KR20170098004A - Printable battery with high power - Google Patents
Printable battery with high power Download PDFInfo
- Publication number
- KR20170098004A KR20170098004A KR1020160019831A KR20160019831A KR20170098004A KR 20170098004 A KR20170098004 A KR 20170098004A KR 1020160019831 A KR1020160019831 A KR 1020160019831A KR 20160019831 A KR20160019831 A KR 20160019831A KR 20170098004 A KR20170098004 A KR 20170098004A
- Authority
- KR
- South Korea
- Prior art keywords
- printing
- layer
- printed
- current collector
- electrode layer
- Prior art date
Links
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/40—Printed batteries, e.g. thin film batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/663—Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
- H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
- H01M6/12—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid with flat electrodes
-
- Y02E60/12—
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Primary Cells (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Abstract
Description
The present invention relates to a high-output printed battery, and more particularly, to a method for manufacturing a high-output printed battery, which comprises two steps of conducting a primary printing current collector layer and a secondary printing current collector layer to minimize electric resistance, To a high-output printed battery containing an excellent metal component to improve the output of the battery and extend the service life of the battery.
Along with the development of electronic devices, a battery serving as a power source has also been developed in various forms. In recent years, thin sheet type thin type batteries are being developed.
Recently, due to the rapid development of Internet, RFID, smart cards and beauty and medical patch technology, the demand for thin type batteries as a power source of these products is increasing.
In the field of thin type electronic devices, a thin type battery having low durability and mechanical flexibility with a thickness of less than several hundred microns is required, and a battery which is attracting much attention and attention in accordance with such characteristics is a thin type printed battery.
The printed battery can easily produce a large number of cells having a complicated shape, and it is possible to integrate the electronic device and the battery by printing the electrode material directly on the electronic device. A thin printed battery includes an anode, a cathode, an electrolyte, and a current collector layer, as well as a general battery, in which a thin film-like battery is implemented by a printing method.
Thin-film printed cells are structurally divided into face-to-face and coplanar cells. The face-type thin-type battery in which the positive electrode and the negative electrode face each other with the separator interposed therebetween exhibits a relatively good output characteristic as compared with the planar type battery. However, in order to increase the output power of the unit cell, There are many problems such as a decrease in productivity, an increase in manufacturing cost, and a complicated manufacturing process.
On the other hand, in a coplanar battery in which anodes and cathodes coexist on the same plane, a problem of low capacity arises when several unit cells are connected in series in one cell in order to recover low output characteristics.
Most conventional batteries are current collectors that use metal such as sheets or bars. In a battery using a metal current collector, sufficient conductivity is provided so that the discharge speed of the battery is not affected by the current collector.
In thin-film printed batteries, which require all processes to be implemented by printing methods, carbon ink has been used as a current collector layer.
In the thin type battery, the current generated at the discharge is collected in the current collecting layer and flows through the external circuit. Impedance Analysis for Current Flow in a Thin Printed Cell From the experimental results, it was confirmed that the current flowing in the battery is a bottleneck section in the current collecting layer made of carbon, which causes a discharge voltage drop of the battery.
That is, it has been found that it is effective to improve the conductivity of the current collector layer in order to increase the output of the battery. In order to reduce the resistance of the current collecting layer, which is a step of controlling the reaction of the battery, it has been studied to introduce metallic ink into the constituent of the current collector layer.
When the metal ink was introduced into the collector layer instead of the carbon ink, the metal component and the electrode material, especially the anode material, directly reacted electrochemically, so that a voltage drop of the battery and a severe swelling phenomenon due to gas generation were observed. This phenomenon appears to be caused by the overlapping of the manganese dioxide potential, the electrode active material, and the reduction potential of the metal component.
In the present invention, the output of a thin-type printed battery is improved by devising a current-collecting layer having a double-layer structure so as to introduce a metal component having excellent conductivity into the current collector to prevent direct contact with the electrode active material.
SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems of the prior art, and it is an object of the present invention to provide a method of manufacturing a semiconductor device, which is performed in two steps of a primary printing current collector layer and a secondary printing current- And a printed output layer containing a metal component having excellent conductivity in the printed collector layer to improve the output of the battery and extend the service life of the battery.
