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KR830009798A - Sulfur recovery - Google Patents

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KR830009798A
KR830009798A KR1019820002267A KR820002267A KR830009798A KR 830009798 A KR830009798 A KR 830009798A KR 1019820002267 A KR1019820002267 A KR 1019820002267A KR 820002267 A KR820002267 A KR 820002267A KR 830009798 A KR830009798 A KR 830009798A
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sulfur
polyvalent metal
mixture
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KR900000187B1 (en
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콘스탄틴 블라이터스 죠오지
다이어즈 제이더
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안토니우스 토니스 푸이슈텔
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493Selection of liquid materials for use as absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1418Recovery of products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425Regeneration of liquid absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1462Removing mixtures of hydrogen sulfide and carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/02Preparation of sulfur; Purification
    • C01B17/04Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/05Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/151Reduction of greenhouse gas [GHG] emissions, e.g. CO2

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Industrial Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음No content

Description

황 회수법Sulfur recovery

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (23)

(가) 한 가지 이상의 다가 금속이온 및 한 가지 이상의 다가 금속 킬레이트 화합물로된 반응물 유효량과 1분자당 4-12개의 탄소원자를 가진 한 가지 이상의 알칸디올로된 반응속도 개질제 유효량을 함유한 반응용액과 산성의 가스 유동물을 황의 용융점 이하의 온도에서 접촉대에서 접촉시키고,(A) a reaction solution containing an effective amount of a reactant consisting of one or more polyvalent metal ions and one or more polyvalent metal chelate compounds, and an effective amount of a reaction rate modifier consisting of one or more alkanediols having 4-12 carbon atoms per molecule; Contact the gas stream at the contact zone at temperatures below the melting point of sulfur, (나) 결정질 황, 환원된 반응물 및 반응속도 개질제를 함유한 혼합물로부터 정제된 가스유동물을 분리하는 단계로 된 산성의 가스유동물로부터 H2S를 제거하는 방법.(B) separating H 2 S from acidic gaseous animals comprising separating purified gaseous animals from mixtures containing crystalline sulfur, reduced reactants and rate modifiers. 청구범위 제1항에 있어서, 1분자당 4-8개의 탄소원자를 가진 한 가지 이상의 알칸디올을 (가) 단계의 반응속도 개질제에 첨가하는 방법.The process of claim 1, wherein at least one alkanediol having 4-8 carbon atoms per molecule is added to the rate modifying agent of step (a). 청구범위 제2항에 있어서 (가) 단계의 반응속도 개질제에 2,3-부탄디올을 첨가하는 방법.The process of claim 2 wherein 2,3-butanediol is added to the reaction rate modifier of step (a). 청구범위 제2항에 있어서 (가) 단계의 반응속도 개질제에 1,4-부탄디올을 첨가하는 방법.The process of claim 2 wherein 1,4-butanediol is added to the reaction rate modifier of step (a). 청구범위 제1항-제4항 중 어느 한 가지에 있어서 (가) 단계에서 반응용 용액 중량에 대하여 반응속도 개질제를 0.1-10wt.%의 량으로 첨가하는 방법.The process according to any one of claims 1 to 4, wherein the reaction rate modifier is added in an amount of 0.1-10 wt.% Based on the weight of the reaction solution in step (a). 청구범위 제1항-제5항 중 어느 한 가지에 있어서 결정질황 중의 최소한 일부를 분리하는 방법.The method of any one of claims 1-5, wherein at least some of the crystalline sulfur is separated. 청구범위 제6항에 있어서 황을 분리한 후에 잔존하거나 (나) 단계에서 분리된 혼합물 중에 존재하는 환원된 반응물을 재생대에서 함산소 가스와 접촉시켜 재생된 반응물을 함유한 혼합물을 제조하는 방법.A process according to claim 6 for producing a mixture containing the regenerated reactant by contacting a reduced reactant remaining after separation of sulfur or present in the mixture separated in step (b) with an oxygenous gas in the regeneration zone. 청구범위 제7항에 있어서 황을 분리한 후 재생된 반응물을 함유한 혼합물을 (가) 단계의 접촉대로 순환시키는 방법.The process of claim 7 wherein after separating the sulfur the mixture containing the regenerated reactant is circulated to the contact of step (a). 청구범위 제1항-제8항 중 어느 한 가지에 있어서 (가) 단계에서 수용액을 반응물 용액으로 하여 첨가하는 방법.The method according to any one of claims 1 to 8, wherein the aqueous solution is added as reactant solution in step (a). 