KR20180058315A - Hair cosmetic composition - Google Patents

Abstract

The present invention provides a hair cosmetic composition which contains 0.001 to 5 wt% of polyquaternium-101, has excellent conditioning power when being rinsed by not containing silicone based substances, provides an excellent conditioning effect by having good adhesion to hair, and can improve moisturizing power, shine, volume, and scent remaining power after drying.

Description

[0001] Hair cosmetic composition [0002]

The present invention relates to a hair cosmetic composition, which comprises polyquaternium-101, wherein the hair cosmetic composition at the time of rinsing increases the adhesive force to hair, has excellent rinsing properties and feeling of use, The present invention relates to a hair cosmetic composition which minimizes chemical stimulation.

Shampoo, a hair cleanser, cleanses hair by removing contaminants and sebum from the hair and scalp. However, if the moisturizing ingredients of sebum and hair are removed through the shampooing process, the softness of the hair becomes weaker and becomes dry, making the hair tangled and difficult to handle . In order to compensate for this, in the case of the shampoo according to the prior art, a hair conditioning agent is included to increase the flexibility of the hair. However, in the case of silicone, which is mainly used as a hair conditioning agent, researches have been carried out to overcome this problem because the hair is washed away in the process of rinsing with water. Research has been conducted to increase the conditioning power by increasing the adhesion of hair during rinsing by using a cationic polymer such as polyquaternium-10, guar hydroxy triimonium chloride and the like. Recently, the hair moisturizing ability, Consumer interest in products with volume effects is increasing.

The hair cosmetic composition is not only a function of cleaning and conditioning but also an additional function, so that a shampoo and a conditioner having a good sustained flavor even after a certain period of time is preferred to obtain a perfume-like effect. Accordingly, the fragrance content is increased or the volatile retention agent is used to increase the fragrance persistence of the hair cleanser composition. However, when such a volatile retention agent is contained, shampoo often inhibits formation of bubbles and feeling of use.

In Japanese Patent No. 5025845, it is proposed to use a volatile retention agent in addition to fragrances in products containing 3- (l-menthoxy) propane-1,2-diol and the like. However, the basic property of the shampoo, And the feeling of use and the conditioning power are not excellent.

SUMMARY OF THE INVENTION [0006]

And to provide a hair cosmetic composition having increased adhesion to hair upon rinsing and enhanced moisturizing power, gloss, volume, and reverberation after drying.

Further, it is intended to provide a hair product made of the cosmetic composition described above.

According to an aspect of the present invention,

0.001 to 5% by weight of polyquaternium-101,

Wherein the hair cosmetic composition does not contain a silicone.

The hair cosmetic composition according to the present invention is excellent in the conditioning ability when rinsed and is well adhered to the hair by using Polyquaternium-101 even in the case of using shampoo and conditioner which are mainly used as a conditioning agent, Provided is a hair cosmetic composition enhanced in moisture resistance, gloss, volume, and reverberation.

The present invention relates to a hair cosmetic composition comprising 0.001 to 5% by weight of polyquaternium-101,

Wherein the hair cosmetic composition does not contain a silicone.

The hair cosmetic composition of the present invention comprises polyquaternium-101.

The content of polyquaternium-101 is preferably 0.001 to 5% by weight based on the total weight of the composition. If the content is less than 0.001% by weight, the conditioning power, moisturizing power, If the weight percentage of the shampoo composition is more than 100% by weight, not only the foaming power and the high quality of the foam, which are the main properties of the shampoo composition, are deteriorated but also the hair build-up phenomenon may occur and the conditioner may cause the hair to build up.

More particularly, the polyquaternium-101 not only plays an effective role in maintaining the phase stability of the entire composition by keeping the fragrance stable even though it contains a high content of fragrance in the hair cleanser composition, Has a cationic property and is well adhered to hair even in the course of hair rinsing. By the hydrophobic alkyl group and nonionic monomer, it increases the collection power of the fragrance, thereby increasing the reverberating power and conditioning power of the hair You can give. In addition, the main chain of polyquaternium-101 is an acrylic polymer structure, which helps to set the hair after drying to give a volume effect, to protect the hair from moisture evaporation, and to improve gloss.

The hair cosmetic composition according to the present invention preferably contains no silicone.

If the silicone is not included, the chemical stimuli applied to the scalp is minimized, and the hair is very smooth when rinsed after rinsing, so that the rinsing property and the feeling of use can be improved.