The present invention relates to a sheet for use as a substrate whose shape can be varied;
A primary printed current collector layer printed on the sheet and containing a metallic component;
A secondary printing current collector layer printed on the primary printing current collector layer and electrically connected to the primary printing current collector layer;
An electrode layer formed on a part of the secondary printed current collector layer;
A hot melt film formed on an edge of the first electrode layer formed on the electrode layer and serving to prevent the gel electrolyte from leaking out from the outside; And
And a separator layer formed on the first electrode layer on the inner side of the hot melt film to form a gel electrolyte,
The center portion of the sheet between the first electrode layer and the second electrode layer formed on the electrode layer is folded so that the first electrode layer and the second electrode layer abut against each other with the separator interposed therebetween.
The primary printed current collector layer is provided with a primary printed first current collector layer on one side of the sheet and a primary printed second current collector layer spaced laterally from the primary printed first current collector layer .
The primary printed current collector layer contains any one of silver, aluminum, stainless steel, nickel, and copper or a combination thereof.
Wherein the secondary printing current collecting layer comprises a secondary printing first current collecting layer printed on the primary printing first current collecting layer formed on the primary printing collecting layer and a secondary printing printing material Two current collecting layers are provided and the secondary printing primary and secondary collecting layers are printed in a structure covering the entire primary printing primary and secondary collecting layers.
The secondary printed current collector layer is made of carbon.
The electrode layer includes a first electrode layer printed on a part of the secondary printing first current collector layer formed on the secondary printing current collector layer and functioning as an anode and printed on a part of the secondary printing secondary current collector layer to function as a cathode And a second electrode layer.
The first electrode layer contains a manganese dioxide powder, a carbon powder and a binder, and the second electrode layer contains a zinc powder, a carbon powder and a binder.
According to the high-output printed battery of the present invention, in the printing of the current collecting layer, the primary printing current collecting layer and the secondary printing current collecting layer are carried out in two steps to minimize the electrical resistance and also to contain a metal component having excellent conductivity in the primary printing current collecting layer The battery output is improved and the battery life is prolonged.
BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a plan view of a primary printing current collector layer printed on a sheet of paper according to one embodiment of the present invention. Fig.
2 is a plan view in which a secondary printing current collector layer is printed on a primary printing current collector layer;
3 is a plan view showing the first and second electrode layers formed on the secondary printed current collector layer.
4 is a plan view showing a hot melt film formed on the edge of the first electrode layer.
5 is a plan view showing a separation film formed on the first electrode layer.
6 is a plan view showing a state in which a central portion of a sheet is folded to form a high-
7 is a graph showing impedance measurement values of an embodiment of the present invention.
8 is a graph showing pulse characteristics of an embodiment of the present invention.
FIG. 9 is a plan view of a primary printing current collector layer printed on a sheet of paper according to another embodiment of the present invention. FIG.
10 is a plan view in which a secondary printing current collector layer is printed on a primary printing current collector layer.
11 is a plan view in which first and second electrode layers are formed on a secondary printed current collector layer.
12 is a plan view showing a hot melt film formed on the edges of the first and second electrode layers.
13 is a plan view in which an electrolyte is applied on the first and second electrode layers.
14 is a cross-sectional view of a hot-melt film in which a high-output printed battery is formed by adhering a fleece sheet to an upper portion thereof.
15 is a graph showing impedance measurement values of another embodiment of the present invention.
16 is a graph showing pulse characteristics of another embodiment of the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings. However, the embodiments of the present invention may be modified into various other forms, and the scope of the present invention is not limited to the embodiments described below. The shape and the size of the elements in the drawings may be exaggerated for clarity and the same elements are denoted by the same reference numerals in the drawings.
1 to 6, the
However, the present invention is not limited to such a
The
The present invention is characterized in that the current collecting layer of a printed battery is formed by two processes, that is, a primary printing current collecting layer (110) and a secondary printing current collecting layer (210).
In order to realize this, the primary printing first current-collecting
The primary printed
The shape, width, and thickness of the primary printed first
The primary printing first
A secondary printed
The secondary printing
The secondary printing first
The primary printed first
The
The
The
The addition of the conductive agent can be eliminated in the cathode according to the required electrical characteristics and the polarities of the
The
The
A predetermined interval is maintained between the
An
In order to maintain a uniform amount of the electrolyte in the
A water-soluble electrolytic solution prepared by dissolving 40% by weight of ZnCl 2 in purified water in purified water of the
The
7 shows impedance data of a high-output printed battery according to an embodiment of the present invention assembled as described above. In Comparative Example 1, on a sheet of paper, a first printed first current-collecting
In the embodiment of the present invention in which the current collecting layer composed of the double printing of the primary printing current collecting layer and the secondary printing current collecting layer was introduced in the manufacturing process of the high output printed battery, the value of about 20? It has an impedance value of 55Ω.