청구범위 제1항-제8항 중 어느 한 가지에 있어서 산성의 가스 유동물 중에 CO2를 함유시켜며 CO2선택선 흡수제를 (가) 단계의 반응물 용액에 첨가하여 (나) 단계에서 분리된 혼합물 중에 흡수된 CO2가 함유되도록 하는 방법.The process according to any one of claims 1 to 8, comprising CO 2 in an acidic gas stream, wherein the CO 2 selector absorber is added to the reactant solution in step (a) and separated in step (b). A method for containing absorbed CO 2 in a mixture. 청구범위 제10항에 있어서 CO2선택성 흡수제로서 H2O에 대한 선택성을 가진 것을 이용하는 방법.The method of claim 10, wherein the CO 2 selective absorbent has a selectivity to H 2 O. 청구범위 제10항 또는 제11항에 있어서 (나) 단계에서 분리된 것으로서 황과 환원된 반응물을 함유한 혼합물로부터 CO2를 분리시키는 방법.Process according to claim 10 or 11 for separating CO 2 from a mixture containing sulfur and a reduced reactant as separated in step (b). 청구범위 제10항 또는 제11항에 있어서 황을 분리한 후 잔존하는 혼합물로부터 CO2를 분리하고 결정질 황중 최소한 일부를 분리하는 방법.12. The process of claim 10 or 11, wherein after separating the sulfur, CO 2 is separated from the remaining mixture and at least some of the crystalline sulfur is separated. 청구범위 제1항-제13항 중 어느 한 가지에 있어서 산성의 가스 혼합물로서 석탄 가스화시에 유도된 탄화수소 혼합물을 이용하는 방법.Process according to any one of claims 1 to 13, using a hydrocarbon mixture derived upon coal gasification as an acidic gas mixture. 청구범위 제1항-제14항 중 어느 한 가지에 있어서 반응물로서는 다음과 같은 일반 구조식(1)을 가진 산과 다가 금속과의 배위 화합물 또는 일반 구조식(2)를 가진 것과 다가 금속과의 배위 화합물 또는 이들 산의 혼합물과 다가 금속과의 배위 화합물을 이용하는 방법.The reactant according to any one of claims 1 to 14, wherein the reactant is a coordination compound of an acid and a polyvalent metal having the general formula (1) as follows, or a coordination compound of a polyvalent metal and a compound having the general formula (2), or Using a coordination compound of a mixture of these acids and a polyvalent metal. (X)3-n-N-(Y)n (1)(X) 3-n -N- (Y) n (1) 위의 식에서 n은 1-3까지의 정수, Y는 카르복시메틸기, 또는 2-카르복시에틸기이고 X는 2-히드록시에틸기 또는 2-히드록시프로필기 또는 1-4개의 탄소원자를 가진 알킬기임.Wherein n is an integer of 1-3, Y is a carboxymethyl group, or 2-carboxyethyl group and X is a 2-hydroxyethyl group or 2-hydroxypropyl group or an alkyl group having 1-4 carbon atoms. (2) (2) 위의 식에서In the above expression -Y중 2-4개는 카르복시메틸기 또는 2-카르복시에틸기이고2-4 of -Y are carboxymethyl group or 2-carboxyethyl group -Y중 0-2개는 2-히드록시에틸기 또는 2-히드록시프로필기이거나 다음과 같은 일반 구조식을 가진 기임.-0-2 of Y are 2-hydroxyethyl group or 2-hydroxypropyl group, or a group having the following general structural formula. 이 식에서 Y는 카르복시메틸기, 2-카르복시에틸기, 2-히드록시에틸기 또는 2-히드록시프로필기.In this formula, Y is a carboxymethyl group, 2-carboxyethyl group, 2-hydroxyethyl group, or 2-hydroxypropyl group. -R은 에틸렌기, 트리메틸렌기, 1-메틸에틸렌기, 1,2-시클로헥실렌기 또는 1,2-벤질렌기.-R is an ethylene group, trimethylene group, 1-methylethylene group, 1,2-cyclohexylene group or 1,2-benzylene group. 청구범위 제15항에 있어서 에틸렌디아민으로부터 유도된 아미노아세트산과 다가 금속과의 배위 착물을 반응물로 이용하는 방법.16. The process of claim 15, wherein the coordination complex of aminoacetic acid and polyvalent metal derived from ethylenediamine is used as reactant. 청구범위 제15항에 있어서 암모니아로부터 유도된 아미노아세트산과 다가금속과의 배위착물을 반응물로 이용하는 방법.The method according to claim 15, wherein the coordination complex of aminoacetic acid and polyvalent metal derived from ammonia is used as a reactant. 청구범위 제1항-제17항 중 어느 한 가지에 있어서 다가 금속으로서 철을 이용하는 방법.18. The method of any one of claims 1-17 using iron as the polyvalent metal. 청구범위 제18항에 있어서 히드록시에틸에틸렌디아민 트리아세트산과 철과의 배위착물을 반응물로 이용하는 방법.The method according to claim 18, wherein the coordination complex of hydroxyethylethylenediamine triacetic acid and iron is used as a reactant. 청구범위 제18항에 있어서 니트릴로트리아세트산과 철과의 배위착물을 반응물로 이용하는 방법.The method according to claim 18, wherein the coordination complex of nitrilotriacetic acid and iron is used as a reactant. 청구범위 제1항에 있어서 각 실시예에 따라 상술된 바와 같은 방법.The method as claimed in claim 1 as described above in accordance with each embodiment. 앞에 나온 각 청구범위 중 어느 한 가지 청구범위에 의한 방법으로 제조되는 결정질 황.Crystalline sulfur produced by the method according to any of the preceding claims. 청구범위 제1항에서부터 제21항까지 중 어느 한 가지 청구범위에 의한 방법으로 제조되는 정제된 가스유동물.Purified gaseous animal prepared by the method according to any one of claims 1 to 21. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR8202267A 1981-05-26 1982-05-22 Sulphur recovery process Expired KR900000187B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US267196 1981-05-25
US06/267,196 US4348368A (en) 1981-05-26 1981-05-26 Method of removing hydrogen sulfide from gases

