KR20180056830A - Hair-dye Composition Comprising Nature Materials - Google Patents

Abstract

The present invention provides a hair dye composition comprising: 2 to 5 parts by weight of a viscous agent; 1 to 4 parts by weight of a binder; 1 to 4 parts by weight of a dye; 1 to 2 parts by weight of tartaric acid; 1 to 2 parts by weight of a coloring agent; 1 to 2 parts by weight of a cationic polymer; 0.1 to 5 parts by weight of a surfactant; 0.1 to 5 parts by weight of talc; 0.05 to 0.5 parts by weight of collagen; 0.1 to 0.5 parts by weight of n-n-bis (2-hydroxyethyl)-p-phenylenediamine sulfate; 0.05 to 0.5 parts by weight of a hydrochloric acid 2.4-diaminoxyethanol; 0.05 to 0.5 parts by weight of sodium lauryl sulfate; and 0.05 to 0.5 parts by weight of perfume, with respect to 100 parts by weight of grain powder. The hair dye composition according to the present invention improves dyeing properties and color persistence and prevents side effects against a human body and hair while preventing damage to hair at the same time.

Description

[0001] Hair-dye Composition Comprising Nature Materials [0002]

The present invention relates to a hair dyeing composition comprising a natural material which is improved in dyeability and color sustainability and which can alleviate hair damage while preventing side effects on the human body and hair.

Generally, a hair dye is generally classified into a temporary hair dye, a semi-permanent hair dye, and a permanent hair dye depending on the durability and color durability of the hair.

The permanent hair dyeing agents include oxidation hair dyeing agents, metal hair dyeing agents and vegetable hair dyeing agents depending on dyes used, and most hair dyeing agents currently in use are oxidation dyeing agents using oxidation dyes such as aromatic amino compounds.

Here, most of the vegetable hair dyeing agents include henna and chamomile, and the dyeing effect is low and it is difficult to dye brightly.

In addition, the metallic hair dye uses the principle of blackening when lead is oxidized, and it is rarely used since it has harmful toxicity to the human body.

Finally, oxidative dyeing agents are excellent in dyeing effect and can be dyed in bright colors, and they are most widely used today.

However, the oxidation dyeing agent has a relatively good salt strength, but has a weak salt-forming ability depending on the hair, and has a disadvantage of gradually fading or discoloring due to sunlight, shampoo, sweat and the like. As a result, the dyeing agent has been improved by increasing the content of the dye used to improve the dyeing property or by improving the penetration and diffusion of the dye by using an alkaline agent such as monoethanolamine or strong ammonia water.

The alkali component used in these hair dyeing agents reduces the shine and gloss of the hair, dissolves the hair component and severely damages the hair. In some cases, it becomes an unnatural color, the texture becomes worse, and the skin allergy There is an easy problem.

In addition, a large amount of dyes used for the purpose of improving the durability not only makes the emulsion system of the hair dyeing agent unstable, but also dissolves the hair components to cause hair damage, and a dye which causes skin irritation when it is put on the scalp or forehead Because it is a substance, its usage is somewhat limited.

As an example of such a hair dye, Korean Patent No. 0239877 discloses a hair treatment composition comprising a surfactant, an oxidative organic dye, a flavoring agent, aqueous ammonia, aqueous hydrogen peroxide, ammonium thioglycolate, fatty acid alcohol and the like.

Disclosure of the Invention The present invention has been made to overcome the above-mentioned problems, and it is an object of the present invention to provide a hair dyeing composition comprising a natural material which is improved in dyeability and color sustainability and which can alleviate hair damage while preventing side effects on the human body and hair .

