R2및 R3그루우프는 인사류해충의 사료 또는 서식처에 0.05중량%의 하기 살충제조성물용액을 접촉하였을 때에 실질적으로 비식물동성이며 인사류 해충에 대하여 LD50의 효과를 나타낼 수 있도록 선택되는 특허청구의 범위 10기재의 이소티오요소 인사류 살충제 조성물.The R, R 1 , R 2 and R 3 grooves are substantially non-physical and exhibit the effect of LD 50 on human pests when 0.05% by weight of the following pesticidal composition solution is contacted with the feed or habitat of the human pest. The isothiourea personnel insecticide composition of 10 bases of the claims selected to be able to. R, R1, R2및 R3그루우프는 인사류해충의 사료 또는 서식처에 0.05중량%의 하기 살충제조성물용액을 접촉하였을 때에 실질적으로 비식물동성이며 인사류 해충에 대하여 LD50의 효과를 나타낼 수 있도록 선택되는 특허청구의 범위 19기재의 인사류 해충억제방법.The R, R 1 , R 2 and R 3 grooves are substantially non-physical and exhibit the effect of LD 50 on human pests when 0.05% by weight of the following pesticidal composition solution is contacted with the feed or habitat of the human pest. Scope of patent claims selected to enable human resources pest control method described in 19. 하기 구조식으로 이루어지는 이소티오요소 인사류 살충제 조성물Isothiourea personnel insecticide composition consisting of the following structural formula 식중, R 및 R1은 C1-C10 알킬, C2-C10알콕시알킬 및 페닐로 이루어지는 그루우프로부터 독자적으로 선택되며, R 및 R1은 함께 탄소원자 12∼22개를 함유하고, R2는 C1-C14알킬, C3-C10알케닐, C3-C4알케닐, C2-C4하이드록시알킬, C2-C6알킬티오알킬, C2-C6알킬옥시알킬, (CH2)n-[X(CH2)n]Y {여기서 n은 1 또는 2이며, X는 0 또는 S이고, Y는 1∼4이며,(여기서 n은 1∼10, 페닐 및 페네틸이다)}로 이루어지는 그루우프로부터 선택되며, R3은 유기 그루우프 또는 인 및 산소 또는 황 및 산소를 함유하는 그루우프이며, R, R1, R2및 R3그루우프는, 인사류 해충의 사료 또는 서식처에 0.05중량%의 하기 살충제조성물 용액을 접촉하였을 때에 실질적으로 비식물독성이며 인사류 해충에 대하여 LD50의 효과를 나타낼 수 있도록, 선택되는 이소티오요소인사류 살충제 조성물.Wherein R and R 1 are independently selected from a group consisting of C 1 -C 1 0 alkyl, C 2 -C 10 alkoxyalkyl and phenyl, and R and R 1 together contain 12 to 22 carbon atoms, R 2 is C 1 -C 14 alkyl, C 3 -C 10 alkenyl, C 3 -C 4 alkenyl, C 2 -C 4 hydroxyalkyl, C 2 -C 6 alkylthioalkyl, C 2 -C 6 alkyl Oxyalkyl, (CH 2 ) n -[X(CH 2 ) n ]Y {where n is 1 or 2, X is 0 or S, Y is 1-4, (Where n is 1 to 10, phenyl and phenethyl)}, and R 3 is an organic group or a group containing phosphorus and oxygen or sulfur and oxygen, and R, R 1 and R 2 and R 3 grooves are selected to be substantially non-phytotoxic and exhibit the effect of LD 50 on human pests when contacted with a 0.05 wt% solution of the following pesticidal composition to the feed or habitat of the human pest. Isothiourea phosphorous insecticide composition. 특허청구의 범위 31기재의 화합물과 부동담체로 이루어지느 이소티오요소 인사류 살충제 조성물.Isothiourea human resources insecticide composition consisting of a compound and an immobilized carrier of 31 bases. 특허청구의 범위 31기재의 인사류 살충제의 유효량을 인사류 해충자체, 또는 그 서식처 또는 그 사료에 적용함으로써 이루어지는 인사류 해충억제방법.Scope of Claims A method for controlling human pests by applying an effective amount of human pesticide described in 31 to human pests or their habitat or feed. 하기 구조식의 인사류 살충화합물의 유효량을 인사류 해충자체 또는 그 서식처 또는 그 사료에 대하여 적용함으로써 이루어지는 인사류 해충억제방법.A method for controlling pests of human resources, which is achieved by applying an effective amount of the human compound of the following structural formula to human pests or their habitats or feed. 식중, R, R1및 R2는 동일하든지 또는 다른 유기 그루우프이며, R 및 R1은 함께 탄소원자 12∼22개를 함유하고, R3은 유기그루우프 또는 인 및 산소 또는 황 및 산소를 함유하는 그루우프이며, R, R1, R2및 R3그루우프는, 인사류해충의 사료 또는 서식체에 0.05중량%의 하기 살충제조성물 용액을 접촉하였을 때에 실질적으로 인사류 해충에 대하여 LD50의 효과를 나타낼 수 있도록, 선택된다.Wherein R, R 1 and R 2 are the same or different organic groups, R and R 1 together contain 12 to 22 carbon atoms, and R 3 is an organic group or phosphorus and oxygen or sulfur and oxygen. It is a containing group, and R, R 1 , R 2 and R 3 group are substantially LD 50 against human pests when the 0.05 wt% of the following pesticidal composition solution is contacted with the feed or inhabitant of the human pest. It is selected, so that it can exhibit the effect of. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: Disclosure is based on the original application.
KR1019800001130A 1979-03-19 1980-03-18 Isothiourea human resources insecticide composition KR830001611A (en)

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