From this fact, it can be seen that the resistance in the current collecting layer greatly affects the impedance of the whole battery in the thin type printed battery, and it is confirmed that increasing the conductivity of the current collecting layer is effective in improving the impedance.
A test was conducted to see how such impedance difference actually affects the pulse discharge of the battery, and the results are shown in FIG. The pulse condition was set as one cycle with a current of 6 mA for 4 ms and a period of 10 S, and the voltage change of the cell was observed when this cycle was repeated.
In the high output printed battery manufactured under the conditions of the embodiment, the closed voltage was 1.35 V when the peak current value was 6 mA and the open circuit voltage was 1.4 V in the rest state. In contrast, in Comparative Example 1, which was tested under the same pulse condition, the closing voltage was about 0.95 V, and the difference from the open-circuit voltage was about 0.45 V. Which is larger than the difference between the open-circuit voltage and the closed-circuit voltage of 0.05 V in one embodiment, which means that the high-power effect is remarkably improved in one embodiment.
In addition, another embodiment of the present invention will be described, which is applied to a coplanar type printed battery, and more detailed description will be made on the basis of FIGS. 9 to 14.
The
However, the present invention is not limited to such a
The
The present invention is characterized in that the current collecting layer of the printed battery is formed by two processes, that is, a primary printing
In order to realize this, the primary printing first current-collecting
The primary printing first
The primary printed
The shape, width, and thickness of the primary printed first
The primary printing first
A secondary printed
The secondary printed
The secondary printing first
The primary printed first
An
The
The mixture is mixed with a binder solution to prepare a slurry state, and the binder is mixed with polyethylene oxide, polyvinyl pyrrolidone, and the like.
The prepared slurry is printed on a part of the secondary printing first
The
The slurry is printed on a part of the secondary printing second
The hot melt film 400 'for sealing the battery is placed on the
The hot melt film 400 'has a sufficient resistance to an electrolytic solution, selects a material having excellent moisture barrier properties, and usually uses polyethylene as a main component.
A predetermined interval is maintained between the
A gel-type water-soluble electrolyte 500 'is formed on the first and second electrode layers 310 and 320 on the inner side of the hot melt film 400'.
The electrolyte 500 'is prepared by preparing a water-soluble electrolytic solution containing 60% by weight of water and 40% by weight of ZnCl 2 and then adding 7% by weight of polyethylene oxide to obtain a sticky ecotype and a viscosity of about 1,000 to 40,000 cps .
The
15 shows impedance data of a high-output printed battery according to another embodiment of the present invention assembled as described above. In Comparative Example 2, on the sheet paper, a first printed first current-collecting
The impedance of another embodiment of the present invention in which the current collecting layer made of the double printing of the primary printed
A test was conducted to see how such impedance difference actually affects the pulse discharge of the battery, and the results are shown in FIG.
The pulse condition was set as one cycle under the conditions of flowing for 3 ms at a current of 3 mA for 5 ms and at rest for 1 S, and the voltage change of the battery was observed when these cycles were repeated.
In another embodiment of the present invention, when the open-circuit voltage is about 1.4 V and the 3-mA current flows for 5 mS, the closed-circuit voltage is about 1.3 V, and the residual pressure drop is about 0.1 V.
On the other hand, in Comparative Example 2, the open-circuit voltage was 1.4 V and the closed-circuit voltage was 1.0 V, which resulted in a voltage drop of 0.4 V. In addition, the life of the battery in a given pulse condition was about 700 hours in the other examples, but was shortened to 550 hours in the case of Comparative Example 2.
As a result, not only the effect of improving the output of the battery according to the present invention, but also the life of the battery can be greatly increased.
From the above test results, it has been confirmed that, in the case of a thin printed battery, the electric resistance of the current collector layer of the battery greatly affects the impedance of the battery and that it is very effective to reduce the electric resistance to improve the output of the battery.
The present invention can be applied to any compact device on a substrate having a built-in thin-type battery system as well as the pitch of the cosmetics and medicine field. For example, an RFID tag, a tag with a sensor, a smart card, or an electronic device requiring power.
The present invention is not limited to the above-described embodiments and the accompanying drawings. It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims, something to do.
