KR20170058146A - Liquid detergent composition having excellent cleansing effect to be packed into foamer containers - Google Patents

Abstract

The present invention relates to a liquid detergent composition for a spray-type and foam-type container, which has improved cleansing power to makeup, such as color cosmetics, which are hard to be cleansed by comprising a combination of specific surfactants and compounds. The liquid detergent composition of the present invention can realize excellent cleansing power, easiness of rinsing, easiness of foaming, dense bubbles, and mild feeling of use, and phase stability, such as low-temperature stability can be ensured. In addition, the make-up cleansing power is improved, and double cleansing is not necessary. Moreover, the liquid detergent composition is easily applicable to a pump foamer container as no clogging occurs in a non-gas type foam pump, and the pH of the composition is in a slightly acid range to be universally used regardless of the skin type.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a liquid detergent composition for a foam container,

The present invention relates to a liquid detergent composition for a foam container which is excellent in makeup detergency, and more particularly to a liquid detergent composition for a foam container which is excellent in detergency against make-up difficulties such as makeup or color cosmetics, ≪ / RTI >

In general, make-up removal can be done simply by using make-up tissues or cotton swabs, then removing the make-up removing oil or cleansing cream, which can dissolve the make-up, secondly, and finally cleansing using soap or cleansing foam It takes a lot of time to clean it and it needs to be cleaned step by step several times. Such multi-level make-up cleansing can improve cleansing power against make-up contamination, but excessively removes sebaceous glands and intercellular lipids to induce skin irritation, and when cleansing the make- Eye irritation may result if eye contact occurs.

Facial cleansers focused on removing makeup are also emerging recently. However, such a cleanser also has a problem in that the make-up is erased well but the oil component is so large that bubbles are scarcely produced and the feeling of use is low and the rinsability is poor. Also, since the lipophilic component that cleans up the makeup has poor compatibility with the hydrophilic cleansing component, there are limited kinds of cleansing surfactants that can be used. These formulations may be regarded as wash-off cleansing products that focus on removing make-up rather than focusing on cleansing. The cleansing agent, which is not so foamy, makes it easier for the user to recognize that the cleansing is not enough and the make-up remains.

A cleanser containing a non-ionic surfactant has been proposed for a low-stimulant make-up cleansing and cleansing. However, since the abundance of bubbles and the densification of bubbles are insufficient, the satisfaction of bubbles at the time of cleansing is lowered and the cleansing power is insufficient.

Most of the cleaning agents must be used beforehand in order to be cleaned, and it is necessary to concentrate the parts which are not cleaned properly after cleaning the entire surface of the part to be cleaned, irrespective of the area where a lot of makeup is applied. . To solve such a problem, a cleanser which can easily generate foam by using a non-gas type foam discharge container has been introduced and various proposals have been proposed so far. Such a liquid detergent composition mixes the air with the contents composition by passing the porous membrane inside the foam dispensing container to produce a foam. However, fatty acid soap is mainly used as such a composition. When fatty acid soap is used, the ability to remove oil-based and silicone-based contaminants which are difficult to remove such as make-up and the like is lowered and the moisturizing effect after use due to excessive washing of sebum and skin oil layer And there arises a problem that clogging tends to occur due to precipitation of higher fatty acids at low temperature storage.

From this background, a detergent composition comprising an amino acid-based anionic surfactant such as N-acyl amino acid salt and an amphoteric surfactant has been proposed, but it is required to secure low temperature stability. When applied to a non-gas type type container, Is insufficient in quality.

Therefore, it is an object of the present invention to provide a liquid detergent for non-gas foam containers which is excellent in the quality of foam during cleaning, less irritating to the skin, easy to remove contaminants on the face such as makeup, It is required to develop a liquid detergent composition capable of discharging a good foam without causing clogging when the foam is filled in a foam container and pressing the pump of the foam container smoothly.

A problem to be solved by the present invention is to provide a liquid detergent composition which is packed in a non-gas type foam discharge container provided with a porous membrane at a discharge port, which is free from clogging in product discharge, Which is excellent in removing power of the skin, has a creamy and stable foam, secures formulation stability at a low temperature, has little irritation to the skin, and does not require double cleansing.