In addition, there is no whitening phenomenon, so that it is transparent, and the feeling of richness can be excellent.

The silicone fluid may be selected from the group consisting of dimethicone, dimethicone polyol, dimethicone polyol acetate, silicone glycol copolyol, dimethicone, methylpolysiloxane, methylphenylpolysiloxane, dimethicone copolyol methyl ether, methylcyclopolysiloxane, dimethylpolysiloxane, hexa Methyldisiloxane, caprylylmethyl polysiloxane, and the like, but are not limited thereto.

In the present invention, the hair cosmetic composition preferably contains at least one additive selected from a surfactant, a fatty alcohol, a conditioning agent, a viscosity regulator, a preservative, a moisturizer, a wetting agent, a hair repair agent and a pearlizing agent.

The surfactant may be at least one selected from anionic surfactants, cationic surfactants, nonionic surfactants and amphoteric surfactants.

The fatty alcohol may be at least one selected from cetyl alcohol, stearyl alcohol and benzyl alcohol.

The conditioning agent may be at least one selected from a cationic polymer, a nonionic polymer, and a positive ionic polymer.

In the present invention, the hair cosmetic composition may further comprise a sulfate anionic surfactant, wherein the sulfate anionic surfactant is selected from sodium lauryl sulfate, sodium laureth sulfate, ammonium lauryl sulfate and ammonium laureth sulfate At least one is preferable.

In the present invention, the hair cosmetic composition may further comprise a tertiary amidoamine, wherein the tertiary amidoamine is selected from the group consisting of stearamidopropyldimethylamine, cocamidopropyldimethylamine, brassicamidopropyldimethylamine, Amine, and behenic amidopropyldimethylamine. However, the present invention is not limited thereto.

Specifically, sodium chloride, ammonium chloride and the like can be used as the viscosity controlling agent, and sodium benzoate and the like can be used as the preservative.

The hair cleansing composition of the present invention may be a hydrolyzed wheat protein or the like. The hair cleansing composition of the present invention having enhanced conditioning ability upon rinsing according to the present invention may contain the above-mentioned specific ingredients But is not limited thereto.

The present invention can provide a hair product made of the hair cosmetic composition, and the hair product can be, but not limited to, hair shampoo, hair rinse, hair conditioner, hair treatment, hair pack or hair cream.

Hereinafter, preferred embodiments of the hair cosmetic composition according to the present invention will be described in detail.

Prior to this, terms and words used in the present specification and claims should not be construed as limited to ordinary or dictionary terms, and the inventor should appropriately interpret the concepts of the terms appropriately It should be interpreted in accordance with the meaning and concept consistent with the technical idea of the present invention based on the principle that it can be defined. Therefore, the configuration shown through the embodiments described herein is merely the most preferred embodiment of the present invention, and does not represent all of the technical ideas of the present invention, so that various equivalents It should be understood that water and variations may be present.

< Example  1 to 3 and Comparative Example  1 to 4>

Sodium laureth sulfate, trihydroxystearin and cetyl alcohol were added to the purified water, and the mixture was heated to 90 ° C. When the temperature reached 90 ° C, the mixture was stirred for 30 minutes while maintaining the temperature, and then cooled to 45 ° C Sodium lauroisocyanate, cocamidopropyl betaine and guar hydroxypropyl trimonium chloride were added and stirred at room temperature for 20 minutes. Then, additives such as polyquaternium-101, pearlizing agent and silicone emulsion were added And further stirred for 20 minutes to prepare Examples 1 to 3 and Comparative Examples 1 to 4 conditioning shampoo compositions.

(The content of each component is shown in Table 1 below).

Category (% by weight) Example Comparative Example One 2 3 One 2 3 4 Sodium laureth sulfate 15 15 15 15 15 15 15 Sodium lauroisocyanate One One One One One One One Cocamidopropyl betaine 5 5 5 5 5 5 5 Polyquaternium-101 0.001 One 5 - - 10 0.0005 Guar hydroxypropyltrimonium chloride 0.6 0.6 0.6 0.6 0.6 0.6 0.6 Dimethicone emulsion - - - - 0.5 - - Trihydroxystearin 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Cetyl alcohol 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Ammonium chloride 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Sodium benzoate 0.05 0.05 0.05 0.05 0.05 0.05 0.05 incense 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Perl topic Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Citric acid Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Proper amount Purified water To100 To100 To100 To100 To100 To100 To100