The present invention

On the basis of 100 parts by weight of the grain powder,

2 to 5 parts by weight of a viscous material;

1 to 4 parts by weight of a binder;

1 to 4 parts by weight of a dye;

1 to 2 parts by weight of tartaric acid;

1 to 2 parts by weight of a colorant;

1 to 2 parts by weight of a cationic polymer;

0.1 to 0.5 parts by weight of a surfactant;

0.1 to 0.5 parts by weight of talc;

0.05 to 0.5 parts by weight of collagen;

0.1 to 0.5 parts by weight of n-n-bis (2-hydroxyethyl) -p-phenylenediamine sulfate;

0.05 to 0.5 parts by weight of hydrochloric acid 2.4-diaminophenoxyethanol;

0.05 to 0.5 parts by weight of sodium lauryl sulfate; And

And 0.05 to 0.5 parts by weight of a perfume.

The hair dye composition according to the present invention improves dyability and color sustainability and can alleviate hair damage while preventing side effects on the human body and hair.

Hereinafter, the present invention will be described in detail.

The terminology used herein is for the purpose of describing particular embodiments only, and is not intended to suggest any invention. As used herein, the singular forms "a," "an," and "the" include singular forms unless the context clearly dictates otherwise. It is also to be understood that the word " comprise " and / or "comprising" when used in this specification and the appended claims are intended to cover such forms, numbers, steps, operations, elements, elements and / And does not preclude the presence or addition of one or more other features, integers, operations, elements, elements, and / or groups.

The present invention relates to a method for producing a grain powder comprising: 2 to 5 parts by weight, based on 100 parts by weight of a grain powder; 1 to 4 parts by weight of a binder; 1 to 4 parts by weight of a sub-dye; 1 to 2 parts by weight of tartaric acid; 1 to 2 parts by weight of a colorant; 1 to 2 parts by weight of a cationic polymer; 0.1 to 0.5 parts by weight of a surfactant; 0.1 to 0.5 parts by weight of talc; 0.05 to 0.5 parts by weight of collagen; 0.1 to 0.5 parts by weight of n-n-bis (2-hydroxyethyl) -p-phenylenediamine sulfate; 0.05 to 0.5 parts by weight of hydrochloric acid 2.4-diaminophenoxyethanol; 0.05 to 0.5 parts by weight of sodium lauryl sulfate; And 0.05 to 0.5 parts by weight of a perfume.

The grain powder according to the present invention is ineffective to the amount used and is easy to use without interfering with the dyeing effect. Any conventional grain powder in the art having such a purpose may be used, , Rice powder, black rice powder in particular, barley powder, soybean powder or a mixture of at least one selected from these.

The hair dye composition according to the present invention is characterized in that the content of the remaining components other than the grain powder of the hair dye composition comprising a natural material is based on 100 parts by weight of the grain powder.

The viscous agent according to the present invention is for forming a viscous solution or gel by binding with a solution, for example, water, and any conventional viscous agent in the art having such a purpose may be used.

As a preferable viscous agent, it is preferable to use sodium carboxymethylcellulose, carboxyethylethylcellulose sodium, guar gum, gum arabic, or a mixture of at least one selected from these, and the amount thereof is 2 to 5 parts by weight based on 100 parts by weight of the grain powder I recommend you.

The binder according to the present invention is to provide a binding force between the constituents of the hair dye composition and any conventional binder in the art having such a purpose may be used. Preferably, however, sodium perborate, sodium sulfate anhydrate, It is preferable to use the mixture in an amount of 1 to 4 parts by weight based on 100 parts by weight of the grain powder.

If the amount of the binder is less than 1 part by weight, the binding force between the components of the composition is weak. If the amount is more than 4 parts by weight, the feeling of use is poor.

The dyes according to the present invention can be used in direct dyes that are conventionally used within a range that does not impair the object. Examples of such direct dyes include Arianol dyes, p-phenylenediamine, p- Aminophenol, o-aminophenol, p-nitro-o-phenylenediamine, nitro-p-phenylenediamine, 2-amino-4-nitrophenol, Henna, which is a vegetable dyestuff of picriminic acid and Henna, or a mixture of at least one selected from these, may be used, but it is preferable to use p-phenylenediamine, p-aminophenol, o-aminophenol .