The present invention relates to a composition containing (A) an amino acid surfactant, (B) an amphoteric surfactant, (C) a nonionic surfactant, (D) sodium lauryl glycocarboxylate, (E) polyoxyethylene Acid) glyceryl and (F) polyhydric alcohols.

As a result of intensive researches to overcome the problems of the prior art, the present inventors have found that a specific kind of surfactant, sodium lauryl glycosyl carboxylate and polyoxyethylene (capryl / capric acid) glyceryl, The inventors of the present invention have surprisingly found that the liquid detergent composition containing the surfactant as an ingredient has excellent washing power, bubble resilience, low temperature stability, no trouble in the foam discharge, and little skin irritation.

In the present invention, the amino acid type surfactant, (B) ampholytic surfactant and (C) nonionic surfactant may be contained in a weight ratio of (A) / (B) + (C) have. The liquid detergent composition of the present invention exhibits the best detergency when the components (A), (B) and (C) are contained in a specific weight ratio as described above. When the ratio (A) / (B) + (C) is less than 1.5, the detergency is insufficient due to the insufficient amount of the amino acid surfactant. When the ratio is more than 3, The amount of the amphoteric surfactant is insufficient, so that the detergency of the main surfactant can not be assured and the detergency is decreased.

In the present invention, the amino acid surfactant (A) used as the main surfactant may be an acylamino acid anionic surfactant having an acyl group having 8 to 14 carbon atoms. The acyl amino acid anionic surfactant of the present invention means an acylated product of a compound containing primary to tertiary amino groups and a carboxylic acid or a sulfonic acid in the same molecule and a fatty acid. This can be produced mainly by a schotten baumann reaction using fatty acid chloride as an acylating agent.

Compounds containing the above-mentioned primary to tertiary amino groups and carboxylic acid or sulfonic acid in the same molecule can be obtained from natural acidic or neutral amino acids obtained by an extraction method or a fermentation method or synthetic acidic or neutral amino acids obtained by a synthetic method or an enzymatic method have. Specific examples of the acidic or neutral amino acid may include at least one selected from the group consisting of glutamic acid, aspartic acid, glycine, alanine, taurine, methyltaurine, saccharin (N-methylglycine) L, D or racemate may be present, either of which may be used.

The above-mentioned acyl amino acid anionic surfactant can be appropriately selected depending on the purpose, and examples thereof include acyl methyl taurine salts, acyl taurine salts, acyl methyl -? - alanine or salts thereof, acyl- At least one selected from the group consisting of a salt thereof, acylglutamic acid or a salt thereof, acylglycine or a salt thereof, acylaspartic acid or a salt thereof, acylsarcosine or a salt thereof and the like may be used.

In order to obtain the persistence of the foam during washing and the smooth feeling after cleaning, it is preferable that the acyl amino acid anionic surfactant is selected from the group consisting of acyl methyl taurine salts, acyl methyl-β-alanine or salts thereof, acyl glutamic acid or salts thereof, Or a salt thereof, and acyl aspartic acid or a salt thereof may be used. More preferably, acyl glutamic acid or its salt or acyl aspartic acid or its salt may be used as the acyl amino acid anionic surfactant. More preferably, the amino acid surfactant (A) may contain 10 to 30% by weight, preferably 13 to 27% by weight, more preferably 15 to 25% by weight of glutamate based on the total weight of the amino acid surfactant, In this case, the persistence of the foam during cleaning and the smooth feeling after cleaning are the most excellent.

The salt may be, for example, an alkali metal salt or an alkanolamine salt, but is not limited thereto. The alkali metal salt may be, for example, a sodium salt or a potassium salt. The alkanolamine salt may be, for example, a monoethanolamine salt or a triethanolamine salt. In order to further increase the persistence of the foam, an alkali metal salt may preferably be used, and more preferably, a sodium salt may be used.

The number of carbon atoms of the acyl group of the amino acid surfactant (A) may be 8 to 14. The carbon number of the acyl group may be preferably 10 to 13, and most preferably 12. When the carbon number of the acyl group is less than 8, the cleansing power is decreased. When the acyl group is more than 14, the cleansing power and the elasticity and persistence of the foam are insufficient.