< Test Example  1>

In order to evaluate the stability of the conditioning shampoo composition prepared through Examples 1 to 3 and Comparative Examples 1 to 4 described above, it was stored at room temperature, 40 ° C, 50 ° C and 5 ° C for 1 month, , The stability of the composition was confirmed, and the results are shown in Table 2. &lt; tb &gt; &lt; TABLE &gt;

division Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Room temperature Good Good Good Good Good discoloration Good 40 ℃ Good Good Good Good Good discoloration Good 50 ℃ Good Good Good Phase separation Phase separation discoloration Phase separation 5 ℃ Good Good Good Phase separation Phase separation discoloration Good ore Good Good Good Good Good discoloration Good

As shown in Table 2 above, the conditioning shampoo composition prepared from Examples 1 to 3 containing 0.001 to 5% by weight of polyquaternium-101 and not including a silicone type had a room temperature of 40 ° C , 50 ° C and 5 ° C, or exposed to light, all showed good results. However, Comparative Example 1, which did not contain both polyquaternium-101 and silicone, and Polyquaternium-101 , Comparative Example 2 containing a silicone fluid showed phase separation at 50 ° C and 5 ° C. In Comparative Example 3 in which the content of polyquaternium-101 exceeded 5% by weight, discoloration was severe and polyquaternium-101 0.0005 weight % In Comparative Example 4 exhibited phase separation at 50 캜 and the stability was lowered.

< Test Example  2>

In order to evaluate the feeling and conditioning effect of the conditioning shampoo composition prepared in Examples 1 to 3 and Comparative Examples 1 to 4, in which stability at room temperature was confirmed by the above-described Test Example 1, hair damaged by hair dyeing and permer 100 women of 25 to 40 years of age were selected. After the conditioning shampoo composition was used for 4 weeks, a feeling test and a conditioning test were conducted to compare the results. The results are shown in Table 3.

(The test score is the lowest score and the highest score is 5 points.)

Evaluation items Example Comparative Example One 2 3 One 2 3 4 There is plenty of foam in the shampoo. 4.1 4.0 4.0 2.8 3.0 3.3 3.2 The feeling of air bubble is good when shampooed 4.1 4.2 4.5 2.8 2.8 2.9 3.3 Hair does not get tangled during shampooing 4.0 4.2 4.6 3.2 3.7 3.0 3.0 The hair does not get caught in the rinse. 4.0 4.2 4.5 3.1 3.6 3.0 3.1 When shampooing, hair is washed neatly. 4.3 4.1 4.1 3.0 3.4 3.2 3.3 Soft hair after drying 4.1 4.2 4.4 3.1 3.1 3.0 3.0 I feel moisturizing after drying 4.0 4.3 4.3 3.3 3.3 3.4 3.5 Hair shines after drying 4.1 4.3 4.2 3.2 3.2 3.7 3.4 The volume of hair after drying is abundant. 4.1 4.5 4.7 2.8 2.9 3.0 3.1

As shown in the above-mentioned Table 3, the conditioning shampoo composition prepared from Examples 1 to 3 containing 0.001 to 5% by weight of polyquaternium-101 described above and not including the silicone type, It can be confirmed that hair condition such as bubble sensation, shampoo and condition of hair at the time of rinsing, moisturizing power after drying, shine, volume, and the like are improved as compared with the conditioning shampoo composition produced through the method.

< Test Example  3>

In order to evaluate the conditioning efficiency of the conditioning shampoo compositions prepared in Examples 1 to 3 and Comparative Examples 1 to 4, in which the stability at room temperature was confirmed by the above-described Test Example 1, the drying shampoo composition after using the above conditioning shampoo composition Evaluation of combing sensation on hair was carried out, and the results are shown in Table 4.

First, hair tress was made with virgin hair of an Asian woman purchased from De-Meo Brothers, USA, and then 10% of Sodium Laureth Sulfate (SLS) After the hair was thoroughly rinsed with water, the hair was completely dried using a drier and allowed to stand in a constant temperature and humidity room for 2 hours. The hair bundle was hung on the load cell ring of the Instron, the comb was fixed, The reference value was set by measuring the load on the hair when combing.

Then, 1 g of the conditioning shampoo composition prepared in Examples 1 to 3 and Comparative Examples 1 to 4 was applied to the hair bundles soaked in water and rinsed for 30 seconds, and then combed using Instron as described above The load value applied to each composition was measured at least three times, and the average load value was calculated to calculate the reduction rate with respect to the reference value.