At this time, the materials usable as the dye can provide various colors by controlling the mixing ratio thereof when they are mixed with each other.

Preferably, the amount of the dye to be used is 1 to 4 parts by weight based on 100 parts by weight of the grain powder.

In a specific embodiment, the hair dye composition according to the present invention may be used in admixture with a dye to further include dye auxiliaries to provide various hues to the hair and to maintain hair dye for a long time.

Preferred dye auxiliaries are resorcinol, 2-methylresorcinol, 2-methyl-5-hydroxyethylaminophenol, p-amino-ocresol, m-aminophenol, m-phenylenediamine hydrochloride, m -Phenylene diamine and? -Naphthol, and the amount of the mixture is 0.01 to 2 parts by weight based on 100 parts by weight of the grain powder.

The tartaric acid according to the present invention is used as an acidifying agent, and the amount thereof is preferably 1 to 2 parts by weight based on 100 parts by weight of the grain powder.

The coloring agent according to the present invention is intended to improve the coloring of the hair dye composition on the hair. Any colorant conventionally used in the art may be used for this purpose, but toluene-2,5-diamine sulfate And the amount thereof used is preferably 1 to 2 parts by weight based on 100 parts by weight of the grain powder.

If the amount of the colorant used is less than 1 part by weight, coloring is not easy. If the amount is more than 2 parts by weight, the coloring performance is not significantly increased.

The cationic polymer according to the present invention is a cationic group and / or a random polymer containing a group which is capable of ionizing a cationic group, at least one C ₈ -C ₃₀ fatty chain, and does not include the 1meq / g or more charge density Is a cationic polymer.

Here, the charge density of the cationic polymer can be measured by the Kjeldahl method.

Preferred cationic polymers are selected from the group consisting of polyketanium, dimethyl sulfate, acrylamide quaternized with dimethyl halide, copolymer of dimethylaminoethyl methacrylate, copolymer of acrylamide and methacryloyloxyethyltrimethylammonium methosulfate, 4 But are not limited to, polyvinylpyrrolidone or polyvinylpyrrolidone or polyvinylpyrrolidone or polyvinylpyrrolidone copolymers, polyvinylpyrrolidone / polyvinylpyrrolidone / polyvinylpyrrolidone / polyvinylpyrrolidone copolymers, Dimethylaminopropyl methacrylamide copolymer, or a mixture of at least one selected from the foregoing, and the amount of use is preferably 1 to 2 parts by weight based on 100 parts by weight of the grain powder.

The surfactant according to the present invention may be any conventional surfactant in the art, but it is preferable to use an anionic surfactant, but not limited thereto, specifically, sodium sulfate, sodium alkylsulfate, Polysorbate, polyoxyhydrogenated castor oil, sodium Nacyl sarcosinate, fatty acid esters, polyoxyethylene hydrogenated castor oil, polyoxyethylene higher alcohol ethers, polyoxyethylene polyoxypropylene copolymers, polyoxyethylene Ethylene polypropylene fatty acid ester, and the like are preferably used singly or in combination. The amount of the ethylene polypropylene fatty acid ester to be used is preferably 0.1 to 0.5 parts by weight based on 100 parts by weight of the grain powder.

The talc according to the present invention is a rock belonging to a monoclinic system used for reducing an artificially shiny feeling after hair application and preventing hair from becoming clogged. The amount of talc used is preferably 0.1 to 0.5 parts by weight based on 100 parts by weight of the grain powder.

The collagen according to the present invention is a major protein that constitutes flesh and connective tissues. It is mainly used in cosmetics for preventing skin aging and supplying nutrients to the skin. For this purpose, any collagen commonly used in the art can be used However, it is preferable to use hydrolyzed collagen, which is obtained by hydrolyzing the bones of bovine or pigs, skin, acids, alkalis and enzymes, respectively, alone or in combination, 0.05 to 0.5 parts by weight of the grain powder is recommended, but not limited thereto.