In the present invention, the amino acid surfactant (A) may be contained in an amount of 0.1 to 20% by weight, preferably 0.5 to 15% by weight, more preferably 1 to 10% by weight based on the total weight of the composition. When the amount of the amino acid surfactant (A) is less than 0.1% by weight, the cleansing power, moist feeling after washing, elasticity and persistence of foam are insufficient. When the amount is more than 20% by weight, The function is degraded. In view of the above, the amino acid surfactant is preferably contained in an amount of 1 to 10% by weight based on the total weight of the composition.

In the present invention, the amphoteric surfactant (B) used as an auxiliary surfactant may be added to the liquid detergent composition of the present invention in order to improve the quality of the foam (the density of the foam, the creaminess of the foam, etc.) Can be used.

The amphoteric surfactant may be appropriately selected according to the purpose among the compounds used in the detergent, and examples thereof include imidazoline type (amide amine type), amide amino acid salt, carbobetaine type (alkyl betaine, Alkyl amide betaine) and sulfobetaine type (alkyl sulfobetaine, alkylhydroxy sulfobetaine), and the like can be used.

As the imidazoline type ampholytic surfactant, for example, stearoyl amide amine or coconut oil alkyl-N-hydroxyethyl imidazolinium betaine and the like may be used. Examples of the amphoteric surfactant of the carbobetaine type include lauryldimethylaminoacetic acid betaine, coconut alkyldimethylaminoacetic acid betaine or stearyldimethylaminoacetic acid betaine as an alkyl betaine; And alkyl amide betaine, palm oil fatty acid amide propyl betaine or lauric acid amidopropyl betaine can be used. As the sulfobetaine type amphoteric surfactant, for example, alkyl sulfobetaine, palm oil fatty acid dimethyl sulfopropyl betaine and the like; Or lauryldimethylaminohydroxysulfobetaine or laurylhydroxysulfobetaine such as alkylhydroxysulfobetaine may be used. Preferably, the amphoteric surfactant may be palm oil fatty amide propyl betaine or lauryl hydroxysulfobetaine, and in this case is excellent in low temperature stability. In the present invention, the amphoteric surfactants may be used singly or in combination of two or more.

The amphoteric surfactant may be used in an appropriate amount in accordance with the purpose of the present invention and may be contained in an amount of 0.4 to 15% by weight, preferably 2 to 10% by weight based on the total weight of the liquid detergent composition of the present invention. When the amphoteric surfactant is contained within the above-mentioned content range, the foam quality and low-temperature stability are excellent, and a mild feeling when using the skin can be obtained. When the amount of the amphoteric surfactant is less than 0.4% by weight, the low temperature stability is deteriorated. When the amount of the amphoteric surfactant is more than 15% by weight, the rinsing speed is lowered and the texture of the bubble drops.

In the present invention, the (C) nonionic surfactant used as the co-surfactant may be an alkyl glucoside surfactant. The alkyl glucoside-based surfactant may be any one selected from the group consisting of, for example, octyl glucoside, nonyl glucoside, decyl glucoside, dodecyl glucoside, lauryl glucoside, myristyl glucoside and palmityl glucoside.

The nonionic surfactant may be contained in an amount of 1 to 20% by weight, preferably 1 to 10% by weight, more preferably 1 to 5% by weight based on the total weight of the liquid detergent composition of the present invention. If the amount of the nonionic surfactant is less than 1% by weight, the cleansing effect and the foaming property are insufficient. If the nonionic surfactant is more than 20% by weight, the affinity with the makeup becomes poor and the usability is deteriorated. There is a problem in terms of surface.

In the present invention, the weight ratio of the amphoteric surfactant (B) and the nonionic surfactant (C) is in the range of 5: 1 to 1: 1, preferably 4: 1 to 1: 1, more preferably 3: : 1 (amphoteric surfactant: nonionic surfactant). If the blending amount of the amphoteric surfactant is less than the nonionic surfactant in the above range, the feeling of stiffness is given after use and the feeling of use is inferior due to lack of bubble texture.

In the present invention, commercially available products of the component (D) sodium lauryl glycol carboxylate can be used. For example, the product "Beaulight SHAA" (Sanyo Chemical Industries Co., Ltd.) may be used, It is not.