100: sheet paper
100 ': Filling sheet
110, 110 ': primary printing collector layer
111: primary printing primary current collecting layer
112: 1st printing 2nd collecting layer
210, 210 ': secondary printing collector layer
211: 2nd printing 1st collecting layer
212: 2nd printing 2nd collecting layer
300, 300 ': electrode layer
310: first electrode layer
320: Second electrode layer
400,400 ': Hot melt film
500:
500 ': gel electrolyte
Claims (14)
A primary printed current collector layer printed on the sheet and containing a metallic component;
A secondary printing current collector layer printed on the primary printing current collector layer and electrically connected to the primary printing current collector layer;
An electrode layer formed on a part of the secondary printed current collector layer;
A hot melt film formed on an edge of the first electrode layer formed on the electrode layer and serving to prevent the gel electrolyte from leaking out from the outside;
And a separator layer formed on the first electrode layer on the inner side of the hot melt film to form a gel electrolyte,
Wherein a center portion of the sheet between the first electrode layer and the second electrode layer formed on the electrode layer is folded so that the first electrode layer and the second electrode layer abut against each other with the separator interposed therebetween.
And a first printing second current collecting layer having a primary printing first current collecting layer disposed on one side of the sheet and spaced laterally from the first printing first current collecting layer.
Wherein the primary printed current collector layer contains any one of silver, aluminum, stainless steel, nickel, and copper, or a combination thereof.
A second printing first current collecting layer printed on the first printing first current collecting layer formed on the primary printing collecting layer and a second printing second collecting layer printed on the first printing second collecting layer, Wherein the first and second current collecting layers are printed in a structure covering the entire first and second current collecting layers.
Wherein the secondary printed current collector layer is made of carbon.
A second electrode layer printed on a part of the secondary printing first current collector layer formed on the secondary printing current collector layer and having a first electrode layer functioning as an anode and being printed on a part of the secondary printing secondary current collector layer, Wherein the high-power printed battery comprises:
Wherein the first electrode layer contains manganese dioxide powder, carbon powder and a binder, and the second electrode layer contains zinc powder, carbon powder and a binder.
A primary printed collector layer disposed on the sheet paper in a concavo-convex shape and containing a metal component;
A secondary printing current collecting layer disposed on the primary printing current collecting layer so as to be meshed with each other and electrically connected to the primary printing current collecting layer;
An electrode layer formed on a part of the secondary printed current collector layer;
A hot melt film formed on an edge of the electrode layer and serving to prevent the gel electrolyte from leaking out from the outside;
A gel-type electrolyte coated on an electrode layer inside the hot melt film;
And a sealing sheet sealed on the top of the hot melt film so as to face the sheet paper.
And a first printing second current collecting layer having a primary printing first current collecting layer disposed on one side of the sheet and spaced laterally from the first printing first current collecting layer.
Wherein the primary printed current collector layer contains any one of silver, aluminum, stainless steel, nickel, and copper, or a combination thereof.
A second printing first current collecting layer printed on the first printing first current collecting layer formed on the primary printing collecting layer and a second printing second collecting layer printed on the first printing second collecting layer, Wherein the first and second current collecting layers are printed in a structure covering the entire first and second current collecting layers.
Wherein the secondary printed current collector layer is made of carbon.
A second electrode layer printed on a part of the secondary printing first current collector layer formed on the secondary printing current collector layer and having a first electrode layer functioning as an anode and being printed on a part of the secondary printing secondary current collector layer, Wherein the high-power printed battery comprises:
Wherein the first electrode layer contains manganese dioxide powder, carbon powder and a binder, and the second electrode layer contains zinc powder, carbon powder and a binder.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020160019831A KR101782973B1 (en) | 2016-02-19 | 2016-02-19 | Printable battery with high power |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020160019831A KR101782973B1 (en) | 2016-02-19 | 2016-02-19 | Printable battery with high power |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20170098004A true KR20170098004A (en) | 2017-08-29 |