The n-n-bis (2-hydroxyethyl) -p-phenylenediamine sulfate according to the present invention is a component for allowing hair to be easily dyeable, and its amount to be used is preferably 0.1 to 0.5 parts by weight based on 100 parts by weight of the grain powder.

If the amount of the nn-bis (2-hydroxyethyl) -p-phenylenediamine sulfate is less than 0.1 part by weight, hair can not be stained well and a desired color can not be obtained. - phenylenediamine sulfate) component, that is, allergic.

The hydrochloric acid 2.4-diaminophenoxyethanol according to the present invention is intended to make the hair dye composition stably and easily stain the hair, and the amount thereof is preferably 0.05 to 0.5 parts by weight based on 100 parts by weight of the grain powder.

The sodium lauryl sulfate according to the present invention is preferably used as a modifier in an amount of 0.05 to 0.5 parts by weight based on 100 parts by weight of the grain powder.

The perfume according to the present invention is intended to improve the user's feeling by adding a perfume to the hair dye composition. Any perfume can be used as long as it has such a purpose in the art. Preferably, the perfume is in the form of lavender, rosemary, oregano, Herbs such as bergamot, yallow, basil, mint, sage or lemon balm, jasmine, borage, anica, spartium, clarysege, peppermint can be used.

In a specific embodiment, the hair dye composition according to the present invention may further comprise 10 to 60 parts by weight of starch based on 100 parts by weight of the grain powder for controlling the viscosity of the hair dye.

Preferred starches include potato starch, sweet potato starch, corn starch or mixtures thereof.

In another specific embodiment, the hair dye composition according to the present invention may further comprise an antioxidant in an amount of 0.01 to 3 parts by weight based on 100 parts by weight of the grain powder to prevent oxidation of the hair dye composition.

The preferred antioxidant may be an amine-based, bisphenol-based, monophenol-based, or sulfur-based antioxidant, and more specifically 2.2-methylenebis (4-methyl-6-t-butylphenol). 2 - M ethylenebis (4 - methyl - 6 - t - butylphenol), 2.6 - di - t - Butyl - 4 - methylphenol or mixtures thereof I recommend you.

In another specific embodiment, the hair dye composition according to the present invention may further comprise 0.001 to 3 parts by weight of a mordant, based on 100 parts by weight of the grain powder.

As a preferable mordant, mordant such as vinegar, salt water, iron ore, alum, natural mordants such as Al, Cu, Cr, Fe, Sn, Ni and the like or a mixture of at least one selected from these may be used.

In another specific embodiment, the hair dye composition according to the present invention may further comprise 0.1 to 1 part by weight of a wetting agent based on 100 parts by weight of the grain powder.

Preferred wetting agents include, but are not limited to, sodium hyaluronate, sorbitol, xylitol, mannitol, maltitol, or a mixture of at least one thereof.

In another specific embodiment, the hair dye composition according to the present invention may further comprise 0.1 to 10 parts by weight, based on 100 parts by weight of the grain powder, of a pH adjusting agent capable of adjusting the pH of the composition.

Preferable pH controlling agents include organic acids such as sodium phosphate, sodium tribasic acid, disodium ethylenediaminetetraacetate (EDTA 2Na), citric acid, succinic acid, lactic acid, malic acid, fumaric acid, maleic acid, glycolic acid, etc., and inorganic acids such as hydrochloric acid, sulfuric acid, Mineral acid and the like can be used, and the sodium salt, potassium salt, ammonium salt and the like of these acids can be used, or at least one of them can be used.

Hereinafter, the present invention will be described in detail by way of examples. However, the following examples are for illustrative purposes only and are not intended to limit the scope of the present invention.