The sodium lauryl glycol carboxylate (D) is present in an amount of from 0.1 to 10% by weight, preferably from 0.3 to 7% by weight, more preferably from 0.5 to 5% by weight, and most preferably from 0.8 to 10% by weight based on the total weight of the liquid detergent composition of the present invention. To 2% by weight. When the amount of sodium lauryl glycol carboxylate is less than 0.1% by weight, foam formation is difficult to achieve and it is difficult to obtain a good cleansing effect. When the amount of the sodium lauryl glycol carboxylate is more than 10% by weight, It tends to be stronger.

In the present invention, (E) polyoxyethylene (capryl / capric acid) glyceryl may be obtained by subjecting ethylene oxide to addition polymerization of mono, di and triglycerides of saturated or unsaturated fatty acids. The number of carbon atoms of the saturated or unsaturated fatty acid is preferably 2 to 12, more preferably 4 to 12, most preferably 8 to 10, or a mixture thereof. The average molar number of addition of the ethylene oxide is 1 to 50 mol, preferably 2 to 30 mol, more preferably 2 to 30 mol, more preferably 1 to 5 mol, More preferably from 4 to 10 moles, per mole of the monomer.

The (E) polyoxyethylene (caprylic / capric acid) glyceryl is added in an amount of 0.5 to 10 wt%, preferably 1 to 8 wt%, more preferably 1.8 to 5 wt%, based on the total weight of the liquid detergent composition of the present invention %. ≪ / RTI > When the amount of the polyoxyethylene (capryl / capric acid) glyceryl (E) is less than 0.5% by weight, the effect of removing makeup is not sufficiently exhibited. When the amount exceeds 10% by weight, And the inner stimulus tends to become strong.

The liquid detergent composition of the present invention contains (E) glyceryl polyoxyethylene (caprylic / capric acid) as an essential component, whereby a remarkably excellent makeup removal effect can be obtained. When a nonionic surfactant other than the polyoxyethylene (capryl / capric acid) glyceryl (E), for example, glyceryl polyoxyethylene isostearate, is used, the effect of makeup removal of the present invention is sufficiently I can not get it.

In the present invention, (F) the polyhydric alcohol is included to prevent the clogging of the pump of the former container and impart a moisturizing feeling after cleaning. Examples of the polyhydric alcohol include glycerin, diglycerin, 1,3-butylene glycol, ethylene glycol, propylene glycol, dipropylene glycol, sorbitol, maltitol, 1,2-pentanediol and 1,2- , And the like. However, the present invention is not limited thereto.

The pH value of the liquid detergent composition of the present invention is not particularly limited, but may be slightly acidic at 25 占 폚 as 4.5 to 9, preferably 5 to 8.5, and more preferably 5.5 to 7 as the undiluted solution. The liquid detergent composition of the present invention has the advantage of improving the moisturizing effect after washing by keeping the pH at 4.5 to 9.0, which is hypoallergenic.

The present invention relates to a composition comprising (A) 1 to 20 wt% of an amino acid surfactant, (B) 0.4 to 15 wt% of an amphoteric surfactant, (C) 1 to 20 wt% of a nonionic surfactant, (F) a liquid detergent composition for a former container comprising 0.1 to 10% by weight of a polyoxyethylene (lauryl glycosyl carboxylate), (E) 0.5 to 10% by weight of polyoxyethylene (capryl / capric acid) glyceryl and do. The liquid detergent composition comprising such a specific weight ratio component combination is excellent in washing power, bubble resilience and low temperature stability, has no obstacle in the foam discharge, and has a weak skin irritating effect.

Further, the weight ratio of the amino acid surfactant (B), the amphoteric surfactant and the nonionic surfactant (A) / (B) + (C) may be 1.5 to 3.0, In this case, the cleaning power is excellently exhibited.

The present invention provides a liquid detergent product comprised in a foam container which is capable of mixing the liquid detergent composition with air and discharging it in a foamed state. The formulation of the liquid detergent composition of the present invention is not particularly limited, and any suitable liquid detergent cleaning agent for discharging the liquid detergent composition in a foam form may be used.