(Instron uses Universal Test Machine, Instron Model 4465 Test System.)

Evaluation items Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Average Load Decrement Rate (%) -33 -34 -38 -24 -29 -29 -27

As shown in Table 4, in the case of the hair containing the conditioning shampoo composition prepared from Examples 1 to 3 containing 0.001 to 5% by weight of polyquaternium-101 described above and containing no silicone, It can be seen that the combing feeling is improved as compared with Examples 1 to 4.

< Test Example  4>

In order to evaluate the degree of reverberation of the conditioning shampoo composition prepared in Examples 1 to 3 and Comparative Examples 1 to 4, in which the stability at room temperature was confirmed by the above Test Example 1, 20 persons were selected. After washing the hair using the above conditioning shampoo composition, the reverberation was evaluated at 4 hours, 8 hours, and 12 hours, and the results are shown in Table 5.

(However, the lowest score is 1 point and the highest score is 5 points.)

Evaluation items Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 After shampooing 4.2 4.3 4.6 3.5 3.3 3.2 3.4 After 4 hours 4.0 4.1 4.3 2.9 3.0 3.0 3.3 After 8 hours 3.8 3.9 4.0 2.4 2.6 2.8 2.9 After 12 hours 3.5 3.5 3.7 2.0 2.4 2.3 2.9

As shown in Table 5, when the conditioning shampoo composition containing 0.001 to 5% by weight of polyquaternium-101 and containing no silicone was used in Examples 1 to 3, Comparative Examples 1 to 4 It can be seen that the degree of reverberation is improved.

Therefore, the conditioning shampoo composition according to the present invention exhibits an excellent effect in providing a shampoo composition having excellent conditioning effect and enhanced reverberation.

< Example  4 to 6 and Comparative Example  5 to 8>

The hair conditioner compositions of Examples 4 to 6 and Comparative Examples 4 to 6 according to the present invention were prepared as shown in Table 6.

Raw material name Example Comparative Example 4 5 6 5 6 7 8 Purified water Balance Balance Balance Balance Balance Balance Balance Stearamidopropyldimethylamine One One One One One One One Glutamic acid 0.4 0.4 0.4 0.4 0.4 0.4 0.4 Cetyl alcohol 3.5 3.5 3.5 3.5 3.5 3.5 3.5 Stearyl alcohol 3.5 3.5 3.5 3.5 3.5 3.5 3.5 Benzyl alcohol 0.01 0.01 0.01 0.01 0.01 0.01 0.01 Dimethicone emulsion - - - - 2 - - Spices Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Suitable amount Polyquaternium-101 0.001 0.1 5 - - 10 0.005

The production methods of Examples 4 to 6 and Comparative Examples 5 to 8 are as follows.

1. Heat the raw materials 1 to 3 at 75 캜 to dissolve them.

2. Heat the ingredients 4 to 6 at 75 ℃ to dissolve.

3. The above-mentioned (2) is added to the above (1) and emulsified by stirring.

4. After cooling the above-mentioned (3) to 50 ° C, the raw materials 7 to 9 are added and mixed uniformly.

The above-mentioned benzyl alcohol can be added to (3) by mixing with the perfume to further increase the adherence of the perfume, but this causes a problem that the freshness of the perfume is inhibited. Do.

< Test Example  5: Evaluation of improvement effect of freeze-thaw stability>

The hardness of the hair conditioner was measured using a rheometer (Model 300) to evaluate the effects of improving the stability of freezing and thawing of the products of Examples 4 to 6 and Comparative Examples 5 to 8.

The hardness was evaluated by measuring the maximum value of the pushing force from the surface of the hair conditioner to the depth of 10 mm using a rheometer adapter at a force of 2 kg and a load of 180 mm / min. The adapter used in this evaluation is cylindrical and has a contact area of 25mm in diameter. The hair conditioner was evaluated in a vertical round PET having a volume of 100 mL.

The samples prepared in Examples 4 to 6 and Comparative Examples 5 to 8 were stored at room temperature and frozen-thawed twice to measure the hardness of the composition. The results are shown in Table 7. The cycle conditions of freezing and thawing were 25 ° C at minus 5 ° C, 8 ° C at minus 5 ° C and 25 ° C, and 25 ° C at minus 5 ° C and 25 ° C at minus 5 ° C And adjusted for 4 hours each.