Publications (2)

Publication Number Publication Date
KR830009798A true KR830009798A (en) 1983-12-23
KR900000187B1 KR900000187B1 (en) 1990-01-23

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US (1) US4348368A (en)
EP (1) EP0066309B1 (en)
JP (1) JPS57197021A (en)
KR (1) KR900000187B1 (en)
AU (1) AU549727B2 (en)
BR (1) BR8203008A (en)
CA (1) CA1173629A (en)
DE (1) DE3262759D1 (en)
IN (1) IN155631B (en)
ZA (1) ZA823577B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3148520A1 (en) * 1981-12-08 1983-07-21 Linde Ag, 6200 Wiesbaden "METHOD FOR REMOVING ACID GASES FROM GAS MIXTURES"
US4478798A (en) * 1981-12-08 1984-10-23 Linde Aktiengesellschaft Prevention of carbonyl formation to avoid fouling of sour gas absorption system
CA1221673A (en) * 1983-12-20 1987-05-12 Zaida Diaz Process for the removal of h.sub.2s from a sour h.sub.2s-containing gaseous stream
AT379759B (en) * 1984-04-05 1986-02-25 Kimura Kakoki Co Ltd METHOD FOR REMOVING SULDURATE FROM GASES
IN168471B (en) * 1985-08-23 1991-04-13 Shell Int Research
DE3781802T2 (en) * 1987-10-31 1993-04-01 Texaco Development Corp SELECTIVE RECOVERY OF CARBON DIOXIDE.
US5648054A (en) * 1995-01-31 1997-07-15 Gas Research Institute Double loop liquid-liquid H2 S removal process
RU2123879C1 (en) * 1998-01-22 1998-12-27 Открытое акционерное общество "Бокситогорский полимер" Gas absorber
GB2450878A (en) * 2007-07-10 2009-01-14 Nexia Solutions Ltd Metal sandwich compounds and their use for binding gases
MX2010003050A (en) * 2007-09-20 2010-05-27 Swapsol Corp Process for destroying carbonaceous materials and composition and system thereof.

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US2881047A (en) * 1956-05-29 1959-04-07 Laurence S Reid Method of simultaneously removing hydrogen sulfide from gaseous mixtures and producing sulfur therefrom
US3068065A (en) * 1956-08-24 1962-12-11 Humphreys & Glasgow Ltd Method of removing hydrogen sulphide from gases
US3580950A (en) * 1967-11-01 1971-05-25 Frederick C Bersworth Chelating compositions based on chelating acids and amines
US4009251A (en) * 1973-08-27 1977-02-22 Rhodia, Inc. Process for the removal of hydrogen sulfide from gaseous streams by catalytic oxidation of hydrogen sulfide to sulfur while inhibiting the formation of sulfur oxides
US3933993A (en) * 1974-06-28 1976-01-20 General Electric Company Use of concentrated chelated iron reagent for reducing pollutant content of a fluid
US4091073A (en) * 1975-08-29 1978-05-23 Shell Oil Company Process for the removal of H2 S and CO2 from gaseous streams

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JPS57197021A (en) 1982-12-03
JPH0144369B2 (en) 1989-09-27
BR8203008A (en) 1983-05-10
EP0066309A1 (en) 1982-12-08
CA1173629A (en) 1984-09-04
ZA823577B (en) 1983-03-30
KR900000187B1 (en) 1990-01-23
DE3262759D1 (en) 1985-05-02
AU8409482A (en) 1982-12-02
AU549727B2 (en) 1986-02-06
IN155631B (en) 1985-02-16
EP0066309B1 (en) 1985-03-27
US4348368A (en) 1982-09-07

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