As the foam container, for example, a non-gas type foam discharge container or the like may be used. The non-gaseous foam discharge container is not particularly limited as long as the liquid detergent composition can be discharged in a foamed state by mixing with the air. For example, the non-gaseous foam discharge container may be a squeeze foam container capable of discharging foam by hand- And a pump former capable of discharging the foam by pressing down the nozzle portion, and can be appropriately selected and used according to the purpose. More specifically, for example, a pump such as a Darin pump or a die and a pipe may be used.

In the present invention, the former container may be a non-gas type foam discharge container and may include a porous membrane body for forming foam. As the material of the porous membrane body, a plastic material such as nylon, polyester or polyolefin may be used. The liquid detergent composition of the present invention can be used in a foamed state by passing through the porous membrane body of a foam container.

The porous membrane may be 100 mesh or more, preferably 100 to 400 mesh, more preferably 200 to 350 mesh, but is not limited thereto, and may be appropriately selected depending on the purpose. The number of the porous membrane bodies is preferably 2 to 4 in order to improve the performance of the foam, but is not limited thereto and can be appropriately selected depending on the purpose.

The liquid detergent composition of the present invention is capable of realizing excellent detergency, ease of rinsing, easiness of foaming, dense bubbles, feeling of mild feeling, and stability of phase such as low temperature stability. In addition, since the makeup cleansing power is improved, no double cleansing is required, and the clogging does not occur in the non-gas type foam pump, so that it is easy to apply in the pump former container and the pH of the composition is in a weak acid range. It does not stimulate the skin barrier after use, so it can be used universally regardless of the skin type.

Hereinafter, embodiments of the present invention will be described in detail to facilitate understanding of the present invention. However, the embodiments according to the present invention can be modified into various other forms, and the scope of the present invention should not be construed as being limited to the following embodiments. Embodiments of the invention are provided to more fully describe the present invention to those skilled in the art. In the following examples all percentages are by weight unless otherwise stated.

The compositions of Examples 1 to 8 and Comparative Examples 1 to 9 were prepared with the compositions shown in Table 1 and Table 2 below.

Example One 2 3 4 5 6 7 8 Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 glycerin 5 5 5 5 5 5 5 5 Butylene glycol 5 5 5 5 Dipropylene glycol 5 5 5 5 5 Potassium cocoyl glycinate 5 5 5 3 3 3 Sodium cocoyl glutamate 5 5 5 5 2 2 3 3 Sodium cocoylalaninate 5 5 3 5 3 3 Hydroxylaurylketone 2 One One One 2 One 2 One Cocamidopropyl betaine One 2 One 2 One 2 One 2 Lauryl glucoside One One 2 One One One One One Sodium dodeca-1, 2-diol acetic acid ether 0.5 One 0.5 One 0.5 One 0.5 One Polyoxyethylene (capryl / capric acid) glycerin 3 3 3 3 3 3 3 3 Preservative proper proper proper proper proper proper proper proper Spices proper proper proper proper proper proper proper proper Test items and results Makeup cleansing power 3.5 3.5 3.6 3.4 3.6 3.7 3.3 3.5 Elasticity of foam 90 90 90 90 90 90 90 90 Low temperature stability OK OK OK OK OK OK OK OK Blockage of pump O O O O O O O O Skin irritation 0.1 0.2 0.1 0.1 0.2 0.1 0.2 0.1

Comparative Example One 2 3 4 5 6 7 8 9 Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 glycerin 5 5 5 5 5 5 5 5 5 Butylene glycol - - - 5 5 5 5 - - Dipropylene glycol 5 5 5 - - - 5 5 5 Potassium cocoyl glycinate 5 5 5 5 2 3 3 - - Sodium cocoyl glutamate 2.5 5 5 One 3 2 3 - - Sodium cocoylalaninate 4 2 5 3 - - Higher fatty acid salt - - - - - - - 10 Sodium laureth sulfate 10 Hydroxylaurylketone 3 One 0.5 One One One 2 One One Cocamidopropyl betaine 2 One 0.5 2 One 2 One 2 2 Lauryl glucoside One One 2 One One One One One Sodium dodeca-1, 2-diol acetic acid ether 0.5 0.5 0.5 One - One 0.5 One One Polyoxyethylene (capryl / capric acid) glycerin 3 3 3 3 3 0.5 - 3 3 Polyoxyethylene glyceryl isostearate - - - - - - 3 - - Preservative proper proper proper proper proper proper proper proper proper Spices proper proper proper proper proper proper proper proper proper Test items and results Makeup cleansing power 2.1 2.2 2.4 3.0 2.5 2.2 1.8 3.0 2.8 Elasticity of foam 80 80 80 80 50 70 60 90 90 Low temperature stability OK OK OK Precipitation OK OK OK Precipitation OK Blockage of pump O O O O O O O X X Skin irritation 0.1 0.2 0.1 0.1 0.2 0.1 0.2 1.3 1.6