Evaluation Products (Unit: g) Example 4 Example 5 Example 6 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Room temperature 152 130 149 157 157 155 153 Frozen - Thaw 2 times 164 145 160 109 118 210 181 Difference in hardness
(Frozen-thawed 2 times and room temperature) 12 15 11 48 39 55 29

The larger the difference in hardness measurement value means that the formulation of the hair conditioner has been deformed, so that it contains 0.001 to 5% by weight of polyquaternium-101, and in Comparative Examples 5 to 8 , It can be seen that the formulation stability according to freezing and thawing is excellent.

< Test Example  6: Evaluation of hair conditioning efficacy>

In order to evaluate the hair conditioning effects of the above Examples 4 to 6 and Comparative Examples 5 to 8, panel evaluation was carried out in the following manner. Twenty women aged 25 to 40 were used for 1 week to 2 days for a total of 3 weeks, and the conditioning effect on each product was evaluated according to the following evaluation items.

- Criteria: Very poor (1), Bad (2), Average (3), Good (4), Very good (5)

Example 4 Example 5 Example 6 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Massage feeling when using 3.6 3.7 3.6 3.2 3.2 3.6 3.5 Softness when rinsing 4.0 4.3 4.1 3.3 3.5 2.8 3.4 Softness in wet conditions 3.8 4.2 3.7 3.3 3.4 3.5 3.4 Softness in dry condition 4.0 4.5 4.1 3.3 3.4 3.0 3.5 Dry feeling 3.9 4.1 4.3 3.0 3.1 3.3 3.5 Shiny feeling in dry condition 3.8 4.6 4.8 3.1 3.0 3.4 3.3 Dry feeling of volume 3.8 4.7 4.8 3.1 2.9 3.0 3.1

As can be seen from Table 8 above, Examples 4 to 6, which contained 0.001 to 5 wt% of polyquaternium-101 and no silicone, showed excellent hair conditioning effect, moisturizing effect, Gloss and volume.

< Test Example  7: Reverberation  Evaluation and evaluation of incense preference>

For the evaluation of the reverberation and the flavor preference of the conditioner, the evaluation was carried out in the following manner in Examples 4 to 6 and Comparative Examples 5 to 8.

The hair shampoo, which had a weight of 10 g and a length of 20 cm, was treated with an unshaven shampoo, treated with each of the above Examples 4 to 6 and Comparative Examples 5 to 8, dried, and then hair bundles Were evaluated.

Three hair bundles were prepared for each composition to improve the reliability of the evaluation results. The evaluation results of the fragrance preference, the reverberation immediately after drying, and after 7 hours of drying are shown in Table 8 below.

- Criteria: Very poor (1), Bad (2), Average (3), Good (4), Very good (5)

Example 4 Example 5 Example 6 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Incense preference 4.0 4.1 3.8 3.4 3.3 3.0 3.5 Reverberation immediately after drying 4.0 4.3 3.9 3.3 3.3 3.6 3.5 Reverberation after 7 hours of drying 3.5 4.0 4.1 3.1 3.0 3.4 3.3

As can be seen from Table 9, Examples 4 to 6 containing 0.001 to 5% by weight of polyquaternium-101 and no silicones exhibited excellent reverberation compared to Comparative Examples 5 to 8 I could.

Claims (7)

0.001 to 5% by weight of polyquaternium-101,
Wherein the hair cosmetic composition does not contain any silicone.
The method according to claim 1,
Wherein the hair cosmetic composition comprises at least one additive selected from the group consisting of a surfactant, a fatty alcohol, a conditioning agent, a viscosity regulator, a preservative, a moisturizer, a wetting agent, a hair repair agent and a pearlizing agent.
3. The method of claim 2,
Wherein the surfactant is at least one selected from anionic surfactants, cationic surfactants, nonionic surfactants and amphoteric surfactants.
3. The method of claim 2,
Wherein the conditioning agent is at least one selected from a cationic polymer, a nonionic polymer, and a positive ion polymer.
The method according to claim 1,
Wherein the hair cosmetic composition comprises a fatty alcohol.
A hair product characterized by being manufactured from the hair cosmetic composition according to any one of claims 1 to 5.
The method according to claim 6,
Wherein the hair product is a hair shampoo, a hair conditioner, a hair conditioner, a hair treatment, a hair pack, or a hair cream.