[Example 1]

2.5 g of sodium perborate, 2.3 g of p-phenylenediamine, 1.4 g of tartaric acid, 1.4 g of toluene-2.5-diamine sulfate, 1.4 g of polystaranium, 0.23 g of sodium sulfate, 0.23 g of talc , 0.12 g of hydrolized collagen, 0.23 g of nn-bis (2-hydroxyethyl) -p-phenylenediamine sulfate, 0.12 g of hydrochloric acid, 2.4-diaminophenoxyethanol, 0.12 g of sodium lauryl sulfate and 0, 12 g of sage perfume were mixed to prepare a hair dye composition.

[Example 2]

The procedure of Example 1 was repeated, except that 0.5 g of 2-methylresorcinol was further added.

[Example 3]

The procedure of Example 1 was repeated, except that 30 g of potato starch was further added.

[Example 4]

The procedure of Example 1 was repeated except that 1.5 g of 2.2-methylenebis (4-methyl-6-t-butylphenol) was further added.

[Example 5]

The procedure of Example 1 was repeated, except that 1 g of aluminum metal salt was further added.

[Example 6]

The procedure of Example 1 was repeated except that 0.5 g of sodium hyaluronate was further added.

[Example 7]

The procedure of Example 1 was repeated, except that 2 g of sodium phosphate was further added.

[Experiment]

Each of the hair dye composition prepared according to Examples 1 to 7, and specifically, the hair dye composition containing natural ingredients was mixed with water at a weight ratio of 1: 4 to measure the salt strength and feeling of use.

The results are shown in Table 1.

Herein, the salt strength and feeling of use were measured for 20 men / women, and the shampoo and rinse were used three times a week. After one month, the salt strength and feeling were measured. The degree of mock discoloration was measured.

Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Salt strength good Very good good good Very good usually usually Feeling good good usually good usually good good Discoloration (10 days) Colorless Colorless Colorless Colorless Colorless Colorless Colorless Discoloration (20 days) Colorless Colorless Fade Colorless Colorless Fade Fade Discoloration (30 days) Fade Colorless Fade Colorless Fade Fade Fade

As shown in Table 1, the hair dye composition according to the present invention, particularly the hair dye composition comprising a natural material, showed a superior salt strength and feel to use, and the degree of discoloration after dyeing was not bad.

As described above, those skilled in the art will understand that the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. It is therefore to be understood that the embodiments described above are all illustrative and not restrictive. The scope of the present invention should be construed as being included in the scope of the present invention without departing from the spirit and scope of the present invention as defined by the appended claims and their equivalents.

Claims (5)

On the basis of 100 parts by weight of the grain powder,
2 to 5 parts by weight of a viscous material;
1 to 4 parts by weight of a binder;
1 to 4 parts by weight of a dye;
1 to 2 parts by weight of tartaric acid;
1 to 2 parts by weight of a colorant;
1 to 2 parts by weight of a cationic polymer;
0.1 to 0.5 parts by weight of a surfactant;
0.1 to 0.5 parts by weight of talc;
0.05 to 0.5 parts by weight of collagen;
0.1 to 0.5 parts by weight of nn-bis (2-hydroxyethyl) -p-phenylenediamine sulfate;
0.05 to 0.5 parts by weight of hydrochloric acid 2.4-diaminophenoxyethanol;
0.05 to 0.5 parts by weight of sodium lauryl sulfate; And
0.05 to 0.5 parts by weight of a perfume.
The method according to claim 1,
Wherein the grain powder comprises a wheat powder, a rice powder, a barley powder, a soybean powder, or a mixture of at least one selected from the foregoing.
The method according to claim 1,
Wherein the viscous agent is at least one selected from the group consisting of sodium carboxymethyl cellulose, carboxyethyl ethyl cellulose sodium, guar gum, gum arabic or a mixture of at least one thereof.
The method according to claim 1,
Wherein the double layering agent is sodium perborate, anhydrous sodium sulfate or a mixture thereof.
The method according to claim 1,
Wherein the collagen is hydrolyzed collagen.