Experimental Example  1: Evaluation of makeup detergency

In order to compare the degree of makeup removal, lipstick and BB cream are applied to the panel at an area of 2cm x 2cm width x width and 10 persons for the panel. After applying lipstick and BB cream, leave the skin exposed at room temperature for 15 minutes. After 15 minutes, the skin was exposed to lukewarm water flowing through the skin applied with make-up for 5 seconds. Then, the pump (Darin pump T2) containing the skin cleanser compositions of Examples and Comparative Examples was pumped once and the foam was applied to the area for applying makeup And then, using appropriate force, roll with about 25 fingers. Rinse with water after making contact with the applied lukewarm water and roll 5 more times. After removing the water lightly, make-up removing force is compared visually.

In order to make an objective comparative judgment, 20 panelists made a feeling test. The average rating of 20 panelists was 3.0 or higher. However, even if the average score is 3.0 or higher, one panelist who evaluates the score as 1 points is rejected.

4.0 points: Makeup is reliably removed, and the cleansing power can be fully realized.

3.0 points: Most of the make-up is removed, and the cleansing power can be realized.

2.0 points: Some of the makeup is not removed and the cleansing power is not felt much.

1.0 point: Most of the makeup is not removed and the cleansing power can not be realized.

Experimental Example  2: Evaluation of elasticity of foam

The pellets were pumped 10 times using a pump vessel into a 200 ml beaker containing the detergent compositions of the examples and the comparative examples. The change in the foam height after 30 minutes and after the lapse of time was judged. The height x 100 after the initial height / . If the value is less than 70 at 30 minutes, it is judged that the elasticity of the foam is insufficient.

Experimental Example  3: Evaluation of low temperature stability

The detergent compositions of the examples and comparative examples were placed in a transparent plastic container and stored for 4 weeks in a thermostat at 4 ° C to observe the changes in properties. It is judged that it is not acceptable if the solid phase is submerged in the lower part of the solution due to separation of two or more phases or precipitation phenomenon.

Experimental Example  4: Evaluation of clogging of pump

The detergent composition was poured into a container having a foam forming former containing a three-stage mesh and pumped twice at the same intervals over time to measure the amount of the discharged detergent. By checking the deterioration of the detergent discharge amount with time, . If the amount of pumped two times at the elapsed time of 7 days is less than 80% of the amount pumped after the initial pumping, it is judged as a failure.

Experimental Example  5: Evaluation of skin irritation

Experiments were conducted to compare the skin irritancy after using the compositions of the examples and comparative examples of the present invention. Experiments on skin irritation were performed by comparing the stimuli sensed by the panel after using each composition. The score of each item of stigma and itching was graded from 0 to 3, and the score of each panel was averaged to evaluate the final skin irritation. The results are shown in Tables 1 and 2 below. If the average is 1.5 or more, it is judged to have failed. [No stimulus: 0, light stimulus: 1, moderate stimulus: 2, and river stimulation: 3].

The results of the evaluations of Experimental Examples 1 to 5 are shown in the lower portions of Tables 1 and 2 for the liquid skin cleanser compositions of Examples and Comparative Examples. It was confirmed that the compositions of Examples 1 to 8 exhibited excellent results in terms of makeup cleaning performance, foam elasticity, low temperature stability, clogging of the pump, and skin irritation.

On the other hand, in Comparative Example 1, the ratio of the content of the amino acid surfactant / (amphoteric surfactant + nonionic surfactant) was less than 1.5, and the makeup remained on the skin after washing.

Further, in Comparative Example 2, the content ratio of the amino acid surfactant / (amphoteric surfactant + nonionic surfactant) was more than 3, and the amount of the nonionic surfactant was insufficient relative to the amino acid surfactant, It can be confirmed that the active agent does not assist the detergency of the main surfactant and the detergency is poor.