KR101782973B1 KR101782973B1 (en) | 2017-09-28 |
Family
ID=59759990
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020160019831A KR101782973B1 (en) | 2016-02-19 | 2016-02-19 | Printable battery with high power |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR101782973B1 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019145224A1 (en) | 2018-01-25 | 2019-08-01 | Bayer Business Services Gmbh | Monitoring of products |
JP2020009764A (en) * | 2018-07-05 | 2020-01-16 | アルモール | Grid current collector, and related device and methods |
WO2020114841A1 (en) | 2018-12-03 | 2020-06-11 | Bayer Aktiengesellschaft | Tracking a collective of objects |
WO2020234209A1 (en) | 2019-05-22 | 2020-11-26 | Bayer Business Services Gmbh | Monitoring of products |
EP3843187A1 (en) * | 2019-12-23 | 2021-06-30 | VARTA Microbattery GmbH | Printed battery, radio tag and production method |
EP3740995A4 (en) * | 2018-01-16 | 2021-10-20 | Printed Energy Pty Ltd | Thin film-based energy storage devices |
EP4181162A1 (en) * | 2021-11-13 | 2023-05-17 | VARTA Microbattery GmbH | Electrochemical energy storage cell and battery |
WO2023052048A3 (en) * | 2021-09-28 | 2023-09-14 | Varta Microbattery Gmbh | Electrochemical zinc-carbon cell with layered design, and battery |
-
2016
- 2016-02-19 KR KR1020160019831A patent/KR101782973B1/en active IP Right Grant
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3740995A4 (en) * | 2018-01-16 | 2021-10-20 | Printed Energy Pty Ltd | Thin film-based energy storage devices |
WO2019145224A1 (en) | 2018-01-25 | 2019-08-01 | Bayer Business Services Gmbh | Monitoring of products |
US11599850B2 (en) | 2018-01-25 | 2023-03-07 | Bayer Aktiengesellschaft | Monitoring of products |
JP2020009764A (en) * | 2018-07-05 | 2020-01-16 | アルモール | Grid current collector, and related device and methods |
WO2020114841A1 (en) | 2018-12-03 | 2020-06-11 | Bayer Aktiengesellschaft | Tracking a collective of objects |
WO2020234209A1 (en) | 2019-05-22 | 2020-11-26 | Bayer Business Services Gmbh | Monitoring of products |
EP3843187A1 (en) * | 2019-12-23 | 2021-06-30 | VARTA Microbattery GmbH | Printed battery, radio tag and production method |
WO2021130345A1 (en) * | 2019-12-23 | 2021-07-01 | Varta Microbattery Gmbh | Printed battery, rfid tag, and production method |
JP2023508987A (en) * | 2019-12-23 | 2023-03-06 | ヴァルタ マイクロバッテリー ゲゼルシャフト ミット ベシュレンクテル ハフツング | PRINTED BATTERY, RFID TAG, AND MANUFACTURING METHOD |
WO2023052048A3 (en) * | 2021-09-28 | 2023-09-14 | Varta Microbattery Gmbh | Electrochemical zinc-carbon cell with layered design, and battery |
EP4181162A1 (en) * | 2021-11-13 | 2023-05-17 | VARTA Microbattery GmbH | Electrochemical energy storage cell and battery |
Also Published As
Publication number | Publication date |
---|---|
KR101782973B1 (en) | 2017-09-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101782973B1 (en) | Printable battery with high power | |
CN105914037B (en) | Electrical storage device and its manufacturing method | |
US20120276434A1 (en) | Highly flexible printed alkaline batteries based on mesh embedded electrodes | |
JP5255432B2 (en) | Batteries, batteries, labels, medical devices with thin flexible electrochemical cells | |
CN109088071B (en) | Composite layer and application thereof | |
US7881042B2 (en) | Cell assembly for an energy storage device with activated carbon electrodes | |
US20100081049A1 (en) | Electrochemical Element | |
US11018343B1 (en) | Current collector surface treatment | |
US20100266895A1 (en) | High current thin electrochemical cell and methods of making the same | |
KR20010015414A (en) | Method for producing film packed battery | |
US11374261B2 (en) | Electrochemical device and solid-state lithium ion rechargeable battery | |
US11108106B2 (en) | Stretchable fabric based electrode-polymer electrolyte battery | |
KR20170015322A (en) | Electrical energy storage element, method and appratus for producing electrical energy storage element | |
WO2015137099A1 (en) | Charging circuit and module using same | |
US8914103B2 (en) | Device and iontophoresis patch comprising thin film battery | |
CN110998951A (en) | Electrode sheet manufacturing method, all-solid-state battery, and all-solid-state battery manufacturing method | |
JP2001015152A (en) | Fully solid layer built cell | |
US20120171547A1 (en) | Printed battery using non-aqueous electrolyte and battery packaging | |
Oliveira et al. | Printed batteries: an overview | |
KR101781140B1 (en) | Thin printable battery | |
Saidi et al. | The effect of ink formulation and electrode geometry design on the electrochemical performance of a printed alkaline battery | |
TW201143190A (en) | Lithium ion battery assembly | |
CN109216776A (en) | Electrochemical device | |
US11251483B2 (en) | Method of preparing an electrochemical cell | |
EP2642567B1 (en) | Redox polymer energy storage system |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
AMND | Amendment | ||
E601 | Decision to refuse application | ||
AMND | Amendment | ||
X701 | Decision to grant (after re-examination) | ||
GRNT | Written decision to grant |