Further, in Comparative Example 3, the amount of the amphoteric surfactant was small in relation to the blending amount of the nonionic surfactant, resulting in a feeling of use after giving a stiff feel. Also, there is a lack of feeling after being extracted from former container due to lack of bubble texture.

In addition, in Comparative Example 4, it was confirmed that the content of the glutamate surfactant in the amino acid surfactant was insufficient and precipitated at a low temperature.

In addition, in Comparative Example 5, since the sodium lauryl glycol carboxylate was not blended, the elasticity of the foam was reduced and the elasticity of the foam and the evaluation result of the cleaning power were rejected.

Further, in Comparative Example 6, the cleaning power was not sufficient because the ratio of polyoxyethylene (capryl / capric acid) glycerin was insufficient.

In Comparative Example 7, 3% of polyoxyethylene isostearic acid glycerin was added instead of polyoxyethylene (caprylic / capric acid) glycerin, but it was confirmed that the elasticity of the foam was poor and the washing power was also low.

In addition, in Comparative Example 8, the amount of the fatty acid salt contained in the Example was blended without adding the amino acid surfactant, and clogging of the pump occurred.

In addition, in Comparative Example 9, irritation of the skin occurs due to the incorporation of sodium laureth sulfate as much as the amount blended in the Examples, without the addition of the amino acid surfactant.

Claims (14)

(A) an amino acid surfactant, (B) an amphoteric surfactant, (C) a nonionic surfactant, (D) sodium lauryl glycocarboxylate, (E) polyoxyethylene (capryl / Re and (F) polyhydric alcohols. The composition according to claim 1, wherein the weight ratio of (A) the amino acid surfactant, (B) the amphoteric surfactant and (C) the nonionic surfactant is (A) / (B) + ≪ / RTI > by weight of a liquid detergent composition. The liquid detergent composition according to claim 1, wherein the composition comprises (A) an amino acid surfactant in an amount of 1 to 20 wt% based on the total weight of the composition. The liquid detergent composition according to claim 3, wherein the amino acid surfactant (A) comprises 10 to 30% by weight of glutamate based on the total weight of the amino acid surfactant. The liquid detergent composition of claim 1, wherein said composition comprises (B) 0.4 to 15% by weight of an amphoteric surfactant based on the total weight of the composition. The liquid detergent composition for a former container according to claim 1, wherein the composition comprises (C) 1 to 20% by weight of a nonionic surfactant based on the total weight of the composition. The composition of claim 1, wherein the composition is characterized in that the weight ratio of (B) amphoteric surfactant and (C) nonionic surfactant is from 5: 1 to 1: 1 (amphoteric surfactant: nonionic surfactant) Liquid detergent composition for foam containers. The liquid detergent composition of claim 1, wherein said composition comprises (D) sodium lauryl glycol carboxylate in an amount of from 0.1 to 10% by weight based on the total weight of the composition. 2. The liquid detergent composition of claim 1, wherein the composition comprises (E) 0.5 to 10% by weight of polyoxyethylene (caprylic / capric acid) glycerin based on the total weight of the composition. 2. The liquid detergent composition of claim 1, wherein the composition has a pH of 4.5 to 9. (A) 1 to 20% by weight of an amino acid surfactant, (B) 0.4 to 15% by weight of an amphoteric surfactant, (C) 1 to 20% by weight of a nonionic surfactant, (D) A liquid detergent composition for former containers comprising 0.1 to 10% by weight of lycoric acid carboxylate, (E) 0.5 to 10% by weight of polyoxyethylene (caprylic / capric acid) glyceryl and (F) a polyhydric alcohol. 12. The composition of claim 11, wherein the weight ratio of (A) the amino acid surfactant, (B) the amphoteric surfactant, and (C) the nonionic surfactant is (A) / (B) + ≪ / RTI > by weight of a liquid detergent composition. 13. A liquid detergent product comprising a foamable container in which the composition of any one of claims 1 to 12 can be mixed with air and discharged in a foamed state. 14. The liquid detergent product of claim 13, wherein the foamer container comprises a porous membrane body for forming a foam, the porous membrane body being 100 to 400 mesh.